Academic literature on the topic 'Inorganic Oxide-Polymer Composites'

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Journal articles on the topic "Inorganic Oxide-Polymer Composites"

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Rahman, Mohammad Mizanur. "Polyurethane/Zinc Oxide (PU/ZnO) Composite—Synthesis, Protective Property and Application." Polymers 12, no. 7 (July 11, 2020): 1535. http://dx.doi.org/10.3390/polym12071535.

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A polyurethane (PU) is a multifunctional polymer prepared by using more than two types of monomers. The unique properties of PU come from monomers, thus broadening the applicability of PU in many different sectors. The properties can be further improved by using many nanoparticles. Different metal oxides as nanoparticles are also widely used in PU materials. ZnO is a widely used inorganic metal oxide nanoparticle for improving polymer properties. In this review article, the techniques to prepare a PU/ZnO composite are reviewed; the key protective properties, such as adhesive strength and self-healing, and applications of PU/ZnO composites are also highlighted. This review also highlights the PU/ZnO composite’s current challenges and future prospects, which will help to broaden the composite practical application by preparing environmentally friendly composites.
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Vázquez-López, Antonio, Marina García-Carrión, Erlend Hall, Anisa Yaseen, Ilknur Kalafat, María Taeño, Junjie Zhu, et al. "Hybrid Materials and Nanoparticles for Hybrid Silicon Solar Cells and Li-Ion Batteries." Journal of Energy and Power Technology 03, no. 02 (November 9, 2020): 1. http://dx.doi.org/10.21926/jept.2102020.

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Hybrid composites based on inorganic nanomaterials embedded into a polymer matrix have were synthesized and characterized. Oxide semiconductor nanoparticles (SnO, SnO2, TiO2, Ga2O3, and NiO) and Si nanoparticles were employed as inorganic counterparts in the hybrid composite, while a conductive polymer (PEDOT:PSS) with diverse additives was used as the organic matrix. The composites were spin-coated on Si or glass substrates. The potential use of these materials in photovoltaic devices to improve Si surface passivation behavior was investigated. Besides, the use of the nanoparticles as active materials for anodes in Li-ion batteries was evaluated. Some other aspects, such as the durability and stability of these materials, were also assessed.
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Zharkova, G. M., K. V. Zobov, N. A. Romanov, V. V. Syzrantsev, and S. P. Bardakhanov. "Polymer-liquid crystal composites doped by inorganic oxide nanopowders." Nanotechnologies in Russia 10, no. 5-6 (May 2015): 380–87. http://dx.doi.org/10.1134/s1995078015030210.

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Prathap, Murali, Kulasekaran Poonkuzhali, Maria Mahimai Berlina, Pushparaj Hemalatha, and Deivanayagam Paradesi. "Synthesis and characterization of sulfonated poly(ether ether ketone)/zinc cobalt oxide composite membranes for fuel cell applications." High Performance Polymers 32, no. 9 (May 5, 2020): 984–91. http://dx.doi.org/10.1177/0954008320922296.

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A new series of polymer composite membranes was fabricated using a linear sulfonated poly(ether ether ketone) (SPEEK) polymer with zinc cobalt oxide (ZCO) as an inorganic filler and evaluated for fuel cell applications. SPEEK was obtained by the direct sulfonation of PEEK using concentrated sulfuric acid, and appropriate quantities of ZCO were loaded into it to yield the polymer composites. Proton nuclear magnetic resonance studies revealed the degree of sulfonation of SPEEK to be 55%, while morphological studies confirmed the successful incorporation of inorganic fillers into the polymer matrix. To evaluate the suitability of the prepared composite membranes for fuel cell applications, their physicochemical properties were studied in detail. The pristine SPEEK membrane exhibited a proton conductivity of 0.009 S cm−1 at 30°C, whereas the values for the composite membranes loaded with 2.5 to 10 wt% of ZCO were in the range 0.012–0.020 S cm−1. Moreover, the composite membranes showed excellent thermal stability up to 370°C. Indeed, the membranes obtained by the incorporation of ZCO into the SPEEK polymer show potential for fuel cell applications.
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Fallah, Mahroo, Kenneth J. D. MacKenzie, John V. Hanna, and Samuel J. Page. "Novel photoactive inorganic polymer composites of inorganic polymers with copper(I) oxide nanoparticles." Journal of Materials Science 50, no. 22 (July 29, 2015): 7374–83. http://dx.doi.org/10.1007/s10853-015-9295-3.

