Dissertations / Theses on the topic 'Heterogeneity of regimes'
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Guo, Lian W. "Effects of Variable and Constant Acclimation Regimes on the Upper Thermal Tolerance of Intertidal Barnacle, Balanus Glandula." Scholarship @ Claremont, 2014. http://scholarship.claremont.edu/scripps_theses/331.
Full textChelova, Mariya. "Divided we stand." Doctoral thesis, Humboldt-Universität zu Berlin, Philosophische Fakultät III, 2012. http://dx.doi.org/10.18452/16563.
Full textIn the aftermath of the breakdown of the Soviet Union, the leadership in the fifteen former republics found themselves challenged by complex processes of independent state- and nation-building. Twenty years later, the political regimes that emerged vary from democracies to autocracies. This dissertation focuses on the grey zone in between the pure types. Conceptualizing hybrid regimes as the ones that combine holding of free and fair, recognized elections, and autocratic governance, it asks the question of what keeps the former viable. This research singles out Georgia, Moldova and Ukraine as the countries with hybrid regimes. It shows that the three are highly ethnically heterogeneous and have relatively poor, very low-growing economies. This dissertation argues that these structural conditions are responsible for the actions of the domestic elites, which together with the incentives that the international donors provide the domestic elites with make hybrid regimes permanent. The political polarization is at the core of the explanatory account this dissertation presents. Ethnic divisions, reflected in political polarization are responsible for emergence of regimes with competitive elections. The elites emphasize the divisive issues in their campaigning, while the donors support the already thriving competitive environment. This keeps competitive hybrid regimes in Moldova and Ukraine viable. Absence of polarization based on easily inflammable issues results in the lack of competitiveness. However, an absence of divisiveness produces orientation on one vector of donors (the West). The stimulation of reform and praise for achievement in governance that the donors provide keep the non-competitive hybrid regime in Georgia afloat.
Leale, Alanna M. "The Emergence, Maintenance and Demise of Diversity in a Spatially Variable Antibiotic Regime." Thesis, Université d'Ottawa / University of Ottawa, 2017. http://hdl.handle.net/10393/36689.
Full textAlvarez, Martinez José Manuel. "Foam-flow behavior in porous media : effects of flow regime and porous-medium heterogeneity /." Digital version accessible at:, 1998. http://wwwlib.umi.com/cr/utexas/main.
Full textWalker, Scott. "Does Cultural Heterogeneity Lead to Lower Levels of Regime Respect for Basic Human Rights?" Thesis, University of North Texas, 2002. https://digital.library.unt.edu/ark:/67531/metadc3303/.
Full textEaron, Robert. "Water supply in hard rock coastal regions : The effect of heterogeneity and kinematic porosity." Licentiate thesis, KTH, Mark- och vattenteknik, 2014. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-143647.
Full textQC 20140331
Nowotny, Klaus, and Dieter Pennerstorfer. "Network migration: do neighbouring regions matter?" Routledge by Taylor & Francis Group, 2019. http://dx.doi.org/10.1080/00343404.2017.1380305.
Full textNguyen, David. "The geography of firm internationalisation in Germany : exploring domestic and foreign heterogeneity across regions and sectors." Thesis, London School of Economics and Political Science (University of London), 2017. http://etheses.lse.ac.uk/3671/.
Full textLipinski, Victor Mendes. "ESTRUTURA ESPACIAL DE COMUNIDADES DE ANUROS DE DUAS REGIÕES FISIOGRÁFICAS DO BIOMA PAMPA." Universidade Federal de Santa Maria, 2013. http://repositorio.ufsm.br/handle/1/5299.
Full textIn this study, we sampled two anuran communities in two physiographic regions of the Pampa biome, Serra do Sudeste and Depressão Central, were made monthly campaigns during the period between September 2011 and August 2012 where there were registered 25 species of frogs. Scinax granulatus, Physalaemus gracilis e Pseudis minuta were the most abundant species in the Serra do Sudeste, while Dendropsophus minutus, D. sanborni and Scinax squalirostris were the most abundant of the Depressão Central. We recorded 15 species of frogs in the larval stage and four reproductive modes classified as generalists. Ordination analysis showed a segregation among the two physiographic regions, related to anurofauna with a difference of 65% between them. The influence of environmental descriptors and physicochemical variables of water in the structure of the two communities showed that the set of variables, pH, number of extracts of emergent vegetation and temperature were important in structuring the community of Depressão Central, as dissolved oxygen, electrical conductivity number of extracts of emergent vegetation, hydroperiod and percentage of vegetation cover were important factors structuring the community of Serra do Sudeste. However the abundance and richness of the Serra do Sudeste community showed no significant relation with the variables tested and the distance between the puddles did not influence the structure of both communities.
