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MA, XIAO, KUNGUANG YANG, and ALI POLAT. "U–Pb ages and Hf isotopes of detrital zircons from pre-Devonian sequences along the southeast Yangtze: a link to the final assembly of East Gondwana." Geological Magazine 156, no. 06 (August 22, 2018): 950–68. http://dx.doi.org/10.1017/s0016756818000511.
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AbstractThe Early Palaeozoic geology of the South China Craton (SCC) is characterized by an Early Palaeozoic intracontinental orogen with folded pre-Devonian strata and migmatites, MP/MT metamorphic rocks and Silurian post-orogenic peraluminous magmatic rocks in both the Yangtze and the Cathaysia blocks. In this contribution, we present new zircon U–Pb ages and Hf isotope data for detrital zircons from the Neoproterozoic to Silurian sedimentary sequences in the southeastern Yangtze Block. Samples from Neoproterozoic rocks generally display a major peak at 900–560 Ma, whereas samples from Lower Palaeozoic rocks are characterized by several broader peaks within the age ranges 600–410 Ma, 1100–780 Ma, 1.6–1.2 Ga and 2.8–2.5 Ga. Provenance analysis indicates that the 900–630 Ma detritus in Cryogenian to Ediacaran samples was derived from the Late Neoproterozoic igneous rocks in South China that acted as an internal source. The occurrence of 620–560 Ma detritus indicates the SE Yangtze was associated with Late Neoproterozoic arc volcanism along the north margin of East Gondwana. The change of provenance resulted in the deposition of 550–520 Ma and 1.1–0.9 Ga detrital zircons in the Cambrian–Ordovician sedimentary rocks. The εHf(t) values of these detrital zircons are similar to those of zircons from NW Australia–Antarctica and South India. This change of provenance in the Cambrian can be attributed to the intracontinental subduction between South China and South Qiangtang, and the convergence of India and Australia when East Gondwana finally amalgamated.
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Adams, C. J., J. D. Bradshaw, and T. R. Ireland. "Provenance connections between late Neoproterozoic and early Palaeozoic sedimentary basins of the Ross Sea region, Antarctica, south-east Australia and southern Zealandia." Antarctic Science 26, no. 2 (July 18, 2013): 173–82. http://dx.doi.org/10.1017/s0954102013000461.
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AbstractThick successions of turbidites are widespread in the Ross–Delamerian and Lachlan orogens and are now dispersed through Australia, Antarctica and New Zealand. U-Pb detrital zircon age patterns for latest Precambrian, Cambrian and Ordovician metagreywackes show a closely related provenance. The latest Neoproterozoic–early Palaeozoic sedimentary rocks have major components, at c. 525, 550, and 595 Ma, i.e. about 40–80 million years older than deposition. Zircons in these components increase from the Neoproterozoic to Ordovician. Late Mesoproterozoic age components, 1030 and 1070 Ma, probably originate from igneous/metamorphic rocks in the Gondwanaland hinterland whose exact locations are unknown. Although small, the youngest zircon age components are coincident with estimated depositional ages suggesting that they reflect contemporaneous and minor, volcanic sources. Overall, the detrital zircon provenance patterns reflect the development of plutonic/metamorphic complexes of the Ross–Delamerian Orogen in the Transantarctic Mountains and southern Australia that, upon exhumation, supplied sediment to regional scale basin(s) at the Gondwana margin. Tasmanian detrital zircon age patterns differ from those seen in intra-Ross Orogen sandstones of northern Victoria Land and from the oldest metasediments in the Transantarctic Mountains. A comparison with rocks from the latter supports an allochthonous western Tasmania model and amalgamation with Australia in late Cambrian time.
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Gatehouse, Robyn D., I. S. Williams, and B. J. Pillans. "Fingerprinting windblown dust in south-eastern Australian soils by uranium-lead dating of detrital zircon." Soil Research 39, no. 1 (2001): 7. http://dx.doi.org/10.1071/sr99078.
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The U-Pb ages of fine-grained zircon separated from 2 dust-dominated soils in the eastern highlands of south-eastern Australia and measured by ion microprobe (SHRIMP) revealed a characteristic age ‘fingerprint’ from which the source of the dust has been determined and by which it will be possible to assess the contribution of dust to other soil profiles. The 2 soils are dominated by zircon 400–600 and 1000–1200 Ma old, derived from Palaeozoic granites and sediments of the Lachlan Fold Belt, but also contain significant components 100–300 Ma old, characteristic of igneous rocks in the New England Fold Belt in northern New South Wales and Queensland. This pattern closely matches that of sediments of the Murray-Darling Basin, especially the Mallee dunefield, suggesting that weathering of rocks in the eastern highlands has contributed large quantities of sediment to the arid and semi-arid inland basins via internally draining rivers of the present and past Murray–Darling River systems, where it has formed a major source of dust subsequently blown eastwards and deposited in the highland soils of eastern Australia.
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Creaser, Robert A., and Chris M. Gray. "Preserved initial in apatite from altered felsic igneous rocks: A case study from the Middle Proterozoic of South Australia." Geochimica et Cosmochimica Acta 56, no. 7 (July 1992): 2789–95. http://dx.doi.org/10.1016/0016-7037(92)90359-q.
