Academic literature on the topic 'Illite rich rocks'

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Journal articles on the topic "Illite rich rocks"

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Bozkaya, Ö., H. Yalçin, and P. A. Schroeder. "Two-step mode of clay formation in the extensional basins: Cambrian–Ordovician clastic rocks of the Antalya unit, SW Turkey." Clay Minerals 52, no. 3 (September 2017): 365–89. http://dx.doi.org/10.1180/claymin.2017.052.3.07.

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AbstractOrdovician clastic rocks of the Antalya unit in SW Turkey bear mineralogical/geochemical evidence of Triassic extensional rift timing and spatial relations. The crystal chemistry of the phyllosilicate assemblages (illite, chlorite, kaolinite, mixed-layer illite-smectite, chlorite-vermiculite and chlorite-smectite) is consistent with the rock experiencing a multi-generational burial history. The appearance of kaolinite and illite-smectite-bearing rocks in the Antalya unit is characteristic of diagenetic-anchimetamorphic conditions and is of higher grade than their anchi-epizonal equivalents in other regions of the Tauride belt. Illites and chlorites are of both detrital and authigenic origin, whereas I-S and kaolinites are authigenic. Detrital micas have been altered to chlorite and K-white mica stacks in which relicts suggest the chlorites were derived from detrital biotites. The broad X-ray diffraction illite peaks show that they are composed both of illite and illite-smectite. Na,K-mica and paragonite occur within the chlorite-mica stacks as replacements of muscovite, probably driven by Na-rich solutions. The authigenic clays were formed within the microporous matrix and the interplanar spaces of {001} planes of chlorite-mica stacks, with textures independent of the bedding and foliation planes of the rocks. The authigenic chlorites exhibit higher Si and Fe and lower Mg contents than their detrital counterparts. Authigenic chlorite thermometry indicates rift-related temperatures of 50–150°C, whereas pre-rift detrital chlorites formed at temperatures of >200°C. Authigenic illite and illite-smectite are phengitic in composition and contain more Si, Mg, Fe and Ca and less Al and K than detrital K-white micas. The textural, mineralogical and chemical characteristics support the hypothesis that the mineral assemblages were a result of a two-step mode of formation with diagenetic overprints of previously anchizonal rocks in extensional basin conditions.
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Papoulis, D., and P. Tsolis-Katagas. "Formation of alteration zones and kaolin genesis, Limnos Island, northeast Aegean Sea, Greece." Clay Minerals 43, no. 4 (December 2008): 631–46. http://dx.doi.org/10.1180/claymin.2008.043.4.08.

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AbstractKaolin deposits extending over an area of ~10 km2in the western and southern parts of Limnos Island, northeast Aegean Sea, Greece, were studied. The kaolin deposits are alteration products of volcanic rocks, mainly trachytes, trachyandesites, andesites and dacites. Study of the collected samples was carried out using X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy-dispersive scanning electron microscopy (SEM-EDS), Fourier transform Raman spectroscopy (FT-Raman), Fourier transform infrared (FTIR) techniques and inductively-coupled plasma (ICP) bulk rock chemical analyses for major, trace and rare earth elements. The extensive alteration of the parent rocks resulted from the circulation of hydrothermal fluids through faults and fractures. The development of the various assemblages depends not only on the temperature and composition of the hydrothermal fluids but also on the distance of the rock from the fault or the channel of the ascending hydrothermal fluids.Kaolinite, dickite, halloysite, illite, smectite and mixed-layer illite-smectite and jarosite were detected in the altered volcanic rocks forming locally various alteration zones. Smectite-rich zones and illite-rich zones are relatively infrequent. In the halloysite-rich zones, the kaolinization of feldspars is accomplished in four stages. The kaolinizaton of feldspars in the kaolinite-dickite-rich zones follows five discrete stages. In the less altered rocks, thin layers of kaolinite are formed on the surface of feldspars. With increasing kaolinization, kaolinite is developed on the surface of feldspars forming extended parallel booklets of newly formed kaolinite. In the third stage, feldspar crystals are partially altered to kaolinite booklets. As kaolinization advances, kaolinite becomes well formed and, in the most altered rocks, feldspars are partially or completely altered to dickite books, depending on the temperature of the hydrothermal fluids.
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Almeida, Delia Del Pilar M. de, Vitor P. Pereira, Adriane Machado, Henrique Zerfass, and Ricardo Freitas. "Late sodic metasomatism evidences in bimodal volcanic rocks of the Acampamento Velho Alloformation, Neoproterozoic III, southern Brazil." Anais da Academia Brasileira de Ciências 79, no. 4 (December 2007): 725–37. http://dx.doi.org/10.1590/s0001-37652007000400012.

