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Journal articles on the topic 'Hydrogène – Solubilité'

Author: Grafiati

Published: 9 June 2023

Last updated: 31 July 2025

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1

Sinha, Sneha, Chelsea Yang, Emily Wu, and William E. Acree. "Abraham Solvation Parameter Model: Examination of Possible Intramolecular Hydrogen-Bonding Using Calculated Solute Descriptors." Liquids 2, no. 3 (2022): 131–46. http://dx.doi.org/10.3390/liquids2030009.

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Published solubility data for 4,5-dihydroxyanthraquinone-2-carboxylic acid dissolved in several organic solvents of varying polarity and hydrogen-bonding character are used to calculate the Abraham model solute descriptors. Calculated descriptor values suggest that 4,5-dihydroxyanthraquinone-2-carboxylic acid engages in intramolecular hydrogen formation between the two phenolic hydrogens and the proton acceptor sites (the lone electron pairs) on the neighboring quinone oxygen atom. Our study further shows that existing group contribution and machine learning methods provide rather poor estimat

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2

Pigeon, Pascal, Feten Najlaoui, Michael James McGlinchey, Juan Sanz García, Gérard Jaouen, and Stéphane Gibaud. "Unravelling the Role of Uncommon Hydrogen Bonds in Cyclodextrin Ferrociphenol Supramolecular Complexes: A Computational Modelling and Experimental Study." International Journal of Molecular Sciences 24, no. 15 (2023): 12288. http://dx.doi.org/10.3390/ijms241512288.

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We sought to determine the cyclodextrins (CDs) best suited to solubilize a patented succinimido-ferrocidiphenol (SuccFerr), a compound from the ferrociphenol family having powerful anticancer activity but low water solubility. Phase solubility experiments and computational modelling were carried out on various CDs. For the latter, several CD-SuccFerr complexes were built starting from combinations of one or two CD(s) where the methylation of CD oxygen atoms was systematically changed to end up with a database of ca. 13 k models. Modelling and phase solubility experiments seem to indicate the p

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3

Yamanaka, Shinsuke, Takahiro Matsuura, and Masanobu Miyake. "Hydrogen Solubility in Molybdenum*." Zeitschrift für Physikalische Chemie 1, no. 1 (1992): 109–15. http://dx.doi.org/10.1524/zpch.1992.1.1.109.

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4

Yamanaka, Shinsuke, Takahiro Matsuura, and Masanobu Miyake. "Hydrogen Solubility in Molybdenum*." Zeitschrift für Physikalische Chemie 179, Part_1_2 (1993): 103–9. http://dx.doi.org/10.1524/zpch.1993.179.part_1_2.103.

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5

Reinertz, J., W. A. Oates, H. Wenzl, and T. Schober. "Hydrogen Solubility in NiAl*." Zeitschrift für Physikalische Chemie 183, Part_1_2 (1994): 99–107. http://dx.doi.org/10.1524/zpch.1994.183.part_1_2.099.

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6

Seta, Shoji, and Hirohisa Uchida. "Hydrogen solubility in LaNi5." Journal of Alloys and Compounds 231, no. 1-2 (1995): 448–53. http://dx.doi.org/10.1016/0925-8388(95)01874-3.

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7

Chen, Huasheng, Chao Liu, and Xiaoxiao Xu. "Molecular dynamic simulation of sulfur solubility in H2S system." International Journal of Modern Physics B 33, no. 08 (2019): 1950052. http://dx.doi.org/10.1142/s0217979219500528.

