Academic literature on the topic 'Friedel Crafts alkylation'

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Journal articles on the topic "Friedel Crafts alkylation"

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Kolb, Kenneth E., and Kurt W. Field. "Friedel-Crafts alkylation products." Journal of Chemical Education 68, no. 1 (January 1991): 86. http://dx.doi.org/10.1021/ed068p86.3.

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Völler, Jan-Stefan. "Biocatalytic Friedel–Crafts alkylation." Nature Catalysis 2, no. 3 (March 2019): 180. http://dx.doi.org/10.1038/s41929-019-0262-2.

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Jiang, Zhen-Yu, Ji-Rong Wu, Li Li, Xi-Huai Chen, Guo-Qiao Lai, Jian-Xiong Jiang, Yixin Lu, and Li-Wen Xu. "Efficient Lewis acid-assisted Brønsted acid (LBA) catalysis in the iron-catalyzed Friedel-Crafts alkylation reaction of indoles." Open Chemistry 8, no. 3 (June 1, 2010): 669–73. http://dx.doi.org/10.2478/s11532-010-0016-0.

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AbstractLewis acid-assisted Brønsted acid (LBA) catalysis was proposed for the iron-catalyzed Friedel-Crafts alkylation of indoles with chalcones. This proposal was supported by the ESI-MS and cyclic voltammetry. The addition of acac to the iron-catalyzed Friedel-Crafts alkylation of indoles with chalcones created a powerful catalytic system, which makes the alkylation reactions occur easily under mild conditions.
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Meima, G. R., G. S. Lee, and J. M. Garces. "ChemInform Abstract: Friedel-Crafts Alkylation." ChemInform 33, no. 41 (May 19, 2010): no. http://dx.doi.org/10.1002/chin.200241267.

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Tsoung, Jennifer, Katja Krämer, Adam Zajdlik, Clemence Liébert, and Mark Lautens. "Diastereoselective Friedel–Crafts Alkylation of Hydronaphthalenes." Journal of Organic Chemistry 76, no. 21 (November 4, 2011): 9031–45. http://dx.doi.org/10.1021/jo201781x.

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Yıldız, Tülay, İrem Baştaş, and Hatice Başpınar Küçük. "Transition-metal-free intramolecular Friedel–Crafts reaction by alkene activation: A method for the synthesis of some novel xanthene derivatives." Beilstein Journal of Organic Chemistry 17 (August 30, 2021): 2203–8. http://dx.doi.org/10.3762/bjoc.17.142.

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In this work, new derivatives (substituted 9-methyl-9-arylxanthenes) of xanthene compounds (5a–l) of possible biological significance were synthesized by developing a new synthesis method. In order to obtain xanthene derivatives, the original alkene compounds to be used as the starting materials were synthesized in four steps using appropriate reactions. A cyclization reaction by intramolecular Friedel–Crafts alkylation was carried out in order to synthesize the desired xanthene derivatives using the alkenes as starting compounds. The intramolecular Friedel–Crafts reaction was catalyzed by trifluoroacetic acid (TFA) and provided some novel substituted 9-methyl-9-arylxanthenes with good yields at room temperature within 6–24 hours. As a result, an alkene compound was used for activation with TFA in the synthesis of xanthene through intramolecular Friedel–Crafts alkylation for the first time.
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Kiasat, A. R., M. Karimi-Cheshmeali, R. Soleymani, and H. Rajabzadeh. "Investigation of Friedel-Crafts Alkylation in the Presence of Supported Sulfonic Acid on Silica Gel." E-Journal of Chemistry 9, no. 4 (2012): 1875–84. http://dx.doi.org/10.1155/2012/610579.

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From the Reaction between cellulose and chloro sulfonic acid was prepared sulfuric acid cellulose composition as a new solid acid. The solid acid supported on silica gel and then as an effective catalyst in Friedel-Crafts alkylation of alcohols and aromatic compounds was used. The reaction progress was controlled using thin layer chromatography and the reaction products were analyzed using IR spectroscopy devise. The results show this new catalyst is effective in the friedel crafts alkylation and C-C bond formation was done in short time with very good yields.
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Liu, Ren-Rong, Ren-Xiao Liang, and Yi-Xia Jia. "Construction of Benzylic Stereogenic Carbon Centers through Enantioselective Arylation Reactions." Synlett 29, no. 02 (October 20, 2017): 157–68. http://dx.doi.org/10.1055/s-0036-1590923.

