Academic literature on the topic 'Gas solid interaction'

Title from PDF of title page (University of Missouri--Columbia, viewed on Feb 24, 2010). The entire thesis text is included in the research.pdf file; the official abstract appears in the short.pdf file; a non-technical public abstract appears in the public.pdf file. Dissertation advisor: Dr. Jerry L. Atwood. Vita. Includes bibliographical references.

Cette thèse est consacrée à l’étude expérimentale et numérique de l’interaction entre gaz et surface solide. L’écoulement de gaz raréfié à travers un microcanal rectangulaire dans des conditions isothermes et nonisothermes ont été évalués expérimentalement. Le coefficient d’accommodation de la composante tangentielle de la quantité de mouvement pour le matériau PEEK (Poly Ether Ether Ketone) associé à cinq gaz (hélium, néon, azote, argon, krypton) a été extrait des écoulements induits par gradient de pression et gradient de température. De plus, des écoulements unidimensionnels stables d’un gaz polyatomique en présence d’une surface adsorbante-désorbante maintenue à température constante et uniforme sont simulés en résolvant numériquement l’équation cinétique de Boltzmann par la méthode Direct Simulation Monte Carlo (DSMC). Il est considéré ici l’écoulement de gaz entre deux parois planes et infinies, où une seule paroi est capable d’adsorber et de désorber les molécules, tandis que l’autre est imperméable. Enfin,des recherches expérimentales et numériques ont été effectuées pour analyser la séparation des espèces BTEX (benzène, toluène, éthylbenzène et xylènes) à l’intérieur d’une colonne chromatographique. De l’étalonnage des constantes d’adsorption et de désorption, le temps de rétention de chaque espèce peut être prévu pour différentes conditions de fonctionnement en utilisant le code numérique développé<br>This thesis is devoted to the experimental and numerical study of the interaction between gas and solid surface. Rarefied gas flows through a rectangular microchannel under both isothermal and non-isothermal conditions were experimentally evaluated. The tangential momentum accommodation coefficient for PEEK (Poly Ether Ether Ketone) material associated to five gases (helium, neon, nitrogen, argon, krypton) was extracted from both pressure and temperature gradient driven flows. Additionally, steady one-dimensional flows of a polyatomic gas in the presence of an adsorbing-desorbing surface kept at constant and uniform temperature are simulated by solving numerically the Boltzmann kinetic equation by the Direct Simulation Monte Carlo (DSMC) method. It is considered the flow of gas between two planar and infinite surfaces,where only one surface is able to adsorb and desorb molecules, while the other one is impermeable. Finally, experimental and numerical investigation were performed to analyze the BTEX (benzene, toluene,ethylbenzene and xylenes) species separation inside a chromatographic column. From calibrating the constants of adsorption and desorption, the retention time of each species can be predicted for different operating conditions using the numerical code developed

Studying the interactions of solid particles and deformable gas<br />bubbles in viscous liquids is very important in many applications,<br />especially in mining and chemical industries. These interactions<br />involve liquid-solid-air multiphase flows and an<br />arbitrary-Lagrangian-Eulerican (ALE) approach is used for the direct<br />numerical simulations. In the system of rigid particles and<br />deformable gas bubbles suspended in viscous liquids, the<br />Navier-Stokes equations coupled with the equations of motion of the<br />particles and deformable bubbles are solved in a finite-element<br />framework. A moving, unstructured, triangular mesh tracks the<br />deformation of the bubble and free surface with adaptive refinement.<br />In this dissertation, we study four problems. In the first three<br />problems the flow is assumed to be axisymmetric and two dimensional<br />(2D) in the fourth problem.