Dissertations / Theses on the topic 'Interface potential'
Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles
Consult the top 50 dissertations / theses for your research on the topic 'Interface potential.'
Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.
You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.
Browse dissertations / theses on a wide variety of disciplines and organise your bibliography correctly.
Pilkington, Mark. "Determination of crustal interface topography from potential fields." Thesis, McGill University, 1985. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=71958.
Full textVariation of auxiliary parameters allows a suite of acceptable models to be produced rapidly and appraised in the light of available geological and geophysical evidence. When independent knowledge concerning the behaviour of specified interfaces is available, the incorporation of such data in the form of linear equality constraints is outlined.
The proposed method is applied to Curie isotherm and Moho mapping in the Abitibi greenstone belt.
Joscelyne, Simon Mark. "Separations using controlled potential packed beds." Thesis, University of Oxford, 1993. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.334876.
Full textZheng, Lin. "Étude et caractérisation des interfaces conducteur/isolant par la méthode de l'onde de pression." Electronic Thesis or Diss., Sorbonne université, 2024. http://www.theses.fr/2024SORUS288.
Full textThe interfaces between a conductor and an insulator are generally assumed to be perfect, meaning that the Debye length in the insulator is considered to be much larger than its thickness. However, this work shows that this is not the case and that interface states generate a contact potential that can significantly alter the behavior of the interface when the material is subjected to a strong electric field. Indeed, the interface dipole responsible for the interface voltage modifies the curvature of the energy bands and thus either promotes or hinders charge injection or extraction. A series of experiments was conducted using the pressure wave method, implemented with a high-power acoustic generator on various polyethylene samples, with different electrodes and under various experimental conditions. The interface dipoles observed through measurement do indeed influence charge injection when the material is under high voltage. It is noteworthy that aluminum has a greater influence, particularly when used with silicone oil. When the insulator does not have electrodes, it is preferable to directly couple it with a carbon-filled polymer and silicone oil rather than deposit electrodes on it under vacuum. The interface dipole observed is indeed closer to that seen with carbon-filled polymer electrodes hot-bonded to the material. Upon applying voltage, charges initially penetrate the sample due to the interface dipole. The migration of these charges then leads to secondary injections caused by a field effect. Fluorinating the surface of the samples did not significantly improve the situation and thus does not act as a shield against charges, but rather as a barrier to the diffusion of impurities
Wong, Chi Man. "Phase information enhanced steady-state visual evoked potential-based brain-computer interface." Thesis, University of Macau, 2011. http://umaclib3.umac.mo/record=b2493316.
Full textYuan, Xichen. "Charges à l’interface liquide/solide : caractérisation par courants d’écoulement et application à la préconcentration de molécules biologiques dans un système micro/nanofluidique." Thesis, Lyon, 2016. http://www.theses.fr/2016LYSE1214/document.
Full textThe charges at liquid/solid interfaces are a key element for both understanding and exploiting the electrokinetic phenomena in micro/nanofluidics. The manuscript of my Ph.D thesis is dedicated to these phenomena, which is divided into three main parts: Above all, a simple overview of charges at the liquid/solid interface is proposed. Then, several common methods for measuring the zeta potential at the liquid/solid interface are described. Next, various effective methods to preconcentrate the biological molecules is presented with the help of the surface charges. Secondly, the streaming current, which is a standard method to measure the zeta potential in our laboratory, is detailed. It contains the upgrade of the experimental setup from the previous version and the development of new protocols, which improve dramatically the stabilization and the reproducibility of the measurements. In addition, an original biological sensor is briefly presented based on these advancements. Lastly, in the final part, we describe a method which is primitively utilised in the fabrication of Micro-Nano-Micro fluidic system. Based on this system, some favorable preconcentration results is obtained. Moreover, numerical simulations are presented to prove the originality of our work
Wu, Chi-Hsu. "A distance adaptable brain-computer interface based on steady-state visual evoked potential." Thesis, University of Strathclyde, 2017. http://digitool.lib.strath.ac.uk:80/R/?func=dbin-jump-full&object_id=27946.
Full textCHITNIS, VENKATESH D. "DEVELOPMENT OF A SOLVER FOR POTENTIAL PROBLEMS AND GRAPHICAL USER INTERFACE FOR UCWAVES." University of Cincinnati / OhioLINK, 2004. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1092095169.
Full textSprague, Samantha A. "The Effects of Working Memory on Brain-Computer Interface Performance." Digital Commons @ East Tennessee State University, 2014. https://dc.etsu.edu/etd/2400.