Neste estudo, foram amostradas duas comunidades de anuros em duas regiões fisiográficas do bioma Pampa, a Serra do Sudeste e a Depressão Central, nestas, foram realizadas campanhas mensais durante o período de setembro de 2011 a agosto de 2012 onde foram registradas 25 espécies de anuros. Scinax granulatus, Physalaemus gracilis e Pseudis minuta foram as espécies mais abundantes na Serra do Sudeste, enquanto Dendropsophus minutus, D. sanborni e Scinax squalirostris foram as mais abundantes da Depressão Central. Foram registrados 15 espécies de anuros em estágio larval e quatro modos reprodutivos generalistas. A análise de ordenação mostrou uma segregação quanto a anurofauna das duas regiões fisiográficas e uma diferença de 65% entre elas. A influência dos descritores ambientais e das variáveis físico-químicas da água na estrutura das duas comunidades mostrou que o conjunto de variáveis, pH, número de extratos de vegetação emergente e temperatura foram importantes na estruturação da comunidade da Depressão Central, já o oxigênio dissolvido, condutividade elétrica número de extratos de vegetação emergente, hidroperíodo e porcentagem de cobertura vegetal foram importantes estruturadores da comunidade da Serra do Sudeste. A abundância e a riqueza de anuros da Serra do Sudeste não apresentou relação significativa com as variáveis testadas e a distância entre as poças não influenciou na estrutura das mesmas.
Belhadj, Aram. "L'intégration monétaire et les pays émergents : application au Maghreb." Thesis, Orléans, 2014. http://www.theses.fr/2014ORLE0501.
Full textThis thesis focuses on the option of the launching of a monetary union across three Maghreb Countries, notablyAlgeria, Morocco and Tunisia. It tries to answer the following questions: What are the characteristics of monetaryregimes in the Maghreb Countries and what are the underlying factors for their choices? Do the countries’ structures andinstitutions constitute a favourable environment for the creation of a monetary union between these countries? What would bethe macroeconomic consequences for these countries if they decided to create a monetary union? Are there any alternativemonetary regimes which would enable them to move toward the final steps of monetary integration in a more appropriate way?In order to answer these questions, we opted for a presentation of four chapters. In a first chapter, we describedthe theoretical foundations of monetary integration through the study of Optimum Currency Area Theory (OCA),their theoretical developments, their drawbacks, their extensions and their empirical applications. We tried in asecond chapter to present the structural and institutional mechanisms that insure the viability of the monetaryintegration process and to recourse to some historical experiences. We attempted in a third chapter to describe themonetary regimes currently in use in the Maghreb Countries and to explain the origin of their heterogeneity beforeanalyzing the possibility of setting up an OCA in this context of heterogeneity. Finally, in a fourth chapter, weassessed the consequences of the creation of a monetary union across the three countries. We also suggest possiblemonetary regimes which, in fine, might allow these countries to successfully move toward monetary union.Our main results show that the creation of a monetary union –and its corollary the implementation of a commonmonetary rule- is not beneficial, especially for Algeria where the variability of inflation and activity is moreimportant than in Morocco and Tunisia. On the other hand, we came to the conclusion that the harmonization ofinflation targets within a quasi-flexible exchange rate or the simultaneous setting up of a currency board in thesecountries could represent an appropriate monetary regime which would allow a safe move to monetary union
Мирошник, Александр Александрович. "Модели и методы поддержки принятия решений в системе управления качеством процесса распределения электрической энергии." Thesis, Харьковский национальный технический университет сельского хозяйства им. Петра Василенко, 2015. http://repository.kpi.kharkov.ua/handle/KhPI-Press/19107.
Full textDissertation for scientific degree of doctor of technical sciences on specialty 05.13.03 – management of systems and processes. – Kharkiv Petro Vasylenko National Technical University of Agriculture. – Kharkiv, 2015. The thesis is devoted to the problem solving of decision-making supporting and valuing their effectiveness in the system of quality management process of distribution of electric power in heterogeneous modes under uncertainty. It was developed valuation methods heterogeneous operating mode of SOED, taking into account unsymmetric with stochastic or deterministic nature, in order to raise the effectiveness of process control of electrical energy distribution. With the purpose of identification of heterogeneous regimes as result of non-sinusoidal voltage distortion in SOED a method based on the wavelet analysis and neural network developed and it allows you to recognize a distorted image signal voltage. It was investigated that wavelet Paul can provide various voltage distortion and gain frequency components and their positions at the time axis simultaneously.It was worked out a method for decision support with a equal distribution of SOED using genetic algorithms, which allows you select the Pareto-optimal solutions in terms of reduction of losses and the quantitative re-strapping. Also, it was developed the method of decision-making in SOED by equal distribution of electro-based neural network that uses voltage average of distribution at the maximum loading per the season, thus reducing the additional losses of electricity.In order to assess the quality of the control system functioning of electricity distribution quality in terms of uncertainty it was developed the method, which evaluates a fuzzy extent accordance to standards and quality indicators to track change of electricity quality even if the major parameters do not exceed permissible values.
Мірошник, Олександр Олександрович. "Моделі та методи підтримки прийняття рішень в системі керування якістю процесу розподілу електричної енергії." Thesis, ФОП Червяк В. Є, 2015. http://repository.kpi.kharkov.ua/handle/KhPI-Press/19104.
