Academic literature on the topic 'Fundamentals of electrochemistry'

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Journal articles on the topic "Fundamentals of electrochemistry"

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Parsons, Roger. "Fundamentals of electrochemistry." Journal of Electroanalytical Chemistry 402, no. 1-2 (February 1996): 226. http://dx.doi.org/10.1016/s0022-0728(96)90031-5.

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Kaden, H. "Fundamentals of Electrochemistry." Zeitschrift für Physikalische Chemie 189, Part_1 (January 1995): 147–48. http://dx.doi.org/10.1524/zpch.1995.189.part_1.147a.

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McEvoy, A. J. "Fundamentals and applications of electrochemistry." EPJ Web of Conferences 54 (2013): 01018. http://dx.doi.org/10.1051/epjconf/20135401018.

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Molina, Angela. "Editorial: Fundamentals and Theoretical Electrochemistry." Current Opinion in Electrochemistry 1, no. 1 (February 2017): A2—A4. http://dx.doi.org/10.1016/j.coelec.2017.02.002.

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Covington, A. K. "V.S. Bagotsky, Fundamentals of electrochemistry." Analytica Chimica Acta 297, no. 3 (November 1994): 468. http://dx.doi.org/10.1016/0003-2670(94)80360-9.

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Ding, Zhifeng. "Books and Software: Translating electrochemistry fundamentals." Analytical Chemistry 76, no. 21 (November 2004): 415 A. http://dx.doi.org/10.1021/ac041654j.

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Long, Yi‐Tao, Patrick R. Unwin, and Lane A. Baker. "Single‐Entity Electrochemistry: Fundamentals and Applications." ChemElectroChem 5, no. 20 (September 3, 2018): 2918–19. http://dx.doi.org/10.1002/celc.201801169.

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Nishi, Naoya. "The 7th Forum of Fundamentals of Electrochemistry." Review of Polarography 53, no. 2 (2008): 96. http://dx.doi.org/10.5189/revpolarography.53.96.

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Nishi, Naoya. "The 9th Forum of Fundamentals of Electrochemistry." Review of Polarography 54, no. 2 (2008): 131. http://dx.doi.org/10.5189/revpolarography.54.131.

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Nishi, Naoya. "The 8th Forum of Fundamentals of Electrochemistry." Review of Polarography 54, no. 1 (2008): 39. http://dx.doi.org/10.5189/revpolarography.54.39.

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Dissertations / Theses on the topic "Fundamentals of electrochemistry"

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Brownson, D. A. C. "Graphene electrochemistry : fundamentals through to electroanalytical applications." Thesis, Manchester Metropolitan University, 2013. http://e-space.mmu.ac.uk/315692/.