Full textBhardwaj, Suresh. "Challenges and potential of technology integration in modern ship management practices." Thesis, University of Plymouth, 2013. http://hdl.handle.net/10026.1/2840.
Full textFranzen, Melissa. "Dinâmica do fósforo na interface água-sedimento em reservatórios." reponame:Biblioteca Digital de Teses e Dissertações da UFRGS, 2009. http://hdl.handle.net/10183/32460.
Full textWater-borne sediments can provide important information for evaluating lentic aquatic ecosystems because a large proportion of their nutrients are found in the solid phase. A toxic algal bloom in the Blang Reservoir, the second of three in the Salto System chain of hydroelectric dams located in Sao Francisco de Paula in Rio Grande do Sul, Brazil, motivated the investigation of possible nutrient sources, especially phosphorus, which was identified as the limiting nutrient for eutrophization. Non-point sources, including soil, water and sediment carried by tributaries, and point sources, including urban areas and the internal load from the reservoir bottom, were examined. Results showed oligotrophic characteristics in the external sources and excess P availability in bottom sediments, indicating that the internal load may be a significant source of nutrients. The possible circulation of hypolimnic water was investigated using adimensional numbers and physical characteristics of the body of water, demonstrating that this is unlikely to occur, since only extreme climatic events could cause inversion of the liquid mass. By excluding external sources, results suggest that the fertilization of the Blang Reservoir was most likely caused by the opening of the floodgates from the Divisa Reservoir immediately upstream during a drought period. The second goal of this study was to evaluate the importance of particle aggregates and particle size selection for chemical analyses of nutrients and water-borne sediments. Results from sediments in lentic and lotic environments from the Salto System show that the larger aggregates (465 - 63 μm) concentrate nitrogen under lentic conditions and that, therefore, analyses should be performed on the fraction smaller than 465 μm in lentic environments and in the fraction ≤ 63 μm in lotic environments. The final objective of this study was to test the effects of oxidation on the phosphate sorption capacity and rate in organic aquatic sediments, identifying the best conditions for retention. Silicate aquatic sediments from different origins in terms of climate and source of organic content (allochtonous or autochtonous) were used, and were represented by the types Dy (Divisa Reservoir, RS) and Sapropel (Tapacurá Reservoir, São Lourenço da Mata, PE), respectively. The experiment was carried out in suspended sediment maintained under levels of redox potential between –200mV and +400mV. Results demonstrated that phosphate sorption is greatest in sediment type Dy under reduced conditions and in Sapropel under oxidized conditions.
Stetner, Michael E. "Improving decoding in intracortical brain-machine interfaces." Case Western Reserve University School of Graduate Studies / OhioLINK, 2010. http://rave.ohiolink.edu/etdc/view?acc_num=case1254235417.
Full textMcCooey, Conor Gerard, and cmccooey@ieee org. "Characterising Evoked Potential Signals using Wavelet Transform Singularity Detection." RMIT University. Electrical and Computer Engineering, 2008. http://adt.lib.rmit.edu.au/adt/public/adt-VIT20080829.101311.
Full textGabriele-Rivet, Vanessa. "Potential spread of rabies in dingo populations of northern Australia." Thesis, University of Sydney, 2020. https://hdl.handle.net/2123/24319.
Full textFuruhashi, Takeshi, Tomohiro Yoshikawa, and Hiromu Takahashi. "Combination of Reliability-based Automatic Repeat ReQuest with Error Potential-based Error Correction for Improving P300 Speller Performance." 日本知能情報ファジィ学会, 2010. http://hdl.handle.net/2237/20693.
Full textSCIS & ISIS 2010, Joint 5th International Conference on Soft Computing and Intelligent Systems and 11th International Symposium on Advanced Intelligent Systems. December 8-12, 2010, Okayama Convention Center, Okayama, Japan
Jones, Gordon A. "Tribology of the mechanical sealing interface : an evaluation of the role and potential of surface engineering." Thesis, University of Salford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.300829.
Full textAdel, Tehseen. "Design, Construction, and Implementation of Ionization Method Surface Potential Instrument For Studies of Charged Surfactants and Inorganic Electrolytes At the Air/Water Interface." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1512122927166396.
Full textRyan, David B. "Improving Brain-Computer Interface Performance: Giving the P300 Speller Some Color." Digital Commons @ East Tennessee State University, 2011. https://dc.etsu.edu/etd/1328.
Full textJean-Chronberg, Anne-Christine. "Aspects structuraux et cinetiques de l'adsorption de polyelectrolytes a l'interface solide-liquide." Université Louis Pasteur (Strasbourg) (1971-2008), 1988. http://www.theses.fr/1988STR13094.