Full textDissertation for scientific degree of doctor of technical sciences on specialty 05.13.03 – management of systems and processes. – Kharkiv Petro Vasylenko National Technical University of Agriculture. – Kharkiv, 2015. The thesis is devoted to the problem solving of decision-making supporting and valuing their effectiveness in the system of quality management process of distribution of electric power in heterogeneous modes under uncertainty. It was developed valuation methods heterogeneous operating mode of SOED, taking into account unsymmetric with stochastic or deterministic nature, in order to raise the effectiveness of process control of electrical energy distribution. With the purpose of identification of heterogeneous regimes as result of non-sinusoidal voltage distortion in SOED a method based on the wavelet analysis and neural network developed and it allows you to recognize a distorted image signal voltage. It was investigated that wavelet Paul can provide various voltage distortion and gain frequency components and their positions at the time axis simultaneously.It was worked out a method for decision support with a equal distribution of SOED using genetic algorithms, which allows you select the Pareto-optimal solutions in terms of reduction of losses and the quantitative re-strapping. Also, it was developed the method of decision-making in SOED by equal distribution of electro-based neural network that uses voltage average of distribution at the maximum loading per the season, thus reducing the additional losses of electricity.In order to assess the quality of the control system functioning of electricity distribution quality in terms of uncertainty it was developed the method, which evaluates a fuzzy extent accordance to standards and quality indicators to track change of electricity quality even if the major parameters do not exceed permissible values.
Schintler, Laurie A., and Manfred M. Fischer. "The Analysis of Big Data on Cites and Regions - Some Computational and Statistical Challenges." WU Vienna University of Economics and Business, 2018. http://epub.wu.ac.at/6637/1/2018%2D10%2D28_Big_Data_on_cities_and_regions_untrack_changes.pdf.
Full textSeries: Working Papers in Regional Science
Downer, Monica Ruth. "Plant Species Richness and Species Area Relationships in a Florida Sandhill." Scholar Commons, 2012. http://scholarcommons.usf.edu/etd/4030.
Full textSchwindt, Daniel [Verfasser], Christof [Gutachter] Kneisel, and Birgit [Gutachter] Terhorst. "Permafrost in ventilated talus slopes below the timberline - A multi-methodological study on the ground thermal regime and its impact on the temporal variability and spatial heterogeneity of permafrost at three sites in the Swiss Alps / Daniel Schwindt. Gutachter: Christof Kneisel ; Birgit Terhorst." Würzburg : Universität Würzburg, 2013. http://d-nb.info/111204003X/34.
Full textFreitas, Dalila Viana de [UNESP]. "Estrutura e distribuição espacial de Calophyllum brasiliense Cambess. (Clusiaceae), em uma floresta de restinga, no Parque Estadual da Serra do Mar, núcleo Picinguaba, Ubatuba - SP." Universidade Estadual Paulista (UNESP), 2009. http://hdl.handle.net/11449/87895.
Full textEstudos abrangendo aspectos da ecologia populacional de plantas fornecem informações importantes sobre os processos de regeneração, ocorrência de perturbações e os meios pelos quais as espécies exploram seus ambientes. Estudos dessa natureza em Florestas de Restinga, feições marcantes no litoral brasileiro, ainda são escassos. Assim, no presente trabalho foram investigados alguns aspectos da ecologia populacional de Calophyllum brasiliense Cambess. (Clusiaceae), uma espécie de ampla ocorrência em ambienteis sujeitos à inundação nas florestas Neotropicais, em 0,5 ha de Floresta de Restinga, localizada no Parque Estadual da Serra do Mar, Núcleo Picinguaba, Ubatuba, SP. Foi realizada uma análise temporal da estrutura de tamanho e do padrão de distribuição espacial da população, visando compreender como a heterogeneidade ambiental, relacionada às variações na microtopografia (mosaico de regiões sobre e entre cordões arenosos), na abertura do dossel da floresta e nas condições de drenagem do solo, afeta os parâmetros da estrutura populacional analisados. Observou-se que a população apresenta estrutura com predomínio de indivíduos nas menores classes de tamanho e distribuição agregada em todas as classes (plântulas, jovens, imaturos e adultos). A saturação hídrica do solo e as diferenças na microtopografia dos cordões arenosos influenciaram o padrão encontrado e afetaram os parâmetros demográficos, entretanto, não foram encontradas correlações entre a abertura de dossel e os parâmetros analisados. Além disso, a análise da estrutura de tamanho em subclasses de altura revelou ausência de indivíduos com alturas entre três e 15 metros, o que pode ser um indicativo de que apesar da população apresentar representantes em todas as classes de tamanho, o acesso dos indivíduos à classe reprodutiva está comprometido...
