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Journal articles on the topic 'Hexachloro-1'

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Published: 4 June 2021

Last updated: 8 February 2022

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1

Jelínek, T., J. Fábry, L. Hummel, K. Malý, and V. Petříček. "Structure of tetramethylammonium 7,8,9,10,11,12-hexachloro-1,2,3,4,5,6-hexahydro-1-carba-closo-dodecaborate(1–)." Acta Crystallographica Section C Crystal Structure Communications 47, no. 5 (1991): 993–95. http://dx.doi.org/10.1107/s0108270190009210.

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2

Lock, Edward A., Iona S. Pratt, and John Ishmael. "Hexachloro-1, 3-butadiene-induced hydropic change in mouse liver." Journal of Applied Toxicology 5, no. 2 (1985): 74–79. http://dx.doi.org/10.1002/jat.2550050207.

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3

Apblett, Allen, Tristram Chivers, James F. Fait, and Rainer Vollmerhaus. "Negative hyperconjugation in hexachloro-3-cyclopentenylaminosulphenyl halides: Preparation and X-ray structure of C5Cl6NSBr and synthesis of C5Cl6NS+AsF6−." Canadian Journal of Chemistry 69, no. 6 (1991): 1022–27. http://dx.doi.org/10.1139/v91-150.

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The reaction of hexachlorocyclopentadiene with (NSCl)3 at 65 °C in the absence of a solvent produced hexachloro-3-cyclopentenylidenaminosulfenyl chloride, C5Cl6NSCl, in good yield. The derivatives C5Cl6NSX(X = Br, I, C5Cl6N, NPr2i, Ph) were prepared by treatment of C5Cl6NSCl with Me3SiBr, Me3SiI, Ph3Sb, iPr2NH, and Ph2Hg, respectively. The crystal structure of C5Cl6NSBr was determined by X-ray crystallography. Crystals of C5Cl6NSBr are triclinic, space group [Formula: see text] with a = 9.626(2), b = 9.810(2), c = 13.736(2) Å, α = 79.68(1), β = 88.62(1), γ = 74.73(1)°, Z = 4, final R and Rw va

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4

Herberhold, Max, Christine Dörnhöfer, and Ulf Thewalt. "Ferrocen-1,1′-dithiolato- und -diselenato-Derivate des Hexachlor-cyclotriphosphazens / Ferrocene-1,1′-dithiolato and -diselenato Derivatives of Hexachloro-cyclotriphosphazene." Zeitschrift für Naturforschung B 45, no. 6 (1990): 741–46. http://dx.doi.org/10.1515/znb-1990-0603.

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The three pairs of geminal chloro substituents in hexachloro-cyclotriphosphazene, N3P3Cl6, are stepwise replaced by chelating ferrocene-1,1′-dichalcogenato groups, [Fe(C5H4E)2.]2-, to give the spiro-cyclotriphosphazenes N3P3Cl6-2n[(EC5H4)2Fe]n (n = 1, 2, 3; E = S (a), Se (b)). The molecular structure of P,P′-bis(ferrocene-1,1′-dithiolato)-P″-dichlorocyclotriphosphazene, N3P3Cl,[(SC5H4)2Fe]2(2a) has been determined.

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5

AVDEENKO, A. P., and A. L. YUSINA. "ChemInform Abstract: Some Reactions of 4-Arylsulfonylimino-2,3,5,5,6,6-hexachloro-2- cyclohexen-1-ones." ChemInform 25, no. 31 (2010): no. http://dx.doi.org/10.1002/chin.199431115.

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6

Balde, L., R. Julien, and G. Morgant. "Crystal structure of 5-azoniaoctane-1,8-diammonium hexachloro tellurate(IV)-hydrogen chloride (1/1), (TeCl6)(C7N3H21) · HCl." Zeitschrift für Kristallographie - New Crystal Structures 216, no. 1-4 (2001): 239–40. http://dx.doi.org/10.1524/ncrs.2001.216.14.239.

