Dissertations / Theses on the topic 'Geology New South Wales Bermagui'

The Quaternary alluvial and aeolian sediments underlying the eastern portion of the Riverine Plain have been examined to assess their impact on groundwater access and movement in the Coleambally district. Over 9800 borehole logs from the Coleambally Irrigation Area (CIA) and surrounding districts were digitized using GIS and database software and supplemented with 632 borehole logs from the Department of Land and Water Conservation (Leeton) to form the platform for stratigraphic and groundwater investigations conducted in this study. The borehole data were summarised into two sediment classification schemes, the first to delineate the distribution of palaeochannel sediments and the second to assess to spatial distribution of aquitards and aquifers. A series of detailed cross-sections differentiated between at least four distinct palaeochannel sequences identified within the Upper Shepparton Formation overlying the clay-dominated Lower Shepparton Formation. The two deepest sequences, the new Gumblebogie and Ugobit members, comprise thick (3-10 m), laterally extensive (up to 25 km wide) sheets of coarse sandy alluvium that occur to the north of the CIA at depths between 12 to 35 metres below the surface. These deposits are evidence of highly active alluvial phases on the plain, more vigorous than any since. Slightly higher in the sequence (typically 10-20 m depth) is a thick (2-15 m), laterally extensive (up to 10 km wide) mixed-load sequence (the new Duderbang member), which is stratigraphically disconnected from the deeper sanddominated units. Near-surface palaeochannel deposits, which consist of less extensive (up to 3 km wide) coarse sandy alluvium at depth and a combination of mixed- and bedload sequences closer to the surface, make up the youngest palaeochannel deposits in the area. The size and extent of reserved palaeochannel sequences beneath the study area have decreased markedly since what is interpreted as the mid Quaternary and is probably symptomatic of declining fluvial activity on the Riverine Plain through to the present. The development of source-bordering dunes associated with belts of palaeochannel material in the area was examined using shallow geophysics (GPR), topographic surveys, laser particle size analysis and thermoluminescence dating. Dune building in Contents the area occurred in conjunction with channel activity during the Kerarbury (55-35 ka) and Coleambally (105-80 ka) palaeochannel phases (Page et al., 1996) when sediment supply conditions were favourable, probably due to strongly seasonal discharges draining the southeastern highlands. The presence of stabilising vegetation on the channel margins is believed to have played a key role in the development of dunes in the area, which show poorly developed internal structure. The increased precipitation that enhanced channel discharges must also have sustained dune vegetation. Increased aridity and reduced vegetation approaching and during the LGM appears to have caused the widespread remobilization of dune crests. The complex alluvial and aeolian stratigraphy of the Shepparton Formation strongly influences groundwater movement in the Coleambally district. Piezometric levels show that deeper, highly permeable units (e.g. Ugobit member) in the northern part of the study area act as conduits for the discharge of groundwater, helping to maintain much lower watertables in the north as well as induce groundwater flow from the CIA. ‘Sediment vs depth’ analysis demonstrates that there is limited vertical connection through the thick, clay-dominated sequence of the Lower Shepparton Formation to the highly transmissive sands and gravels of the underlying Calivil Formation. The tendency of the Lower Shepparton Formation to restrict downward leakage is likely to both contribute to the problem of shallow irrigation-induced watertables in the CIA as well as impede efforts to lower watertables by pumping from deeper aquifers. The upper 3 metres of the Shepparton Formation are clay-dominated with a low water storage capacity, causing near-surface watertables to be highly responsive to recharge by surface water. The available data indicate that when piezometric levels fall below this clay-rich zone they are able to absorb short-term increases in recharge due to the higher proportion permeable alluvium in the unsaturated zone.

Thesis (PhD)--Macquarie University, Division of Environmental & Life Sciences, Graduate School of the Environment, 2002.
Includes bibliographical references: p. 228-232.
Geomorphology, archaeology and geoarchaeology: introduction and background -- Surface stone artefact scatters: why can we see them? -- Geomorphic controls on spatial patterning of the surface stone artefact record -- A temporal framework for interpreting surface artefact scatters in Western NSW -- Synthesis: stone artefact scatters in a dynamic landscape.
Surface scatters of stone artefacts are the most ubiquitous feature of the Australian Aboriginal archaeological record, yet the most underutilized by archaeologists in developing models of Aboriginal prehistory. Among the many reasons for this are the lack of understanding of geomorphic processes that have exposed them, and the lack of a suitable chronological framework for investigating Aboriginal 'use of place'. This thesis addresses both of these issues. -- In arid western NSW, erosion and deposition accelerated as a result of the introduction of sheep grazing in the mid 1800s has resulted in exposure of artefact scatters in some areas, burial in others, and complete removal in those parts of the landscape subject to concentrated flood flows. The result is a patchwork of artefact scatters exhibiting various degrees of preservation, exposure and visibility. My research at Stud Creek, in Sturt National Park in far western NSW, develops artefact and landscape survey protocols to accommodate this dynamic geomorphic setting. A sampling strategy stratified on the basis of landscape morphodynamics is presented that allows archaeologists to target areas of maximum artefact exposure and minimum post-discard disturbance. Differential artefact visibility at the time of the survey is accommodated by incorporating measures of surface cover which quantify the effects of various ephemeral environmental processes, such as deposition of sediments, vegetation growth, and bioturbation, on artefact count. -- While surface stone artefact scatters lack the stratigraphy usually considered necessary for establishing the timing of Aboriginal occupation, a combination of radiocarbon determinations on associated heat-retainer ovens, and stratigraphic analysis and dating of the valley fills which underlie the scatters, allows a two-stage chronology for huntergatherer activity to be developed. In the Stud Creek study area, dating of the valley fill by OSL established a maximum age of 2,040±100 y for surface artefact scatters. The heatretainer ovens ranged in age from 1630±30 y BP to 220±55 y BP. Bayesian statistical analysis of the sample of 28 radiocarbon determinations supported the notion, already established from analysis of the artefacts, that the Stud Creek valley was occupied intermittently for short durations over a relatively long period of time, rather than intensively occupied at any one time. Furthermore, a gap in oven building between about 800 and 1100 years ago was evident. Environmental explanations for this gap are explored, but the paiaeoenvironmental record for this part of the Australian arid zone is too sparse and too coarse to provide explanations of human behaviour on time scales of just a few hundred years. -- Having established a model for Stud Creek of episodic landscape change throughout the late Pleistocene and Holocene, right up to European contact, its veracity was evaluated in a pilot study at another location within the region. The length of the archaeological record preserved in three geomorphically distinct locations at Fowlers Gap, 250 km south of Stud Creek, is a function of geomorphic dynamics, with a record of a few hundred years from sites located on channel margins and low terraces, and the longest record thus far of around 5,000 years from high terrace surfaces more remote from active channel incision. But even here, the record is not continuous, and like Stud Creek, the gaps are interpreted to indicate that Aboriginal people moved into and out of these places intermittently throughout the mid to late Holocene. -- I conclude that episodic nonequilibrium characterizes the geomorphic history of these arid landscapes, with impacts on the preservation of the archaeological record. Dating of both archaeological and landform features shows that the landscape, and the archaeological record it preserves, are both spatially and temporally disjointed. Models of Aboriginal hunter-gatherer behaviour and settlement patterns must take account of these discontinuities in an archaeological record that is controlled by geomorphic activity. -- I propose a new geoarchaeological framework for landscape-based studies of surface artefact scatters that incorporates geomorphic analysis and dating of landscapes, as well as tool typology, into the interpretation of spatial and temporal patterns of Aboriginal huntergatherer 'use of place'.
