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1

Jacob, Sarah, John Javornizky, George H. Wolf, and C. Austen Angell. "Oxide ion conducting glasses." International Journal of Inorganic Materials 3, no. 3 (June 2001): 241–51. http://dx.doi.org/10.1016/s1466-6049(01)00024-1.

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2

Minami, Tsutomu. "Fast ion conducting glasses." Journal of Non-Crystalline Solids 73, no. 1-3 (August 1985): 273–84. http://dx.doi.org/10.1016/0022-3093(85)90353-9.

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3

Burckhardt, W., B. Rudolph, and U. Schütze. "New Li+-ion conducting glasses." Solid State Ionics 28-30 (September 1988): 739–42. http://dx.doi.org/10.1016/s0167-2738(88)80137-1.

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4

Burckhardt, W. "New Li+-ion conducting glasses." Solid State Ionics 36, no. 3-4 (November 1989): 153–54. http://dx.doi.org/10.1016/0167-2738(89)90160-4.

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5

KADONO, K., K. MITANI, M. YAMASHITA, and H. TANAKA. "New lithium ion-conducting glasses." Solid State Ionics 47, no. 3-4 (September 1991): 227–30. http://dx.doi.org/10.1016/0167-2738(91)90243-5.

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6

Pradel, A., and M. Ribes. "Ion transport in superionic conducting glasses." Journal of Non-Crystalline Solids 172-174 (September 1994): 1315–23. http://dx.doi.org/10.1016/0022-3093(94)90658-0.

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7

Weitzel, Karl Michael. "Bombardment Induced Ion Transport through Ion Conducting Glasses." Diffusion Foundations 6 (February 2016): 107–43. http://dx.doi.org/10.4028/www.scientific.net/df.6.107.

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The recently developed bombardment induced ion transport (BIIT) technique is reviewed. BIIT is based on shining an energy-selected alkali ion beam at the surface of a sample of interest. Attachment of these ions leads to the build-up of a surface potential and a surface particle density. This in turn generates the corresponding gradients which induce ion transport towards a single metal electrode connected to the backside of the sample where it is detected as a neutralization current. Two different versions of BIIT are presented, i.) the native ion BIIT and ii.) the foreign ion BIIT. The former is demonstrated to provide access to absolute ionic conductivities and activation energies, the latter leads to the generation of electrodiffusion profiles. Theoretical modelling of these concentration profiles by means of the Nernst-Planck-Poisson theory allows to deduce the concentration dependence of diffusion coefficients.
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8

Bhattacharya, S., and A. Ghosh. "Electrical properties of ion conducting molybdate glasses." Journal of Applied Physics 100, no. 11 (2006): 114119. http://dx.doi.org/10.1063/1.2400116.

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9

Doi, Akira. "Free volumes in several ion-conducting glasses." Journal of Non-Crystalline Solids 246, no. 1-2 (April 1999): 155–58. http://dx.doi.org/10.1016/s0022-3093(99)00056-3.

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10

KUWANO, J. "Silver ion conducting glasses and some applications." Solid State Ionics 40-41 (August 1990): 696–99. http://dx.doi.org/10.1016/0167-2738(90)90101-v.

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11

CHOWDARI, B., R. GOPALAKRISHNAN, and K. TAN. "ESCA studies of fast ion conducting glasses." Solid State Ionics 40-41 (August 1990): 709–13. http://dx.doi.org/10.1016/0167-2738(90)90105-z.

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12

Swenson, J., and St Adams. "Structure-conductivity relations in ion conducting glasses." Ionics 9, no. 1-2 (January 2003): 28–35. http://dx.doi.org/10.1007/bf02376533.

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13

Frechero, M. A., L. Padilla, H. O. Mártin, and J. L. Iguain. "Intermediate-range structure in ion-conducting tellurite glasses." EPL (Europhysics Letters) 103, no. 3 (August 1, 2013): 36002. http://dx.doi.org/10.1209/0295-5075/103/36002.

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14

Bychkov, E. "Tracer diffusion studies of ion-conducting chalcogenide glasses." Solid State Ionics 136-137, no. 1-2 (November 2, 2000): 1111–18. http://dx.doi.org/10.1016/s0167-2738(00)00516-6.

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15

Luo, Zhiwei, Jing Zhang, Jianlei Liu, Jun Song, and Anxian Lu. "La2O3-added lithium-ion conducting silicate oxynitride glasses." Solid State Ionics 317 (April 2018): 76–82. http://dx.doi.org/10.1016/j.ssi.2018.01.008.

