Journal articles on the topic 'Intermolecular forces'

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1

Leckband, Deborah, and Jacob Israelachvili. "Intermolecular forces in biology." Quarterly Reviews of Biophysics 34, no. 2 (May 2001): 105–267. http://dx.doi.org/10.1017/s0033583501003687.

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0. Abbreviations 1061. Introduction: overview of forces in biology 1081.1 Subtleties of biological forces and interactions 1081.2 Specific and non-specific forces and interactions 1131.3 van der Waals (VDW) forces 1141.4 Electrostatic and ’double-layer‘ forces (DLVO theory) 1221.4.1 Electrostatic and double-layer interactions at very small separation 1261.5 Hydration and hydrophobic forces (structural forces in water) 1311.6 Steric, bridging and depletion forces (polymer-mediated and tethering forces) 1371.7 Thermal fluctuation forces: entropic protrusion and undulation forces 1421.8 Comparison of the magnitudes of the major non-specific forces 1461.9 Bio-recognition 1461.10 Equilibrium and non-equilibrium forces and interactions 1501.10.1 Multiple bonds in parallel 1531.10.2 Multiple bonds in series 1552. Experimental techniques for measuring forces between biological molecules and surfaces 1562.1 Different force-measuring techniques 1562.2 Measuring forces between surfaces 1612.3 Measuring force–distance functions, F(D) 1612.4 Relating the forces between different geometries: the ‘Derjaguin Approximation’ 1622.5 Adhesion forces and energies 1642.5.1 An example of the application of adhesion mechanics of biological adhesion 1662.6 Measuring forces between macroscopic surfaces: the surface forces apparatus (SFA) 1672.7 The atomic force microscope (AFM) and microfiber cantilever (MC) techniques 1732.8 Micropipette aspiration (MPA) and the bioforce probe (BFP) 1772.9 Osmotic stress (OS) and osmotic pressure (OP) techniques 1792.10 Optical trapping and the optical tweezers (OT) 1812.11 Other optical microscopy techniques: TIRM and RICM 1842.12 Shear flow detachment (SFD) measurements 1872.13 Cell locomotion on elastically deformable substrates 1893. Measurements of equilibrium (time-independent) interactions 1913.1 Long-range VDW and electrostatic forces (the two DVLO forces) between biosurfaces 1913.2 Repulsive short-range steric–hydration forces 1973.3 Adhesion forces due to VDW forces and electrostatic complementarity 2003.4 Attractive forces between surfaces due to hydrophobic interactions: membrane adhesion and fusion 2093.4.1 Hydrophobic interactions at the nano- and sub-molecular levels 2113.4.2 Hydrophobic interactions and membrane fusion 2123.5 Attractive depletion forces 2133.6 Solvation (hydration) forces in water: forces associated with water structure 2153.7 Forces between ‘soft-supported’ membranes and proteins 2183.8 Equilibrium energies between biological surfaces 2194. Non-equilibrium and time-dependent interactions: sequential events that evolve in space and time 2214.1 Equilibrium and non-equilibrium time-dependent interactions 2214.2 Adhesion energy hysteresis 2234.3 Dynamic forces between biomolecules and biomolecular aggregates 2264.3.1 Strengths of isolated, noncovalent bonds 2274.3.2 The strengths of isolated bonds depend on the activation energy for unbinding 2294.4 Simulations of forced chemical transformations 2324.5 Forced extensions of biological macromolecules 2354.6 Force-induced versus thermally induced chemical transformations 2394.7 The rupture of bonds in series and in parallel 2424.7.1 Bonds in series 2424.7.2 Bonds in parallel 2444.8 Dynamic interactions between membrane surfaces 2464.8.1 Lateral mobility on membrane surfaces 2464.8.2 Intersurface forces depend on the rate of approach and separation 2494.9 Concluding remarks 2535. Acknowledgements 2556. References 255While the intermolecular forces between biological molecules are no different from those that arise between any other types of molecules, a ‘biological interaction’ is usually very different from a simple chemical reaction or physical change of a system. This is due in part to the higher complexity of biological macromolecules and systems that typically exhibit a hierarchy of self-assembling structures ranging in size from proteins to membranes and cells, to tissues and organs, and finally to whole organisms. Moreover, interactions do not occur in a linear, stepwise fashion, but involve competing interactions, branching pathways, feedback loops, and regulatory mechanisms.
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2

Keating, S. P. "Optics and intermolecular forces." Molecular Physics 58, no. 1 (May 1986): 33–52. http://dx.doi.org/10.1080/00268978600100971.