Mode of access: World Wide Web.
vii, 232 p. ill., maps

The Patonga Claystone, a red bed facies in the Narrabeen Group of the Sydney Basin, is one of the most unfavorable rock units in the basin from a geotechnical point of view. This rock unit is composed of sandstone, siltstone, mudstone and claystone. One of the unfavorable characteristics is the low shear strength, which causes instability of cut slopes; another is its slaking-prone behaviour. Numerous measurements of geotechnical properties, along with extensive mineralogical and geochemical determinations, were carried out to identify cause of this slaking behaviour. Key techniques were the use of quantitative X-ray diffractometry for mineralogical analysis, and the determination of slake durability index and related properties to evaluate the slaking behaviour under both standard and more extended conditions. Standard (two cycle) slake durability test results indicate a range from low to high slake durability index values, with some mudstone samples having very low durability and some sandstones having very high slake durability indices. Jar slake test results indicate that the rock samples break rapidly and/or develop several fractures (Ij = 4) in an as-received state, but degrade to a pile of flakes or mud (Ij = 1) if the samples are oven dried before testing. The results for jar slake testing of oven-dried material are comparable, for individual samples, to those obtained from the more comprehensive slake durability tests. The mineralogy of the samples was evaluated by quantitative X-ray diffraction techniques using the Rietveld-based Siroquant processing system. Comparison to independent chemical data show a generally good level of agreement, suggesting that the mineralogical analysis results are consistent with the chemical composition of the individual rock samples. Good correlations were also obtained between clay mineralogy determined from orientedaggregate XRD analysis of the <2 micron fraction and the results from powder diffractometry and Siroquant analysis of the whole-rock samples. Evaluation of the slake durability characteristics and other geotechnical properties in relation to the quantitative mineralogy suggests that quartz and feldspar form a rigid framework in the rocks that resists the disruptive pressures that cause slaking. Expansion of the clay minerals by various processes, including the incorporation of water into the interlayer spaces of illite/smectite as well as changes in pore pressures associated with entry of water into micro-fractures in the clay matrix, are thought to produce the disruptions that cause slaking and degradation. An abundant clay matrix also reduces the strength of the rock materials, probably because of the less rigid nature of the clay minerals relative to the quartz and feldspar particles. As well as the mineralogy, the loss on ignition (LOI) and water absorption percentage were found to provide good indicators of longer-term slaking behaviour. Both properties are also related to the overall clay content. Rock samples with water absorption values of <10, 10-15 and >15% behave as highly durable, intermediate and less durable materials respectively. Rocks with LOI values of greater than 5% by weight behave as less durable rock materials, at least for the strata encompassed by the present study. The water absorption and LOI values were also used to develop a predictive model of slake durability characteristics for the different rock materials in the Patonga Claystone, providing a relatively simple basis for predicting longer-term stability in a range of geotechnical studies.

Thesis (PhD)--Macquarie University, Division of Environmental & Life Sciences, Department of Earth and Planetary Sciences, 2005.
Bibliography: leaves 202-224.
Introduction -- Geological setting of the New England Fold Belt -- Regional geophysical investigation -- Data acquisition and reduction -- Modelling and interpretation of magnetic data over the Peel Fault -- Modelling and interpretation of magnetic data over the Mooki Fault -- Gravity modelling of the Tamworth Belt and Gunnedah Basin -- Interpretation and discussion -- Conclusions.
