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Journal articles on the topic 'Hybrid Halide Perovskites'

Author: Grafiati

Published: 6 September 2023

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1

Marchenko, Ekaterina I., Sergey A. Fateev, Eugene A. Goodilin, and Alexey B. Tarasov. "Band Gap and Topology of 1D Perovskite-Derived Hybrid Lead Halide Structures." Crystals 12, no. 5 (May 4, 2022): 657. http://dx.doi.org/10.3390/cryst12050657.

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The unprecedented structural flexibility of hybrid halide perovskites is accompanied by a wide range of useful optoelectronic properties, causing a high interest in this family of materials. However, there are no systematic studies yet on the relationships between the topology of structures derived of chain 1D hybrid halide perovskites and their optoelectronic properties such as the band gap as already reported for 3D and 2D hybrid halide perovskites. In the present work, we introduce a rational classification of hybrid lead iodide 1D structures. We provide a theoretical assessment of the relationship between the topology of 1D hybrid halide perovskite-derived structures with vertex-connected octahedra and show that the distortions of geometry of the chains of PbI6 octahedra are the main parameters affecting the band gap value while the distance between the chains of vertex-connected octahedra has a minor effect on the band gap.

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2

Ben Haj Salah, Maroua, Justine Tessier, Nicolas Mercier, Magali Allain, Antonin Leblanc, Xiaoyang Che, Claudine Katan, and Mikael Kepenekian. "A 3D Lead Iodide Hybrid Based on a 2D Perovskite Subnetwork." Crystals 11, no. 12 (December 16, 2021): 1570. http://dx.doi.org/10.3390/cryst11121570.

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Lead halide perovskites have emerged as promising materials for various optoelectronic applications. For photovoltaics, the reference compound is the 3D perovskite (MA)PbI3 (MA+ = methylammonium). However, this material suffers from instabilities towards humidity or light. This makes the search of new stable 3D lead halide materials very relevant. A strategy is the use of intermediate size cations instead of MA, which are not suitable to form the 3D ABX3 perovskites or 2D perovskites. Here, we report on a novel 3D metal halide hybrid material based on the intermediate size cation hydroxypropylammonium (HPA+), (HPA)6(MA)Pb5I17. We will see that extending the carbon chain length from two CH2 units (in the hydroxylethylammonium cation, HEA+) to three (HPA+) precludes the formation of a perovskite network as found in the lead and iodide deficient perovskite (HEA,MA)1+xPbxI3−x. In (HPA)6(MA)Pb5I17 the 3D lead halide network results from a 2D perovskite subnetworks linked by a PbI6 octahedra sharing its faces. DFT calculations confirm the direct band gap and reveal the peculiar band structure of this 3D network. On one hand the valence band has a 1D nature involving the p orbitals of the halide. On the other, the conduction band possesses a clear 2D character involving hybridization between the p orbitals of the metal and the halide.

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3

McDonald, Calum, Chengsheng Ni, Paul Maguire, Paul Connor, John Irvine, Davide Mariotti, and Vladimir Svrcek. "Nanostructured Perovskite Solar Cells." Nanomaterials 9, no. 10 (October 18, 2019): 1481. http://dx.doi.org/10.3390/nano9101481.

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Over the past decade, lead halide perovskites have emerged as one of the leading photovoltaic materials due to their long carrier lifetimes, high absorption coefficients, high tolerance to defects, and facile processing methods. With a bandgap of ~1.6 eV, lead halide perovskite solar cells have achieved power conversion efficiencies in excess of 25%. Despite this, poor material stability along with lead contamination remains a significant barrier to commercialization. Recently, low-dimensional perovskites, where at least one of the structural dimensions is measured on the nanoscale, have demonstrated significantly higher stabilities, and although their power conversion efficiencies are slightly lower, these materials also open up the possibility of quantum-confinement effects such as carrier multiplication. Furthermore, both bulk perovskites and low-dimensional perovskites have been demonstrated to form hybrids with silicon nanocrystals, where numerous device architectures can be exploited to improve efficiency. In this review, we provide an overview of perovskite solar cells, and report the current progress in nanoscale perovskites, such as low-dimensional perovskites, perovskite quantum dots, and perovskite-nanocrystal hybrid solar cells.

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4

Jiang, Wenhao. "Design and Development of Hybrid Halide Perovskites in Laser Devices." Highlights in Science, Engineering and Technology 27 (December 27, 2022): 311–18. http://dx.doi.org/10.54097/hset.v27i.3772.

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Organic-inorganic hybrid halide perovskite is a significant semiconductor material in photonics. Their outstanding optoelectronic characteristics have been reported, increasing energy conversion efficiency of perovskite solar battery by up to 25.5%, which is expected to be major competitors in silicon industry. According to the fundamentals of physics, a viable candidate for a light emitter must really be a superior direct band gap material. Even though there are a lot of papers on perovskite-based light emitting devices in this area, the corresponding laser devices are still lack of research. Here, since the first publication of lasing in hybrid perovskites in the 1990s, great effort has been made especially in 2014. Halide perovskites have the potential to revolutionize the nanophotonics field due to their solution-processed gain medium, almost defect-free semiconductor formation, high luminous efficiency, flexibility of nanostructure, excellent stability, and wide wavelength tunability. This article highlights the important researches on the optical gain from diverse hybrid halide perovskite material and the future challenges of lasing.

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5

Cheng, Ling, and Yingjie Cao. "A two-dimensional organic–inorganic hybrid perovskite-type semiconductor: poly[(2-azaniumylethyl)trimethylphosphanium [tetra-μ-bromido-plumbate(II)]]." Acta Crystallographica Section C Structural Chemistry 75, no. 3 (February 21, 2019): 354–58. http://dx.doi.org/10.1107/s2053229619001712.