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A mineralogical study was carried out in mafic and felsic volcanic rocks of the Acampamento Velho Alloformation at Cerro do Bugio, Perau and Serra de Santa Bárbara areas (Camaquã Basin) in southern Brazil. The Acampamento Velho bimodal event consists of two associations: lower mafic at the base and upper felsic at the top. Plagioclase and alkali-feldspar were studied using an electronic microprobe, and magnetite, ilmenite, rutile, illite and alkali-feldspar were investigated through scanning electron microscopy. The rocks were affected by a process of late sodic autometasomatism. In mafic rocks, Ca-plagioclase was transformed to albite and pyroxenes were altered. In felsic rocks, sanidine was partially pseudomorphosed, generating heterogeneous alkali-feldspar. In this association, unstable Ti-rich magnetite was replaced by rutile and ilmenite. In mafic rocks, the crystallization sequence was: (1) Ti-rich magnetite (?), (2) pyroxene and Ca-plagioclase, (3) albite (alteration to Ca-plagioclase), (4) sericite, chlorite and calcite (alteration to pyroxene), and kaolinite (alteration to plagioclase/albite). In felsic rocks: (1) zircon, (2) Ti-rich magnetite, (3) sanidine, (4) quartz. The introduction of late Na-rich fluids, generated the formation of (5) heterogeneous alkali-feldspar, (6) ilmenite and rutile from the Ti-rich magnetite, (7) albite in the spherulites. Finally, alteration of sanidine, vitroclasts and pumice to (8) illite.
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Brattli, B. "A rectorite-pyrophyllite-chlorite-illite assemblage in pelitic rocks from Colombia." Clay Minerals 32, no. 3 (September 1997): 425–34. http://dx.doi.org/10.1180/claymin.1997.032.3.05.

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AbstractIn samples of slate from the Fomeque Formation near Bogota, Colombia, pyrophyllite was found to occur together with mixed-layered illite-smectite, chlorite and illite. Other minerals were quartz, K-feldspar, dolomite and pyrite. X-ray diffraction patterns revealed that the mixed-layer represents an R1 ordered rectorite with 80–90% illite layers. The microfabric is developed as a closely spaced cleavage in the phyllosilicate-rich rocks, and grades into a fracture cleavage with coarsening of the grain size. No cleavage was observed in the interbedded siltstones. It is suggested that the microfrabrics developed in these rocks correspond to high diagenetic to anchizonal conditions. The illite crystallinity from the slate has been measured on glycolated samples and ranges from 0.47 to 0.55°Δ2θ with a mean of 0.52°Δ2θ Based on the stability of R1 ordered rectorite, the illite crystallinity and the microfabric development, it is proposed that the rocks have been subjected to a temperature of ∼200°C at low pressure. At this temperature, pyrophyllite can only be stabilized at the expense of kaolinite and quartz if aH2O ≪ 1.
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Zhang, Jie, En Lin Yang, Yong Ning Di, Fei Xie, and Guo Feng Yang. "Study of Material Characteristics about Lower Cambrian Black Shale in ZhiJin-KaiYang-XiFeng, Guizhou." Applied Mechanics and Materials 170-173 (May 2012): 1162–66. http://dx.doi.org/10.4028/www.scientific.net/amm.170-173.1162.