Studies concerning plant population ecology provide important information about status of regeneration, occurrence of disturbances and the means by which the species exploit the environment. Studies like these, in the “Restingas” forests, striking features in the Brazilian coast, are still scarce. Therefore, we investigated some aspects of population ecology of Calophyllum brasiliense Cambess. (Clusiaceae), in 0.5 ha of the Restinga Forest, in the “Parque Estadual da Serra do Mar”, “Núcleo Picinguaba”, Municipality of Ubatuba, São Paulo State. We performed a temporal analysis of size structure and spatial pattern, to understand how the environmental heterogeneity, such as microtopography variations, light availability and soil drainage conditions can affect the population structure. Population structure presented dominance of individuals in lower size classes as well as aggregated distribution. These patterns result of both drainage and microtopography conditions, however, no correlations were found between canopy openness and the parameters analyzed. In addition, the size structure analysis, performed into different height classes, showed no individuals with heights between 3 and 15 m, which can suggest that the access to reproductive class seems to be compromised, even though there were individuals within all size classes. It was also observed a high frequency of herbivory damage; however, such damage did not contribute to increase the mortality rate of the population. In general, it could be concluded that environmental heterogeneity has a major influence on the size structure and spatial distribution, mainly in smaller size classes, and that the population seems to have trouble reaching the reproductive stage, which can lead, as a long term, to its disappearance in the area.
Koutchade, Obafèmi-Philippe. "Hétérogénéité inobservée et solutions en coin dans les modèles micro-économétriques de choix de production multiculture." Thesis, Rennes, Agrocampus Ouest, 2018. http://www.theses.fr/2018NSARE048/document.
Full textIn this thesis, we are interested in questions of unobserved heterogeneity and corner solutions in acreage choice models. To answer these questions, we rely on a NMNL acreage share multi-crop models, of which we propose extensions. These extensions lead to specific estimation problems, to which we provide solutions.The question of unobserved heterogeneity is dealt with by considering a random parameter specification. This allows us to take into account the effects of the unobserved heterogeneity on all the parameters of the model. We show that the stochastic versions of the EM algorithm are particularly suitable for estimating this type of modelOur estimation and simulation results show that farmers react heterogeneously to economic incentives and that ignoring this heterogeneity can lead to biased simulated effects of public policies.In order to take account of the corner solutions in acreage choices, we propose modelling based on endogenous regime switching models with regime fixed costs. Unlike approaches based on censored regression systems, our model is “fully” consistent from a micro-economic viewpoint. Our results show that the regime fixed costs play an important role in farmers’ choice to produce or not some crops and they are, in the short term, an important determinant of acreage choices
Moreira, Ana Sofia Pereira. "Study of modifications induced by thermal and oxidative treatment in oligo and polysaccharides of coffee by mass spectrometry." Doctoral thesis, Universidade de Aveiro, 2016. http://hdl.handle.net/10773/17074.
Full textOs polissacarídeos são os componentes maioritários dos grãos de café verde e torrado e da bebida de café. Os mais abundantes são as galactomananas, seguindo-se as arabinogalactanas. Durante o processo de torra, as galactomananas e arabinogalactanas sofrem modificações estruturais, as quais estão longe de estar completamente elucidadas devido à sua diversidade e à complexidade estrutural dos compostos formados. Durante o processo de torra, as galactomananas e arabinogalactanas reagem com proteínas, ácidos clorogénicos e sacarose, originando compostos castanhos de alto peso molecular contendo nitrogénio, designados de melanoidinas. As melanoidinas do café apresentam diversas atividades biológicas e efeitos benéficos para a saúde. No entanto, a sua estrutura exata e os mecanismos envolvidos na sua formação permanecem desconhecidos, bem como a relação estrutura-atividade biológica. A utilização de sistemas modelo e a análise por espectrometria de massa permitem obter uma visão global e, simultaneamente, detalhada das modificações estruturais nos polissacarídeos do café promovidas pela torra, contribuindo para a elucidação das estruturas e mecanismos de formação das melanoidinas. Com base nesta tese, oligossacarídeos estruturalmente relacionados com a cadeia principal das galactomananas, (β1→4)-Dmanotriose (Man3), e as cadeias laterais das arabinogalactanas, (α1→5)-Larabinotriose (Ara3), isoladamente ou em misturas com ácido 5-Ocafeoilquínico (5-CQA), o ácido clorogénico mais abundante nos grãos de café verde, e péptidos compostos por tirosina e leucina, usados como modelos das proteínas, foram sujeitos a tratamento térmico a seco, mimetizando o processo de torra. A oxidação induzida por radicais hidroxilo (HO•) foi também estudada, uma vez que estes radicais parecem estar envolvidos na modificação dos polissacarídeos durante a torra. A identificação das modificações estruturais induzidas por tratamento térmico e oxidativo dos compostos modelo foi feita por estratégias analíticas baseadas principalmente em espectrometria de massa, mas também em cromatografia líquida. A cromatografia de gás foi usada na análise de açúcares neutros e ligações glicosídicas. Para validar as conclusões obtidas com os compostos modelo, foram também analisadas amostras de polissacarídeos do café obtidas a partir de resíduo de café e café instantâneo. Os resultados obtidos a partir dos oligossacarídeos modelo quando submetidos a tratamento térmico (seco), assim como à oxidação induzida por HO• (em solução), indicam a ocorrência de despolimerização, o