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The elemental sulfur solubility in sour gas plays an important role in H2S-rich gas reservoir development and transportation. While the solubility of elemental sulfur in sour gas can be measured in macroscopical respect, the interaction of solid deposition is not clear at microscale. In this work, molecular dynamic simulation (MD) was adopted to predict the solubility of elemental sulfur in hydrogen sulfide at nanoscale. It is found that the results of new nanoscale solubility model are close to the reported experimental data. The average relative error of the solubility of elemental sulfur in

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8

TRUSH, VASYL. "INFLUENCE OF HYDROGEN SATURATION ON CHARACTERISTICS OF ZIRCONIUM." Herald of Khmelnytskyi National University. Technical sciences 307, no. 2 (2022): 159–68. http://dx.doi.org/10.31891/2307-5732-2022-307-2-159-168.

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The article presents a literature review on the effect of hydrogen saturation on the properties of zirconium alloys. Zirconium alloys are an indispensable structural material for the core of nuclear reactors. During operational loads, the interaction of zirconium materials with interstitial elements (oxygen, nitrogen, hydrogen) necessarily occurs. Zirconium shows the greatest affinity for hydrogen. One of the vulnerable zirconium elements is fuel rod tubes. The safe operation of a nuclear reactor depends on their integrity. In addition, it is fuel tubes that are most exposed to hydrogen. There

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9

Chen, Liang, Qian Wang, Wugui Jiang, and Haoran Gong. "Hydrogen Solubility in Pd3Ag Phases from First-Principles Calculation." Metals 9, no. 2 (2019): 121. http://dx.doi.org/10.3390/met9020121.

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First-principles calculation was used to systematically investigate hydrogen solubility in Pd3Ag phases. It was found that the solubility of hydrogen in Pd3Ag phases was much greater than in face-centered cubic (FCC) Pd, suggesting that Ag atoms enhanced hydrogen solubility with respect to FCC Pd. In addition, the present calculation also revealed that the anti-site defect formation enthalpies of Pd3Ag were close to zero, and the values of vacancy were positive and large, which indicated that Pd3Ag distributed compactly. In the process of hydrogen separation, anti-site defects decreased the hy

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10

Watanabe, N., G. Zhang, Hiroshi Yukawa, et al. "Hydrogen Solubility and Resistance to Hydrogen Embrittlement of Nb-Pd Based Alloys for Hydrogen Permeable Membrane." Advanced Materials Research 26-28 (October 2007): 873–76. http://dx.doi.org/10.4028/www.scientific.net/amr.26-28.873.

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The alloying effects of Pd on the hydrogen solubility and the resistance to hydrogen embrittlement are investigated for Nb-xmol%Pd-ymol%Zr (x=0~19; y=0, 1) alloys. The hydrogen solubility at 673 K is found to decrease with increasing Pd content in the alloys. Both pure Nb and Nb-Pd alloys possessed ductility in vacuum at 673 K. However, severe hydrogen embrittlement occurs in pure Nb when it is tested under the hydrogen pressure even as low as 0.01 MPa. In view of the small punch (SP) absorption energy, the addition of Pd into Nb improves the resistance to hydrogen embrittlement by decreasing

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11

Plyasov, A. A., V. V. Novikov, and Yu N. Devyatko. "Hydrogen Solubility in Zirconium Alloys." Physics of Atomic Nuclei 83, no. 9 (2020): 1328–38. http://dx.doi.org/10.1134/s1063778820090185.

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12

SHIROTA, Minori, Tomoyuki IMADA, Kohei ITO, Hidetaka MURAMATSU, Yasuyuki TAKATA, and Motoo FUJII. "F113 Hydrogen solubility in water." Proceedings of the National Symposium on Power and Energy Systems 2008.13 (2008): 269–70. http://dx.doi.org/10.1299/jsmepes.2008.13.269.

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13

Parent, J. Scott, and Garry L. Rempel. "Solubility of Hydrogen in Chlorobenzene." Journal of Chemical & Engineering Data 41, no. 2 (1996): 192–94. http://dx.doi.org/10.1021/je950213h.

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14

Sivakumar, R. "Hydrogen solubility studies in Zr0.2Tb0.8Fe1.5Co1.5." International Journal of Hydrogen Energy 25, no. 9 (2000): 861–69. http://dx.doi.org/10.1016/s0360-3199(99)00110-x.

