Journal articles: 'Hydrogen peroxide direct synthesis'

1

Szuromi, P. "Direct hydrogen peroxide synthesis." Science 351, no. 6276 (February 25, 2016): 929–31. http://dx.doi.org/10.1126/science.351.6276.929-n.

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Kolehmainen, E., and I. Turunen. "Direct synthesis of hydrogen peroxide in microreactors." Russian Journal of General Chemistry 82, no. 12 (December 2012): 2100–2107. http://dx.doi.org/10.1134/s1070363212120304.

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Ranganathan, Sumanth, and Volker Sieber. "Recent Advances in the Direct Synthesis of Hydrogen Peroxide Using Chemical Catalysis—A Review." Catalysts 8, no. 9 (September 5, 2018): 379. http://dx.doi.org/10.3390/catal8090379.

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Hydrogen peroxide is an important chemical of increasing demand in today’s world. Currently, the anthraquinone autoxidation process dominates the industrial production of hydrogen peroxide. Herein, hydrogen and oxygen are reacted indirectly in the presence of quinones to yield hydrogen peroxide. Owing to the complexity and multi-step nature of the process, it is advantageous to replace the process with an easier and straightforward one. The direct synthesis of hydrogen peroxide from its constituent reagents is an effective and clean route to achieve this goal. Factors such as water formation due to thermodynamics, explosion risk, and the stability of the hydrogen peroxide produced hinder the applicability of this process at an industrial level. Currently, the catalysis for the direct synthesis reaction is palladium based and the research into finding an effective and active catalyst has been ongoing for more than a century now. Palladium in its pure form, or alloyed with certain metals, are some of the new generation of catalysts that are extensively researched. Additionally, to prevent the decomposition of hydrogen peroxide to water, the process is stabilized by adding certain promoters such as mineral acids and halides. A major part of today’s research in this field focusses on the reactor and the mode of operation required for synthesizing hydrogen peroxide. The emergence of microreactor technology has helped in setting up this synthesis in a continuous mode, which could possibly replace the anthraquinone process in the near future. This review will focus on the recent findings of the scientific community in terms of reaction engineering, catalyst and reactor design in the direct synthesis of hydrogen peroxide.

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Khan, Zainab, Nicholas F. Dummer, and Jennifer K. Edwards. "Silver–palladium catalysts for the direct synthesis of hydrogen peroxide." Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 376, no. 2110 (November 27, 2017): 20170058. http://dx.doi.org/10.1098/rsta.2017.0058.

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A series of bimetallic silver–palladium catalysts supported on titania were prepared by wet impregnation and assessed for the direct synthesis of hydrogen peroxide, and its subsequent side reactions. The addition of silver to a palladium catalyst was found to significantly decrease hydrogen peroxide productivity and hydrogenation, but crucially increase the rate of decomposition. The decomposition product, which is predominantly hydroxyl radicals, can be used to decrease bacterial colonies. The interaction between silver and palladium was characterized using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy (XPS) and temperature programmed reduction (TPR). The results of the TPR and XPS indicated the formation of a silver–palladium alloy. The optimal 1% Ag–4% Pd/TiO 2 bimetallic catalyst was able to produce approximately 200 ppm of H 2 O 2 in 30 min. The findings demonstrate that AgPd/TiO 2 catalysts are active for the synthesis of hydrogen peroxide and its subsequent decomposition to reactive oxygen species. The catalysts are promising for use in wastewater treatment as they combine the disinfectant properties of silver, hydrogen peroxide production and subsequent decomposition. This article is part of a discussion meeting issue ‘Providing sustainable catalytic solutions for a rapidly changing world’.

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Ntainjua, Edwin N., Simon J. Freakley, and Graham J. Hutchings. "Direct Synthesis of Hydrogen Peroxide Using Ruthenium Catalysts." Topics in Catalysis 55, no. 11-13 (July 25, 2012): 718–22. http://dx.doi.org/10.1007/s11244-012-9866-3.