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The high cambrian black rock series of clay under Zhijin, Kaiyang, Xifeng and other areas of Guizhou , are high carbon black shale - clay rocks characterized by containing illite ores[1]. After deep processing, it will be served as illite ores belonging to a useful clay minerals, and the main directions of development and application include filler, new building materials and ceramics. After the activation, potassium can be extracted from illite that is often rich in potassium which can be prepared for potash fertilizer. Carrying out the study of mineral material science of high carbon black clay mineral rock , the aim is developing and using this type of non-metallic mineral. Based on this study, recoverying useful metal elements by exploring the reasonable technical process will be significant to enhance the comprehensive value of the type of deposit and improve its economic efficiency.
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Mahmoud, Soliman Abu Elatta A., and Hani H. Ali. "Geology and genesis of vein-type corundum deposits in the Hafafit-Nugrus area, South Eastern Desert, Egypt." Geologos 26, no. 3 (December 1, 2020): 181–97. http://dx.doi.org/10.2478/logos-2020-0018.

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Abstract Unusual deposits formed by corundum are described from two separate pegmatitic veins in the Hafafit-Nugrus area of the South Eastern Desert of Egypt. Other related minerals are described too. The vein-type of corundum at Locality 1 (Vein 1) crosscuts through exposed rocks of an ophiolitic mélange, whereas at Locality 2 (Vein 2), it crosscuts through exposed serpentinised ultramafic rocks. The main minerals in Vein 1 are plagioclase, corundum, grossular, phlogopite, muscovite and clinochlore, while almandine, xenotime-(Y), allanite-(Ce), zircon, Cr-rich spinel, apatite, titanite, fergusonite-(Y), meta-ankoleite, U-rich thorite (uranothorite), carbonate and illite are the accessories. In Vein 2, the main minerals are plagioclase, corundum, phlogopite and chlorite, while clinochlore, euxenite-(Y), Nb-rich rutile, almandine, xenotime-(Y), allanite-(Ce), zircon, spinel, apatite, titanite, kasolite, dickite, illite, carbonate, antigorite and talc are accessories. The two types of corundum veins differ in their concentrations of Th, U, Zr, Nb, Ta, REE, Y and Li in whole-rock compositions. Field observations, mineralogy and chemical analyses of samples from the two veins of corundum deposits, as well as concentrations of chromophore elements in corundum crystals, suggest metasomatic origins. The present study suggests that the two types of corundum veins formed at different ages from different residual magmas that underwent in-situ hybridisation with the host rocks.
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Xiao, Zhenghui, Yunjiang Cao, Wei Jiang, Ping Zhou, Yanran Huang, and Jisong Liu. "Minerals and Enrichment of W, Rb, and Cs in Late Permian Coal from Meitian Mine, Meitian Coalfield, Southern China by Magmatic Hydrothermal Fluids." Minerals 8, no. 11 (November 5, 2018): 504. http://dx.doi.org/10.3390/min8110504.