<br /><br />Firstly, we study the interaction between a rising deformable bubble<br />and a solid wall in highly viscous liquids. The mechanism of the<br />bubble deformation as it interacts with the wall is described in<br />terms of two nondimensional groups, namely the Morton number (Mo)<br />and Bond number (Bo). The film drainage process is also<br />considered. It is found that three modes of bubble-rigid wall<br />interaction exist as Bo changes at a moderate Mo.<br />The first mode prevails at small Bo where the bubble deformation<br />is small. For this mode, the bubble is<br /> hard to break up and will bounce back and eventually attach<br />to the rigid wall. In the second mode, the bubble may break up after<br />it collides with the rigid wall, which is determined by the film<br />drainage. In the third mode, which prevails at high Bo, the bubble<br />breaks up due to the bottom surface catches up the top surface<br />during the interaction.<br /><br />Secondly, we simulate the interaction between a rigid particle and a<br />free surface. In order to isolate the effects of viscous drag and<br />particle inertia, the gravitational force is neglected and the<br />particle gains its impact velocity by an external accelerating<br />force. The process of a rigid particle impacting a free surface and<br />then rebounding is simulated. Simplified theoretical models are<br />provided to illustrate the relationship between the particle<br />velocity and the time variation of film thickness between the<br />particle and free surface. Two film thicknesses are defined. The<br />first is the thickness achieved when the particle reaches its<br />highest position. The second is the thickness when the particle<br />falls to its lowest position. The smaller of these two thicknesses<br />is termed the minimum film thickness and its variation with the<br />impact velocity has been determined. We find that the interactions<br />between the free surface and rigid particle can be divided into<br />three regimes according to the trend of the first film thickness.<br />The three regimes are viscous regime, inertial regime and jetting<br />regime. In viscous regime, the first film thickness decreases as the<br />impact velocity increases. Then it rises slightly in the inertial<br />regime because the effect of liquid inertia becomes larger as the<br />impact velocity increases. Finally, the film thickness decreases<br />again due to Plateau-Rayleigh instability in the jetting regime.<br />We also find that the minimum film thickness corresponds to an<br />impact velocity on the demarcation point between the viscous and<br />inertial regimes. This fact is caused by the balance of viscous<br />drag, surface deformation and liquid inertia.<br /><br />Thirdly, we consider the interaction between a rigid particle and a<br />deformable bubble. Two typical cases are simulated: (1) Collision of<br />a rigid particle with a gas bubble in water in the absence of<br />gravity, and (2) Collision of a buoyancy-driven rising bubble with a<br />falling particle in highly viscous liquids. We also compare our<br />simulation results with available experimental data. Good agreement<br />is obtained for the force on the particle and the shape of the<br />bubble.<br /><br />Finally, we investigated the collisions of groups of bubbles and<br />particles in two dimensions. A preliminary example of the oblique<br />collision between a single particle and a single bubble is conducted<br />by giving the particle a constant acceleration. Then, to investigate<br />the possibility of particles attaching to bubbles, the interactions<br />between a group of 22 particles and rising bubbles are studied. Due<br />to the fluid motion, the particles involved in central collisions<br />with bubbles have higher possibilities to attach to the bubble.<br>Ph. D.

Thesis (Ph. D.)--West Virginia University, 2009.<br>Title from document title page. Document formatted into pages; contains xii, 122 p. : ill. (some col.). Includes abstract. Includes bibliographical references (p. 115-122).