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Xie, Jiliang. "Application of Graphene Oxide–Natural Polymer Composite Adsorption Materials in Water Treatment." Symmetry 15, no. 9 (August 31, 2023): 1678. http://dx.doi.org/10.3390/sym15091678.

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Graphene is a new type of carbon material with excellent properties that has been developed in recent years. Graphene composites have potential application value in solving the problem of water pollution. In this study, we investigated the properties and performance of graphene composites prepared through polymer modification and inorganic particle doping modification. Our research focused on the composites’ ability to adsorb heavy metal ions and degrade organic compounds through photocatalysis. In this study, we prepared graphene oxide (GO) first and then grafted p-phenylenediamine onto its surface. The process was successful and yielded promising results. The aniline grafted onto the graphene oxide surface was used as anchor point for the in situ redox polymerization of aniline, and a polyaniline macromolecular chain was grafted onto the edge of graphene oxide. The structure of the composite was determined using Fourier transform infrared spectroscopy, thermogravimetry, X-ray diffraction, and Raman spectroscopy and transmission electron microscopy. The adsorption performance of Pb+ on GO-PANI composite was studied. The maximum adsorption capacity of the GO-PANI composite for Pb+ is 1416 mg/g, 2.3 times that of PANI. Graphene/polyaniline composites can be used as an excellent adsorbent for Pb2+ heavy metal ions and have great application prospects in heavy metal wastewater treatment.
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Danchenko, Yuliya, Vladimir Andronov, Tatyana Obizhenko, Anatoliy Kosse, and Igor Khmyrov. "The Influence of Inorganic Fillers on the Protective Properties of Epoxy Polymer Composite Materials." International Journal of Engineering & Technology 7, no. 4.3 (September 15, 2018): 279. http://dx.doi.org/10.14419/ijet.v7i4.3.19804.

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The influence of regularities of the chemical-mineralogical nature, the dispersity, and the surface properties of inorganic fillers on the protective properties of epoxy polymer composite materials have been investigated. Polymeric compositions based on epoxy resin of ED-20 brand and aliphatic amine curing agent of diethylenetriamine of DETA brand have been chosen as the research materials. The fillers were the air-dry dispersed materials of different nature: oxide, clay and quartz. The resistance of the composites to water and aqueous solutions (absorbency) was investigated by dipping the samples into an aggressive aqueous medium. For the received samples of the filled composites, thermogravimetric (TG) and differential scanning calorimetry (DSC) method were used using the SDT Q600 device manufactured by TA Instruments (USA). It has been found that the thermal stability and the absorbing capacity of the filled composites in water and aqueous acidic and alkaline mediums correlate with each other. It has been shown that to obtain materials with improved protective characteristics, it is necessary to use oxide or clay fillers with the basic (alkaline) surface function.
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Korzekwa, Joanna, Elżbieta Bociąga, and Dariusz Bochenek. "Investigation of Selected Polymer Composite-Aluminum Oxide Coating Tribological Systems." Materials 13, no. 23 (December 2, 2020): 5491. http://dx.doi.org/10.3390/ma13235491.

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The tribotesting of friction systems requires discussion on proper selection of its conditions and data presentation. System tribology is based, for example, on analysis of the friction contact, the roughness of the cooperating surfaces, and the wear rate of the rubbing elements or coefficient of friction in relation to the sliding distance. Friction pairs, consisting of an aluminum alloy sample with an oxide layer (Al2O3) with and without the addition of inorganic fullerenes like tungsten disulphide (IF-WS2) nanoparticles on its surface cooperating with a counter-sample made of polymer composites prepared on the basis of phenol-formaldehyde resin with different fillers, were tested using a device with a pin-on-plate friction pair system. The results of the experiments showed sufficient durability of the Al2O3 and Al2O3/IF-WS2 oxide coatings in combination with the polymer composite. It was found that resin fillers such as cotton fibers, jute fibers, molybdenum disulphide (MoS2) or graphite (C) influence the friction behavior of the tribological pairs. Although the values of the coefficient of friction obtained in the tests were quite high, their course during the tests ensured stable cooperation of the aluminum coating/polymer composite friction pair on a 15 km distance, under a load of 0.5 MPa. The lowest coefficients of friction were obtained for oxide layers formed on aluminum combined with a polymer composite filled with cotton fibers and graphite. These studies provide information on the tribological properties of commercially available polymer composites cooperating with the produced oxide coatings, supplementing the available literature with the results of research on new, so far unexplored tribological partners. Microscopic investigation of the structure and morphology of the formed surface oxide layers and also microgeometry studies of both the friction elements were used to better understand the obtained research results.
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Berman, Diana, Yuchen Sha, and Elena V. Shevchenko. "Effect of Polymer Removal on the Morphology and Phase of the Nanoparticles in All-Inorganic Heterostructures Synthesized via Two-Step Polymer Infiltration." Molecules 26, no. 3 (January 28, 2021): 679. http://dx.doi.org/10.3390/molecules26030679.