que está de acordo com estudos anteriores que reportam a despolimerização das galactomananas e arabinogalactanas do café durante a torra. Foram ainda identificados outros compostos resultantes da quebra do anel de açúcares formados durante o tratamento térmico e oxidativo da Ara3. Por outro lado, o tratamento térmico a seco dos oligossacarídeos modelo (individualmente ou quando misturados) promoveu a formação de oligossacarídeos com um maior grau de polimerização, e também polissacarídeos com novos tipos de ligações glicosídicas, evidenciando a ocorrência de polimerização através reações de transglicosilação não enzimática induzidas por tratamento térmico a seco. As reações de transglicosilação induzidas por tratamento térmico a seco podem ocorrer entre resíduos de açúcares provenientes da mesma origem, mas também de origens diferentes com formação de estruturas híbridas, contendo arabinose e manose como observado nos casos dos compostos modelo usados. Os resultados obtidos a partir de amostras do resíduo de café e de café instantâneo sugerem a presença de polissacarídeos híbridos nestas amostras de café processado, corroborando a ocorrência de transglicosilação durante o processo de torra. Além disso, o estudo de misturas contendo diferentes proporções de cada oligossacarídeo modelo, mimetizando regiões do grão de café com composição distinta em polissacarídeos, sujeitos a diferentes períodos de tratamento térmico, permitiu inferir que diferentes estruturas híbridas e não híbridas podem ser formadas a partir das arabinogalactanas e galactomananas, dependendo da sua distribuição nas paredes celulares do grão e das condições de torra. Estes resultados podem explicar a heterogeneidade de estruturas de melanoidinas formadas durante a torra do café. Os resultados obtidos a partir de misturas modelo contendo um oligossacarídeo (Ara3 ou Man3) e 5-CQA sujeitas a tratamento térmico a seco, assim como de amostras provenientes do resíduo de café, mostraram a formação de compostos híbridos compostos por moléculas de CQA ligadas covalentemente a um número variável de resíduos de açúcar. Além disso, os resultados obtidos a partir da mistura contendo Man3 e 5-CQA mostraram que o CQA atua como catalisador das reações de transglicosilação. Por outro lado, nas misturas modelo contendo um péptido, mesmo contendo também 5-CQA e sujeitas ao mesmo tratamento, observou-se uma diminuição na extensão das reações transglicosilação. Este resultado pode explicar a baixa extensão das reações de transglicosilação não enzimáticas durante a torra nas regiões do grão de café mais ricas em proteínas, apesar dos polissacarídeos serem os componentes maioritários dos grãos de café. A diminuição das reações de transglicosilação na presença de péptidos/proteínas pode dever-se ao facto de os resíduos de açúcares redutores reagirem preferencialmente com os grupos amina de péptidos/proteínas por reação de Maillard, diminuindo o número de resíduos de açúcares redutores disponíveis para as reações de transglicosilação. Além dos compostos já descritos, uma diversidade de outros compostos foram formados a partir dos sistemas modelo, nomeadamente derivados de desidratação formados durante o tratamento térmico a seco. Em conclusão, a tipificação das modificações estruturais promovidas pela torra nos polissacarídeos do café abre o caminho para a compreensão dos mecanismos de formação das melanoidinas e da relação estrutura-atividade destes compostos.
Polysaccharides are the major components of green and roasted coffee beans, and coffee brew. The most abundant ones are galactomannans, followed by arabinogalactans. During the roasting process, galactomannans and arabinogalactans undergo structural modifications that are far to be completely elucidated due to their diversity and complexity of the compounds formed. During the roasting process, galactomannans and arabinogalactans react with proteins, chlorogenic acids, and sucrose, originating high molecular weight brown compounds containing nitrogen, known as melanoidins. Several biological activities and beneficial health effects have been attributed to coffee melanoidins. However, their exact structures and the mechanisms involved in their formation remain unknown, as well as the structure-biological activity relationship. The use of model systems and mass spectrometry analysis allow to obtain an overall view and, simultaneously, detailed, of the structural modifications in coffee polysaccharides promoted by roasting, contributing to the elucidation of the structures and formation mechanisms of melanoidins. Based on this thesis, oligosaccharides structurally related to the backbone of galactomannans, (β1→4)-D-mannotriose, and the side chains of arabinogalactans, (α1→5)-Larabinotriose, alone or in mixtures with 5-O-caffeoylquinic acid, the most abundant chlorogenic acid in green coffee beans, and dipeptides composed by tyrosine and leucine, used as models of proteins, were submitted to dry thermal treatments, mimicking the coffee roasting process. The oxidation induced by hydroxyl radicals (HO•) was also studied, since these radicals seem to be involved in the modification of the polysaccharides during roasting. The identification of the structural modifications induced by thermal and oxidative treatment of the model compounds was performed mostly by mass spectrometry-based analytical strategies, but also using liquid chromatography. Gas chromatography was used in the analysis of neutral sugars and glycosidic linkages. To validate the conclusions achieved with the model compounds, coffee polysaccharide samples obtained from spent coffee grounds and instant coffee were also analysed. The results obtained from the model oligosaccharides when submitted to thermal treatment (dry) or oxidation induced by HO• (in solution) indicate the occurrence of depolymerization, which is in line with previous studies reporting the depolymerization of coffee galactomannans and arabinogalactans during roasting. Compounds resulting from sugar ring cleavage were also formed during thermal treatment and oxidative treatment of Ara3. On the other hand, the dry thermal treatment