Academic literature on the topic 'Hydroamination'
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Journal articles on the topic "Hydroamination"
Tobisch, Sven. "CuH-catalysed hydroamination of arylalkynes with hydroxylamine esters – a computational scrutiny of rival mechanistic pathways." Chemical Science 8, no. 6 (2017): 4410–23. http://dx.doi.org/10.1039/c7sc01107e.
Full textLi, Ping, Boon Chong Lee, Ming Joo Koh, and Xiaoxiang Zhang. "Base-Mediated Site-Selective Hydroamination of Alkenes." Synthesis 54, no. 06 (October 28, 2021): 1566–76. http://dx.doi.org/10.1055/a-1681-4720.
Full textYang, Song, Quan-Zhe Li, Chen Xu, Qin Xu, and Min Shi. "Rhodium-catalyzed asymmetric hydroamination and hydroindolation of keto-vinylidenecyclopropanes." Chemical Science 9, no. 22 (2018): 5074–81. http://dx.doi.org/10.1039/c8sc01595c.
Full textTobisch, Sven. "Aluminium-catalysed intramolecular hydroamination of aminoalkenes: computational perusal of alternative pathways for aminoalkene activation." Dalton Transactions 44, no. 27 (2015): 12169–79. http://dx.doi.org/10.1039/c5dt00121h.
Full textPalchak, Zachary L., Daniel J. Lussier, Conor J. Pierce, Hoseong Yoo, and Catharine H. Larsen. "Catalytic Tandem Markovnikov Hydroamination-Alkynylation and Markovnikov Hydroamination-Hydrovinylation." Advanced Synthesis & Catalysis 357, no. 2-3 (January 30, 2015): 539–48. http://dx.doi.org/10.1002/adsc.201401037.
Full textSuleymanov, Yury. "Anti-Markovnikov hydroamination." Science 366, no. 6467 (November 14, 2019): 834.2–834. http://dx.doi.org/10.1126/science.366.6467.834-b.
Full textHong, Sukwon, and Tobin J. Marks. "Organolanthanide-Catalyzed Hydroamination." Accounts of Chemical Research 37, no. 9 (September 2004): 673–86. http://dx.doi.org/10.1021/ar040051r.
Full textOgasawara, M., T. Takahashi, W. Lin, A. Hu, T. Sakamoto, A. Okada, and K. Nakajima. "Intermolecular Asymmetric Hydroamination." Synfacts 2007, no. 1 (January 2007): 0049. http://dx.doi.org/10.1055/s-2006-955723.
Full textShibuya, Masatoshi, Shohei Kawano, Shoji Fujita, and Yoshihiko Yamamoto. "Boron‐Catalyzed Hydroamination/Hydroallylation and Hydroamination/Hydrocyanation of Unactivated Alkynes." Asian Journal of Organic Chemistry 8, no. 7 (May 21, 2019): 1075–79. http://dx.doi.org/10.1002/ajoc.201900165.
Full textCasnati, Alessandra, Aleksandr Voronov, Damiano Giuseppe Ferrari, Raffaella Mancuso, Bartolo Gabriele, Elena Motti, and Nicola Della Ca’. "PdI2 as a Simple and Efficient Catalyst for the Hydroamination of Arylacetylenes with Anilines." Catalysts 10, no. 2 (February 2, 2020): 176. http://dx.doi.org/10.3390/catal10020176.
Full textDissertations / Theses on the topic "Hydroamination"
Shasha, Adelle. "Metal-Catalysed Hydroamination." Science. School of Chemistry, 2007. http://hdl.handle.net/2123/1710.