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We report on the effects of magmatic hydrothermal fluids on the mineralogical and geochemical compositions of 12U and 12L Coals from the Meitian Mine in the Meitian Coalfield, southern China. The minerals in 12U Coal are predominantly chlorite, quartz, and calcite, while the minerals in 12L Coal consist mainly of illite, quartz, chlorite, kaolinite, and mixed-layer illite/smectite (I/S). The vesicle- and fracture-filling illite, chlorite, I/S, pyrite, and fluorite, cleat- and fracture-filling carbonate minerals (i.e., calcite, and dolomite), and cleat-filling tremolite, diopside, and talc have epigenetic hydrothermal origins. Tremolite, diopside, and talc were probably formed from the reaction between dolomite and Si-rich magmatic hydrothermal fluids. Elevated Pb–Zn–Sn–Cd assemblages are characteristic for the 12U Coal, while 12L Coal is enriched in W, Rb, Cs, Th, V, Zn, and Zr, most notably W, Rb, and Cs. REY (Rare Earth Elements and Yttrium) plots for almost all coals, partings and host rocks are similar, showing an M-type REY distribution, Gd-maximum, positive Y anomalies, and negative Ce anomalies, suggesting acid hydrothermal circulation in the coal-bearing strata. Rubidium and cesium in the coal is clearly associated with K-rich clay minerals (illite + I/S), and to a lesser extent with silicate minerals that were precipitated from hydrothermal solutions. W in the coals mainly occurs in the inorganic constituents of illite and pyrite, especially illite. Enrichment of W, Rb, and Cs in the coal and host rocks is genetically associated with magmatic hydrothermal fluids. Specifically, magmatic hydrothermal fluids of relatively high temperatures that are rich in volatile matter can extract abundant W, Rb, and Cs from granitic melts. The enrichment of these rare metals in the coal is mainly related to illitization. Our study results suggest that, for coal intruded by magmatic rocks, the type of hydrothermal alteration may greatly influence the enrichment of elements.
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Clauer, Norbert. "How Can Technical Aspects Help Improving K-Ar Isotopic Data of Illite-Rich Clay Materials into Meaningful Ages? The Case of the Dominique Peter Uranium Deposit (Saskatchewan, Canada)." Geosciences 10, no. 8 (July 27, 2020): 285. http://dx.doi.org/10.3390/geosciences10080285.

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Previously published K-Ar dating results of <2 μm illite separates from uranium-hosting and associated barren rocks from Dominique Peter district of the Carswell circular structure in the Athabasca Basin (Canada) were considered to trace four distinct tectonic-thermal events at 1447 ± 45, 1282 ± 40 and 1184 ± 15 (all errors at ± 2 Ma, with a younger, less constrained episode at ~900 Ma. Recent analyses of K-Ar ages of additional <0.2 μm illite fractions from a few initial samples demonstrate that the intermediate ages at ~1280 and ~1185 Ma result, in fact, from mixing of two generations of illite that precipitated at ~1450 and ~900 Ma. They have, therefore, no stratigraphic value, while the two tectonic-thermal episodes at 1448 ± 48 and 937 ± 39 Ma appear to be historically sound. In fact, the analytical procedure of isotopic dating clay materials is of more importance than is often stated. For instance, a safe way to evaluate and constrain best numerical isotopic data of clay separates into ages is combining data of two size splits from several samples. If such age data, especially from size fractions of indurated host rocks, are scattered and point towards the higher data of the coarser fractions, they are potentially enriched in earlier crystallized K-rich components, and should consequently be discarded. The occurrence of detrital or early-crystallized components in clay-rich separates becomes a serious concern when comparing ages generated by various isotopic methods on mineral separates of various whole rocks. It is especially verified in very old, metal-rich deposits such as the uranium-rich deposits of the Saskatchewan Basin. These deposits and their host rocks were studied extensively by a large spectrum of isotopic methods on many types of rocks in a widely dispersed area, and for which the numerical statistics became, sometimes, more central in the interpretation than the specificity of the successive events in the host rocks.
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Velde, B. "Possible chemical controls of illite/smectite composition during diagenesis." Mineralogical Magazine 49, no. 352 (June 1985): 387–91. http://dx.doi.org/10.1180/minmag.1985.049.352.09.