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15

Rajalakshmi, N., U. V. Varada Raju, and K. V. S. Rama Rao. "Solubility of hydrogen in Ti3Cu." Journal of the Less Common Metals 128 (February 1987): 57–64. http://dx.doi.org/10.1016/0022-5088(87)90191-3.

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16

Ramaprabhu, Sundara, Natarajan Rajalakshmi, and Alarich Weiss. "Solubility of hydrogen in Ti3In." Journal of the Less Common Metals 157, no. 1 (1990): 85–95. http://dx.doi.org/10.1016/0022-5088(90)90409-d.

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17

Voyt, A., N. Sidorov, I. Sipatov, M. Dobrotvorskii, V. Piven, and I. Gabis. "Hydrogen solubility in V85Ni15 alloy." International Journal of Hydrogen Energy 42, no. 5 (2017): 3058–63. http://dx.doi.org/10.1016/j.ijhydene.2016.10.033.

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18

Shirasu, Yoshirou, Shinsuke Yamanaka, and Masanobu Miyake. "Hydrogen solubility in boron carbide." Journal of Alloys and Compounds 190, no. 1 (1992): 87–90. http://dx.doi.org/10.1016/0925-8388(92)90180-h.

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19

Katsuta, H., H. Iwamoto, and H. Ohno. "Hydrogen solubility in liquid Li17Pb83." Journal of Nuclear Materials 133-134 (August 1985): 167–70. http://dx.doi.org/10.1016/0022-3115(85)90127-8.

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20

Lewis, F. A. "Solubility of hydrogen in metals." Pure and Applied Chemistry 62, no. 11 (1990): 2091–96. http://dx.doi.org/10.1351/pac199062112091.

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21

Yamanaka, S., K. Higuchi, and M. Miyake. "Hydrogen solubility in zirconium alloys." Journal of Alloys and Compounds 231, no. 1-2 (1995): 503–7. http://dx.doi.org/10.1016/0925-8388(95)01864-6.

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22

Lv, Yating, Feifei Xu, Fei Liu, and Maoshen Chen. "Investigation of Structural Characteristics and Solubility Mechanism of Edible Bird Nest: A Mucin Glycoprotein." Foods 12, no. 4 (2023): 688. http://dx.doi.org/10.3390/foods12040688.

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In this study, the possible solubility properties and water-holding capacity mechanism of edible bird nest (EBN) were investigated through a structural analysis of soluble and insoluble fractions. The protein solubility and the water-holding swelling multiple increased from 2.55% to 31.52% and 3.83 to 14.00, respectively, with the heat temperature increase from 40 °C to 100 °C. It was observed that the solubility of high-Mw protein increased through heat treatment; meanwhile, part of the low-Mw fragments was estimated to aggregate to high-Mw protein with the hydrophobic interactions and disulf

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23

Will, J., and C. Haberstroh. "Solubility of hydrogen in liquid helium - development of a measurement apparatus." IOP Conference Series: Materials Science and Engineering 1327, no. 1 (2025): 012143. https://doi.org/10.1088/1757-899x/1327/1/012143.

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Abstract The solubility of hydrogen in liquid helium seems to be unknown. One potential explanation for this could be the exceedingly low solubility limit, making this phenomenon irrelevant for the vast majority of applications. In cryogenics, however, this effect is crucial. Traces of hydrogen in liquid helium and in the liquid helium supply systems result in a malfunction of liquid helium flow cryostats and throttle devices. The project HyLiqHe (granted by DFG) aims among other objectives to quantify the solubility limits by measurement. Two specialized disciplines must come together for suc

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24

Johnsen, Hennie Marie, Marianne Hiorth, and Jo Klaveness. "Molecular Hydrogen Therapy—A Review on Clinical Studies and Outcomes." Molecules 28, no. 23 (2023): 7785. http://dx.doi.org/10.3390/molecules28237785.

