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1

Kashkoush, Ismail, Rich Novak, and Eric Brause. "In-Situ Chemical Concentration Control for Wafer Wet Cleaning." Journal of the IEST 41, no. 3 (May 14, 1998): 24–30. http://dx.doi.org/10.17764/jiet.41.3.f573u112344t8pr5.

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This paper demonstrates the use of conductivity sensors to monitor and control the concentration of RCA cleaning and hydrofluoric acid (HF) etching solutions. Commercially available electrodeless conductivity sensors were used to monitor and control the concentration of these process solutions. A linear relationship between the conductivity of the solution and the chemical concentration was obtained within the range studied. A chemical injection scheme was developed to maintain the chemical concentration within specified limits. Different concentrations of RCA-based cleaning solutions and HF solutions were investigated. Results show that these techniques are suitable for monitoring and controlling the concentration of chemicals in the process tanks for better process control. These techniques provide low cost of ownership of the process by using dilute chemicals and longer bath life (i.e., a more environmentally sound process).
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2

Ling, Zhigang, Naruhito Hori, Tadahisa Iwata, and Akio Takemura. "In-situ Analysis of Chemical Structure ofAPI Adhesive Using FT-NIR Spectroscopy." Journal of The Adhesion Society of Japan 51, s1 (2015): 322–31. http://dx.doi.org/10.11618/adhesion.51.322.

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3

Timmerman, Craig L., and Leonard N. Zintak. "Application of In-Situ Vitrification at the Parsons Chemical Site." Remediation Journal 8, no. 2 (1998): 75–85. http://dx.doi.org/10.1002/rem.3440080208.

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4

Ten Cate, J. M. "In Situ Models, Physico-Chemical Aspects." Advances in Dental Research 8, no. 2 (July 1994): 125–33. http://dx.doi.org/10.1177/08959374940080020201.

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In situ (intra-oral) caries models are used for two purposes. First, they provide information about oral physiological processes. Such information helps to detail our knowledge of the oral ecosystem and to verify conclusions from in vitro experiments. Second, in situ models are utilized to test preventive agents in the phase between laboratory testing and clinical trials. Most investigations involving enamel inserts have been aimed at testing new dentifrices. The experimental designs of such studies usually do not allow one to draw conclusions on physico-chemical processes, e.g., because of single point measurements. Studies of model parameters (lesion type, lesion severity, and de/remineralization in time) constitute only a minority of the research reports. The most striking observation obtained with in situ models has been the significant differences in de/remineralization observed among individuals and, more importantly, within one individual during different time periods and between different sites in the same mouth (for review, see ten Cate et al., 1992). Regardless of this, some general findings can be inferred: During in situ demineralization, up to 62 vol%μm/day may be removed from enamel. For dentin specimens, this value may be as high as 89 vol%μm/day. For remineralization, during fluoride dentifrice treatment, a median deposition rate of 0.7%/day (for lesions with integrated mineral loss values between 2000 and 4000 vol%μm) is found. The rate of deposition seems to be correlated with the extent of the pre-formedlesion. This suggests that the number of sites (crystallite surface) available for calcium phosphate precipitation is an important parameter. However, the rate at which mineral ions are supplied (by saliva) could also be a limiting factor, as is shown in a theoretical analysis of mass-balance of enamel constituents. The few studies that have monitored caries development in time reveal that mineral loss (and also lesion progression in depth) from enamel in situ is linear in time. This is in contrast to results from laboratory findings.
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5

Marken, Frank. "Chemical and electro-chemical applications of in situ microwave heating." Annual Reports Section "C" (Physical Chemistry) 104 (2008): 124. http://dx.doi.org/10.1039/b703986g.

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6

Prien, Ralf D. "The future of chemical in situ sensors." Marine Chemistry 107, no. 3 (December 2007): 422–32. http://dx.doi.org/10.1016/j.marchem.2007.01.014.

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7

Wang, Fushun, Baoguo Chen, Lei Wu, Qiuhua Zhao, and Lidong Zhang. "In Situ Swelling-Gated Chemical Sensing Actuator." Cell Reports Physical Science 1, no. 2 (February 2020): 100011. http://dx.doi.org/10.1016/j.xcrp.2019.100011.

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8

Gogotsi, Y., N. Naguib, and J. A. Libera. "In situ chemical experiments in carbon nanotubes." Chemical Physics Letters 365, no. 3-4 (October 2002): 354–60. http://dx.doi.org/10.1016/s0009-2614(02)01496-3.