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AbstractRe-interpretation of the significance of phase assemblages present in two sequences of rocks having experienced similar burial diagenesis allows one to establish that the change of oxidation state of iron in sediments could have the effect of changing the smectite content of the mixed layer mineral. This is used to explain an almost isothermal change in the composition of a sequence while others do not show such a rapid change. An indicator of the reaction is seen in the composition of the chlorite present in the rocks which is iron-rich and alumina-poor compared to chlorites in rocks showing a slower rate of change in the smectite content of the mixed-layered mineral. In order to reveal such a relation, one must make an analysis of the clay mineral assemblage, especially in the number of phases present during the course of diagenesis.
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Clauer, N., N. Liewig, and I. Bobos. "K-Ar, δ18O and REE constraints on the genesis of ammonium illite from the Harghita Bãi hydrothermal system, Romania." Clay Minerals 45, no. 3 (September 2010): 393–411. http://dx.doi.org/10.1180/claymin.2010.045.3.393.

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AbstractAmmonium illite and ammonium illite-smectite mixed layers, together with potassium illite, smectite and minute amounts of kaolinite were identified in hydrothermally altered andesite rocks from the Harghita Bãi area of the Eastern Carpathians, Romania. K-Ar dating and oxygen isotope tracing, as well as rare-earth elemental analyses were made to provide new information on the timing and crystal-chemical processes characterizing the crystallization and further evolution of these illite-type mineral phases.The combined results suggest the occurrence of hydrothermal activity in two distinct episodes with nucleation of two generations of illite-type particles of different chemistry and morphology. About 9.5 Ma ago, potassium illite crystallized in alteration halos of the porphyry Cu system, probably at a temperature of ~270ºC from fluids having a δ18O of ~2.9% (V-SMOW). Associated smectite seems to have precipitated slightly later in external alteration halos at a similar temperature, but from fluids depleted in alkalis and with a different δ18O. Alternately, ammonium-rich illite-smectite mixed layers formed very recently, less than ~1 million years ago at a temperature of ~90ºC from fluids of probable meteoric origin that altered the previously crystallized potassium illite, resulting in the crystallization of a new generation of ammonium illite-smectite mixed layers. Evidence of this dissolution-precipitation process is provided by a significant increase in the δ18O of the mixed-layer structures and by a significant change in their REE contents and distribution patterns. Occurrence of potassium in the ammonium-rich mixed layers probably relates to the progressive alteration of the first-generation potassium illite and a discrete concomitant take up of released K by the new NH4-rich interlayers of the ammonium mixed layered sequence.
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Book chapters on the topic "Illite rich rocks"

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Jain, Ronak. "Feature-Oriented Principal Component Selection (FPCS) for Delineation of the Geological Units Using the Integration of SWIR and TIR ASTER Data." In Remote Sensing [Working Title]. IntechOpen, 2021. http://dx.doi.org/10.5772/intechopen.99046.

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Geological studies have been performed using the Band Ratios (BR), Relative Band Depth (RBD), Mineral Indices (MI), Principal Component Analysis (PCA), Independent Component Analysis (ICA), lithological and mineral classification techniques from Short-Wave Infrared (SWIR) and Thermal Infrared (TIR) data. The chapter aims to delineate various geological units present in the area using the combination of SWIR and TIR ASTER bands through the Feature-Oriented Principal Component Selection (FPCS) technique. Different BRs and RBDs were applied to map the minerals having Al-OH and Mg-OH compounds with the chemical composition of clay (kaolinite, smectite), mica (sericite, muscovite, illite), ultramafic (lizardite, antigorite, chrysotile), talc, and carbonate (dolomite) from SWIR bands. The MI was used to map quartz-rich, mafic/ultramafic, and carbonate rocks using TIR bands. The BRs, RBDs, and MIs mapped the geological units but every single greyscale image showed a variety of features. To compile these features False Color Composite (FCC) was prepared by the combination of RBDs and MIs in the R:G:B channels which demarked various geological units to a larger extent present in the region. To overcome the limitation, the FPCS technique was applied with the integration of all BRs, RBDs, and MIs. The FPCS technique extracts valuable information from different input bands and shifts the information in the first few bands. The generated eigenvalues and eigenvectors represented the retrieved information in the specific band. The loadings of the eigenvector were used for the selection of the different brands to create the FCC for the delineation of geological strata. The best discrimination was made by the selection of FPCS1, FPCS3, and FPCS6 which differentiated all the geological units like ultramafics, dolomites, thin bands of talc, and muscovite and illite (as phyllite and mica-schist), silica-rich rocks (as quartzite), and granite outcrops.
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Conference papers on the topic "Illite rich rocks"

