Relevant bibliographies by topics / Green sustainable chemistry

Contents

  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers
  6. Reports

Academic literature on the topic 'Green sustainable chemistry'

Author: Grafiati
Published: 11 July 2023

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Journal articles on the topic "Green sustainable chemistry"

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KARAGÖLGE, Zafer, and Bahri GÜR. "Sustainable Chemistry: Green Chemistry." Journal of the Institute of Science and Technology 6, no. 2 (June 20, 2016): 89. http://dx.doi.org/10.21597/jist.2016218851.

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Payal Rathi, Saba Nausheen, and Nisha. "Green chemistry and technology for sustainable development." International Journal of Science and Research Archive 8, no. 2 (March 30, 2023): 161–65. http://dx.doi.org/10.30574/ijsra.2023.8.2.0225.

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Green chemistry is one of the most explored topics these days. Major research on green chemistry aims to reduce or eradicate the production of harmful bi-products and maximizing the desired product in an eco friendly way. The green chemistry is required to minimize the harm of the nature by anthropogenic materials and the processes applied to generate them. Green chemistry indicates research emerges from scientific discoveries about effluence responsiveness. Green chemistry involves 12 principals which minimize or eliminates the use or production of unsafe substances. Scientists and Chemists can significantly minimize the risk to environment and health of human by the help of all the valuable ideology of green chemistry. The principles of green chemistry can be achieved by the use environmental friendly, harmless, reproducible and solvents and catalysts during production of medicine, and in researches. Green chemistry could include anything from reducing waste to even disposing of waste in the correct manner. All chemical wastes should be disposed of in the best possible manner without causing any damage to the environment and living beings. This article presents selected examples of implementation of green chemistry principles in everyday life.
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Lattes, Armand, and Isabelle Rico-Lattes. "Green and sustainable chemistry." Comptes Rendus Chimie 14, no. 7-8 (July 2011): 619–20. http://dx.doi.org/10.1016/j.crci.2011.07.007.

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Abyzbekova, G. M., D. K. Ongar, A. S. Tapalova, S. O. Espenbetova, K. Sh Arynova, and G. T. Balykbaeva. "GREEN CHEMISTRY IS THE KEY TO SUSTAINABLE DEVELOPMENT." Bulletin of Korkyt Ata Kyzylorda University 57, no. 2 (2021): 100–105. http://dx.doi.org/10.52081/bkaku.2021.v57.i2.042.

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It speaks of the emergence of the Green Chemistry direction, which has become the philosophy of thinking of all chemists, the pace of development in the world, 12 principles and the metric of green chemistry, significance. Directions for the development of green chemistry, its development in the countries of the world and the work carried out in this direction in universities were outlined. New chemical reaction and process schemes developed in many laboratories around the world are designed to radically reduce the environmental impact of large-scale chemical production. Manufacturers of chemical hazards arising from the use of an aggressive environment traditionally try to reduce the connection of workers with these substances, limiting their connection.At the same time, green chemistry offers another strategy - a careful selection of starting materials and technological schemes that exclude the use of harmful substances. Thus, green chemistry is a kind of technology that allows not only to obtain the necessary substance, but also to obtain it at all stages of production by means that are not harmful to the environment. On the development of green chemical education in the countries of the world and the work carried out at the university in this direction. Keywords: sustainable development, green chemistry, E-factor, atomic efficiency, green chemical formation
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Misono, Makoto. "Sustainable Society and Green Chemistry." TRENDS IN THE SCIENCES 10, no. 6 (2005): 78–81. http://dx.doi.org/10.5363/tits.10.6_78.

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Popa, Valentin, and Irina Volf. "GREEN CHEMISTRY AND SUSTAINABLE DEVELOPMENT." Environmental Engineering and Management Journal 5, no. 4 (2006): 545–58. http://dx.doi.org/10.30638/eemj.2006.042.

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Tundo, Pietro, and Elena Griguol. "Green Chemistry for Sustainable Development." Chemistry International 40, no. 1 (January 1, 2018): 18–24. http://dx.doi.org/10.1515/ci-2018-0105.

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Centi, Gabriele, and Siglinda Perathoner. "Catalysis and sustainable (green) chemistry." Catalysis Today 77, no. 4 (January 2003): 287–97. http://dx.doi.org/10.1016/s0920-5861(02)00374-7.

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Cole-Hamilton, David J. "EuCheMS – Green and Sustainable Chemistry." Green Chemistry 17, no. 4 (2015): 2281–82. http://dx.doi.org/10.1039/c5gc90018b.

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Dutta, Pinak, and Mita Dutta. "MULTICOMPONENT REACTIONS: GREEN HOPE TOWARD SUSTAINABLE DEVELOPMENT." RASAYAN Journal of Chemistry 15, no. 03 (2022): 1728–34. http://dx.doi.org/10.31788/rjc.2022.1536854.