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With its antioxidant properties, hydrogen gas (H2) has been evaluated in vitro, in animal studies and in human studies for a broad range of therapeutic indications. A simple search of “hydrogen gas” in various medical databases resulted in more than 2000 publications related to hydrogen gas as a potential new drug substance. A parallel search in clinical trial registers also generated many hits, reflecting the diversity in ongoing clinical trials involving hydrogen therapy. This review aims to assess and discuss the current findings about hydrogen therapy in the 81 identified clinical trials a

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25

Gao, Guang Hua, and Guang Wei Zhai. "Determination of Solubility of Hydrogen in Polymer Solution at High Pressure." Advanced Materials Research 641-642 (January 2013): 253–55. http://dx.doi.org/10.4028/www.scientific.net/amr.641-642.253.

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Abstract. The solubility of hydrogen in styrene-butadiene-styrene (SBS) block copolymer-cyclohexane solution was determined under 3, 6 and 10 MPa pressures and at temperatures from 50°C to 150°C respectively. The experimental results showed that the solubility of hydrogen increases with risen pressure, temperature as well as concentration of SBS polymer in the cyclohexane solvent. The measured data of gas solubility could be successfully correlated by PRSV equation of state.

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26

Lho, Taihyeop, Yong-Sup Choi, and HyonJae Park. "Hydrogen Solubility of FLiNaK with Hydrogen Plasma Interaction." Fusion Science and Technology 63, no. 1T (2013): 106–10. http://dx.doi.org/10.13182/fst13-a16882.

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27

Cysewski, Piotr, Tomasz Jeliński, Maciej Przybyłek, Anna Mai, and Julia Kułak. "Experimental and Machine-Learning-Assisted Design of Pharmaceutically Acceptable Deep Eutectic Solvents for the Solubility Improvement of Non-Selective COX Inhibitors Ibuprofen and Ketoprofen." Molecules 29, no. 10 (2024): 2296. http://dx.doi.org/10.3390/molecules29102296.

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Deep eutectic solvents (DESs) are commonly used in pharmaceutical applications as excellent solubilizers of active substances. This study investigated the tuning of ibuprofen and ketoprofen solubility utilizing DESs containing choline chloride or betaine as hydrogen bond acceptors and various polyols (ethylene glycol, diethylene glycol, triethylene glycol, glycerol, 1,2-propanediol, 1,3-butanediol) as hydrogen bond donors. Experimental solubility data were collected for all DES systems. A machine learning model was developed using COSMO-RS molecular descriptors to predict solubility. All studi

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28

Abraham, Michael H., Gary S. Whiting, Wendel J. Shuely, and Ruth M. Doherty. "The solubility of gases and vapours in ethanol - the connection between gaseous solubility and water-solvent partition." Canadian Journal of Chemistry 76, no. 6 (1998): 703–9. http://dx.doi.org/10.1139/v98-029.

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Ostwald solubility coefficients, as log L, for solutes in water and ethanol have been combined to give log PEtOH for partition between the two pure solvents. Sixty-four such values have been correlated through our solvation equation, the coefficients of which lead to the conclusion that ethanol and water solvents are equally strong hydrogen-bond bases, but that ethanol is much weaker as a hydrogen-bond acid. A slightly different solvation equation has been used to correlate 68 values of log LEtOH; the coefficients in this equation yield the same conclusions as to the hydrogen-bond acidity and

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29

Yukawa, Hiroshi, T. Nambu, and Yoshihisa Matsumoto. "In Situ Analysis of Hydrogen Mobility during Hydrogen Permeation through Nb-Based Hydrogen Permeable Membranes." Defect and Diffusion Forum 312-315 (April 2011): 506–12. http://dx.doi.org/10.4028/www.scientific.net/ddf.312-315.506.