Full textFrewin, Christopher L. "The Neuron-Silicon Carbide Interface: Biocompatibility Study and BMI Device Development." Scholar Commons, 2009. https://scholarcommons.usf.edu/etd/1973.
Full textSprague, Samantha A. "Improving the P300-Based Brain-Computer Interface by Examining the Role of Psychological Factors on Performance." Digital Commons @ East Tennessee State University, 2016. https://dc.etsu.edu/etd/3097.
Full textAkinci, Berna. "Realization Of A Cue Based Motor Imagery Brain Computer Interface With Its Potential Application To A Wheelchair." Master's thesis, METU, 2010. http://etd.lib.metu.edu.tr/upload/12612607/index.pdf.
Full textRiyahi, Pouria. "A Steady-State Visual Evoked Potential Brain-Computer Interface System Evaluation as an In-Vehicle Warning Device." Thesis, The George Washington University, 2014. http://pqdtopen.proquest.com/#viewpdf?dispub=1566776.
Full textThis thesis is part of current research at Center for Intelligence Systems Research (CISR) at The George Washington University for developing new in-vehicle warning systems via Brain-Computer Interfaces (BCIs). The purpose of conducting this research is to contribute to the current gap between BCI and in-vehicle safety studies. It is based on the premise that accurate and timely monitoring of human (driver) brain's signal to external stimuli could significantly aide in detection of driver's intentions and development of effective warning systems. The thesis starts with introducing the concept of BCI and its development history while it provides a literature review on the nature of brain signals. The current advancement and increasing demand for commercial and non-medical BCI products are described. In addition, the recent research attempts in transportation safety to study drivers' behavior or responses through brain signals are reviewed. The safety studies, which are focused on employing a reliable and practical BCI system as an in-vehicle assistive device, are also introduced. A major focus of this thesis research has been on the evaluation and development of the signal processing algorithms which can effectively filter and process brain signals when the human subject is subjected to Visual LED (Light Emitting Diodes) stimuli at different frequencies. The stimulated brain generates a voltage potential, referred to as Steady-State Visual Evoked Potential (SSVEP). Therefore, a newly modified analysis algorithm for detecting the brain visual signals is proposed. These algorithms are designed to reach a satisfactory accuracy rate without preliminary trainings, hence focusing on eliminating the need for lengthy training of human subjects. Another important concern is the ability of the algorithms to find correlation of brain signals with external visual stimuli in real-time. The developed analysis models are based on algorithms which are capable of generating results for real-time processing of BCI devices. All of these methods are evaluated through two sets of recorded brain signals which were recorded by g.TEC CO. as an external source and recorded brain signals during our car driving simulator experiments. The final discussion is about how the presence of an SSVEP based warning system could affect drivers' performances which is defined by their reaction distance and Time to Collision (TTC). Three different scenarios with and without warning LEDs were planned to measure the subjects' normal driving behavior and their performance while they use a warning system during their driving task. Finally, warning scenarios are divided into short and long warning periods without and with informing the subjects, respectively. The long warning period scenario attempts to determine the level of drivers' distraction or vigilance during driving. The good outcome of warning scenarios can bridge between vehicle safety studies and online BCI system design research. The preliminary results show some promise of the developed methods for in-vehicle safety systems. However, for any decisive conclusion that considers using a BCI system as a helpful in-vehicle assistive device requires far deeper scrutinizing.
Travillian, Ravensara S. "Ontology recapitulates phylogeny : design, implementation and potential for usage of a comparative anatomy information system /." Thesis, Connect to this title online; UW restricted, 2006. http://hdl.handle.net/1773/7156.
Full textRunge, Benjamin [Verfasser]. "X-Ray Scattering Investigations of the Temperature and Potential Dependent Structure of the Mercury-Electrolyte Interface / Benjamin Runge." Kiel : Universitätsbibliothek Kiel, 2015. http://d-nb.info/1075756979/34.
Full textGregori, Federica. "Sistemi di comunicazione alternativa basati su Brain Computer Interface: stato dell’arte e prospettive future." Bachelor's thesis, Alma Mater Studiorum - Università di Bologna, 2020. http://amslaurea.unibo.it/19912/.
Full textReyes, Huamantinco Andrei. "Semiconductor growth on an oxide using a metallic surfactant and interface studies for potential gate stacks from first principles." [Clausthal-Zellerfeld] : [Univ.-Bibliothek], 2008. http://d-nb.info/99014996X/34.