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9

Waclavek, Ján, Gabriel Krausko, and Jaroslava Škriniarová. "Opticalin situ monitoring of wet chemical etching." Surface and Interface Analysis 26, no. 1 (January 1998): 56–61. http://dx.doi.org/10.1002/(sici)1096-9918(199801)26:1<56::aid-sia348>3.0.co;2-j.

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10

Karpenko, Olexandr, Vira Lubenets, Elena Karpenko, and Volodymyr Novikov. "Chemical Oxidants for Remediation of Contaminated Soil and Water. A Review." Chemistry & Chemical Technology 3, no. 1 (March 15, 2009): 41–45. http://dx.doi.org/10.23939/chcht03.01.041.

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This review covers the main agents used for in situ and ex situ chemical oxidation of organic contaminants particularly oil products, in soil and water environments. Among them there are hydrogen peroxide, permanganate salts, ozone and sodium persulfate. The fields of application, as well as benefits and disadvantages of the mentioned agents use were described.
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11

Reddy, Ramana G., and V. Kumar. "Chemical In Situ Synthesis of Aluminum Alloy Composites." Materials Science Forum 561-565 (October 2007): 701–4. http://dx.doi.org/10.4028/www.scientific.net/msf.561-565.701.

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Aluminum alloys were reinforced with AlN particles using a novel chemical in situ technique. Thermodynamic analyses were made to identify the conditions for the in situ formation of the AlN in Al alloys. Experiments were conducted in the temperature range of 1173-1473 K by injecting ammonia gas. The composites with AlN quantity varying from 5 to 51 wt % were produced. Effect of process variables such as gas injection time, flow rate of ammonia gas and temperature of the alloy melt on the formation of AlN was studied. Increase in either injection time or flow rate of the ammonia gas increased the nitride content. AlN particles with an average size of 500 nm were produced. The measured Vickers hardness of the composites formed increased with increasing AlN content. The amount of AlN experimentally formed is in good agreement with the thermodynamically predicted data.
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12

Schmidt-Ott, A., and P. Büscher. "In situ chemical classification of atmospheric aerosol particles." Journal of Aerosol Science 22 (1991): S307. http://dx.doi.org/10.1016/s0021-8502(05)80098-9.

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13

Ohashi, Y. "Real-Time In Situ Observation of Chemical Reactions." Acta Crystallographica Section A Foundations of Crystallography 54, no. 6 (November 1, 1998): 842–49. http://dx.doi.org/10.1107/s0108767398009118.

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14

Brea, Roberto J., Christian M. Cole, and Neal K. Devaraj. "In Situ Vesicle Formation by Native Chemical Ligation." Angewandte Chemie 126, no. 51 (October 24, 2014): 14326–29. http://dx.doi.org/10.1002/ange.201408538.

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15

Brea, Roberto J., Christian M. Cole, and Neal K. Devaraj. "In Situ Vesicle Formation by Native Chemical Ligation." Angewandte Chemie International Edition 53, no. 51 (October 24, 2014): 14102–5. http://dx.doi.org/10.1002/anie.201408538.

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16

Suthersan, Suthan, Jeff McDonough, Matt Schnobrich, and Craig Divine. "In Situ Chemical Treatment: A Love-Hate Relationship." Groundwater Monitoring & Remediation 37, no. 1 (February 2017): 17–26. http://dx.doi.org/10.1111/gwmr.12203.

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17

Vlahakis, J., C. Rogers, V. P. Manno, R. White, M. Moinpour, D. Hooper, and S. Anjur. "Synchronous, In Situ Measurements in Chemical Mechanical Planarization." Journal of The Electrochemical Society 156, no. 10 (2009): H794. http://dx.doi.org/10.1149/1.3205456.

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18

SCHÄFER, M., R. STARZMANN, and A. H. FOITZIK. "CHEMICAL MICROREACTORS FOR IN-SITU ONLINE PROCESS MONITORING." International Journal of Computational Engineering Science 04, no. 03 (September 2003): 601–4. http://dx.doi.org/10.1142/s146587630300185x.

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19

Vuillemin, R., D. Le Roux, P. Dorval, K. Bucas, J. P. Sudreau, M. Hamon, C. Le Gall, and P. M. Sarradin. "CHEMINI: A new in situ CHEmical MINIaturized analyzer." Deep Sea Research Part I: Oceanographic Research Papers 56, no. 8 (August 2009): 1391–99. http://dx.doi.org/10.1016/j.dsr.2009.02.002.