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Practicing sustainable chemistry is one of the best ways to address ‘man-made’ environmental perils. The decorum set by the laws of green chemistry can lead us towards mitigating such menace. Multi-component reactions are one such weapon in the armoury of a chemist towards developing and inventing commodities ranging from life-saving drugs to lifestyle products through sustainable synthetic methodologies. Though much advancement is accomplished in developing such reactions, a correlation between ‘environmentally benign operation’ and ‘mere synthesis’ is yet to be realized. Herein, we have tried to highlight the gradual advancement of this procedure and what still needs to be achieved to entice the philosopher within ourselves towards greener thoughts and ideas.
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Dissertations / Theses on the topic "Green sustainable chemistry"

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Stanley, Jessica. "Novel applications of catalysis for green and sustainable chemistry." Thesis, The University of Sydney, 2014. http://hdl.handle.net/2123/12679.

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This thesis examines fundamental studies of catalysts for more sustainable processes, addressing three particular challenges: (1) Developing sulfur resistant catalysts that have potential applications in the processing of biomass for the production of liquid transportation fuels. (2) Reducing energy requirements and increasing the catalyst ease-of-use (especially water tolerance) for the hydrogenation of aromatics, particularly for the safe and feasible storage of hydrogen using the reversible toluene/methylcyclohexane couple. (3) Catalytically converting models of lignin building blocks as a source for renewable aromatic chemicals.
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Stanley, Jessica Nicole Gonzalo <1987&gt. "Novel applications of catalysis for green and sustainable chemistry." Doctoral thesis, Università Ca' Foscari Venezia, 2014. http://hdl.handle.net/10579/5655.

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This thesis examines fundamental studies of catalysts for more sustainable processes, addressing three particular challenges: (1) Developing sulfur resistant catalysts that have potential applications in the processing of biomass for the production of liquid transportation fuels. (2) Reducing energy requirements and increasing the catalyst ease-of-use (especially water tolerance) for the hydrogenation of aromatics, particularly for the safe and feasible storage of hydrogen using the reversible toluene/methylcyclohexane couple. (3) Catalytically converting models of lignin building blocks as a source for renewable aromatic chemicals.
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Marus, Gregory Alan. "The application of green chemistry and engineering to novel sustainable solvents and processes." Diss., Georgia Institute of Technology, 2011. http://hdl.handle.net/1853/43755.

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The implementation of sustainable solvents and processes is critical to new developments in reducing environmental impact, improving net efficiency, and securing economic profitability in the chemical and pharmaceutical industries. In order to address the challenge of sustainability, researchers have used switchable solvents for both reaction and separation by utilizing a built-in switch to undergo a step change in chemical and physical properties. This allows us to facilitate reactions in the solvent then activate the switch to enable separation and facile product recovery. Subsequently, we can recover the solvent for reuse and avoid energy- or waste-intensive separation processes; thus we are developing and using these switchable solvents as sustainable and environmentally benign alternatives to traditional processes. In this research, we enable the sustainable scale-up of a switchable solvent - piperylene sulfone - a "volatile" and recyclable DMSO replacement. In the development of this process, we improved the reaction performances and developed a green purification method. Furthermore, we enable and demonstrate the implementation of a Meerwein-Ponndorf-Verley (MPV) reduction, a pharmaceutically relevant reaction, into a continuous flow platform. The innovation of continuous flow processes can replace traditional batch reaction technology, and is indeed a key research area that has been acknowledged by the pharmaceutical industry. Additionally, we utilize the switchable sulfone solvents, piperylene and butadiene sulfone, for reaction and separation of HMF produced from monosaccharides as an alternative to a process which has been limited by an inefficient separation step.
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CATERINA, RISI. "Studies on organic synthesis through sustainable catalysis." Doctoral thesis, Università di Siena, 2020. http://hdl.handle.net/11365/1094721.

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Today the development of sustainable processes in the chemical industry is critical, and Green Chemistry represents an evolution from the conventional concepts of process efficiency. Twenty years ago, Paul Anastas and John Warner introduced this concept within the twelve principles. In this work, many aspects the twelve principles are applied, developing sustainable methods involving the use of metal catalysis and biocatalysis through one pot and cascade reactions.
In the first part of the PhD period, the use of the micellar catalysis was investigated, to perform reactions in water avoiding (or limiting) the use of the traditional organic solvents. The possibility to apply the micellar conditions for the hydrogen borrowing (HB) reaction to prepare amines was explored. Different Ru catalysts were screened using water as medium, under Microwave (MW) dielectric heating. Once optimized, the scope of the reaction was investigated using differently substituted amines and alcohols. Besides, the use of a biomass-derived solvent (GVL) was explored in Pd/C catalysed transformations to avoid the arching phenomena frequently observed using conventional solvents (e.g. toluene). A sustainable protocol for the synthesis of benzimidazoles employed different aliphatic and aromatic amines through a hydrogen transfer Pd/C. A heating profile and various studies of stability have been reported. A biocatalytic approach to pyridine and furans is also reported. These heterocycles are fundamental building blocks for the synthesis of pharmaceuticals, agrochemicals and organic material. Furthermore, these compounds are also employed in flavour and fragrance industry owing to their peculiar olfactory properties. Classical methodologies for their synthesis are based on low-yielding multistep methods, which involve the use of harsh conditions. Therefore, novel mild and greener methodologies for the preparation of heterocycles compounds are highly desirable. Aromatization of substituted 1,2,3,6-tetrahydropyridines (THPs) was performed using whole-cell monoamine oxidase MAO-N (variants from Aspergillus niger) catalyst. The aromatization of the tetrahydropyridine starting materials into the pyridine products was monitored through 1H NMR spectroscopy. During the optimization, different pyridine compounds are prepared to screen the best co-solvents and MAO-N variants. The kinetic profile of the biocatalytic transformation by MAO-N was also monitored via in situ 19F NMR experiments. Aromatization of different 2,5-dihydrofurans into corresponding furans was also performed using the Laccase/TEMPO catalytic system using mild conditions. A chemo- enzymatic cascade reaction starting directly from acyclic aliphatic precursor has been developed showing that metathesis Grubb's catalyst and the Laccase/TEMPO system can be used in combination for an efficient protocol.
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CALASCIBETTA, ADIEL MAURO. "SUSTAINABLE SYNTHETIC METHODOLOGIES FOR THE PREPARATION OF ORGANIC SEMICONDUCTING MATERIALS: ORGANIC (OPTO)ELECTRONICS GROWING “GREEN”." Doctoral thesis, Università degli Studi di Milano-Bicocca, 2021. http://hdl.handle.net/10281/312085.