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de Caritat, Patrice, Anthony Dosseto, and Florian Dux. "A strontium isoscape of inland southeastern Australia." Earth System Science Data 14, no. 9 (September 22, 2022): 4271–86. http://dx.doi.org/10.5194/essd-14-4271-2022.
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Abstract. The values and distribution patterns of the strontium (Sr) isotope ratio 87Sr/86Sr in Earth surface materials are of use in the geological, environmental, and social sciences. Ultimately, the 87Sr/86Sr ratios of soils and everything that lives in and on them are inherited from the rocks that are the parent materials of the soil's components. In Australia, there are few large-scale surveys of 87Sr/86Sr available, and here we report on a new, low-density dataset using 112 catchment outlet (floodplain) sediment samples covering 529 000 km2 of inland southeastern Australia (South Australia, New South Wales, Victoria). The coarse (<2 mm) fraction of bottom sediment samples (depth ∼ 0.6–0.8 m) from the National Geochemical Survey of Australia were milled and fully digested before Sr separation by chromatography and 87Sr/86Sr determination by multicollector-inductively coupled plasma mass spectrometry. The results show a wide range of 87Sr/86Sr values from a minimum of 0.7089 to a maximum of 0.7511 (range 0.0422). The median 87Sr/86Sr (± median absolute deviation) is 0.7199 (± 0.0071), and the mean (± standard deviation) is 0.7220 (± 0.0106). The spatial patterns of the Sr isoscape observed are described and attributed to various geological sources and processes. Of note are the elevated (radiogenic) values (≥∼ 0.7270; top quartile) contributed by (1) the Palaeozoic sedimentary country rock and (mostly felsic) igneous intrusions of the Lachlan geological region to the east of the study area; (2) the Palaeoproterozoic metamorphic rocks of the central Broken Hill region; both these sources contribute radiogenic material mainly by fluvial processes; and (3) the Proterozoic to Palaeozoic rocks of the Kanmantoo, Adelaide, Gawler, and Painter geological regions to the west of the area; these sources contribute radiogenic material mainly by aeolian processes. Regions of low 87Sr/86Sr (≤∼ 0.7130; bottom quartile) belong mainly to (1) a few central Murray Basin catchments; (2) some Darling Basin catchments in the northeast; and (3) a few Eromanga geological region-influenced catchments in the northwest of the study area; these sources contribute unradiogenic material mainly by fluvial processes. The new spatial Sr isotope dataset for the DCD (Darling–Curnamona–Delamerian) region is publicly available (de Caritat et al., 2022; https://dx.doi.org/10.26186/146397).
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Smith, I. E. M., A. J. R. White, B. W. Chappell, and R. A. Eggleton. "Fractionation in a zoned monzonite pluton: Mount Dromedary, southeastern Australia." Geological Magazine 125, no. 3 (May 1988): 273–84. http://dx.doi.org/10.1017/s0016756800010219.
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AbstractMount Dromedary pluton is one of several predominantly monzonite plutons and smaller intrusive bodies which constitute the Dromedary igneous complex in southeastern New South Wales. The pluton exhibits a striking arrangement of petrographically, but not always chemically, distinct zones ranging from mafic monzonite at the outside to quartz monzonite in the centre. The rocks display a mineralogical and geochemical integrity which indicates a consanguineous relationship. Minor compositional discontinuities between zones, together with observed and inferred minor intrusive zone boundaries, suggest that each zone has to some extent evolved independently. Negative Eu anomalies in REE abundance patterns show that some of the zones have been affected by fractionation of feldspar, but complementary accumulates are not found at the present levels of exposure. The pattern of zoning can be explained by a process of shallow fractional crystallization in which variations within zones are the result of lateral accretion of alkali feldspar as well as settling and/or lateral accretion of mafic phases at lower levels in the intrusion and upward displacement of fractionated magma. The parental magma of the pluton probaby originated by partial melting of an alkali basalt composition with an amphibolite mineralogy at the base of the crust.
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Borissova, Irina, Chris Southby, George Bernardel, Jennifer Totterdell, Robbie Morris, and Ryan Owens. "Northern Houtman Sub-basin prospectivity—preliminary results." APPEA Journal 56, no. 2 (2016): 577. http://dx.doi.org/10.1071/aj15083.
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In 2014–15 Geoscience Australia acquired 3,300 km of deep 2D seismic data over the northern part of the Houtman Sub-basin (Perth Basin). Prior to this survey, this area had a very sparse coverage of 2D seismic data with 50–70 km line spacing in the north and an industry grid with 20 km line spacing in the south. Initial interpretation of the available data has shown that the structural style, major sequences, and potential source rocks in this area are similar to those in the southern Houtman and Abrolhos sub-basins. The major difference between these depocentres, however, is in the volume and distribution of volcanic and intrusive igneous rocks. The northern part of the Houtman Sub-basin is adjacent to the Wallaby Plateau Large Igneous Province (LIP). The Wallaby Plateau and the Wallaby Saddle, which borders the western flank of the Houtman Sub-basin, had active volcanism from the Valanginian to at least the end of the Barremian. Volcanic successions significantly reduce the quality of seismic imaging at depth, making it difficult to ascertain the underlying thickness, geometry and structure of the sedimentary basin. The new 2D seismic dataset across the northern Houtman Sub-basin provides an opportunity for improved mapping of the structure and stratigraphy of the pre-breakup succession, assessment of petroleum prospectivity, and examination of the role of volcanism in the thermal history of this frontier basin.