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Graphene is reported to possess a range of unique and highly desired properties and consequently has potential to revolutionise the field of electrochemistry if diligently employed as a new-generation electrode material. Graphene potentially represents the world’s thinnest electrode material, but there are experimental parameters to be overcome: the first problem is how to electrically wire/connect to the graphene sample(s) as to obtain the reported benefits; the second issue is how to reduce aggregation of graphene sheets back to their lowest energy conformation, that is, graphite, due to the strong π–π interactions between the graphene sheets; the third and final limitation is that various fabrication routes produce graphene to differing qualities, a factor that must be considered when exploring its fundamental electrochemical properties and electroanalytical implementation. This thesis reports on the fundamental electrochemical characterisation and resultant electroanalytical applicability of utilising graphene as a novel electrode material. The thesis consists of four key contributions, each developing on the knowledge gained from the previous. Chapters 1 through to 3 give an overview of the relevant fundamental electrochemical concepts with which this thesis is concerned. Chapter 4 provides a ‘snap-shot’ of the state of the graphene literature from 2010 (upon the commencement of this work), from which successive chapters follow the chronological development and investigation of graphene as produced through a variety of synthesis methods, gradually building a complete picture and understanding of the electrochemistry of graphene and the implications of its properties towards the fabrication and implementation of graphene as an electroanalytical sensor substrate. IV | P a g e Chapter 5 details the relevant experimental information and the full physicochemical characterisation of the various graphene materials utilised within this work. Chapters 6 and 7 utilise graphenes that are fabricated via a ‘top-down’ approach, which is most commonly employed in the literature, where in order to ‘connect to’ the graphene a liquid suspension is immobilised onto a suitable electrode surface. Chapter 6 uses surfactant-modified graphene and investigates, for the first time, the influence that such surfactants have on the observed electrochemistry. Chapter 7 uses pristine graphene in solution and considers; the aspects of various ‘coverages’ of graphene, the supporting electrode substrate, and how the formation of few and multiple layered graphene structures can influence the observed response. These parameters are overlooked within the current literature. Chapter 8 utilises graphene that is fabricated via a ‘bottom-up’ Chemical Vapour Deposition approach, which gives rise to high quality single layer graphene domains that, once efficiently ‘housed’ in order to connect to the graphene, allow the electrochemical exploration of monolayer graphene to be realised and be compared to quasi-graphene and defect abundant graphene structures for the first time. This approach allows the structure of graphene to be correlated with that of the electrochemical response for the first time. Critically, this work unambiguously demonstrates that the electrochemical response is edge plane like defect dependent. The final part of this thesis (Chapter 9) utilises a range of modified graphenes including novel three-dimensional (3D) structures (a graphene foam and graphene paste) and functionalised graphene (graphene/graphitic oxide), with the effects of said modifications explored towards the fundamental electrochemical and electroanalytical properties obtained. The first part of this chapter reports the electrochemistry of a novel freestanding 3D graphene V | P a g e foam and, for the first time, critically compares this to a freestanding 3D carbon foam alternative. It is demonstrated that the graphene foam gives rise to beneficial voltammetric responses in non-aqueous media, namely ionic liquids. This chapter also explores the use of a graphene paste electrode and demonstrates that the voltammetric response is no better than that of a graphite based paste electrode. Last, the use of graphene/graphitic oxide as an electrode material is explored and shown to give rise to unique voltammetric signatures, which are coverage dependant and can be utilised as a means of characterising the successful production of graphene through the reduction of graphene/graphitic oxide (as commonly utilised within the current electrochemical literature). Furthermore, it is shown that the unique voltammetry observed at graphene/graphitic oxide modified electrodes can be used beneficially for electrocatalytic processes. This thesis demonstrates that, within the graphene electrochemical literature, control experiments are often an overlooked comparison, which are needed for the electrochemical response of graphene to be understood and before the benefits of graphene can be claimed in such instances where superiority is ‘demonstrated’.
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Meng, Lingcong. "Thermo-electrochemistry of boron doped diamond from fundamentals to application." Thesis, University of Warwick, 2016. http://wrap.warwick.ac.uk/88929/.

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Boron doped diamond (BDD), due to its exceptional electrochemical response (extended solvent window and low background current) and thermal properties (large thermal diffusivity and extreme resistance to thermal ablation), is investigated as the electrode material for thermoelectrochemical studies. A pulsed infrared (IR) laser technique is used to heat the electrode from the back (nonsolution) side. The non-isothermal pulsed technique enables mass transport to be more readily controlled as opposed to isothermal heating approaches such as a water bath. The effect of temperature on fundamental electrochemical processes, such as mass transport, electron transfer (ET) kinetics and thermodynamics of both outer sphere and inner sphere redox mediators is investigated on both BDD macro- and micro- electrodes. The effective temperature increase at electrode surface can be determined both experimentally and theoretically using finite element models. Enhanced mass transport and ET process at elevated temperatures, in addition to the temperature coefficient of the redox mediators, play a crucial role in the temperature dependent electrochemical response. Thermoelectrochemical studies are extended to an electroactive species which forms a solid structure after electrolysis. In particular, the cathodic electrodeposition of lead/lead oxide (Pb/PbO) under non-isothermal heating conditions in nitrate containing solutions is investigated. The effect of deposition potential, time, dissolved oxygen content and temperature are explored to understand the mechanism for the synthesis of crystalline PbO “plate” structures, and the role of electrodeposited Pb. Further work explores the effect of temperature on an electroactive species which upon electrolysis forms a solid product which fouls the electrode surface. Using a BDD microelectrode it is possible to show how temperature can be used to minimise the effect of surface blocking after the oxidation of a neurotransmitter, dopamine, which is known to lead to electrode fouling. Finally, proof of concept studies are undertaken to assess the suitability of a thermoelectrochemical approach to the detection of single nucleotide polymorphism (SNP) in deoxyribonucleic acid (DNA). Initial studies investigate immobilisation strategies for both (in separate experiments) electrochemically active self-assembled monolayers (SAM) and redox-labelled double stranded DNA on gold and BDD electrodes.
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Stevens, Michaela. "Fundamentals and Industrial Applications: Understanding First Row Transition Metal (Oxy)Hydroxides as Oxygen Evolution Reaction Catalysts." Thesis, University of Oregon, 2017. http://hdl.handle.net/1794/22633.

