Academic literature on the topic 'Interfacial enrichment'

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Journal articles on the topic "Interfacial enrichment"

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Zhao, Yue, Yu Ding, Bin Qiao, Kai Zheng, Pei Liu, Fumin Li, Shuni Li, and Yu Chen. "Interfacial proton enrichment enhances proton-coupled electrocatalytic reactions." Journal of Materials Chemistry A 6, no. 36 (2018): 17771–77. http://dx.doi.org/10.1039/c8ta06856a.

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PdNi alloy nanostructures–polyethyleneimine inorganic–organic nanocomposites exhibit enhanced catalytic activity for the oxygen reduction reaction and hydrogen evolution reaction in acidic media due to interfacial proton enrichment.
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Beier, J. A., Stuart G. Wakeham, C. H. Pilskaln, and S. Honjo. "Enrichment in saturated compounds of Black Sea interfacial sediment." Nature 351, no. 6328 (June 1991): 642–44. http://dx.doi.org/10.1038/351642a0.

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Yang, Yafan, Weiwei Zhu, Yukun Ji, Tao Wang, and Guangsi Zhao. "Interfacial Properties of H2O+CO2+Oil Three-Phase Systems: A Density Gradient Theory Study." Atmosphere 13, no. 4 (April 14, 2022): 625. http://dx.doi.org/10.3390/atmos13040625.

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The interfacial property of H2O+CO2+oil three-phase systems is crucial for CO2 flooding and sequestration processes but was not well understood. Density gradient theory coupled with PC-SAFT equation of state was applied to investigate the interfacial tension (IFT) of H2O+CO2+oil (hexane, cyclohexane, and benzene) systems under three-phase conditions (temperature in the range of 323–423 K and pressure in the range of 1–10 MPa). The IFTs of the aqueous phase+vapor phase in H2O+CO2+oil three-phase systems were smaller than the IFTs in H2O+CO2 two-phase systems, which could be explained by enrichment of oil in the interfacial region. The difference between IFTs of aqueous phase+vapor phase in the three-phase system and IFTs in H2O+CO2 two-phase system was largest in the benzene case and smallest in the cyclohexane case due to different degrees of oil enrichment in the interface. Meanwhile, CO2 enrichment was observed in the interfacial region of the aqueous phase+oil-rich phase, which led to the reduction of IFT with increasing pressure while different pressure effects were observed in the H2O+oil two-phase systems. The effect of CO2 on the IFTs of aqueous phase+benzene-rich phase interface was small in contrast to that on the IFTs of aqueous phase+alkane (hexane or cyclohexane)-rich phase interface. H2O had little effect on the interfacial properties of the oil-rich phase+vapor phase due to the low H2O solubilities in the oil and vapor phase. Further, the spreading coefficients of H2O+CO2 in the presence of different oil followed this sequence: benzene > hexane > cyclohexane.
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Chen, Xia, Wei Zhao, and Pengxiang Li. "Elements enrichment characteristics in interfacial transition zone of MgO concrete." Wuhan University Journal of Natural Sciences 18, no. 1 (January 31, 2013): 88–92. http://dx.doi.org/10.1007/s11859-013-0898-8.

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Chen, Kuan-Yu, Webber Wei-Po Lai, Hui-Ju Wang, Cheng-Chieh Lin, Chun-Wei Chen, and Angela Yu-Chen Lin. "Clean water generation through a multifunctional activated carbon-TiO2 interfacial solar distillation system." RSC Advances 11, no. 37 (2021): 23036–44. http://dx.doi.org/10.1039/d1ra02185k.

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Staubach, Jens, and Simon Stephan. "Interfacial properties of binary azeotropic mixtures of simple fluids: Molecular dynamics simulation and density gradient theory." Journal of Chemical Physics 157, no. 12 (September 28, 2022): 124702. http://dx.doi.org/10.1063/5.0100728.