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3

Henderson, S. J., and J. W. White. "Microassembly by intermolecular forces." Journal of Applied Crystallography 21, no. 6 (December 1, 1988): 744–50. http://dx.doi.org/10.1107/s0021889888008118.

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4

Chen, Wenhua, and Jan A. K. Paul. "Intermolecular Forces in Porphyrin Crystals." Inorganic Chemistry 34, no. 1 (January 1995): 199–201. http://dx.doi.org/10.1021/ic00105a033.

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5

Meot-Ner, Michael. "Intermolecular forces in organic clusters." Journal of the American Chemical Society 114, no. 9 (April 1992): 3312–22. http://dx.doi.org/10.1021/ja00035a024.

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6

Gupta, N. P. "Intermolecular forces in solid neon." Solid State Communications 54, no. 11 (June 1985): 1017–20. http://dx.doi.org/10.1016/0038-1098(85)90177-2.

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7

Liang, Ying Q., and K. L. C. Hunt. "Intramolecular screening of intermolecular forces." Journal of Chemical Physics 98, no. 6 (March 15, 1993): 4626–35. http://dx.doi.org/10.1063/1.464990.

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8

ROAMBA, Brahima, Jean de Dieu ZABSONRE, and Yacouba ZONGO. "On the Existence of Global Weak Solutions to 1D Pollutant Transport Model." Journal of Mathematics Research 9, no. 4 (July 23, 2017): 124. http://dx.doi.org/10.5539/jmr.v9n4p124.

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We consider a one-dimensionnal bilayer model coupling shallow water and Reynolds lubrication equations with a molecular interactions between molecules. These molecular interactions give rise to intermolecular forces, namely the long-range van der Waals forces and short-range Born intermolecular forces. In this paper, an expression will be used to take into account all these intermolecular forces. Our model is a similar model studied in (Roamba, Zabsonré & Zongo, 2017). The model considered is represented by the two superposed immiscible fluids. A similar model was studied in (Zabsonré Lucas & Fernandez-Nieto, 2009) but the authors do not take into account the intermolecular forces. Without hypothesis about the unknowns as in (Roamba, Zabsonré & Zongo, 2017), we show the existence of global weak solution in time in a periodic domain.
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9

Patrick, Chris. "Altering intermolecular forces with optical cavities." Scilight 2021, no. 10 (March 5, 2021): 101106. http://dx.doi.org/10.1063/10.0003732.

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10

Wash, Paul L., Shihong Ma, Ulrike Obst, and Julius Rebek. "Nitrogen−Halogen Intermolecular Forces in Solution." Journal of the American Chemical Society 121, no. 34 (September 1999): 7973–74. http://dx.doi.org/10.1021/ja991653m.

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11

Yaminsky, I., P. Gorelkin, and G. Kiselev. "Concurrence of Intermolecular Forces in Monolayers." Japanese Journal of Applied Physics 45, no. 3B (March 27, 2006): 2316–18. http://dx.doi.org/10.1143/jjap.45.2316.

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12

Hall, Randall W., and Peter G. Wolynes. "Intermolecular Forces and the Glass Transition†." Journal of Physical Chemistry B 112, no. 2 (January 2008): 301–12. http://dx.doi.org/10.1021/jp075017j.

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13

Elrod, Matthew J., and Richard J. Saykally. "Many-Body Effects in Intermolecular Forces." Chemical Reviews 94, no. 7 (November 1994): 1975–97. http://dx.doi.org/10.1021/cr00031a010.

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14

Zhang, X., and Vincent T. Moy. "Intermolecular Forces of Leukocyte Adhesion Molecules." Microscopy and Microanalysis 10, S02 (August 2004): 1422–23. http://dx.doi.org/10.1017/s1431927604886902.