Master of Science<br>Department of Mechanical and Nuclear Engineering<br>Steven J. Eckels<br>NanoActiveTM metal oxide particles have the ability to destructively adsorb organophosphorus compounds and chlorocarbons. These nanomaterials with unique surface morphologies are subjected to separate, low concentrations of gaseous ammonia in air. NanoActiveTM materials based on magnesium oxide have large specific surface areas and defective sites that enhance surface reactivity and consequently improved adsorptivity. In gas contaminant removal by adsorption, presence of vast specific surface area is essential for effective gas-solid interaction to take place. This is also the case in many industrial and chemical applications such as purification of gases, separation and recovery of gases, catalysis etc,. Typically carbonaceous compounds are utilized and engineered in toxic gas control systems. The purpose of this study was to compare NanoActiveTM materials with carbon based compounds in the effectivity of toxic gas adsorption at low concentrations. A test facility was designed to investigate the adsorption properties of novel materials such as adorption capacity and adsorption rate. Adsorption capacity along with adsorption kinetics is a function of properties of the adsorbent and the adsorbate as well as experimental conditions. Nanomaterials were placed on a silica matrix and tested with increasing flow rates. Electrochemical sensing devices were placed at inlet and outlet of the facility to monitor real time continuous concentration profiles. Breakthrough curves were obtained from the packed bed column experiments and saturation limits of adsorbents were measured. Adsorption rates were obtained from the breakthrough curves using modified Wheeler-Jonas equation. The NanoActiveTM materials adsorbed ammonia though to a lesser extent than the Norit® compounds. This study also included measurement of pressure drop in packed beds. This information is useful in estimating energy losses in packed bed reactors. Brauner Emmet Teller tests were carried out for the calculation of surface area, pore volume and pore size of materials. These calculations suggest surface area alone had no notable influence on adsorption capacity and adsorption rates. This lead to the conclusion that adsorption was insignificant cause of absence of functional groups with affinity towards ammonia. In brief, adsorption of ammonia is possible on NanoActiveTM materials. However functional groups such as oxy-flouro compounds should be doped with novel materials to enhance the surface interactions.

Gas-solid fluidized bed reactors are widely applied in chemical and energy industries, and their design and scale-up are virtually empirical, extremely expensive and time consuming. This scenario has motivated the development of alternative theoretical tools, and two-fluid modeling, where gas and particulate are both treated as interpenetrating continuum phases, has appeared as a most promising approach. Owing to the large domains to be resolved in real-scale fluidized bed reactors, only filtered modeling approaches are feasible, and closure models become necessary to recover sub-grid effects that are filtered by the very coarse numerical grids that are imposed owing to computational limitations. Those closure models, which in hydrodynamic formulations account for filtered interphase momentum exchanges and filtered and residual stresses in the phases, can be derived from results of highly resolved simulations (HRS) performed over small size domains under refined numerical grids. One widely practiced approach consists of applying two-fluid modeling under micro-scale defined closures, generally known as microscopic two-fluid modeling. This approach includes microscopic closures for solid phase stresses derived from the kinetic theory of granular flows (KTGF), which accounts for kinetic-collisional effects only, and is adequate to dilute flows. Otherwise, the conventional KTGF does not account for interparticle friction effects, and its application to dense flow conditions is quite questionable. In this work a literature available modified version of KTGF is applied which also accounts for interparticle friction, and highly resolved simulations are performed for dense flow conditions in order to evaluate the effects of friction over relevant filtered parameters (namely effective drag coefficient, filtered and residual stresses). Ranges of domain average solid volume fractions and gas Reynolds numbers are considered (macro-scale conditions) embracing dense gas-solid fluidized flows from suspensions up to pneumatic transport. The MFIX open source code is used in all the simulations, which are performed over 