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Turner, Simon P., and Kurt Stüwe. "Low-pressure corona textures between olivine and plagioclase in unmetamorphosed gabbros from Black Hill, South Australia." Mineralogical Magazine 56, no. 385 (December 1992): 503–9. http://dx.doi.org/10.1180/minmag.1992.056.385.06.
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AbstractOlivine-plagioclase corona textures occur in ophitic to sub-ophitic olivine gabbros at Black Hill, South Australia. Contrasting with many corona and symplectite textures previously described, these do not involve spinel or garnet as reaction products and did not form under high-pressure conditions. Rather, the coronas formed at no more than 1 kbar pressure and are composed of a shell of orthopyroxene around the olivine often succeeded by a shell of amphibole or occasionally biotite. Beyond this, a vermicular symplectite of anorthite containing orthopyroxene and rarer amphibole vermicules extends out to host plagioclase of labradorite composition. Textural relations are used to infer a subsolidus igneous origin for all but the orthopyroxene shell which may have formed in the presence of some magma. Compositional zonation is absent from all the constituent phases except the amphibole shell which is strongly zoned in Mg# and may have a late origin. An average maximum corona width of 150- 200 μm indicates a limiting distance for subsolidus chemical diffusion. The corona products involve the reactants olivine and plagioclase in the proportions 1:3 and symplectite formation may have been promoted by a Na potential gradient. The system must also have been open to minor components including H2O and TiO2, with H2O possibly being derived from a hydrothermal system. Such systems may have been set up in the country rocks on intrusion of the magma and subsequently collapsed inwards into the pluton during sub-solidus cooling.
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Cuney, Michel. "Felsic magmatism and uranium deposits." Bulletin de la Société Géologique de France 185, no. 2 (February 1, 2014): 75–92. http://dx.doi.org/10.2113/gssgfbull.185.2.75.
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Abstract The strongly incompatible behaviour of uranium in silicate magmas results in its concentration in the most felsic melts and a prevalence of granites and rhyolites as primary U sources for the formation of U deposits. Despite its incompatible behavior, U deposits resulting directly from magmatic processes are quite rare. In most deposits, U is mobilized by hydrothermal fluids or ground water well after the emplacement of the igneous rocks. Of the broad range of granite types, only a few have U contents and physico-chemical properties that permit the crystallization of accessory minerals from which uranium can be leached for the formation of U deposits. The first granites on Earth, which crystallized uraninite, dated at 3.1 Ga, are the potassic granites from the Kaapval craton (South Africa) which were also the source of the detrital uraninite for the Dominion Reef and Witwatersrand quartz pebble conglomerate deposits. Four types of granites or rhyolites can be sufficiently enriched in U to represent a significant source for the genesis of U deposits: peralkaline, high-K metaluminous calc-alkaline, L-type peraluminous and anatectic pegmatoids. L-type peraluminous plutonic rocks in which U is dominantly hosted in uraninite or in the glass of their volcanic equivalents represent the best U source. Peralkaline granites or syenites are associated with the only magmatic U-deposits formed by extreme fractional crystallization. The refractory character of the U-bearing minerals does not permit their extraction under the present economic conditions and make them unfavorable U sources for other deposit types. By contrast, felsic peralkaline volcanic rocks, in which U is dominantly hosted in the glassy matrix, represent an excellent source for many deposit types. High-K calc-alkaline plutonic rocks only represent a significant U source when the U-bearing accessory minerals (U-thorite, allanite, Nb oxides) become metamict. The volcanic rocks of the same geochemistry may be also a favorable uranium source if a large part of the U is hosted in the glassy matrix. The largest U deposit in the world, Olympic Dam in South Australia is hosted by highly fractionated high-K plutonic and volcanic rocks, but the origin of the U mineralization is still unclear. Anatectic pegmatoids containing disseminated uraninite which results from the partial melting of uranium-rich metasediments and/or metavolcanic felsic rocks, host large low grade U deposits such as the Rössing and Husab deposits in Namibia. The evaluation of the potentiality for igneous rocks to represent an efficient U source represents a critical step to consider during the early stages of exploration for most U deposit types. In particular a wider use of the magmatic inclusions to determine the parent magma chemistry and its U content is of utmost interest to evaluate the U source potential of sedimentary basins that contain felsic volcanic acidic tuffs.
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Alavi, Norman, Leon Bagas, Peter Purcell, Irena Kivior, and John Brett. "Lower Paleozoic stratigraphy and petroleum potential of the Wallal Rift System, southwest Canning Basin, Western Australia." APPEA Journal 54, no. 2 (2014): 521. http://dx.doi.org/10.1071/aj13094.