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Interfacial properties of binary azeotropic mixtures of Lennard-Jones truncated and shifted fluids were studied by molecular dynamics (MD) simulation and density gradient theory (DGT) in combination with an equation of state. Three binary mixtures were investigated, which differ in the energetic cross interaction parameter that yields different types of azeotropic behavior. This study covers a wide temperature and composition range. Mixture A exhibits a heteroazeotrope at low temperatures, which changes to a low-boiling azeotrope at high temperatures, mixture B exhibits a low-boiling azeotrope, and mixture C exhibits a high-boiling azeotrope. The phase behavior and fluid interfacial properties as well as their relation were studied. Vapor–liquid, liquid–liquid, and vapor–liquid–liquid equilibria and interfaces were considered. Density profiles, the surface tension, the interfacial thickness, as well as the relative adsorption and enrichment of the components at the interface were studied. The results obtained from the two independent methods (MD and DGT) are overall in good agreement. The results provide insights into the relation of the phase behavior, particularly the azeotropic behavior, of simple fluid mixtures and the corresponding interfacial properties. Strong enrichment was found for the mixture with a heteroazeotrope in the vicinity of the three-phase equilibrium, which is related to a wetting transition.
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Ishizuka, Shinnosuke, Tomihide Fujii, Akira Matsugi, Yosuke Sakamoto, Tetsuya Hama, and Shinichi Enami. "Controlling factors of oligomerization at the water surface: why is isoprene such a unique VOC?" Physical Chemistry Chemical Physics 20, no. 22 (2018): 15400–15410. http://dx.doi.org/10.1039/c8cp01551a.

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The interfacial oligomerization of isoprene is facilitated by the resonance stabilization through the formation of a tertiary carbocation with a conjugated CC bond pair, and electron enrichment induced by the neighboring methyl group.
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Wei, Gao Feng, Hong Fen Gao, and Hai Hui Jiang. "Stress Intensity Factor for Interfacial Cracks in Bi-Materials Using Incompatible Numerical Manifold Method." Advanced Materials Research 327 (September 2011): 109–14. http://dx.doi.org/10.4028/www.scientific.net/amr.327.109.

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Incompatible numerical manifold method (INMM) uses interpolation functions based on the concept of partition of unity, and considers the asymptotic solution and the discontinuity of displacement. This paper describes the application of INMM to bi-material interfacial crack. The two dimensional near-tip asymptotic displacement functions are added to the trial function approximation. This enables the domain to be modeled by manifold elements without explicitly meshing the crack surfaces. The crack-tip enrichment functions are chosen as those that span the asymptotic displacement fields for an interfacial crack. The INMM facilitates the incorporation of the oscillatory nature of the singularity within a conforming manifold element approximation. The complex stress intensity factors for bi-material interfacial cracks are numerically evaluated. Good agreement between the numerical results and the analytical solutions for benchmark interfacial crack problems is realized.
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Liu, Dongmei, Kai Gong, Ye Lin, Tao Liu, Yu Liu, and Xiaozheng Duan. "Dissipative Particle Dynamics Study on Interfacial Properties of Symmetric Ternary Polymeric Blends." Polymers 13, no. 9 (May 8, 2021): 1516. http://dx.doi.org/10.3390/polym13091516.

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We investigated the interfacial properties of symmetric ternary An/AmBm/Bn and An/Am/2BmAm/2/Bn polymeric blends by means of dissipative particle dynamics (DPD) simulations. We systematically analyzed the effects of composition, chain length, and concentration of the copolymers on the interfacial tensions, interfacial widths, and the structures of each polymer component in the blends. Our simulations show that: (i) the efficiency of the copolymers in reducing the interfacial tension is highly dependent on their compositions. The triblock copolymers are more effective in reducing the interfacial tension compared to that of the diblock copolymers at the same chain length and concentration; (ii) the interfacial tension of the blends increases with increases in the triblock copolymer chain length, which indicates that the triblock copolymers with a shorter chain length exhibit a better performance as the compatibilizers compared to that of their counterparts with longer chain lengths; and (iii) elevating the triblock copolymer concentration can promote copolymer enrichment at the center of the interface, which enlarges the width of the phase interfaces and reduces the interfacial tension. These findings illustrate the correlations between the efficiency of copolymer compatibilizers and their detailed molecular parameters.
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Xu, Guang-Rui, Juan Bai, Jia-Xing Jiang, Jong-Min Lee, and Yu Chen. "Polyethyleneimine functionalized platinum superstructures: enhancing hydrogen evolution performance by morphological and interfacial control." Chemical Science 8, no. 12 (2017): 8411–18. http://dx.doi.org/10.1039/c7sc04109h.

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Books on the topic "Interfacial enrichment"

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Inter-laboratory calibration of redox potential and total sulfide measurements in interfacial marine sediments and the implications for organic enrichment assessment. St. Andrews, N.B: Fisheries and Oceans Canada, Marine Environmental Sciences Divisions, 2004.