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20

Qin, Hua, Andong Zhao, and Xiaobing Fu. "Chemical modulation of cell fates: in situ regeneration." Science China Life Sciences 61, no. 10 (August 9, 2018): 1137–50. http://dx.doi.org/10.1007/s11427-018-9349-5.

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21

Wackett, Lawrence P. "In situ physico‐chemical methods in environmental microbiology." Environmental Microbiology 23, no. 1 (January 2021): 525–26. http://dx.doi.org/10.1111/1462-2920.15379.

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22

Liu, Min-Hsin, Chung-Ming Hsiao, Chih-En Lin, and Jim Leu. "Application of Combined In Situ Chemical Reduction and Enhanced Bioremediation to Accelerate TCE Treatment in Groundwater." Applied Sciences 11, no. 18 (September 9, 2021): 8374. http://dx.doi.org/10.3390/app11188374.

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Groundwater at trichloroethylene (TCE)-contaminated sites lacks electron donors, which prolongs TCE’s natural attenuation process and delays treatment. Although adding electron donors, such as emulsified oil, accelerates TCE degradation, it also causes the accumulation of hazardous metabolites such as dichloroethylene (DCE) and vinyl chloride (VC). This study combined in situ chemical reduction using organo-iron compounds with enhanced in situ bioremediation using emulsified oil to accelerate TCE removal and minimize the accumulation of DCE and VC in groundwater. A self-made soybean oil emulsion (SOE) was used as the electron donor and was added to liquid ferrous lactate (FL), the chemical reductant. The combined in situ chemical reduction and enhanced in situ bioremediation achieved favorable results in a laboratory microcosm test and in an in situ biological field pilot test. Both tests revealed that SOE+FL accelerated TCE degradation and minimized the accumulation of DCE and VC to a greater extent than SOE alone after 160 days of observation. When FL was added in the microcosm test, the pH value decreased from 6.0 to 5.5; however, during the in situ biological pilot test, the on-site groundwater pH value did not exhibit obvious changes. Given the geology of the in situ pilot test site, the SOE+FL solution that was injected underground continued to be released for at least 90 days, suggesting that the solution’s radius of influence was at least 5 m.
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23

Stock, H. R., C. Jarms, H. Berndt, B. Wielage, and A. Hofmann. "In-situ and ex-situ examination of the early stages of chemical vapor deposition." Fresenius' Journal of Analytical Chemistry 361, no. 6-7 (August 3, 1998): 645–46. http://dx.doi.org/10.1007/s002160050978.

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24

Lengyel, Istvan, and Klavs F. Jensen. "A chemical mechanism for in situ boron doping during silicon chemical vapor deposition." Thin Solid Films 365, no. 2 (April 2000): 231–41. http://dx.doi.org/10.1016/s0040-6090(00)00758-6.

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25

BORMAN, STU. "IN SITU CLICK CHEMISTRY." Chemical & Engineering News 80, no. 6 (February 11, 2002): 29–34. http://dx.doi.org/10.1021/cen-v080n006.p029.

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26

Shevah, Y., and M. Waldman. "In-situ and on-site treatment of groundwater (Technical Report)." Pure and Applied Chemistry 67, no. 8-9 (January 1, 1995): 1549–61. http://dx.doi.org/10.1351/pac199567081549.

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27

Koca, Atıf, Şerife Bayar, Hatice A. Dinçer, and Ergün Gonca. "Voltammetric, in-situ spectroelectrochemical and in-situ electrocolorimetric characterization of phthalocyanines." Electrochimica Acta 54, no. 10 (April 2009): 2684–92. http://dx.doi.org/10.1016/j.electacta.2008.11.028.

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28

Buist, Ian, James McCourt, Steve Potter, Sy Ross, and Ken Trudel. "In Situ Burning." Pure and Applied Chemistry 71, no. 1 (January 1, 1999): 43–65. http://dx.doi.org/10.1351/pac199971010043.