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7

Kirby, Gordon M., and Peter H. Bach. "Enhanced Hexachloro-1:3-butadiene Nephrotoxicity in Rats with a Preexisting Adriamycin-Induced Nephrotic Syndrome." Toxicologic Pathology 23, no. 3 (1995): 303–12. http://dx.doi.org/10.1177/019262339502300307.

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8

Oesch, Franz, and C. Roland Wolf. "Properties of the microsomal and cytosolic glutathione transferases involved in hexachloro-1:3-butadiene conjugation." Biochemical Pharmacology 38, no. 2 (1989): 353–59. http://dx.doi.org/10.1016/0006-2952(89)90049-x.

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9

Ketchersid, Mary L., Frederick W. Plapp, and Morris G. Merkle. "Sorghum (Sorghum bicolor) Seed Safeners as Insecticide Synergists." Weed Science 33, no. 6 (1985): 774–78. http://dx.doi.org/10.1017/s0043174500083338.

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Certain oximes, including cyometrinil [(Z)-α-(cyanomethoxy)iminobenzeneacetonitrile], CGA-92194 [N-(1,3-dioxolan-2-yl-methoxy)-iminobenzeneacetonitrile], 2-pyridinealdoxime-O-benzyl ether (PA-B), and 2-pyridinealdoxime-O-phenethyl ether (PA-PE), which are known to protect sorghum from chloroacetanilide herbicides, increased the toxicity of the insecticide propoxur (o-isopropoxyphenyl-methyl carbamate) to a resistant strain of housefly (Musca domesticaL.). Flurazole [5-thiazolecarboxylic acid, benzyl ester, 2-chloro-4-(trifluoromethyl)], a nonoxime protectant for grain sorghum, had less effect

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10

Golinske, Dirk, and Jürgen Voss. "Electroreduction of Organic Compounds, 35. Quantum Chemical Calculations of Reaction Pathways for the Cathodic Dehalogenation of Chlorodibenzofurans and Oligochlorobenzenes." Zeitschrift für Naturforschung B 60, no. 7 (2005): 780–86. http://dx.doi.org/10.1515/znb-2005-0714.

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Quantum chemical (DFT) calculations on the course of the electroreductive carboxylation of chloroarenes were performed. An explanation for the extraordinary behaviour of 2- chlorodibenzofuran (2) as compared with the corresponding 1-chloro, 3-chloro and 4-chloro derivatives was sought for and was found in the particular reaction coordinate of 2 and in the SOMO spin density distributions of the four isomers. In the same way, the regioselectivity in the formation of dicarboxylic acids from hexachloro- and 1,2,4,5-tetrachlorobenzene was investigated by DFT-MO calculations and was shown to be due

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11

Hinrichs, Winfried, Peer Berges, and Günter Klar. "Elementorganische Verbindungen mit ö-Phenylenresten, XI [1] 3:l-Komplexe von Hexachlor-dibenzo-p-dioxin-2,3-chinon mit 2,3,7,8-Tetramethoxythianthren und -selenanthren / Organometallic Compounds with o-Phenylene Substituents, Part XI [1] 3:1 Complexes of Hexachloro-dibenzo-p-dioxin-2,3-quinone with 2,3,7,8-Tetram ethoxythianthrene and Selenanthrene." Zeitschrift für Naturforschung B 41, no. 9 (1986): 1133–41. http://dx.doi.org/10.1515/znb-1986-0913.

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Abstract The title com pounds can be isolated from concentrated solutions of 2,3,7,8-tetramethoxy thianthrene or selenanthrene and tetrachloro-o-benzoquinone as dark blue crystals. Bond distances and bond and folding angles of the components indicate these com pounds to be charge transfer complexes in which the tetramethoxy thianthrene or selenanthrene molecules act as donors (D), the hexachloro-dibenzo-p-dioxin-2,3-quinone molecules as acceptors (A). In the asymmetric units of the two isostructural complexes an acceptor, a donor and another acceptor molecule are arranged parallel to each othe

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12

Ramos Silva, M., A. Matos Beja, J. A. Paixão та J. Martin-Gil. "Di-μ-chloro-1:2κ2Cl;3:4κ2Cl-hexachloro-1κ3Cl,4κ3Cl-tetra-μ-dimethylglycine-2:3κ8O:O′-tetracopper(II)". Acta Crystallographica Section C Crystal Structure Communications 61, № 8 (2005): m380—m382. http://dx.doi.org/10.1107/s0108270105021591.

