Academic literature on the topic 'Fundamental chemistry'
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Journal articles on the topic "Fundamental chemistry"
KATO, Masayoshi. "Fundamental chemistry of etching." Journal of the Metal Finishing Society of Japan 38, no. 5 (1987): 172–79. http://dx.doi.org/10.4139/sfj1950.38.172.
Full textMATSUMOTO, Osamu. "Fundamental aspects of plasma chemistry." Jitsumu Hyomen Gijutsu 34, no. 10 (1987): 379–90. http://dx.doi.org/10.4139/sfj1970.34.379.
Full textLÜ, Ping, and Yanguang WANG. "Stereoelectronic Effects in Fundamental Organic Chemistry." University Chemistry 33, no. 12 (2018): 113–20. http://dx.doi.org/10.3866/pku.dxhx201811001.
Full textISHIKAWA, Masamichi. "Fundamental Physics and Chemistry under Microgravity." Journal of the Society of Mechanical Engineers 107, no. 1025 (2004): 258–60. http://dx.doi.org/10.1299/jsmemag.107.1025_258.
Full textCanac, Yves. "Carbon Ligands: From Fundamental Aspects to Applications." Molecules 26, no. 8 (April 8, 2021): 2132. http://dx.doi.org/10.3390/molecules26082132.
Full textChaloner, Penny A. "Organotransition metal chemistry; fundamental concepts and applications." Journal of Organometallic Chemistry 317, no. 1 (December 1986): C17—C18. http://dx.doi.org/10.1016/s0022-328x(00)99355-0.
Full textROSS, LINDA. "UNDERGRADUATE CHEMISTRY NSF to promote fundamental changes." Chemical & Engineering News 71, no. 21 (May 24, 1993): 4–5. http://dx.doi.org/10.1021/cen-v071n021.p004.
Full textS, S. J. "Organotransition Metal Chemistry, Fundamental Concepts and Applications." Journal of Molecular Structure 172 (February 1988): 437. http://dx.doi.org/10.1016/0022-2860(88)87036-4.
Full textSkull, Alan. "Eurozone crisis, green chemistry, and fundamental research." Focus on Surfactants 2012, no. 9 (September 2012): 1. http://dx.doi.org/10.1016/s1351-4210(12)70237-8.
Full textKrebs, Bernt, and Jan Reedijk. "Bioinorganic Chemistry - From Fundamental Research to Applications." Zeitschrift für anorganische und allgemeine Chemie 639, no. 8-9 (July 2013): 1295–96. http://dx.doi.org/10.1002/zaac.201310001.
Full textDissertations / Theses on the topic "Fundamental chemistry"
Tun, Zin-Min. "Fundamental Chlorophosphazene Chemistry." University of Akron / OhioLINK, 2011. http://rave.ohiolink.edu/etdc/view?acc_num=akron1321278169.
Full textWheatley, James Ernest. "Fundamental chemistry of carbon dioxide capture." Thesis, University of Leeds, 2017. http://etheses.whiterose.ac.uk/18363/.
Full textStiel, Jason A. "Fundamental Chemistry of Chlorophosphazenes and Polysilanes." University of Akron / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=akron1467990664.
Full textLamm, Ashley, and Ashley Lamm. "Fundamental Chemistry of 1,2-Dihydro-1,2-Azaborines." Thesis, University of Oregon, 2012. http://hdl.handle.net/1794/12514.
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Saleh, Nidal. "Chiral complexes : from fundamental chirality to helicene chemistry." Thesis, Rennes 1, 2013. http://www.theses.fr/2013REN1S112/document.
Full textIn this PhD work, we first investigated a fundamental aspect of chirality at the molecular level aiming to determine the parity violation (PV) energy difference between two enantiomers. We focused on chiral oxorhenium complexes for which the two corresponding enantiomers show theoretically different infrared absorption energies. Their chiroptical properties and especially their vibrational circular dichroism (VCD) were examined. Other chiral metal complexes such as platinum complexes bearing an asymmetric fluorinated carbon have also been prepared. Furthermore, we have investigated the helical chirality derived from the skew shape of ortho-fused aromatic ring. Indeed, helicenes bearing 2,2’-bipyridine functionalities were synthesized and they showed interesting photophysical and chiroptical properties. The presence of N^N’ or N-C chelating moieties enabled us to study the coordination effect of different transition metals (Re(I) and Pt(II)) on their properties and to conceive new acid-base triggered chiroptical switches
McKay, Hayley. "Fundamental studies of surface reaction mechanisms." Thesis, University of Cambridge, 2010. https://www.repository.cam.ac.uk/handle/1810/252213.