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Ivanishin, Igor, Bradley Abell, and Hadi Nasrabadi. "Optimized X-Ray Diffraction Analysis Predicts the Swelling Potential of Shales." In SPE Eastern Regional Meeting. SPE, 2022. http://dx.doi.org/10.2118/211879-ms.

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Abstract The presence of expandable clay minerals within the reservoir and source rocks causes many issues over the life of the well. These include wellbore instability and increased mud losses during drilling operations, complications and decrease in production during and after hydraulic fracturing, etc. Existing standard laboratory test methods, e.g., capillary suction time test, do not adequately predict swelling potential. The present work provides the technique to determine the properties and quantify the concentration of expandable clay minerals, thus predicting the swelling potential of clay-rich rocks. A collection of ash layer and bentonite mine samples has been analyzed for the bulk and clay fraction mineral composition and swelling in completion fluids. Comparison of X-ray diffractograms recorded from air-dried and ethylene glycolated clay fractions of ash layer samples confirmed the absence of discrete smectite but revealed the presence of interstratified illite/smectite and illite. X-ray diffractograms of all the ethylene glycolated samples have characteristic complex reflections with two maximas: one between 6.8–7.8°2θ (11.3–13.1 Å), another between 9.3–9.6°2θ (9.3–9.5 Å). Both correspond to the 001 reflection of interstratified illite/smectite mineral, and not a pure endmember illite or smectite. Two properties of this mineral vary among the samples and influence their expandability: (1) illite:smectite ratio in the range 3:2–9:1, and (2) the nature of the interstratification, i.e., the degree of ordering. The shifts of the peak maximas in the regions 6.8–9.6°2θ and 42.0–48.0°2θ are used to calculate the proportion of the component layers. Proposed technique of optimized XRD analysis reveals that the samples containing less illite/smectite mineral, but the higher concentration of smectite layers in this mixed-layer mineral are more expandable. Optimized XRD analysis correctly predicts the swelling potential of a given clay-rich zone (e.g., ash layer) as confirmed by confined immersion testing. Provided technique of XRD analysis is fast, requires small quantities of sample, and could possibly be integrated to field logs in the future. Obtained knowledge can be applied by engineers and researchers working with shale formations around the world.
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Silveira de Araujo, Isa, and Zoya Heidari. "Quantifying Interfacial Interactions Between Minerals and Reservoir/Fracturing Fluids." In 2022 SPWLA 63rd Annual Symposium. Society of Petrophysicists and Well Log Analysts, 2022. http://dx.doi.org/10.30632/spwla-2022-0072.