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Blanco-Brieva, Gema, Frederique Desmedt, Pierre Miquel, Jose Campos-Martin, and Jose Fierro. "Silica Bifunctional Supports for the Direct Synthesis of H2O2: Optimization of Br/Acid Sites and Pd/Br Ratio." Catalysts 12, no. 7 (July 19, 2022): 796. http://dx.doi.org/10.3390/catal12070796.

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We have studied the direct synthesis of hydrogen peroxide using a catalytic system consisting of palladium supported on silica bifunctionalized with sulfonic acid groups and bromide in the absence of acid and halide promoters in solution. Catalysts with several bromide substituents were employed in the catalyst synthesis. The prepared samples were characterized by TXRF, XPS, and hydrogen peroxide decomposition. Catalysts characterization indicated the presence of only palladium (II) species in all of the samples, with similar values for surface and bulk of Pd/Br atomic ratio. The catalysts were tested via direct synthesis, and all samples were able to produce hydrogen peroxide at 313 K and 5.0 MPa. The hydrogen peroxide yield and selectivity changed with the Pd/Br ratio. A decrease in the Pd/Br ratio increases the final hydrogen peroxide concentration, and the selectivity for H2O2 reaches a maximum at a Pd/Br ratio around 0.16 and then decreases. However, the maximum hydrogen peroxide concentration and selectivity occur at slightly different Pd/Br ratios, i.e., resp. 0.4 vs. 0.16.

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Edwards, Jennifer K., James Pritchard, Peter J. Miedziak, Marco Piccinini, Albert F. Carley, Qian He, Christopher J. Kiely, and Graham J. Hutchings. "The direct synthesis of hydrogen peroxide using platinum promoted gold–palladium catalysts." Catal. Sci. Technol. 4, no. 9 (2014): 3244–50. http://dx.doi.org/10.1039/c4cy00496e.

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8

Inoue, Tomoya, Yoshikuni Kikutani, Satoshi Hamakawa, Kazuma Mawatari, Fujio Mizukami, and Takehiko Kitamori. "Reactor design optimization for direct synthesis of hydrogen peroxide." Chemical Engineering Journal 160, no. 3 (June 2010): 909–14. http://dx.doi.org/10.1016/j.cej.2010.02.027.

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Inoue, Tomoya, Kenichiro Ohtaki, Sunao Murakami, and Sohei Matsumoto. "Direct synthesis of hydrogen peroxide based on microreactor technology." Fuel Processing Technology 108 (April 2013): 8–11. http://dx.doi.org/10.1016/j.fuproc.2012.04.009.

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Crole, David A., Simon J. Freakley, Jennifer K. Edwards, and Graham J. Hutchings. "Direct synthesis of hydrogen peroxide in water at ambient temperature." Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 472, no. 2190 (June 2016): 20160156. http://dx.doi.org/10.1098/rspa.2016.0156.

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The direct synthesis of hydrogen peroxide (H 2 O 2 ) from hydrogen and oxygen has been studied using an Au–Pd/TiO 2 catalyst. The aim of this study is to understand the balance of synthesis and sequential degradation reactions using an aqueous, stabilizer-free solvent at ambient temperature. The effects of the reaction conditions on the productivity of H 2 O 2 formation and the undesirable hydrogenation and decomposition reactions are investigated. Reaction temperature, solvent composition and reaction time have been studied and indicate that when using water as the solvent the H 2 O 2 decomposition reaction is the predominant degradation pathway, which provides new challenges for catalyst design, which has previously focused on minimizing the subsequent hydrogenation reaction. This is of importance for the application of this catalytic approach for water purification.

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11

Edwards, Jennifer K., Simon J. Freakley, Richard J. Lewis, James C. Pritchard, and Graham J. Hutchings. "Advances in the direct synthesis of hydrogen peroxide from hydrogen and oxygen." Catalysis Today 248 (June 2015): 3–9. http://dx.doi.org/10.1016/j.cattod.2014.03.011.