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Introduction: The use of in situ burning as a spill response technique is not new, having been researched and used for a variety of oil spills since the late 1960s. In general, the technique has proved effective for oil spills in ice conditions and has been used successfully to remove oil spills in ice-covered waters resulting from storage tank and ship accidents in Alaska, Canada and Scandinavia.Although there have been numerous incidents of vessel oil spills that inadvertently caught fire, the intentional ignition of oil slicks on open water has only been seriously considered since the development of fire-resistant oil containment boom beginning in the early 1980s. The development of these booms offered the possibility of conducting controlled burns in open water conditions. In situ burning operations using these booms have been conducted at three spills in the last decade: a major offshore tanker spill, a burning blowout in an inshore environment, and a pipeline spill into a river. In situ burning of thick, fresh slicks can be initiated very quickly by igniting the oil with devices as simple as an oil-soaked sorbent pad. In situ burning can remove oil from the water surface very efficiently and at very high rates. Removal efficiencies for thick slicks can easily exceed 90%. Removal rates of 2000 m3/hr can be achieved with a fire area of only about 10,000 m2 or a circle of about 100 m in diameter. The use of towed fire containment boom to capture, thicken and isolate a portion of a spill, followed by ignition, is far less complex than the operations involved in mechanical recovery, transfer, storage, treatment and disposal. If the small quantities of residue from an efficient burn require collection, the viscous, taffy-like material can be collected and stored for further treatment and disposal. There is a limited window of opportunity for using in situ burning with the presently available technology. This window is defined by the time it takes the oil slick to emulsify; once water contents of stable emulsions exceed about 25%, most slicks are unignitable. Research is ongoing to overcome this limitation. Despite the strong incentives for considering in situ burning as a primary countermeasure method, there remains some resistance to the approach. There are two major concerns: first, the fear of causing secondary fires that threaten human life, property and natural resources; and, second, the potential environmental and human-health effects of the by-products of burning, primarily the smoke. The objective of this chapter is to review the science, technology, operational capabilities and limitations and ecological consequences of in situ burning as a countermeasure for oil spills on water. The main focus of this section is on marine oil spills in open water conditions. The use of in situ burning for spills in ice conditions is dealt with in another chapter. Much of the content of this chapter is updated from an in-depth review of in situ burning produced for the Marine Spill Response Corporation (MSRC) in 1994 (ref. 1). Interested readers are encouraged to refer to the original report for fully-referenced details of the summary presented here. The MSRC report is available from the American Petroleum Institute in Washington, DC.
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29

SEOL, Y. "A Review of In Situ Chemical Oxidation and Heterogeneity." Environmental and Engineering Geoscience 9, no. 1 (February 1, 2003): 37–49. http://dx.doi.org/10.2113/9.1.37.

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30

Hazard, John E., Rich Dulcey, and Marie Pittignano. "IN SITU CHEMICAL OXIDATION OF CARBON DISULFIDE IMPACTED SOIL." Proceedings of the Water Environment Federation 2002, no. 14 (January 1, 2002): 92–107. http://dx.doi.org/10.2175/193864702784248368.

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31

Mirsaidov, Utkur. "Visualizing Chemical Processes in Semiconductors with In Situ TEM." Microscopy and Microanalysis 26, S2 (July 30, 2020): 2038. http://dx.doi.org/10.1017/s1431927620020231.

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32

Morrison, Shaunna M., Robert T. Downs, David F. Blake, David T. Vaniman, Douglas W. Ming, Allan H. Treiman, Cherie N. Achilles, et al. "Predicting Martian mineral compositions in situ: crystal chemical techniques." Acta Crystallographica Section A Foundations and Advances 75, a1 (July 20, 2019): a202. http://dx.doi.org/10.1107/s0108767319098015.

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33

Mann, J. R., N. Vora, and I. L. Repins. "In Situ thickness measurements of chemical bath-deposited CdS." Solar Energy Materials and Solar Cells 94, no. 2 (February 2010): 333–37. http://dx.doi.org/10.1016/j.solmat.2009.10.009.

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34

Watts, Richard J., Mushtaque Ahmad, Amanda K. Hohner, and Amy L. Teel. "Persulfate activation by glucose for in situ chemical oxidation." Water Research 133 (April 2018): 247–54. http://dx.doi.org/10.1016/j.watres.2018.01.050.

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35

Takahashi, Yasufumi, Yuanshu Zhou, and Takeshi Fukuma. "In situ chemical sensing by using scanning probe microscope." Folia Pharmacologica Japonica 153, no. 6 (2019): 267–72. http://dx.doi.org/10.1254/fpj.153.267.

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36

Pac, Timothy J., James Baldock, Brendan Brodie, Jennifer Byrd, Beatriz Gil, Kevin A. Morris, Denice Nelson, et al. "In situ chemical oxidation: Lessons learned at multiple sites." Remediation Journal 29, no. 2 (February 28, 2019): 75–91. http://dx.doi.org/10.1002/rem.21591.