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16

Usuki, T., K. Nakajima, T. Furukawa, M. Sakurai, S. Kohara, T. Nasu, Y. Amo, and Y. Kameda. "Structure of fast ion conducting AgI–As2Se3 glasses." Journal of Non-Crystalline Solids 353, no. 32-40 (October 2007): 3040–44. http://dx.doi.org/10.1016/j.jnoncrysol.2007.05.036.

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17

Roling, B., and M. D. Ingram. "Mixed alkaline–earth effects in ion conducting glasses." Journal of Non-Crystalline Solids 265, no. 1-2 (March 2000): 113–19. http://dx.doi.org/10.1016/s0022-3093(99)00899-6.

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18

Saha, S. K., and D. Chakravorty. "Inhomogeneous conductor model and fast ion conducting glasses." Journal of Non-Crystalline Solids 167, no. 1-2 (January 1994): 89–91. http://dx.doi.org/10.1016/0022-3093(94)90371-9.

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19

Balkanski, M., R. F. Wallis, J. Deppe, and M. Massot. "Dynamical properties of fast-ion-conducting borate glasses." Materials Science and Engineering: B 12, no. 3 (February 1992): 281–98. http://dx.doi.org/10.1016/0921-5107(92)90300-x.

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20

Tatsumisago, M., and T. Minami. "Lithium ion conducting glasses prepared by rapid quenching." Materials Chemistry and Physics 18, no. 1-2 (October 1987): 1–17. http://dx.doi.org/10.1016/0254-0584(87)90107-6.

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21

Mehrer, Helmut. "Diffusion and Ion Conduction in Cation-Conducting Oxide Glasses." Diffusion Foundations 6 (February 2016): 59–106. http://dx.doi.org/10.4028/www.scientific.net/df.6.59.

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In this Chapter we review knowledge about diffusion and cation conduction in oxide glasses. We first remind the reader in Section 1 of major aspects of the glassy state and recall in Section 2 the more common glass families. The diffusive motion in ion-conducting oxide glasses can be studied by several techniques – measurements of radiotracer diffusion, studies of the ionic conductivity by impedance spectroscopy, viscosity studies and pressure dependent studies of tracer diffusion and ion conduction. These methods are briefly reviewed in Section 3. Radiotracer diffusion is element-specific, whereas ionic conduction is not. A comparison of both types of experiments can throw considerable light on the question which type of ions are carriers of ionic conduction. For ionic conductors Haven ratios can be obtained from the tracer diffusivity and the ionic conductivity for those ions which dominate the conductivity.In the following sections we review the diffusive motion of cations in soda-lime silicate glass and in several alkali-oxide glasses based mainly on results from our laboratory published in detail elsewhere, but we also take into account literature data.Section 4 is devoted to two soda-lime silicate glasses, materials which are commonly used for window glass and glass containers. A comparison between ionic conductivity and tracer diffusion of Na and Ca isotopes, using the Nernst-Einstein relation to deduce charge diffusivities, reveals that sodium ions are the carriers of ionic conduction in soda-lime glasses. A comparison with viscosity data on the basis of the Stokes-Einstein relation shows that the SiO2 network is many orders of magnitude less mobile than the relatively fast diffusing modifier cations Na. The Ca ions are less mobile than the Na ions but nevertheless Ca is considerably more mobile than the network.Section 5 summarizes results of ion conduction and tracer diffusion for single Na and single Rb borate glasses. Tracer diffusion and ionic conduction have been studied in single alkali-borate glasses as functions of temperature and pressure. The smaller ion is the faster diffusing species in its own glass. This is a common feature of all alkali oxide glasses. The Haven ratio of Na in Na borate glass is temperature independent whereas the Haven ratio of Rb diffusion in Rb borate glass decreases with decreasing temperature.Section 6 reviews major facts of alkali-oxide glasses with two different alkali ions. Such glasses reveal the so-called mixed-alkali effect. Its major feature is a deep minimum of the conductivity near some middle composition for the ratio of the two alkali ions. Tracer diffusion shows a crossover of the two tracer diffusivities as functions of the relative alkali content near the conductivity minimum. The values of the tracer diffusivities also reveal in which composition range which ions dominate ionic conduction. Tracer diffusion is faster for those alkali ions which dominate the composition of the mixed glass.Section 7 considers the pressure dependence of tracer diffusion and ionic conduction. Activation volumes of tracer diffusion and of charge diffusion are reviewed. By comparison of tracer and charge diffusion the so-called Haven ratios are obtained as functions of temperature, pressure and composition. The Haven ratio of Rb in Rb borate glass decreases with temperature and pressure whereas that of Na in Na borate glass is almost constant.Section 8 summarizes additional common features of alkali-oxide glasses. Activation enthalpies of charge diffusion decrease with decreasing average ion-ion distance. The Haven ratio is unity for large ion-ion distances and decreases with increasing alkali content and hence with decreasing ion-ion distance.Conclusions about the mechanism of diffusion are discussed in Section 9. The Haven ratio near unity at low alkali concentrations can be attributed to interstitial-like diffusion similar to interstitial diffusion in crystals. At higher alkali contents collective, chain-like motions of several ions prevail and lead to a decrease of the Haven ratio. The tracer diffusivities have a pressure dependence which is stronger than that of ionic conductivity. This entails a pressure-dependent Haven ratio, which can be attributed to an increasing degree of collectivity of the ionic jump process with increasing pressure. Monte Carlo simulations showed that the number of ions which participate in collective jump events increases with increasing ion content – i.e. with decreasing average ion-ion distance. For the highest alkali contents up to four ions can be involved in collective motion. Common aspects of the motion process of ions in glasses and of atoms in glassy metals are pointed out. Diffusion in glassy metals also occurs by collective motion of several atoms.Section 10 summarizes the major features of ionic conduction and tracer diffusion and its temperature and pressure dependence of oxide glasses.
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22