of the model oligosaccharides (alone or when mixed) promoted the formation of oligosaccharides with a higher degree of polymerization, and also polysaccharides with new type of glycosidic linkages, evidencing the occurrence of polymerization via non-enzymatic transglycosylation reactions induced by dry thermal treatment. The transglycosylation reactions induced by dry thermal treatment can occur between sugar residues from the same origin, but also of different origins, with formation of hybrid structures, containing arabinose and mannose in the case of the model compounds used. The results obtained from spent coffee grounds and instant coffee samples suggest the presence of hybrid polysaccharides in these processed coffee samples, corroborating the occurrence of transglycosylation during the roasting process. Furthermore, the study of mixtures containing different proportions of each model oligosaccharide, mimicking coffee bean regions with distinct polysaccharide composition, subjected to different periods of thermal treatment, allowed to infer that different hybrid and non-hybrid structures may be formed from arabinogalactans and galactomannans, depending on their distribution in the bean cell walls and on roasting conditions. These results may explain the heterogeneity of melanoidins structures formed during coffee roasting. The results obtained from model mixtures containing an oligosaccharide (Ara3 or Man3) and 5-CQA and subjected to dry thermal treatment, as well as samples derived from spent coffee grounds, showed the formation of hybrid compounds composed by CQA molecules covalently linked to a variable number of sugar residues. Moreover, the results obtained from the mixture containing Man3 and 5-CQA showed that CQA acts as catalyst of transglycosylation reactions. On the other hand, in the model mixtures containing a peptide, even if containing 5-CQA and subjected to the same treatment, it was observed a decrease in the extent of transglycosylation reactions. This outcome can explain the low extent of non-enzymatic transglycosylation reactions during roasting in coffee bean regions enriched in proteins, although polysaccharides are the major components of the coffee beans. The decrease of transglycosylation reactions in the presence of peptides/proteins can be related with the preferential reactivity of reducing residues with the amino groups of peptides/proteins by Maillard reaction, decreasing the number of reducing residues available to be directly involved in the transglycosylation reactions. In addition to the compounds already described, a diversity of other compounds were formed from model systems, namely dehydrated derivatives formed during dry thermal treatment. In conclusion, the identification of the structural modifications in coffee polysaccharides promoted by roasting pave the way to the understanding of the mechanisms of formation of melanoidins and structure-activity relationship of these compounds.
Gaspar, José Maria Lopes. "New Economic Geography: perspectives, multiple regions and individual heterogeneity." Tese, 2017. https://repositorio-aberto.up.pt/handle/10216/105494.
Full textGaspar, José Maria Lopes. "New Economic Geography: perspectives, multiple regions and individual heterogeneity." Doctoral thesis, 2017. https://repositorio-aberto.up.pt/handle/10216/105494.
Full textWu, Hsiu-Hui, and 吳㛢慧. "The Investigation of the Problem of Individual Heterogeneity in Attribution Theory under SEM/SEO Regime." Thesis, 2017. http://ndltd.ncl.edu.tw/handle/ctkw5a.
Full text國立交通大學
經營管理研究所
105
It becomes more difficult for researcher to analyze data from internet or company due to data increases dramatically. Therefore, when researcher intends to find the causal relationship from the database to study or decide, the traditional experiment needs to be modified. Fortunately, DID approximation provides a way to solve this problem. When the analysis is made, we should choose independent variable and dependent variable based on theory to avoid tautology mistake. In addition, the individual heterogeneity is also a very important parameter for research results. However, the individual experience of subject may influence his/her attitude in the studying process, and further affect the behavior he/she presents in the study. Once it happens, the truth may be hidden beyond the individual characteristics or thinking and the correct attribution cannot be obtained.
Pereira, Marcelo Gomes Raposo dos Santos. "The cyclical behavior of commodities and their investment benefits." Master's thesis, 2013. http://hdl.handle.net/10071/10201.
Full textAs commodities são conhecidas por exibir um comportamento cíclico. O presente trabalho estuda a dinâmica dos regimes das commodities e as suas propriedades de diversificação da carteira. Utilizando uma extensão do modelo de mudança de regime, observamos que as doze commodities estudadas podem ser agrupadas em quatro classes com diferentes dinâmicas de regime. Este resultado demonstra que as commodities se encontram longe de apresentar um comportamento homogéneo enquanto classe de ativos. A existência de dois regimes é transversal aos ativos estudados. Um dos regimes é marcado por uma alta volatilidade e o outro por uma baixa volatilidade. Em ambos os regimes, a maior parte das commodities estudadas apresenta retornos que não são estatisticamente diferentes dos apresentados pelo mercado de acções. As exceções são o Crude Oil-Brent e o Gás Natural no regime de baixa volatilidade. A análise da sincronização de regimes entre os ativos estudados mostra que a nossa proxy do mercado de ações apresenta uma baixa sincronização com as commodities. Este resultado sugere a existência de um potencial valor de diversificação resultante da adição de commodities a uma carteira de ações. Da construção da fronteira eficiente de portfolio com os ativos estudados para cada um dos regimes da nossa proxy do mercado acionista, verificamos que as commodities têm valor de diversificação quando adicionadas a uma carteira de ações em ambos os regimes. Este valor de diversificação é particularmente evidente no regime de contração do mercado acionista.