Full textNisbel, Aron. "Investigation Of Complex Strategy Games On Console: Evaluating The Potential Possibilities Of One User Interface To Rule Them All." Thesis, Umeå universitet, Institutionen för tillämpad fysik och elektronik, 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:umu:diva-181616.
Full textAlvarado, Marie L. "A risk assessment of human-robot interface operations to control the potential of injuries/losses at XYZ manufacturing company." Online version, 2002. http://www.uwstout.edu/lib/thesis/2002/2002alvaradom.pdf.
Full textExartier, Corinne. "Étude de la répartition des charges et des potentiels à l'interface acier inoxydable/solution par des mesures de potentiel d'écoulement." Grenoble INPG, 1998. http://www.theses.fr/1998INPG0006.
Full textSomasundaram, Theepaharan. "Simulation studies of molecular transport across the liquid-gas interface." Thesis, Queen's University Belfast, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.314223.
Full textZheng, Yilong, Fadi M. Jradi, Timothy C. Parker, Stephen Barlow, Seth R. Marder, and S. Scott Saavedra. "Influence of Molecular Aggregation on Electron Transfer at the Perylene Diimide/Indium-Tin Oxide Interface." AMER CHEMICAL SOC, 2016. http://hdl.handle.net/10150/622363.
Full textRyan, David B. "Utilizing Visual Attention and Inclination to Facilitate Brain-Computer Interface Design in an Amyotrophic Lateral Sclerosis Sample." Digital Commons @ East Tennessee State University, 2014. https://dc.etsu.edu/etd/2461.
Full textRühmann, Lisa Marie. "ITG - Tangible Geometry for the Visually Impaired : Exploring the potential of extending tablet functionality with appcessories." Thesis, Linnéuniversitetet, Institutionen för medieteknik (ME), 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:lnu:diva-56457.
Full textCuenca-Garcia, Carmen. "The interface of geophysical & geochemical survey at Scottish archaeological sites : exploring the potential of an integrated approach for archaeological prospection." Thesis, University of Glasgow, 2013. http://theses.gla.ac.uk/4535/.
Full textGrundell, Vendela. "Flow and Friction : On the Tactical Potential of Interfacing with Glitch Art." Doctoral thesis, Stockholms universitet, Institutionen för kultur och estetik, 2016. http://urn.kb.se/resolve?urn=urn:nbn:se:su:diva-129130.
Full textKorczowski, Louis. "Méthodes pour l'électroencéphalographie multi-sujet et application aux interfaces cerveau-ordinateur." Thesis, Université Grenoble Alpes (ComUE), 2018. http://www.theses.fr/2018GREAT078/document.
Full textThe study of several brains interacting (hyperscanning) with neuroimagery allows to extend our understanding of social neurosciences. We propose a framework for hyperscanning using multi-user Brain-Computer Interfaces (BCI) that includes several social paradigms such as cooperation or competition. This dissertation includes three interdependent contribution. The first contribution is the development of an experimental platform consisting of a multi-player video game, namely Brain Invaders 2, controlled by classification of visual event related potentials (ERP) recorded by electroencephalography (EEG). The plateform is validated through two experimental protocols including nineteen and twenty two pairs of subjects while using different adaptive classification approaches using Riemannian geometry. Those approaches are theoretically and experimentally compared during the second contribution ; we demonstrates the superiority in term of accuracy of merging independent classifications over the classification of the hyperbrain during the second contribution. Analysis of inter-brain synchronizations is a common approach for hyperscanning, however it is challenging for transient EEG waves with an great spatio-temporal variability (intra- and inter-subject) and with low signal-to-noise ratio such as ERP. Therefore, as third contribution, we propose a new blind source separation model, namely composite model, to extract simultaneously evoked EEG sources and ongoing EEG sources that allows to compensate this variability. A solution using approximate joint diagonalization is given and implemented with a fast Jacobi-like algorithm. We demonstrate on Brain Invaders 2 data that our solution extracts simultaneously evoked and ongoing EEG sources and performs better in term of accuracy and robustness compared to the existing models
Kaliszczak, Magdalena. "Polarisation chimique de l'interface liquide-liquide vers une cocristallisation contrôlée." Electronic Thesis or Diss., Université de Lorraine, 2022. http://www.theses.fr/2022LORR0332.