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Tang, Ying, and Jin Zhang. "Direct oxidation of benzene to phenol catalyzed by a vanadium-substituted heteropolymolybdic acid catalyst." Journal of the Serbian Chemical Society 71, no. 2 (2006): 111–20. http://dx.doi.org/10.2298/jsc0602111t.

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The direct synthesis of phenol by hydroxylation of benzene with hydrogen peroxide over a vanadium substituted heteropolymolybdic acid catalyst was investigated at 70 ?C. Hydrogen peroxide was used as the oxidant while 36 wt.% acetic acid was employed as the solvent. After 100 minutes, the selectivity for phenol was 93% and the yield of phenol was 10.1 %. The catalyst was characterized by elemental analysis, thermogravimetry, infrared spectroscopy, UV-Vis spectroscopy, X-ray diffraction, and 31P-NMR and 51V-NMR techniques. The experimental conditions, such as reaction temperature, the amount of hydrogen peroxide and catalyst, were investigated. The as-prepared phenol could be separated by column chromatography and was characterized by infrared and mass spectrometry.

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13

PASHKOVA, A., K. SVAJDA, and R. DITTMEYER. "Direct synthesis of hydrogen peroxide in a catalytic membrane contactor." Chemical Engineering Journal 139, no. 1 (May 15, 2008): 165–71. http://dx.doi.org/10.1016/j.cej.2007.09.003.

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14

Edwards, J. K., B. Solsona, E. N. N, A. F. Carley, A. A. Herzing, C. J. Kiely, and G. J. Hutchings. "Switching Off Hydrogen Peroxide Hydrogenation in the Direct Synthesis Process." Science 323, no. 5917 (February 20, 2009): 1037–41. http://dx.doi.org/10.1126/science.1168980.

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15

Han, Geun-Ho, Ki Yoon Kim, Hyunji Nam, Hyeonjin Kim, Jihwan Yoon, Jung-Hyun Lee, Hong-Kyu Kim, et al. "Facile Direct Seed-Mediated Growth of AuPt Bimetallic Shell on the Surface of Pd Nanocubes and Application for Direct H2O2 Synthesis." Catalysts 10, no. 6 (June 10, 2020): 650. http://dx.doi.org/10.3390/catal10060650.

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The selective enhancement of catalytic activity is a challenging task, as catalyst modification is generally accompanied by both desirable and undesirable properties. For example, in the case of the direct synthesis of hydrogen peroxide, Pt on Pd improves hydrogen conversion, but lowers hydrogen peroxide selectivity, whereas Au on Pd enhances hydrogen peroxide selectivity but decreases hydrogen conversion. Toward an ideal catalytic property, the development of a catalyst that is capable of improving H-H dissociation for increasing H2 conversion, whilst suppressing O-O dissociation for high H2O2 selectivity would be highly beneficial. Pd-core AuPt-bimetallic shell nanoparticles with a nano-sized bimetallic layer composed of Au-rich or Pt-rich content with Pd cubes were readily prepared via the direct seed-mediated growth method. In the Pd-core AuPt-bimetallic shell nanoparticles, Au was predominantly located on the {100} facets of the Pd nanocubes, whereas Pt was deposited on the corners of the Pd nanocubes. The evaluation of Pd-core AuPt-bimetallic shell nanoparticles with varying Au and Pt contents revealed that Pd-core AuPt-bimetallic shell that was composed of 2.5 mol% Au and 5 mol% Pt, in relation to Pd, exhibited the highest H2O2 production rate (914 mmol H2O2 gmetal−1 h−1), due to the improvement of both H2O2 selectivity and H2 conversion.