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15

Mathpal, Rajesh, B. K. Joshi, S. Joshi, and N. D. Kandpal. "Intermolecular Forces of Sugars in Water." Monatshefte für Chemie - Chemical Monthly 137, no. 3 (February 15, 2006): 375–79. http://dx.doi.org/10.1007/s00706-005-0435-3.

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16

Mahanty, J. "Screening of Intermolecular Forces in Adsorbates." Acta Physica Polonica A 81, no. 1 (January 1992): 73–84. http://dx.doi.org/10.12693/aphyspola.81.73.

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17

Gao, J., and J. H. Weiner. "Screened intermolecular forces and covalent bond forces in polymer melts." Journal of Chemical Physics 98, no. 10 (May 15, 1993): 8256–61. http://dx.doi.org/10.1063/1.464530.

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18

Oh, Eun-Suok, Jay R. Walton, and John C. Slattery. "A Theory of Fracture Based Upon an Extension of Continuum Mechanics to the Nanoscale." Journal of Applied Mechanics 73, no. 5 (November 23, 2005): 792–98. http://dx.doi.org/10.1115/1.2166651.

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A theory of fracture is presented that is based upon an extension of continuum mechanics to the nanoscale through the incorporation of long-range intermolecular forces which correct bulk material descriptions near interfaces. The surface energy on crack surfaces, which is given in terms of the long-range intermolecular forces, plays an important role in an expression for the stress distribution near the crack tip. It is observed through numerical simulation that the incorporation of these long-range intermolecular forces removes the square-root stress singularity predicted by classical linear elastic fracture mechanics.
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19

Lin, F., R. Wang, L. Liu, B. Li, L. W. Ouyang, and W. J. Liu. "Enhanced intermolecular forces in supramolecular polymer nanocomposites." Express Polymer Letters 11, no. 9 (2017): 690–703. http://dx.doi.org/10.3144/expresspolymlett.2017.67.

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20

Niblett, Samuel P., Mirza Galib, and David T. Limmer. "Learning intermolecular forces at liquid–vapor interfaces." Journal of Chemical Physics 155, no. 16 (October 28, 2021): 164101. http://dx.doi.org/10.1063/5.0067565.

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21

Hocking, L. M. "The spreading of drops with intermolecular forces." Physics of Fluids 6, no. 10 (October 1994): 3224–28. http://dx.doi.org/10.1063/1.868054.

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22

Ewing, M. B., M. L. McGlashan, and J. P. M. Trusler. "Intermolecular forces from the speed of sound." Molecular Physics 60, no. 3 (February 20, 1987): 681–90. http://dx.doi.org/10.1080/00268978700100461.

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23

Borden, Mark Andrew. "Intermolecular Forces Model for Lipid Microbubble Shells." Langmuir 35, no. 31 (December 13, 2018): 10042–51. http://dx.doi.org/10.1021/acs.langmuir.8b03641.

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24

Eckberg, Christine, John Zimmer, James Reeves, and Charles Ward. "An Intermolecular Forces Study Using IBM PSL." Journal of Chemical Education 71, no. 9 (September 1994): A225. http://dx.doi.org/10.1021/ed071pa225.

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25

Thakkar, A. J. "William J. Meath—doyen of intermolecular forces." Journal of Molecular Structure: THEOCHEM 591, no. 1-3 (August 2002): viii—x. http://dx.doi.org/10.1016/s0166-1280(02)00204-x.

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26

Benhamou, Mabrouk. "Theory of Intermolecular Forces, by Anthony Stone." Contemporary Physics 54, no. 4 (July 2013): 227–28. http://dx.doi.org/10.1080/00107514.2013.833992.

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27

Burgos, E., E. Halac, and H. Bonadeo. "Intermolecular forces and phase transitions in solidC60." Physical Review B 49, no. 22 (June 1, 1994): 15544–49. http://dx.doi.org/10.1103/physrevb.49.15544.

