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Luong, Khang Quang, Hung The Khuong, Dung Tien Vo, and Tuyen Danh Nguyen. "Mineralogical and geological characteristics of the Nui Phao tungsten deposit and its resource in the Dai Tu area, northeastern Vietnam." Journal of Mining and Earth Sciences 63, no. 6 (December 31, 2022): 1–11. http://dx.doi.org/10.46326/jmes.2022.63(6).01.
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Typically, granitic intrusions that document the lengthy and intricate history of the magmatic-hydrothermal system are linked to tungsten deposits. Uncertainty persists about the genetic relationship between tungsten mineralization and magmatic-hydrothermal development. The primary tungsten deposit in the Dai Tu region, known as the Nui Phao deposit, has been the subject of a petrographical and microscopic examination. Tungsten mineralization in the Dai Tu area often occurs in association with the formation of skarn and greisen bodies, and it has drawn much attention from geoscientists. Based on microscopic observations, tungsten ores can be divided into three mineralization stages, namely skarnisation, greisenization, and hydrothermal stage. To examine the geochemical features of the tungsten ores, the SEM-EDS and Microscope analytical methods were performed in this study. Research results indicate that the Nui Phao tungsten deposit was formed due to different tectonic and magmatism episodes. Accordingly, the Nui Phao tungsten deposit is relatively complicated with the multi-sources of ore components. Most of the tungsten ore was accumulated in association with the metasomatism between the Ordovician-Silurian carbonate-terrigenous sedimentary rocks of the Phu Ngu formation and the Cretaceous two-mica granite of the Pia Oac complex. The research results indicate that tungsten resources obtained at levels 122 and 333 are about 227.6 thousand tons. Moreover, the hydrothermal alteration and metasomatism in the study area are influenced by at least three metasomatic episodes, including skarnisation, greisenisation, and the late hydrothermal alteration of medium to a low temperature that is genetically related to fluorite-polymetallic mineralization.
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Paoli, Dini, Petrelli, and Rocchi. "HFSE‐REE Transfer Mechanisms During Metasomatism of a Late Miocene Peraluminous Granite Intruding a Carbonate Host (Campiglia Marittima, Tuscany)." Minerals 9, no. 11 (November 4, 2019): 682. http://dx.doi.org/10.3390/min9110682.
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The different generations of calc‐silicate assemblages formed during sequential metasomatic events make the Campiglia Marittima magmatic–hydrothermal system a prominent case study to investigate the mobility of rare earth element (REE) and other trace elements. These mineralogical assemblages also provide information about the nature and source of metasomatizing fluids. Petrographic and geochemical investigations of granite, endoskarn, and exoskarn bodies provide evidence for the contribution of metasomatizing fluids from an external source. The granitic pluton underwent intense metasomatism during post‐magmatic fluid–rock interaction processes. The system was initially affected by a metasomatic event characterized by circulation of K‐rich and Ca(‐Mg)‐rich fluids. A potassic metasomatic event led to the complete replacement of magmatic biotite, plagioclase, and ilmenite, promoting major element mobilization and crystallization of K‐feldspar, phlogopite, chlorite, titanite, and rutile. The process resulted in significant gain of K, Rb, Ba, and Sr, accompanied by loss of Fe and Na, with metals such as Cu, Zn, Sn, W, and Tl showing significant mobility. Concurrently, the increasing fluid acidity, due to interaction with Ca‐rich fluids, resulted in a diffuse Ca‐metasomatism. During this stage, a wide variety of calc‐silicates formed (diopside, titanite, vesuvianite, garnet, and allanite), throughout the granite body, along granite joints, and at the carbonate–granite contact. In the following stage, Ca‐F‐rich fluids triggered the acidic metasomatism of accessory minerals and the mobilization of high-field-strength elements (HFSE) and REE. This stage is characterized by the exchange of major elements (Ti, Ca, Fe, Al) with HFSE and REE in the forming metasomatic minerals (i.e., titanite, vesuvianite) and the crystallization of HFSE‐REE minerals. Moreover, the observed textural disequilibrium of newly formed minerals (pseudomorphs, patchy zoning, dissolution/reprecipitation textures) suggests the evolution of metasomatizing fluids towards more acidic conditions at lower temperatures. In summary, the selective mobilization of chemical components was related to a shift in fluid composition, pH, and temperature. This study emphasizes the importance of relating field studies and petrographic observations to detailed mineral compositions, leading to the construction of litho‐geochemical models for element mobilization in crustal magmatic‐hydrothermal settings.
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Willan, R. C. R., R. J. Pankhurst, and F. Hervé. "A probable Early Triassic age for the Miers Bluff Formation, Livingston Island, South Shetland Islands." Antarctic Science 6, no. 3 (September 1994): 401–8. http://dx.doi.org/10.1017/s095410209400060x.
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Fifteen samples of very low-grade mudstones from two widely separated sections in the Miers Bluff Formation on Hurd Peninsula yield an Rb-Sr errorchron (MSWD=8.9) corresponding to an age of 243 ± 8 Ma. This age is interpreted as representing effective homogenization, on a kilometres scale, during turbidite deposition and diagenesis in early Triassic times. The initial 87Sr/86Sr ratio 0.7085 ± 0.0003 represents a mature crustal source and is consistent with the re-working of material comparable to that eroded from the Chilean fore-arc accretionary complex. Four further samples, collected near to a zone of quartz-carbonate veins, lie to the right of the errorchron, with two samples having unusually low Sr contents. These samples fall on a 113 Ma reference line and indicate metasomatic disturbance in Cretaceous times. Metasomatism was probably related to hydrothermal alteration accompanying widespread silicification and quartz veining on western Hurd Peninsula. A mid-to late Cretaceous age for metasomatic disturbance agrees with field relations which indicate that the hydrothermal activity preceded or was coeval with the mid- to late Cretaceous period of volcanism on Livingston Island. Hence the hydrothermal rocks are not related to the Eocene Barnard Point pluton, as previously suggested.
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Zanchetta, Stefano, Sofia Locchi, Gregorio Carminati, Manuel Mancuso, Chiara Montemagni, and Andrea Zanchi. "Metasomatism by Boron-Rich Fluids along Permian Low-Angle Normal Faults (Central Southern Alps, N Italy)." Minerals 12, no. 4 (March 25, 2022): 404. http://dx.doi.org/10.3390/min12040404.
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Low-Angle Normal Faults (LANFs) represent in the central Southern Alps area (N Italy) the main structures along which the Variscan basement is in contact with the Upper Carboniferous-Permian volcanic-sedimentary succession. Tourmalinites frequently occur along LANFs, usually replacing former cataclasites. The mineralogy and chemical composition of tourmalinites point to a metasomatic origin. LANFs, together with high-angle faults, controlled the opening of the Permian Orobic Basin and likely acted as a preferred pathway for hydrothermal fluids that triggered the Boron-metasomatism. Along the Aga-Vedello LANF, tourmalinites appear to have formed after the cessation of fault activity, as no brittle post-metasomatism deformation overprint has been observed. These relationships suggest that the circulation of B-rich fluids occurred after the opening of the Orobic Basin that is broadly constrained to the Early Permian. At the same time, ca. 285–270 Ma, a strong magmatic activity affected all the Southern Alps, ranging in composition from mafic to acidic rocks and from intrusions at deep crustal levels to effusive volcanic products. The Early Permian magmatism was likely the source of the late-stage hydrothermal fluids that formed the tourmalinites. The same fluids could also have played a significant role in the formation of the Uranium ore deposit of the Novazza-Vedello mining district, as the ore bodies in the Vedello valley are concentrated along the basement-cover contact.
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German, C. R., B. A. Barreiro, N. C. Higgs, T. A. Nelsen, E. M. Ludford, and M. R. Palmer. "Seawater-metasomatism in hydrothermal sediments (Escanaba Trough, northeast Pacific)." Chemical Geology 119, no. 1-4 (January 1995): 175–90. http://dx.doi.org/10.1016/0009-2541(94)00052-a.
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Kepezhinskas, Pavel, Nikita Kepezhinskas, and Nikolai Berdnikov. "Gold, platinum and palladium enrichments in arcs: role of mantle wedge, arc crust and halogen-rich slab fluids." E3S Web of Conferences 98 (2019): 08010. http://dx.doi.org/10.1051/e3sconf/20199808010.
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Arc-related magmas are frequently enriched in Au, Pt and Pd in respect to MORB and OIB igneous suites. Magmatic arcs commonly host large-scale hydrothermal Au and Au-Cu and PGE mineralization related to young volcanic systems and zoned ultramafic complexes respectively. Island-arc mantle xenoliths show Au, Pt, Pd enrichments related to mantle wedge metasomatism by slab-derived fluids. Long-lived plumbing systems in arc crust (arc magma chambers) show further enhancement of Au, Pt and Pd enrichments through subduction-related metamorphic and metasomatic processes in the presence of halogen-rich, aqueous fluids. We propose that Au-Pt-Pd enrichments in arcs are caused by mantle wedge-slab interactions followed by differentiation and metamorphism of magmatic conduits in arc crust.
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Neumayr, P., J. R. Ridley, and D. I. Groves. "sPhysicochemical conditions of fluid–wall rock interaction at amphibolite-facies conditions in two Archean hydrothermal gold deposits in the Mt. York District, Pilbara Craton, Western Australia." Canadian Journal of Earth Sciences 32, no. 7 (July 1, 1995): 993–1016. http://dx.doi.org/10.1139/e95-083.