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16

Gu, Junjie, Suli Wang, Zhiyuan He, You Han, and Jinli Zhang. "Direct synthesis of hydrogen peroxide from hydrogen and oxygen over activated-carbon-supported Pd–Ag alloy catalysts." Catalysis Science & Technology 6, no. 3 (2016): 809–17. http://dx.doi.org/10.1039/c5cy00813a.

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A series of bimetallic PdAg catalysts on an activated carbon support were prepared for the direct synthesis of hydrogen peroxide from hydrogen and oxygen. The addition of Ag to Pd caused an increase in selectivity due to ensemble and electronic effects.

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17

Blanco-Brieva, G., M. Montiel-Argaiz, F. Desmedt, P. Miquel, J. M. Campos-Martin, and J. L. G. Fierro. "Direct synthesis of hydrogen peroxide with no ionic halides in solution." RSC Advances 6, no. 101 (2016): 99291–96. http://dx.doi.org/10.1039/c6ra22874g.

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18

Pham, Xuan Thao. "SYNTHESIS OF UREA-HYDROGEN PEROXIDE AND ITS APPLICATION FOR PREPARING THIOSULFINATE." Journal of Science and Technique 15 (April 6, 2020): 5–12. http://dx.doi.org/10.56651/lqdtu.jst.v15.n01.88.

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The Urea-Hydrogen Peroxide complex (UHP) was synthesized from urea and hydrogen peroxide, characterized by FT-IR. This UHP complex could be employed as an oxidizing agent for metal-free oxidation reaction of disulfides to thiosulfinate compounds. This protocol was carried out under very mild conditions at 0oC in CH3CO2H solvent, was efficient and compatible with a range of alkyl, aryl or allyl disulfides to afford direct access to thiosulfinate compounds in very good yields up to 92% and high selectivities.

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19

Arrigo, Rosa, Manfred E. Schuster, Salvatore Abate, Gianfranco Giorgianni, Gabriele Centi, Siglinda Perathoner, Sabine Wrabetz, Verena Pfeifer, Markus Antonietti, and Robert Schlögl. "Pd Supported on Carbon Nitride Boosts the Direct Hydrogen Peroxide Synthesis." ACS Catalysis 6, no. 10 (September 20, 2016): 6959–66. http://dx.doi.org/10.1021/acscatal.6b01889.

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20

Biasi, Pierdomenico, Federica Menegazzo, Francesco Pinna, Kari Eränen, Paolo Canu, and Tapio O. Salmi. "Hydrogen Peroxide Direct Synthesis: Selectivity Enhancement in a Trickle Bed Reactor." Industrial & Engineering Chemistry Research 49, no. 21 (November 3, 2010): 10627–32. http://dx.doi.org/10.1021/ie100550k.

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21

Sun, Mingzi, Xinyue Liu, and Bolong Huang. "Dynamically self-activated catalyst for direct synthesis of hydrogen peroxide (H2O2)." Materials Today Energy 10 (December 2018): 307–16. http://dx.doi.org/10.1016/j.mtener.2018.10.004.

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22

Ratchananusorn, Warin, Davood Gudarzi, and Ilkka Turunen. "Catalytic direct synthesis of hydrogen peroxide in a novel microstructured reactor." Chemical Engineering and Processing: Process Intensification 84 (October 2014): 24–30. http://dx.doi.org/10.1016/j.cep.2014.01.005.

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23

Li, Shuo, Zhansheng Lu, Yi Zhang, Dongwei Ma, and Zongxian Yang. "Mechanisms of direct hydrogen peroxide synthesis on silicon and phosphorus dual-doped graphene: a DFT-D study." Physical Chemistry Chemical Physics 19, no. 13 (2017): 9007–15. http://dx.doi.org/10.1039/c6cp08668c.

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24

Inoue, Tomoya, Martin A. Schmidt, and Klavs F. Jensen. "Microfabricated Multiphase Reactors for the Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen." Industrial & Engineering Chemistry Research 46, no. 4 (February 2007): 1153–60. http://dx.doi.org/10.1021/ie061277w.