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28

Gao, Jiabin, Djamal Djaidi, Christopher E. Marjo, Mohan M. Bhadbhade, Alison T. Ung, and Roger Bishop. "Weak Intermolecular Forces, but High Melting Points." Australian Journal of Chemistry 70, no. 5 (2017): 538. http://dx.doi.org/10.1071/ch16565.

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The poorly soluble racemic compound 6,6a,13,13a-tetrahydropentaleno[1,2-b:4,5-b′]diquinoline (4) has an exceptionally high melting point range of 352–354°C despite its low molar mass (308.38) and a structure containing only 40 atoms (38 of which are C and H). Analysis of the X-ray crystal structure and Hirshfeld surface of 4, along with comparison with its isostructural homologue 2, reveals how this occurs in the absence of Pauling-type hydrogen bonding. Excellent complementarity between homochiral molecules of 4 allows formation of enantiomerically pure layers using C–H⋯π, aromatic π⋯π, and C–H⋯N interactions. The alternating layers of opposite handedness are then crosslinked by means of aza-1,3-peri hydrogen interactions. This bifurcated C–H⋯N⋯H–C motif acts as a molecular clip creating a highly rigid network structure. The role of weaker intermolecular forces in influencing the solubility and bioavailability of potential drug molecules is discussed in the context of the popular Lipinski ‘rule of 5’ guidelines.
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29

Pirani, Fernando, Mario Capitelli, Gianpiero Colonna, and Annarita Laricchiuta. "Transport cross sections from accurate intermolecular forces." Rendiconti Lincei. Scienze Fisiche e Naturali 30, no. 1 (February 2, 2019): 49–56. http://dx.doi.org/10.1007/s12210-019-00773-0.

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30

Dickrell, Daniel J., and W. Gregory Sawyer. "Intermolecular Forces, Adhesion, and the Elastic Foundation." Tribology Letters 50, no. 2 (March 20, 2013): 245–60. http://dx.doi.org/10.1007/s11249-013-0117-y.

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31

Allen, K. W. "Cohesion: a scientific history of intermolecular forces." International Journal of Adhesion and Adhesives 24, no. 2 (April 2004): 180. http://dx.doi.org/10.1016/j.ijadhadh.2003.08.001.

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32

Hurst, G. J. B., P. W. Fowler, A. J. Stone, and A. D. Buckingham. "Intermolecular forces in van der waals dimers." International Journal of Quantum Chemistry 29, no. 5 (May 1986): 1223–39. http://dx.doi.org/10.1002/qua.560290520.

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33

Szalewicz, Krzysztof. "Symmetry-adapted perturbation theory of intermolecular forces." Wiley Interdisciplinary Reviews: Computational Molecular Science 2, no. 2 (August 30, 2011): 254–72. http://dx.doi.org/10.1002/wcms.86.

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34

Dykstra, Clifford E. "Finding the way through intermolecular forces. Perspective on "Permanent and induced molecular moments and long-range intermolecular forces"." Theoretical Chemistry Accounts: Theory, Computation, and Modeling (Theoretica Chimica Acta) 103, no. 3-4 (February 9, 2000): 278–80. http://dx.doi.org/10.1007/s002140050035.

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35

Dykstra, Clifford E. "Finding the way through intermolecular forces. Perspective on “Permanent and induced molecular moments and long-range intermolecular forces”." Theoretical Chemistry Accounts 103, no. 3 (February 9, 2000): 0278–80. http://dx.doi.org/10.1007/s002149900039.

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36

Hou, Xin, Jingyang Li, Yuanzhe Li, and Yu Tian. "Intermolecular and surface forces in atomic-scale manufacturing." International Journal of Extreme Manufacturing 4, no. 2 (March 28, 2022): 022002. http://dx.doi.org/10.1088/2631-7990/ac5e13.