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The worldwide demand for energy-efficient and high-performing (opto)electronics, along with the increasing need for economically feasible and environmentally friendly chemistry, both require semiconducting materials that are both scalable and sustainable. The concern with waste generation and toxic/hazardous chemicals usage has already moulded many operations in chemical and manufacturing industries. To date, common syntheses to access organic semiconductors require the use of large quantities of toxic and/or flammable organic solvents, often involving reagents and by-products that are harmful to health and environment. Research in the field of organic electronics is now increasingly focusing on the development of new sustainable methodologies that allow to prepare active materials in a more efficiently way, caring further on safety and sustainability associated with production processes. The immediate approach applicable consist on the removal, or at least on the minimization, of harmful and toxic substances commonly employed within standard processes. The big elephant in the room in the synthesis of active materials is the amount of organic solvent employed, which could ideally be reduced by using aqueous solution of surfactants: in these nano/micro heterogeneous environments organic transformations can happen and often with unprecedent efficiency. Clearly, the process occur not through the dissolution of the reagents (starting materials and catalyst) but from their dispersion in water. Kwon as “micellar catalysis”, this strategy has proven to be highly effective on improving sustainability becoming a prominent topic in modern organic synthesis. In particular, the micellar catalysis strategy is compatible with the most common modern strategies employed for C-C and C-heteroatom bonds forming reactions and allow to perform reactions with high yields, in water and under very mild conditions. Nonetheless, the use of such method in the field of organic semiconductors is still limited, with only few relevant examples reported in literature concerning the preparation of π-conjugated molecular and polymeric materials. This Thesis describes the importance of introducing sustainability in the synthesis of organic semiconductors, satisfying several principles of the green chemistry guidance. Our research purpose is not to provide an exhaustive list of examples of such chemistry, but rather to identify a few key developments in the field that seem especially suited to large-scale synthesis. Then, the discussion will consider the synthetic approaches typically employed to access semiconducting materials with extended π-conjugated structures. In particular, the discussion will involve the well-known Pd-catalysed cross-coupling techniques. Finally, the topic of the work will focus on micro-heterogeneous environments as a new tool for introducing sustainability in the preparation of active materials in water, satisfying several criteria relevant to green chemistry. On my opinion, the micellar catalysis approach constitute today the more promising method to lower the overall cost and environmental impact in the production of organic semiconductors without affecting yields, purity, and device performance.
The worldwide demand for energy-efficient and high-performing (opto)electronics, along with the increasing need for economically feasible and environmentally friendly chemistry, both require semiconducting materials that are both scalable and sustainable. The concern with waste generation and toxic/hazardous chemicals usage has already moulded many operations in chemical and manufacturing industries. To date, common syntheses to access organic semiconductors require the use of large quantities of toxic and/or flammable organic solvents, often involving reagents and by-products that are harmful to health and environment. Research in the field of organic electronics is now increasingly focusing on the development of new sustainable methodologies that allow to prepare active materials in a more efficiently way, caring further on safety and sustainability associated with production processes. The immediate approach applicable consist on the removal, or at least on the minimization, of harmful and toxic substances commonly employed within standard processes. The big elephant in the room in the synthesis of active materials is the amount of organic solvent employed, which could ideally be reduced by using aqueous solution of surfactants: in these nano/micro heterogeneous environments organic transformations can happen and often with unprecedent efficiency. Clearly, the process occur not through the dissolution of the reagents (starting materials and catalyst) but from their dispersion in water. Kwon as “micellar catalysis”, this strategy has proven to be highly effective on improving sustainability becoming a prominent topic in modern organic synthesis. In particular, the micellar catalysis strategy is compatible with the most common modern strategies employed for C-C and C-heteroatom bonds forming reactions and allow to perform reactions with high yields, in water and under very mild conditions. Nonetheless, the use of such method in the field of organic semiconductors is still limited, with only few relevant examples reported in literature concerning the preparation of π-conjugated molecular and polymeric materials. This Thesis describes the importance of introducing sustainability in the synthesis of organic semiconductors, satisfying several principles of the green chemistry guidance. Our research purpose is not to provide an exhaustive list of examples of such chemistry, but rather to identify a few key developments in the field that seem especially suited to large-scale synthesis. Then, the discussion will consider the synthetic approaches typically employed to access semiconducting materials with extended π-conjugated structures. In particular, the discussion will involve the well-known Pd-catalysed cross-coupling techniques. Finally, the topic of the work will focus on micro-heterogeneous environments as a new tool for introducing sustainability in the preparation of active materials in water, satisfying several criteria relevant to green chemistry. On my opinion, the micellar catalysis approach constitute today the more promising method to lower the overall cost and environmental impact in the production of organic semiconductors without affecting yields, purity, and device performance.
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Downs, Emma. "An Investigation of Transition Metal Catalysts for Cyanohydrin Hydration: The Interface of Homogeneous and Heterogeneous Catalysis." Thesis, University of Oregon, 2014. http://hdl.handle.net/1794/18348.