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The Wallal Rift System (new name) extends north-northwest for more than 300 km along the southwestern margin of the Canning Basin. The rift contains the Wallal and the Waukarlycarly embayments and the Samphire Graben. The rift segments vary in depth to 4.5 km and are all under-explored. Seismic coverage is better in the north than in the south. Six shallow wildcat and stratigraphic wells in the north provide some control on the age of the pre-Permian section. Another well on the northeastern flank of the Samphire Graben terminated in Neoproterozoic granitic rocks beneath the Lower Ordovician Nambeet Formation. The well is tied to a seismic line that indicates a synrift Ordovician section in the graben. An equivalent section is inferred in the Wallal and the Waukarlycarly embayments, and Permian syn-rift sediments are recognised in all rifts. Transtension along a regional geosuture—the Camel-Tabletop Fault Zone—may have caused initial rifting during the waning of the Paterson Orogeny (c. 550 Ma), co-incident with extrusion in the Kalkarindji Large Igneous Province. Thus, Cambrian volcano-clastics deposits may be present at the base of the (2–3 km thick) pre-Permian section, which is considered to be primarily Early Paleozoic sediments and expected to contain potential source rocks. A relatively hot Proterozoic crust and eruption of continental flood basalts during the Cambrian may have facilitated source rock maturation. Reservoirs may be more common along rift-margins and intra-rift ridges, where fault-controlled traps are also present.
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McPhie, J. "Evolution of a non-resurgent cauldron: the Late Permian Coombadjha Volcanic Complex, northeastern New South Wales, Australia." Geological Magazine 123, no. 3 (May 1986): 257–77. http://dx.doi.org/10.1017/s0016756800034749.
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AbstractThe Coombadjha Volcanic Complex is the remnant of a Late Permian cauldron. It is part of an extensive sequence of silicic calc-alkaline volcanics that covers the southeastern portion of the New England Orogen in NSW. The Complex is elliptical, measuring 15 × 24 km, and is outlined by a ring pluton and an arcuate fault. Bedding in the volcanic units of the Complex defines a structural basin, with steep inward dips at the monoclinal rim and gentle to horizontal orientations near the centre. An older group of outflow ignimbrites, lavas, breccias and volcaniclastic rocks at least 1500 m thick, is conformably overlain by more than 500 m of texturally homogeneous, crystal-rich, dacitic ignimbrite. Ignimbrites of the older group are the products of several discrete eruptions from separate vents, all of which were situated outside the Coombadjha area. Silicic lava domes with volcaniclastic aprons, and a tuff ring, mark the positions of local vents active on a small scale during intervals between the emplacement of the outflow ignimbrites. No significant subsidence occurred, nor did a caldera exist at this stage. Cauldron subsidence occurred in response to the large magnitude eruption that produced the crystal-rich ignimbrite. The central cauldron block was lowered at least 2000 m by downwarping and fault displacement, and remained largely intact. There is no evidence for resurgent doming of the cauldron after subsidence, although igneous activity continued with intrusion of an adamellite ring pluton along much of the cauldron margin. The crystal-rich ignimbrite and the ring pluton are similar in composition and may have been successive products of a common magma source that sustained this simple, single cauldron cycle.
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Randive, Kirtikumar, and Tushar Meshram. "An Overview of the Carbonatites from the Indian Subcontinent." Open Geosciences 12, no. 1 (March 26, 2020): 85–116. http://dx.doi.org/10.1515/geo-2020-0007.
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AbstractCarbonatites are carbonate-rich rocks of igneous origin. They form the magmas of their own that are generated in the deep mantle by low degrees of partial melting of carbonated peridotite or eclogite source rocks. They are known to occur since the Archaean times till recent, the activity showing gradual increase from older to younger times. They are commonly associated with alkaline rocks and be genetically related with them. They often induce metasomatic alteration in the country rocks forming an aureole of fenitization around them. They are host for economically important mineral deposits including rare metals and REE. They are commonly associated with the continental rifts, but are also common in the orogenic belts; but not known to occur in the intra-plate regions. The carbonatites are known to occur all over the globe, majority of the occurrences located in Africa, Fenno-Scandinavia, Karelian-Kola, Mongolia, China, Australia, South America and India. In the Indian Subcontinent carbonatites occur in India, Pakistan, Afghanistan and Sri Lanka; but so far not known to occur in Nepal, Bhutan, Bangladesh and Myanmar. This paper takes an overview of the carbonatite occurrences in the Indian Subcontinent in the light of recent data. The localities being discussed in detail cover a considerable time range (>2400 Ma to <0.6 Ma) from India (Hogenakal, Newania, Sevathur, Sung Valley, Sarnu-Dandali and Mundwara, and Amba Dongar), Pakistan (Permian Koga and Tertiary Pehsawar Plain Alkaline Complex which includes Loe Shilman, Sillai Patti, Jambil and Jawar), Afghanistan (Khanneshin) and Sri Lanka (Eppawala). This review provide the comprehensive information about geochemical characteristics and evolution of carbonatites in Indian Subcontinent with respect to space and time.
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Wang, Wei, Peter A. Cawood, Christopher J. Spencer, Manoj K. Pandit, Jun-Hong Zhao, Xiao-Ping Xia, Jian-Ping Zheng, and Gui-Mei Lu. "Global-scale emergence of continental crust during the Mesoarchean–early Neoarchean." Geology 50, no. 2 (November 9, 2021): 184–88. http://dx.doi.org/10.1130/g49418.1.