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Intermittent renewable energy sources, such as solar and wind, will only be viable if the electrical energy can be stored efficiently. It is possible to store electrical energy cleanly by splitting the water into oxygen (a clean byproduct) and hydrogen (an energy dense fuel) via water electrolysis. The efficiency of hydrogen production is limited, in part, by the high kinetic overpotential of the oxygen evolution reaction (OER). OER catalysts have been extensively studied for the last several decades. However, no new highly active catalyst has been developed in decades. One reason that breakthroughs in this research are limited is because there have been many conflicting activity trends. Without a clear understanding of intrinsic catalyst activity it is difficult to identify what makes catalysts active and design accordingly. To find commercially viable catalysts it is imperative that electrochemical activity studies consider and define the catalyst’s morphology, loading, conductivity, composition, and structure. The research goal of this dissertation is twofold and encompasses 1) fundamentally understanding how catalysis is occurring and 2) designing and developing a highly active, abundant, and stable OER catalyst to increase the efficiency of the OER. Specifically, this dissertation focuses on developing methods to compare catalyst materials (Chapter II), understanding the structure-compositional relationships that make Co-Fe (oxy)hydroxide materials active (Chapter III), re-defining activity trends of first row transition metal (oxy)hydroxide materials (Chapter IV), and studying the role of local geometric structure on active sites in Ni-Fe (oxy)hydroxides (Chapter V). As part of a collaboration with Proton OnSite, the catalysts studied are to be integrated into an anion exchange membrane water electrolyzer in the future. This dissertation includes previously published and unpublished co-authored material.
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Yoon, Dalsung. "Electrochemical Studies of Cerium and Uranium in LiCl-KCl Eutectic for Fundamentals of Pyroprocessing Technology." VCU Scholars Compass, 2016. http://scholarscompass.vcu.edu/etd/4602.

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Understanding the characteristics of special nuclear materials in LiCl-KCl eutectic salt is extremely important in terms of effective system operation and material accountability for safeguarding pyroprocessing technology. By considering that uranium (U) is the most abundant and important element in the used nuclear fuel, measurements and analyses of U properties were performed in LiCl-KCl eutectic salt. Therefore, the electrochemical techniques such as cyclic voltammetry (CV), open circuit potential (OCP), Tafel, linear polarization (LP), and electrochemical impedance spectroscopy (EIS) were conducted under different experimental conditions to explore the electrochemical, thermodynamic, and kinetic properties of U in LiCl-KCl eutectic. The ultimate goal of this study was to develop proper methodologies for measuring and analyzing the exchange current density (i0) of U3+/U reaction, which has not been fully studied and understood in literature. In the preliminary study, cerium (Ce) was selected as a surrogate material for uranium and its behavior was being explored with the developments of experimental methods. CV was performed to evaluate Ce properties such as the diffusion coefficients (D), apparent standard reduction potential (E0*), Gibbs free energy (DG), and activity coefficient (g). In addition, EIS methods were adapted and specific experimental procedures were established for the proper i0 measurements providing repeatable and reproducible data sets. The i0 values for Ce3+/Ce pair were ranging from 0.0076 A cm-2 to 0.016 A cm-2, depending on the experimental conditions. These preliminary results give insight in developing the experimental setups and methods to evaluate the properties of U in LiCl-KCl. Plus, Ce is one of the lanthanide (Ln) fission products in electrorefiner (ER) system; therefore, the resulting data values yield useful information of the fundamental behaviors of Ln elements in the system. Based on these developed methodologies, the experimental designs and routines were established to explore the main properties (e.g., D, E0*, etc.) of UCl3 in LiCl-KCl eutectic salt under different concentrations (0.5 wt% to 4 wt% UCl3) and temperatures (723 K to 798 K). Specially, the i0 values of U3+/U were evaluated via EIS, LP, Tafel, and CV methods. All i0 values had linear trends with the change of concentration and temperature; however, these values measured by LP, Tafel, and CV methods were greatly influenced by the change in electrode surface area. Overall, the i0 values agreed within 33% relative error range with the EIS method being the most consistent and accurate in comparison to reported literature values. The measured values of i0 were ranging from 0.0054 A cm-2 to 0.102 A cm-2. Therefore, an extremely reliable database for i0 was provided and it is feasible to anticipate the i0 kinetics in other experimental conditions by using the provided equation models. Furthermore, GdCl3 was added to the LiCl-KCl-UCl3 system to explore the effects of other elements on the U properties such as the diffusion coefficients, thermodynamic properties, and i0 kinetics. The diffusion coefficient was generally decreased by 12 ~ 35% with addition of GdCl3 in LiCl-KCl-UCl3; however, the apparent standard potentials and exchange current density follow the same trends with data obtained without GdCl3 additions. Hence, the results indicate that the thermodynamic and kinetic values for U3+/U reaction in LiCl-KCl eutectic salt are not greatly influenced by the presence of GdCl3.
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Franco, Alejandro A. "A multiscale modeling framework for the transient analysis of PEM Fuel Cells - From the fundamentals to the engineering practice." Habilitation à diriger des recherches, Université Claude Bernard - Lyon I, 2010. http://tel.archives-ouvertes.fr/tel-00740967.