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13

Ban, M., and J. de Céaurriz. "Probenecid-induced protection against acute hexachloro-1, 3-butadiene and methyl mercury toxicity to the mouse kidney." Toxicology Letters 40, no. 1 (1988): 71–76. http://dx.doi.org/10.1016/0378-4274(88)90184-1.

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14

Ismail, B. S., and A. O. S. Enoma. "MICROBIAL DEGRADATION OF ENDOSULFAN IN AGRICULTURAL SOILS." ASEAN Journal on Science and Technology for Development 22, no. 3 (2017): 233. http://dx.doi.org/10.29037/ajstd.161.

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A study of the degradation of endosulfan (6, 7, 8, 9, 10, 10-hexachloro – 1, 5, 5a, 6, 9, 9a –hexahydro – 6, 9- methano – 2, 4, 3 – benzodioxanthiepin 3 – oxide) in Malaysian sandy loam and clay soils was carried out using a radioisotopic technique under laboratory conditions. It was demonstrated that endosulfan possessed long half-lives of 433, 495 and 462 days in aerobic sandy loam, aerobic clay and anaerobic clay soils respectively. Endosulfan degrades faster in non-sterile than in sterile soils. This study indicates that microorganisms are involved in the degradation of endosulfan. In gene

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15

Cristofori, Patrizia, Rossella Defazio, Arianna Chiusolo, et al. "Hyaline droplet accumulation in kidney of rats treated with hexachloro-1:3-butadiene: influence of age, dose and time-course." Journal of Applied Toxicology 33, no. 3 (2011): 183–89. http://dx.doi.org/10.1002/jat.1732.

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16

Hensen, K., A. Lemke, and C. N�ther. "Darstellung und Einkristall-Strukturanalyse von Hexachloro-?-dichloro-bis[N-(trimethylsilyl)imidazol]dititan-Chloroform (1/2) [Ti2Cl8(C6H12N2Si)2] � 2 CHCl3." Zeitschrift f�r anorganische und allgemeine Chemie 623, no. 12 (1997): 1973–77. http://dx.doi.org/10.1002/zaac.19976231223.

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17

Chiusolo, Arianna, Rossella Defazio, Edoardo Zanetti, et al. "Kidney Injury Molecule-1 Expression in Rat Proximal Tubule after Treatment with Segment-Specific Nephrotoxicants." Toxicologic Pathology 38, no. 3 (2010): 338–45. http://dx.doi.org/10.1177/0192623310362244.

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Dose-response expression of kidney injury molecule-1 (KIM-1) gene in kidney cortex and its correlation with morphology and traditional biomarkers of nephrotoxicity (plasma creatinine and blood urea nitrogen, BUN) or segment-specific marker of proximal tubule injury (kidney glutamine synthetase, GSK) were studied in male rats treated with proximal tubule segment-specific nephrotoxicants. These included hexachloro-1:3-butadiene (HCBD, S3 segment-specific), potassium dichromate (chromate, S1-S2 segment-specific), and cephaloridine (Cph, S2 segment-specific). Rats were treated with a single intrap

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18

Iavicoli, I., G. Carelli, A. Marinaccio, L. Fontana, and EJ Calabrese. "Effects of sub-chronic exposure to palladium (as potassium hexachloro-palladate) on cytokines in male Wistar rats." Human & Experimental Toxicology 27, no. 6 (2008): 493–97. http://dx.doi.org/10.1177/0960327108090489.