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Acrylic monomers are important materials that represent a large portion of the economy. The current industrial synthesis hydrates cyanohydrins with sulfuric acid, a process which results in large amounts of waste and significant energy costs. A transition metal catalyzed, acid free hydration of cyanohydrins would be beneficial from both economic and environmental standpoints. However, this reaction is challenging, as many catalysts are poisoned by the cyanide released when cyanohydrins degrade. Therefore the development of a catalyst that is resistant to cyanide poisoning is the ideal method to circumvent these difficulties. This dissertation describes several cyanohydrin hydration catalysts, with an emphasis on nanoparticle catalysts. These are at the interface between the homogeneous and heterogeneous catalysts that have been explored previously for this reaction. Chapter I surveys previous studies on nanoparticle catalysts for nitrile hydration and their implications for the hydration of cyanohydrins. Chapter II reports on the homogeneous platinum catalysts [PtHCl(P(NMe2)3)2] and [PtH2(P(NMe2)3)2], exploring secondary coordination sphere effects to enhance nitrile hydration. Chapter III describes another example of this type of complex, [PtH2(P(OMe)3)2], that forms catalytically active nanoparticles under reaction conditions. Explorations of the reactivity of this catalyst with nitriles and cyanohydrins are also described in this chapter. Chapter IV investigates a silver nanoparticle catalyst with a water soluble phosphine (1,3,5-triaza-7-phosphaadamantane) ligand for its activity towards the hydration of nitriles and cyanohydrins. The results of the degradation of the nanoparticles in the presence of cyanide are also described. Chapter V reports on the preparation and examination of a solid supported nickel catalyst for cyanohydrin hydration. Finally, Chapter VI describes how these investigations have made progress towards the development of a cyanide resistant nitrile hydration catalyst. This dissertation includes previously published and unpublished co-authored material.
2015-09-29
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Hellman, Oskar. "Synthesis of framework porous sorbents using sustainable precursors." Thesis, Uppsala universitet, Nanoteknologi och funktionella material, 2021. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-445896.

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Metal organic frameworks (MOFs) is a quite recently discovered porous material group which shows potential in many different areas. One of these areas is carbon capture; the framework structure of the porous materials allows gas molecules to adsorb to the surface of the pores. MOFs are conventionally synthesised at high temperatures and with hazardous solvents. The goal of this projectwas to synthesise highly porous MOFs at room temperature with water as the main solvent, using environmentally friendly and non-hazardous precursors. As well as the room temperature synthesis, conventional synthesis methods were used with the same precursors as comparison. The materials were characterised with X-ray diffraction, thermogravimetrical methods and IR-spectroscopy. To assess the porosity of the materials, gas adsorption evaluation was performed with CO2, N2, SF6, and CH4 at 20⁰C. In the end, three novel porous magnesium-based materials and one zirconium-based material were successfully synthesised. One of the magnesium-based materials showed a moderately high CO2 adsorption (2.38mmol/g), and could be synthesised at room temperature. The zirconium-based material showed a remarkably high selectivity (17.7) for SF6 over N2 and a high surface area (550m2/g)
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Shearouse, William C. "Development and mechanistic understanding of ball milling as a sustainable alternative to traditional synthesis." University of Cincinnati / OhioLINK, 2012. http://rave.ohiolink.edu/etdc/view?acc_num=ucin1353089340.

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Falco, Camillo. "Sustainable biomass-derived hydrothermal carbons for energy applications." Phd thesis, Universität Potsdam, 2012. http://opus.kobv.de/ubp/volltexte/2012/5978/.