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The hydrogen solubility and the hydrogen permeability have been measured for Nb-based alloys in order to investigate the alloying effects on the hydrogen diffusivity during hydrogen permeation. It is found that the hydrogen solubility decreases by the addition of ruthenium, tungsten or molybdenum into niobium. The mobility for hydrogen diffusion during hydrogen permeation is estimated from the linear relationship between the normalized hydrogen flux, , and the product of the hydrogen concentration and the difference of hydrogen chemical potential, . It is found that the mobility for hydrogen d

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30

Ji, Shunfeng, and Anran Zeng. "Solubility and Activation of Hydrogen in the Non-Catalytic Upgrading of Venezuela Orinoco, China Liaohe, and China Fengcheng Atmospheric Residues." Processes 9, no. 12 (2021): 2274. http://dx.doi.org/10.3390/pr9122274.

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The solubility of hydrogen in the Venezuela Orinoco, China Liaohe, and China Fengcheng atmospheric residues under reaction conditions of 400 °C, 4 MPa for 20 min was analyzed by determining the composition and structure changes of the products. Activation of hydrogen during the upgrading process was also determined and discussed by the probe method. The results show that lighter components produced in the reaction can increase the hydrogen solubility as the reaction proceeds, and the lighter components present at the liquid level have positive effects on the transfer of hydrogen from the gas p

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31

Marukovich, E. I., V. Yu Stetsenko, and A. V. Stetsenko. "Dissolution of hydrogen in metals and casting alloys." Litiyo i Metallurgiya (FOUNDRY PRODUCTION AND METALLURGY), no. 3 (October 14, 2022): 53–57. http://dx.doi.org/10.21122/1683-6065-2022-3-53-57.

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Thermodynamic calculations have shown that hydrogen from atmospheric water vapors can penetrate aluminum, iron and copper, especially into their melts. Hydrogen atoms in these metals are in free and adsorbed states. Strong and dense oxide films on the surfaces of aluminum, iron and copper significantly reduce the solubility of hydrogen in these metals. Copper and iron nanocrystals more actively adsorb atomic hydrogen than aluminum nanocrystals. This is one of the main reasons for the weak solubility of hydrogen in aluminum and the large desorption of hydrogen atoms in the crystallization of al

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32

Honjo, Takamitsu, Tohru Nobuki, Masafumi Chiba, and Toshiro Kuji. "Hydrogen Solubility of Mg-C Composites." Journal of the Japan Institute of Metals 71, no. 8 (2007): 603–7. http://dx.doi.org/10.2320/jinstmet.71.603.

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33

IMABAYASHI, Mamoru, Minoru ICHIMURA, and Yasushi SASAJIMA. "Solubility of hydrogen in molten aluminum." Journal of Japan Institute of Light Metals 45, no. 5 (1995): 278–83. http://dx.doi.org/10.2464/jilm.45.278.

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34

Tuli, Vidur, Antoine Claisse, and Patrick A. Burr. "Hydrogen solubility in Zr–Nb alloys." Scripta Materialia 214 (June 2022): 114652. http://dx.doi.org/10.1016/j.scriptamat.2022.114652.

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35

ICHIMURA, Minoru, Yasushi SASAJIMA, and Mamoru IMABAYASHI. "Hydrogen solubility in aluminum-copper alloys." Journal of Japan Institute of Light Metals 39, no. 9 (1989): 639–45. http://dx.doi.org/10.2464/jilm.39.639.

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36

Binns, M. J., R. C. Newman, S. A. McQuaid, and Edward C. Lightowlers. "Hydrogen Solubility and Defects in Silicon." Materials Science Forum 143-147 (October 1993): 861–66. http://dx.doi.org/10.4028/www.scientific.net/msf.143-147.861.

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37

Talbot, D. E. J., and P. N. Anyalebechi. "Solubility of hydrogen in liquid aluminium." Materials Science and Technology 4, no. 1 (1988): 1–4. http://dx.doi.org/10.1179/mst.1988.4.1.1.