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Synamphibolite facies Archean gold mineralization in the Mt. York District, Pilbara Craton, Western Australia, is hosted in metamorphosed banded iron formation (Main Hill–Breccia Hill prospect), amphibolites, and ultramafic schists (Zakanaka prospect). Mineralization at Main Hill occurs in quartz breccias with sulfide matrices and in altered wall rock adjacent to quartz–biotite–amphibole ± clinopyroxene veins. Alteration associated with quartz veins is zoned, with biotite—pyrrhotite vein selvedges and a distal calcic-amphibole, arsenopyrite–lôllingite zone. Hydrothermal biotite and actinolite have highest Mg/(Mg + Fe) ratios where associated with abundant sulfarsenides in the distal alteratin zone. Whole-rock geochemical analyses and calculated metasomatic reactions indicate the addition of K, Al, S, As, Au, Ag, and Ni during hydrothermal alteration. Mineralization at Zakanaka is characterized by a broad wall rock alteration halo of biotite–amphibole, and zoned quartz–calc silicate veins proximal to ore. Wall rock adjacent to the veins contains pyrrhotite, pyrite, and gold. The alteration is explained by K-metasomatism distal to mineralization and K and Ca metasomatism proximal to mineralization. Balanced metasomatic reactions and mass-balance calculations indicate addition of K and depletion of Na, Ca, Mg, and Fe in distal alteration zones and addition of K, Ca, Mg, Fe, and Ti in proximal zones. Gold precipitation at both prospects occurred through loss of S, and possibly As, from the ore fluid during sulfidation reactions with Fe-rich amphiboles and biotites to form Mg-enriched equivalents and sulfarsenides. Changes in the oxidation state of the ore fluid may have enhanced gold precipitation, though pH changes are unlikely to have been important. The controls on mineralization are thus similar to those at many lower temperature, mesothermal deposits. The lack of consistently increasing Mg ratios of calc-silicate phases with increasing intensity of alteration and sulfidation at Main Hill may be the result of coupled substitutions in amphiboles and biotites during infiltration of a fluid with high-S, but low-As, activities.
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Groves, David I., Liang Zhang, and M. Santosh. "Subduction, mantle metasomatism, and gold: A dynamic and genetic conjunction." GSA Bulletin 132, no. 7-8 (November 4, 2019): 1419–26. http://dx.doi.org/10.1130/b35379.1.
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Abstract Global gold deposit classes are enigmatic in relation to first-order tectonic scale, leading to controversial genetic models and exploration strategies. Traditionally, hydrothermal gold deposits that formed through transport and deposition from auriferous ore fluids are grouped into specific deposit types such as porphyry, skarn, high- and low-sulfidation–type epithermal, gold-rich volcanogenic massive sulfide (VMS), Carlin-type, orogenic, and iron-oxide copper-gold (IOCG), and intrusion-related gold deposits (IRGDs). District-scale mineral system approaches propose interrelated groups such as porphyry Cu-Au, skarn Cu-Au-Ag, and high-sulfidation Au-Ag. In this study, the temporal evolution of subduction-related processes in convergent margins was evaluated to propose a continuum of genetic models that unify the various types of gold deposits. At the tectonic scale of mineral systems, all hydrothermal gold deposits are interrelated in that they formed progressively during the evolution of direct or indirect subduction-related processes along convergent margins. Porphyry-related systems formed initially from magmatic-hydrothermal fluids related to melting of fertile mantle to initiate calc-alkaline to high-K felsic magmatism in volcanic arcs directly related to subduction. Formation of gold-rich VMS systems was related to hydrothermal circulation driven by magmatic activity during rifting of oceanic arcs. Orogenic gold deposits formed largely through fluids derived from devolatilization of the downgoing slab and overlying sediment wedge during late transpression in the orogenic cycle. Carlin-type deposits, IRGDs, and some continental-arc porphyry systems formed during the early stages of orogenic collapse via fluids directly or indirectly related to hybrid magmatism from melting of lithosphere that was metasomatized and gold-fertilized by earlier fluid release from subduction zones near margins of continental blocks. The IOCGs were formed during postorogenic asthenosphere upwelling beneath such subduction-related metasomatized and fertilized lithospheric blocks via fluid release and explosive emplacement of volatile-rich melts. Thus, importantly, subduction is clearly recognized as the key unifying dynamic factor in gold metallogenesis, with subduction-related fluids or melts providing the critical ore components for a wide variety of gold-rich deposit types.
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Kontonikas-Charos, Alkis, Cristiana L. Ciobanu, Nigel J. Cook, Kathy Ehrig, Roniza Ismail, Sasha Krneta, and Animesh Basak. "Feldspar mineralogy and rare-earth element (re)mobilization in iron-oxide copper gold systems from South Australia: a nanoscale study." Mineralogical Magazine 82, S1 (February 28, 2018): S173—S197. http://dx.doi.org/10.1180/minmag.2017.081.040.
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ABSTRACTNanoscale characterization (TEM on FIB-SEM-prepared foils) was undertaken on feldspars undergoing transformation from early post-magmatic (deuteric) to hydrothermal stages in granites hosting the Olympic Dam Cu-U-Au-Ag deposit, and from the Cu-Au skarn at Hillside within the same iron-oxide copper-gold (IOCG) province, South Australia. These include complex perthitic textures, anomalously Ba-, Fe-, or REE-rich compositions, and REE-flourocarbonate + molybdenite assemblages which pseudomorph pre-existing feldspars. Epitaxial orientations between cryptoperthite (magmatic), patch perthite (dueteric) and replacive albite (hydrothermal) within vein perthite support interface-mediated reactions between pre-existing alkali-feldspars and pervading fluid, irrespective of micro-scale crystal morphology. Such observations are consistent with a coupled dissolution-reprecipitation reaction mechanism, which assists in grain-scale element remobilization via the generation of transient interconnected microporosity. Micro-scale aggregates of hydrothermal hyalophane (Ba-rich K-feldspar), crystallizing within previously albitized areas of andesine, reveal a complex assemblage of calc-silicate, As-bearing fluorapatite and Fe oxides along reaction boundaries in the enclosing albite-sericite assemblage typical of deuteric alteration. Such inclusions are good REE repositories and their presence supports REE remobilization at the grain-scale during early hydrothermal alteration. Iron-metasomatism is recognized by nanoscale maghemite inclusions within ‘red-stained’ orthoclase, as well as by hematite in REE-fluorocarbonates, which reflect broader-scale zonation patterns typical for IOCG systems. Potassium-feldspar from the contact between alkali-granite and skarn at Hillside is characterized by 100–1000 ppm REE, attributable to pervasive nanoscale inclusions of calc-silicates, concentrated along microfractures, or pore-attached. Feldspar replacement by REE-fluorcarbonates at Olympic Dam and nanoscale calc-silicate inclusions in feldspar at Hillside are both strong evidence for the role of feldspars in concentrating REE during intense metasomatism. Differences in mineralogical expression are due to the availability of associated elements. Lattice-scale intergrowths of assemblages indicative of Fe-metasomatism, REE-enrichment and sulfide deposition at Olympic Dam are evidence for a spatial and temporal relationship between these processes.
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Wang, Yiyun, Guangming Li, Wei Liang, and Zhi Zhang. "The Chemical Characteristics and Metallogenic Mechanism of Beryl from Cuonadong Sn-W-Be Rare Polymetallic Deposit in Southern Tibet, China." Minerals 12, no. 5 (April 19, 2022): 497. http://dx.doi.org/10.3390/min12050497.
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The Cuonadong deposit is the first large scale Sn-W-Be rare polymetallic deposit located in southern Tibet, China, where beryl is the main beryllium-bearing mineral. In this paper, the beryl crystals in the pegmatitic and hydrothermal vein orebody from the Xianglin area of the Cuonadong deposit are the research objects, marked as Beryl-I and Beryl-II, and they are investigated by EPMA, LA-ICP-MS and in situ micro-X-ray diffraction (XRD). Data by EPMA and LA-ICP-MS reveal that beryls from this area are alkaline beryls, among which Beryl-I is composed of Li-Cs beryl, and Beryl-II is composed of Na beryl and Na-Li beryl, indicating that beryls have undergone noticeable alkali metasomatism during formation. The Cs/Na ratio in Beryl-I ranges from 0.10 to 0.44, and the Mg/Fe ratio is almost 0, showing that Beryl-I is formed under high-differentiation evolution conditions and is rarely affected by hydrothermal transformation, whereas the Mg/Fe ratio in Beryl-II ranges from 2.73 to 17.31, and the Cs/Na ratio is nearly 0, indicating that Beryl-II has been obviously affected by late hydrothermal metasomatism. In situ XRD analysis shows that both Beryl-I and Beryl-II are t-beryl, and the c/a ratio of Beryl-I (1.0010–1.0012) is slightly higher than that of Beryl-II (1.0005–1.0008), which may also reflect the transition from magmatism to hydrothermal metasomatism in the late stage of pegmatitic magmatism. Based on comprehensive analysis, we believe that the precipitation of Beryl-I is mainly caused by the emplacement of highly fractionated magma containing Be to the top of the rock mass or surrounding rock, the melt-fluid undercooling, and the crystallization of volatile-bearing minerals (such as tourmaline and fluorite). Moreover, the Be-bearing ore-forming fluid has further migrated upward along the near north–south faults formed in the middle Miocene (16–15 Ma), during which Beryl-II precipitates owing to the hydrothermal water mixing, the ore-forming fluid cooling, and large amounts of crystallization of volatile-bearing minerals (mainly fluorite). Therefore, it can be concluded that beryl mineralization largely reflects the process of magmatic–hydrothermal mineralization. Because of a large number of mineralized areas with the similar metallogenic backgrounds to the Cuonadong deposit in the Himalayan region, it has great potential to be a new globally significant rare metal metallogenic belt.