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In recent years, Polymer Electrolyte Membrane Fuel Cells (PEMFC) have attracted much attention due to their potential as a clean power source for many applications, including automotive, portable and stationary devices. This resulted in a tremendous technological progress, such as the development of new membranes and electro-catalysts or the improvement of electrode structures. However, in order to compete within the most attractive markets, the PEMFC technologies did not reach all the required characteristics yet, in particular in terms of cost and durability.Because of the strong coupling between different physicochemical phenomena, the interpretation of experimental observations is difficult, and analysis through modeling becomes crucial to elucidate the degradation and failure mechanisms, andto help improving both PEMFC electrochemical performance and durability.The development of a theoretical tool is essential for industrials and the scientific community to evaluate the PEMFC degradation and to predict itsperformance and durability in function of the materials properties and in a diversity of operating conditions. This manuscript summarizes my scientific research efforts in this exciting topic during the last 9 years in France, including my invention of the MEMEPhys multiscale simulation package,developed on the basis of my childhood passion for the New Technologies for Energyin Argentina. My perspectives of adapting this approach to other electrochemical systems such as water electrolyzers and batteries are also discussed.
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Böhme, Solveig. "Fundamental Insights into the Electrochemistry of Tin Oxide in Lithium-Ion Batteries." Doctoral thesis, Uppsala universitet, Strukturkemi, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-319428.

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This thesis aims to provide insight into the fundamental electrochemical processes taking place when cycling SnO2 in lithium-ion batteries (LIBs). Special attention was paid to the partial reversibility of the tin oxide conversion reaction and how to enhance its reversibility. Another main effort was to pinpoint which limitations play a role in tin based electrodes besides the well-known volume change effect in order to develop new strategies for their improvement. In this aspect, Li+ mass transport within the electrode particles and the large first cycle charge transfer resistance were studied. Li+ diffusion was proven to be an important issue regarding the electrochemical cycling of SnO2. It was also shown that it is the Li+ transport inside the SnO2 particles which represents the largest limitation. In addition, the overlap between the potential regions of the tin oxide conversion and the alloying reaction was investigated with photoelectron spectroscopy (PES) to better understand if and how the reactions influence each other`s reversibility. The fundamental insights described above were subsequently used to develop strategies for the improvement of the performance and the cycle life for SnO2 electrodes in LIBs. For instance, elevated temperature cycling at 60 oC was employed to alleviate the Li+ diffusion limitation effects and, thus, significantly improved capacities could be obtained. Furthermore, an ionic liquid electrolyte was tested as an alternative electrolyte to cycle at higher temperatures than 60 oC which is the thermal stability limit for the conventional LP40 electrolyte. In addition, cycled SnO2 nanoparticles were characterized with transmission electron microscopy (TEM) to determine the effects of long term high temperature cycling. Also, the effect of vinylene carbonate (VC) as an electrolyte additive on the cycling behavior of SnO2 nanoparticles was studied in an effort to improve the capacity retention. In this context, a recently introduced intermittent current interruption (ICI) technique was employed to measure and compare the development of internal cell resistances with and without VC additive.
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Palencsar, Iozsef Attila. "SINGLE PARTICLE MICROELECTRODES AND MICROBATTERIES: FUNDAMENTAL STUDIES." Case Western Reserve University School of Graduate Studies / OhioLINK, 2006. http://rave.ohiolink.edu/etdc/view?acc_num=case1144340892.