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Recently, with the prevalence of `perovskite fever', organic–inorganic hybrid perovskites (OHPs) have attracted intense attention due to their remarkable structural variability and highly tunable properties. In particular, the optical and electrical properties of organic–inorganic hybrid lead halides are typical of the OHP family. Besides, although three-dimensional hybrid perovskites, such as [CH3NH3]PbX 3 (X = Cl, Br or I), have been reported, the development of new organic–inorganic hybrid semiconductors is still an area in urgent need of exploration. Here, an organic–inorganic hybrid lead halide perovskite is reported, namely poly[(2-azaniumylethyl)trimethylphosphanium [tetra-μ-bromido-plumbate(II)]], {(C5H16NP)[PbBr4]} n , in which an organic cation is embedded in inorganic two-dimensional (2D) mesh layers to produce a sandwich structure. This unique sandwich 2D hybrid perovskite material shows an indirect band gap of ∼2.700 eV. The properties of this compound as a semiconductor are demonstrated by a series of optical characterizations and indicate potential applications for optical devices.

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6

García, Teresa, Rocío García-Aboal, Josep Albero, Pedro Atienzar, and Hermenegildo García. "Vapor-Phase Photocatalytic Overall Water Splitting Using Hybrid Methylammonium Copper and Lead Perovskites." Nanomaterials 10, no. 5 (May 18, 2020): 960. http://dx.doi.org/10.3390/nano10050960.

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Films or powders of hybrid methylammonium copper halide perovskite exhibit photocatalytic activity for overall water splitting in the vapor phase in the absence of any sacrificial agent, resulting in the generation of H2 and O2, reaching a maximum production rate of 6 μmol H2 × g cat−1h−1 efficiency. The photocatalytic activity depends on the composition, degreasing all inorganic Cs2CuCl2Br2 perovskite and other Cl/Br proportions in the methylammonium hybrids. XRD indicates that MA2CuCl2Br2 is stable under irradiation conditions in agreement with the linear H2 production with the irradiation time. Similar to copper analogue, hybrid methylammonium lead halide perovskites also promote the overall photocatalytic water splitting, but with four times less efficiency than the Cu analogues. The present results show that, although moisture is strongly detrimental to the photovoltaic applications of hybrid perovskites, it is still possible to use these materials as photocatalysts for processes requiring moisture due to the lack of relevance in the photocatalytic processes of interparticle charge migration.

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7

Cheng, Dan, Zhaohai Yang, and Yilan Liang. "Preparation and Energy Storage Performance of Perovskite Luminescent Materials by an Electrochemiluminescence Method." Adsorption Science & Technology 2022 (October 3, 2022): 1–10. http://dx.doi.org/10.1155/2022/3092941.

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In recent years, metal halide perovskites have become attractive photosensitive materials due to their excellent optoelectronic properties. Due to its good characteristics, perovskites are used in solar photovoltaic power generation, light-emitting diodes, photodetectors, photocatalysis, and sensors and many other fields. Considering the wide application of perovskites and the study of potential bifunctional devices, the application of perovskites in energy storage devices is relatively small, and a small number of studies focus on organic-inorganic hybrid lead-halide perovskites. However, the related energy storage research on all-inorganic lead-halide perovskites with better stability, which has also been widely concerned, is very scarce. And nontoxic all-inorganic nonperovskite has zero research in energy storage. Based on the above situation, this paper selects the lead-free perovskite Cs2AgSbCl6, and two lead halide perovskites with different dimensions, -0-dimensional Cs4PbBr6 and 3-dimensional CsPbBr3, these three all-inorganic perovskites. It was for electrochemical performance testing.

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8

Mozur, Eve M., and James R. Neilson. "Cation Dynamics in Hybrid Halide Perovskites." Annual Review of Materials Research 51, no. 1 (July 26, 2021): 269–91. http://dx.doi.org/10.1146/annurev-matsci-080819-012808.

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Hybrid halide perovskite semiconductors exhibit complex, dynamical disorder while also harboring properties ideal for optoelectronic applications that include photovoltaics. However, these materials are structurally and compositionally distinct from traditional compound semiconductors composed of tetrahedrally coordinated elements with an average valence electron count of silicon. The additional dynamic degrees of freedom of hybrid halide perovskites underlie many of their potentially transformative physical properties. Neutron scattering and spectroscopy studies of the atomic dynamics of these materials have yielded significant insights into their functional properties. Specifically, inelastic neutron scattering has been used to elucidate the phonon band structure, and quasi-elastic neutron scattering has revealed the nature of the uncorrelated dynamics pertaining to molecular reorientations. Understanding the dynamics of these complex semiconductors has elucidated the temperature-dependent phase stability and origins of defect-tolerant electronic transport from the highly polarizable dielectric response. Furthermore, the dynamic degrees of freedom of the hybrid perovskites provide additional opportunities for application engineering and innovation.

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9

Albero, Josep, and Hermenegildo García. "Luminescence control in hybrid perovskites and their applications." Journal of Materials Chemistry C 5, no. 17 (2017): 4098–110. http://dx.doi.org/10.1039/c7tc00714k.

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Hybrid metal halide perovskites have emerged as promising photoluminescence materials in efficient light emitting devices and lasing applications. The review focus on the perovskite composition design as a tool to modulate the luminescence properties.