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Polymer templates play an essential role in the robust infiltration-based synthesis of functional multicomponent heterostructures with controlled structure, porosity, and composition. Such heterostructures are be used as hybrid organic–inorganic composites or as all-inorganic systems once the polymer templates are removed. Using iron oxide/alumina heterostructures formed by two-step infiltration of polystyrene-block-polyvinyl pyridine block copolymer with iron and aluminum precursors from the solution and vapor-phases, respectively, we show that the phase and morphology of iron oxide nanoparticles dramatically depend on the approach used to remove the polymer. We demonstrate that thermal and plasma oxidative treatments result in iron oxide nanoparticles with either solid or hollow morphologies, respectively, that lead to different magnetic properties of the resulting materials. Our study extends the boundaries of structure manipulations in multicomponent heterostructures synthesized using polymer infiltration synthesis, and hence their properties.
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Ahadzade, Sh M., I. A. Vakulenko, and Kh Asgarov. "Factors Influence on Electrophysical Parameters of the Composite Varistors." Science and Transport Progress, no. 1(101) (March 14, 2023): 29–36. http://dx.doi.org/10.15802/stp2023/283013.

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Purpose. Evaluation influence structural state polymer phase on the response voltage and coefficient nonlinearity of a multilayer varistor based on zinc oxide. Methodology. Zinc oxide consisted of 97% zinc oxide and 3% total oxides of Bi2O3, Co3O4, MnO2, B2O3, SbO3, ZrO2, Al2O3. At a temperature of 1573°K, the synthesis of semiconductor ceramics based on Zinc oxide was carried out. For composite of thermoplastic polymers and Zinc oxide, non-polar and polar polymers, high pressure polyethylene and polyvinylidene fluoride were used. The composites were obtained by hot pressing at the melting temperature of the polymer phase and a pressure of 15 MPa. After that, using silver paste, measuring electrodes 10 mm in diameter were applied to the surface of the synthesized samples, and then current–voltage characteristics were measured. Modification of composites under action of gas-discharge plasma was carried out in a special cell that creates a dielectric-gas-composite system. The structure of the composites was studied by X-ray diffraction analysis and IR spectroscopy. Findings. The obtained experimental results show that the size of the particles of the inorganic phase significantly affects the current-voltage characteristics of the composite varistor: at a given thickness of the composite varistor, the operation voltage decreases markedly, and the nonlinearity coefficient increases. Numerous experimental results obtained by us show that the impact of electric discharge plasma on the polymer Zinc oxide-composite leads to a significant change in the permittivity and the concentration of local levels at the interface of the composite. The results research showed that effect electrical plasma on the opening voltage depends on the polarity of polymer matrices. Moreover, plasma processing itself significantly changes the structure of the polymer phase at composite. Originality. The magnitude of the potential barrier at phase boundary is mainly determined by the volume fraction and size of the main structural element of ZnO ceramics. Changing the structural state of the polymer matrix allows the adjust response voltage and coefficient nonlinearity of volt-ampere characteristic of the multilayer varistor. Practical value. The discovered development of electron-ion processes at polymer phase of the varistor indicates the need to take into account change in its service characteristics from the duration and intensity of use. The result obtained has a certain practical significance, since it indicates not only the reason for the change in properties, but also the need to develop measures to increase the service life of the varistor.
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Dissertations / Theses on the topic "Inorganic Oxide-Polymer Composites"

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Bhaway, Sarang M. "Fabrication of Block Copolymer Templated Mesoporous Metal Oxide Composites for Energy Storage Applications." University of Akron / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=akron1468417723.