"Dielectric Response of Glass-Forming Liquids in the Nonlinear Regime." Doctoral diss., 2016. http://hdl.handle.net/2286/R.I.37049.
Full textDissertation/Thesis
Doctoral Dissertation Chemistry 2016
Schwindt, Daniel. "Permafrost in ventilated talus slopes below the timberline - A multi-methodological study on the ground thermal regime and its impact on the temporal variability and spatial heterogeneity of permafrost at three sites in the Swiss Alps." Doctoral thesis, 2013. https://nbn-resolving.org/urn:nbn:de:bvb:20-opus-90099.
Full textIn den zentralen Alpen kann oberhalb einer Höhe von 2300 m ü NN, bei mittleren Jährlichen Lufttemperaturen von weniger als -1 °C mit Permafrost gerechnet werden. Isolierte Permafrostvorkommen können jedoch in nordexponierten Hangschutthalden bei positiven Jahresmitteltemperaturen bis weit unterhalb der Waldgrenze gefunden werden. Ziel dieser Arbeit ist es ein tieferes Verständnis des Faktorenkomplexes zu erreichen, der das standortspezifische, kleinräumige thermale Regime bedingt und damit die räumlich begrenzten, zeitlich hochvariablen Permafrostvorkommen in Hangschutthalden unterhalb der Waldgrenze steuert und ermöglicht. Drei unterkühlte Hangschutthalden in den Schweizer Alpen wurden zur Untersuchung ausgewählt. Bei der Auswahl wurde im Speziellen auf fundamentale Unterschiede der Standortfaktoren Wert gelegt. Im Unterengadin gelegen sind die klimatischen Bedingungen, Höhenlage sowie die Dimensionen der Hangschutthalden an den Standorten Val Bever und Val Susauna vergleichbar; Eigenschaften des Hangschuttes, Charakteristik der organischen Auflage sowie der Vegetation unterscheiden sich. Der in den Appenzeller Alpen gelegenen Standort Brüeltobel unterscheidet sich in Bezug auf die klimatischen Bedingungen, der Höhenlage und der Ausmaße der Hangschutthalde deutlich, zeigt jedoch eine zum Val Susauna ähnliche Humus- und Vegetationscharakteristik. Der Nachweis und die Charakterisierung von Untergrundeis basiert auf der Kombination von elektrischer Widerstandstomographie und seismischer Refraktionstomographie. Zur Detektion der räumlichen Verbreitung von Untergrundeis wurden diese Methoden durch quasi-3D Widerstandstomographie ergänzt. Zum Nachweis von Permafrost und zur Analyse seiner zeitlichen Variabilität wurden Monitoringauslagen konstruiert und an den Standorten fest installiert. Widerstandsmessungen wurden ganzjährig durchgeführt. In Ergänzung zu dem Widerstandsmonitoring wurde im Val Susauna erstmalig seismische Refraktionstomographie zum Monitoring der Permafrostentwicklung im Winter durchgeführt. Die Analyse des thermalen Regimes basiert auf der Analyse von Temperaturlogger Daten. Dabei wurden neben Luft- und Bodentemperaturen vor allem die Temperaturentwicklung in den Schloten sowie in der Humusauflage berücksichtigt. Zur Untersuchung des Zusammenhangs der Permafrostverbreitung mit der Humus- und Vegetationscharakteristik wurde im Val Susauna eine Kartierung der Humuseigenschaften sowie der Vegetationszusammensetzung durchgeführt. An allen untersuchten Standorten konnte Permafrost nachgewiesen werden. Räumlich sind die Permafrostkörper sehr scharf von benachbarten Hangbereichen abgegrenzt. Am Standort Val Susauna konnte ein hoher räumlicher Zusammenhang zwischen der Permafrostverbreitung und Bereichen mit besonders mächtiger Humusauflage, einem hohen Anteil an Moosen und Flechten im Unterwuchs sowie einem ausgeprägtem Zwergwuchs nachgewiesen werden. Die zeitliche Variabilität des Permafrost hat sich an allen Standorten als außergewöhnlich hoch herausgestellt. Dabei übersteigt die Magnitude der saisonalen Variabilität die mehrjährigen Veränderungen deutlich. Das Winterhalbjahr zeigt sich durch eine effiziente Unterkühlung geprägt. Die Schneeschmelze im Frühling steht in Verbindung mit einem deutlichen Eiszuwachs, der durch ein wiedergefrieren des versickernden Schmelzwassers an dem unterkühlten Hangschutt verursacht wird. Die Ergebnisse haben den fundamentalen Einfluss des Chimney Effekt auf die Existenz und zeitliche Variabilität von Permafrost in Hangschutthalden bestätigt. Unterschiede in der Wirkungsweise des thermalen Regimes konnten herausgestellt werden, die in erster Linie auf die unterschiedliche Ausprägung der Humusauflage, Charakteristik des Hangschutts, und die Vegetationszusammensetzung zurückzuführen sind. Während des Sommers ermöglicht die sehr geringe thermische Leitfähigkeit der im oberflächennahen Bereich meist recht trockenen organischen Auflage eine ausgeprägte Isolation des Untergrundes gegenüber hohen Außentemperaturen. Die in grobblockigen Hangschutthalden zu findende ungleichmäßige, von Blockmaterial fragmentierte organische Auflage zeigt eine deutlich geringere Isolationsfähigkeit und ermöglicht einen effektiven, Wärmeaustausch durch Konvektion und perkolierendes Niederschlagswasser. Im Winterhalbjahr steigt die thermische Leitfähigkeit des organischen Materials unter durchfeuchteten sowie gefrorenen Bedingungen massiv an und ermöglicht eine effiziente Auskühlung der Hangschutts. Die Unterkühlung in grobblockigen Hangschutthalden zeigt aufgrund des auch im Winter ausgeprägten konvektiven Wärmeflusses eine höhere Magnitude und ein früheres Einsetzen als bei homogenen Humusauflagen, wo konduktiver Wärmefluss dominiert und eine Auskühlung im Herbst durch eine ausgeprägte zero-curtain Periode gepuffert wird. Der Einfluss der Schneedecke auf das thermale Regime ist insgesamt gering; ihre Isolationsfähigkeit ist, annähernd unabhängig von der Schneemächtigkeit, stark reduziert