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Wu, Bin, Han-Jie Wen, Christophe Bonnetti, Ru-Cheng Wang, Jin-Hui Yang, and Fu-Yuan Wu. "Rinkite-(Ce) in the nepheline syenite pegmatite from the Saima alkaline complex, northeastern China: Its occurrence, alteration, and implications for REE mineralization." Canadian Mineralogist 57, no. 6 (November 30, 2019): 903–24. http://dx.doi.org/10.3749/canmin.1900042.
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Abstract The nepheline syenite pegmatite in the Saima alkaline complex in northeastern China is characterized by REE mineralization, mainly rinkite-(Ce) and associated alteration minerals. As the most abundant REE-bearing mineral in the pegmatite, rinkite-(Ce) closely coexists with microcline, nepheline, natrolite, and calcite. Some rinkite-(Ce) grains show compositional sector-zonation, in which the inner core displays relatively high Ti, Ca, and Sr concentrations, but low Zr, REE, and Na contents. Primary rinkite-(Ce) has undergone multiple episodes of fluid interactions, and accordingly, from weak to strong, three different mineral assemblages of hydrothermal alteration can be summarized: (1) rinkite-(Ce) + secondary natrolite ± K-feldspar ± minor fluorbritholite-(Ce); (2) rinkite-(Ce) relics + secondary natrolite + K-feldspar + fluorbritholite-(Ce) + unidentified Ca-Ti silicate mineral + fluorite and calcite; and (3) pseudomorphs after rinkite-(Ce). The pseudomorphs can be divided into two groups characterized by distinct mineral associations: (1) Ca-bearing strontianite + fluorbritholite-(Ce) + natrolite + fluorite + calcite coexisting with silicate minerals; and (2) calcite + fluorite + fluorbritholite-(Ce) + rinkite-(Ce) relics ± Ca-bearing strontianite ± ancylite-(Ce) associated with a calcite matrix. These alteration mineral assemblages are evidence of magmatic-derived alkali metasomatism due to an alkali-CO2-F-rich fluid and Ca-metasomatism due to a different, externally derived Sr- and Ca-rich fluid. The metasomatic events acted as the potential driving force for the rinkite-(Ce) dissolution and pseudomorph-forming process. The high concentration of rinkite-(Ce) in the nepheline syenite pegmatite results from the fractional crystallization of the Saima CO2-rich alkaline silicate magma, and the successive alterations of rinkite-(Ce) attest to the important role played by hydrothermal fluids in controlling the remobilization of REE and the crystallization of secondary rare earth minerals.
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Tvrdý, Jaromír, Zdeněk Dolníček, Jana Ulmanová, Ondřej Krátký, and Michal Nekl. "REE minerály fenitů čistecko-jesenického masivu (Česká republika)." Bulletin Mineralogie Petrologie 29, no. 2 (2021): 297–320. http://dx.doi.org/10.46861/bmp.29.297.
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Alkaline metasomatites (fenites) originated by pervasive Na metasomatism of granitoids of the Čistá-Jesenice Pluton (belonging to the Teplá-Barrandian unit in the NW part of the Bohemian Massif) contain a rich association of REE-bearing minerals. The occurrence of REE carbonates (bastnäsite, parisite), monazite, rhabdophane, churchite, fergusonite and pyrochlore was found in relatively weakly altered rocks (typical fenites), whereas much richer assemblage was observed in rocks which underwent the strongest metasomatism (so called reomorphic cancrinite-nepheline syenites). Here, the mineral assemblage includes in addition to all above mentioned minerals also xenotime and REE silicates, including tritomite/melanocerite, allanite, perbøeite, gadolinite and a Mn-analogue of hingganite. A common mineral phase is zircon in these rocks, too. Cerium, yttrium, and to lesser extent also lanthanum are dominating cations in the studied REE phases. A total of 24 mineral species was identified, including three unnamed phases. In most of the studied phases, the level of fractionation of REEs is high, exceptionally even extreme. Chondrite-normalized REE patterns of some phases are characterized by a pronounced M-type tetrad effect. The results of microprobe analyses suggest that individual minerals originated during several episodes, characterized by different chemical composition of the mineral-forming medium (especially with contrasting concentrations of strong REE-complexing ligands and oxygen fugacity) and/or temperature. We did not find any significant differences in chemistry of individual minerals present in various rock types showing different levels of metasomatic alteration. The obtained data are consistent with hydrothermal origin of most (if not all) reported REE-bearing phases. The material source and genesis of the studied REE+Nb+Zr mineralization was in all probability associated with hydrothermal activity in the exocontact of a deep-seated hypothetical carbonatite intrusion, as was suggested already in earlier works dealing with these remarkable rocks.
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Galliski, Miguel A., Encarnación Roda-Robles, Frédéric Hatert, María Florencia Márquez-Zavalía, and Viviana A. Martínez. "The Phosphate mineral assemblages from La Viquita Pegmatite, San Luis, Argentina." Canadian Mineralogist 58, no. 6 (November 1, 2020): 733–46. http://dx.doi.org/10.3749/canmin.1900106.
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ABSTRACT La Viquita is a rare-element pegmatite of LCT signature, REL-Li subclass, spodumene subtype, that shows Fe > Mn mineral paragenesis instead of Mn > Fe, which is more common in the rare-element pegmatite population of the San Luis ranges. The phosphate mineral association of this pegmatite can be subdivided into (1) primary, with dendritic triphylite [(Fe/(Fe + Mn) = 0.72] and montebrasite–amblygonite as main phases; (2) metasomatic, with subsolidus replacement of triphylite by ferrisicklerite and heterosite; and (3) hydrothermal, with secondary growth of alluaudite at the expense of heterosite and wardite from montebrasite caused by Na-metasomatism. A Ca-rich influx under oxidizing conditions produced childrenite–eosphorite–ernstite, jahnsite-(CaMnFe), and kingsmountite. Apatite-group minerals are present throughout the processes. Very late-stage solutions formed millimetric crystals of hydroxylherderite associated with hydroxylapatite in cavities in K-feldspar.
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Sazonov, Anatoly M., Aleksei E. Romanovsky, Igor F. Gertner, Elena A. Zvyagina, Tatyana S. Krasnova, Oleg M. Grinev, Sergey A. Silyanov, and Yurii V. Kolmakov. "Genesis of Precious Metal Mineralization in Intrusions of Ultramafic, Alkaline Rocks and Carbonatites in the North of the Siberian Platform." Minerals 11, no. 4 (March 29, 2021): 354. http://dx.doi.org/10.3390/min11040354.
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The gold and platinum-group elements (PGE) mineralization of the Guli and Kresty intrusions was formed in the process of polyphase magmatism of the central type during the Permian and Triassic age. It is suggested that native osmium and iridium crystal nuclei were formed in the mantle at earlier high-temperature events of magma generation of the mantle substratum in the interval of 765–545 Ma and were brought by meimechite melts to the area of development of magmatic bodies. The pulsating magmatism of the later phases assisted in particle enlargement. Native gold was crystallized at a temperature of 415–200 °C at the hydrothermal-metasomatic stages of the meimechite, melilite, foidolite and carbonatite magmatism. The association of minerals of precious metals with oily, resinous and asphaltene bitumen testifies to the genetic relation of the mineralization to carbonaceous metasomatism. Identifying the carbonaceous gold and platinoid ore formation associated genetically with the parental formation of ultramafic, alkaline rocks and carbonatites is suggested.
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Wu, Bin, Christophe Bonnetti, Yue Liu, Zhan-Shi Zhang, Guo-Lin Guo, Guang-Lai Li, Yin-Qiu Hu, and Zhao-Yan Yan. "Uraninite from the Guangshigou Pegmatite-Type Uranium Deposit in the North Qinling Orogen, Central China: Its Occurrence, Alteration and Implications for Post-Caledonian Uranium Circulation." Minerals 11, no. 7 (July 5, 2021): 729. http://dx.doi.org/10.3390/min11070729.
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The Guangshigou deposit is the largest pegmatite-type uranium deposit in the Shangdan domain of the North Qinling Orogenic Belt, which is characterized by the enrichment of uraninite hosted in biotite granitic pegmatites. At Guangshigou, uraninite commonly occurs as mineral inclusions in quartz, K-feldspar and biotite or in interstices of these rock-forming minerals with magmatic characteristics (e.g., U/Th < 100, high ThO2, Y2O3 and REE2O3 contents and low concentrations of CaO, FeO and SiO2). It crystallized at 407.6 ± 2.9 Ma from fractionated calc-alkaline high-K pegmatitic melts under conditions of 470–700 °C and 2.4–3.4 kbar as deduced by the compositions of coexisting peritectic biotite. The primary uranium mineralization took place during the Late Caledonian post-collisional extension in the North Qinling Orogen. After this magmatic event, uraninite has experienced multiple episodes of fluid-assisted metasomatism, which generated an alteration halo of mineral assemblages. The alteration halo (or radiohalo) was the result of the combined effects of metamictization and metasomatism characterized by an assemblage of goethite, coffinite and an unidentified aluminosilicate (probably clay minerals) around altered uraninite. This fluid-assisted alteration was concomitant with the albitization of K-feldspar subsequently followed by the coffinitization of uraninite during the major period of 84.9–143.6 Ma, as determined by U-Th-Pb chemical ages. Further investigations revealed that the metasomatic overprinting on uraninite initially and preferentially took place along microcracks or cavities induced by metamictization and promoted their amorphization, followed by the release of U and Pb from structure and the incorporation of K, Ca and Si from the fluids, finally resulting in various degrees of uraninite coffinitization. The released U and Pb were transported by alkali-rich, relatively oxidizing fluids and then re-precipitated locally as coffinite and an amorphous U-Pb-rich silicate under low to moderate temperature conditions (85–174 °C). The compositional changes in primary uraninite, its structure amorphization together with the paragenetic sequence of secondary phases, therefore, corroborate a combined result of intense metamictization of uraninite and an influx of alkali–metasomatic fluids during the Late Mesozoic Yanshanian magmatic event in the region. Hence, the remobilization and circulation of uranium in the North Qinling Orogen was most likely driven by post-Caledonian magmatism and hydrothermal activities related to large-scale tectonic events. In this regards, Paleozoic pegmatite-type uranium mineralization may represent a significant uranium source for Mesozoic hydrothermal mineralization identified in the Qinling Orogenic Belt.