Full textWood, David John. "Fundamental studies on ionomer glasses." Thesis, University of Greenwich, 1993. http://gala.gre.ac.uk/6347/.
Full textHan, Qi. "Electrocatalysis at the Electrode-Adsorbate-Solution Interface: Fundamental Studies." Case Western Reserve University School of Graduate Studies / OhioLINK, 2019. http://rave.ohiolink.edu/etdc/view?acc_num=case1574855036013662.
Full textPappas, Iraklis. "Fundamental investigations into dinitrogen fixation by group 4 metals." Thesis, Princeton University, 2016. http://pqdtopen.proquest.com/#viewpdf?dispub=10120357.
Full textAddition of terminal or internal alkynes to a base free titanocene oxide results in synthesis of the corresponding oxometallocyclobutene. With appropriate cyclopentadienyl substitution, these compounds undergo reversible C-C reductive elimination offering a unique approach to cyclopentadienyl modification. Subsequent reactivity demonstrates the complete scission of the Ti=O multiple bond.
Cycloaddition of monosubstituted allenes with a monomeric, base free titanocene oxide resulted in isolation and crystallographic characterization of the corresponding oxatitanacyclobutanes. In solution these compounds are a mixture of (E) and (Z) isomers and interconvert by mechanisms that are dependent on the specific substitution of the allene. Facile carbonylation of the oxatitanacyclobutanes was also observed to yield rare examples of structurally characterized oxatitanacyclopentanones. These studies highlight the new chemistry available from synthesis of base free titanocene oxide compounds enabled by appropriate cyclopentadienyl substitution.
The hydrogenolysis of titanium nitrogen bonds in a family of bis(cyclopentadienyl) titanium amides, hydrazides, and imides via proton coupled electron transfer (PCET) is demonstrated. (η5-C5Me5)(py-Ph)Rh-H (py-Ph = 2-pyridylphenyl, [Rh]-H) and (η5- C5R5)(CO)3CrH ([Cr]R-H, R= H, Me) were used as catalysts for homolytic H2 activation followed by PCET to the nitrogen-containing fragment. Detailed mechanistic studies and an analysis of the underlying thermochemistry are employed to explain the decreased catalytic efficiency of [Cr]R-H compared to [Rh]-H. The N-H bond dissociation free energies (BDFEs) in 12 structurally similar compounds were determined through a combination of experimental and computational methods, providing a foundation for the use of N-H BDFEs as a metric to enable NH3 synthesis from H 2 and N2 at a well-defined metal center.
Combination of the readily available a-diimine ligand, ((ArN=C(Me)) 2 Ar = 2,6-iPr2-C6H3), (iPrDI) with air-stable nickel(II) bis(carboxylates) generated a highly active catalyst exhibiting anti-Markovnikov selectivity for the hydrosilylation of alkenes with (EtO)3SiH. The exclusive selectivity for formation of terminal alkyl silanes was also observed with internal alkenes via a tandem isomerization-hydrosilylation pathway. The hydrosilylation of 1-octene with triethoxysilane, a reaction performed commercially in the silicones industry on a scale of > 12,000,000 lbs/year, was performed on a 10 g scale with 96 % yield and >98 % selectivity for the desired product.
Pastor, Michael B. "Bimetallic Complexes| The Fundamental Aspects of Metalmetal Interactions, Ligand Sterics and Application." Thesis, University of the Pacific, 2018. http://pqdtopen.proquest.com/#viewpdf?dispub=10932512.
Full textMetal containing complexes have been used to catalyze various organic transformations for the past few decades. The success of several mononuclear catalysts led to transition metal catalysts used in pharmaceuticals, environmental, and industrial processes. While mononuclear complexes have been used extensively, bimetallic systems have received far less attention. Bimetallic or polynuclear sites are commonly found in metalloenzymes that perform elegant transformation in biological systems, underlying their significance. Inorganic chemists take inspiration from nature and design model bimetallic complexes to further study this cooperativity effect. A bimetallic platform offers many structural and functional differences such as the identity of the metal atoms and the bonding interactions between metals, which have been reflected in their unique catalytic ability and reactivity.