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37

Nießner, Reinhard. "Chemical Characterization of Aerosols: On-Line and In Situ." Angewandte Chemie International Edition in English 30, no. 5 (May 1991): 466–76. http://dx.doi.org/10.1002/anie.199104661.

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38

Ertl, G. "In-situ-Investigations of Physico-Chemical Processes at Interfaces." Berichte der Bunsengesellschaft für physikalische Chemie 97, no. 3 (March 1993): 279. http://dx.doi.org/10.1002/bbpc.19930970302.

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39

Sasaki, K., and J. Maier. "In situ EPR studies of chemical diffusion in oxides." Physical Chemistry Chemical Physics 2, no. 13 (2000): 3055–61. http://dx.doi.org/10.1039/b002850i.

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40

Huling, Scott G., Randall R. Ross, and Kimberly Meeker Prestbo. "In Situ Chemical Oxidation: Permanganate Oxidant Volume Design Considerations." Groundwater Monitoring & Remediation 37, no. 2 (January 19, 2017): 78–86. http://dx.doi.org/10.1111/gwmr.12195.

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41

Nuñez, L., B. A. Buchholz, and G. F. Vandegrift. "Waste Remediation Using in Situ Magnetically Assisted Chemical Separation." Separation Science and Technology 30, no. 7-9 (April 1995): 1455–71. http://dx.doi.org/10.1080/01496399508010357.

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42

Müller, B. "In situ Measurements in Lake Sediments with Chemical Sensors." Mineralogical Magazine 62A, no. 2 (1998): 1034–35. http://dx.doi.org/10.1180/minmag.1998.62a.2.208.

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43

Cavé, Lisa, Niels Hartog, Tom Al, Beth Parker, K. Ulrich Mayer, and Steven Cogswell. "Electrical Monitoring of In Situ Chemical Oxidation by Permanganate." Groundwater Monitoring & Remediation 27, no. 2 (March 2007): 77–84. http://dx.doi.org/10.1111/j.1745-6592.2007.00139.x.

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44

Gates, Dianne D., and Robert L. Siegrist. "In-Situ Chemical Oxidation of Trichloroethylene Using Hydrogen Peroxide." Journal of Environmental Engineering 121, no. 9 (September 1995): 639–44. http://dx.doi.org/10.1061/(asce)0733-9372(1995)121:9(639).

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45

Murali, V., A. T. Wu, L. Dass, M. R. Frost, D. B. Fraser, J. Liao, and J. Crowley. "In-situ processing using rapid thermal chemical vapor deposition." Journal of Electronic Materials 18, no. 6 (November 1989): 731–36. http://dx.doi.org/10.1007/bf02657526.

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46

Teo, P. S., H. N. Lim, N. M. Huang, C. H. Chia, and I. Harrison. "Room temperature in situ chemical synthesis of Fe3O4/graphene." Ceramics International 38, no. 8 (December 2012): 6411–16. http://dx.doi.org/10.1016/j.ceramint.2012.05.014.

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47

Zhang, Long, Tingmei Wang, and Peng Liu. "Polyaniline-coated halloysite nanotubes via in-situ chemical polymerization." Applied Surface Science 255, no. 5 (December 2008): 2091–97. http://dx.doi.org/10.1016/j.apsusc.2008.06.187.

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48

CAVALCANTI, F. "In situ chemical trapping of CO/H2 surface species." Journal of Catalysis 113, no. 1 (September 1988): 1–12. http://dx.doi.org/10.1016/0021-9517(88)90232-1.

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49

TRANTER, M., M. J. SHARP, G. H. BROWN, I. C. WILLIS, B. P. HUBBARD, M. K. NIELSEN, C. C. SMART, S. GORDON, M. TULLEY, and H. R. LAMB. "VARIABILITY IN THE CHEMICAL COMPOSITION OFIN SITU SUBGLACIAL MELTWATERS." Hydrological Processes 11, no. 1 (January 1997): 59–77. http://dx.doi.org/10.1002/(sici)1099-1085(199701)11:1<59::aid-hyp403>3.0.co;2-s.

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50

Tarifa, J. M., C. P. A. Ruiz, and J. L. M. Barillas. "ANALYZING CHEMICAL REACTION MODELS FOR IN SITU COMBUSTION PROCESS." Brazilian Journal of Petroleum and Gas 10, no. 2 (July 12, 2016): 89–103. http://dx.doi.org/10.5419/bjpg2016-0008.

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