Jamnický, Miroslav, Jaroslav Sedláček, and Peter Znášik. "The Structure and Properties of Cuprous Ion Conducting Glasses." Solid State Phenomena 90-91 (April 2003): 221–26. http://dx.doi.org/10.4028/www.scientific.net/ssp.90-91.221.

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23

Sidebottom, D. L., and J. Zhang. "Scaling of the ac permittivity in ion-conducting glasses." Physical Review B 62, no. 9 (September 1, 2000): 5503–7. http://dx.doi.org/10.1103/physrevb.62.5503.

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24

Herczog, Andrew. "Sodium Ion Conducting Glasses for the Sodium‐Sulfur Battery." Journal of The Electrochemical Society 132, no. 7 (July 1, 1985): 1539–45. http://dx.doi.org/10.1149/1.2114161.

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25

Börjesson, L., L. M. Torell, and W. S. Howells. "Brillouin scattering and neutron diffraction in ion-conducting glasses." Philosophical Magazine B 59, no. 1 (January 1989): 105–23. http://dx.doi.org/10.1080/13642818908208450.

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26

Minami, T. "Preparation and characterization of lithium ion-conducting oxysulfide glasses." Solid State Ionics 136-137, no. 1-2 (November 2, 2000): 1015–23. http://dx.doi.org/10.1016/s0167-2738(00)00555-5.

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27

BANHATTI, R. "Dielectric function and localized diffusion in ion conducting glasses." Solid State Ionics 175, no. 1-4 (November 2004): 661–63. http://dx.doi.org/10.1016/j.ssi.2004.09.063.

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28

Deshpande, V. K., Megha A. Salorkar, and Nalini Nagpure. "Study of lithium ion conducting glasses with Li2SO4 addition." Journal of Non-Crystalline Solids 527 (January 2020): 119737. http://dx.doi.org/10.1016/j.jnoncrysol.2019.119737.

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29

Swenson, J., L. Börjesson, R. L. McGreevy, and W. S. Howells. "Structure and conductivity of fast ion-conducting borate glasses." Physica B: Condensed Matter 234-236 (June 1997): 386–87. http://dx.doi.org/10.1016/s0921-4526(96)01037-x.

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30

Staesche, Halgard, Sevi Murugavel, and Bernhard Roling. "Nonlinear Conductivity and Permittivity Spectra of Ion Conducting Glasses." Zeitschrift für Physikalische Chemie 223, no. 10-11 (December 2009): 1229–38. http://dx.doi.org/10.1524/zpch.2009.6076.

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31

DALBA, G., P. FORNASINI, F. ROCCA, and E. BURATTINI. "XANES IN FAST ION CONDUCTING GLASSES AgI : Ag2O : B2O3." Le Journal de Physique Colloques 47, no. C8 (December 1986): C8–749—C8–752. http://dx.doi.org/10.1051/jphyscol:19868142.

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32

Kowada, Y., M. Tatsumisago, T. Minami, and H. Adachi. "Electronic state of sulfide-based lithium ion conducting glasses." Journal of Non-Crystalline Solids 354, no. 2-9 (January 2008): 360–64. http://dx.doi.org/10.1016/j.jnoncrysol.2007.07.085.

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33

Price, David Long, and Adam J. G. Ellison. "Atomic structure and dynamics of fast-ion conducting glasses." Journal of Non-Crystalline Solids 177 (November 1994): 293–98. http://dx.doi.org/10.1016/0022-3093(94)90543-6.