This thesis presents new magnetic and gravity data for the Southern New England Fold Belt (SNEFB) and the Gunnedah Basin that adjoins to the west along the Mooki Fault in New South Wales. The SNEFB consists of the Tamworth Belt and Tablelands Complex that are separated by the Peel Fault. The Tablelands Complex to the east of the Peel Fault represents an accretionary wedge, and the Tamworth Belt to the west corresponds to the forearc basin. A total of five east-north-east trending gravity profiles with around 450 readings were conducted across the Tamworth Belt and Gunnedah Basin. Seven ground magnetic traverses of a total length of 60 km were surveyed across the bounding faults of the Tamworth belt, of which five were across the Peel Fault and two were across the Mooki Fault. The gravity data shows two distinct large positive anomalies, one over the Tamworth Belt, known as the Namoi Gravity High and another within the Gunnedah Basin, known as the Meandarra Gravity Ridge. All gravity profiles show similarity to each other. The magnetic data displays one distinct anomaly associated with the Peel Fault and an anomaly immediately east of the Mooki Fault. These new potential field data are used to better constrain the orientation of the Peel and Mooki Faults as well as the subsurface geometry of the Tamworth Belt and Gunnedah Basin, integrating with the published seismic data, geologic observations and new physical properties data. --Magnetic anomalies produced by the serpentinite associated with the Peel Fault were used to determine the orientation of the Peel fault. Five ground magnetic traverses were modelled to get the subsurface geometry of the serpentinite body. Modelling results of the magnetic anomalies across the Peel Fault indicate that the serpentinite body can be mostly modelled as subvertical to steeply eastward dipping tabular bodies with a minimum depth extent of 1-3 km, although the modelling does not constrain the vertical extent. This is consistent with the modelling of the magnetic traverses extracted from aeromagnetic data. Sensitivity analysis of a tabular magnetic body reveals that a minimum susceptibility of 4000x10⁻⁶cgs is needed to generate the observed high amplitude anomalies of around 2000 nT, which is consistent with the susceptibility measurements of serpentinite samples along the Peel Fault ranging from 2000 to 9000 x 10⁻⁶ cgs. Rock magnetic study indicates that the serpentinite retains a strong remanence at some locations. This remanence is a viscous remanent magnetisation (VRM) which is parallel to the present Earth's magnetic field, and explains the large anomaly amplitude over the Peel fault at these locations. The remanence of serpentinite at other localities is not consistent enough to contribute to the observed magnetic anomalies. A much greater depth extent of the Peel Fault was inferred from gravity models. It is proposed that the serpentinite along the Peel Fault was emplaced as a slice of oceanic floor that has been accreted to the front of the arc, or as diapirs rising off the serpentinised part of the mantle wedge above the supra subduction zone.
Magnetic anomalies immediately east of the Mooki Fault once suggested to be produced by a dyke-like body emplaced along the fault were modelled along two ground magnetic traverses and three extracted aeromagnetic lines. Modelling results indicate that the anomalies can be modelled as an east-dipping overturned western limb of an anticline formed as a result of a fault-propagation fold with a shallow thrust step-up angle from the décollement. Interpretation of aeromagnetic data and modelling of the magnetic traverses indicate that the anomalies along the Mooki Fault are produced by the susceptibility contrast between the high magnetic Late Carboniferous Currabubula Formation and/or Early Permian volcanic rocks of the Tamworth Belt and the less magnetic Late Permian-Triassic Sydney-Gunnedah Basin rocks. Gravity modelling indicates that the Mooki Fault has a shallow dip ( ̃25°) to the east. Modelling of the five gravity profiles shows that the Tamworth Belt is thrust westward over the Sydney-Gunnedah Basin for 15-30 km. --The Meandarra Gravity Ridge within the Gunnedah Basin was modelled as a high density volcanic rock unit with a density contrast of 0.25 tm⁻³, compared to the rocks of the Lachlan Fold Belt in all profiles. The volcanic rock unit has a steep western margin and a gently dipping eastern margin with a thickness ranging from 4.5-6 km, and has been generally agreed to have formed within an extensional basin. --The Tamworth Belt, being mainly the product of volcanism of mafic character and thus has high density units, together with the high density Woolomin Association, which is composed chiefly of chert/jasper, basalt, dolerite and metabasalt, produces the Namoi Gravity High. Gravity modelling results indicate that the anomaly over the Tamworth Belt can be modelled as either a configuration where the Tablelands Complex extends westward underthrusting the Tamworth Belt, or a configuration where the Tablelands Complex has been thrust over the Tamworth Belt. When the gravity profiles were modelled with the first configuration, the Peel Fault with a depth extent of around 1 km can only be modelled for the Manilla and Quirindi profiles, modelling of the rest of the gravity profiles indicates that the Tablelands Complex underthrust beneath the Tamworth belt at a much deeper location.
Mode of access: World Wide Web.
xi, 242 leaves ill., maps

The three-dimensional thermal maturity pattern has been investigated and the hydrocarbon generation potential assessed for the Permian and Triassic sequences of the southern Bowen and northern Gunnedah Basins and the lower part of the overlying Jurassic Cretaceous Surat Basin sequence in northern New South Wales. An oil-source rock correlation also has been investigated in the Gunnedah Basin. Vitrinite reflectance measurements were conducted on 256 samples from 28 boreholes. A total of 50 of these samples were subjected to Rock-Eval pyrolysis analysis, and 28 samples extracted for additional organic geochemical studies (GCMS). A re-evaluation of the stratigraphy in the southern Bowen Basin and a stratigraphic correlation between that area and the northern Gunnedah Basin was also included in the study. An overpressured shaly interval has been identified as a marker bed within the lower parts of the Triassic Moolayember and Napperby Formations, in the Bowen and Gunnedah Basins respectively. Suppressed vitrinite reflectance in the Permian sequence was used as another marker for mapping the stratigraphic sequence in the southern Bowen Basin. The Permian sequence in the Bowen Basin thins to the south, and probably pinches out over the Moree High and also to the west. The coal-bearing Kianga Formation is present in the north and northeastern parts of the study area. A disconformity surface between Digby and Napperby Formations in the Gunnedah Basin is probably time-equivalent to deposition of the Clematis Group and Showgrounds Sandstone in the Bowen Basin. The Clematis Group is absent in the study area, and the Moolayember Formation considered equivalent to the Napperby Formation. Although in many cases core samples were not available, handpicking of coal or shaly materials from cuttings samples where geophysical log signatures identify these materials helped in reducing contamination from caved debris. Histogram plots of reflectance also helped where the target and caved debris were of similar lithology. Vertical profiles of the vitrinite reflectance identified suppressed intervals in the study area due to marine influence (Back Creek Group and Maules Creek Formation) and liptinite rich source organic matter (Goonbri Formation). The suppression occurs due to the perhydrous character of the preserved organic matter. High reflectance values were noted within intrusion-affected intervals, and two types of igneous intrusion