2D periodical domains for a unique monodisperse particulate. The HRS results (i.e. meso-scale flow fields) are filtered over regions compatible with grid sizes in large scale simulations, and the relevant filtered parameters of concern are derived and classified by ranges of other filtered parameters taken as independent variables (filtered solid volume fraction, filtered slip velocity, and filtered kinetic energy of solid velocity fluctuations, which are referred to as markers). Results show that the relevant filtered parameters of concern are well correlated to all of those filtered markers, and also to all of the imposed macro-scale conditions. Otherwise, interparticle friction showed no significant effects over any filtered parameter. It is recognized that this issue clearly requires further investigation notably regarding the suitability of the markers that were assumed for classifying the filtered results. The current work is intended as a contribution for future developments of more accurate closure models for large scale simulations of gas-solid fluidized flows.<br>Reatores de leito fluidizado de escoamento gás-sólido são largamente utilizados nas indústrias química e de energia, e o seu projeto e escalonamento são virtualmente empíricos, extremamente caros e demorados. Este cenário tem motivado o desenvolvimento de ferramentas teóricas alternativas, e a modelagem de dois fluidos, onde gás e particulado são ambos tratados com fases contínuas interpenetrantes, tem surgido como uma aproximação muito promissora. Devido aos grandes domínios a serem resolvidos em reatores de leito fluidizado de escala real, apenas aproximações de modelagem filtradas são viáveis, e modelos de fechamento tornam-se necessários para recuperar efeitos sub-malha que são filtrados pelas malhas numéricas grosseiras que são impostas devido as limitações computacionais. Estes modelos de fechamento, que em formulações hidrodinâmicas respondem principalmente por trocas de momentum filtradas entre fases e tensões filtradas e residuais nas fases, podem ser obtidos de resultados de simulações altamente resolvidas (SAR) realizadas em domínios de dimensões reduzidas sob malhas numéricas refinadas. Uma aproximação largamente praticada consiste na aplicação de modelagem de dois fluidos sob fechamentos definidos na micro-escala, genericamente conhecida como modelagem microscópica de dois fluidos. Esta aproximação inclui fechamentos microscópicos para tensões da fase sólida obtidos da teoria cinética dos escoamentos granulares (TCEG), que considera apenas efeitos cinéticos-colisionais, e é adequada para escoamentos diluídos. Por outro lado, a TCEG convencional não leva em conta efeitos de fricção interpartículas, e sua aplicação para condições densas de escoamento é bastante questionável. Neste trabalho aplica-se uma versão modificada da TCEG disponível na literatura que também leva em conta fricção interpartículas, e simulações altamente resolvidas são realizadas para condições de escoamentos densos visando avaliar os efeitos da fricção sobre os parâmetros filtrados relevantes (coeficiente de arrasto efetivo, tensões filtradas e residuais). Considera-se faixas de frações volumétricas de sólido e números de Reynolds do gás médios no domínio (condições de macro-escala) abrangendo escoamentos gás-sólido fluidizados densos desde suspensões até transporte pneumático. O código aberto MFIX é utilizado em todas as simulações, que foram executadas sobre domínios periódicos 2D para um único particulado monodisperso. Os resultados das SAR (i.e., campos de escoamento de meso-escala) foram filtrados sobre regiões compatíveis com tamanhos de malha praticados em simulações de grandes escalas, e os parâmetros filtrados relevantes de interesse são calculados e classificados por faixas de outros parâmetros filtrados tomados como variáveis independentes (fração volumétrica de sólido filtrada, velocidade de deslizamento filtrada, e energia cinética das flutuações de velocidade da fase sólida filtrada, que são referidos como marcadores). Os resultados mostram que os parâmetros filtrados relevantes de interesse são bem correlacionados com todos os marcadores, e também com todas as condições de macro-escala impostas. Por outro lado, a fricção interpartículas não mostrou efeitos significativos sobre qualquer parâmetro filtrado. Reconhece-se que este aspecto claramente requer investigações adicionais, notadamente com respeito à adequação dos marcadores que foram considerados para classificação dos resultados filtrados. O trabalho corrente é posto como uma contribuição para o desenvolvimento futuro de modelos de fechamento mais acurados para simulações de grandes escalas de escoamentos gás-sólido fluidizados.