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Abstract The timing of the emergence of subaerial landmasses is equivocally constrained as post-Archean and continues to be a much-debated issue. In this study, we document exceptionally 18O-depleted (δ18O < 4.7‰) Mesoarchean to early Neoarchean magmatism in India that shows a similarity with the coeval low-δ18O magmas reported from Australia, South America, and northern China. Such global-scale low-δ18O magmatism would require high-temperature meteoric water–rock interaction in the uppermost crust synchronous with magma generation, necessitating the emergence of a substantial volume of the continental crust. The timing of this low-δ18O magmatism coincides with the development of extensive, subaerial large igneous provinces, a downward shift in δ18O and Δ17O values in pelitic rocks, the rise of normalized 87Sr/86Sr in seawater, and an intermittent upsurge in the proportion of atmospheric oxygen. We propose that the emergence of substantial volumes of continental crust initiated at ca. 3.2 Ga and peaked at 2.8–2.6 Ga, facilitating the generation of globally distributed low-δ18O magmas, and this event can be linked to the first appearance of atmospheric oxygen.
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Ashley, P. M., N. D. J. Cook, and C. M. Fanning. "Geochemistry and age of metamorphosed felsic igneous rocks with A-type affinities in the Willyama Supergroup, Olary Block, South Australia, and implications for mineral exploration." Lithos 38, no. 3-4 (September 1996): 167–84. http://dx.doi.org/10.1016/0024-4937(96)00011-4.
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Turner, Simon, Janne Blichert-Toft, Bruce Schaefer, Francis Albarède, and John Foden. "A reappraisal of the evolution of the palaeo-Pacific margin of Gondwana from the Pb and Os isotope systematics of igneous rocks from the southern Adelaide fold belt, South Australia." Gondwana Research 45 (May 2017): 152–62. http://dx.doi.org/10.1016/j.gr.2017.01.006.
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Moreno, Teresa, Fulvio Amato, Xavier Querol, Andrés Alastuey, and Wes Gibbons. "Trace element fractionation processes in resuspended mineral aerosols extracted from Australian continental surface materials." Soil Research 46, no. 2 (2008): 128. http://dx.doi.org/10.1071/sr07121.
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Unconsolidated surface soil and dust samples of varying trace element (TE) content were collected from remote locations in central and south-eastern Australia. The finer grained fraction of the samples (<10 µm, PM10) was separated and geochemically compared to the parent particulate matter (PMPAR). TE are mostly hosted in phosphates and oxides/hydroxides or adsorbed to clay minerals, and are normally fractionated into the PM10, producing PM10/PMPAR ratios >1, especially in siliceous, TE-depleted dusts. In contrast, samples TE-enriched by primary silicate minerals eroded from igneous and metamorphic rocks can produce PM10/PMPAR <1 for more mobile elements such as K, Na, Ba, Rb, and Sr. K/Rb is normally lower in PM10 (unless the PMPAR is muscovite-rich) as is the light/heavy rare earth elements (LREE/HREE) ratio because both Rb and HREE are preferentially adsorbed by fine clay particles. Zr and Hf are mostly hosted by zircon crystals initially >10 µm but these diminish in size with time and sedimentological transport so that PM10 aerosol concentrations of these elements are typically telescoped into a narrower range than the PMPAR. Nb is strongly fractionated into PM10, with Nb/TiO2 ratios characteristic of the durable host mineral rutile in all but the most TE-enriched PM. TE content of PM10 in continental dusts is controlled by both physical and chemical processes. Fresh primary silicates suppress PM10/PMPAR ratios of TE with low ionic potential, whereas the opposite effect is induced by hydraulic sorting and/or physical attrition during surface transport, as well as clay absorbtion and fixation of TE in small, resistant accessory minerals.
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Franz, Gerhard, Oleksii Vyshnevskyi, Michail Taran, Vladimir Khomenko, Michael Wiedenbeck, Ferry Schiperski, and Jörg Nissen. "A new emerald occurrence from Kruta Balka, Western Peri-Azovian region, Ukraine: Implications for understanding the crystal chemistry of emerald." American Mineralogist 105, no. 2 (February 1, 2020): 162–81. http://dx.doi.org/10.2138/am-2020-7010.