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10

Shin, Jiwon, Kyeong-Yoon Baek, Jonghoon Lee, Woocheol Lee, Jaeyoung Kim, Juntae Jang, Jaehyoung Park, Keehoon Kang, Kyungjune Cho, and Takhee Lee. "Proton irradiation effects on mechanochemically synthesized and flash-evaporated hybrid organic–inorganic lead halide perovskites." Nanotechnology 33, no. 6 (November 18, 2021): 065706. http://dx.doi.org/10.1088/1361-6528/ac34a7.

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Abstract A hybrid organic–inorganic halide perovskite is a promising material for developing efficient solar cell devices, with potential applications in space science. In this study, we synthesized methylammonium lead iodide (MAPbI3) perovskites via two methods: mechanochemical synthesis and flash evaporation. We irradiated these perovskites with highly energetic 10 MeV proton-beam doses of 1011, 1012, 1013, and 4 × 1013 protons cm−2 and examined the proton irradiation effects on the physical properties of MAPbI3 perovskites. The physical properties of the mechanochemically synthesized MAPbI3 perovskites were not considerably affected after proton irradiation. However, the flash-evaporated MAPbI3 perovskites showed a new peak in x-ray diffraction and an increased fluorescence lifetime in time-resolved photoluminescence under high-dose conditions, indicating considerable changes in their physical properties. This difference in behavior between MAPbI3 perovskites synthesized via the abovementioned two methods may be attributed to differences in radiation hardness associated with the bonding strength of the constituents, particularly Pb–I bonds. Our study will help to understand the radiation effect of proton beams on organometallic halide perovskite materials.

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11

Kalaph, Kawther A., Aqel Mashot Jafar, Nisreen Kh Abdalameer, and Amar Moula Hmood. "A Review on Recent Advances in Materials of Hybrid Organic–Inorganic Perovskite Solar Cells." Iraqi Journal of Industrial Research 9, no. 2 (October 20, 2022): 148–58. http://dx.doi.org/10.53523/ijoirvol9i2id181.

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This study is an emphasis on the metal halide perovskite solar cells that are susceptible to factors that influence their power conversion efficiency (PCE). Perovskite solar cells, also known as PSCs, have been shown to have a high power conversion efficiency (PCE) due to a number of various factors. As they reached a power conversion efficiency of 25%, solar cells based on metal halide perovskite were a game-changer in the quest for photovoltaic performance. A flurry of activity in the fields of structure design, materials chemistry, process engineering, and device physics has helped the solid-state perovskite solar cell to become a leading contender for the next generation of solar energy harvesters in the world today. This follows up on the ground-breaking development of the solid-state perovskite solar cell in 2012. This cell has a higher efficiency compared to commercial silicon or other organic and inorganic solar cells, as well as a lower cost of materials and processes. However, it has the disadvantage that these high efficiencies can only be obtained with lead-based perovskites, which increases the cost of the cell. As a result of this fact, a new study area on lead-free metal halide perovskites was established, and it is now exhibiting a remarkable degree of vibrancy. This provided us with the impetus to review this burgeoning area of research and discuss possible alternative elements according to current theoretical and practical investigations that might be utilized to replace lead in metal halide perovskites as well as the features of the perovskite materials that correspond to these elements.

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12

Ferri, Davide. "Catalysis by Metals on Perovskite-Type Oxides." Catalysts 10, no. 9 (September 15, 2020): 1062. http://dx.doi.org/10.3390/catal10091062.

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Perovskites are currently on everyone’s lips and have made it in high-impact scientific journals because of the revolutionary hybrid organic–inorganic lead halide perovskite materials for solar cells [...]

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13

Hartati, Sri, Pramitha Yuniar Diah Maulida, Taufiq Zakly, Irma Mulyani, Djulia Onggo, Muhammad Haris Mahyuddin, Alfian Noviyanto, Arramel Arramel, and Nurul Taufiqu Rochman. "Vibrational and Structural Properties of Two-Dimensional Tin Mixed-Halide Perovskites." Nano Hybrids and Composites 40 (July 31, 2023): 1–6. http://dx.doi.org/10.4028/p-kaxs1n.

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The emergence of two-dimensional (2D) hybrid metal-halide perovskites has garnered significant attentions for optoelectronic devices and light-emitting applications. Since the toxicity of lead-based perovskites could potentially be harmful to the environment, several works have attempted to change the active metal to tin (Sn). Here, we investigate the characterization of (PEA)2SnBrxI4-x mixed halide perovskites using X-ray fluorescence (XRF), X-ray diffraction (XRD), and Fourier transform infrared (FTIR) spectroscopy. Qualitative XRF analysis suggests the presence of tin, bromine and iodine emissions under the mid-Z and high-Z ranges. In mid-Z range, Br-Kα peak appeared on 11.96 keV and Br-Kβ was detected on 13.3 keV. Meanwhile Sn-Kα, I-Kα, I-Kβ1, and I-Kβ2 peaks were detected in high-Z range on 25.24 keV, 28.6 keV, 32.35 keV and 33.11 keV, respectively. Thus, the elemental composition of mixed halide components exhibits an indicative control that bromine-rich or iodine-rich can be synthesized via rational chemical design. XRD pattern display a systematic progression at the peak 5.18° (corresponds to (002) plane), which unambiguously demonstrated the feasibility to tune halide composition in tin-based hybrid perovskite. It also confirms that (2D) hybrid metal-halide with tunable halide have identical structure for both bromine-rich and iodine-rich composition. Furthermore, the 2θ peaks slightly shifted to lower angle with increasing bromine composition. The presence of C−I bonding on ~500 cm-1 and C-Br bond on ~600 cm-1 in FTIR spectra highlights the functional group of organic cations. These experimental results promote a foundation to implement compositional engineering on 2D-tin mixed-halide perovskites for optoelectronics and scintillators.

