Academic literature on the topic 'FSM-16'

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Journal articles on the topic "FSM-16"

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Yamamoto, Takashi, Tsunehiro Tanaka, Takuzo Funabiki, and Satohiro Yoshida. "Acidic Property of FSM-16." Journal of Physical Chemistry B 102, no. 30 (July 1998): 5830–39. http://dx.doi.org/10.1021/jp980675c.

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KATOH, MASAHIRO, TOSHIHIDE HORIKAWA, and TAHEI TOMIDA. "PHOTOCATALYTIC REACTION OF ACETONE ON MESOPOROUS CHROMIUM SILICATE." International Journal of Modern Physics B 20, no. 25n27 (October 30, 2006): 3854–59. http://dx.doi.org/10.1142/s0217979206040489.

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Cr -containing mesoporous silicates ( Cr -FSM-16) were prepared and characterized by several spectroscopic analyses. Their photocatalytic reactivity for acetone under UV- and visible-light irradiations has been investigated and the effect of adsorption on the reactivity was discussed. XPS spectra showed the Cr -oxide moieties were in the mesoporous framework of FSM-16. The UV-VIS spectra of the Cr -FSM-16 exhibited three distinct absorption bands, which could be assigned to charge transfer from O 2- to Cr 6+ of the tetrahedrally coordinated moieties. In particular, the band at 460 nm was assigned to the symmetry-forbidden nature of the 1 A 1 → 1 T 1 transition of tetrahedral Cr -oxide. The absorption showed Cr -FSM-16 has the photocatalytic reactivity under visible light irradiation. Acetone was adsorbed strongly on Cr -FSM-16, and then adsorbed acetone was decomposed to CO 2 and H 2 O on Cr -FSM-16 under visible light irradiation. But the amount of CO 2 produced was much less than the stoichiometric amount of CO 2 calculated from adsorbed acetone. This may be due to adsorption of acetone, and/or CO 2 on Cr -FSM-16.
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Wakayama, Hiroaki, and Yoshiaki Fukushima. "Preparation of Nanoparticles in Nanoporous Silica, FSM-16." JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 42, no. 2 (2009): 134–38. http://dx.doi.org/10.1252/jcej.08we147.

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Ishikawa, Tatsuo, Mitsuhiko Matsuda, Akemi Yasukawa, Kazuhiko Kandori, Shinji Inagaki, Toshiaki Fukushima, and Seiichi Kondo. "Surface silanol groups of mesoporous silica FSM-16." Journal of the Chemical Society, Faraday Transactions 92, no. 11 (1996): 1985. http://dx.doi.org/10.1039/ft9969201985.

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Sugiyama, Shigeru, Yuhki Kato, Takahiro Wada, Shirou Ogawa, Keizo Nakagawa, and Ken-Ichiro Sotowa. "Ethanol Conversion on MCM-41 and FSM-16, and on Ni-Doped MCM-41 and FSM-16 Prepared without Hydrothermal Conditions." Topics in Catalysis 53, no. 7-10 (April 1, 2010): 550–54. http://dx.doi.org/10.1007/s11244-010-9485-9.

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Matsumoto, Akihiko, Tatsuo Sasaki, Nobuyuki Nishimiya, and Kazuo Tsutsumi. "Thermal stability and hydrophobicity of mesoporous silica FSM-16." Colloids and Surfaces A: Physicochemical and Engineering Aspects 203, no. 1-3 (April 2002): 185–93. http://dx.doi.org/10.1016/s0927-7757(01)01105-0.

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Yoshida, Hisao, Chizu Murata, Yoshitaka Inaki, and Tadashi Hattori. "Photooxidation of Propene by Molecular Oxygen over FSM-16." Chemistry Letters 27, no. 11 (November 1998): 1121–22. http://dx.doi.org/10.1246/cl.1998.1121.

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Katoh, Masahiro, Hitoshi Takao, Naoto Abe, and Tahei Tomida. "Adsorption Selectivity of FSM-16 for Several Organic Compounds." Journal of Colloid and Interface Science 242, no. 2 (October 2001): 294–99. http://dx.doi.org/10.1006/jcis.2001.7841.

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Yoshida, Hisao, Koichi Kimura, Yoshitaka Inaki, and Tadashi Hattori. "Catalytic activity of FSM-16 for photometathesis of propene." Chemical Communications, no. 1 (1997): 129–30. http://dx.doi.org/10.1039/a607406e.

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Itoh, Akichika, Tomohiro Kodama, Shinji Inagaki, and Yukio Masaki. "Photooxidation of Arylmethyl Bromides with Mesoporous Silica FSM-16." Organic Letters 2, no. 16 (August 2000): 2455–57. http://dx.doi.org/10.1021/ol0061081.

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Dissertations / Theses on the topic "FSM-16"

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Corkery, Robert, and robert corkery@anu edu au. "Artificial biomineralisation and metallic soaps." The Australian National University. Research School of Physical Sciences and Engineering, 1998. http://thesis.anu.edu.au./public/adt-ANU20080124.190014.