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Palladium (Pd) is a heavy metal belonging to the platinum group elements. It has been shown that Pd and its compounds can cause sensitization, asthma and dermatologic disorders. In this study, Wistar rats were exposed for 3 months to 0, 1, 10, 100, and 250 ng/ml of Pd (as potassium hexachloro-palladate) in drinking water. At the end of exposure, possible changes in two type-1 cytokines [interleukin (IL)-2, interferon (INF)-γ] and one type-2 cytokine (IL-4) in the serum were measured. After the sub-chronic exposure, analysis of variance of IL-2 and INF-γ response shows that the difference betwe

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19

Swain, Aubrey, John Turton, Cheryl Scudamore, et al. "Nephrotoxicity of hexachloro-1:3-butadiene in the male Hanover Wistar rat; correlation of minimal histopathological changes with biomarkers of renal injury." Journal of Applied Toxicology 32, no. 6 (2011): 417–28. http://dx.doi.org/10.1002/jat.1727.

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20

Maguire, David P., John A. Turton, Cheryl L. Scudamore, et al. "Correlation of Histopathology, Urinary Biomarkers, and Gene Expression Responses Following Hexachloro-1:3-Butadiene–induced Acute Nephrotoxicity in Male Hanover Wistar Rats." Toxicologic Pathology 41, no. 5 (2012): 779–94. http://dx.doi.org/10.1177/0192623312464306.

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21

Modesto Filho, P., P. Amerlynck, E. J. Nyns, and H. P. Naveau. "Acclimatization of a Methanogenic Consortium to Polychlorinated Compounds in a Fixed Film Stationary Bed Reactor." Water Science and Technology 25, no. 7 (1992): 265–73. http://dx.doi.org/10.2166/wst.1992.0158.

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With the objective of destruction of organic toxic or recalcitrant compounds by a microbial anaerobic mixed population, a new concept has been devised : the Destox concept. It has been applied here to the destruction of a toxic mixture of about 30 polychlorinated aliphatic compounds (PAC-MIX 1), including 51 % of hexachloro-l,3-butadiene. The basic step for initiating the degradation is thought to be reductive dechlorination by microbial interspecies hydrogen transfer in a system using at all times a non-toxic co-substrate as major source of carbon and energy. In an upflow laboratory-scale rea

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22

Don Waite, Phillip Bailey,, Lynne Quinnett-Abbott, and Brian D. Ripley. "Residues of DDT and other selected organochlorine pesticides in soils from Saskatchewan, Canada (1999)." Canadian Journal of Soil Science 85, no. 2 (2005): 265–71. http://dx.doi.org/10.4141/s04-012.

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A study of samples from a broad range of soils across the province of Saskatchewan, Canada, in 1999 has shown evidence that residues of organochlorine pesticides, and in particular DDT [1,1,1-trichloro-2,2- bis(4-chlorophenyl)ethane] and related compounds, are present even after several decades since the last application. In particular, residue levels of total DDT {DDTt = DDT + DDD [1,1-dichloro-2,2- bis(p-chlorophenyl)ethane] + DDE [1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene]} in Prince Albert National Park approach some of the highest levels measured to date at non-agricultural locations w

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23

Pereira, Ines, Aubrey Swain, John Turton, et al. "Urinary biomarkers of renal injury in the hexachloro-1:3-butadiene treated male Hanover Wistar rat; a dose-response study at low dose levels." Toxicology 290, no. 2-3 (2011): 138–39. http://dx.doi.org/10.1016/j.tox.2011.09.066.

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24

LOCK, E. "Effect of the organic acid transport inhibitor probenecid on renal cortical uptake and proximal tubular toxicity of hexachloro-1,3-butadiene and its conjugates*1." Toxicology and Applied Pharmacology 81, no. 1 (1985): 32–42. http://dx.doi.org/10.1016/0041-008x(85)90117-6.

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25

Palumbo, J. C., and C. A. Sanchez. "Imidacloprid Does Not Enhance Growth and Yield of Muskmelon in the Absence of Whitefly." HortScience 30, no. 5 (1995): 997–99. http://dx.doi.org/10.21273/hortsci.30.5.997.