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Rahman, Md Mijanur, Tabassum Hasnat Reshmi, Suhel Ahmed, and Md Ashraful Alam. "Impact of localized surface plasmon resonance on efficiency of zinc oxide nanowire-based organic–inorganic perovskite solar cells fabricated under ambient conditions." RSC Advances 12, no. 39 (2022): 25163–71. http://dx.doi.org/10.1039/d2ra04346g.

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Organometal halide perovskites as hybrid light absorbers have been investigated and used in the fabrication of perovskite solar cells (PSCs) due to their low-cost, easy processability and potential for high efficiency.

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15

Wyn Jones, Eurig, Peter James Holliman, Leon Bowen, Arthur Connell, Christopher Kershaw, and Diana Elizabeth Meza-Rojas. "Hybrid Al2O3-CH3NH3PbI3 Perovskites towards Avoiding Toxic Solvents." Materials 13, no. 1 (January 6, 2020): 243. http://dx.doi.org/10.3390/ma13010243.

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We report the synthesis of organometal halide perovskites by milling CH3NH3I and PbI2 directly with an Al2O3 scaffold to create hybrid Al2O3-CH3NH3PbI3 perovskites, without the use of organic capping ligands that otherwise limit the growth of the material in the three dimensions. Not only does this improve the ambient stability of perovskites in air (100 min versus 5 min for dimethylformamide (DMF)-processed material), the method also uses much fewer toxic solvents (terpineol versus dimethylformamide). This has been achieved by solid-state reaction of the perovskite precursors to produce larger perovskite nanoparticles. The resulting hybrid perovskite–alumina particles effectively improve the hydrophobicity of the perovskite phase whilst the increased thermal mass of the Al2O3 increases the thermal stability of the organic cation. Raman data show the incorporation of Al2O3 shifts the perovskite spectrum, suggesting the formation of a hybrid 3D mesoporous stack. Laser-induced current mapping (LBIC) and superoxide generation measurements, coupled to thermogravimetric analysis, show that these hybrid perovskites demonstrate slightly improved oxygen and thermal stability, whilst ultra-fast X-ray diffraction studies using synchrotron radiation show substantial (20×) increase in humidity stability. Overall, these data show considerably improved ambient stability of the hybrid perovskites compared to the solution-processed material.

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16

Adjogri, Shadrack J., and Edson L. Meyer. "A Review on Lead-Free Hybrid Halide Perovskites as Light Absorbers for Photovoltaic Applications Based on Their Structural, Optical, and Morphological Properties." Molecules 25, no. 21 (October 30, 2020): 5039. http://dx.doi.org/10.3390/molecules25215039.

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Despite the advancement made by the scientific community in the evolving photovoltaic technologies, including the achievement of a 29.1% power conversion efficiency of perovskite solar cells over the past two decades, there are still numerous challenges facing the advancement of lead-based halide perovskite absorbers for perovskite photovoltaic applications. Among the numerous challenges, the major concern is centered around the toxicity of the emerging lead-based halide perovskite absorbers, thereby leading to drawbacks for their pragmatic application and commercialization. Hence, the replacement of lead in the perovskite material with non-hazardous metal has become the central focus for the actualization of hybrid perovskite technology. This review focuses on lead-free hybrid halide perovskites as light absorbers with emphasis on how their chemical compositions influence optical properties, morphological properties, and to a certain extent, the stability of these perovskite materials.

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17

Zhao, Yue, Qingsen Zeng, Yue Yu, Tanglue Feng, Yajie Zhao, Zidong Wang, Yi Li, et al. "Enhanced charge separation and photocatalytic hydrogen evolution in carbonized-polymer-dot-coupled lead halide perovskites." Materials Horizons 7, no. 10 (2020): 2719–25. http://dx.doi.org/10.1039/d0mh00955e.

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This work demonstrates that carbonized polymer dots (CPDs) can efficiently promote the charge separation and photocatalytic performance of metal halide perovskites, highlighting their excellent charge-transfer ability and great potential in developing efficient perovskite-based hybrid photocatalysts.

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18

Zhou, Yuanyuan, and Wei Chen. "Hybrid organic–inorganic halide perovskites." Journal of Applied Physics 128, no. 20 (November 28, 2020): 200401. http://dx.doi.org/10.1063/5.0034825.

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19

Petrov, Andrey A., Artem A. Ordinartsev, Sergey A. Fateev, Eugene A. Goodilin, and Alexey B. Tarasov. "Solubility of Hybrid Halide Perovskites in DMF and DMSO." Molecules 26, no. 24 (December 13, 2021): 7541. http://dx.doi.org/10.3390/molecules26247541.

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Solution methods remain the most popular means for the fabrication of hybrid halide perovskites. However, the solubility of hybrid perovskites has not yet been quantitively investigated. In this study, we present accurate solubility data for MAPbI3, FAPbI3, MAPbBr3 and FAPbBr3 in the two most widely used solvents, DMF and DMSO, and demonstrate huge differences in the solubility behavior depending on the solution compositions. By analyzing the donor numbers of the solvents and halide anions, we rationalize the differences in the solubility behavior of hybrid perovskites with various compositions, in order to take a step forward in the search for better processing conditions of hybrid perovskites for solar cells and optoelectronics.

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Ganose, Alex M., Keith T. Butler, Aron Walsh, and David O. Scanlon. "Relativistic electronic structure and band alignment of BiSI and BiSeI: candidate photovoltaic materials." Journal of Materials Chemistry A 4, no. 6 (2016): 2060–68. http://dx.doi.org/10.1039/c5ta09612j.