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Abstract Atomic and close-to-atomic scale manufacturing (ACSM) aims to provide techniques for manufacturing in various fields, such as circuit manufacturing, high energy physics equipment, and medical devices and materials. The realization of atomic scale material manipulation depending on the theoretical system of classical mechanics faces great challenges. Understanding and using intermolecular and surface forces are the basis for better designing of ACSM. Transformation of atoms based on scanning tunneling microscopy or atomic force microscopy (AFM) is an essential process to regulate intermolecular interactions. Self-assemble process is a thermodynamic process involving complex intermolecular forces. The competition of these interaction determines structure assembly and packing geometry. For typical nanomachining processes including AFM nanomachining and chemical mechanical polishing, the coupling of chemistry and stress (tribochemistry) assists in the removal of surface atoms. Furthermore, based on the principle of triboelectrochemistry, we expect a further reduction of the potential barrier, and a potential application in high-efficiency atoms removal and fabricating functional coating. Future fundamental research is proposed for achieving high-efficiency and high-accuracy manufacturing with the aiding of external field. This review highlights the significant contribution of intermolecular and surface forces to ACSM, and may accelerate its progress in the in-depth investigation of fundamentals.
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37

Apriliani*, Fera, Erlina Erlina, Husna Amalya Melati, Rody Putra Sartika, and Ira Lestari. "Pengembangan Video Gaya Antarmolekul Berbasis Multipel Representasi untuk Mengatasi Miskonsepsi." Jurnal Pendidikan Sains Indonesia 10, no. 4 (October 22, 2022): 790–802. http://dx.doi.org/10.24815/jpsi.v10i4.25890.

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Intermolecular forces are one of the topics in basic chemistry. Intermolecular forces consist of abstract concepts that require multiple representations (macroscopic, submicroscopic, and symbolic) to visualize those concepts. Moreover, the multiple representations are needed to help students understand the abstract concepts of intermolecular forces. Multiple representations were presented as pictures, diagrams, and animation in the videos. The aims of this research are to develop a video of intermolecular forces based on multiple representations and to determine the level of validity and student’s responses to the video. This study employs the 4D method formulated by Thiagarajan which consist of 4 stages. However, this study only adopted 3 stages; define (to know the problem), design (manufacture of product to solve the problem), and development (to determine the level of validity and student responses). The instruments used in this study were the validity and the response questionnaires. Data collected were then analyzed using the percentage criteria proposed by Riduwan. The video provides the conceps and real-life example of the London forces and hydrogen bonding. Video validation shows the level of subject matter validity is 95,38%, media validity is 98,89%, and language validity is 91,11%, where all the aspects were very valid criteria. Every aspect is validated by 3 experts. Student responses on a limited scale by 7 students show a percentage of 87,8% and a large scale by 20 students of 88,9% with very good criteria. Based on the result, the video can be used in the study of intermolecular forces
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38

Yan, Rong, Xin Hua Li, and Xiao Jun Qi. "Study on Intermolecular Forces of Corn Gluten with the Chemical Reagent Treatment." Advanced Materials Research 1049-1050 (October 2014): 547–50. http://dx.doi.org/10.4028/www.scientific.net/amr.1049-1050.547.

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Corn gluten were steeped with different chemical reagents, 2%urea, 5%tween80, 5% NaCl, 2%L - cysteine, using distilled water as control. Intermolecular forces in corn gluten under different reagents were analyzed using the amount of free starch measuring by iodine calorimetry. By the light microscope, intermolecular structure transformation in corn gluten was analyzed before the treatment and after. The results show that Urea, twain, NaCl, and L-cysteine all can make the starch that closely combined with protein migrate away, in which the effect of L-cysteine and NaCl were better, releasing more free starch. It is found through microscopic observation that the starch granule existing in corn gluten is small granule from cutin endosperm, and microscopic observation results consistent with the free starch results. By analysis of the amount of free starch and the microscopic structure change of corn gluten and the mechanism of measuring intermolecular forces with the chemical reagent, it is demonstrated that disulfide bond and electrostatic attraction were main intermolecular forces in corn gluten, which was the main reason for the search combining with the protein .The effect of intermolecular hydrogen bonds and hydrophobic interaction were weaker.
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39

Chaw, K. C., M. Manimaran, and Francis E. H. Tay. "Role of Silver Ions in Destabilization of Intermolecular Adhesion Forces Measured by Atomic Force Microscopy in Staphylococcus epidermidis Biofilms." Antimicrobial Agents and Chemotherapy 49, no. 12 (December 2005): 4853–59. http://dx.doi.org/10.1128/aac.49.12.4853-4859.2005.