This dissertation encompasses work related to the computational study of metal-metal interactions of bimetallic systems, the 1H NMR study of stereochemical and conformational changes in solution of N,N'-diarylformamidines, the synthesis of dizinc formamidinate complexes, and the synthesis and catalytic ability of dicopper formamidinate complexes.
In the first part, DFT calculations are used to study factors that influence metal-metal bond lengths in various complexes. Several experimentally obtained X-ray crystal structures were used as the basis for the study. Differences in metal-metal separations were investigated through various functionals, indicating the importance of charge, orbital interactions, and formal bond order. BH&HLYP SDD/aug-CC-PVDZ geometry optimizations of octahalodimetalate anions Tc2X8n- (X = Cl, Br; n=2, 3), Re2X82- (X = Cl, Br), and Mo2Cl 84- reproduced M-M bond distance trends observed experimentally. The study demonstrated that the increase in σ and π bond strength resulted in the shortening in Tc-Tc bond distance from Tc2X 82- to Tc2X83-, which was further supported by the short Mo-Mo bond in the Mo2Cl 84- ion. This study was expanded further through the inclusion of [M2Cl4(PMe3)4] n+ (M = Tc, Re, n = 0-2) and [Mo2E4] n- (E = HPO4 or SO4, n = 2-4), allowing a systematic study on the role of charge on the metal atoms. PBEO SDD/aug-CC-PVDZ calculations revealed that both formal bond order and formal charge on the metal atoms dictate the trends in M-M bond strength.
The second half of this dissertation focuses on the synthesis and characterization of bimetallic Zn- and Cu-formamidinate complexes. The stereochemical exchange of substituted N,N'-diarylformamidines were studied through 1H NMR in various solvents. Alkyl substituents placed on the ortho positions were found to shift the isomeric equilibrium in solution through destabilization of the hydrogen-bond dimer evident in X-ray crystal structures. The Z-isomer of substituted N,N'-diarylformamidines is observed in CDCl3, C6D6, and DMSO-d6 when the ligands feature significant steric hinderance. Similar ortho substituted N,N'-diarylformamidines were also used to enforce steric interactions to limit the nuclearity of Zn-formamidinate complexes. Various dizinc formamidinate complexes were synthesized through direct and transmetalation routes. NMR and mass spectrometry were used alongside X-ray crystal structures to fully characterize the dizinc complexes. Dicopper formamidinates formed through a transmetallation route were synthesized and feature distinct short Cu …Cu separations thought to be brought about by metalophillic interactions. Preliminary results suggest catalytic ability of dicopper formamidinates in cyclopropanation and aziridination of styrene with various diazo compounds. The catalytic activity suggests the formation of dicopper carbene and nitrene intermediates, of which only few published experimentally observed examples exist in the literature.
Books on the topic "Fundamental chemistry"
Lukehart, Charles M. Fundamental transition metalorganometallic chemistry. Monterey, CA: Brooks/Cole, 1985.
Find full textBrändas, Erkki J., and Eugene S. Kryachko, eds. Fundamental World of Quantum Chemistry. Dordrecht: Springer Netherlands, 2004. http://dx.doi.org/10.1007/978-94-017-0448-9.
Full textBrändas, Erkki J., and Eugene S. Kryachko, eds. Fundamental World of Quantum Chemistry. Dordrecht: Springer Netherlands, 2003. http://dx.doi.org/10.1007/978-94-010-0113-7.
Full textCalbreath, Donald F. Clinical chemistry: A fundamental textbook. Philadelphia: Saunders, 1992.
Find full textFundamental transition metal organometallic chemistry. Monterey, Calif: Brooks/Cole, 1985.
Find full textPhysical organic chemistry: The fundamental concepts. 2nd ed. New York: M. Dekker, 1990.
Find full textOrganotransition metal chemistry: Fundamental concepts and applications. New York: Wiley, 1986.
Find full textLahaye, Jacques. Fundamental Issues in Control of Carbon Gasification Reactivity. Dordrecht: Springer Netherlands, 1991.
Find full textCalbreath, Donald F. Instructor's manual to Clinical chemistry: A fundamental textbook. Philadelphia: W.B. Saunders, 1992.
Find full textBrongersma, H. H. Fundamental Aspects of Heterogeneous Catalysis Studied by Particle Beams. Boston, MA: Springer US, 1991.
Find full textBook chapters on the topic "Fundamental chemistry"
Sartor, Klaus. "Fundamental Physics and Chemistry." In MR Imaging of the Skull and Brain, 1–32. Berlin, Heidelberg: Springer Berlin Heidelberg, 1992. http://dx.doi.org/10.1007/978-3-642-75525-5_1.