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Imidacloprid is a new, chloronicotinyl insecticide currently being used to control sweetpotato whitefly [Bemisia tabaci Genn, also known as silverleaf whitefly (Bemisia argentifolii Bellows and Perring)]. Large growth and yield increases of muskmelon (Cucumis melo L.) following the use of imidacloprid have caused some to speculate that this compound may enhance growth and yield above that expected from insect control alone. Greenhouse and field studies were conducted to evaluate the growth and yield response of melons to imidacloprid in the presence and absence of whitefly pressure. In greenho

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26

Titze, Christoph, and Wolfgang Kaim. "Polychlorinated Biaryl Heterocycles as Potential Ligands. Reactions between Octachloro-1,10-phenanthroline and -2,2′-bipyridine with Copper(I) and Other Metal Ions." Zeitschrift für Naturforschung B 51, no. 7 (1996): 981–88. http://dx.doi.org/10.1515/znb-1996-0713.

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Perchlorinated derivatives of the common o-diimine chelate ligands 2,2′-bipyridine and 1,10- phenanthroline were synthesized and tested for their coordination behavior towards metal ions. Octachloro-1,10-phenanthroline (ocp) was obtained via chlorination with PCl5 under pressure (300°C, 18 h). It fails to form stable complexes with e.g. Fe2+, Mn2+, Ru2+, Ni2+. Zn2+ or Cd2+, but yields complex cations [M(ocp)2]+ with M = Cu, Ag. The crystal structure analysis of the red tetrafluoroborate of the copper(I) complex cation reveals a distorted tetrahedral coordination at the metal with a slight ten

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27

Swain, Aubrey, John Turton, Cheryl L. Scudamore та ін. "Urinary biomarkers in hexachloro-1:3-butadiene-induced acute kidney injury in the female Hanover Wistar rat; correlation ofα-glutathioneS-transferase, albumin and kidney injury molecule-1 with histopathology and gene expression". Journal of Applied Toxicology 31, № 4 (2010): 366–77. http://dx.doi.org/10.1002/jat.1624.

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28

Iavicoli, Ivo, Beatrice Bocca, Luca Fontana, Stefano Caimi, Antonio Bergamaschi, and Alessandro Alimonti. "Distribution and elimination of palladium in rats after 90-day oral administration." Toxicology and Industrial Health 26, no. 3 (2010): 183–89. http://dx.doi.org/10.1177/0748233710362383.

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This study determined the distribution in internal organs and the elimination routes in rats after oral administration of potassium hexachloro-palladate. Forty male Wistar rats were exposed for 90 days to 0, 10, 100 and 250 ng/mL of the palladium (Pd) salt in drinking water. Samples of urine and feces were collected on days 1, 30, 60 and 90, while organs (kidney, liver, lung, spleen and bones) and blood were collected at the end of the experiment. Quantification method was based on the sector-field inductively coupled plasma mass spectrometry. Results indicated that Pd ions were rapidly elimin

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29

Schröder, H. Fr. "Chlorinated Hydrocarbons in Biological Sewage Purification – Fate and Difficulties in Balancing." Water Science and Technology 19, no. 3-4 (1987): 429–38. http://dx.doi.org/10.2166/wst.1987.0223.

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The fate of some chosen chlorinated hydrocarbons in the biological sewage purification was determined. Fixed quantities (250 µg/l waste water) of the different volatile compounds such as chloroform, trichloroethylene, chlorobenzene, hexachloro-1, 3-butadiene, 1,2-dichlorobenzene, 1,2, 3-trichlorobenzene, hexach lorobenzene, 2,4-dichlorophenol and γ-hexachlorocyclohexane were dosed into the aeration tanks of the pilot plants. Chlorinated hydrocarbons in the inflow, waste air, effluent and excess sludge were extracted and tested for by GC/ECD. The results of these experiments were adapted with t

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30

Alam, MJ, Y. Daoxian, S. Yachuan, YJ Jiang, ME Quayum, and LJ Cheng. "Hexachloro benzene in the Nanshan Karst systems, China." Bangladesh Journal of Scientific and Industrial Research 50, no. 2 (2015): 109–16. http://dx.doi.org/10.3329/bjsir.v50i2.24351.