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38

Sakamoto, Y., Y. Tanaka, K. Baba, and T. B. Flanagan. "Hydrogen Solubility in Palladium-Boron Alloys." Zeitschrift für Physikalische Chemie 158, Part_2 (1988): 237–51. http://dx.doi.org/10.1524/zpch.1988.158.part_2.237.

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39

Sakamoto, Y., K. Kajihara, Y. Fukusaki, and Ted B. Flanagan. "Hydrogen Solubility in Palladium-Yttrium Alloys." Zeitschrift für Physikalische Chemie 159, Part_1 (1988): 61–74. http://dx.doi.org/10.1524/zpch.1988.159.part_1.061.

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40

Rajalakshmi, N. "Hydrogen solubility properties of Ti0.42Zr0.08Fe0.50 alloy." International Journal of Hydrogen Energy 24, no. 7 (1999): 625–29. http://dx.doi.org/10.1016/s0360-3199(98)00121-9.

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41

Uno, M., K. Takahashi, T. Maruyama, H. Muta, and S. Yamanaka. "Hydrogen solubility of BCC titanium alloys." Journal of Alloys and Compounds 366, no. 1-2 (2004): 213–16. http://dx.doi.org/10.1016/s0925-8388(03)00749-7.

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42

MATYSINA, Z. "Hydrogen solubility in alloys under pressure." International Journal of Hydrogen Energy 21, no. 11-12 (1996): 1085–89. http://dx.doi.org/10.1016/s0360-3199(96)00050-x.

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43

Lal, D., F. D. Otto, and A. E. Mather. "Solubility of hydrogen in Athabasca bitumen." Fuel 78, no. 12 (1999): 1437–41. http://dx.doi.org/10.1016/s0016-2361(99)00071-x.

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44

Xu, Z. R., and R. B. McLellan. "The solubility of hydrogen in NiAl." Acta Materialia 46, no. 8 (1998): 2877–80. http://dx.doi.org/10.1016/s1359-6454(97)00480-1.

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45

Ronze, Didier, Pascal Fongarland, Isabelle Pitault, and Michel Forissier. "Hydrogen solubility in straight run gasoil." Chemical Engineering Science 57, no. 4 (2002): 547–53. http://dx.doi.org/10.1016/s0009-2509(01)00404-3.

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46

Yang, L., and R. B. McLellan. "The solubility of hydrogen in Ni3Al." Acta Metallurgica et Materialia 42, no. 12 (1994): 3993–96. http://dx.doi.org/10.1016/0956-7151(94)90176-7.

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47

Lin, Jinq-Jy, Tsong-Pyng Perng, and Chuin-Tih Yeh. "Hydrogen solubility in amorphous Fe40Ni38Mo4B18 alloy." Scripta Metallurgica et Materialia 25, no. 5 (1991): 1179–82. http://dx.doi.org/10.1016/0956-716x(91)90524-5.

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48

Zhou, Zhiming, Zhenmin Cheng, Dong Yang, Xiao Zhou, and Weikang Yuan. "Solubility of Hydrogen in Pyrolysis Gasoline." Journal of Chemical & Engineering Data 51, no. 3 (2006): 972–76. http://dx.doi.org/10.1021/je050478o.

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49

Sakamoto, Y., K. Kajihara, E. Ono, K. Baba, and Ted B. Flanagan. "Hydrogen Solubility in Palladium — Vanadium Alloys." Zeitschrift für Physikalische Chemie 165, Part_1 (1989): 67–81. http://dx.doi.org/10.1524/zpch.1989.165.part_1.067.

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50

Moehlecke, S., C. F. Majkrzak, and Myron Strongin. "Enhanced hydrogen solubility in niobium films." Physical Review B 31, no. 10 (1985): 6804–6. http://dx.doi.org/10.1103/physrevb.31.6804.

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