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The need to reduce humankind reliance on fossil fuels by exploiting sustainably the planet renewable resources is a major driving force determining the focus of modern material research. For this reason great interest is nowadays focused on finding alternatives to fossil fuels derived products/materials. For the short term the most promising substitute is undoubtedly biomass, since it is the only renewable and sustainable alternative to fossil fuels as carbon source. As a consequence efforts, aimed at finding new synthetic approaches to convert biomass and its derivatives into carbon-based materials, are constantly increasing. In this regard, hydrothermal carbonisation (HTC) has shown to be an effective means of conversion of biomass-derived precursors into functional carbon materials. However the attempts to convert raw biomass, in particular lignocellulosic one, directly into such products have certainly been rarer. Unlocking the direct use of these raw materials as carbon precursors would definitely be beneficial in terms of HTC sustainability. For this reason, in this thesis the HTC of carbohydrate and protein-rich biomass was systematically investigated, in order to obtain more insights on the potentials of this thermochemical processing technique in relation to the production of functional carbon materials from crude biomass. First a detailed investigation on the HTC conversion mechanism of lignocellulosic biomass and its single components (i.e. cellulose, lignin) was developed based on a comparison with glucose HTC, which was adopted as a reference model. In the glucose case it was demonstrated that varying the HTC temperature allowed tuning the chemical structure of the synthesised carbon materials from a highly cross-linked furan-based structure (T = 180oC) to a carbon framework composed of polyaromatic arene-like domains. When cellulose or lignocellulosic biomass was used as carbon precursor, the furan rich structure could not be isolated at any of the investigated processing conditions. These evidences were indicative of a different HTC conversion mechanism for cellulose, involving reactions that are commonly observed during pyrolytic processes. The evolution of glucose-derived HTC carbon chemical structure upon pyrolysis was also investigated. These studies revealed that upon heat treatment (Investigated temperatures 350 – 900 oC) the furan-based structure was progressively converted into highly curved aromatic pre-graphenic domains. This thermal degradation process was observed to produce an increasingly more hydrophobic surface and considerable microporosity within the HTC carbon structure. In order to introduce porosity in the HTC carbons derived from lignocellulosic biomass, KOH chemical activation was investigated as an HTC post-synthesis functionalisation step. These studies demonstrated that HTC carbons are excellent precursors for the production of highly microporous activated carbons (ACs) and that the porosity development upon KOH chemical activation is dependent on the chemical structure of the HTC carbon, tuned by employing different HTC temperatures. Preliminary testing of the ACs for CO2 capture or high pressure CH4 storage yielded very promising results, since the measured uptakes of both adsorbates (i.e. CO2 and CH4) were comparable to top-performing and commercially available adsorbents, usually employed for these end-applications. The combined use of HTC and KOH chemical activation was also employed to produce highly microporous N-doped ACs from microalgae. The hydrothermal treatment of the microalgae substrate was observed to cause the depletion of the protein and carbohydrate fractions and the near complete loss (i.e. 90%) of the microalgae N-content, as liquid hydrolysis/degradation products. The obtained carbonaceous product showed a predominantly aliphatic character indicating the presence of alkyl chains presumably derived from the lipid fractions. Addition of glucose to the initial reaction mixture was found out to be extremely beneficial, because it allowed the fixation of a higher N amount, in the algae derived HTC carbons (i.e.  60%), and the attainment of higher product yields (50%). Both positive effects were attributed to Maillard type cascade reactions taking place between the monosaccharides and the microalgae derived liquid hydrolysis/degradation products, which were in this way recovered from the liquid phase. KOH chemical activation of the microalgae/glucose mixture derived HTC carbons produced highly microporous N-doped carbons. Although the activation process led to a major reduction of the N-content, the retained N-amount in the ACs was still considerable. These features render these materials ideal candidates for supercapacitors electrodes, since they provide extremely high surface areas, for the formation of electric double-layer, coupled to abundant heteroatom doping (i.e. N and O) necessary to obtain a pseudocapacitance contribution.
Die Notwendigkeit, die Abhängigkeit der Menschheit von fossilen Brennstoffen zu reduzieren ist die treibende Kraft hinter aktuellen Forschungsanstrengungen in den Materialwissenschaften. Folglich besteht heutzutage ein erhebliches Interesse daran Alternativen zu Materialien, die aus fossilen Resourcen gewonnen werden, zu finden. Kurzfristig ist zweifellos Biomasse die vielversprechendste Alternative, da sie aus heutiger Sicht die einzige nicht-fossile, nachhaltige und nachwachsende Kohlenstoffquelle ist. Konsequenterweise werden die Antrengungen neue Syntheseansätze zur Konvertierung von Biomasse und ihren Derivaten in kohlenstoffbasierten Materialien forwährend erhöht. In diesem Zusammenhang hat sich die Hydrothermalkarbonisierung (HTC) als sehr vielseitiges Werkzeug zur Konvertierung von Biomasse-basierten Ausgangsstoffen in funktionale Kohlenstoffmaterialien herausgestellt. Dennoch gibt es bisher wenige Ansätze um rohe Biomasse, genauer gesagt Lignicellulose, direkt in funktionale Materialien umzusetzen. Könnte der direkte Einsatz von roher Biomasse Verfahren wie der HTC zugänglich gemacht werden, würde dies die Nachhaltigkeit des Verfahrens immens steigern. Daher wurde in dieser Dissertation die Hydrothermalkarbonisierung von kohlenhydratreicher (d. h. Lignicelluse) und proteinreicher (d. h. Microalgae) Biomasse systematisch analysiert. Diese Untersuchung galt dem Ziel einen besseren Einblick in das Potential dieser thermochemischen Verarbeitungsmethode funktionale Kohlenstoffmaterialien aus unverarbeiteter Biomasse hervorzubringen zu gewinnen. Die hergestellten Materialien wurden mittels chemischer Aktivierung nachträglich weiter behandelt. Dieser zusätzliche Verarbeitungsschritt ermöglichte die Herstellung hochporöser aktiverter Kohlenstoffe (AC). Die aus Lignicellulose gewonnenen ACs zeigten exzellente Eigenschaften bei der Aufnahme von CO2 und der Hochdruckspeicherung von CH4 währen die aus Microalgae gewonnen Eigenschaften an den Tag legten (z. B. hohe Oberfläche und N-Dotierung), welche sie zu vielversprechenden Materialien für Superkondensatoren machen. Die in dieser Dissertation präsentierte Arbeit zeigte außergewöhnliche Fortschritte in Richtung der Anwendung von unbehandelter Biomasse als Ausgangsmaterial für die Produktion von funktionalen Kohlenstoffen.
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Waldebäck, Monica. "Pressurized Fluid Extraction : A Sustainable Technique with Added Values." Doctoral thesis, Uppsala University, Department of Chemistry, 2005. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-6022.