Gbohoui, William Dieudonné Yélian. "Essays on the Effects of Corporate Taxation." Thèse, 2016. http://hdl.handle.net/1866/13976.
Full textThis thesis is a collection of three papers in macroeconomics and public finance. It develops Dynamic Stochastic General Equilibrium Models with a special focus on financial frictions to analyze the effects of changes in corporate tax policy on firm level and macroeconomic aggregates. Chapter 1 develops a dynamic general equilibrium model with a representative firm to assess the short-run effects of changes in the timing of corporate profit taxes. First, it extends the Ricardian equivalence result to an environment with production and establishes that a temporary corporate profit tax cut financed by future tax-increase has no real effect when the tax is lump sum and capital markets are perfect. Second, I assess how strong the ricardian forces are in the presence of financing frictions. I find that when equity issuance is costly, and when the firm faces a lower bound on dividend payments, a temporary tax cut reduces temporary the marginal cost of investment and implies positive marginal propensity of investment. Third, I analyze how do the intertemporal substitution effects of tax cuts interact with the stimulative effects when tax is not lump-sum. The results show that when tax is proportional to corporate profit, the expectations of high future tax rates reduce the expected marginal return on investment and mitigate the stimulative effects of tax cuts. The net investment response depends on the relative strength of each effect. Chapter 2 is co-authored with Rui Castro. In this paper, we quantify how effective temporary corporate tax cuts are in stimulating investment and output via relaxation of financing frictions. In fact, policymakers often rely on temporary corporate tax cuts in order to provide incentives for business investment in recession times. A common motivation is that such policies help relax financing frictions, which might bind more during recessions. We assess whether this mechanism is effective. In an industry equilibrium model where some firms are financially constrained, marginal propensities to invest are high. We consider a transitory corporate tax cut, funded by public debt. By increasing current cash flows, corporate tax cuts are effective at stimulating current investment. On impact, aggregate investment increases by 26 cents per dollar of tax stimulus, and aggregate output by 3.5 cents. The stimulative output effects are long-lived, extending past the period the policy is reversed, leading to a cumulative effect multiplier on output of 7.2 cents. A major factor preventing larger effects is that this policy tends to significantly crowd out investment among the larger, unconstrained firms. Chapter 3 studies the effects of the 1992's U.S. Treasury Department proposal of a Comprehensive Business Income Tax (CBIT) reform. According to the U.S. tax code, dividend and capital gain are taxed at the firm level and further taxed when distributed to shareholders. This double taxation may reduce the overall return on investment and induce inefficient capital allocation. Therefore, tax reforms have been at the center of numerous debates among economists and policymakers. As part of this debate, the U.S. Department of Treasury proposed in 1992 to abolish dividend and capital gain taxes, and to use a Comprehensive Business Income Tax (CBIT) to levy tax on corporate income. In this paper, I use an industry equilibrium model where firms are subject to financing frictions, and idiosyncratic productivity and entry/exit shocks to assess the long run effects of the CBIT. I find that the elimination of the capital gain and dividend taxes is not self financing. More precisely, the corporate profit tax rate should be increased from 34\% to 42\% to keep the reform revenue-neutral. Overall, the results show that the CBIT reform reduces capital accumulation and output by 8\% and 1\%, respectively. However, it improves capital allocation by 20\%, resulting in an increase in aggregate productivity by 1.41\% and in a modest welfare gain.
(8741097), Ritwik Bandyopadhyay. "ENSURING FATIGUE PERFORMANCE VIA LOCATION-SPECIFIC LIFING IN AEROSPACE COMPONENTS MADE OF TITANIUM ALLOYS AND NICKEL-BASE SUPERALLOYS." Thesis, 2020.
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