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Carvalho, Thaís. "Preparação e caracterização de compósitos com matriz de poliuretano e híbridos fibrosos modificados com óxido de magnésio hidratado." Universidade de São Paulo, 2016. http://www.teses.usp.br/teses/disponiveis/97/97136/tde-20112017-123925/.

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A versatilidade das espumas poliuretanas permite sua aplicação em inúmeros setores industriais, devido à possibilidade de se obter diferentes conjuntos de propriedades apenas alterando sua formulação básica. Um tipo recorrente de alteração é a incorporação de diferentes tipos de fibras em matrizes de poliuretano, vastamente estudada com o objetivo de gerar materiais compósitos com melhores propriedades mecânicas do que a matriz original. Inúmeros autores reportaram a utilização de celulose cristalina como uma alternativa renovável aos agentes de reforço e revelaram que a celulose utilizada como aditivo em matrizes poliméricas afetou as propriedades mecânicas da matriz original e, em menor escala, exerceu influência sobre a estabilidade térmica do compósito. O presente trabalho dedicou-se a isolar a celulose cristalina contida nas fibras de bananeira mediante tratamento com ácido acético concentrado. Os tratamentos químicos são necessários para modificar a superfície do material e melhorar a adesão do agente de reforço à matriz. Tendo em vista os resultados associados à estabilidade térmica dos compósitos de poliuretano reforçados com celulose, buscou-se sintetizar materiais híbridos de celulose e MgO.nH2O. Foi observado que, mesmo em pequenas quantidades, a presença do óxido hidratado de magnésio afetou significativamente a estabilidade térmica do HB 98:2. Estudos térmicos indicam que os materiais compósitos estudados apresentaram comportamento semelhante ao da matriz PU. Estudos das propriedades compressivas dos materiais poliméricos gerados mostraram que a incorporação do HB 98:2 ao PU afetou positivamente as propriedades mecânicas do material, sendo que o compósito PU + 1 HB 98:2 apresentou desempenho mecânico superior ao da matriz pura.
The versatility of polyurethanes foams allows its application in numerous industries because of the possibility of obtaining different sets of properties just by changing its basic formulation. A recurrent type of modification is the incorporation of different types of fibers in polyurethane matrices widely studied with the objective of generating composite materials with better mechanical properties than the original matrix. Numerous authors have reported the use of crystalline cellulose as a renewable alternative to fillers and showed that the cellulose used as additive in polymer matrices affect the mechanical properties of the original matrix and, to a lesser extent, influence upon thermal stability of the composite. This work was dedicated to isolate the crystalline cellulose contained in banana fibers by treatment with concentrated acetic acid. The chemical treatments are needed to modify the surface of the material and improve adhesion of the filler to the matrix. In view of the results associated with the thermal stability of the composite polyurethane reinforced with cellulose, sought to synthesize hybrid materials cellulose and MgO.nH2O. It has been observed that even in small quantities, the presence of hydrated magnesium oxide significantly affect the thermal stability of HB 98: 2. thermal studies indicate that the studied composites showed similar behavior to the PU matrix. Studies of the compressive properties of polymeric materials generated showed that the incorporation of HB 98: 2 to PU positively affect the mechanical properties of the material, and the composite PU + HB 98 1: 2 had mechanical performance superior to that of pure matrix.
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Alfinaikh, Reem. "Preparation and Characterization of Poly(Ethylene Oxide)(MW 35K and 100K)/ Silica Nanoparticle Composites." DigitalCommons@Robert W. Woodruff Library, Atlanta University Center, 2017. http://digitalcommons.auctr.edu/cauetds/109.