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34

Salorkar, Megha A., and V. K. Deshpande. "Study of lithium ion conducting glasses for solid electrolyte application." Physica B: Condensed Matter 627 (February 2022): 413590. http://dx.doi.org/10.1016/j.physb.2021.413590.

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35

Shastry, M. C. R., and K. J. Rao. "Physico chemical investigation of fast ion conducting AgI−Ag2SeO4 glasses." Proceedings / Indian Academy of Sciences 102, no. 4 (August 1990): 541–53. http://dx.doi.org/10.1007/bf02867833.

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36

Mori, Kazuhiro. "Structure Studies of Lithium Ion Conducting Glasses Using Neutron Diffraction." Materia Japan 56, no. 7 (2017): 443–47. http://dx.doi.org/10.2320/materia.56.443.

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37

Ohto, M., and K. Tanaka. "Scanning tunneling spectroscopy of Ag–As–Se ion-conducting glasses." Applied Physics Letters 71, no. 23 (December 8, 1997): 3409–11. http://dx.doi.org/10.1063/1.120350.

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38

Roling, B., and C. Martiny. "Nonuniversal Features of the ac Conductivity in Ion Conducting Glasses." Physical Review Letters 85, no. 6 (August 7, 2000): 1274–77. http://dx.doi.org/10.1103/physrevlett.85.1274.

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39

Bokova, M., I. Alekseev, and E. Bychkov. "Tl+ ion Conducting Glasses in the Tl-Ge-S System." Physics Procedia 44 (2013): 35–44. http://dx.doi.org/10.1016/j.phpro.2013.04.005.

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40

Swenson, J. "Relations between structure and conductivity in fast ion conducting glasses." Solid State Ionics 105, no. 1-4 (January 1, 1998): 55–65. http://dx.doi.org/10.1016/s0167-2738(97)00449-9.

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41

BHATTACHARYA, S., and A. GHOSH. "Relaxation of silver ions in fast ion conducting molybdate glasses." Solid State Ionics 176, no. 13-14 (April 29, 2005): 1243–47. http://dx.doi.org/10.1016/j.ssi.2005.03.002.

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42

Dyre, Jeppe C. "Is there a ‘native’ band gap in ion conducting glasses?" Journal of Non-Crystalline Solids 324, no. 1-2 (August 2003): 192–95. http://dx.doi.org/10.1016/s0022-3093(03)00237-0.

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43

Gowda, V. C. Veeranna, R. V. Anavekar, and K. J. Rao. "Elastic properties of fast ion conducting lithium based borate glasses." Journal of Non-Crystalline Solids 351, no. 43-45 (November 2005): 3421–29. http://dx.doi.org/10.1016/j.jnoncrysol.2005.09.002.

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44

Doi, Akira. "Simulation and scaling of ac conductivities in ion-conducting glasses." Journal of Non-Crystalline Solids 352, no. 8 (June 2006): 777–82. http://dx.doi.org/10.1016/j.jnoncrysol.2006.02.031.

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45

Julien, C. "Annealing studies of fast ion conducting glasses by FTIR microscopy." Solid State Ionics 34, no. 4 (June 1989): 269–73. http://dx.doi.org/10.1016/0167-2738(89)90454-2.

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46

Swenson, J., A. Matic, C. Karlsson, L. Börjesson, and W. S. Howells. "Free volume and dissociation effects in fast ion conducting glasses." Journal of Non-Crystalline Solids 263-264 (March 2000): 73–81. http://dx.doi.org/10.1016/s0022-3093(99)00670-5.

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47

Mehrer, Helmut. "Diffusion in Ion-conducting Oxide Glasses and in Glassy Metals." Zeitschrift für Physikalische Chemie 223, no. 10-11 (December 2009): 1143–60. http://dx.doi.org/10.1524/zpch.2009.6070.

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48

Schäf, O. "Potentiometric CO2 - sensors with ion - conducting glasses as solid electrolytes." Ionics 2, no. 3-4 (May 1996): 266–73. http://dx.doi.org/10.1007/bf02376033.

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49

Horopanitis, E. E., G. Perentzis, E. Pavlidou, and L. Papadimitriou. "Electrical properties of lithiated boron oxide fast-ion conducting glasses." Ionics 9, no. 1-2 (January 2003): 88–94. http://dx.doi.org/10.1007/bf02376543.

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50

Minami, T., and N. Machida. "Preparation of Cu+ ion-conducting glasses and mixed-anion effect in conductivity of the glasses." Materials Chemistry and Physics 23, no. 1-2 (August 1989): 63–74. http://dx.doi.org/10.1016/0254-0584(89)90017-5.

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