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Abstract We investigated emerald, the bright-green gem variety of beryl, from a new locality at Kruta Balka, Ukraine, and compare its chemical characteristics with those of emeralds from selected occurrences worldwide (Austria, Australia, Colombia, South Africa, Russia) to clarify the types and amounts of substitutions as well as the factors controlling such substitutions. For selected crystals, Be and Li were determined by secondary ion mass spectrometry, which showed that the generally assumed value of 3 Be atoms per formula unit (apfu) is valid; only some samples such as the emerald from Kruta Balka deviate from this value (2.944 Be apfu). An important substitution in emerald (expressed as an exchange vector with the additive component Al2Be3Si6O18) is (Mg,Fe2+)NaAl–1☐–1, leading to a hypothetical end-member NaAl(Mg,Fe2+)[Be3Si6O18] called femag-beryl with Na occupying a vacancy position (☐) in the structural channels of beryl. Based on both our results and data from the literature, emeralds worldwide can be characterized based on the amount of femag-substitution. Other minor substitutions in Li-bearing emerald include the exchange vectors LiNa2Al–1☐–2 and LiNaBe–1☐–1, where the former is unique to the Kruta Balka emeralds. Rarely, some Li can also be situated at a channel site, based on stoichiometric considerations. Both Cr- and V-distribution can be very heterogeneous in individual crystals, as shown in the samples from Kruta Balka, Madagascar, and Zimbabwe. Nevertheless, taking average values available for emerald occurrences, the Cr/(Cr+V) ratio (Cr#) in combination with the Mg/(Mg+Fe) ratio (Mg#) and the amount of femag-substitution allows emerald occurrences to be characterized. The “ultramafic” schist-type emeralds with high Cr# and Mg# come from occur-rences where the Fe-Mg-Cr-V component is controlled by the presence of ultramafic meta-igneous rocks. Emeralds with highly variable Mg# come from “sedimentary” localities, where the Fe-Mg-Cr-V component is controlled by metamorphosed sediments such as black shales and carbonates. A “transitional” group has both metasediments and ultramafic rocks as country rocks. Most “ultramafic” schist type occurrences are characterized by a high amount of femag-component, whereas those from the “sedimentary” and “transitional” groups have low femag contents. Growth conditions derived from the zoning pattern—combined replacement, sector, and oscillatory zoning—in the Kruta Balka emeralds indicate disequilibrium growth from a fluid along with late-stage Na-infiltration. Inclusions in Kruta Balka emeralds (zircon with up to 11 wt% Hf, tourmaline, albite, Sc-bearing apatite) point to a pegmatitic origin.
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"Laterite weathering profiles of Precambrian igneous rocks at the Worsley Alumina Refinery site, South West Division, Western Australia." International Journal of Rock Mechanics and Mining Sciences & Geomechanics Abstracts 22, no. 6 (December 1985): 172. http://dx.doi.org/10.1016/0148-9062(85)90048-8.
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Hammerli, Johannes, Carl Spandler, and Nicholas H. S. Oliver. "Element redistribution and mobility during upper crustal metamorphism of metasedimentary rocks: an example from the eastern Mount Lofty Ranges, South Australia." Contributions to Mineralogy and Petrology 171, no. 4 (March 30, 2016). http://dx.doi.org/10.1007/s00410-016-1239-7.
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Breitfeld, H. Tim, Lorin Davies, Robert Hall, Richard Armstrong, Marnie Forster, Gordon Lister, Matthew Thirlwall, Nathalie Grassineau, Juliane Hennig-Breitfeld, and Marco W. A. van Hattum. "Mesozoic Paleo-Pacific Subduction Beneath SW Borneo: U-Pb Geochronology of the Schwaner Granitoids and the Pinoh Metamorphic Group." Frontiers in Earth Science 8 (December 11, 2020). http://dx.doi.org/10.3389/feart.2020.568715.
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The Schwaner Mountains in southwestern Borneo form a large igneous province with a complex magmatic history and poorly known tectonic history. Previously it was known that Cretaceous granitoids intruded metamorphic rocks of the Pinoh Metamorphic Group assumed to be of Paleozoic age. Jurassic granitoids had been reported from the southern Schwaner Mountains. Most ages were based on K-Ar dating. We present new geochemistry, zircon U-Pb and 40Ar/39Ar age data from igneous and metamorphic rocks from the Schwaner Mountains to investigate their tectono-magmatic histories. We subdivide the Schwaner Mountains into three different zones which record rifting, subduction-related and post-collisional magmatism. The Northwest Schwaner Zone (NWSZ) is part of the West Borneo Block which in the Triassic was within the Sundaland margin. It records Triassic to Jurassic magmatism during early Paleo-Pacific subduction. In contrast, the North Schwaner Zone (NSZ) and South Schwaner Zone (SSZ) are part of the SW Borneo (Banda) Block that separated from NW Australia in the Jurassic. Jurassic granitoids in the SSZ are within-plate (A-type) granites interpreted to have formed during rifting. The SW Borneo (Banda) Block collided with eastern Sundaland at c. 135 Ma. Following this, large I-type granitoid plutons and arc volcanics formed in the NWSZ and NSZ between c. 90 and 132 Ma, associated with Cretaceous Paleo-Pacific subduction. The largest intrusion is the c. 110 to 120 Ma Sepauk Tonalite. After collision of the East Java-West Sulawesi (Argo) Block, subduction ceased and post-collisional magmatism produced the c. 78 to 85 Ma Sukadana Granite and the A-type 72 Ma Sangiyang Granite in the SSZ. Rocks of the Pinoh Metamorphic Group mainly exposed in the NSZ, previously assumed to represent Paleozoic basement, contain abundant Early Cretaceous (110 to 135 Ma) zircons. They are interpreted as volcaniclastic sediments that formed contemporaneously with subduction-related volcanic rocks of the NSZ subsequently metamorphosed during intrusion of Cretaceous granitoids. There are no igneous rocks older than Cretaceous in the NSZ and older than Jurassic in the SSZ and there is no evidence for a continuation of a Triassic volcanic arc crossing Borneo from Sundaland to the east.