profiles were identified; these are simple and complex profiles. An isoreflectance map for the non-suppressed interval at the base of the Triassic sequence in the southern Bowen Basin shows that the organic matter is mature more towards the east close to the Goondiwindi Fault, and also towards the west where the Triassic sequence directly overlies the basement. High values also occur over the Gil Gil Ridge in the middle, to the south over the Moree High, and to the north where the sequence is thicker. The reflectance gradient in the suppressed intervals is higher than in the overlying non-suppressed sequences, especially when the rank has resulted from burial depth. Tmax from Rock-Eval pyrolysis was found to be lower in the perhydrous intervals, and was high in mature and igneous intrusion-affected intervals. Based on the source potential parameters, the Permian Back Creek Group is a better source than the Kianga Formation, while the Goonbri Formation is better than the Maules Creek Formation. The Triassic Napperby Formation has a fair capacity to generate oil, and is considered a better source rock than the equivalent Moolayember Formation. The Jurassic Walloon Coal Measures is a better source than Evergreen Formation, and has the best source rock characteristics, but is immature. The Rock-Eval S1 value shows better correlation with extracted hydrocarbon compounds (saturated and aromatics) than the total extractable organic matter. This suggests that solvent extraction has a greater ability to extract NSO compounds than temperature distillation over the Rock-Eval S1 interval. Terrestrial organic matter is the main source input for the sequences studied. This has been identified from organic petrology and from the n-alkane distributions and the relatively high C29 steranes and low sterane/hopane ratios. The absence of marine biomarker signatures in the Permian marine influenced sequence, could be attributed to their dilution by overwhelming amounts of non-marine organic matter. A mainly oxic to suboxic depositional environment is inferred from trace amounts of 25-NH, BNH and TNH. This is further supported by relatively high pr/ph ratios. Although C29/C30 is generally regarded as an environmental indicator, high values were noted in intrusion-affected samples. The 22S and 20S ratios were inverted ????reaches pseudo-equilibrium???? in such rapidly heated, high maturity samples. The ratio of C24 tetracyclic terpane to C21-C26 tricyclic terpanes decreases, instead of increasing, within the Napperby Formation close to a major igneous intrusive body. The 22S ratio, which is faster in reaction than the other terpane and sterane maturity parameters, shows that the Permian sequence lies within the oil generation stage in the Bowen Basin, except for a Kianga Formation sample. The Triassic sequence is marginally mature, and the Jurassic sequence is considered immature. In the Gunnedah Basin, the Permian sequence in Bellata-1 and Bohena-1, and the Triassic sequence in Coonarah-1A, lie within the oil generation range. In the intrusion-affected high maturity samples, the ratio is reaches pseudo-equilibrium. This and other terpane and sterane maturity parameters are not lowered (suppressed) in the perhydrous intervals. The ???????? sterane ratio, however, is slowest in reaction to maturity, and variations in low maturity samples are mainly due to facies changes. Diasterane/sterane ratios, in the current study, increase with increasing TOC content up to 5% TOC, but decrease in rocks with higher TOC contents including coals. Highly mature samples, as expected, in both cases are anomalous with high ratios. Calculated vitrinite reflectance based on the method of Radke and Welte (1983), as well as MPI 1 and MPI 2, shows the best comparison to observed values. These aromatic maturity parameters are lowered within the reflectance-suppressed intervals. Oil stains in the Jurassic Pilliga Sandstone in the Bellata-1 well have been identified as being indigenous and not due to contamination. The vitrinite reflectance calculated to the oil stain suggests that the source rock should be within a late mature zone. Such high maturity levels are only recognised within intrusion-affected intervals. A close similarity between the oil stain sample and the intruded interval of the Napperby Formation is evident from the thermal maturity and biomarker content. Hydrocarbon generation and expulsion from the lower part of the Napperby Formation as a result of igneous intrusion effects is suggested as the source of the oil in this particular occurrence. Terpane and sterane maturity parameters increase with increasing burial depth in the intervals with suppressed (perhydrous) vitrinite reflectance. The generation maturity parameters also increase through intervals with perhydrous vitrinite, which suggests that hydrocarbons continue to be generated and the actual amount is increasing even though traditional rank ????????????stress???????????? maturity parameters are lowered. Accordingly, the Permian sequences in the lower part of the Bowen Basin are at least within the peak oil generation zone, and probably within late oil generation in the north and northeast of the study area. To generate significant amounts of hydrocarbon, however, the thickness of the shaly and coaly intervals in the Permian sequence is probably a critical parameter. In the Gunnedah Basin, a significant amount of hydrocarbon generation is probably only possible as a result of igneous intrusions.

The development of an open pit mine at the Endeavour 42 (E42) epithermal gold deposit, situated in the Junee-Narromine Volcanic Belt of the Ordovician Macquarie Arc, central New South Wales, has provided a 3D view of the structurally controlled deposit which was hitherto not available due to the paucity of outcrop in the region. Outcropping geological relationships present a complicated history of overprinting structural deformation and vein events, including the spatial characterization of the gold-mineralizing system. Host rocks consisting of interbedded sedimentary and resedimented volcaniclastic facies, trachyandesite and porphyritic andesite lavas and intrusions (coherent and autoclastic facies), intruded by a large diorite sill, were initially tilted and faulted, followed by the emplacement of multiple dyke phases along faults. Economic gold mineralization at E42 is restricted to faults, fault-hosted breccias, and veins, and was deposited over a period spanning two distinct structural regimes. Early gold-bearing veins are steeply dipping and interpreted as forming coevally along two sets of faults and dykes within a tensional stress regime. High grade fault-hosted, hydrothermally cemented breccia intervals are included temporally with early gold-bearing veins based on comparable mineralogy and steep, fault parallel orientations. Crosscutting the early steep gold-bearing vein sets are two populations of coeval inclined gold-bearing veins, dipping moderately to the southwest and northwest, respectively, which formed in a compressional stress regime with tension directed subvertically. The E42 epithermal deposit likely developed in the period of overall crustal extension, ca. 443-433 Ma, following Phase 1 of the Late Ordovician – Early Silurian Benambran Orogeny. The generation of permeability, styles of fracture propagation, and the reactivation of pre-existing planes of weakness in the rock package are key factors in the development and current geometry of the E42 gold deposit. High grade veins and faults are commonly flanked by sericite-quartz ± carbonate alteration haloes, which exhibit consistent geochemical patterns for metals and pathfinder elements, both laterally away from structures, and vertically within the deposit. Au, Ag, As, Hg, Sb, Tl, Cu, Pb, and Zn, all display increasing concentrations towards high-grade structures, as well as higher up in the epithermal system, with varying dispersion haloes.