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In this thesis, geometry is used as a basis for conducting experiments aimed at growing and arranging inorganic minerals on curved interfaces. Mineralisation is directed using crystalline and liquid-crystalline metallic soaps and surfactant/water systems as templates.¶ A review of the history, syntheses, structure and liquid crystallinity of metallic soaps and other amphiphiles is presented as a foundation to understanding the interfacial architectures in mesostructured template systems in general.¶ In this study, a range of metallic soaps of varying chain length and cation type are synthesised and characterised to find potentially useful templates for mineral growth. These include alkaline-earth, transition metal, heavy metal and lanthanide soaps. These are systematically characterised using a variety of analytical techniques, including chemical analyses, x-ray diffraction (XRD) infrared spectroscopy (IR) and differential scanning calorimetry (DSC). Their molecular and crystal structures are studied using transmission electron microscopy (TEM), cryo-TEM, electron diffraction (ED), electron paramagnetic spin resonance (EPR), absorption spectroscopy (UV-VIS), high resolution laser spectroscopy, atomic force microscopy (AFM), nuclear magnetic resonance spectroscopy, scanning electron microscopy (SEM), electron dispersive x-ray analysis (EDXA), thermal gravimetric analysis (TGA) and magnetic measurements. Models for the molecular and crystal structures of metallic soaps are proposed. The soaps are predominantly lamellar crystalline or liquid crystalline lamellar rotor phases with tilted and/or untilted molecular constituents. These display evidence of varying degrees of headgroup organisation, including superstructuring and polymerisation. A single crystal structure is presented for a complex of pyridine with cobalt soap. Simple models for their structure are discussed in terms of their swelling properties in water and oils. Experiments are also presented to demonstrate the sorbent properties of aluminium soaps on oil spills.¶ The thermotropic liquid crystallinity of alkaline earth, transition metal, heavy metal and lanthanide soaps is investigated in detail. This is done to assess their suitability as templates, and to document their novel thermotropic behaviour, particularly the relatively unknown lanthanide soaps. Liquid crystalline behaviours are studied using high-temperature XRD (HTXRD), hot-stage optical microscopy and DSC. Models for a liquid crystalline phase progression from crystals to anisotropic liquids are discussed in terms of theories of self-assembly and interfacial curvature. The terminology required for this is drawn from various nomenclature systems for amphiphilic crystals and liquid crystals. General agreement with previous studies is reported for known soaps, while liquid crystallinity is demonstrated in the lanthanide and some non-lanthanide soaps for the first time. A general phase progression of crystalline lamellar through liquid crystalline lamellar to non-lamellar liquid crystalline is discussed in terms of models concerned with the molecular and crystal structures of the soaps and their phase transitions via headgroup and chain re-arrangements.¶ Experiments aimed at guiding growth of metal sulfides using metallic soaps as templates are described, and a model for this growth is discussed. Metal sulfides have been successfully grown by reacting crystalline and liquid crystalline transition metal and heavy metal soaps with H2S gas at room temperature and at elevated temperature. These have been characterised using XRD, TEM, ED and IR. Sulfide growth is demonstrated to be restricted and guided by the reacting soap template architecture. Zinc, cadmium, indium and lead soaps formed confined nanoparticles within the matrix of their reacting soap template. In contrast, curved and flat sheet-like structures, some resembling sponges were found in the products of sulfided iron, cobalt, nickel, copper, tin and bismuth soaps. A model to explain this behaviour is developed in terms of the crystal and liquid crystal structures of the soaps and the crystal structures of the metal sulfide particles.¶ Liquid crystalline iron soaps have been subjected to controlled thermal degradation yielding magnetic iron oxide nanoparticles. Some XRD and TEM evidence has been found for formation of magnetic mesostructures in heat-treated iron soaps. Models for the molecular and liquid crystalline structure of iron soaps, their thermotropic phase progression and eventual conversion to these magnetic products are discussed. Systematic syntheses of mesoporous silicates from sheeted clays are discussed.¶The templates that have been used are cationic surfactants and small, organic molecular salts. Experiments are reported where a cooperative self-assembly of surfactant/water/kanemite plus or minus salt and oils yields 'folded sheet materials' (FSM'S). Templating of kanemite has also been achieved using cobalt cage surfactants. A theoretical prediction of the specific surface areas and specific volumes of homologous sets of FSM's gave excellent agreement with measured values. The geometry and topology of the mesostructures are discussed. A theoretical model is also discussed regarding the curvature found in the sheets of natural clays , and results of templating clays and silica using metallic soaps are presented. Experiments and a model for low temperature nucleation and growth of microporous silicalite-1 are described in terms of silica templating by water clathrates.¶ Finally, the problem of finding minimal surface descriptions of crystal networks is addressed. Combinatoric methods are used to disprove the existence of possible embeddings of type I and II clathrate networks in non-self intersecting periodic minimal surfaces. The crystal network of the clathrate silicate, melanophlogite is successfully embedded in the WI-10 self-intersecting surface. Details of a previously unreported, genus-25 periodic surface with symmetry Im3m are discussed.
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Books on the topic "FSM-16"

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Archives and Museums. Conference Pacific Islands Association of Libraries. Pacific visions: Finding, selecting, and using resources for your libraries, archives, and museums : 19th Annual PIALA Conference, Pohnpei, FSM, November 16-21, 2009. Pohnpei, Federated States of Micronesia: Pacific Islands Association of Libraries, Archives and Museums, 2011.