This project was compiled in co-operation with the Royal Institute of Technology, Stockholm and Veolia Environmental Services (Australia) at the Woodlawn Bioreactor in NSW, Australia. Hydrogen sulphide is an unwanted component of landfill gas, raising occupational health and safety concerns, whilst leading to acid gas corrosion of power generation equipment and increased emissions of SOx, a primary constituent of acidification. Australian governmental requirements to place a periodic cover over the unused proportion of the tipping surface of landfills and bioreactors create an interesting opportunity for the removal of the hydrogen sulphide component of landfill gas. Using waste materials containing a high concentration of metals as waste cover can enhance the precipitation of sulphur in the form of metal sulphides. The reduction of sulphate via sulphate reducing bacteria is prevalent in sites that have a sizeable inflow of sulphate. The Woodlawn Bioreactor is located in an area where the influence of sulphate has a critical influence of bioreactor performance and production of hydrogen sulphide. Through a series of experimental bioreactors it was established that from the use of metalliferous periodic waste covers, the hydrogen sulphide component of landfill gas was maintained at an extremely low level when compared to the levels of hydrogen sulphide produced in waste under the influence of high sulphate loads with no waste cover.<br>www.ima.kth.se

The present research project is carried out at the von Karman Institute for Fluid Dynamics (Rhode-Saint-Genèse, Belgium) with the financial support of the European Space Agency.<p><p>The first stage of spacecrafts (e.g. Ariane 5, Vega, Shuttle) generally consists of large solid propellant rocket motors (SRM), which often consist of segmented structure and incorporate a submerged nozzle. During the combustion, the regression of the solid propellant surrounding the nozzle integration part leads to the formation of a cavity around the nozzle lip. The propellant combustion generates liquefied alumina droplets coming from chemical reaction of the aluminum composing the propellant grain. The alumina droplets being carried away by the hot burnt gases are flowing towards the nozzle. Meanwhile the droplets may interact with the internal flow. As a consequence, some of the droplets are entrapped in the cavity forming an alumina puddle (slag) instead of being exhausted through the throat. This slag reduces the performances.<p><p>The aim of the present study is to characterize the slag accumulation process in a simplified model of the MPS P230 motor using primarily optical experimental techniques. Therefore, a 2D-like cold-gas model is designed, which represents the main geometrical features of the real motor (presence of an inhibitor, nozzle and cavity) and allows to approximate non-dimensional parameters of the internal two-phase flow (e.g. Stokes number, volume fraction). The model is attached to a wind-tunnel that provides quasi-axial flow (air) injection. A water spray device in the stagnation chamber realizes the models of the alumina droplets, which are accumulating in the aft-end cavity of the motor.<p><p>To be able to carry out experimental investigation, at first the the VKI Level Detection and Recording(LeDaR) and Particle Image Velocimetry (PIV) measurement techniques had to be adapted to the two-phase flow condition of the facility.<p><p>A parametric liquid accumulation assessment is performed experimentally using the LeDaR technique to identify the influence of various parameters on the liquid deposition rate. The obstacle tip to nozzle tip distance (OT2NT) is identified to be the most relevant, which indicates how much a droplet passing just at the inhibitor tip should deviate transversally to leave through the nozzle and not to be entrapped in the cavity.<p><p>As LeDaR gives no indication of the driving mechanisms, the flow field is analysed experimentally, which is supported by numerical simulations to understand the main driving forces of the accumulation process. A single-phase PIV measurement campaign provides detailed information about the statistical and instantaneous flow structures. The flow quantities are successfully compared to an equivalent 3D unsteady LES numerical model.<p><p>Two-phase flow CFD simulations suggest the importance of the droplet diameter on the accumulation rate. This observation is confirmed by two-phase flow PIV experiments as well. Accordingly, the droplet entrapment process is described by two mechanisms. The smaller droplets (representing a short characteristic time) appear to follow closely the air-phase. Thus, they may mix with the air-phase of the recirculation region downstream the inhibitor and can be carried into the cavity. On the other hand, the large droplets (representing a long characteristic time) are not able to follow the air-phase motion. Consequently, a large mean velocity difference is found between the droplets and the air-phase using the two-phase flow measurement data. Therefore, due to the inertia of the large droplets, they may fall into the cavity in function of the OT2NT and their velocity vector at the level of the inhibitor tip.<p><p>Finally, a third mechanism, dripping is identified as a contributor to the accumulation process. In the current quasi axial 2D-like set-up large drops are dripping from the inhibitor. In this configuration they are the main source of the accumulation process. Therefore, additional numerical simulations are performed to estimate the importance of dripping in more realistic configurations. The preliminary results suggest that dripping is not the main mechanism in the real slag accumulation process. However, it may still lead to a considerable contribution to the final amount of slag.<p><br>Doctorat en Sciences de l'ingénieur<br>info:eu-repo/semantics/nonPublished