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ABSTRACT In this paper, we report on the potential use of atomic force microscopy (AFM) as a tool to measure the intermolecular forces in biofilm structures and to study the effect of silver ions on sessile Staphylococcus epidermidis cell viability and stability. We propose a strategy of destabilizing the biofilm matrix by reducing the intermolecular forces within the extracellular polymeric substances (EPSs) using a low concentration (50 ppb) of silver ions. Our AFM studies on the intermolecular forces within the EPSs of S. epidermidis RP62A and S.epidermidis 1457 biofilms suggest that the silver ions can destabilize the biofilm matrix by binding to electron donor groups of the biological molecules. This leads to reductions in the number of binding sites for hydrogen bonds and electrostatic and hydrophobic interactions and, hence, the destabilization of the biofilm structure.
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40

Pacheco Santos, Valderi. "Phase Equilibrium: Influence of the Intermolecular Forces on Phase Diagrams." Revista Virtual de Química 12, no. 6 (2020): 1541–58. http://dx.doi.org/10.21577/1984-6835.20200117.

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41

Mistry, Aashutosh. "Intermolecular forces for self-assembly identified through simulations." MRS Bulletin 42, no. 07 (July 2017): 482–83. http://dx.doi.org/10.1557/mrs.2017.151.

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42

Marques, Jorge M. C., Frederico V. Prudente, and Fernando Pirani. "Intermolecular Forces: From Atoms and Molecules to Nanostructures." Molecules 27, no. 10 (May 11, 2022): 3072. http://dx.doi.org/10.3390/molecules27103072.

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Intermolecular forces, determined by the critical balance of interacting components having physical and chemical natures, control most of the static and dynamic properties of matter such as their existence in solid, liquid and gaseous phases, with their relative stability, and their chemical reactivity [...]
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43

Yoo, Jejoong, and Aleksei Aksimentiev. "The structure and intermolecular forces of DNA condensates." Nucleic Acids Research 44, no. 5 (February 15, 2016): 2036–46. http://dx.doi.org/10.1093/nar/gkw081.

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44

Clary, David C., and James P. Henshaw. "Chemical reactions dominated by long-range intermolecular forces." Faraday Discussions of the Chemical Society 84 (1987): 333. http://dx.doi.org/10.1039/dc9878400333.

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45

Moy, V., E. Florin, and H. Gaub. "Intermolecular forces and energies between ligands and receptors." Science 266, no. 5183 (October 14, 1994): 257–59. http://dx.doi.org/10.1126/science.7939660.

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46

Westwell, Martin S., Mark S. Searle, David J. Wales, and Dudley H. Williams. "Empirical Correlations between Thermodynamic Properties and Intermolecular Forces." Journal of the American Chemical Society 117, no. 18 (May 1995): 5013–15. http://dx.doi.org/10.1021/ja00123a001.

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47

Mundell, Donald W., and James H. Maynard. "Dancing Crystals: A Dramatic Illustration of Intermolecular Forces." Journal of Chemical Education 84, no. 11 (November 2007): 1773. http://dx.doi.org/10.1021/ed084p1773.

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48

Rantih, N. K., S. Mulyani, and T. Widhiyanti. "An analyses of multiple representation about intermolecular forces." Journal of Physics: Conference Series 1157 (February 2019): 042029. http://dx.doi.org/10.1088/1742-6596/1157/4/042029.

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49

Trenzado, J. L., S. Rozas, R. Alcalde, M. Atilhan, and S. Aparicio. "Intermolecular forces in pyrrolidones + 1,2-alkanediol liquid mixtures." Journal of Molecular Liquids 302 (March 2020): 112539. http://dx.doi.org/10.1016/j.molliq.2020.112539.

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50

Peckham, Gavin D., and Ian J. McNaught. "Teaching Intermolecular Forces to First-Year Undergraduate Students." Journal of Chemical Education 89, no. 7 (April 18, 2012): 955–57. http://dx.doi.org/10.1021/ed200802p.

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