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Sayın, Ş. Ali. "The Role of Hydrogen - Metasomatism in the Hydrothermal Kaolin Occurrences, Gönen, Western Turkey." Key Engineering Materials 264-268 (May 2004): 1379–82. http://dx.doi.org/10.4028/www.scientific.net/kem.264-268.1379.
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Almond, D. C., A. A. Osman, and F. Ahmed. "The Arba'at Granite, Sudan: a mineralised, Pan-African intrusion enhanced by hydrothermal metasomatism." Journal of African Earth Sciences 24, no. 3 (April 1997): 335–50. http://dx.doi.org/10.1016/s0899-5362(97)00048-1.
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Angus, Norman S., and Raymond Kanaris-Sotiriou. "Adinoles revisited: hydrothermal Na(Ca)-metasomatism of pelite screens adjacent to tholeiitic dykes in the Dublin terrane, Ireland." Mineralogical Magazine 59, no. 396 (September 1995): 367–82. http://dx.doi.org/10.1180/minmag.1995.059.396.01.
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AbstractThe albitisation of pelitic metasediments to form adinoles adjacent to minor mafic intrusions has in the past been attributed to Na-bearing metasomatizing fluids emanating from the intrusions themselves. The chemistry and mineralogy of adinoles associated with dykes forming a high-intensity swarm in the Tallaght area, County Dublin, Ireland, confirms a metasomatic origin for the adinoles described, with Na and to a lesser extent Ca introduced into the country rocks at the expense of K. We suggest, however, that the source of the metasomatizing fluids was external to the dykes — possibly involving a hydrothermal system driven by an underlying magma reservoir that was parental to the dykes and also contributed volatiles to the hydrothermal system by degassing. Heat flow from the dykes was instrumental in promoting the reaction between muscovite in the country rock pelites and the Na(Ca)-bearing fluids to form albite, temperatures of ∼350°C in the country rocks within a metre of the contact being indicated. The mechanism of adinolization proposed is shown to be compatible with recent experimental work on the hydrothermal alteration of greywackes and basalts and also with the likely temperature gradients adjacent to dykes.
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Kadashnikova, A. Yu, A. A. Sorokin, V. A. Ponomarchuk, A. V. Travin, and V. A. Ponomarchuk. "THE AGE OF GOLD MINERALIZATION AT THE ELGA DEPOSIT (MONGOL-OKHOTSK FOLD BELT): 40AR/39AR GEOCHRONOLOGICAL CONSTRAINTS." Tikhookeanskaya Geologiya 41, no. 2 (2022): 89–100. http://dx.doi.org/10.30911/0207-4028-2022-41-2-89-100.
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In our 40Ar/39Ar geochronological study, the age of gold mineralization of the Elga deposit is determined. The Elga deposit is located in the eastern part of the Mongol-Okhotsk fold belt. The data obtained indicate that the age of ore metasomatites and hydrothermally and metasomatically altered carbon-bearing sericite-feldspar-quartz shales can be estimated at 139–137 Ma. It is impossible to link the ore mineralization of the Elga deposit with magmatic processes since the igneous complexes located within the study area are either younger or significantly older than mineralization. The sericite from the Talyma Formation shales outside the ore zone is found to be almost of the identical age, that is, 139 Ma. Thus, the final stage of regional metamorphism and deformation is coeval with the formation of ore metasomatites. We suggest that the main factors in the mobilization, redistribution of the ore matter and the formation of the Elga deposit were post-collisional dislocation processes accompanied by hydrothermal activity and metasomatism.
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Bagiński, Bogusław, Petras Jokubauskas, Justyna Domańska-Siuda, Pavel Kartashov, and Ray Macdonald. "Hydrothermal metasomatism of a peralkaline granite pegmatite, Khaldzan Buragtag massif, Mongolian Altai; complex evolution of REE-Nb minerals." Acta Geologica Polonica 66, no. 3 (September 1, 2016): 477–95. http://dx.doi.org/10.1515/agp-2016-0021.
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Abstract The low-temperature hydrothermal alteration of certain rare-metal minerals is recorded in a quartz-epidote metasomatite from the Tsakhirin Khuduk occurrence in the Khaldzan-Buragtag Nb-REE-Zr deposit, Mongolian Altai. A peralkaline granitic pegmatite was metasomatized by hydrothermal fluids released from associated intrusions, with the formation of, inter alia, chevkinite-(Ce), fergusonite-(Nd) and minerals of the epidote group. The textural pattern indicates recrystallization and coarsening of these phases. Later, low-temperature alteration by fluids resulted in the chevkinite-(Ce) being replaced by complex titanite-TiO2 -cerite-(Ce)-hingganite-hydroxylbastnasite-( Ce) assemblages. Calcite formed late-stage veins and patches. The hydrous fluids were poor in F and CO2 but had high Ca contents.
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Vafeas, N. A., L. C. Blignaut, K. S. Viljoen, and P. Le Roux. "An investigation into the 87Sr/86Sr radiogenic isotope geochemistry of the manganese ore of the Kalahari Manganese Field with a view on hydrothermal fluid flow and related rare earth element enrichments." South African Journal of Geology 122, no. 2 (June 1, 2019): 237–48. http://dx.doi.org/10.25131/sajg.122.0016.
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Abstract The Paleoproterozoic Kalahari Manganese Field is the largest known land-based manganese (Mn) deposit on Earth and comprises five erosional relics of the iron- and manganese-rich Hotazel Formation. A total of 19 manganese ore samples from the lower manganese ore horizon of the Hotazel Formation were selected for analysis based on their relative metasomatic alteration states. These samples range from primary diagenetic, classic supergene enriched, hydrothermally enriched (Wessels-type ore) and thrusted manganese ore. When normalised to Post-Archaean Australian shale composites, rare earth elemental analyses on the selected samples indicate significant relative enrichments within the thrusted manganese ore, an ore type that hasn’t been studied from a geochemical point of view, so far. A comparison between these respective enrichments and 87Sr/86Sr ratios indicates a distinct link between REE enrichments and associated alteration events, and a progressive increase in 87Sr/86Sr isotope values. An isotopic relationship between fluid infiltration events and REE redistribution within the Hotazel Formation has been established, highlighting unique isotope signatures necessary in better defining and characterising metasomatism within the Paleoproterozoic Kalahari Manganese Field.
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Bebout, Gray E., and Mark D. Barton. "Fluid flow and metasomatism in a subduction zone hydrothermal system: Catalina Schist terrane, California." Geology 17, no. 11 (1989): 976. http://dx.doi.org/10.1130/0091-7613(1989)017<0976:ffamia>2.3.co;2.
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CATHELINEAU, M. "The Hydrothermal Alkali Metasomatism Effects on Granitic Rocks: Quartz Dissolution and Related Subsolidus Changes." Journal of Petrology 27, no. 4 (August 1, 1986): 945–65. http://dx.doi.org/10.1093/petrology/27.4.945.
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Roza Llera, Ana, Mercedes Fuertes-Fuente, Antonia Cepedal, and Agustín Martin-Izard. "Barren and Li–Sn–Ta Mineralized Pegmatites from NW Spain (Central Galicia): A Comparative Study of Their Mineralogy, Geochemistry, and Wallrock Metasomatism." Minerals 9, no. 12 (November 29, 2019): 739. http://dx.doi.org/10.3390/min9120739.
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In Central Galicia, there are occurrences of barren and Li–Sn–Ta-bearing pegmatites hosted by metasedimentary rocks. A number of common and contrasting features between Panceiros pegmatites (barren) and Li–Sn–Ta mineralized Presqueira pegmatite are established in this study. K-feldspar and muscovite have the same trace elements (Rb, Cs, P, Zn, and Ba), but the mineralized one has the highest Rb and Cs and the lowest P contents. The barren bodies show fluorapatite and eosphorite–childrenite replacing early silicates. The mineralized body has primary phosphates (fluorapatite and montebrasite), a metasomatic paragenesis (fluorapatite and goyazite) replacing early silicates, and a late hydrothermal assemblage (vivianite and messelite). Ta–Nb oxides from the Presqueira body show a trend from columbite-(Fe) to tantalite-(Fe) and tapiolite-(Fe). In this body, the Li-aluminosilicate textures support primary crystallization of petalite that was partially transformed into Spodumene + Quartz (SQI) during cooling, and into myrmekite during a Na-metasomatism stage. As a result of both processes, spodumene formed. The geochemical study supports magmatic differentiation increasing from the neighboring granites to the Li–Sn–Ta mineralized pegmatite. In both barren and mineralized bodies, the pegmatite-derived fluids that migrated into the wallrock were enriched in B, F, Li, Rb, and Cs and, moreover, in Sn, Zn, and As.
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Song, Yueting, Shanrong Zhao, and Chang Xu. "Crystallographic orientation relationships between quartz and feldspar in myrmekite: a case study in monzodiorite from Meichuan pluton, China." Mineralogical Magazine 85, no. 3 (April 19, 2021): 406–15. http://dx.doi.org/10.1180/mgm.2021.39.