Arsenic (As) in groundwater systems is a problem in many parts of the world owing to ever-increasing extraction of groundwater resources to meet the needs of growing populations. Surprisingly, the occurrence of elevated As concentrations in coastal sandy aquifers has only recently been published as a result of this research. Sandy aquifers are commonly used as a clean and reliable source of water for domestic, agricultural and industrial needs due to their high recharge rates and the filtering capacity of sands. Water quality monitoring in Australian sandy aquifers is usually limited to a small suite of major elements and salinity measurements to determine the quality of groundwater and to identify any potential problems from seawater intrusion as a result of over extraction. Minor and trace elements, particularly toxic elements, have largely been ignored in regular monitoring programs. Prompted by an emerging pattern of human health problems in a community reliant on groundwater, hydrogeochemical investigations of the Stuarts Point coastal sand aquifer, on the North Coast of New South Wales, Australia, identified elevated As concentrations of up to 337 ????g/L in the catchment's Pleistocene barrier sands. These concentrations are well in excess of the World Health Organisation and the Australian National Health and Medical Research Council water quality criteria of 10 and 7 ????g/L respectively. From research into the Stuarts Point geology, geochemistry, geomorphology, hydrogeology and hydrogeochemistry, and with the assistance of environmental isotopes, the spatial distribution, occurrence and mobilisation processes of As were determined. The presence and distribution of elevated As concentrations in the regional coastal aquifer system are sporadic and involve a series of complex hydrogeochemical processes. No single hydrogeochemical process can describe the release of As from solid phase to groundwater system on the regional scale. Processes of competitive exchange with PO43- and HCO3-, reductive dissolution of Fe oxyhydroxides and arsenical pyrite oxidation, though not forming dominant correlations, are still evident and influence As chemistry at this scale. Detailed investigations of the hydrogeochemistry on the vertical scale have identified two main processes as causing As to be released and mobilised. The first process is associated with the oxidation of arsenical pyrite in Acid Sulphate Soils and metal hydrolysis reactions which mobilise As in the acidic environment. In the absence of dissolved oxygen (DO), NO3- acts as the oxyanion facilitating arsenical pyrite oxidation and releasing As into solution. The second process that mobilises As from the sediments is the liberation of As from metal-oxyhydroxides in the carbon-rich environment, where HCO3- originates from the dissolution of shell material in the Pleistocene barrier sands. The marine influenced depositional history and geomorphology of the aquifer provide opportunities for As to become incorporated into the aquifers matrix in a variety of mineral forms, which is an occurrence not considered to be unique to the Stuarts Point catchment. The findings presented here are amongst the first detailed studies of naturally occurring As in an Australian groundwater system as well as in the Pleistocene coastal sand aquifer environment. The understanding of As accumulation and mobilisation identified as a result of this research emphasises the need for potential As occurrences in similar groundwater systems in other coastal environments in Australia, and globally, to be considered.

"1990".
Thesis (PhD)--Macquarie University, School of Earth Sciences, 1991.
Bibliography: p. 596-630.
PART 1. INTRODUCTION AND METHODOLOGY -- General introduction -- Methodology -- Classification of ichnofacies and lithofacies as used in the present study -- Definition of trace fossil zones (intervals, subintervals and levels) -- General classification of the palaeoenvironments and summary overview of the stratigraphic and geographic distribution of palaeoenvironments in the study area -- PART 2. SYSTEMATIC ICHNOTAXONOMY -- Large dwelling-burrows -- U-shaped burrows -- Vertical cylindrical burrows -- Thalassinoides, Ophiomorpha, Spongeliomorpha and turn-arounds -- Pellets and ovoid-shaped structures -- Bedding-parallel feeding and/or dwelling structures -- Dendritic feeding-burrows -- Rosette-shaped structures -- Escape-structures -- Tracks, trails and resting-traces -- Body fossils and root-penetration structures -- Miscellaneous traces -- PART 3. SYNTHESIS AND CONCLUSIONS -- Trace fossil assemblages (suites) in intervals IC to IF and their distribution in the study area -- Interpretation of the palaeoenvironmental affinities of the trace fossil zones and depositional setting of the study area -- Palaeogeographic synthesis and conclusions.