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Chemical interactions between the injected fluids and the minerals during the fracturing process can affect fluid-flow and production. However, there is still a need for understanding the impact of geochemistry on the interactions at the rock- fluids interface, and how these interactions affect wettability of the rock and the fluid-flow in organic-rich mudrocks. In this paper, we quantify the mineral-fluid affinity by performing adsorption calculations. Molecular Dynamics Simulations (MDS) are carried out to (i) quantify adsorption of fracturing fluids on the surface of minerals, (ii) perform sensitivity analysis on the composition of fracturing fluid and reservoir temperature on adsorption, and (iii) analyze the spatial distribution of water and chemicals on mineral surfaces. The minerals evaluated include illite, and the fracturing fluid components are methanol, citric acid, sodium chloride and water. Initially, we evaluate the effect of each chemical separately. We generate systems composed of mineral surface in contact with water, salt and each one of the chemicals. Finally, we analyze the complete system containing water, salt and all additives. MDS are carried out in the canonical (NVT) ensemble at the temperature of 330K to evaluate the adsorption of the fracturing fluid. To quantify the impacts of reservoir temperature, we carry out MDS at temperature of 360K. Results suggest that methanol does not have a strong effect on water adsorption and on the ion spatial distribution on illite surface. We found that citric acid tends to forms aggregates and that some cations present in the solution, specially sodium, participate in these citric acid aggregates. When methanol or citric acid are added to the brine solution we observed that mobility of both sodium and water decreased. The effects on mobility of sodium cations were more intense when citric acid was present in the solution. The effects of each additive on the affinity between illite and the fracturing fluids were also investigated. We found that the number of hydrogen bonds between illite and the fluid did not change when additives were added, however we observe a decrease in the number of hydrogen bonds between water molecules when methanol or citric acid were in the solution. The quantification of adsorption in the molecular scale provides fundamental understanding of the electrochemical interactions between the rock surface and the fracturing/reservoir fluids at reservoir conditions, which enables enhanced design of fracturing-fluid composition for different reservoir types. This information can also be used to quantify the impacts of injected and reservoir fluids on wettability of the rocks.
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Silveira de Araujo, Isa, and Zoya Heidari. "Quantification of Adsorption of Water on Clay Surfaces and Electrical Double Layer Properties Using Molecular Simulations." In 2022 SPWLA 63rd Annual Symposium. Society of Petrophysicists and Well Log Analysts, 2022. http://dx.doi.org/10.30632/spwla-2022-0005.

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Quantification of adsorption of water on the clay mineral surface at a molecular scale can provide fundamental insights on the properties of electrical double layer (EDL), cation exchange capacity (CEC), and production performance of clay-rich formations. However, there are limited fundamental studies on quantifying the impacts of reservoir temperature/pressure on water adsorption on clay surface, and on the factors controlling the properties of EDL. In this project, we use molecular simulations to (i)investigate water adsorption on clay minerals (ii)quantify the impacts of reservoir temperature onadsorption (iii) investigate the structure of the EDL onclay surface as a function of electrolyte concentrationand pore size and calculate diffusion coefficients. Grand Canonical Monte Carlo (GCMC) simulations are performed to calculate water adsorption. These simulations are performed at 330K at the pressure of 5MPa. Then, an electrolyte (including NaCl) is added to the system and Molecular Dynamics (MD) simulations are performed at temperature range of 330K to 380K. To investigate the impact of electrolyte concentration on the geochemistry of the solid-fluid interface, these simulations are performed at electrolyte concentrations ranging from of 0.7 mol/dm3, 1.4 mol/dm3 and 1.9 mol/dm3. To analyze the effects of confinement on water adsorption, MD simulations performed on 2 and 4 nm-wide illite slit pores. We applied the proposed methods on multiple types of clay minerals including illite and kaolinite. Our results show the formation of two hydration layers on the surface of illite and kaolinite. We found that the position of the adsorbed cations and anions inside the clay nanopore do not change significantly with ionic strength, and that clay geochemistry is the main factor determining the adsorption planes of ions. As temperature increases the mobility of water and ions increase, however when temperature is increased from 360 K to 380 K the increase in mobility is not significant. Results also showed that the diffusion coefficient of molecules across the surface of clay walls is smaller compared to that parallel to the surface. Besides that, we found that as confinement effect increases, spatial distribution of ions does not change, but the van der Waals interactions between clay surface and brine increases. Quantification of water adsorption and characterization of EDL in clay minerals at reservoir conditions cannot be easily assessed experimentally. The proposed method enabled quantifying water adsorption and EDL characterization in different types of clay minerals and elucidating the clay-water interface at such conditions. The outcomes of this work can potentially contribute to development of quantitative models for CEC and wettability assessment as a function of geochemistry of the rock.
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