Full textIwasaki, Masayuki, and Yasushi Nishihara. "Mechanisms and Fundamental Reactions." In Lecture Notes in Chemistry, 17–39. Berlin, Heidelberg: Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/978-3-642-32368-3_2.
Full textFan, L. T., D. Neogi, and M. Yashima. "Fundamental Concepts and Definitions." In Lecture Notes in Chemistry, 3–15. Berlin, Heidelberg: Springer Berlin Heidelberg, 1991. http://dx.doi.org/10.1007/978-3-642-45690-9_2.
Full textHoffman, Donald B., Beth E. Zedeck, and Morris S. Zedeck. "Fundamental Issues of Postmortem Toxicology." In Forensic Chemistry Handbook, 457–81. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118062241.ch13.
Full textTsuneda, Takao. "Appendix: Fundamental Conditions." In Density Functional Theory in Quantum Chemistry, 189–96. Tokyo: Springer Japan, 2014. http://dx.doi.org/10.1007/978-4-431-54825-6_8.
Full textKemp, William. "The Fundamental Basis of Magnetic Resonance." In NMR in Chemistry, 14–28. London: Macmillan Education UK, 1986. http://dx.doi.org/10.1007/978-1-349-18348-7_2.
Full textFujita, Shinsaku. "Silver Halide Crystals. Fundamental Properties." In Organic Chemistry of Photography, 59–74. Berlin, Heidelberg: Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/978-3-662-09130-2_3.
Full textTrubert, D., and C. Le Naour. "Fundamental Aspects of Single Atom Chemistry." In The Chemistry of Superheavy Elements, 95–116. Boston, MA: Springer US, 2003. http://dx.doi.org/10.1007/0-306-48415-3_3.
Full textJoost, Maximilian. "Fundamental Elementary Steps in Gold Chemistry." In Synthesis and Original Reactivity of Copper and Gold Complexes, 31–81. Cham: Springer International Publishing, 2015. http://dx.doi.org/10.1007/978-3-319-18690-0_3.
Full textTalapatra, Sunil Kumar, and Bani Talapatra. "Fundamental Stereochemical Concepts and Nomenclatures." In Chemistry of Plant Natural Products, 23–201. Berlin, Heidelberg: Springer Berlin Heidelberg, 2014. http://dx.doi.org/10.1007/978-3-642-45410-3_2.
Full textConference papers on the topic "Fundamental chemistry"
HYDUTSKY, D. P., D. E. BERGERON, T. E. DERMOTA, J. R. STAIRS, K. L. KNAPPENBERGER, K. M. DAVIS, C. E. JONES, et al. "FUNDAMENTAL CLUSTER STUDIES OF MATERIALS AND ATMOSPHERIC CHEMISTRY." In Clusters and Nano-Assemblies - Physical and Biological Systems. WORLD SCIENTIFIC, 2005. http://dx.doi.org/10.1142/9789812701879_0011.
Full textCooper, Valentino R. "Extending first principles modeling with crystal chemistry: a bond-valence based classical potential." In Fundamental Physics of Ferroelectrics 2003. AIP, 2003. http://dx.doi.org/10.1063/1.1609957.
Full textLumetta, Gregg J., Brian M. Rapko, and Herman M. Cho. "Studies of the Fundamental Chemistry of Hanford Tank Sludges." In ASME 2003 9th International Conference on Radioactive Waste Management and Environmental Remediation. ASMEDC, 2003. http://dx.doi.org/10.1115/icem2003-4633.
Full textIshikawa, Masamichi. "Japanese Programs of Fundamental Physics and Chemistry under Microgravity." In 54th International Astronautical Congress of the International Astronautical Federation, the International Academy of Astronautics, and the International Institute of Space Law. Reston, Virigina: American Institute of Aeronautics and Astronautics, 2003. http://dx.doi.org/10.2514/6.iac-03-j.1.02.
Full textVentzek, P. L. G. "Fundamental Atomic Plasma Chemistry for Semiconductor Manufacturing Process Analysis." In ATOMIC PROCESSES AND PLASMAS: 13th APS Topical Conference on Atomic Processes in Plasmas. AIP, 2002. http://dx.doi.org/10.1063/1.1516290.