The coastal exposures of the Triassic System in the Sydney Northshore area aggregate about 180 m in thickness and comprise the uppermost part of the Narrabeen Group (namely, in ascending stratigraphic order: the Bald Hill Claystone, the Garie Formation, and the Newport Formation, the latter divisible into Lower, Middle and Upper Members) and the overlying Hawkesbury Sandstone. With the exception of mainly allochthonous plant macrofossils and palynomorphs which occur sporadically and with varying abundance in the mudrock facies of these formations, environmentally-diagnostic body fossils are rare, and, where they occur, are nowhere unequivocally indicative of marine affinities. For this reasons, and because of the predominantly fluvial lithofacies characteristics exhibited by these formations throughout much of their stratigraphic extent and especially by their channel-form/channel-like sandstones lithosomes, most previous workers have interpreted these formations to be of fluvial or fluvio-lacustrine origin except possibly for several thin planar-and thinly-bedded fine-grained intervals encompassing the Garie and Newport Formations for which several lines of evidence, including lithofacies, equivocal palaeontological, and ichnological evidence, have prompted several workers to speculate a shallow- marine, possibility coastal lagoonal or estuarine origin. -- Although trace fossils occur in reasonable abundance at various stratigraphic levels within these uppermost Narrabeen Group rocks and particularly within the Newport Formation, they have hitherto received very little systematic study. A comprehensive study of this ichnofauna shows that it is relatively diverse, comprising almost 100 different ichnotaxa (including varietal categories) of predominantly invertebrate origin, and includes several new ichnogenera and ichnospecies among the more notable of which are: two large bioglyph-bearing dwelling-burrows of probable crustacean origin (Turimettichnus conaghani and T. webbyi) and one (Pytiniichnus trifurcatum) made either by a small reptile or an amphibian; a multi-stage spiral star-shaped feeding-trace (Helikospirichnus veeversi), probably made by a worm or worm-like deposit-feeder; several new species and varieties of Rhizocorallium (the first record of this ichnogenus in the Triassic of Australia); a new species and new variety of the saltatorial running vertebrate trackway Moodieichnus (an ichnogenus previously known only from the Late Permian of North America); and a new ichnogenus of vertical/steeply-inclined cylindrical branching dwelling-burrow (Barrenjoeichnus mitchelli). -- An alternating stratigraphic pattern of trace fossil abundance and diversity characterizes the upper Narrabeen Group strata in the Sydney Northshore area, and involves four relatively thin separate assemblage zones of relatively diverse ichnofauna and thicker intervening assemblage zones which lack ichnotaxo-nomic diversity. The assemblage zones of diverse trace fossils contain some elements in common to two or more zones, notably: Thalassinoides, Skolithos, Ophiomorpha, Chondrites, Rhizocorallium Palaeophycus, and Planolites, all of which are known to have unequivocal brackish- to shallow-marine palaeoecological affinities and which globally are characteristic of the Skolithos ichnofacies. Additionally, each of these four diverse assemblage zones is characterized by one or more particular index ichnogen-era which for convenience lend their name(s) to the zones as follows, in ascending stratigraphic order: Turimettichnus-Ophio-morpha assemblage zone; Skolithos-Diplocraterion assemblage zone; Helikospirichnus assemblage zone; and Rhizocorallium-Thalass inoides assemblage zone. The intervening ichnotaxonomically less-diverse and relatively impoverished assemblage zones are not similarly and separately named but are characterized by Barrenjoeichnus mitchelli and some species of Palaeophycus, Planolites and Skolithos as well as various plant-root petrification structures, all of which are here argued to have predominantly non-marine palaeoecological affinities. These latter assemblage zones can be referred to the Scoyenia-Teredolites ichnofacies. This stratigraphic pattern of alternating ichnologi-cally diverse and impoverished assemblage zones confirms the suggestions of previous workers (notably Bunny and Herbert, and Retallack) regarding the presence of brackish-/shallow-marine palaeoenvironmental influence in these Lower and Middle Triassic strata and allow for the first time the stratigraphic resolution of the marine strata into four marine tongues which are here named after their respective type localities. These are, in ascending order: The Turimetta Head Tongue (2 m to 3 m thick; extending from at least the middle part of the Bald Hill Clay-stone almost to the top of this formation); the St. Michaels Cave Tongue (4 m to 5 m thick; encompassing the Garie Formation and the lower part of the lower Member of the Newport Formation); the Bangalley Head Tongue (3 m to 5 m thick; extending from the uppermost part of the Lower Member into the lower part of the Middle Member of the Newport Formation); and the Palm Beach Tongue (3 m to 4 m thick; comprising the uppermost part of the Middle Member of the Newport Formation). The trace fossil assemblages in each of these marine tongues are indicative of a complex of brackish- to very shallow-marine low-energy palaeoenvi-ronments typical of modern coastal lagoons or estuaries and imply the presence of a protecting coeval topographic barrier of some kind to the east or southeast. This lagoon is herein called the Newport (Coastal) Lagoon and its development in the central-eastern part of the Sydney Basin coincides approximately with the geographic and depocentral axis of the basin which trends NW-SE and intersects the present coastline in the Sydney metropolitan area. The non-marine affinities of the impoverished and less-diverse trace fossil assemblages in the intervening and overlying strata are consistent with the fluvial/fluvio-lacustrine environmental interpretations of these thicker and predominantly sandstone-dominant intervals made by many other workers. Palaeocur-rent and petrographic data from these fluvial sediments show that the streams in which they formed debouched episodically into the Newport Lagoon variously from the northwest, west and southwest and were sourced variously from both the craton (Lachlan Fold Belt) to the southwest and the New England Orogen to the northeast.
With the exception of evidence of short-lived brackish-marine conditions at the base of the Narrabeen Group in the northeastern Sydney Basin and in the top of the Ashfield Shale in the Wianamatta Group (above the Hawkesbury Sandstone) in the central part of the basin, the Triassic System of the basin is dominated by fluvial/fluvio-lacustrine sediments and the presently described marine tongues of the Newport Lagoon in the uppermost Narrabeen Group are the only other presently known record of marine conditions during the Triassic history of the basin. The development of the Newport Lagoon in the geographic and depocentral axis of the basin attests to the presence of a mild short-lived marine transgression in the latest Early and early Middle Triassic at the end of a period of declining piedmont clastic alluviation from the coeval New England Orogen to the northeast and immediately prior to the onset of a new phase of fluvial sedimentation sourced from the craton to the southwest and manifested by the deposition of the Middle Triassic Hawkesbury Sandstone.