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AbstractMyrmekites occurring in monzodiorite from the Meichuan pluton in the Dabie ultrahigh-pressure metamorphic belt were investigated. The petrographic evidence demonstrates a metasomatic origin for myrmekite formation at the scale of individual alkali feldspar grains, and that the myrmekitic quartz and plagioclase matrix are generated simultaneously replacing precursor feldspar. Energy-dispersive X-ray spectroscopy and electron microprobe analysis indicate a low anorthite content in the narrow rim of host plagioclase near the myrmekite–alkali-feldspar interface. The Ca2+, Na+ proportion of hydrothermal fluids replacing precursor alkali feldspar is 1:5.4, calculated from the anorthite content of the inner part of the host plagioclase and the neighbouring alkali feldspar. Electron back-scattered diffraction was used to identify the crystallographic orientation of the myrmekitic quartz, plagioclase matrix and the precursor alkali feldspar. The crystallographic orientation relationships (110)Kfs//(11$\bar{2}\bar{1}$)Qtz, (20$\bar{1}$)Kfs//(11$\bar{2}$1)Qtz and [11$\bar{2}3]$Qtz//[001]Kfs between myrmekitic quartz and adjacent alkali feldspar were obtained from statistical analysis. No clear crystallographic orientation relationship between quartz and plagioclase was found. The growth of myrmekitic quartz is constrained by the precursor alkali feldspar rather than the simultaneously crystallised plagioclase. This research is helpful for understanding the intergrowth mechanism during metasomatism.
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Whitney, Philip R., and James F. Olmsted. "Rare earth element metasomatism in hydrothermal systems: the Willsboro-Lewis wollastonite ores, New York, USA." Geochimica et Cosmochimica Acta 62, no. 17 (September 1998): 2965–77. http://dx.doi.org/10.1016/s0016-7037(98)00230-0.
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Shabeer, K. P., T. Okudaira, M. Satish-Kumar, S. S. Binu-Lal, and Y. Hayasaka. "Ca-W metasomatism in high-grade matapelites: an example from scheelite mineralization in Kerala Khondalite Belt, southern India." Mineralogical Magazine 67, no. 3 (June 2003): 465–83. http://dx.doi.org/10.1180/0026461036730111.
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AbstractScheelite mineralization in the granulite-facies supracrustal sequences of the Kerala Khondalite Belt, southern India is reported. The supracrustal sequences where the mineralization is found comprise granulite-grade metasediments which underwent metamorphism at ∼550 Ma. The mineralization is assumed to have formed by late-stage metasomatism that overprinted the regional metamorphism of the country rock (garnet-biotite gneiss) and occurs along a quartz vein that intrudes the regional foliation. The paragenetic data from the vein demonstrate unambiguously a separate cycle of hydrothermal activity, resulting in metasomatism and mineralization. Scheelite is found in both the altered host rock along the foliation plane and in the quartz vein. Fluid inclusions preserved in the vein suggest that the mineralizing fluids were saline-aqueous in composition, while those in the country rocks were predominantly CO2-rich. The mineral chemistry and bulk-rock chemical composition of the mineralized domain reveal the unusual enrichment of Ca in the mineralised zone with the depletion of K. We propose that fluid discharging from a crystallizing deep-seated magma, mixing with deep circulating Ca-bearing palaeo-groundwater gave rise to the deposition of scheelite. The scheelite mineralization and the quartz vein emplacement occurred after the Pan-African regional metamorphism.
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Zhang, Jingsen, Jing Zhang, and Yanchao Zhai. "Geochemistry of hydrothermally altered rocks with gold mineralization hosted in alkaline complex in Hongshan area, Taihang Orogen, North China." World Journal of Engineering 13, no. 1 (February 8, 2016): 23–34. http://dx.doi.org/10.1108/wje-02-2016-001.
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Purpose This paper aims to elucidate the geochemical characteristics of the hydrothermally altered rocks with gold mineralization and the elemental transfers in hydrothermal alteration hosted in alkaline complex in Hongshan area, Taihang Orogen, North China, and preliminarily discuss the relationship between the gold mineralization and the hydrothermal alteration. Design/methodology/approach Based on detailed field investigation, sampling and petrographical observation, major oxides and trace elements of nine rock samples are analyzed, and the method of mass balance equation is used in calculation of the elemental transfer. Findings Three alteration stages in the Hongshan area are identified, which are the early, main and late alterations. The early one is characteristic of extensive pyritization in the complex, which is related to the mantle-derived magmas and occurs before gold mineralization. The main one is characterized by developing a great deal of altered rock in fracture zones with the gain of many elements and the loss of a few elements. The late one is dominated by limonitization, that is limonite replacing the early pyrite or Fe2O3 replacing FeO in rocks. In the main alteration, the altered rocks obviously gain fluid component (LOI, i.e. loss on ignition) and elements such as V, As, Rb, Au, La, Ce and Nd and total rare earth elements (REEs). Elements such as K, Fe, Cu, Zn, Y, Mo, Sb, W, Re and U are gained in some altered rocks. Na and Sr are lost in all altered rocks, and Th and Bi are lost in some ones in the meantime. The following elements: Si, Mg, Mn, Ca, Li, Sc, Cr, Co, Ni, Zr, Ag, Ba and Hg show either gain or loss in different altered rocks. Au is notably enriched in the hydrothermal alteration. The elemental gain or loss in the altered rocks indicates that the main mineralization develops extensive de-alkalinization, local potassic metasomatism, silicification or desilicification.
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Wang, Xinyu, Shulai Wang, Huiqiong Zhang, Yuwang Wang, Xinyou Zhu, and Xing Yang. "Geochemical Characteristics of the Mineral Assemblages from the Niukutou Pb-Zn Skarn Deposit, East Kunlun Mountains, and Their Metallogenic Implications." Minerals 13, no. 1 (December 23, 2022): 18. http://dx.doi.org/10.3390/min13010018.
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The Niukutou Pb-Zn deposit is typical of skarn deposits in the Qimantagh metallogenic belt (QMB) in the East Kunlun Mountains. In this study, based on detailed petrographical observations, electron microprobe analyses (EMPAs), and laser-ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) analyses, we report the major and trace element compositions of the typical skarn mineral assemblages (garnet, pyroxene, ilvaite, epidote, and chlorite) in this deposit. Three hydrothermal mineralization stages with different mineral assemblages of the prograde metamorphic phase were determined, which were distributed from the inside to the outside of the ore-forming rock mass. Grt1+Px1 (Stage 1), Grt2+Px2 (Stage 2), and Px3 (Stage 3) were distinguished in the Niukutou deposit. Furthermore, the ilvaites in the retrograde metamorphic phase can be divided into three stages, namely Ilv1, Ilv2, and Ilv3. The ore-forming fluid in Stage 1 exhibited high ∑REE, U, and Nd concentrations and δEu, δCe, and LREE/HREE values, which were likely derived from a magmatic–hydrothermal source and formed at high temperatures, high fO2 values, and mildly acidic pH conditions, and probably experienced diffusive metasomatism in a closed system with low water/rock ratios. In Stages 2 and 3, the ore-forming exhibited lower ∑REE, U, and Nd concentrations and δEu, δCe, and LREE/HREE values, with high Mn content that had likely experienced infiltrative metasomatism in an open system with high water/rock ratios. From Ilv1 to Ilv3, the δEu and U contents decreased, whereas the Mn content increased, indicating that the oxygen fugacity of mineralization was in decline. The ore-forming fluid evolution of the Niukutou deposit can be characterized as follows: from Stage 1 to Stage 3, the hydrothermal fluid migrated from the deep plutons to the shallow skarn and marble; the environment altered from the high fO2 and temperature conditions to low fO2 and temperature values, and the pH and Mn contents increased. The fluids contained considerable metal ore-forming materials that were favorable for the enrichment and precipitation of the Fe content. In the retrograde metamorphic phase, with the decrease in oxygen fugacity (from Ilv1 to Ilv3), the temperature and oxygen fugacity of the theore-forming fluid environment decreased, ultimately becoming conducive to the dissolution and precipitation of Pb and Zn elements.
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Samal, Amiya K., Rajesh K. Srivastava, and Dewashish Upadhyay. "Major, Trace, and Rare-Earth Element Geochemistry of Nb-V Rich Andradite-Schorlomite-Morimotoite Garnet from Ambadungar-Saidivasan Alkaline Carbonatite Complex, India: Implication for the Role of Hydrothermal Fluid-Induced Metasomatism." Minerals 11, no. 7 (July 13, 2021): 756. http://dx.doi.org/10.3390/min11070756.
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In situ major, trace and rare-earth element composition of Ti-rich garnets from Ambadungar-Saidivasan alkaline carbonatite complex (ASACC) are presented to constrain its likely genesis. The garnets are characterized by high andradite (42.7–57.3), schorolomite (22.0–31.0), and morimotoite (15.6–26.5) end members. No distinct chemical zonation is noticed except for minor variations in Ti content. The garnets are enriched in LREE (average 731 ppm) and relatively depleted in HREE (average 186 ppm) and show an M-type first tetrad that leads to a convex upward pattern between Ce and Gd. Mildly positive to no Eu anomalies are observed (Eu/Eu* = 1.06–1.17). The REE patterns (LaN/YbN = 1.11–2.11) are similar to those of garnets from skarn deposits. The presence of tetrad effect in the LREE pattern suggests an active role of metasomatic processes involving hydrothermal fluids during the growth of the garnets. These garnets also contain high Nb (282–2283 ppm) and V (1083–2155 ppm) concentrations, which stand out against the composition of the host rock. Therefore, late-stage metasomatic reactions of earlier formed minerals with hydrothermal fluid enriched in Fe, Si, LREE, Nb, V, and Ti led to the formation of garnet. The primary source for these elements could be magnetite, ilmenite, and pyrochlore present in different varieties of carbonatites in the ASACC, with the required elements being released during their interaction with the hydrothermal fluid. The hydrothermal fluid was likely to be moderately acidic, and having fluoride and sulfate as the primary ligands.