Full textControlled formation of cocrystals is an important objective in drug development. This work used the electrochemistry at interface between two immiscible liquids (ITIES) to control the formation of cocrystals. In the first part, the electrochemical behaviour of caffeine was investigated by the means of cyclic voltammetry (CV) and alternating current voltammetry (ACV). The caffeine is the hydrophilic cation thus, it transferred at highly positive potential. Transfer of caffeine (Caff) was verified at various pH and the pH 2 was chosen to be the most optimal for the cocrystals formation. The control experiment proved that 1-hydroxy-2-naphthoic (1H2N) did not transfer at ITIES. ACV provided the information about the influence of the aqueous and organic phase composition. Values have changed when CaffH+ alone, 1H2N alone and both 1H2N and CaffH+ were present in the aqueous phase. These suggest that these two molecules are interfacially active. In the third part the simultaneous measurement of potential (∆E) and current (I) variations at the ITIES, which were polarised using tetraalkylammonium cations as a common ion was reported. Various concentration ratios of tetramethyl-, tetraethyl-, and tetrapropylammonium were dissolved in both phases. Such biphasic systems were then used to verify that the interfacial potential difference measured fit the theoretical calculations. This experimental set-up was next used to probe the interfacial cocrystallisation process of hydrophilic and cationic CaffH+ with lipophilic 1H2N. The presence of caffeine in the aqueous phase led to higher current values, caused by interfacial charge transfer. Analysis of the electrochemical current noise showed a clear difference between cells in which cocrystals are formed and those in which cocrystallisation is hindered, either by a negative potential or by a change in pH. The EN method is a powerful tool to follow the changes occurring at ITIES in common ion experiments by simultaneous measurement of potential and current. In the last part, cocrystals were formed on the ITIES according to the conditions chosen by the design of experiments (DoE) method. Various factors were tested: electrolytes in the aqueous phase, various solvents and salts applying positive potential. The XRD analysis showed the conditions to obtain almost pure Phase I and almost pure phase II. Study of simultaneous ∆E and I and the interfacial tension proved that the applied potential influences the kinetics of the cocrystallization process. DoE method indicated organic salt as the factor having an active impact on cocrystallization at ITIES
Hamma, Christopher C. "EFFECTS OF WILDLAND-URBAN INTERFACE FUEL TREATMENTS ON POTENTIAL FIRE BEHAVIOR AND ECOSYSTEM SERVICES IN THE CENTRAL SIERRA NEVADA MOUNTAINS OF CALIFORNIA." DigitalCommons@CalPoly, 2011. https://digitalcommons.calpoly.edu/theses/465.
Full textBouchereau, Stéphane. "Modélisation et simulation numérique de l'électro-mouillage." Université Joseph Fourier (Grenoble), 1997. http://www.theses.fr/1997GRE10064.
Full textLi, Xiaoji. "Understanding Liquid-Air Interface Corrosion of Steel in Simplified Liquid Nuclear Waste Solutions." The Ohio State University, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=osu1365506823.
Full textCoons, Marc P. L. "Solvent Effects for Vertical Ionization Processes in Liquid Water and at the Liquid-Vapor Interface." The Ohio State University, 2017. http://rave.ohiolink.edu/etdc/view?acc_num=osu1503014629752161.
Full textWen, James. "The Potential for Augmented Reality to Bring Balance betweenthe Ease of Pedestrian Navigation and the Acquisition of Spatial Knowledge." Thesis, University of Canterbury. Computer Science, 2014. http://hdl.handle.net/10092/10339.
Full textNguyen, Anh. "An application of steady state visual evoked potential brain-computer interface as an augmentative alternative communication system for individuals with severe motor impairments." Thesis, Boston University, 2013. https://hdl.handle.net/2144/12172.
Full textPURPOSE: Tbis study will look at the feasibility of Steady State Visually Evoked Potential (SSVEP) brain-computer interfaces (BCI) as possible augmentative and alternative communication (AAC) systems for individuals who are severely disabled such as those with Locked-in Syndrome (LIS). The study intended to test whether there is a difference in BCI performance between healthy and impaired individuals and why. Specifically, the study focused on the operational competency, such as ocular motor function, ofthe impaired individuals as it relates to performance. Further, the study also attempted to explore the contributions of environmental distracts to performance. The results oftbis investigation will provide insights valuable for future BCI-AAC development and the potential for their acceptance by the AAC and LIS communities. METHODS: The study consisted of 12 healthy adults and 5 severely disabled adults presenting with 4 different neurological disorders. Tbis study consisted to two parts. The first part was an assessment ofthe communicative abilities ofthe impaired subjects. The assessment was conducted through a video recorded interview, from which communication rates were calculated and behavioral observations of each impaired subject's communicative behaviors were made with a focus on ocular motor behavior. The second part involved testing of the SSVEP BCI. All subjects performed selection tasks from a choice of four directions in the UDLR task. For each trial, the subject was prompted to attend to a specific SSVEP stimulus. Each stimulus was selected at random to flash at one of four frequencies (12, 13, 14, or 15Hz) (Lorenz, 2012). After 4 seconds, the BCI predicted the attended cue direction (Up, Down, Left, Right). If the prediction was correct, a "thumbs-up" feedback signal was shown to the subject; a "thumbs-down" was shown for incorrect predictions. The UDLR data collected for each trial consisted of a table with two columns: one column recorded the ground truth, which was the target direction, and one column recorded the decoded, or classified direction. Two additional columns were added. One column indicated whether the subject had any ocular motor impairment with a 1 or 0. A binary logistic regression was completed to investigate the main effect of age, subject group, and ocular motor impairment with respect to BCI accuracy. Additionally, observations regarding the affect of environmental distractions were also made. [TRUNCATED]
FURUHASHI, Takeshi, Tomohiro YOSHIKAWA, Hiromu TAKAHASHI, Shotaro NAKAMURA, 武. 古橋, 大弘 吉川, 弘武 高橋, and 翔太郎 中村. "脳波を用いた手足の運動想起判別における準備電位の傾きを用いた特徴抽出法に関する検討." 日本知能情報ファジィ学会, 2010. http://hdl.handle.net/2237/20686.