Mode of access: World Wide Web.
xxxv, 630 p. ill., maps

Alkalic porphyry style Au-Cu deposits of the Cadia district are associated with Late-Ordovician monzonite intrusions, which were emplaced during the final phase of Macquarie Arc magmatism at the end of the Benambran Orogeny. N-striking faults, including the curviplanar, northerly striking, moderately west-dipping basement thrust faults of the Cadiangullong system, developed early in the district history. NE-striking faults formed during rifting in the late Silurian. Subsequent E-W directed Siluro- Devonian extension followed by regional E-W shortening during the Devonian Tabberabberan Orogeny dismembered these intrusions, thereby superposing different levels porphyry Au-Cu systems as well as the host stratigraphy. During the late Silurian, the partially exhumed porphyry systems were buried beneath the Waugoola Group sedimentary cover sequence, which is generally preserved in the footwall of the Cadiangullong thrust fault system. The Waugoola Group is a typical rift-sag sequence, deposited initially in local fault-bounded basins which then transitioned to a gradually shallowing marine environment as local topography was overwhelmed. Basin geometry was controlled by pre-existing basement structures, which were subsequently inverted during the Devonian Tabberabberan Orogeny, offsetting the unconformity by up to 300m vertically. In the Waugoola Group cover, this shortening was accommodated via a complex network of minor detachments that strike parallel to major underlying basement faults. For this reason, faults and folds measured at the surface in the sedimentary cover can be used as a predictive tool to infer basement structures at depth.

The mechanisms of denudation over the last 25,000 yrs are studied for Wangrah Creek, a headwater drainage basin of the Murrumbidgee River, N.S.W. The controls on denudation of climate, humans, and autonomous geomorphic change, are then resolved for different times in the past, by comparison with independent palaeoenvironmental data. The study also puts the history of the basin since settlement, 150 yrs ago, in it's longer term context. The stratigraphy of alluvial and colluvial deposits is investigated together with monitoring of streamflow, slope runoff and sediment yield. Historical changes to denudation are analysed from maps, air photographs and the most recent deposits. Extensive radiocarbon dating of deposits is included. The stratigraphy and morphology of Limekiln Creek, a tributary valley within the larger basin, allows modes of deposition to be attributed to certain lithologies. In particular, mildly organic, fine grained alluvium is associated with swampy meadows. These are valley floors with no continuous channel, a permanently saturated surface, and a dense vegetation of sedges and grasses. Planar bedded sands and gravels, deposited across the valley floor, are associated with discontinuous gullies. There was a period of rapid hillslope erosion in Wangrah Creek between 20,000 and 25,000 yrs BP. This left thick deposits in all valleys. A period of intense valley erosion removed the Pleistocene deposits from the main valleys and started incision of smaller valleys. The reworking of Pleistocene deposits became the dominant source of sediment in swampy meadows and small alluvial fans throughout the Holocene. Surface wash and gully extension were the mechanisms of erosion. Pleistocene deposits were the dominant source of sediment because of very low amounts of runoff from slopes. Impermeable sub-soils probably caused greater runoff from Pleistocene deposits. The Holocene was a period of low denudation rates, of the order of 1 mm of ground lowering per 1,000 years, averaged across the basin. Three times during the Holocene, as swampy meadows spread up valleys, intrinsically unstable conditions developed and a short period of gully erosion ensued. Monitoring of streamflow, and a simple hydrological model indicate that as swampy meadows expanded, runoff from moderate sized storms increased and small channels developed in the valley. The small channels are believed to promote gully initiation during large floods. Gullies started to infill once swampy meadows developed on the gully floor. Sediment delivery downstream then decreased to very low levels. Environmental changes during the Holocene had no effect on mechanisms of denudation and little effect on rates of denudation. With European settlement, gully erosion became more widespread than since the Pleistocene, although many gullies have now stabilised. In Wangrah Creek, gully erosion after settlement was initiated by different mechanisms than during the Holocene, and was probably the result of site-specific disturbances to the valley floor. Monitoring of erosion since a fire, coupled with the stratigraphic study, show that mild bushfires, whether anthropogenic or natural, will not accelerate erosion in Wangrah Creek. Aboriginal burning of the landscape in the late Holocene had little effect on denudation.

"Two independent geochronological techniques specifically targeting post-kinematic or late-stage growth of kyanite, staurolite and late-stage garnet in the southern Curnamona Province has found that these minerals grew during the Delamerian Orogeny (~530-500 Ma). Prograde metamorphism during the Delamerian Orogeny attained kyanite-staurolite-garnet grade (amphibolite-facies). Previous interpretations of an anticlockwise P-T path for the Olarian Orogeny need revising, as these interpretations have been shown in this study to be based on textural relationships spanning ~1100 million years. This highlights the importance of in situ geochronological techniques in defining robust P-T-t paths for a region." --p. 121 of source document.
Thesis (Ph.D.)--School of Earth and Environmental Sciences, 2006.