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Karst areas have much higher ecological vulnerability and are easy to be contaminated with hexachlorinated benzene (HCB) which is introduced as health risk pollutants. HCB concentrations were used to understand the transport of HCB conducted in the Nanshan karst system, China. Water, sediments from the underground river and water, sediments and soil from the surface systems were collected monthly in 2011 - 2012 and HCB were analyzed. The levels of HCB were 19.9 ng L-1 in underground waters and 11.6 ng g-1 in underground sediments while 99.1 ng L-1 in surface waters and 110.5 ng g-1 in surface

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31

Booker, R. "Microbial reductive dechlorination of hexachloro-1,3-butadiene in a methanogenic enrichment culture." Water Research 34, no. 18 (2000): 4437–45. http://dx.doi.org/10.1016/s0043-1354(00)00214-1.

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32

Davis, Mary E. "Effects of AT-125 on the nephrotoxicity of hexachloro-1,3-butadiene in rats." Toxicology and Applied Pharmacology 95, no. 1 (1988): 44–52. http://dx.doi.org/10.1016/s0041-008x(88)80006-1.

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33

Shamir, Jacob, Shalom Luski, Avi Bino, Shmuel Cohen, and Dan Gibson. "Tetrachloro-phosphonium salts of hexachloro antimonate and niobate and their solvates. Preparation and structure by vibrational spectroscopy and x-ray crystallography." Inorganica Chimica Acta 104, no. 2 (1985): 91–97. http://dx.doi.org/10.1016/s0020-1693(00)86422-1.

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34

Battaglia, LP, AB Corradi, R. Battistuzzi та T. Manfredini. "Crystal and Molecular Structure of Triaqua-tri-μ-chloro-hexachloro-triangulo-trirhenium(III)-Bis[4,6-dimetylpyrimidine-2(1H)-thione hydrochloride]-Dihydrate". Australian Journal of Chemistry 40, № 12 (1987): 2123. http://dx.doi.org/10.1071/ch9872123.

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Reaction between rhenium(III) chloride and 4,6-dimethylpyrimidine-2(1H)- thione hydrochloride in concentrated HCl solution results in the formation of [Re3C19(H2O)3].2(C6H7N2S.HCl).-2H2O. The compound crystallizes in the orthorhombic space group Pnma with cell dimensions a 16.797(4), b 21.917(4), c 9.514(1) � and Z 4. The structure was solved by the heavy-atom method and refined by least-squares calculations to a final R value of 0.0517 (R' 0.0602). The structure consists of discrete [Re3Cl9(H2O)3] units, protonated organic molecules, chloride ions, and water molecules. In the cluster three rh

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35

Alikhanova, Aygun I., Zeliha Atioğlu, Mehmet Akkurt, and Sixberth Mlowe. "Crystal structure and Hirshfeld surface analysis of (3aR,4S,7S,7aS)-4,5,6,7,8,8-hexachloro-2-{6-[(3aR,4R,7R,7aS)-4,5,6,7,8,8-hexachloro-1,3-dioxo-1,3,3a,4,7,7a-hexahydro-2H-4,7-methanoisoindol-2-yl]hexyl}-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione." Acta Crystallographica Section E Crystallographic Communications 77, no. 8 (2021): 775–79. http://dx.doi.org/10.1107/s2056989021006952.