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The challenge for the future was defined by the Brundtland Commission (1987) and by the Rio Declaration (1992), in which the fundamental principles for achieving a sustainable development were provided. Sustainable chemistry can be defined as the contribution of chemistry to the implementation of the Rio Declaration. This thesis shows how Pressurized Fluid Extraction (PFE) can be utilized in chemical analysis, and how this correlates to Green Chemistry.

The reliability and efficiency of the PFE technique was investigated for a variety of analytes and matrices. Applications discussed include: the extraction of the antioxidant Irganox 1076 from linear low density polyethylene, mobile forms of phosphorus in lake sediment, chlorinated paraffins from source-separated household waste, general analytical method for pesticide residues in rape seed, total lipid content in cod muscle, and squalene in olive biomass. Improved or comparable extraction yields were achieved with reduced time and solvent consumption. The decrease in use of organic solvents was 50-90%, resulting in minimal volatile organic compounds emissions and less health-work problem. Due to higher extraction temperatures and more efficient extractions, the selection of solvent is not as important as at lower temperatures, which makes it possible to choose less costly, more environmentally and health beneficial solvents. In general, extraction times are reduced to minutes compared to several hours. As a result of the very short extraction times, the amount of co-extracted material is relatively low, resulting in fewer clean-up step and much shorter analysis time. Selective extractions could be obtained by varying the solvent or solvent mixture and/or using adsorbents.

In this thesis, the PFE technique was compared to the twelve principles of Green Chemistry, and it was shown that it follows several of the principles, thus giving a major contribution to sustainable chemistry.

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Books on the topic "Green sustainable chemistry"

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Summerton, Louise, Helen F. Sneddon, Leonie C. Jones, and James H. Clark, eds. Green and Sustainable Medicinal Chemistry. Cambridge: Royal Society of Chemistry, 2016. http://dx.doi.org/10.1039/9781782625940.

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Minu, Gupta-Bhowon, ed. Chemistry for sustainable development. Dordrecht: Springer, 2012.

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Alexei, Lapkin, and Constable David 1958-, eds. Green chemistry metrics: Measuring and monitoring sustainable processes. [Ames, Iowa]: Blackwell Pub., 2008.

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Alexei, Lapkin, and Constable David 1958-, eds. Green chemistry metrics: Measuring and monitoring sustainable processes. [Ames, Iowa]: Blackwell Pub., 2008.

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Kümmerer, Klaus, and Maximilian Hempel. Green and sustainable pharmacy. Berlin: Springer, 2010.

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Sanghi, Rashmi. Green chemistry for environmental remediation. Salem, Mass: Scrivener Pub., 2012.

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Chemistry of sustainable energy. Boca Raton: CRC Press, 2014.

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Manahan, Stanley E. Green chemistry: Fundamentals of sustainable chemical science and technology. Columbia, Mo: ChemChar Research, 2004.

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1962-, Anastas Paul T., Heine Lauren G. 1957-, and Williamson Tracy C. 1963-, eds. Green engineering. Washington, DC: American Chemical Society, 2001.

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Green chemistry: Fundamentals and applications. Toronto: Apple Academic Press, 2014.

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Book chapters on the topic "Green sustainable chemistry"

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Nedwin, Glenn E. "Green Chemistry." In Biotechnology in the Sustainable Environment, 13–32. Boston, MA: Springer US, 1997. http://dx.doi.org/10.1007/978-1-4615-5395-3_3.

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Torrens, Francisco, and Gloria Castellano. "Chemistry and Sustainable Development." In Green Chemistry and Green Engineering, 211–22. Includes bibliographical references and index.: Apple Academic Press, 2020. http://dx.doi.org/10.1201/9781003057895-11.

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Shahare, Hitesh V., and Shweta S. Gedam. "Sustainable Chemistry and Pharmacy." In Green Chemistry and Green Engineering, 109–21. Includes bibliographical references and index.: Apple Academic Press, 2020. http://dx.doi.org/10.1201/9781003057895-5.

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Savitskaya, Tatsiana, Iryna Kimlenka, Yin Lu, Dzmitry Hrynshpan, Valentin Sarkisov, Jie Yu, Nabo Sun, Shilei Wang, Wei Ke, and Li Wang. "Green Chemistry and Sustainable Development." In Green Chemistry, 107–23. Singapore: Springer Singapore, 2021. http://dx.doi.org/10.1007/978-981-16-3746-9_5.