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周如琪 and Ruqi Zhou. "Fundamental and applied studies of the low melting 1-methyl-3-ethylimidazolium chloride system for lithium battery application." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2002. http://hub.hku.hk/bib/B31243940.

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Zhou, Ruqi. "Fundamental and applied studies of the low melting 1-methyl-3-ethylimidazolium chloride system for lithium battery application /." Hong Kong : University of Hong Kong, 2002. http://sunzi.lib.hku.hk/hkuto/record.jsp?B24728883.

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Voci, Silvia. "Electrochemiluminescence at different scales : From new fundamental properties to surface-confined microscopy." Thesis, Bordeaux, 2019. http://www.theses.fr/2019BORD0294.

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L’électrochimiluminescence (ECL) est un phénomène d’émission de lumière obtenue suite à la génération d’espèces très réactives à l’électrode. Ces dernières vont subir une série de réactions de transfert d’électrons qui conduisent à la formation d’un état excité qui mène à l’émission finale de photons. La première partie de mon travail de thèse a porté sur l’étude de deux systèmes supramoléculaires. Les performances ECL d’un dérivé du spirofluorène et de trois composés modifiés avec un truxène comme partie centrale sont examinées. L’étude d’un deuxième système supramoléculaire, [18]-C-6bispyréne, a permis de démontrer une nouvelle propriété de l’ECL, maintenant capable de distinguer entre deux énantiomères, grâce à la détection du niveau de polarisation de l’émission ECL résultante. La combinaison entre ECL et systèmes confinés est présentée dans la deuxième partie de ma thèse. L’amplification du signal ECL par annihilation a été possible grâce à l’emploi d’un dispositif comprenant deux électrodes séparées par une distance de 100 nm. De plus, l’imagerie ECL a été utilisée pour mettre en évidence l’amélioration des performances de l’ECL bipolaire en utilisant une configuration comprenant un micropore planaire de 20 µm de long. Enfin, une nouvelle microscopie basée sur l’ECL a été développée. En perméabilisant la membrane cellulaire, l’ensemble de la cellule est visualisé par ECL. De plus, en se basant sur la distribution de l’émission ECL dans différents plans focaux, nous avons pu démontrer qu’une des caractéristiques fondamentales de cette nouvelle microscopie ECL est d’être confinée à la surface de l’électrode du fait des temps de vie limités des radicaux électro-générés. L’utilisation d’électrodes transparentes de nanotubes de carbone imprimés sur une lamelle de microscope a permis de réaliser l’imagerie ECL de cellules marquées aussi bien en réflexion qu’en transmission
Electrogenerated chemiluminescence (ECL) is a light emission phenomenon initiated by electrochemically generated radical species, which then undergo a series of electron transfer reactions. It leads to the final generation of an excited state that radiatively decays to the ground state. In this work, my goal was to develop fundamental aspects of ECL as well as analytical applications at different scales. In the first part, two supramolecular systems are studied. The ECL performances of spirofluorene derivatives based on trigonal truxene-core structure are investigated, focusing on the role of the different functional groups on the ECL properties. Then a bispyrene scaffold mounted on a constrained polyether macrocycle displaying intense excimer fluorescence has been selected to study the circularly polarized ECL. We show for the first time that ECL can discriminate enantiomers. In the second part of the thesis, annihilation ECL is enhanced by exploiting nanogap amplification. Furthermore, ECL imaging experiments enabled to demonstrate the increase in the performances of a bipolar electrochemistry system by employing a solid-state micropore configuration. Finally, the first steps in the development of a new ECL-based microscopy are presented. Using a unique ECL mechanism, which involves short-lifetime electrogenerated radicals, surface-confinement of ECL microscopy was demonstrated by cellular membranes’ imaging. ECL microscopy applied to cells imaging was further improved by adding a permeabilization step during cells labeling procedure. Disposable transparent carbon nanotube-based electrodes inkjet-printed on classic microscope glass coverslips, were used to image cells in both reflection and transmission configurations
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Books on the topic "Fundamentals of electrochemistry"

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Fundamentals of electrochemistry. New York: Plenum, 1993.