Full textThis thesis describes the synthesis of terminal and internal amino and amidoalkynes and their hydroamination (cyclisation) catalysed by the complex (bis(N-methylimidazol-2-yl)methane)dicarbonylrhodium(I) tetraphenylborate (1). A series of analogous palladium complexes were also prepared and investigated for catalytic hydroamination. The scope of the rhodium(I) complex (1) for the intramolecular hydroamination of more complex amino and amidoalkyne substrates was investigated. This was made possible with the synthesis of aliphatic substrates, namely, 4 pentyn 1 amide (3) and 5 hexyn 1 amide (4) and a number of aromatic substrates, namely, 1, 4 diamino-2, 5 diethynylbenzene (5), 1, 4-diamino-2, 5 bis(phenylethynyl)benzene (6), 2, 3-diamino-1, 4-diethynylbenzene (7), 2, 3-diamino-1, 4-bis(phenylethynyl)benzene (8), 1, 5-bis(acetamido)-2, 4-diethynylbenzene (9), N-(acetyl)-2-ethynylbenzylamine (10) and N-(acetyl)-2-(phenylethynyl)benzylamine (11). The rhodium(I) complex (1) catalytically cyclised the aliphatic 4 pentyn 1 amide (3) regioselectively to the 6 membered ring, 3, 4 dihydro 2 pyridone (64) as the sole product. Attempts to cyclise 5 hexyn 1 amide (4) to produce either the 6 or 7 membered ring were unsuccessful. Compounds 5, 6, 7 and 8 were doubly cyclised to 1, 5 dihydro pyrrolo[2, 3 f]indole (71), 1, 5-dihydro-2, 6-diphenyl-pyrrolo[2, 3 f]indole (73), 1, 8-dihydro-pyrrolo[2, 3 g]indole (74) and 1, 8-dihydro-2, 7-diphenyl-pyrrolo[2, 3 g]indole (75) respectively. The aromatic amides with terminal acetylenes 9 and 10 cyclised to give 1, 7 diacetyl pyrrolo[3, 2 f]indole (76) and N (acetyl) 1, 2 dihydroisoquinoline (77) respectively. However, attempts to cyclise 11 were unsuccessful. Thus the rhodium(I) complex (1) successfully catalysed via hydroamination both terminal and internal acetylenic amine and amide substrates, to give pyridones, indoles and isoquinolines. Cationic and neutral palladium complexes incorporating the bidentate heterocyclic nitrogen donor ligand bis(N-methylimidazol-2-yl)methane (bim; 2) were synthesised: [Pd(bim)Cl2] (15), [Pd(bim)2][BF4]2 (17) [Pd(bim)(Cl)(CH3)] (14), [Pd(bim)(CH3)(NCCH3)][BF4] (16). All of the complexes were active as catalysts for the intramolecular hydroamination reaction, using the cyclisation of 4 pentyn 1 amine (21) to 2 methyl 1 pyrroline (22) as the model test reaction. Percentage conversions, turnover numbers and reaction profiles for each complex were compared to the rhodium(I) complex (1). These studies have shown that the catalytic activity was not significantly dependent on the bim donor ligand or the choice of metal. Substitution of the bim (2) ligand with the COD ligand and the use of methanol as the solvent did impact significantly on the efficiency of the hydroamination reactions.
Shasha, Adelle. "Metal-Catalysed Hydroamination." Thesis, The University of Sydney, 2006. http://hdl.handle.net/2123/1710.
Full textPenzien, Jochen. "New heterogeneous catalysts for hydroamination reactions." [S.l. : s.n.], 2002. http://deposit.ddb.de/cgi-bin/dokserv?idn=964639076.
Full textJiménez, Silva Oriol. "Novel heterogeneous catalysts for intermolecular hydroamination reactions." [S.l.] : [s.n.], 2006. http://mediatum2.ub.tum.de/doc/601479/document.pdf.
Full textCouce, Ríos Almudena. "Mechanistic insights into metal-catalyzed hydroamination reactions." Doctoral thesis, Universitat Autònoma de Barcelona, 2017. http://hdl.handle.net/10803/403762.
Full textThe topic of this thesis is the DFT study of the mechanism of intermolecular hydroaminations catalyzed by rhodium and gold catalyst. The nitrogen-containing compounds are very valuable and have a lot of uses ranging from pharmaceutical to chemical. The hydroamination reaction is the most economical pathway to synthesize substituted amines. Metal catalysts developed for direct hydroamination includes lanthanides, as well as early and late transition metals. The most versatile catalysts for the intermolecular hydroamination are based on late transition metals. There are a lot of studies published in recent years about this reaction, but despite the effort some questions remain open. The main challenges of hydroamination reactions are the use of simple amines and unactivated substrates, the intermolecular version, the control of regioselectivity (especially the anti-Markovnikov version) and the asymmetrical version. In this thesis we mainly focused on the study of the control of regioselectivity in the intermolecular version of this reaction and an asymmetric process. The first and second chapters are an introduction to the subject and a theoretical explanation of all the topics used in this thesis. In the third chapter are collected the points this work pretends to achieve, in the fourth chapter we studied an anti-Markovnikov hydroamination of alkenes catalyzed by a rhodium catalyst developed by Hartwig et al. The fifth chapter deals with the enantioselective hydroamination of allenes catalyzed by a rhodium catalyst. The system developed by Breit and coworkers has been chosen for our study. The sixth chapter is devoted to the hydroamination reaction of alkynes, alkenes and allenes with hydrazine catalyzed by three different cationic gold catalysts developed by Bertrand and Hasmi’s groups. In the seventh chapter we studied an Au-catalyzed anti-Markovnikov hydroamination. The Widenhoefer system has been selected since is the only example in the literature. The last chapter of this thesis includes a brief conclusion and summary of the outcome of the work carried out.