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Book chapters on the topic "FSM-16"

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Inagaki, Shinji. "FSM-16 and mesoporous organosilicas." In Mesoporous Crystals and Related Nano-Structured Materials, Proceedings of the Meeting on Mesoporous Crystals and Related Nano-Structured Materials, 109–32. Elsevier, 2004. http://dx.doi.org/10.1016/s0167-2991(04)80195-2.

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Nagai, M., K. Kunieda, S. Izuhal, and S. Omi. "Preparation of Carbided WO3/FSM-16 and Al-FSM-16 and Its Catalytic Activity." In Nanotechnology in Mesostructured Materials, Proceedings of the 3rd International Materials Symposium, 733–36. Elsevier, 2003. http://dx.doi.org/10.1016/s0167-2991(03)80488-3.

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Nagai, Masatoshi, Toshihiro Nishibayashi, and Shinzo Omi. "Methane reforming on molybdenum carbide on Al-FSM-16." In Nanotechnology in Mesostructured Materials, Proceedings of the 3rd International Materials Symposium, 729–32. Elsevier, 2003. http://dx.doi.org/10.1016/s0167-2991(03)80487-1.

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Pérez-Romo, P., M. L. Guzmán-Castillo, H. Armendáriz-Herrera, R. Flores-Rodríguez, J. Navarrete-Bolaños, J. A. Montoya de la Fuente, and J. J. Fripiat. "Physicochemical properties of FSM-16 modified by fluoride and HPA." In Nanoporous Materials IV, Proceedings of the 4th International Symposium on Nanoporous Materials, 171–76. Elsevier, 2005. http://dx.doi.org/10.1016/s0167-2991(05)80204-6.

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Selvam, T., V. R. R. Marthala, R. Herrmann, W. Schwieger, N. Pfänder, R. Schlögl, H. Ernst, and D. Freude. "Al-rich mesoporous FSM-16 materials: Synthesis, characterization and catalytic properties." In Molecular Sieves: From Basic Research to Industrial Applications, Proceedings of the 3rd International Zeolite Symposium (3rd FEZA), 501–8. Elsevier, 2005. http://dx.doi.org/10.1016/s0167-2991(05)80378-7.

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Fujishima, Keiko, Atsushi Fukuoka, and Masaru Ichikawa. "Photooxidation of benzene to phenol by Ru complex occluded in mesoporous FSM-16." In Studies in Surface Science and Catalysis, 1979–84. Elsevier, 2000. http://dx.doi.org/10.1016/s0167-2991(00)80492-9.

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Fukuoka, Atsushi, Naonori Higashimoto, Makoto Sasaki, Masafumi Harada, Shinji Inagaki, Yoshiaki Fukushima, and Masaru Ichikawa. "Templating fabrication and catalysis of platinum nanowires in mesoporous channels of FSM-16." In Studies in Surface Science and Catalysis, 3041–46. Elsevier, 2000. http://dx.doi.org/10.1016/s0167-2991(00)80935-0.

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Inagaki, S., Y. Fukushima, and K. Kuroda. "Synthesis and characterization of highly ordered mesoporous material; FSM-16, from a layered polysilicate." In Studies in Surface Science and Catalysis, 125–32. Elsevier, 1994. http://dx.doi.org/10.1016/s0167-2991(08)64105-1.

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Pérez-Romo, Patricia, M. de Lourdes Guzmán-Castillo, Héctor Armendáriz-Herrera, Juan Navarrete-Bolaños, R. Isela Conde-Velasco, and José Fripiat. "Role of Na in the ionic equilibrium ruling the synthesis of mesoporous FSM-16 materials." In Zeolites and related materials: Trends, targets and challenges, Proceedings of the 4th International FEZA Conference, 425–28. Elsevier, 2008. http://dx.doi.org/10.1016/s0167-2991(08)80233-9.

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Nagai, M., K. Kunieda, S. Izuhal, and S. Omi. "29-P-29-Preparation of tungsten carbide supported on (Al-)FSM-16 and its catalytic activity." In Studies in Surface Science and Catalysis, 319. Elsevier, 2001. http://dx.doi.org/10.1016/s0167-2991(01)81724-9.

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Conference papers on the topic "FSM-16"

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Umehara, Akio, Shoji Nitta, Takashi Itoh, Ryo Yasuda, and Shuichi Nonomura. "Preparation and properties of one-dimensional C 60 nanostructures confined in the zeolite FSM-16." In Optical Science, Engineering and Instrumentation '97, edited by Zakya H. Kafafi. SPIE, 1997. http://dx.doi.org/10.1117/12.283761.

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