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1939-, Wildish David, Canada. Dept. of Fisheries and Oceans., and Canada. Dept. of Fisheries and Oceans. Biological Station (St. Andrews, N.B.), eds. Inter-laboratory calibration of redox potential and total sulfide measurements in interfacial marine sediments and the implications for organic enrichment assessment. St. Andrews, N.B: Fisheries and Oceans Canada, Biological Station, 2004.

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Book chapters on the topic "Interfacial enrichment"

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Chen, Guangyao, Juyun Kang, Pengyue Gao, Wajid Ali, Ziwei Qin, Xionggang Lu, and Chonghe Li. "Effect of CaO Additive on the Interfacial Reaction Between the BaZrO3 Refractory and Titanium Enrichment Melt." In Rare Metal Technology 2018, 235–44. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-72350-1_22.

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Miliotis, Tasso, David Ericsson, György Marko-Varga, Simon Ekström, Johan Nilsson, and Thomas Laurell. "Interfacing Protein and Peptide Separation to Maldi-TOF MS Using Microdispensing and on-Target Enrichment Strategies." In Micro Total Analysis Systems 2000, 387–90. Dordrecht: Springer Netherlands, 2000. http://dx.doi.org/10.1007/978-94-017-2264-3_90.

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Conference papers on the topic "Interfacial enrichment"

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Pathak, Himanshu, Akhilendra Singh, Indra Vir Singh, and Sunny Zafar. "Modeling and Simulation of 3-D Interfacial Cracks by XFEM." In ASME 2017 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2017. http://dx.doi.org/10.1115/imece2017-70275.

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The structural integrity of multi-layered material depends on the mechanical properties and the fracture behaviour at the interface. The sudden jump in mechanical properties across the interface is the major source of failure in layered materials. An accurate evaluation of mixed-mode SIFs becomes essential for safe design of layered structure components. In this work, extended finite element method (XFEM) has been used to analyze interfacial cracked three-dimensional structures under mechanical loading. In XFEM, partition of unity enrichment concept is used to model a crack e.g. a crack surface is modeled by Heaviside enrichment function whereas a crack front is modeled by branch enrichment functions. Discontinuity due the presence of bi-material interface is modeled by the signed distance function. Modified domain based interaction integral approach has been used to evaluate the individual stress intensity factors. Three-dimensional cylindrical domain having an interfacial crack is taken for the simulations. A comparative analysis has been performed with and without an interface for an embedded penny shape crack. The effect of material interface on the SIFs has been analyzed in detail. Finally, a three-dimensional interfacial crack growth simulation has been performed for arbitrary shape crack.
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Zhou, Wei, and Wenzhong Zhou. "Multiphysics Modeling of Fabrication Methods’ Effect on UO2-BeO Composite Fuels’ Performance." In 2018 26th International Conference on Nuclear Engineering. American Society of Mechanical Engineers, 2018. http://dx.doi.org/10.1115/icone26-81429.

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UO2-BeO is one of the most promising accident tolerant nuclear fuels due to its excellent thermal conductivity compared to pure UO2 fuel. Two different UO2-BeO fabrication methods have demonstrated the capability to fabricate enhanced thermal conductivity UO2-BeO composite fuels and improve fuel performance. In one method, BeO is continuously distributed around UO2 grains while BeO is dispersed in the UO2 phase in the other method. In the former type, BeO is considered as matrix and UO2 as dispersed particle. However, in the later type, BeO is considered as dispersed particle and UO2 as matrix. To calculate the thermal conductivity of UO2-BeO composite, Hasselman-Johnson model has been applied, which shows good agreement with experimental data. In this model, it includes the influence of thermal conductivity of matrix and particle, volume fraction of particle, radius of particle and the interfacial thermal conductivity between matrix and particle. To balance the improvement of thermal conductivity and enrichment of UO2, a UO2-BeO composite fuel with 10% volume fraction of BeO has been chosen. Besides, the grain size of matrix should be noticeable smaller than particle to relax thermal stress which may cause micro-cracks and destruction, leading to the grain sizes of UO2 in two types being distinctive, and resulting in very big effect on fission gas release. In the paper the thermal conductivity has been intensively studied as well as fuel performance in two different types of UO2-BeO fuels, and the two fabrication methods have also been compared to assess their applications in commercial reactors.
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