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The molecule of the title compound, C24H16Cl12N2O4, is generated by a crystallographic inversion centre at the midpoint of the central C—C bond. A kink in the molecule is defined by a torsion angle of −169.86 (15)° about this central bond of the alkyl bridge. The pyrrolidine ring is essentially planar [max. deviation = 0.014 (1) Å]. The cyclohexane ring has a boat conformation, while both cyclopentane rings adopt an envelope conformation. In the crystal structure, molecules are linked by intermolecular C—H...O, C—H...Cl and C—Cl...π interactions, and short intermolecular Cl...O and Cl...Cl con

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36

Manohar, R., M. Harikrishna, S. Harikrishna Etti, C. Ramanathan, and K. Gunasekaran. "Crystal structure of 4,5,6,7,8,8-hexachloro-2-(3,4-dimethoxyphenethyl)-3a,4,7,7a-tetrahydro-1H-4,7-methanoisoindole-1,3(2H)-dione [+solvent]." Acta Crystallographica Section E Crystallographic Communications 75, no. 5 (2019): 562–64. http://dx.doi.org/10.1107/s2056989019004109.

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In the title compound, C19H15Cl6NO4 [+solvent], the six-membered ring of the norbornene moiety adopts a boat conformation and the two five-membered rings have envelope conformations. The pyrrolidine ring makes a dihedral angle of 14.83 (12)° with the 3,4-dimethoxyphenyl ring, which are attached to each other by an extended N—CH2—CH2—Car bridge. In the crystal, the structure features C—H...O intermolecular hydrogen bonds, an offset π–π interaction [intercentroid distance = 3.564 (1) Å] and a C—Cl...π interaction. The contribution of some disordered solvent to the scattering was removed using th

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37

Gou, Lei. "Crystal structure of hexachloro-bis-((4'-(pyridin-3-yl)-2,2':6',2''- terpyridine)-trizinc(II)-methanol, [Zn3(3-pytpy)2Cl6)]CH3OH, C41H32Cl6N8OZn3." Zeitschrift für Kristallographie - New Crystal Structures 228, no. 1 (2013): 15–16. http://dx.doi.org/10.1524/ncrs.2013.0011.

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L, Alois Haas, and Thomas Mischo. "The preparation of thiazyltrifluoromethane, CF3SN, the hexachloro-3-cyclopentenylidenaminosulfides C5Cl6NSX (X = CF3, Cl, NSO, SCF3, C5Cl6N) and the crystal structures of C5Cl6NSX (X = CF3, Cl)." Canadian Journal of Chemistry 67, no. 11 (1989): 1902–8. http://dx.doi.org/10.1139/v89-296.

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CF3S(Cl) = NSi(CH3)3 is found to undergo intermolecular decomposition to give oligomeric, possibly cyclic (CF3SN)x rather than monomeric CF3SN, formed by intramolecular decomposition. Monomeric thiazyltrifluoromethane, CF3SN, is formed in the thermal decomposition of CF3SN3 and may be trapped before polymerizing by formation of a 1:1 adduct with hexachlorocyclopentadiene. The structure of this adduct is determined by single crystal X-ray diffraction. From the molecular structure it is evident that a (4 + 2) cycloaddition has not occurred but rather the formation of a thioketimine (I). The same

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Vornholt, Simon, Ruth Herrmann та Guido J. Reiss. "Crystal structure of the trinuclear complex hexachlorido-1κ3Cl,3κ3Cl-bis(µ2-dimethylphosphorylmethanamine-1:2κ2N:O,3:2κ2N:O)- bis(dimethylphosphorylmethanamine-2κ2N,O)trizinc(II), C12H40Cl6N4O4P4Zn3". Zeitschrift für Kristallographie - New Crystal Structures 229, № 4 (2014): 440–42. http://dx.doi.org/10.1515/ncrs-2014-9047.

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Abdikarimov, Malik N., R. Kh Turgumbayeva, S. S. Sagintaeva, R. Mussabekov, and S. K. Abildinova. "Heatfireprotection Polymer Coatings on the Basis of EPDM-40 with Additives." Key Engineering Materials 816 (August 2019): 356–61. http://dx.doi.org/10.4028/www.scientific.net/kem.816.356.