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Feng, Mingyou, Tian Liu, Tong Lin, Xiaohong Liu, Ningxin Li, and Aihua Xi. "Fracture Fillings and Implication of Fluid Activities in Volcanic Rocks: Dixi Area in Kelameili Gas Field, Junggar Basin, Northwestern China." Minerals 9, no. 3 (March 3, 2019): 154. http://dx.doi.org/10.3390/min9030154.
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The Carboniferous Batamayineishan Formation of the Kelameili Gas Field is a specific weathered crust-related volcanic reservoir that has a significant production rate in the Junggar Basin, Northwestern China, attributed to debatable processes of fluid evolution. The results suggest that various types of fluids occurring in volcanic rocks lead to the filling of quartz and calcite in fractures and their associated alteration haloes. The silica that formed quartz veins was mainly derived from deep hydrothermal fluids, while the carbon dioxide that formed calcite veins originated from sources characterized by mixing and alteration of deep hydrothermal and hydrocarbon fluids. Siliceous hydrothermal fluids rich in sulphur dioxide and other volatile components were driven by a pressure gradient and buoyancy, and circulated both laterally and vertically along the fractures, forming quartz veins and tension fractures under different temperature conditions. Moreover, changes in salinity, pressure, and carbon dioxide of deep fluids, varying from acidic to weakly alkaline, resulted in earlier calcite precipitation in contraction fractures and weathered fractures. Tectonic uplift resulted in the long-term exposure of volcanic rocks, where fresh water mixed with the partially alkaline fluid escaping the basin to form calcite cements, thus retaining the characteristics of a seepage environment in the weathered fractures. Structural fractures occurred due to tectonic movements during the burial period. Filling and leakage of hydrocarbons caused pore fluids to convert from acidic to alkaline, precipitating late sparry calcite in dissolution fractures. Late hydrothermal fluid metasomatism, brought about by infiltration into the permeable zone, caused partial dissolution of local calcite along cleavage cracks.
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Corteel, C., and P. De Paepe. "Boron metasomatism in the Brabant Massif (Belgium): Geochemical and petrographical evidence of Devonian tourmalinite pebbles." Netherlands Journal of Geosciences 82, no. 2 (July 2003): 197–208. http://dx.doi.org/10.1017/s0016774600020746.
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AbstractNew petrographical and geochemical evidence of tourmalinite pebbles from two Lower and three Middle Devonian formations from Belgium is presented. Petrography, REE, transition metal and microprobe data of the studied rocks suggest it are (meta)sediment-derived tourmalinites formed by boron metasomatism (and hydrothermal brecciation) in an intrusive setting. Tourmaline mineralizations within eastern Avalonia are known in south-east Ireland, the English Lake District and East Anglia. Based on previously suggested relations between Early Palaeozoic igneous activity in last two mentioned regions and the Brabant Massif, it is presumed that the Brabant Massif also underwent granite-related tourmalinization and that this was the source of the studied pebbles. Petrologie differences between pebbles found in Middle Devonian formations and pebbles from Lower Devonian formations, suggest that fluid circulation occurred on a regional scale, possibly extending into the Stavelot massif.
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Saitoh, Masafumi, Sami Nabhan, Christophe Thomazo, Nicolas Olivier, Jean-François Moyen, Yuichiro Ueno, and Johanna Marin-Carbonne. "Multiple Sulfur Isotope Records of the 3.22 Ga Moodies Group, Barberton Greenstone Belt." Geosciences 10, no. 4 (April 16, 2020): 145. http://dx.doi.org/10.3390/geosciences10040145.
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The Moodies Group, the uppermost unit in the Barberton Greenstone Belt (BGB) in South Africa, is a ~3.7-km-thick coarse clastic succession accumulated on terrestrial-to-shallow marine settings at around 3.22 Ga. The multiple sulfur isotopic composition of pyrite of Moodies intervals was newly obtained to examine the influence of these depositional settings on the sulfur isotope record. Conglomerate and sandstone rocks were collected from three synclines north of the Inyoka Fault of the central BGB, namely, the Eureka, Dycedale, and Saddleback synclines. The sulfur isotopic composition of pyrite was analyzed by Secondary Ion Mass Spectrometry (SIMS) for 6 samples from the three synclines and by Isotope Ratio Mass Spectrometry (IR-MS) for 17 samples from a stratigraphic section in the Saddleback Syncline. The present results show a signal of mass-independent fractionation of sulfur isotopes (S-MIF), although t-tests statistically demonstrated that the Moodies S-MIF signals (mostly 0‰ < ∆33S < +0.5‰) are significantly small compared to the signal of the older Paleoarchean (3.6–3.2 Ga) records. These peculiar signatures might be related to initial deposition of detrital pyrite of juvenile origin from the surrounding intrusive (tonalite–trondhjemite–granodiorite; TTG) and felsic volcanic rocks, and/or to secondary addition of hydrothermal sulfur during late metasomatism. Moreover, fast accumulation (~0.1–1 mm/year) of the Moodies sediments might have led to a reduced accumulation of sulfur derived from an atmospheric source during their deposition. As a result, the sulfur isotopic composition of the sediments may have become susceptible to the secondary addition of metasomatic sulfur on a mass balance point of view. The sulfur isotopic composition of Moodies pyrite is similar to the composition of sulfides from nearby gold mines. It suggests that, after the Moodies deposition, metasomatic pyrite formation commonly occurred north of the Inyoka Fault in the central BGB at 3.1–3.0 Ga.
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Qin, Ming-Kuan, Shao-Hua Huang, Jia-Lin Liu, Zhang-Yue Liu, Qiang Guo, Li-Cheng Jia, and Wen-Jian Jiang. "Hydrothermal Alteration and Its Superimposed Enrichment for Qianjiadian Tabular-Type Uranium Deposit in Southwestern Songliao Basin." Minerals 12, no. 1 (December 30, 2021): 52. http://dx.doi.org/10.3390/min12010052.
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The evolution characteristics of hydrothermal activity and superimposed uranium mineralization in the Qianjiadian ore field in southwestern Songliao Basin are still controversial and lack direct evidence. In this comprehensive study, a detailed identification of dolerite and hydrothermally altered un-mineralized sandstone and sandstone-hosted ore in the Yaojia Formation have been performed through the use of scanning electron microscopy observation, electron probe, carbon-oxygen-sulfur isotope, and fluid inclusion analyses. The results show that the hydrothermal fluid derived from the intermediate-basic magma intrusion is a low-temperature reducing alkaline fluid and rich in CO2, Si, Zr, Ti, Fe, Mg, Mn, and Ca, producing different types of altered mineral assemblages in the rocks, including carbonation, pyritization, sphalerite mineralization, clausthalite mineralization, silicification, and biotitization. Specifically, the carbonate minerals in sandstone are mixed products of deep hydrothermal fluid and meteoric water, with carbon and oxygen isotopes ranging from −5.2‰ to −1.7‰ and −20.4‰ to −11.1‰, respectively. Carbon source of the carbonate minerals in dolerite is mainly inorganic carbon produced at the late stage of intermediate-basic magma evolution, with carbon and oxygen isotopes from −16.1‰ to −7.2‰ and −18.2‰ to −14.5‰, respectively. Various carbonate minerals in the rocks may have been precipitated by the hydrothermal fluid after the magmatic stage, due to the change of its CO2 fugacity, temperature, and cation concentration during the long-term evolution stage. A series of carbonate minerals were generated as calcite, dolomite, ankerite, ferromanganese dolomite, and dawsonite. The precipitation processes and different types of carbonate mineral mixtures identified in this study mainly occur as parallel, gradual transition, interlacing, or inclusion metasomatism in the same vein body, without obvious mineralogical and petrologic characteristics of penetrating relationship. Homogenization temperature of fluid inclusions in calcite is high, in the range of 203–234 °C, with a low salinity of 0.71–4.34% NaCl, and the data range is relatively concentrated. Homogenization temperature of fluid inclusions in ankerite is usually low, ranging from 100 °C to 232 °C, with a high salinity of 4.18–9.98% NaCl. The precipitation processes of carbonate minerals and the results of this study are basically in consistent. Overall, the sandstone-type uranium deposits have a temporal and genetic relationship with hydrothermal activities during Paleogene. (1) Hydrothermal activity was directly involved in uranium mineralization, result in dissolution and reprecipitation of earlier uranium minerals, forming uranium-bearing ankerite and complexes containing uranium, zirconium, silicon, and titanium. (2) Hydrothermal fluid activity provided reducing agent to promote hydrocarbon generation from pyrolysis of carbonaceous fragments and accelerate uranium precipitation rate. (3) Regional water stagnation prolongs reaction time, contributing to huge uranium enrichment. This study provides new petrologic, mineralogical, and geochemical evidence for multi-fluid coupled and superimposed mineralization of sandstone-hosted uranium deposits in the sedimentary basin.
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Schandl, E. S., and M. P. Gorton. "HYDROTHERMAL ALTERATION AND CO2 METASOMATISM (NATURAL CARBON SEQUESTRATION) OF KOMATIITES IN THE SOUTH-WESTERN ABITIBI GREENSTONE BELT." Canadian Mineralogist 50, no. 1 (February 1, 2012): 129–46. http://dx.doi.org/10.3749/canmin.50.1.129.