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Bismuth-based solar absorbers are of interest due to similarities in the chemical properties of bismuth halides and the exceptionally efficient lead halide hybrid perovskites. Here, we computationally screen BiSI and BiSeI and show they possess electronic structures ideal for solar cell applications.

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21

Obraztsov, Petr A., Vladislava V. Bulgakova, Pavel A. Chizhov, Alexander A. Ushakov, Dmitry S. Gets, Sergey V. Makarov, and Vladimir V. Bukin. "Hybrid Perovskite Terahertz Photoconductive Antenna." Nanomaterials 11, no. 2 (January 26, 2021): 313. http://dx.doi.org/10.3390/nano11020313.

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Hybrid organic–inorganic perovskites, while well examined for photovoltaic applications, remain almost completely unexplored in the terahertz (THz) range. These low-cost hybrid materials are extremely attractive for THz applications because their optoelectronic properties can be chemically engineered with relative ease. Here, we experimentally demonstrate the first attempt to apply solution-processed polycrystalline films of hybrid perovskites for the development of photoconductive terahertz emitters. By using the widely studied methylammonium-based perovskites MAPbI3 and MAPbBr3, we fabricate and characterize large-aperture photoconductive antennas. The work presented here examines polycrystalline perovskite films excited both above and below the bandgap, as well as the scaling of THz emission with the applied bias field and the optical excitation fluence. The combination of ultrafast time-resolved spectroscopy and terahertz emission experiments allows us to determine the still-debated room temperature carrier lifetime and mobility of charge carriers in halide perovskites using an alternative noninvasive method. Our results demonstrate the applicability of hybrid perovskites for the development of scalable THz photoconductive devices, making these materials competitive with conventional semiconductors for THz emission.

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Rothmann, Mathias Uller, Judy S. Kim, Juliane Borchert, Kilian B. Lohmann, Colum M. O’Leary, Alex A. Sheader, Laura Clark, et al. "Atomic-scale microstructure of metal halide perovskite." Science 370, no. 6516 (October 29, 2020): eabb5940. http://dx.doi.org/10.1126/science.abb5940.

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Hybrid organic-inorganic perovskites have high potential as materials for solar energy applications, but their microscopic properties are still not well understood. Atomic-resolution scanning transmission electron microscopy has provided invaluable insights for many crystalline solar cell materials, and we used this method to successfully image formamidinium lead triiodide [CH(NH2)2PbI3] thin films with a low dose of electron irradiation. Such images reveal a highly ordered atomic arrangement of sharp grain boundaries and coherent perovskite/PbI2 interfaces, with a striking absence of long-range disorder in the crystal. We found that beam-induced degradation of the perovskite leads to an initial loss of formamidinium [CH(NH2)2+] ions, leaving behind a partially unoccupied perovskite lattice, which explains the unusual regenerative properties of these materials. We further observed aligned point defects and climb-dissociated dislocations. Our findings thus provide an atomic-level understanding of technologically important lead halide perovskites.

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Guo, Yuan-Yuan, Lin-Jie Yang, Jason A. McNulty, Alexandra M. Z. Slawin, and Philip Lightfoot. "Structural variations in (001)-oriented layered lead halide perovskites, templated by 1,2,4-triazolium." Dalton Transactions 49, no. 47 (2020): 17274–80. http://dx.doi.org/10.1039/d0dt02936j.

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Maafa, Ibrahim M. "All-Inorganic Perovskite Solar Cells: Recent Advancements and Challenges." Nanomaterials 12, no. 10 (May 12, 2022): 1651. http://dx.doi.org/10.3390/nano12101651.

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Organic–inorganic metal-halide-based hybrid perovskite solar cells (SCs) have attracted a great deal of attention from researchers around the globe with their certified power conversion efficiencies (PCEs) having now increased to 25.2%. Nevertheless, organic–inorganic hybrid halide perovskite SCs suffer the serious drawback of instability with respect to moisture and heat. However, all-inorganic perovskite SCs have emerged as promising candidates to tackle the thermal instability problem. Since the introduction of all-inorganic perovskite materials to the field of perovskite photovoltaics in 2014, a plethora of research articles has been published focusing on this research topic. The PCE of all-inorganic PSCs has climbed to a record 18.4% and research is underway to enhance this. In this review, I survey the gradual progress of all-inorganic perovskites, their material design, the fabrication of high-quality perovskite films, energetics, major challenges and schemes opening new horizons toward commercialization. Furthermore, techniques to stabilize cubically phased low-bandgap inorganic perovskites are highlighted, as this is an indispensable requirement for stable and highly efficient SCs. In addition, I explain the various energy loss mechanisms at the interface and in the bulk of perovskite and charge-selective layers, and recap previously published reports on the curtailment of charge-carrier recombination losses.

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Senocrate, Alessandro, Gee Yeong Kim, Michael Grätzel, and Joachim Maier. "Thermochemical Stability of Hybrid Halide Perovskites." ACS Energy Letters 4, no. 12 (October 25, 2019): 2859–70. http://dx.doi.org/10.1021/acsenergylett.9b01605.

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26

Ma, Zi-Qian, Xiuli Zhu, and Chuanhui Wang. "Design of Lead Hybrid Halide Perovskite for Solar Cells." Journal of Physics: Conference Series 2473, no. 1 (April 1, 2023): 012022. http://dx.doi.org/10.1088/1742-6596/2473/1/012022.