Shanbhag, G. V. "Studies on hydroamination reactions using heterogeneous catalysts." Thesis(Ph.D.), CSIR-National Chemical Laboratory, Pune, 2008. http://dspace.ncl.res.in:8080/xmlui/handle/20.500.12252/2626.
Full textAbadie, Marc-Antoine. "Hydroamination intramoléculaire asymétrique d'alcènes catalysée à l'or." Thesis, Lille 1, 2014. http://www.theses.fr/2014LIL10065/document.
Full textThe intramolecular gold catalyzed asymmetric hydroamination of alkenes was studied screening a series of mononuclear gold(I) and (III) complexes in combination with silver salts. Among the various chiral phosphine and diaminocarbene ligands tried, the best catalysts arose from mononuclear gold(I) complexes synthesized from BINOL based phosphoramidite ligands. The latest were improved by addition of bulky substituents at specific positions of the BINOL scaffold. The resulting gold(I) complexes were combined with selected silver salts to afford efficient catalysts for intramolecular hydroamination of alkenes at mild temperatures, with good conversions and average enantioselectivities. Afterwards binuclear gold(I) complexes were investigated as catalysts for the intramolecular asymmetric hydroamination of alkenes. When combined to a silver salt, selected diphosphine binuclear gold(I) chloride complex afforded chiral amines for the first time in high conversions and enantioselectivities, within mild conditions and the presence of water. Both enantiomers of the products could be obtained by controlling the molecular ion-pairs through the solvent polarity. The gold(I) cationic active species was characterized for the first time unambiguously at the solid state by X-ray analysis and in solution by DOSY 1H NMR experiments. No contribution of silver chloride was observed on the bonding mode of the catalyst
Abadie, Marc-Antoine. "Hydroamination intramoléculaire asymétrique d'alcènes catalysée à l'or." Electronic Thesis or Diss., Lille 1, 2014. http://www.theses.fr/2014LIL10065.
Full textThe intramolecular gold catalyzed asymmetric hydroamination of alkenes was studied screening a series of mononuclear gold(I) and (III) complexes in combination with silver salts. Among the various chiral phosphine and diaminocarbene ligands tried, the best catalysts arose from mononuclear gold(I) complexes synthesized from BINOL based phosphoramidite ligands. The latest were improved by addition of bulky substituents at specific positions of the BINOL scaffold. The resulting gold(I) complexes were combined with selected silver salts to afford efficient catalysts for intramolecular hydroamination of alkenes at mild temperatures, with good conversions and average enantioselectivities. Afterwards binuclear gold(I) complexes were investigated as catalysts for the intramolecular asymmetric hydroamination of alkenes. When combined to a silver salt, selected diphosphine binuclear gold(I) chloride complex afforded chiral amines for the first time in high conversions and enantioselectivities, within mild conditions and the presence of water. Both enantiomers of the products could be obtained by controlling the molecular ion-pairs through the solvent polarity. The gold(I) cationic active species was characterized for the first time unambiguously at the solid state by X-ray analysis and in solution by DOSY 1H NMR experiments. No contribution of silver chloride was observed on the bonding mode of the catalyst
Ng, Peter J. "Directed Organocatalytic Intermolecular Cope-type Hydroamination of Alkenes." Thèse, Université d'Ottawa / University of Ottawa, 2011. http://hdl.handle.net/10393/19895.
Full textRizk, Toni. "Synthesis of pyridines and pyrazines using intramolecular hydroamination." Thesis, University of Ottawa (Canada), 2010. http://hdl.handle.net/10393/28453.
Full textBooks on the topic "Hydroamination"
Antonio, Togni, and Grützmacher Hansjörg, eds. Catalytic heterofunctionalization: From hydroanimation [i.e. hydroamination] to hydrozirconation. Weinheim: Wiley-VCH, 2001.
Find full textHultzsch, K. C. Hydroamination and Hydroaminoalkylation Reaction. Wiley & Sons, Limited, John, 2021.
Find full textTogni, Antonio, and Hansjörg Grützmacher. Catalytic Heterofunctionalization: From Hydroamination to Hydrozirconization. Wiley & Sons, Incorporated, John, 2001.
Find full textTogni, Antonio, and Hansjörg Grützmacher. Catalytic Heterofunctionalization: From Hydroamination to Hydrozirconization. Wiley & Sons, Incorporated, John, 2020.
Find full textBook chapters on the topic "Hydroamination"
Reznichenko, Alexander L., and Kai C. Hultzsch. "Asymmetric Hydroamination." In Chiral Amine Synthesis, 341–75. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2010. http://dx.doi.org/10.1002/9783527629541.ch11.