Full textJiang, Boquan, Ting Liu, Min Xu, Xu Li, and Zhengping Chen. "Establishment of Comprehensive Evaluation System of Fundamental Chemistry Experiment Course." In 2014 International Conference on Education, Management and Computing Technology (ICEMCT-14). Paris, France: Atlantis Press, 2014. http://dx.doi.org/10.2991/icemct-14.2014.108.
Full textSwiderek, Petra, Markus Rohdenburg, Neha Thakur, and Sonia Castellanos. "Electron-induced chemistry fundamental to state-of-the-art nanotechnology." In Advances in Patterning Materials and Processes XXXVIII, edited by Douglas Guerrero and Daniel P. Sanders. SPIE, 2021. http://dx.doi.org/10.1117/12.2584166.
Full textJarrahian, Khosro, Kenneth Sorbie, Michael Singleton, Lorraine Boak, and Alexander Graham. "Building a Fundamental Understanding of Scale Inhibitor Retention in Carbonate Formations." In SPE International Conference on Oilfield Chemistry. Society of Petroleum Engineers, 2019. http://dx.doi.org/10.2118/193635-ms.
Full textSEEBERGER, PETER H. "AUTOMATED OLIGOSACCHARIDE SYNTHESIS: FROM INSIGHTS INTO FUNDAMENTAL GLYCOBIOLOGY TO VACCINES AND DIAGNOSTICS." In 23rd International Solvay Conference on Chemistry. WORLD SCIENTIFIC, 2014. http://dx.doi.org/10.1142/9789814603836_0020.
Full textLuk′yanov, Oleg, Nina Shlykova, Vladimir Parakhin, Galina Pokhvisneva, Tatyana Ternikova, Sergey Nikitin, and Gennady Smirnova. "HIGH-ENERGY POLYNITRO HEXAAZAISOWURTZITANES: SYNTHESIS AND FUNDAMENTAL PHISICOCHEMICAL PROPERTIES." In Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m728.aks-2019/93-96.
Full textReports on the topic "Fundamental chemistry"
Simonson, John M., James G. Blencoe, Sheng Dai, Ariel A. Chialvo, and Peter T. Cummings. Fundamental Chemistry and Thermodynamics of Hydrothermal Oxidation Processes. Office of Scientific and Technical Information (OSTI), June 1999. http://dx.doi.org/10.2172/828161.
Full textSimonson, J. M. Fundamental Chemistry And Thermodynamics Of Hydrothermal Oxidation Processes. Office of Scientific and Technical Information (OSTI), December 2001. http://dx.doi.org/10.2172/828164.
Full textShuh, David K., and Ian l. Pegg. Research Program to Investigate the Fundamental Chemistry of Technetium. Office of Scientific and Technical Information (OSTI), September 2005. http://dx.doi.org/10.2172/893269.
Full textPegg, Ian. Research Program to Investigate the Fundamental Chemistry of Technetium. Office of Scientific and Technical Information (OSTI), June 2005. http://dx.doi.org/10.2172/884865.
Full textEdelstein, Norman M., Carol J. Burns, David D. Shuh, and Wayne Lukens. Research Program to Investigate the Fundamental Chemistry of Technetium. Office of Scientific and Technical Information (OSTI), June 2000. http://dx.doi.org/10.2172/829921.
Full textEdelstein, Norman M., Carol J. Burns, David K. Shuh, and Wayne Lukens. Research Program to Investigate the Fundamental Chemistry of Technetium. Office of Scientific and Technical Information (OSTI), June 2000. http://dx.doi.org/10.2172/829922.
Full textShuh, David K., Carol J. Burns, and Wayne W. Lukens, Jr. Research Program to Investigate the Fundamental Chemistry of Technetium. Office of Scientific and Technical Information (OSTI), June 2001. http://dx.doi.org/10.2172/834461.
Full textShuh, David K., Carol J. Burns, and Wayne W. Lukens, Jr. Research Programs to Investigate the Fundamental Chemistry of Technetium. Office of Scientific and Technical Information (OSTI), July 2002. http://dx.doi.org/10.2172/834462.
Full textShuh, David K. Research Program to Investigate the Fundamental Chemistry of Technetium. Office of Scientific and Technical Information (OSTI), August 2004. http://dx.doi.org/10.2172/839285.
Full textShuh, David K., and Ian L. Pegg. Research Program to Investigate the Fundamental Chemistry of Technetium. Office of Scientific and Technical Information (OSTI), August 2004. http://dx.doi.org/10.2172/839331.
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