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Abstract Hybrid organic-inorganic halide perovskites solar cells have attracted extensive interest because of their outstanding properties, including an optimal band gap, high carrier mobility, and excellent optoelectronic merits. We study the electronic and crystal structural properties of hybrid organic-inorganic halide APbX3 (A = Cs, methylammonium (MA), formamidinium (FA), X = I, Br) perovskites using first-principles calculations based on density functional theory. We find that halide atoms and A-site cations strongly affect their structural and electronic properties. The radius of a halide atom and the size of an organic molecule determine their lattice parameters and bond length. A relatively large halide atom can increase the value of the lattice parameters (a and b). Meanwhile, the electronic properties (band gap & carrier effective mass) of the Pb-based hybrid halide APbX3 can be effectively modified by adopting appropriate A- and X-site atoms or organic sections. We predict that HOIPs may have outstanding potential in solar light harvesting with promoted power conversion efficiency due to a tunable band gap and excellent electronic properties.

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Chatterjee, Soumyo, and Amlan J. Pal. "Influence of metal substitution on hybrid halide perovskites: towards lead-free perovskite solar cells." Journal of Materials Chemistry A 6, no. 9 (2018): 3793–823. http://dx.doi.org/10.1039/c7ta09943f.

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28

Xiang, Wanchun, Shengzhong (Frank) Liu, and Wolfgang Tress. "A review on the stability of inorganic metal halide perovskites: challenges and opportunities for stable solar cells." Energy & Environmental Science 14, no. 4 (2021): 2090–113. http://dx.doi.org/10.1039/d1ee00157d.

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29

Körbel, Sabine, Miguel A. L. Marques, and Silvana Botti. "Stable hybrid organic–inorganic halide perovskites for photovoltaics from ab initio high-throughput calculations." Journal of Materials Chemistry A 6, no. 15 (2018): 6463–75. http://dx.doi.org/10.1039/c7ta08992a.

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By means of high-throughput first-principles calculations, we screen a large number of hypothetical hybrid perovskite compounds by stability, band gap and effective mass to find the best perovskites for photovoltaics.

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30

Xian, Siyi, Sumin Hou, Huafang Zhang, Jiazhen Yang, Gencai Pan, Huiping Gao, Wenwu You, Zhenlong Zhang, Baohua Zhu, and Yanli Mao. "High quality quasi-two-dimensional organic–inorganic hybrid halide perovskite film for high performance photodetector." Applied Physics Letters 122, no. 10 (March 6, 2023): 103503. http://dx.doi.org/10.1063/5.0139686.

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Two-dimensional (2D) Ruddlesden–Popper perovskites have attracted extensive attention in photodetectors (PDs) due to their exceptional optoelectronic properties. The performances of PDs show extremely strong dependence on defects in 2D perovskites. Herein, high quality and less defective BA2FAPb2I7 perovskite films were obtained by a simple one-step spin coating method with rare earth doping assisted crystal growth. Furthermore, BA2FAPb2I7 perovskite films were used as photoresponsive materials to fabricate architectural simplicity photoconductor PDs. Under 405 nm laser illumination, the PDs show remarkable balance detect properties with a low dark current of 5.1 × 10−11 A, a large on/off ratio of 2.2 × 105, a high responsivity (R) of 4.51 A/W, an outstanding detectivity [Formula: see text] of 4.31 × 1013 Jones, and a response speed of 80 μs/76 μs. The R and [Formula: see text] of the PDs are outstanding in the reported quasi-2D perovskite PDs with the same structure. Our work not only paves an indubitably feasible way for fabrication of quasi-2D perovskite PDs via improving their natural material properties but also provides a clear direction for further enhancing the performance of other perovskites optoelectronics.

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Zarick, Holly F., Naiya Soetan, William R. Erwin, and Rizia Bardhan. "Mixed halide hybrid perovskites: a paradigm shift in photovoltaics." Journal of Materials Chemistry A 6, no. 14 (2018): 5507–37. http://dx.doi.org/10.1039/c7ta09122b.

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This review gives a comprehensive overview of recent progress made in mixed-halide hybrid perovskite materials, focusing in particular on the impact of halide substitution on optoelectronic properties and trends in carrier dynamics.

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32

Petrovai, Ioan, Otto Todor-Boer, Leontin David, and Ioan Botiz. "Growth of Hybrid Perovskite Crystals from CH3NH3PbI3–xClx Solutions Subjected to Constant Solvent Evaporation Rates." Materials 16, no. 7 (March 26, 2023): 2625. http://dx.doi.org/10.3390/ma16072625.

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In this work, we subjected hybrid lead-mixed halide perovskite (CH3NH3PbI3–xClx) precursor inks to different solvent evaporation rates in order to facilitate the nucleation and growth of perovskite crystals. By controlling the temperature of perovskite solutions placed within open-air rings in precise volumes, we established control over the rate of solvent evaporation and, thus, over both the growth rate and the shape of perovskite crystals. Direct utilization of diluted lead-mixed halide perovskites solutions allowed us to control the nucleation and to favor the growth of only a low number of perovskite crystals. Such crystals exhibited a clear sixfold symmetry. While crystals formed at a lower range of temperatures (40–60 °C) exhibited a more compact dendritic shape, the crystals grown at a higher temperature range (80–110 °C) displayed a fractal dendritic morphology.

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33

Ren, Yingke, Delong Li, Jing Chen, Xinge Guo, Chao He, Zhaoqian Li, and Xingtao An. "Enhanced crystallization in the CsPbBr₃ all-inorganic perovskite via an advanced nucleation method." Journal of Materials Chemistry C 10, no. 9 (2022): 3429–34. http://dx.doi.org/10.1039/d1tc05924f.