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In recent years, polymer-inorganic nanoparticle compositions have been a subject of considerable interest in order to achieve desired chemical, physical properties and mechanical properties. In this study a polymer nanocomposites have been prepared by incorporating silica nanoparticles (~20 nm) as fillers into poly(ethylene oxide) matrix. The composites of poly(ethylene oxide) and silica nanoparticles were prepared by solution blending. The product composites were powders. The thermal properties of the composites were investigated using the Differential Scanning Calorimetry. The Nuclear Magnetic Resonance (13C solid state, T1ρ), Atomic Force Microscopy, X-ray diffraction and Fourier Transform Infrared Spectroscopy were used to investigate the effect of the nanoparticles on the polymer matrix. The results suggest that the silica nanoparticles were reasonably well dispersed in the PEO 35K. The dispersion was accompanied by slightly reduced the crystallinity. However, with increasing the SiO2 nanoparticles the aggregation Phenomenon appears. Moreover, with increase in the MW of the PEO to 100K the dispersion of the nanoparticles decreased and aggregation phenomenon is observed even at lower of SiO2 contents.
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Book chapters on the topic "Inorganic Oxide-Polymer Composites"

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Naghib, Seyed Morteza, Samin Hoseinpour, and Shadi Zarshad. "Carbon Nanostructure/polymer Composites Processing and Characteristics in Localized Controlled Drug Delivery System (LCDDSs)." In Localized Micro/Nanocarriers for Programmed and On-Demand Controlled Drug Release, 71–92. BENTHAM SCIENCE PUBLISHERS, 2022. http://dx.doi.org/10.2174/9789815051636122010005.

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Carbon nanostructures such as carbon nanotubes, graphene, graphene oxide and their derivatives, have been recognized in biomedicine and drug delivery, due to their outstanding optical, mechanical, thermal, and electrical characteristics. Carbon nanostructures/ polymer composites with various active and functional groups provide many binding sites for inorganic/organic species and biomolecules and are described as favorable candidates to label and drag different drugs, genes, proteins and therapeutic molecules. This chapter focuses on studies about the deployment of nanostructures/ polymer composites, for efficient drug delivery, especially localized controlled drug/gene delivery systems (LCDDS). Effects of various parameters and features, including composite microstructures, hydrophobicity and hydrophilicity of composites, glass transition and polymer matrix molecular weight, on LCDDS are fully examined and discussed.
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Conference papers on the topic "Inorganic Oxide-Polymer Composites"

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Zhang, Yue, Yiping Cui, Chi-Chang J. Wung, Paras N. Prasad, and Ryszard Burzynski. "Sol-gel processed novel multicomponent inorganic oxide: organic polymer composites for nonlinear optics." In San Diego, '91, San Diego, CA, edited by Kenneth D. Singer. SPIE, 1991. http://dx.doi.org/10.1117/12.50723.

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WEN, Z. Y., Z. X. LIN, J. D. CAO, T. ITOH, and O. YAMAMOTO. "CHARACTERISTICS OF COMPOSITE POLYMER ELECTROLYTES BASED ON POLY(ETHELYENE OXIDE) AND INORGANIC FIBER." In Proceedings of the 7th Asian Conference. WORLD SCIENTIFIC, 2000. http://dx.doi.org/10.1142/9789812791979_0060.

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Wellinghoff, S. T., D. P. Nicolella, D. P. Hanson, H. R. Rawls, and B. K. Norling. "Photopolymerizable Liquid Crystal Monomer-Oxide Nanoparticle Composites." In ASME 2002 International Mechanical Engineering Congress and Exposition. ASMEDC, 2002. http://dx.doi.org/10.1115/imece2002-39367.

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Methacrylate and acrylate terminated monomers can be rapidly polymerized to polymer glasses useful in biomaterials, photolithography and rapid prototyping, optical coatings and composites. Unfortunately, polymerization shrinkage results in loss of tolerance and the development of internal stresses which can be especially critical in the case of highly crosslinked glasses. Structurally complicated oligomeric mixes of dimethacrylate monomers that exhibit a nematic liquid crystal to isotropic transition above room temperature have been synthesized in a low cost one pot synthesis to surmount the problem of polymerization shrinkage and the propensity of single component monomers to crystallize from the liquid state. Photopolymerization from the ordered liquid crystal state into a less ordered glass minimizes volumetric shrinkages to between 1–2% at greater than 90% polymerization conversion. These polymer glasses exhibited elastic bending moduli of 1.2 GPa to 1.5GPa, fracture strengths of 70–100MPa and fracture toughness of K=0.3–0.4 (MPa)1/2. In some cases the glasses exhibited ductile behavior which is unusual for highly crosslinked materials. Room temperature viscosities of 100P–2000P permit facile processing of the liquid crystal monomers with inorganic particles to make dental restorative composites.
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