Full textDemeaux, Julien. "Impact des phénomènes aux interfaces électrode/électrolyte sur les performances des batteries Li-ion haute tension : faiblesses et atouts des électrolytes à base de carbonates d'alkyles et de sulfones face aux électrodes LiNi0,4Mn1,6 O4 et Li4Ti5O12." Thesis, Tours, 2013. http://www.theses.fr/2013TOUR4032/document.
Full textLiNi0.4Mn1.6O4 (LNMO)/Li4Ti5O12 (LTO) accumulators should theoretically achieve the power and energy densities that provide sufficient autonomy to electric vehicles. However, two major issues related to the use of LNMO limit their performances: the pronounced oxidation of the alkylcarbonate-based electrolytes and the transition metal ion (Mn2+, Ni2+) dissolution. The ethylene carbonate (EC)-based formulations get an ability to form polymer-covering films onto the active material. The galvanostatic cycling tests, after storage or not, confirm the superiority of these electrolytes, leading to reduced capacity losses of the LNMO electrode. Furthermore, sulfones are promising compounds to be applied to LNMO/LTO batteries. The use of symmetric and asymmetric cells demonstrates that sulfones are non-reactive towards the LNMO/electrolyte and LTO/electrolyte interfaces. However, this non-reactivity does not allow the deposition of polymer films, which would have enabled to stop the Mn2+ and Ni2+ dissolution from the positive electrode. This results in degraded performances of batteries at 30°C compared to those using EC in electrolytes
Reyes, Huamantinco Andrei [Verfasser]. "Semiconductor growth on an oxide using a metallic surfactant and interface studies for potential gate stacks from first principles / vorgelegt von Andrei Reyes Huamantinco." [Clausthal-Zellerfeld] : [Univ.-Bibliothek], 2008. http://d-nb.info/99014996X/34.
Full textCecchetto, Claudia. "Neuronal Population Encoding of Sensory Information in the Rat Barrel Cortex: Local Field Potential Recording and Characterization by an Innovative High-Resolution Brain-Chip Interface." Doctoral thesis, Università degli studi di Padova, 2016. http://hdl.handle.net/11577/3424482.