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34

Tathavadekar, Mukta, Shrreya Krishnamurthy, Aparna Banerjee, Satyawan Nagane, Yogesh Gawli, Anil Suryawanshi, Suresh Bhat, Dhanya Puthusseri, Aditya D. Mohite, and Satishchandra Ogale. "Low-dimensional hybrid perovskites as high performance anodes for alkali-ion batteries." Journal of Materials Chemistry A 5, no. 35 (2017): 18634–42. http://dx.doi.org/10.1039/c7ta04529h.

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Molecularly engineered low-dimensional hybrid perovskites are demonstrated as anode materials for alkali-ion batteries. The electrochemical performance can be dramatically improved by tuning the dimensionality of halide-perovskites from 3D to 2D to 1D.

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35

Shan, Yingying, Zhensheng Lyu, Xinwei Guan, Adnan Younis, Guoliang Yuan, Junling Wang, Sean Li, and Tom Wu. "Solution-processed resistive switching memory devices based on hybrid organic–inorganic materials and composites." Physical Chemistry Chemical Physics 20, no. 37 (2018): 23837–46. http://dx.doi.org/10.1039/c8cp03945c.

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36

Roy, Mrinmoy, Vikram, Bhawna, Aftab Alam, and M. Aslam. "Photoinduced quasi-2D to 3D phase transformation in hybrid halide perovskite nanoplatelets." Physical Chemistry Chemical Physics 23, no. 48 (2021): 27355–64. http://dx.doi.org/10.1039/d1cp03529k.

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37

Zhou, Dahua, Leyong Yu, Peng Zhu, Hongquan Zhao, Shuanglong Feng, and Jun Shen. "Lateral Structured Phototransistor Based on Mesoscopic Graphene/Perovskite Heterojunctions." Nanomaterials 11, no. 3 (March 5, 2021): 641. http://dx.doi.org/10.3390/nano11030641.

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Due to their outstanding optical properties and superior charge carrier mobilities, organometal halide perovskites have been widely investigated in photodetection and solar cell areas. In perovskites photodetection devices, their high optical absorption and excellent quantum efficiency contribute to the responsivity, even the specific detectivity. In this work, we developed a lateral phototransistor based on mesoscopic graphene/perovskite heterojunctions. Graphene nanowall shows a porous structure, and the spaces between graphene nanowall are much appropriated for perovskite crystalline to mount in. Hot carriers are excited in perovskite, which is followed by the holes’ transfer to the graphene layer through the interfacial efficiently. Therefore, graphene plays the role of holes’ collecting material and carriers’ transporting channel. This charge transfer process is also verified by the luminescence spectra. We used the hybrid film to build phototransistor, which performed a high responsivity and specific detectivity of 2.0 × 103 A/W and 7.2 × 1010 Jones, respectively. To understand the photoconductive mechanism, the perovskite’s passivation and the graphene photogating effect are proposed to contribute to the device’s performance. This study provides new routes for the application of perovskite film in photodetection.

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38

Coccia, Clarissa, Marco Moroni, and Lorenzo Malavasi. "Chiral Metal Halide Perovskites: Focus on Lead-Free Materials and Structure-Property Correlations." Molecules 28, no. 16 (August 21, 2023): 6166. http://dx.doi.org/10.3390/molecules28166166.

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Hybrid organic–inorganic perovskites (HOIPs) are promising materials in several fields related to electronics, offering long carrier-diffusion lengths, high absorption coefficients, tunable band gaps, and long spin lifetimes. Recently, chiral perovskites have attracted huge interest thanks to the possibility of further widening the applications of HOIPs. Chiral materials, being intrinsically non-centrosymmetric, display several attractive physicochemical properties, including circular dichroism, circularly polarized photoluminescence, nonlinear optics, ferroelectricity, and spin-related effects. Recent studies have shown that chirality can be transferred from the chiral organic ligands into the inorganic perovskite framework, resulting in materials combining the advantages of both chirality and perovskite superior optoelectronic characteristics. As for HOIPs for photovoltaics, strong interest is currently devoted towards the development of lead-free chiral perovskites to overcome any toxicity issue. While considering the basic and general features of chiral HOIPs, this review mainly focuses on lead-free materials. It highlights the first attempts to understand the correlation between the crystal structure characteristics and the chirality-induced functional properties in lead and lead-free chiral perovskites.

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39

Hasegawa, Hiroyuki, and Tamotsu Inabe. "Electrical properties of organic–inorganic hybrid tin bromide cubic perovskites: hole-doping and iodide substitution effects." New Journal of Chemistry 40, no. 8 (2016): 7043–47. http://dx.doi.org/10.1039/c6nj00439c.

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40

Senocrate, Alessandro, and Joachim Maier. "Solid-State Ionics of Hybrid Halide Perovskites." Journal of the American Chemical Society 141, no. 21 (April 18, 2019): 8382–96. http://dx.doi.org/10.1021/jacs.8b13594.

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41

Franssen, Wouter M. J., and Arno P. M. Kentgens. "Solid–state NMR of hybrid halide perovskites." Solid State Nuclear Magnetic Resonance 100 (August 2019): 36–44. http://dx.doi.org/10.1016/j.ssnmr.2019.03.005.

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42

Gebhardt, Julian, and Andrew M. Rappe. "Design of Metal-Halide Inverse-Hybrid Perovskites." Journal of Physical Chemistry C 122, no. 25 (March 13, 2018): 13872–83. http://dx.doi.org/10.1021/acs.jpcc.8b01008.

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43

Li, Tianyang, Wiley A. Dunlap-Shohl, Eric W. Reinheimer, Pierre Le Magueres, and David B. Mitzi. "Melting temperature suppression of layered hybrid lead halide perovskites via organic ammonium cation branching." Chemical Science 10, no. 4 (2019): 1168–75. http://dx.doi.org/10.1039/c8sc03863e.