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White, Alistair J. R., Raymond E. Smith, Patrick Nadoll, and Monica Legras. "Regional-scale Metasomatism in the Fortescue Group Volcanics, Hamersley Basin, Western Australia: Implications for Hydrothermal Ore Systems." Journal of Petrology 55, no. 5 (April 12, 2014): 977–1009. http://dx.doi.org/10.1093/petrology/egu013.
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Leão-Santos, Marcelo, Roberto Moraes, Yaoguo Li, Maria Irene Raposo, and Boxin Zuo. "Hydrothermal Alteration Zones’ Magnetic Susceptibility Footprints and 3D Model of Iron Oxide-Copper-Gold (IOCG) Mineralization, Carajás Mineral Province, Brazil." Minerals 12, no. 12 (December 9, 2022): 1581. http://dx.doi.org/10.3390/min12121581.
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Brownfield areas are important targets of exploration; however, the extensive drilling present in these areas has not fully exploited their prospective potential. The appropriate use of drill hole cores in these areas can play an important role in deep exploration. We present a case study of iron oxide-copper-gold (IOCG) Furnas Southeast deposit, located in the Carajás Mineral Province, Brazil. This deposit has disseminated chalcopyrite, bornite and gold mineralization associated with a silicic (Si), potassic (K), calcic (Na), sodic-calcic (Na-Ca) hydrothermal alteration, and intense iron metasomatism with massive magnetite (Fe) alteration. Petrophysical hand-held equipment measurements were carried out on drill core samples with the purpose of studying the potential roles that magnetic susceptibility properties can play in high-grade mineralization. The results indicate that the geological complexity of the IOCG deposit is readily reflected in the extensive variation of the measurements. The statistical analysis shows how the detailed characterization of this physical property carried out for this mineral association could effectively define and describe ore, and the magnetic susceptibility footprints of hydrothermal alteration zones. Furthermore, we were able to perform a magnetic susceptibility 3D modeling of diamagnetic, paramagnetic, and ferrimagnetic responses strictly correlated with known orebody. Thus, petrophysical analyses can form a quantitative geological criterion for ore delineation.
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Lusheng, Yin, Dongdong Wang, Shen Lijun, Zhu Yuzhen, Li Zengxue, and Wang Yongjun. "Coexistence and Development Model of Multi-Minerals Dominated by Multilayer Magma Intrusion." Global Journal of Earth Science and Engineering 8 (November 4, 2021): 45–61. http://dx.doi.org/10.15377/2409-5710.2021.08.4.
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The diversity of coal measure determines the occurrence state and spatial distribution complexity of mineral resources. Abundant resources have become an important part of geological resources and have attracted more and more attention. Coal measure and their overlying and underlying strata often coexist with various mineral resource types, and there is a certain relationship between their genesis and occurrence. In order to further enrich the theory of comprehensive exploration and coordinated development of multi-mineral resources, this paper takes the Huanghebei Coalfield as an example to systematically study the genesis mechanism and occurrence law of coal seam, coalbed methane, and coal-measure shale gas in Late Paleozoic and rich iron ore in Ordovician limestone underlie coal measure. The research is that: 1) The Late Paleozoic Carboniferous-Permian Marine facies, terrestrial facies, and transitional facies all developed in the coal-bearing area in the Huanghebei Coalfield, and the coal seams and mud shales developed well in Shanxi Formation and Taiyuan Formation. 2) Yanshanian magmatic intruded into Ordovician limestone. Contact metasomatism occurred between the ore-bearing hydrothermal fluids and the surrounding rocks, which led to skarn formation. The magnetite mineralization occurred in the metasomatism alteration process, and finally, the contact metasomatic iron deposit was formed; 3) Yanshanian magma intrusion has a significant impact on the generation of coal from coalbed methane and shale gas in the coal measures of Late Paleozoic. The magma carries a lot of heat by baking the coal seam and overlying shale, which is reflected explicitly in the increasing metamorphism degree of coal. Under the action of high temperature, the secondary gas of coal seam and coalbed methane increase sharply. The maturity and thermal evolution of organic matter in shale beds increased, and the shale gas entered a favorable range. The intrusion of magma greatly enhances the thermal evolution of organic matter in coal and shale, forming a variety of coals and promoting the generation and accumulation of coalbed methane and shale gas. At the same time, Mesozoic magmatic intrusion also controlled the formation of rich iron ores. According to the characteristics of mineral development and distribution in the study area, a multi-mineral development and distribution model of “coal - coalbed methane - shale gas - rich iron ore” coexists in the Huanghebei Coalfield, which is referred to as the “Huanghebei model”.
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Heilimo, Esa, Sini Halonen, Satu Mertanen, Sami Niemi, and Perttu Mikkola. "Hiekkapohja hydrothermal system – ore mineral, lithogeochemical and paleomagnetic evidence from the Paleoproterozoic Central Finland Granitoid Complex." Bulletin of the Geological Society of Finland 94, no. 2 (December 27, 2022): 145–64. http://dx.doi.org/10.17741/bgsf/94.2.003.
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The Paleoproterozoic Svecofennian Central Finland Granitoid Complex (CFGC) has been regarded as an area of low mineralisation potential. The Hiekkapohja area, 20km north-east of the town of Jyväskylä, host a concentration of variable metalliferous showings. Samples from mineralised boulders and outcrops display variable combinations of anomalously high concentrations of Cu, Mo, Zn, Pb, W, Pb, Ag, As, and Au. The area is composed mainly of peraluminous and ferroan granitoids. The dominant porphyritic Hiekkapohja granodiorite (~1.88 Ga) is cross-cut by the equigranular Soimavuori granite of similar age. The porphyritic Lehesvuori granite on the western side of the study area represents marginally older (~1.89 Ga) magmatism. The paragenetic sequence of the ore minerals shows that the Hiekkapohja area has been affected by at least two separate stages of hydrothermal activity. The first mineralisation stage was widespread, crystallising typically chalcopyrite, pyrrhotite, sphalerite, galena, arsenopyrite, magnetite and Ag-bearing minerals. After the first stage, a low temperature oxidising phase formed hematite and marcasite. The second mineralisation stage enclosed low temperature minerals, such as marcasite and native Ag and Ag-minerals, as inclusions inside chalcopyrite, pyrite, pyrrhotite, sphalerite, and arsenopyrite. The mineralised samples typically display signs of K-metasomatism and less commonly signs of propylitic alteration. During the second mineralisation stage the fluid flow was controlled by the dominant 120°–135° trending shear zones. Both the hydrothermal activity and the regional geology indicate that porphyry type ore forming processes have occurred in the Hiekkapohja area. Paleoproterozoic resetting of the remanent magnetisation is further evidence for the role of the hydrothermal system.
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Clark, T., A. Gobeil, and J. David. "Iron oxide - copper - gold-type and related deposits in the Manitou Lake area, eastern Grenville Province, Quebec: variations in setting, composition, and style." Canadian Journal of Earth Sciences 42, no. 10 (October 1, 2005): 1829–47. http://dx.doi.org/10.1139/e05-048.
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The Manitou Lake area (Kwyjibo and Lac Marmont sectors), located in Quebec's eastern Grenville Province, contains magnetite-rich deposits with variable morphological, mineralogical, and chemical characteristics. Most Kwyjibo sector deposits are rich in Cu, rare-earth elements (REE), Y, P, F, and Ag and are anomalous in Th, U, Mo, W, Zr, and Au, and Lac Marmont sector deposits are commonly poor in these elements. Deposits occur in or are closely associated with 11751168 Ma leucogranite. They contain combinations of magnetite, clinopyroxene, bluegreen hornblende, titanite, apatite, fluorite, quartz, biotite, andradite, epidote, albite, hematite, sulfides (chalcopyrite, pyrite, pyrrhotite, molybdenite, sphalerite), ilmenite, allanite, and other REE-bearing minerals. Veins and breccias are common. Most of the magnetite mineralization was preceded by potassic metasomatism (microcline) and was followed by most of the sulfides and radioactive minerals. Nearby sulfide-dominant deposits may be related. The deposits were formed by metasomatic replacement and fracture filling from hydrothermal fluids of variable composition, which were probably channeled in major, active faults. Oxygen-isotope data from magnetite-rich rocks suggest that fluids were predominantly magmatic and (or) metamorphic and that, locally, mixing with cooler meteoric water may have facilitated precipitation of sulfides and rare-metal minerals. Titanites in mineralized rock have been dated at 972 ± 5 Ma, but most magnetite may be older. Mineralization was syn- to post-tectonic and occurred in an orogenic to orogenic-collapse setting. The CuREEY-rich deposits are similar to iron oxide copper gold (IOCG) Olympic Dam type deposits, and copper- and rare-metals-poor occurrences resemble magnetite ± apatite Kiruna-type deposits.
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Koutsovitis, P., C. Kanellopoulos, S. Passa, K. Foni, E. Tsapara, G. Oikonomou, N. Xirokostas, Κ. Vallianatou, and Ε. Mouxiou. "MINERALOGICAL, PETROLOGICAL AND GEOCHEMICAL FEATURES OF THE UNIQUE LAPIS LACEDAEMONIUS (KROKEATIS LITHOS) FROM LACONIA, GREECE: APPROACH ON PETROGENETIC PROCESSES WITHIN THE TRIASSIC VOLCANIC CONTEXT." Bulletin of the Geological Society of Greece 50, no. 4 (July 28, 2017): 1903. http://dx.doi.org/10.12681/bgsg.14235.