Full textReznichenko, Alexander L., Agnieszka J. Nawara-Hultzsch, and Kai C. Hultzsch. "Asymmetric Hydroamination." In Stereoselective Formation of Amines, 191–260. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/128_2013_500.
Full textLi, Tianshu, Jelena Wiecko, and Peter W. Roesky. "Zinc-Catalyzed Hydroamination Reactions." In Zinc Catalysis, 83–118. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2015. http://dx.doi.org/10.1002/9783527675944.ch5.
Full textNishina, Naoko, and Yoshinori Yamamoto. "Late Transition Metal-Catalyzed Hydroamination." In Hydrofunctionalization, 115–43. Berlin, Heidelberg: Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/3418_2012_31.
Full textSchafer, Laurel L., Jacky C. H. Yim, and Neal Yonson. "Transition-Metal-Catalyzed Hydroamination Reactions." In Metal-Catalyzed Cross-Coupling Reactions and More, 1135–258. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527655588.ch15.
Full textChen, Zhiwei, and Vy M. Dong. "Rhodium(I)-Catalyzed Hydroformylation and Hydroamination." In Rhodium Catalysis in Organic Synthesis, 49–62. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2019. http://dx.doi.org/10.1002/9783527811908.ch3.
Full textFärber, T., Arno Behr, and Andreas J. Vorholt. "Hydroamination and Telomerisation of β-Myrcene." In Catalysis by Metal Complexes, 177–89. Cham: Springer International Publishing, 2017. http://dx.doi.org/10.1007/978-3-319-54161-7_10.
Full textArcadi, Antonio. "Gold-Catalyzed Synthesis of Nitrogen Heterocyclic Compounds via Hydroamination Reactions." In Topics in Heterocyclic Chemistry, 53–85. Cham: Springer International Publishing, 2015. http://dx.doi.org/10.1007/7081_2015_5001.
Full textJimenez, Oriol, Thomas E. Müller, and Johannes A. Lercher. "Tailoring Adsorption-Desorption Properties of Hydroamination Catalysts with Ionic Liquids." In ACS Symposium Series, 267–80. Washington, DC: American Chemical Society, 2007. http://dx.doi.org/10.1021/bk-2007-0950.ch021.
Full textJulian, Lisa D. "Synthesis of Saturated Heterocycles via Metal-Catalyzed Alkene Hydroamination or Hydroalkoxylation Reactions." In Topics in Heterocyclic Chemistry, 109–55. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/7081_2013_105.
Full textConference papers on the topic "Hydroamination"
Seijas, Julio, M. Vazquez-Tato, Luis Barreiro-Castro, and Raquel Romero-Van-der-Schoot. "Hydroamination of Cinnamyl Alcohol." In The 3rd International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 1999. http://dx.doi.org/10.3390/ecsoc-3-01736.
Full textSeijas, Julio, M. Vazquez-Tato, and M. Martinez. "Microwave Enhanced Hydroamination of Styrene." In The 3rd International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 1999. http://dx.doi.org/10.3390/ecsoc-3-01733.
Full textLavilla, Rodolfo, Federica Catti, Davide Bello, and Edgar Báguena. "Hydroamination of alkynes as a new source of Imines for Ugi MCRs - Scope and Limitations." In The 12th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01231.
Full textMerican, Zulkifli, Bao Khanh Vu, Vera A. Solovyeva, Valentin O. Rodionov, Cheng Seong Khe, Sokkalingam Rajalingam, and Pandian Vasant. "Fluorocarbon compatibilized gold-silica nanocomposites for recyclable regioselective hydroamination of alkynes in a fluorous biphasic system." In 4TH INTERNATIONAL CONFERENCE ON FUNDAMENTAL AND APPLIED SCIENCES (ICFAS2016). Author(s), 2016. http://dx.doi.org/10.1063/1.4968079.
Full textReports on the topic "Hydroamination"
Hovey, Megan. Ligand strategies for green chemistry. Catalysts for amide reduction and hydroamination. Office of Scientific and Technical Information (OSTI), January 2014. http://dx.doi.org/10.2172/1226561.
Full textBertrand, Guy. Ammonia and hydrazine. Transition-metal-catalyzed hydroamination and metal-free catalyzed functionalization. Office of Scientific and Technical Information (OSTI), June 2012. http://dx.doi.org/10.2172/1253630.
Full textManna, Kuntal. Transition metal complexes of oxazolinylboranes and cyclopentadienyl-bis(oxazolinyl)borates: Catalysts for asymmetric olefin hydroamination and acceptorless alcohol decarbonylation. Office of Scientific and Technical Information (OSTI), December 2012. http://dx.doi.org/10.2172/1082975.
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