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25

Urban, Sebastian, Andreas Weltin, Hubert Flamm, Jochen Kieninger, Benedikt J. Deschner, Manfred Kraut, Roland Dittmeyer, and Gerald A. Urban. "Electrochemical multisensor system for monitoring hydrogen peroxide, hydrogen and oxygen in direct synthesis microreactors." Sensors and Actuators B: Chemical 273 (November 2018): 973–82. http://dx.doi.org/10.1016/j.snb.2018.07.014.

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26

Tan, Xin, Hassan A. Tahini, and Sean C. Smith. "Understanding the high activity of mildly reduced graphene oxide electrocatalysts in oxygen reduction to hydrogen peroxide." Materials Horizons 6, no. 7 (2019): 1409–15. http://dx.doi.org/10.1039/c9mh00066f.

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The direct electrochemical synthesis of hydrogen peroxide (H₂O₂) would provide an attractive alternative to the traditional anthraquinone oxidation process for continuous on-site applications.

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27

Wang, Sheng, Richard J. Lewis, Dmitry E. Doronkin, David J. Morgan, Jan-Dierk Grunwaldt, Graham J. Hutchings, and Silke Behrens. "The direct synthesis of hydrogen peroxide from H2 and O2 using Pd–Ga and Pd–In catalysts." Catalysis Science & Technology 10, no. 6 (2020): 1925–32. http://dx.doi.org/10.1039/c9cy02210d.

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The direct synthesis of hydrogen peroxide is investigated using PdGa/TiO₂ and PdIn/TiO₂ catalysts prepared by an acid-washed sol-immobilisation procedure, which allows for enhanced catalytic selectivity.

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28

Liu, Yawen, Pengzhao Gao, Nikolay Cherkasov, and Evgeny V. Rebrov. "Direct amide synthesis over core–shell TiO2@NiFe2O4 catalysts in a continuous flow radiofrequency-heated reactor." RSC Advances 6, no. 103 (2016): 100997–1007. http://dx.doi.org/10.1039/c6ra22659k.

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A core–shell TiO₂@NiFe₂O₄ catalyst showed high activity and stability in direct amide synthesis with easy regeneration from coke by a treatment with a 30 wt% hydrogen peroxide solution.

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29

Blanco-Brieva, G., F. Desmedt, P. Miquel, J. M. Campos-Martin, and J. L. G. Fierro. "Direct synthesis of hydrogen peroxide without the use of acids or halide promoters in dissolution." Catalysis Science & Technology 10, no. 8 (2020): 2333–36. http://dx.doi.org/10.1039/d0cy00416b.

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30

Han, Geun‐Ho, Seok‐Ho Lee, Seong‐Yeon Hwang, and Kwan‐Young Lee. "Hydrogen Peroxide Synthesis: Advanced Development Strategy of Nano Catalyst and DFT Calculations for Direct Synthesis of Hydrogen Peroxide (Adv. Energy Mater. 27/2021)." Advanced Energy Materials 11, no. 27 (July 2021): 2170104. http://dx.doi.org/10.1002/aenm.202170104.

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31

Kim, Min-Cheol, and Sang Soo Han. "Electrochemically Modeling a Nonelectrochemical System: Hydrogen Peroxide Direct Synthesis on Palladium Catalysts." Journal of Physical Chemistry Letters 12, no. 19 (May 6, 2021): 4490–95. http://dx.doi.org/10.1021/acs.jpclett.1c01223.

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32

Urban, Sebastian, Andreas Weltin, Hubert Flamm, Jochen Kieninger, Benedikt J. Deschner, Manfred Kraut, Roland Dittmeyer, and Gerald A. Urban. "Electrochemical Multisensor System for Monitoring the Hydrogen Peroxide Direct Synthesis in Microreactors." Proceedings 1, no. 4 (August 8, 2017): 630. http://dx.doi.org/10.3390/proceedings1040630.