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Lu, Yongjun, Michael T. D. Wingate, Robert H. Smithies, Klaus Gessner, Simon P. Johnson, Anthony I. S. Kemp, David E. Kelsey, et al. "Preserved intercratonic lithosphere reveals Proterozoic assembly of Australia." Geology, August 2, 2022. http://dx.doi.org/10.1130/g50256.1.
Full textAbstract:
The Proterozoic assembly of Australia, the understanding of which is critical for reconstructing Proterozoic supercontinents, involved amalgamation of the West Australian (WAC), North Australian (NAC), and South Australian cratons (SAC). However, the basement between these Archean to early Proterozoic lithospheric blocks is mostly buried beneath younger basins; hence, its composition and age and the timing of Proterozoic assembly remain uncertain. In situ zircon U-Pb-O-Hf analyses of igneous rocks from drillholes that intersected basement beneath the northwestern Canning Basin reveal the presence of a substantial domain of juvenile Proterozoic lithosphere, the Percival Lakes province, between the WAC and NAC. Although isotopically distinct from the neighboring WAC and NAC, the Percival Lakes province is strikingly similar to other juvenile Proterozoic tectonic elements between the WAC, NAC, and SAC. Combining isotope and seismic data, we interpret the Percival Lakes province as part of an ~1700 × 400 km Proterozoic lithospheric domain that lacks evidence of Archean provenance but consists mainly of reworked remnants of Mesoproterozoic oceanic crust that survived WAC-NAC-SAC convergence. The apparent absence of Archean lithosphere between the cratons implies they never directly collided or that complete collision was prevented by impingement of three-dimensional promontories in the converging lithospheric blocks. Instead, the Percival Lakes province and other Proterozoic elements between the WAC, NAC, and SAC consist of oceanic lithosphere extracted from Earth’s mantle in the Proterozoic. Our results imply that WAC-NAC convergence was younger than Columbia amalgamation at ca. 1.8 Ga and that Proterozoic Australia formed during the earliest phases of Rodinia assembly at ca. 1.3 Ga.
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Anenburg, Michael, John A. Mavrogenes, and Vickie C. Bennett. "The Fluorapatite P–REE–Th Vein Deposit at Nolans Bore: Genesis by Carbonatite Metasomatism." Journal of Petrology 61, no. 1 (January 2020). http://dx.doi.org/10.1093/petrology/egaa003.
Full textAbstract:
Abstract Nolans Bore is a rare earth element (REE) ore deposit in the Reynolds Range, Aileron Province, Northern Territory, Australia. It consists primarily of fluorapatite and alteration products thereof, surrounded by a diopside-dominated selvage. Previously considered to form via hydrothermal fluids, we now suggest that the deposit formed by a metasomatic reaction between a mantle-derived carbonatite and granulite-facies felsic host rocks, after peak metamorphism. REE patterns of fluorapatite are strongly light REE (LREE) enriched, convex with maxima at Ce to Nd, and contain a weak negative Eu anomaly. Textural and geochemical properties of the fluorapatite are consistent with its formation from a carbonatite liquid. Sinusoidal REE patterns in diopside along with strong Yb–Lu enrichment relative to coexisting titanite are suggestive of derivation from a Ca-rich carbonatite. Likewise, hyalophane present in the selvages forms by reaction of a BaCO3 component in the carbonatite with K-feldspar in the silicate host rocks. The overall morphology of Nolans Bore is consistent with carbonatite–silicate reaction experiments, with the carbonatite itself migrating elsewhere owing to the open-system nature of Nolans Bore. Ekanite veins in massive fluorapatite zones and allanite–epidote crusts on fluorapatite in contact with the diopside selvages formed by hydrothermal fluids exsolved from the carbonatite. Minor interstitial calcite was not igneous but was the last mineral to crystallize from the carbonatite-exsolved fluid. Y/Ho ratios qualitatively trace the transition from mantle-dominated igneous minerals to later low-temperature hydrothermal minerals. Rb–Sr and Sm–Nd analyses of unaltered minerals (fluorapatite, allanite, calcite) show that the carbonatite had homogeneous initial 87Sr/86Sr ≈ 0·7054 and εNd ≈ –4 at 1525 Ma, the best age estimate of the mineralization. Fluorapatite–allanite Sm–Nd dating results in an age of 1446 ± 140 Ma, consistent with forming soon after the end of the Chewings Orogeny. Neodymium depleted mantle model ages are older than 2 Ga, indicating the presence of recycled crustal material within the source. We suggest that the carbonatite was sourced from a mantle enriched by subduction of LREE-rich oceanic crustal rocks, marine sediments, and phosphorites, potentially from the south, or the Mount Isa area to the east. Nolans Bore represents the root zone of a now-eroded carbonatite. Other Nolans-type deposits (Hoidas Lake, Canada and Kasipatnam, India) are similarly hosted within siliceous granulite-facies rocks in regions with a long tectonic history, suggesting common processes that led to the formation of all three deposits. The REE-rich compositions of the mid-crustal Nolans Bore fluorapatite are the cumulates hypothesized to cause REE depletion in some unmineralized carbonatites. The rocks at Nolans Bore demonstrate that carbonatites, previously thought to be mostly unreactive, can undergo modification and modify the composition of the silicate rocks which they encounter, forming an ‘antiskarn’. At igneous temperatures, the resulting mineral assemblage (other than fluorapatite) consists of diopside and titanite, both of which are common in granulite-facies rocks. Therefore, carbonatite metasomatism can remain unnoticed if the resulting assemblage does not contain distinctively carbonatitic minerals.