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Fundamentals of electrochemistry. 2nd ed. Hoboken, N.J: Wiley-Interscience, 2006.

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Bagotsky, V. S. Fundamentals of Electrochemistry. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2005. http://dx.doi.org/10.1002/047174199x.

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Bagot︠s︡kiĭ, V. S. Fundamentals of Electrochemistry. New York: John Wiley & Sons, Ltd., 2005.

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Ohtsuka, Toshiaki, Atsushi Nishikata, Masatoshi Sakairi, and Koji Fushimi. Electrochemistry for Corrosion Fundamentals. Singapore: Springer Singapore, 2018. http://dx.doi.org/10.1007/978-981-10-6820-1.

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Oldham, Keith B. Fundamentals of electrochemical science. San Diego: Academic Press, 1994.

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C, Myland Jan, ed. Fundamentals of electrochemical science. San Diego: Academic Press, 1994.

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1944-, Faulkner Larry R., ed. Electrochemical methods: Fundamentals and applications. 2nd ed. New York: Wiley, 2001.

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Physical electrochemistry: Fundamentals, techniques and applications. Weinheim: Wiley-VCH, 2011.

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Fuchigami, Toshio, Shinsuke Inagi, and Mahito Atobe, eds. Fundamentals and Applications of Organic Electrochemistry. Chichester, United Kingdom: John Wiley & Sons Ltd, 2014. http://dx.doi.org/10.1002/9781118670750.

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Book chapters on the topic "Fundamentals of electrochemistry"

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Gründler, Peter. "Fundamentals." In Monographs in Electrochemistry, 3–21. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-662-45818-1_2.

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Brett, Christopher. "Fundamentals of Electrochemistry." In Piezoelectric Transducers and Applications, 185–94. Berlin, Heidelberg: Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-662-05361-4_11.

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Chandrasekhar, Prasanna. "Electrochemistry of CPs." In Conducting Polymers, Fundamentals and Applications, 77–99. Boston, MA: Springer US, 1999. http://dx.doi.org/10.1007/978-1-4615-5245-1_4.

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Chandrasekhar, Prasanna. "Basic Electrochemistry of CPs." In Conducting Polymers, Fundamentals and Applications, 283–309. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-69378-1_30.

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Rajeshwar, Krishnan. "Photoelectrochemistry, Fundamentals and Applications." In Encyclopedia of Applied Electrochemistry, 1550–56. New York, NY: Springer New York, 2014. http://dx.doi.org/10.1007/978-1-4419-6996-5_38.

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Atobe, Mahito. "Fundamental Principles of Organic Electrochemistry: Fundamental Aspects of Electrochemistry Dealing with Organic Molecules." In Fundamentals and Applications of Organic Electrochemistry, 1–10. Chichester, United Kingdom: John Wiley & Sons Ltd, 2014. http://dx.doi.org/10.1002/9781118670750.ch01.

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Inagi, Shinsuke, and Toshio Fuchigami. "Related Fields of Organic Electrochemistry." In Fundamentals and Applications of Organic Electrochemistry, 187–98. Chichester, United Kingdom: John Wiley & Sons Ltd, 2014. http://dx.doi.org/10.1002/9781118670750.ch07.

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Ying, Yi-Lun, Jiajun Wang, Xue-Yuan Wu, and Yi-Tao Long. "Chapter 2. Fundamentals of Biological Nanopore Electrochemistry." In Confining Electrochemistry to Nanopores, 9–43. Cambridge: Royal Society of Chemistry, 2020. http://dx.doi.org/10.1039/9781788013260-00009.

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Rees, Neil V. "Electrochemistry Fundamentals: Nanomaterials Evaluation and Fuel Cells." In Nanostructure Science and Technology, 1–29. Cham: Springer International Publishing, 2016. http://dx.doi.org/10.1007/978-3-319-29930-3_1.