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33

Edwards, Jennifer K., Albert F. Carley, Andrew A. Herzing, Christopher J. Kiely, and Graham J. Hutchings. "Direct synthesis of hydrogen peroxide from H2and O2using supported Au–Pd catalysts." Faraday Discuss. 138 (2008): 225–39. http://dx.doi.org/10.1039/b705915a.

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34

Kilpiö, Teuvo, Pierdomenico Biasi, Alice Bittante, Tapio Salmi, and Johan Wärnå. "Modeling of Direct Synthesis of Hydrogen Peroxide in a Packed-Bed Reactor." Industrial & Engineering Chemistry Research 51, no. 41 (October 3, 2012): 13366–78. http://dx.doi.org/10.1021/ie301919y.

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35

Solsona, Benjamin E., Jennifer K. Edwards, Philip Landon, Albert F. Carley, Andrew Herzing, Christopher J. Kiely, and Graham J. Hutchings. "Direct Synthesis of Hydrogen Peroxide from H2and O2Using Al2O3Supported Au−Pd Catalysts." Chemistry of Materials 18, no. 11 (May 2006): 2689–95. http://dx.doi.org/10.1021/cm052633o.

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36

Waldt, Conor T., Sahithi Ananthaneni, and Rees B. Rankin. "Towards quaternary alloy Au–Pd catalysts for direct synthesis of hydrogen peroxide." Materials Today Energy 16 (June 2020): 100399. http://dx.doi.org/10.1016/j.mtener.2020.100399.

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37

Ren, Ming-Guang, Mao Mao, Xue-You Duan, and Qin-Hua Song. "Hydrogen peroxide synthesis by direct photoreduction of 2-ethylanthraquinone in aerated solutions." Journal of Photochemistry and Photobiology A: Chemistry 217, no. 1 (January 2011): 164–68. http://dx.doi.org/10.1016/j.jphotochem.2010.10.004.

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38

Inoue, Tomoya, Jiro Adachi, Kenichiro Ohtaki, Ming Lu, Sunao Murakami, Xu Sun, and Dong F. Wang. "Direct hydrogen peroxide synthesis using glass microfabricated reactor – Paralleled packed bed operation." Chemical Engineering Journal 278 (October 2015): 517–26. http://dx.doi.org/10.1016/j.cej.2014.11.019.

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39

MELADA, S., R. RIODA, F. MENEGAZZO, F. PINNA, and G. STRUKUL. "Direct synthesis of hydrogen peroxide on zirconia-supported catalysts under mild conditions." Journal of Catalysis 239, no. 2 (April 25, 2006): 422–30. http://dx.doi.org/10.1016/j.jcat.2006.02.014.

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40

Wang, Sheng, Dmitry E. Doronkin, Martin Hähsler, Xiaohui Huang, Di Wang, Jan‐Dierk Grunwaldt, and Silke Behrens. "Palladium‐Based Bimetallic Nanocrystal Catalysts for the Direct Synthesis of Hydrogen Peroxide." ChemSusChem 13, no. 12 (May 11, 2020): 3243–51. http://dx.doi.org/10.1002/cssc.202000407.

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41

Ntainjua, Edwin N., Marco Piccinini, James C. Pritchard, Jennifer K. Edwards, Albert F. Carley, Christopher J. Kiely, and Graham J. Hutchings. "Direct synthesis of hydrogen peroxide using ceria-supported gold and palladium catalysts." Catalysis Today 178, no. 1 (December 2011): 47–50. http://dx.doi.org/10.1016/j.cattod.2011.06.024.

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42

Fan, Shuangshuang, Jianhua Yi, Li Wang, and Zhentao Mi. "Direct synthesis of hydrogen peroxide from H2/O2 using Pd/Al2O3 catalysts." Reaction Kinetics and Catalysis Letters 92, no. 1 (September 21, 2007): 175–82. http://dx.doi.org/10.1007/s11144-007-5062-z.