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Brown, Dillon A., Laura J. Morrissey, John W. Goodge, and Martin Hand. "Absence of evidence for Palaeoproterozoic eclogite-facies metamorphism in East Antarctica: no record of subduction orogenesis during Nuna development." Scientific Reports 11, no. 1 (March 24, 2021). http://dx.doi.org/10.1038/s41598-021-86184-4.
Full textAbstract:
AbstractThe cratonic elements of proto-Australia, East Antarctica, and Laurentia constitute the nucleus of the Palaeo-Mesoproterozoic supercontinent Nuna, with the eastern margin of the Mawson Continent (South Australia and East Antarctica) positioned adjacent to the western margin of Laurentia. Such reconstructions of Nuna fundamentally rely on palaeomagnetic and geological evidence. In the geological record, eclogite-facies rocks are irrefutable indicators of subduction and collisional orogenesis, yet occurrences of eclogites in the ancient Earth (> 1.5 Ga) are rare. Models for Palaeoproterozoic amalgamation between Australia, East Antarctica, and Laurentia are based in part on an interpretation that eclogite-facies metamorphism and, therefore, collisional orogenesis, occurred in the Nimrod Complex of the central Transantarctic Mountains at c. 1.7 Ga. However, new zircon petrochronological data from relict eclogite preserved in the Nimrod Complex indicate that high-pressure metamorphism did not occur in the Palaeoproterozoic, but instead occurred during early Palaeozoic Ross orogenesis along the active convergent margin of East Gondwana. Relict c. 1.7 Ga zircons from the eclogites have trace-element characteristics reflecting the original igneous precursor, thereby casting doubt on evidence for a Palaeoproterozoic convergent plate boundary along the current eastern margin of the Mawson Continent. Therefore, rather than a Palaeoproterozoic (c. 1.7 Ga) history involving subduction-related continental collision, a pattern of crustal shortening, magmatism, and high thermal gradient metamorphism connected cratons in Australia, East Antarctica, and western Laurentia at that time, leading eventually to amalgamation of Nuna at c. 1.6 Ga.
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Holford, Simon P., Paul F. Green, Ian R. Duddy, Richard R. Hillis, Steven M. Hill, and Martyn S. Stoker. "Preservation of late Paleozoic glacial rock surfaces by burial prior to Cenozoic exhumation, Fleurieu Peninsula, Southeastern Australia." Journal of the Geological Society, June 21, 2021, jgs2020–250. http://dx.doi.org/10.1144/jgs2020-250.
Full textAbstract:
The antiquity of the Australian landscape has long been the subject of debate, with some studies inferring extraordinary longevity (>108 myr) for some subaerial landforms dating back to the early Paleozoic. A number of early Permian glacial erosion surfaces in the Fleurieu Peninsula, southeastern Australia, provide an opportunity to test the notion of long-term subaerial emergence, and thus tectonic and geomorphic stability, of parts of the Australian continent. Here we present results of apatite fission track analysis (AFTA) applied to a suite of samples collected from localities where glacial erosion features of early Permian age are developed. Our synthesis of AFTA results with geological data reveals four cooling episodes (C1-4), which are interpreted to represent distinct stages of exhumation. These episodes occurred during the Ediacaran to Ordovician (C1), mid-Carboniferous (C2), Permian to mid-Triassic (C3) and Eocene to Oligocene (C4).The interpretation of AFTA results indicates that the Neoproterozoic−Lower Paleozoic metasedimentary rocks and granitic intrusions upon which the glacial rock surfaces generally occur were exhumed to the surface by the latest Carboniferous−earliest Permian during episodes C2 and/or C3, possibly as a far-field response to the intraplate Alice Springs Orogeny. The resulting landscapes were sculpted by glacial erosive processes. Our interpretation of AFTA results suggests that the erosion surfaces and overlying Permian sedimentary rocks were subsequently heated to between c. 60 and 80°C, which we interpret as recording burial by a sedimentary cover comprising Permian and younger strata, roughly 1 km in thickness. This interpretation is consistent with existing thermochronological datasets from this region, and also with palynological and geochronological datasets from sediments in offshore Mesozoic−Cenozoic-age basins along the southern Australian margin that indicate substantial recycling of Permian−Cretaceous sediments. We propose that the exhumation which led to the contemporary exposure of the glacial erosion features began during the Eocene to Oligocene (episode C4), during the initial stages of intraplate deformation that has shaped the Mt Lofty and Flinders Ranges in South Australia. Our findings are consistent with several recent studies, which suggest that burial and exhumation have played a key role in the preservation and contemporary re-exposure of Gondwanan geomorphic features in the Australian landscape.