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Fernández-Solis, Christian D., Ashokanand Vimalanandan, Abdulrahman Altin, Jesus S. Mondragón-Ochoa, Katharina Kreth, Patrick Keil, and Andreas Erbe. "Fundamentals of Electrochemistry, Corrosion and Corrosion Protection." In Soft Matter at Aqueous Interfaces, 29–70. Cham: Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-24502-7_2.

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Conference papers on the topic "Fundamentals of electrochemistry"

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Andersson, Martin, Jinliang Yuan, Bengt Sunde´n, Ting Shuai Li, and Wei Guo Wang. "Modeling Validation and Simulation of an Anode Supported SOFC Including Mass and Heat Transport, Fluid Flow and Chemical Reactions." In ASME 2011 9th International Conference on Fuel Cell Science, Engineering and Technology collocated with ASME 2011 5th International Conference on Energy Sustainability. ASMEDC, 2011. http://dx.doi.org/10.1115/fuelcell2011-54006.

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Fuel cells are electrochemical devices that directly transform chemical energy into electricity, which are promising for future energy systems, since they are energy efficient and, when hydrogen is used as fuel, there are no direct emissions of greenhouse gases. The cell performance depends strongly on the material characteristics, the operating conditions and the chemical reactions that occur inside the cell. The chemical- and electrochemical reaction rates depend on temperature, material structure, catalytic activity, degradation and the partial pressures for the different species components. There is a lack of information, within the open literature, concerning the fundamentals behind these reactions. Experimental as well as modeling studies are needed to reduce this gap. In this study experimental data collected from an intermediate temperature standard SOFC with H2/H2O in the fuel stream are used to validate a previously developed computational fluid dynamics model based on the finite element method. The developed model is based on the governing equations of heat and mass transport and fluid flow, which are solved together with kinetic expressions for internal reforming reactions of hydrocarbon fuels and electrochemistry. This model is further updated to describe the experimental environment concerning cell design. Discussion on available active area for electrochemical reactions and average ionic transport distance from the anodic- to the cathodic three-phase boundary (TPB) are presented. The fuel inlet mole fractions are changed for the validated model to simulate a H2/H2O mixture and 30% pre-reformed natural gas.
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Wang, C. Y., W. B. Gu, R. Cullion, and B. Thomas. "Heat and Mass Transfer in Advanced Batteries." In ASME 1999 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 1999. http://dx.doi.org/10.1115/imece1999-1000.

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Abstract This paper presents an overview of heat and mass transfer issues in advanced rechargeable batteries such as nickel-metal hydride (Ni-MH) and lithium-ion (Li-ion) batteries. These batteries are important power sources for ultra-clean, fuel-efficient vehicles and modern portable electronics. Recent demands for environmentally responsible vehicles and strong portable power have prompted fundamental studies of heat and mass transport processes in battery systems in conjunction with electrochemistry and materials science. In this paper, discussions are presented on what are the critical heat and mass transfer issues present in advanced batteries and how these issues affect the battery performance, safety, life cycle, and cost. A theoretical framework describing the transport phenomena with electrochemical reactions is provided. Selected results are presented to illustrate the importance of coupled electrochemical and thermal modeling for advanced batteries. The recent progress is also reviewed in developing and validating battery models at Penn State GATE Center for Advanced Energy Storage.
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Zabihian, Farshid, Alan S. Fung, and Murat Koksal. "Performance of Biogas Fueled Hybrid Solid Oxide Fuel Cell (SOFC) and Gas Turbine Cycle." In ASME 2010 4th International Conference on Energy Sustainability. ASMEDC, 2010. http://dx.doi.org/10.1115/es2010-90149.

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The macro level model of a solid oxide fuel cell (SOFC) system was developed considering fundamental equations of thermodynamics, chemical reactions, and electrochemistry. The SOFC model was implemented in a hybrid SOFC-gas turbine (GT) cycle model using Aspen Plus® to simulate two configurations, system with and without anode recirculation. In order to monitor the performance of the system, parameters such as SOFC and system thermal efficiency; SOFC, GT, and cycle net and specific work; as well as air to fuel ratio, and air and fuel mass flow rate were investigated. The results of simulation for different types of fuel, namely, pure methane, natural gas, coal syngas, different types of biomass syngas, and farm and sewage biogas showed that system output and operation parameters were greatly influenced by changes in the fuel composition. Therefore, in feasibility study of a SOFC-GT hybrid cycle fueled by biogas, gasified biomass, and syngas, it is vital that possibility of variation of inlet fuel composition and its impacts on system performance to be considered and investigated.
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Ma, Zhiwen, Scott Blanchet, Ramki Venkataraman, Gianluca Iaccarino, and Parviz Moin. "Mathematical Modeling of an Internal-Reforming, Carbonate Fuel Cell Stack." In ASME 2004 2nd International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2004. http://dx.doi.org/10.1115/fuelcell2004-2486.