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43

Edwards, Jennifer K., James Pritchard, Li Lu, Marco Piccinini, Greg Shaw, Albert F. Carley, David J. Morgan, Christopher J. Kiely, and Graham J. Hutchings. "The Direct Synthesis of Hydrogen Peroxide Using Platinum-Promoted Gold-Palladium Catalysts." Angewandte Chemie 126, no. 9 (January 29, 2014): 2413–16. http://dx.doi.org/10.1002/ange.201308067.

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44

Guo, Yu, Yujia Jin, Hongmei Wu, Dongxin Li, Xianfeng Fan, Lidai Zhou, and Xiongfu Zhang. "Direct synthesis of propylene oxide using hydrogen peroxide in a membrane reactor." Chemical Papers 71, no. 1 (December 2, 2016): 49–57. http://dx.doi.org/10.1007/s11696-016-0035-1.

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45

Edwards, Jennifer K, and Graham J Hutchings. "Palladium and Gold-Palladium Catalysts for the Direct Synthesis of Hydrogen Peroxide." Angewandte Chemie International Edition 47, no. 48 (September 16, 2008): 9192–98. http://dx.doi.org/10.1002/anie.200802818.

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46

Edwards, Jennifer K., James Pritchard, Li Lu, Marco Piccinini, Greg Shaw, Albert F. Carley, David J. Morgan, Christopher J. Kiely, and Graham J. Hutchings. "The Direct Synthesis of Hydrogen Peroxide Using Platinum-Promoted Gold-Palladium Catalysts." Angewandte Chemie International Edition 53, no. 9 (January 29, 2014): 2381–84. http://dx.doi.org/10.1002/anie.201308067.

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47

Lee, Jong Won, Jeong Kwon Kim, Tae Hun Kang, and In Kyu Song. "Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen Over Size-Controlled Palladium Nanocube Catalysts." Journal of Nanoscience and Nanotechnology 16, no. 10 (October 1, 2016): 10426–30. http://dx.doi.org/10.1166/jnn.2016.13172.

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48

Hu, Bizhong, Weiping Deng, Rongsheng Li, Qinghong Zhang, Ye Wang, Francine Delplanque-Janssens, Deschrijver Paul, Frederique Desmedt, and Pierre Miquel. "Carbon-supported palladium catalysts for the direct synthesis of hydrogen peroxide from hydrogen and oxygen." Journal of Catalysis 319 (November 2014): 15–26. http://dx.doi.org/10.1016/j.jcat.2014.08.001.

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49

Park, Sunyoung, Sang Hee Lee, Sun Ho Song, Dong Ryul Park, Sung-Hyeon Baeck, Tae Jin Kim, Young-Min Chung, Seung-Hoon Oh, and In Kyu Song. "Direct synthesis of hydrogen peroxide from hydrogen and oxygen over palladium-exchanged insoluble heteropolyacid catalysts." Catalysis Communications 10, no. 4 (January 2009): 391–94. http://dx.doi.org/10.1016/j.catcom.2008.10.002.

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50

Chen, Zheng, Hongyan Pan, Qian Lin, Xin Zhang, Sheng Xiao, and Shun He. "The modification of Pd core–silica shell catalysts by functional molecules (KBr, CTAB, SC) and their application to the direct synthesis of hydrogen peroxide from hydrogen and oxygen." Catalysis Science & Technology 7, no. 6 (2017): 1415–22. http://dx.doi.org/10.1039/c7cy00105c.

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Pd core–silica shell catalysts were prepared with different functional molecules. The catalyst Pd_KBr@SiO₂ had the highest H₂O₂ selectivity and productivity in the direct synthesis of hydrogen peroxide.

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Journal articles on the topic 'Hydrogen peroxide direct synthesis'

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