This thesis concerns a sedimentological study of the Late Permian Broughton, Pheasants Nest and Erins Vale Formations, southern Sydney Basin, New South Wales, aimed at producing a palaeoenvironmental interpretation of these sequences. It is based on facies analysis of borecore data, vertical and lateral profiling of outcrop sequences, including architectural element analysis, and an integration of the results of these studies with previous work. The sequences studied begin with the interdigitating lower offshore silt of the upper Berry Siltstone and lower offshore sand-belt of the lower Broughton Formation, including progradational volcanic shoreface sequences. Sedimentation occurred in the 'Broughton Seaway' between the western cratonic landmass and a north-northeast oriented volcanic barrier in the east. River-derived meltwater underflows, massflows, tidally-driven longshore currents and migration of large sandwaves into the lower offshore sand-belt were the major depositional processes. The upper offshore sand-sheets of the middle Broughton Formation represent a widespread development of time-transgressive, above storm wave base, aggradational sedimentation. The progradational sandskirts of volcanic alluvial fans in the south (Jamberoo Sandstone Member) constructed a delta which was of a mixed type between a pyroclastic and alluvial fan delta. These kinds of deltas probably served as significant sources and depositional conduits for the offshore sediments which were dispersed mainly through wave action in a storm-dominated setting._ Submarine volcanic flows and associated shallow marine environments, and emerged volcanic islands with woodlands were coevally present in the southeast during the deposition of the Broughton Formation. The upper Broughton Formation is generally marked by a northeastward diachronous progradation of the southern shoreline, which progressively filled up the Broughton Seaway. Progradational evolution of the deltaic to barred shoreline, reflecting waning influence of the Gerringong volcanic barriers, was contemporaneous with the upper deltaic and distributary coastal zone sedimentation of the Pheasants Nest Formation. Actually, the periglacial braided subaerial fans and subaerial volcanism modelled for the lower and middle Pheasants Nest Formation greatly contributed to a northward progradation of the shoreline and retreat of the Broughton Seaway. With additional contributions from the western craton, a centripetal sediment transport pattern toward a northeast-oriented depocentre resulted. This meant development of a northeasterly flowing longitudinal drainage system. Physiographically, most of the former Broughton Seaway had now transformed into a broad valley between the volcanic and cratonic hinterlands. During the upper Pheasants Nest Formation time, extensive development of a flat, alluvial plain with an axial drainage pattern, low-lying coastal swamps and networks of high sinuosity, single channel or multiple channel anastomosing river systems is postulated. A shallow epeiric Erins Vale sea was caused by transgression across the topographically low-lying northeastern to northern alluvial plains of the Pheasants Nest Formation . The lower-middle Erins Vale Formation represents shoreface-offshore conditions in the east and north, including an oxygen-deficient, lower offshore regime (Kulnura Marine Tongue) - and shoreline fades of a transgressive barrier system in the west and south. Deposition during the upper Erins Vale Formation occurred through fan delta progradation from the western craton, which passed upward into the subaerial fan of the Marangaroo Conglomerate; a central and southern regressive barrier system and an energetic shoreface sand in the east which passed upward into the Wilton Formation. The upper Nowra Sandstone and lower Berry Siltstone form a transgressive systems tract. A sustained tectonic loading producing protracted subsidence was apparently the primary cause of basin subsidence. The upper Berry Siltstone and lower to middle Broughton Formation represent an overall highstand systems tract with portions of the upper Berry Siltstone and the lowest Broughton Formation showing interludes of minor transgressive pulses. This reflected a more stabilized base-level situation, following a reduction of basin subsidence rate. The upper Broughton Formation and lower-middle Pheasants Nest Formation constitute a lowstand systems tract, including early regressive phases represented by the upper Broughton Formation. It was related to the development of a foreswell on the basin margin and subsidence in the depocentre caused by the propagation of compressional energy from the orogen. The upper Pheasants Nest Formation indicates an early transgressive stage and the lower Erins Vale Formation, including the Kulnura Marine Tongue, is a transgressive systems tract. The middle Erins Vale Formation represents a highstand systems tract. Subsequently, the early regressive phases represented by the upper Erins Vale Formation, the lowstand wedge of the basal Wilton Formation and the Marangaroo Conglomerate constituted a lowstand systems tract. They developed as a result of erosion of a fores well produced on the cratonic margin. This study provides evidence in support of the Currarong Orogen. The Offshore Uplift is probably a preserved portion of the Currarong Orogen and the Newcastle Sub-basin was a likely depocentre for the Late Permian sequences. A periglacial climate with seasonal freezing and thawing had significant influence on sedimentation. Episodic meltwater discharge mobilized large volumes of volcaniclastic materials in spring (as lahars at times of large floods and/ or volcanic eruptions) and associated ice floes enroute to the sea. The major variables for the studied sequences in the southern Sydney Basin are constrained in this thesis, and comparative studies identified modern and ancient global examples that are broadly similar to the Late Permian sequences.

Research Doctorate - Doctor of Philosophy (PhD)
Geographical identity of wines and wine regions is a potent marketing took that highlights the value and uniqueness of a particular product. Many Old World viticultural countries place great importance on the role of soil properties in determining geographical identity of wines. However this view has not gained currency in Australia, which does not have the density of plantings to highlight any soil influences on wine. It is relatively intuitive to suggest that soils have an influence on wine style and quality. After all, grapevines are grown in soils and are dependent upon them for support, nutrients and water. However, although there is a voluminous world literature declaring this relationship to be true, a meticulous examination of it points to the fact that the scientific evidence is scant and that very few studies could claim to have established clear links via truly repeatable, rigorous scientific methods. Much of what has been written is either biased by preconceived notions, journalistic licence, or flawed by an inattention to the complexity of the path from soil through root, vine and grape, to wine. Previous attempts at establishing relationships between soil geography and wine have been embroiled in the complexities of the definition of the French term 'terroir'. Examination is made of the world literature on terroir and the various attempts at classifying regions based on this sometimes tenuous concept. Literature related to the classification of wines based on their labaratory-determined constituents is also examined. By using a rigorously controlled geographical approach, this thesis attempts to "bridge the gap" between the wine industry's use and misuse of the concept of terroir and the detailed soil and plant physiological research which, although extremely valuable, has not often been readily transferable to the field situation. 11 soil locations were identified and described in the Pokolbin viticultural district that had distinctly different soil properties but were: a) planted to same grape variety (shiraz) with the same age and history; b) within the same mesoclimatic area; c) having identical soil and canopy management; and d) no irrigation influences. Thus all possible environmental influences on grape composition were controlled for except for soil variation. A wide range of juice and grape composition measures were obtained at harvest from each soil location, over three successive vintages, 1994, 1995 and 1996. These included yield parameters, juice composition, pigments, phenolics, glycosyl and mineral composition. Differences in grape composition were compared between soil locations and between years to gauge the relative influence of soil versus seasonal effects. Soil properties were examined in detail and used to help explain the variation in grape composition. It was found that significant variation in grape composition existed that could only have been attributed to soil variation. In many instances the soil location effects were significantly more influential than the vintage effect, even though the three seasons studied differed considerably in climatic conditions. Multivariate analysis of the grape composition data highlighted interactions between measures that were influenced by soil location effects. Interactions between calcium and magnesium in the grape were examined in more detail, and it was shown that a positive correlation exists between these two measures. This relationship is influenced and hidden by soil properties, namely the relative proportion of calcium and magnesium in soils. The broad implications of these results are discussed with relevance to site selection of vineyards and viticultural trials, the relative importance of soil chemistry in viticulture, irrigation management, and Geographical Indications in Australia.