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44

Kiran, Saira, Umair Mumtaz, Aymen Mustafa, Muhammad Imran, Fayyaz Hussain, Umbreen Rasheed, R. M. A. Khalil, Ejaz Ahmad Khera, and Alia Nazir. "An ab initio investigation of the structural, mechanical, electronic, optical, and thermoelectric characteristics of novel double perovskite halides Cs₂CaSnX₆ (X = Cl, Br, I) for optically influenced RRAM devices." RSC Advances 13, no. 16 (2023): 11192–200. http://dx.doi.org/10.1039/d3ra00078h.

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45

Fan, Ping, Huan-Xin Peng, Zhuang-Hao Zheng, Zi-Hang Chen, Shi-Jie Tan, Xing-Ye Chen, Yan-Di Luo, Zheng-Hua Su, Jing-Ting Luo, and Guang-Xing Liang. "Single-Source Vapor-Deposited Cs2AgBiBr6 Thin Films for Lead-Free Perovskite Solar Cells." Nanomaterials 9, no. 12 (December 11, 2019): 1760. http://dx.doi.org/10.3390/nano9121760.

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Lead-free double perovskites have been considered as a potential environmentally friendly photovoltaic material for substituting the hybrid lead halide perovskites due to their high stability and nontoxicity. Here, lead-free double perovskite Cs2AgBiBr6 films are initially fabricated by single-source evaporation deposition under high vacuum condition. X-ray diffraction and scanning electron microscopy characterization show that the high crystallinity, flat, and pinhole-free double perovskite Cs2AgBiBr6 films were obtained after post-annealing at 300 °C for 15 min. By changing the annealing temperature, annealing time, and film thickness, perovskite Cs2AgBiBr6 solar cells with planar heterojunction structure of FTO/TiO2/Cs2AgBiBr6/Spiro-OMeTAD/Ag achieve an encouraging power conversion efficiency of 0.70%. Our preliminary work opens a feasible approach for preparing high-quality double perovskite Cs2AgBiBr6 films wielding considerable potential for photovoltaic application.

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46

Solis-Ibarra, D., I. C. Smith, and H. I. Karunadasa. "Post-synthetic halide conversion and selective halogen capture in hybrid perovskites." Chemical Science 6, no. 7 (2015): 4054–59. http://dx.doi.org/10.1039/c5sc01135c.

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47

Smith, Matthew D., Adam Jaffe, Emma R. Dohner, Aaron M. Lindenberg, and Hemamala I. Karunadasa. "Structural origins of broadband emission from layered Pb–Br hybrid perovskites." Chemical Science 8, no. 6 (2017): 4497–504. http://dx.doi.org/10.1039/c7sc01590a.

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48

Filippetti, A., P. Wadhwa, C. Caddeo, and A. Mattoni. "A promising outlook on the development of lead halide perovskites as spin-orbitronic materials." Applied Physics Letters 121, no. 20 (November 14, 2022): 200501. http://dx.doi.org/10.1063/5.0107903.

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Hybrid lead halide perovskites have progressively overcome the horizon of materials for novel, highly efficient solar cells and are now proposed for a variety of optoelectronic, nanoelectronic, and thermoelectric applications. In this Perspective, we focus on a still scarcely explored and yet extremely thrilling playground: the use of lead halide perovskites to design efficient magneto-electronic and magneto-optic applications. Our analysis is pointed to emphasize the unique combination of strong spin–orbit coupling and wide structural and chemical flexibility, which characterize the lead halide perovskites. Using model calculations, we furnish a qualitative evidence of their capabilities for what concerns the charge–spin conversion mechanism, which is basic to some of the most visionary spin-orbitronic implementations, such as the magnetoelectric switching and the spin-diffusive transistor.

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49

Cordero, Francesco, Floriana Craciun, Anna Maria Paoletti, and Gloria Zanotti. "Structural Transitions and Stability of FAPbI3 and MAPbI3: The Role of Interstitial Water." Nanomaterials 11, no. 6 (June 18, 2021): 1610. http://dx.doi.org/10.3390/nano11061610.

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We studied the influence of water on the structural stability and transformations of MAPI and FAPI by anelastic and dielectric spectroscopies under various temperature and H2O partial pressure protocols. Before discussing the new results in terms of interstitial water in MAPI and FAPI, the literature is briefly reviewed, in search of other studies and evidences on interstitial water in hybrid halide perovskites. In hydrated MAPI, the elastic anomaly between the cubic α and tetragonal β phases may be depressed by more than 50%, demonstrating that there are H2O molecules dispersed in the perovskite lattice in interstitial form, that hinder the long range tilting of the PbI6 octahedra. Instead, in FAPI, interstitial water accelerates in both senses the reconstructive transformations between 3D α and 1D δ phases, which is useful during the crystallization of the α phase. On the other hand, the interstitial H2O molecules increase the effective size of the MA and FA cations to which are bonded, shifting the thermodynamic equilibrium from the compact perovskite structure to the open δ and hydrated phases of loosely bonded chains of PbI6 octahedra. For this reason, when fabricating devices based on hybrid metal-organic halide perovskites, it is important to reduce the content of interstitial water as much as possible before encapsulation.

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Tang, Weidong, Jinshuai Zhang, Sinclair Ratnasingham, Fabiola Liscio, Kan Chen, Tianjun Liu, Kening Wan, et al. "Substitutional doping of hybrid organic–inorganic perovskite crystals for thermoelectrics." Journal of Materials Chemistry A 8, no. 27 (2020): 13594–99. http://dx.doi.org/10.1039/d0ta03648j.

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