Full textLe reti neuronali sono alla base della codifica dell'informazione cerebrale. L'obiettivo principale dello studio delle popolazioni neuronali è quello di caratterizzare la relazione tra uno stimolo e la risposta individuale o globale dei neuroni e di studiare il rapporto tra le varie attività elettriche dei neuroni appartenenti ad una particolare rete, comprendendo anche come la topologia e la connettività della rete neuronale influiscano sulla loro funzionalità. Fino ad oggi, molte tecniche sono state sviluppate per studiare questi sistemi complessi: studi a singola cellula mirano a studiare singoli neuroni e le loro connessioni con un numero limitato di altre cellule; sul lato opposto, approcci su larga scala e a bassa risoluzione, come la risonanza magnetica funzionale o l'elettroencefalogramma, registrano segnali elettrofisiologici generati nel cervello da vaste popolazioni di cellule. Più recentemente, sono state sviluppate tecniche di registrazione multisito che mirano ad abbattere le limitazioni dei precedenti approcci, rendendo possibile la misurazione ad alta risoluzione di segnali generati da grandi ensamble neuronali e da diverse regioni del cervello simultaneamente, ad esempio mediante l'uso di chip impiantabili a semiconduttore. I potenziali di campo locali (LFP) catturano processi sinaptici chiave che non possono essere estratti dall'attività di spiking di qualche neurone isolato. Numerosi studi hanno utilizzato gli LFP per studiare i meccanismi corticali coinvolti nei processi sensoriali, motori e cognitivi, come la memoria e la percezione. Gli LFP rappresentano anche dei segnali interessanti nell'ambito delle applicazioni neuroprotesiche e per monitorare l'attività cerebrale negli esseri umani, dal momento che possono essere registrati più stabilmente e facilmente in impianti cronici rispetto agli spike neuronali. In questo studio, sono riportati dei profili LFP registrati dalla barrel cortex di ratto tramite chip ad ago ad alta risoluzione basati su tecnologia CMOS e confrontati con quelli ottenuti tramite elettrodi convenzionali in Ag/AgCl inseriti in micropipette di vetro, strumenti comunemente usati in elettrofisiologia. La barrel cortex di ratto è un esempio ben noto di mapping topografico, nel quale ogni baffo sul muso dell'animale è mappato in una specifica area corticale, chiamata barrel. La barrel cortex contiene la rappresentazione sensoriale dei baffi dell'animale e rappresenta uno dei primi stadi di elaborazione dell'informazione tattile, insieme al ganglio del trigemino e al talamo. Essa è un'area di primaria importanza per lo studio del funzionamento della corteccia cerebrale, visto che le colonne corticali che formano i blocchi di base della neocorteccia possono essere visualizzati facilmente all'interno della barrel cortex. La barrel cortex inoltre è utilizzata come sistema di test in numerose metodologie innovative, grazie alla sua struttura unica ed istantaneamente identificabile, e grazie anche al fatto che le specie dotate di barrel, i roditori, sono gli animali da laboratorio più comuni. La barrel cortex e le sue interconnessioni neuronali sono stati oggetto delle ricerche più disparate in questi ultimi decenni. Attualmente, alcuni studi (come questo) non mirano solamente a comprendere meglio la barrel cortex, ma anche ad analizzare problematiche in campi scientifici collegati, utilizzando la barrel cortex come modello base. In questo lavoro, sono stati evocati segnali LFP nella barrel cortex tramite deflessioni ripetute dei baffi dell'animale, realizzate in modo controllato tramite un sistema di deflessione piezoelettrica a closed-loop innescato da un sistema di acquisizione LabView. Le risposte evocate generate nella barrel dalla stimolazione ripetuta dei baffi presentano elevata variabilità nella forma e nelle latenze temporali. Inoltre, il tipo di anestesia utilizzata può influenzare profondamente il profilo della risposta evocata. Questo studio riporta i risultati preliminari sulla variabilità della risposta neuronale e sull'effetto di due anestetici di uso comune su questi segnali, confrontando le distribuzioni delle risposte evocate in ratti anestetizzati con tiletamina-xylazina (il quale agisce prevalentemente sui recettori eccitatori di tipo NMDA) e uretano (che agisce in modo più bilanciato e complesso su entrambi i sistemi eccitatori ed inibitori, preservando la plasticità sinaptica). Sono state analizzate e discusse alcune caratteristiche rappresentative del segnale evocato (ad esempio, le latenze temporali e l'ampiezza degli eventi), registrato a varie profondità corticali. Per tutte le prondità corticali acquisite, sono state stimate le distribuzioni statistiche di tali parametri, in modo da valutare la variabilità degli LFP evocati dalle stimolazioni meccaniche individuali delle vibrisse del ratto lungo l'intera colonna corticale. I primi risultati presentano una grande variabilità nelle risposte corticali, sia in latenza che in ampiezza. Inoltre, è stata riscontrata una differenza significativa nella latenza del primo picco principale delle risposte evocate: gli LFP evocati in animali anestetizzati con tiletamina-xylazina presentavano una latenza più lunga di quelli registrati in ratti anestetizzati con uretano. Inoltre, le distribuzioni dei parametri analizzati erano più strette e piccate in uretano, in corrispondenza di tutte le profondità corticali. Questo comportamento è sicuramente