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Vaz, Sílvio. "Green Chemistry and Agrochemistry." In Sustainable Agrochemistry, 307–19. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-17891-8_10.

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Kümmerer, Klaus, and James Clark. "Green and Sustainable Chemistry." In Sustainability Science, 43–59. Dordrecht: Springer Netherlands, 2016. http://dx.doi.org/10.1007/978-94-017-7242-6_4.

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Constable, David J. C. "Green Chemistry and Sustainability." In Green Chemistry and Sustainable Technology, 1–16. Berlin, Heidelberg: Springer Berlin Heidelberg, 2016. http://dx.doi.org/10.1007/978-3-662-53704-6_1.

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Vaca-Garcia, Carlos. "Plant-Based Green Chemistry: Moving Towards Petroleum-Free Chemistry." In Green Chemistry and Sustainable Technology, 1–14. Singapore: Springer Singapore, 2019. http://dx.doi.org/10.1007/978-981-13-3810-6_1.

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Andraos, John, and Albert S. Matlack. "Materials for a Sustainable Economy." In Introduction to Green Chemistry, 379–408. 3rd ed. Boca Raton: CRC Press, 2022. http://dx.doi.org/10.1201/9781003033615-12.

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Zhang, Hui, Marshall Shuai Yang, Mohammad T. I. Bhuiyan, and Jesse Zhu. "CHAPTER 15. Green Chemistry for Automotive Coatings: Sustainable Applications." In Green Chemistry Series, 368–94. Cambridge: Royal Society of Chemistry, 2019. http://dx.doi.org/10.1039/9781788012997-00368.

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Conference papers on the topic "Green sustainable chemistry"

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Boughton, Bob. "California's Green Chemistry initiative." In 2009 IEEE International Symposium on Sustainable Systems and Technology (ISSST). IEEE, 2009. http://dx.doi.org/10.1109/issst.2009.5156787.

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WARNER, JOHN C. "GREEN CHEMISTRY: A NECESSARY STEP TO A SUSTAINABLE FUTURE." In International Seminar on Nuclear War and Planetary Emergencies 42nd Session. WORLD SCIENTIFIC, 2010. http://dx.doi.org/10.1142/9789814327503_0017.

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González, María, M. Angeles Andrés, Fabio Hernández, Izaskun Dávila, Pedro Luis de Hoyos, and M. Mirari Antxustegi. "TEACHING GREEN CHEMISTRY IN ENGINEERING DEGREES: THE SUSTAINABLE APPROACH." In 14th annual International Conference of Education, Research and Innovation. IATED, 2021. http://dx.doi.org/10.21125/iceri.2021.0675.

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Johnson, Alexander, and Cliff I. Davidson. "Chemistry of Stormwater Runoff from a Large Green Roof in Syracuse, NY." In International Conference on Sustainable Infrastructure 2017. Reston, VA: American Society of Civil Engineers, 2017. http://dx.doi.org/10.1061/9780784481196.005.

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Mulyanti, Sri, Asep Kadarohman, and Ratnaningsih Eko S. "Green chemistry based: Development of substitution reactions experiments." In THE 3RD INTERNATIONAL CONFERENCE ON SCIENCE EDUCATION (ICoSEd 2021): Education for Sustainable Development (ESD) 2030: The Impacts, Challenges, and Strategies in Science Education. AIP Publishing, 2022. http://dx.doi.org/10.1063/5.0112195.

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Sukmawardani, Yulia, Fia Nur Aulia, and Ida Farida. "Developing of gas stoichiometry learning kit based on green chemistry." In PROCEEDINGS OF THE SYMPOSIUM ON ADVANCE OF SUSTAINABLE ENGINEERING 2021 (SIMASE 2021): Post Covid-19 Pandemic: Challenges and Opportunities in Environment, Science, and Engineering Research. AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0114197.

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Korn, Maria das Graças Andrade, and Marcus Vinícius Aamral Leal Filho. "EVALUATION OF BRAZILIAN CONTRIBUTION TO THE SUSTAINABLE DEVELOPMENT GOALS THROUGH GREEN CHEMISTRY: A SYSTEMIC REVIEW." In VI Simpósio Internacional de Inovação e Tecnologia. São Paulo: Editora Blucher, 2020. http://dx.doi.org/10.5151/siintec2020-evaluationofbrazilian.

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Grigoryeva, Marina, Sergey Belopukhov, Inna Dmitrevskaya, and Inga Seregina. "“Green” Chemistry as the Basis for Development of the Philosophy of Sustainable Education in an Agricultural University." In Second Conference on Sustainable Development: Industrial Future of Territories (IFT 2021). Paris, France: Atlantis Press, 2021. http://dx.doi.org/10.2991/aebmr.k.211118.121.