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The Lapis Lacedaemonius (krokeatis lithos) is a well-known meta-volcanic rock of great historical importance. Petrographic observations, mineral chemistry data, as well as geochemical analysis of selected samples, reveal that these rocks are porphyritic metabasaltic rocks which have been significantly affected by saussuritization and also by restricted silicification processes. They represent subduction related calc-alkaline volcanic rocks which also appear in the adjacent Hellenic Triassic volcanic outcrops, and appear to be associated with the rift/drift phase within the Pindos oceanic realm. The unique features of the Lapis Lacedaemonius, when compared to geochemically similar volcanic rock outcrops, are mainly attributed to their distinct porphyritic textures, predominantly with microlithically textured groundmass along with the coarse grained plagioclase, and to saussuritization processes. The Lapis Lacedaemonius seems to have been formed in a sub-volcanic system closely associated with epidosites, suggesting that metasomatism occurred within hydrothermal upflow zones.
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AGRELL, S. O., G. A. CHINNER, and P. D. ROWLEY. "The black skarns of Pine Canyon, Piute County, Utah." Geological Magazine 136, no. 4 (July 1999): 343–59. http://dx.doi.org/10.1017/s0016756899002800.
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A small micromonzonite pluton intruding Miocene extrusives of the Marysvale volcanic field of southern Utah has undergone a sequence of explosive brecciation, syenite veining, rheomorphism, calcium metasomatism and zeolitization. Skarn-like occurrences of magnetite and Al-spinel-rich feldspathoidal rocks within the outcrop are of two main types: (1) an olivine-bearing variety with occasional REE-rich minerals (zirconolite) occurs as veins and seams in desilicated latite screens and xeno-liths.; (2) an aluminous, corundum- and hibonite-bearing variety with accessory zirconolite, perovskite and armalcolite occurs mainly as fillings to the micromonzonite breccias. The chemically disparate types are interpreted as having initiated as propylitic, and argillic/alunitic, alterations of latite country rock in the early hydrothermal system of the pluton. Subsequent intrusion of the micromonzonite to higher levels has incorporated these products into the igneous complex, in which they have experienced varying degrees of nephelinization, pyrometamorphism, rheomorphism and veining.
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Dalstra, H., and S. Guedes. "GIANT HYDROTHERMAL HEMATITE DEPOSITS WITH Mg-Fe METASOMATISM: A COMPARISON OF THE CARAJAS, HAMERSLEY, AND OTHER IRON ORES." Economic Geology 99, no. 8 (December 1, 2004): 1793–800. http://dx.doi.org/10.2113/gsecongeo.99.8.1793.
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Anenburg, Michael, and John A. Mavrogenes. "Carbonatitic versus hydrothermal origin for fluorapatite REE-Th deposits: Experimental study of REE transport and crustal “antiskarn” metasomatism." American Journal of Science 318, no. 3 (March 2018): 335–66. http://dx.doi.org/10.2475/03.2018.03.
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Cui, Fang-Hua, Chao Zhang, Dai-Tian Jin, Lu-Yuan Wang, Ji-Lei Gao, Ming Ma, and Ya-Dong Li. "Mineral Chemistry of the Lower Cretaceous Jinling Iron Skarn Deposit, Western Shandong Province, North China Craton: Implications for the Iron Skarn Mineralization Process." Minerals 12, no. 9 (September 12, 2022): 1152. http://dx.doi.org/10.3390/min12091152.
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The source of iron material and the mineralization process of iron skarn deposits within the eastern North China Craton are ambiguous. In this study, we present new mineral chemical data of the Jinling skarn deposit, located in western Shandong Province, east China. Based on the petrography study and mineral chemical data, we suggest that the Jinling iron skarn deposit is hydrothermal and the metallogenic iron is enriched by leaching of Fe-rich fluids derived from primitive magmatic melt from the solidified diorites. The Jinling iron skarn deposit formed as a result of several mineralization processes: (1) Fe-rich hydrothermal fluids exsolved from a hydrous parental magma that was characterized by high iron content, oxygen fugacity (fO2), and salinity; (2) the Fe content of the fluids was augmented during the alkali metasomatism stage via the leaching of Fe from the solidified dioritic rocks; (3) diopside and garnet in skarns formed under relatively alkaline and oxidizing conditions during the later prograde skarn stage; (4) during the retrograde skarn stage, amphibole, chlorite, epidote, phlogopite, serpentine, biotite, and chlorite formed under more oxidizing conditions, and subsequent mixing of the Fe-rich fluids with meteoric water triggered the precipitation of the massive magnetite; and (5) the final sulfide–carbonate stage was involved in the formation of carbonate and sulfide minerals as a result of a change in conditions from oxidizing to reducing.
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Zongyong, Wang, Han Xin, LV Guxian, Zhang Xunyu, Zhang Yingchun, Fan Xiao, Huo Qinglong, and Xu Yaqing. "Rb-Sr Isotopic Geochronology and Geological Implications of Dongfeng Gold Deposit in Jiaodong Area." Earth Sciences Research Journal 20, no. 1 (April 30, 2016): 1–7. http://dx.doi.org/10.15446/esrj.v20n1.55178.
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<p>The superlarge Dongfeng gold deposit is located in the Potouqing faults-alteration belt of the eastern part of the ‘Zhao-Lai-gold ore belt’, which belongs to the northwestern part of the Jiaodong area. Tectonically, ore bodies are controlled by faults and gold mainly occurs in the pyrite and polymetallic sulfide-bearing quartz vein. In this paper, Rb–Sr isotopic analysis is carried out with the beresite, which formed by hydrothermal metasomatism, and the Rb–Sr isochron age is 125.5±6.7Ma, indicating this deposit set up in the early Cretaceous of the late Yanshanian. Based on the relationship between the Dongfeng gold deposit and the Mesozoic granite, it is suggested that the formation of the gold deposit is a complex geological process of gradual enrichment and precipitation of the ore-forming elements. The initial <sup>87</sup>Sr/<sup>86</sup>Sr ratio of the beresite is 0.711502±0.000069, which indicates the ore-forming materials mainly come from the crust. Combined with the complex mineralization process of the Dongfeng gold deposit and the reported H-O isotopic data, it is suggested that the ore-forming materials are mainly derived from the crust with some mantle materials, while the ore-forming fluids are originated primarily from magmatic hydrothermal and mantle with some precipitate water.</p>
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Ganino, Clément, and Guy Libourel. "Fumarolic-like activity on carbonaceous chondrite parent body." Science Advances 6, no. 27 (July 2020): eabb1166. http://dx.doi.org/10.1126/sciadv.abb1166.
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Comparative planetology studies are key for understanding the main processes driving planetary formation and evolution. None have been yet applied to pristine asteroids formed in the solar protoplanetary disk, mainly because of their comminution during their 4.5-billion-year collisional lifetime. From remarkable textural, mineralogical, chemical, and thermodynamic similarities, we show that the high-temperature Kudryavy volcano fumarolic environment from Kurile Islands is a likely proxy of the Fe-alkali-halogen metasomatism on the CV and CO carbonaceous chondrite parent bodies. Ca-Fe–rich and Na-Al-Cl–rich secondary silicates in CV and CO chondrites are, thus, inferred to be fumarolic-like incrustations that precipitate from hot and reduced hydrothermal vapors after interactions with the wallrocks during buoyancy-driven Darcy flow percolation. These vapors may originate from the progressive heating and devolatilization of a chondritic protolith on their parent body or are remnant of the cooling of residual local nebular gases at the time of their primary planetesimal accretion.
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Wei, Hao, Jiuhua Xu, Guorui Zhang, Xihui Cheng, Haixia Chu, Chunjing Bian, and Zeyang Zhang. "Hydrothermal Metasomatism and Gold Mineralization of Porphyritic Granite in the Dongping Deposit, North Hebei, China: Evidence from Zircon Dating." Minerals 8, no. 9 (August 21, 2018): 363. http://dx.doi.org/10.3390/min8090363.
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A porphyritic granite intrusion was recently discovered in the Zhuanzhilian section of the Dongping gold deposit. There is as many as one tonnage of Au in the fractured shear zone within the porphyritic granite intrusion, but no relevant reports concerning the origin and age of the intrusion has been published as yet. In this paper, zircon U-Pb dating is used to study the geochronology of porphyritic granite, in order to find out the evidence of age and the relationship with gold mineralization. There are two groups of zircon 207Pb/235U-206Pb/238U concordant ages of porphyritic granites: The concordant age of 373.0 ± 3.5 Ma, with the weighted mean age of 373.0 ± 6.4 Ma; and the concordant age of 142.02 ± 1.2 Ma with the weighted mean age of 142.06 ± 0.84 Ma. We believe that the first group might represent the age of residual zircon of alkaline complex, while the second group might be related with main gold mineralization. The obtained results of the petrography and electron probe analysis indicate that the porphyritic quartz and porphyritic granite, as well as gold mineralization, might be products of a late replacement of tectonic-hydrothermal fluid, which was rich in Si, Na and K originally and later yielded gold-forming fluids.
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Gartz, V. H., and H. E. Frimmel. "Complex metasomatism of an Archean placer in the Witwatersrand Basin, South Africa; the Ventersdorp contact reef; a hydrothermal aquifer?" Economic Geology 94, no. 5 (August 1, 1999): 689–706. http://dx.doi.org/10.2113/gsecongeo.94.5.689.
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Torabi, Ghodrat, Shoji Arai, Tomoaki Morishita, and Akihiro Tamura. "Mantle hornblendites of Naein ophiolite (Central Iran): Evidence of deep high temperature hydrothermal metasomatism in an upper mantle section." Petrology 25, no. 1 (January 2017): 114–37. http://dx.doi.org/10.1134/s0869591117010076.
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