da attribuire al differente meccanismo d'azione dei due anestetici su specifici recettori sinaptici, e quindi nell'elaborazione e nella trasmissione dell'informazione sensoriale lungo tutto il percorso corticale. E' stato inoltre discusso il ruolo della attività basale nella modulazione della risposta evocata. A questo proposito, è stata registrata l'attività spontanea in corrispondenza dei vari layer corticali ed analizzata nel contesto statistico delle 'valanghe neuronali'. Una valanga neuronale è una cascata di attività elettrica in una rete neuronale, la cui distribuzione statistica dei parametri principali (dimensione e vita media) può essere approssimata da una legge di potenza. La distribuzione delle dimensioni di una valanga in una rete neuronale segue una legge di potenza del tipo P(s)=s^-a, con a=1.5. Tale esponente è un riflesso delle correlazioni spaziali a lungo raggio nell'attività neuronale spontanea. Dal momento che i picchi negativi (nLFPs) nelle tracce elettrofisiologiche originano dalla somma di potenziali d'azione sincronizzati generati da neuroni posti nelle vicinanze dell'elettrodo di registrazione, ci siamo chiesti se fosse possibile modellizare i singoli nLFP registrati nell'attività basale tramite un singolo elettrodo come il risultato di valanghe neuronali locali. Pertanto, abbiamo analizzato la distribuzione della dimensione (cioè l'ampiezza in uV) di tali picchi, in modo da identificare una distribuzione power-law appropriata, che potesse descrivere anche le registrazioni a singolo elettrodo. Infine, sono presentate e discusse le prime registrazioni in assoluto degli LFP evocati lungo un'intera colonna corticale ottenute tramite l'ultima generazione di chip impiantabili a tecnologia CMOS. Questi ultimi presentano una matrice di 256 siti di registrazione, organizzata secondo due possibili topologie, 16 x 16 o 4 x 64, e avente una distanza tra gli elettrodi pari a 15 um o 33 um rispettivamente. Una precisa dinamica di propagazione dei potenziali evocati può già essere riconosciuta in questi primissimi profili corticali. Nel prossimo futuro, l'uso di questi dispositivi a semiconduttore potrà aiutare a comprendere il decorso di sindromi neurodegerative come il Parkinson o l'Alzheimer, associando sintomi e comportamenti tipo della malattia a specifiche caratteristiche neuronali. I chip impiantabili potranno anche essere utilizzati come 'electroceuticals', ossia potranno aiutare a rallentare (o addirittura a capovolgere) il decorso delle malattie neurogenerative, costituendo le basi di protesi neuronali in grado di sostenere fisicamente o allenare funzionalmente le popolazioni neuronali danneggiate. L'identificazione e il rilevamento di segnali neuronali ad alta risoluzione aiuterà anche a sviluppare complesse interfacce cervello-macchina, che consentiranno il controllo di protesi intelligenti e che forniranno sofisticati meccanismi di feedback a chi ha perso l'uso di alcune parti del proprio corpo o determinate funzioni cerebrali.
Turi, Federica. "Interface cerveau-ordinateur adaptée à l'utilisateur." Thesis, Université Côte d'Azur, 2020. https://tel.archives-ouvertes.fr/tel-03149221.
Full textBrain-Computer Interface (BCI) allows communication between a user and a machine, by converting the user's brain activity into commands that control external devices. Many limitations prevent the diffusion of BCI systems in real applications, such as the calibration phase that is a consequence of the issue of variability across sessions and among users. The calibration phase is fundamental because it allows to set the main parameters to extract the relevant information from the electroencephalograpy (EEG) signal of the subject, but it is considered time consuming and tedious for the user.The objective of this thesis is to overcome these limitations by novel methods based on the improvement or even replacement of the traditional calibration phase, proposing the development of a user-centered BCI system.Firstly, we present a design to develop an adaptive BCI system for two different applications. The former deals with a code-modulated Visual Evoked Potential (c-VEP) speller where an adaptive parameter setting phase is proposed to replace the standard calibration phase. The latter application concerns the development of a Mental Imagery (MI) BCI for a disabled user, characterized by a long user-centered multi-stage training phase, in the context of a international BCI competition.Secondly, we propose an auto-calibration c-VEP BCI system exploiting the language information. In our model the fundamental properties that characterize the VEP response are used to predict the full word using a dictionary, eliminating the traditional calibration phase.The proposed methods showed promising results and open new perspectives to the diffusion of BCI
BOUDH-HIR, MOHAMED ESSALAH. "Contribution a l'etude theorique de la structure et de la thermodynamique d'un fluide polaire au voisinage d'une surface." Paris 6, 1987. http://www.theses.fr/1987PA066040.
Full textGualandi, Giovanni <1973>. "Chlorinated aliphatic and aromatic hydrocarbons biodegradation: bioaugmentation tests in slurry microcosmos and study of the catabolic potential of microbial community in the interface between groundwater and surface water." Doctoral thesis, Alma Mater Studiorum - Università di Bologna, 2007. http://amsdottorato.unibo.it/382/1/giovanni_gualandi.pdf.
Full text