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Nazario-Naveda, Renny, Daniel Delfin-Narciso, David Asmat-Campos, Segundo J. Rojas Flores, Santiago M. Benites, Fernanda Mantilla-Sifuentes, and Yessica Alayo-Zavaleta. "Active biodegradable films from mango starch integrated with silver nanoparticles synthesized by green chemistry." In 20th LACCEI International Multi-Conference for Engineering, Education and Technology: “Education, Research and Leadership in Post-pandemic Engineering: Resilient, Inclusive and Sustainable Actions”. Latin American and Caribbean Consortium of Engineering Institutions, 2022. http://dx.doi.org/10.18687/laccei2022.1.1.536.

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Sari, Sari, Maya Amelia, Neneng Windayani, and Deni Miharja. "The development of a simple distillation kit for green chemistry oriented organic liquid waste recycling." In PROCEEDINGS OF THE SYMPOSIUM ON ADVANCE OF SUSTAINABLE ENGINEERING 2021 (SIMASE 2021): Post Covid-19 Pandemic: Challenges and Opportunities in Environment, Science, and Engineering Research. AIP Publishing, 2023. http://dx.doi.org/10.1063/5.0118590.

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Reports on the topic "Green sustainable chemistry"

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Kalman, Joseph, and Maryam Haddad. Wastewater-derived Ammonia for a Green Transportation Fuel. Mineta Transportation Institute, July 2022. http://dx.doi.org/10.31979/mti.2021.2041.

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The energy-water nexus (i.e., availability of potable water and clean energy) is among the most important problems currently facing society. Ammonia is a carbon-free fuel that has the potential to reduce the carbon footprint in combustion related vehicles. However, ammonia production processes typically have their own carbon footprint and do not necessarily come from sustainable sources. This research examines wastewater filtration processes to harvest ammonia for transportation processes. The research team studied mock wastewater solutions and was able to achieve ammonia concentrations above 80%(nanofiltration) and 90% (reverse osmosis). The research team also investigated the influence of transmembrane pressure and flow rates. No degradation to the membrane integrity was observed during the process. This research used constant pressure combustion simulations to calculate the ignition delay times for NH3-air flames with expected impurities from the wastewater treatment processes. The influence of impurities, such as H2O, CO, CO2, and HCl, were studied under a range of thermodynamic conditions expected in compression ignition engines. The team observed carbon monoxide and water vapor to slightly decrease (at most 5%) ignition delay time, whereas HCl, in general, increased the ignition delay. The changes to the combustion chemistry and its influence of the reaction mechanism on the results are discussed. The experimental wastewater treatment study determined that reverse osmosis produced higher purity ammonia. The findings of the combustion work suggest that ignition delays will be similar to pure ammonia if HCl is filtered from the final product.
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Kalman, Joseph, and Maryam Haddad. Wastewater-derived Ammonia for a Green Transportation Fuel. Mineta Transportation Institute, July 2022. http://dx.doi.org/10.31979/mti.2022.2041.

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Abstract:
The energy-water nexus (i.e., availability of potable water and clean energy) is among the most important problems currently facing society. Ammonia is a carbon-free fuel that has the potential to reduce the carbon footprint in combustion related vehicles. However, ammonia production processes typically have their own carbon footprint and do not necessarily come from sustainable sources. This research examines wastewater filtration processes to harvest ammonia for transportation processes. The research team studied mock wastewater solutions and was able to achieve ammonia concentrations above 80%(nanofiltration) and 90% (reverse osmosis). The research team also investigated the influence of transmembrane pressure and flow rates. No degradation to the membrane integrity was observed during the process. This research used constant pressure combustion simulations to calculate the ignition delay times for NH3-air flames with expected impurities from the wastewater treatment processes. The influence of impurities, such as H2O, CO, CO2, and HCl, were studied under a range of thermodynamic conditions expected in compression ignition engines. The team observed carbon monoxide and water vapor to slightly decrease (at most 5%) ignition delay time, whereas HCl, in general, increased the ignition delay. The changes to the combustion chemistry and its influence of the reaction mechanism on the results are discussed. The experimental wastewater treatment study determined that reverse osmosis produced higher purity ammonia. The findings of the combustion work suggest that ignition delays will be similar to pure ammonia if HCl is filtered from the final product.
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Simpson, Sean D., Tanus Abdalla, Steve D. Brown, Christina Canter, Robert Conrado, James Daniell, Asela Dassanayake, et al. Development of a Sustainable Green Chemistry Platform for Production of Acetone and Downstream Drop-in Fuel and Commodity Products directly from Biomass Syngas via a Novel Energy Conserving Route in Engineered Acetogenic Bacteria. Office of Scientific and Technical Information (OSTI), March 2019. http://dx.doi.org/10.2172/1599328.

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Tschaplinski, Timothy J., Payal Charania, Nancy L. Engle, Richard J. Giannone, Robert {Bob} L. Hettich, Dawn Marie Klingeman, Suresh Poudel, et al. DEVELOPMENT OF A SUSTAINABLE GREEN CHEMISTRY PLATFORM FOR PRODUCTION OF ACETONE AND DOWNSTREAM DROP-IN FUEL AND COMMODITY PRODUCTS DIRECTLY FROM BIOMASS SYNGAS VIA A NOVEL ENERGY CONSERVING ROUTE IN ENGINEERED ACETOGENIC BACTERIA. Office of Scientific and Technical Information (OSTI), July 2019. http://dx.doi.org/10.2172/1543199.

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