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Triple ethylene-propylene copolymers (EPDM) are used for the making of structural elements exposed to mechanical loads and are heat-resistant [1, 2], but their widespread use in aviation and shipbuilding equipment and other industries is limited due to Flammability. Double ethylene-propylene rubbers are practically limiting, and triple (EPDM), Dicyclopentadiene is used as the third component, due to the small content of double bonds in the side chains, have high heat resistance compared to diene rubbers [2], and therefore the issues of fire resistance of rubber-technical products based on them

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"Biological Activity of Halogen-Containing Derivatives of N-Substituted Quinone Imines." Biointerface Research in Applied Chemistry 10, no. 6 (2020): 7070–76. http://dx.doi.org/10.33263/briac106.70707076.

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The different halogen-containing derivatives of N-substituted quinone imines have been synthesized by the halogenation and hydrohalogenation of the corresponding quinone imines. N,N'-(Cyclohexa-2-en-1,4-diylidene)-diarylsulfonamides are good insecticides. They cause 89–97% of the insects to die. Compared with quinone imine, compounds having 4-oxocyclohexa-2,5-en-1-ylidene structure show higher fungicidal activity. N-(3,5-Dichloro-4-oxocyclohexa-2,5-dien-1-ylidene)-4-methylbenzene-1-sulfonamide and 4-chloro-N-[2,3,5,5,6,6-hexachloro-4-oxocyclohexa-2-en-1-ylidene]benzene-1-sulfonamide inhibit th

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MULLEROVA, D., M. PESTA, J. DVORAKOVA, et al. "Polychlorinated Biphenyl 153 in Lipid Medium Modulates Differentiation of Human Adipocytes." Physiological Research, August 15, 2017, 653–62. http://dx.doi.org/10.33549/physiolres.933280.

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Emerging evidence indicates that polychlorinated biphenyls (PCBs) are involved in the development of diabetes mellitus in the obese. The purpose of this study was to determine mechanisms by which PCB 153 (2,2′,4,4′,5,5′-hexachloro-biphenyl) could influence diet-induced obesity and insulin resistance during adipogenesis. Lineage of h-ADMSCs was differentiated either as control (differentiation medium only), or with lipid vehicle modeling high fat nutrition (NuTRIflex) or lipid free vehicle (dimethylsulfoxide) for 28 days with or without PCB 153 daily co-exposure (in three concentrations 0.1, 1,

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Wu, Qiong, Catherine Munschy, Yann Aminot, Nathalie Bodin, and Walter Vetter. "High levels of halogenated natural products in large pelagic fish from the Western Indian Ocean." Environmental Science and Pollution Research, June 15, 2021. http://dx.doi.org/10.1007/s11356-021-14738-0.

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AbstractConcentrations, profiles and muscle-liver distribution of halogenated natural products (HNPs) and anthropogenic persistent organic pollutants (POPs) were investigated in five large pelagic fish species and one smaller planktivore fish species from the Western Indian Ocean. Analysis of swordfish muscle from the Seychelles revealed the predominance of HNPs, with the highest concentrations found for 2′-methoxy-2,3′,4,5′- tetraBDE (2′-MeO-BDE 68 or BC-2), 6-methoxy-2,2′,4,4′- tetraBDE (6-MeO-BDE 47 or BC-3) and 2,3,3′,4,4′,5,5′-heptachloro-1′-methyl-1,2′-bipyrrole (Q1), along with varied c

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Ma, Yuxin, Munan Hao, Ruijin Sun, Shifeng Jin та Changchun Zhao. "Crystal structure of tris(3-iodopyridin-1-ium) catena-poly[(hexachlorido-κ1 Cl)-(μ2-trichlorido-κ2 Cl:Cl)diantimony(III)], C15H15Cl9I3N3Sb2". Zeitschrift für Kristallographie - New Crystal Structures, 30 червня 2021. http://dx.doi.org/10.1515/ncrs-2021-0156.

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Abstract C15H15Cl9I3N3Sb2, monoclinic, C2/c (no. 15), a = 28.2633(7) Å, b = 12.4964(3) Å, c = 9.1542(3) Å, β = 99.5840(10)°, V = 3188.04(15) Å3, Z = 4, R gt (F) = 0.0274, wR ref (F 2) = 0.0687, T = 273.15 K.

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