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The objective of this work is the development of a practical computational model of a carbonate fuel cell stack. Previously published carbonate fuel cell models have focused more on the fundamental mechanisms of fuel cell operation than on evaluation of practical fuel cell product designs. Efficient development of a fuel cell product requires a predictive tool that couples all the important mechanisms with the capability to evaluate the performance of many design iterations quickly. The important mechanisms typically include three dimensional fluid flow, heat and mass transfer, gas-phase and surface chemistry, electrochemistry and structural mechanics. For large-scale fuel cell with applications in the power generation industry, thermal management is of significant interest for stack performance, reliability and life. Minimizing peak cell temperatures improves cell life and minimizing stack temperature gradients reduces stack thermal stress and improves cell performance. In this paper, the fuel cell model is presented along with experimental data validating its accuracy and predictive capabilities. The tool has proven to be a valuable asset for design evaluation and optimization of fuel cell stack designs at FuelCell Energy.
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5

Stamps, Michael A., and Hsiao-Ying Shadow Huang. "Mixed Modes Fracture and Fatigue Evaluation for Lithium-Ion Batteries." In ASME 2012 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2012. http://dx.doi.org/10.1115/imece2012-88037.

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Lithium ion batteries have become a widely known commodity for satisfying the world’s mobile energy storage needs. But these needs are becoming increasingly important, especially in the transportation industry, as concern for rising oil prices and environmental impact from fossil fuels are pushing for deployment of more electric vehicles (EV) or plug in hybrid-electric vehicles (PHEV) and renewable energy sources. The objective of this research is to obtain a fundamental understanding of degradation mechanisms and rate-capacity loss in lithium-ion batteries through fracture mechanics and fatigue analysis approaches. In this study we follow empirical observations that mechanical stresses accumulate on electrode materials during the cycling process. Crack induced fracturing will then follow in the material which electrical contact surface area is degraded and over capacitance of the battery reduces. A fatigue analysis simulation is applied using ANSYS finite element software coupled with analytical models to alleviate these parameters that play the most pivotal roles in affecting the rate-capacity and cycle life of the lithium-ion battery. Our results have potential to provide new models and simulation tools for clarifying the interplay of structure mechanics and electrochemistry while offering an increased understanding of fatigue degradation mechanisms in rechargeable battery materials. These models can aid manufacturers in the optimization of battery materials to ensure longer electrochemical cycling life with high-rate capacity for improved consumer electronics, electric vehicles, and many other military or space applications.
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Rose, Cameron, and Ben Pence. "Parameter Optimization of a New Battery Model." In ASME 2021 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2021. http://dx.doi.org/10.1115/imece2021-68768.

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Abstract The lithium-ion battery (LiB) has become increasingly popular in electric vehicles (EVs), laptops, phones and many other devices that people use every day. It is popular due to its high energy density, low cost, lack of memory effect (typical of older battery types), longer life cycle (more full cycles till battery dies), and more. Because of its common use in everyday applications, knowing the state of charge (SOC) of a lithium-ion battery becomes an important problem to solve. The first goal of this work was to develop and present a new battery model derived from fundamental principles of electrochemistry, Fick’s first law of diffusion, and a mass balance of lithium-ions between the anode and cathode. A voltage equation was developed based on the the open circuit voltage, the Nernst equation, and Ohm’s law. The battery model aims to accurately track the movement of lithium ions without being too computationally demanding, while the voltage equation relates the output of the model to the voltage of the cell. These equations are coupled and solved simultaneously. The SOC of the battery could then be determined based on the mass of lithium in the anode. The second goal of this work was to optimize the parameters of the battery model to make it match experimental data. A cost function was defined and a genetic algorithm was implemented to minimize the cost function by altering the model parameters. The genetic algorithm successfully reduced the cost function. The model matched the experimental data and is therefore ready for commercial application.
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