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Compounds bearing chiral benzylic stereocenters are important and frequently occur in natural products and drug molecules. In this account, we discuss our recent results on the construction of ­benzylic stereogenic centers based on enantioselective arylation and related domino sequences, mainly including asymmetric Friedel–Crafts alkylation reactions and asymmetric Heck reactions.1 Introduction2 The Catalytic Asymmetric Friedel–Crafts Alkylation Reaction2.1 Reactions of Electron-Deficient Alkenes2.2 Reactions of Active Ketimines2.3 Reactions of Nitrones2.4 Reactions of Aziridines3 The Asymmetric Heck Reaction3.1 Dearomative Heck Reactions and Related Domino Sequences3.2 Heck Reactions of in situ Formed Enamines4 Conclusion and Outlook
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Nayak, Yogeesha N., Swarnagowri Nayak, Y. F. Nadaf, Nitinkumar S. Shetty, and Santosh L. Gaonkar. "Zeolite Catalyzed Friedel-Crafts Reactions: A Review." Letters in Organic Chemistry 17, no. 7 (July 7, 2020): 491–506. http://dx.doi.org/10.2174/1570178616666190807101012.

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Friedel-Crafts reaction is one of the most useful synthetic tools in organic chemistry, mainly in the synthesis of aromatic ketones. The active catalysts for this reaction are modified zeolites and are preferable catalysts when shape selectivity affects the formation of the expected product. In this review, our aim is to corroborate recent literature available on zeolite catalyzed Friedel-Crafts alkylation and acylation reaction.
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Deng, Xiong-fei, Ying-wei Wang, Shi-qi Zhang, Ling Li, Guang-xun Li, Gang Zhao, and Zhuo Tang. "An organocatalytic asymmetric Friedel–Crafts reaction of 2-substituted indoles with aldehydes: enantioselective synthesis of α-hydroxyl ketones by low loading of chiral phosphoric acid." Chemical Communications 56, no. 16 (2020): 2499–502. http://dx.doi.org/10.1039/c9cc09637j.

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Dissertations / Theses on the topic "Friedel Crafts alkylation"

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Burguin, Emilie. "Zirconia based solid acids for Friedel-Crafts alkylation reactions." Thesis, University of York, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.420266.

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Gonçalves, de Almeida José Luis. "Alkylation du benzène par le 1-dodécène sur catalyseurs zéolithiques." Lyon 1, 1994. http://www.theses.fr/1994LYO10292.

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L'alkylation du benzene par le 1-dodecene pour la production des alkylbenzenes lineaires-lab, matiere premiere pour la fabrication de detergent biodegradable, a ete etudiee sur des catalyseurs zeolithiques (h-zsm-5, h-zsm-12, h-y et h-modernites), en vue de leur possible utilisation industrielle, en remplacement des catalyseurs homogenes hf, alcl#3, h#2so#4. Dans ce travail, il a ete analysee l'effet de la force et de la concentration des sites acides sur l'activite et la selectivite dans la formation de lab et de l'isomere 2-phenyl dodecane. Il a egalement ete analysee, comment la variation des proprietes structurales peuvent affecter la diffusion et la distribution des produits du lab. Il a ete mis en evidence que les caracteristiques structurales des zeolithes h-zsm-5, h-zsm-12 et h-y desaluminee jouent un role predominant par rapport aux seules caracteristiques acides et determinant sur l'activite et la selectivite. En ce qui concerne la zeolithe y, malgre la constatation que la force des sites acides augmente avec le taux de desalumination, l'activite de la reaction d'alkylation du benzene par le 1-dodecene croit proportionnellement au nombre de sites acides. La zeolithe y n'exhibe pas des effets de selectivite de forme. Pour les mordenites, l'effet decisive pour la formation des phenyl dodecanes provient de la creation d'une mesoporosite par le processus de desalumination. La presence presque exclusive des 2- et 3-phenyl dodecane, les isomeres les moins encombres, est attribuee a la selectivite de forme envers l'etat de transition ou envers les produits
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POIRIER, JEAN-LUC. "Alkylation de l'isobutane par l'ethylene en presence de catalyseurs solides de friedel-crafts." Caen, 1994. http://www.theses.fr/1994CAEN2037.

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La reaction d'un melange d'isobutane et d'ethylene maintenu liquide a ete etudiee en presence de diverses alumines chlorees. L'influence des parametres de reaction, temperature, dilution, temps de passage a ete examinee. L'alkylat contient uniquement des alcanes. Le catalyseur initialement tres actif se desactive ensuite progressivement. A une temperature proche de 0c et a dilution elevee en ethylene, les hexanes sont les produits majoritaires, le complement etant constitue essentiellement des octanes. La selectivite pour les paraffines branchees est elevee. La reaction de monoalkylation est preponderante et conduit au 2,3-dimethylbutane. Des trimethylpentanes et dimethylhexanes sont obtenus en quantites equivalentes par alkylations successives. Cette selectivite particuliere amene a proposer un nouveau mecanisme par ion carbonium cyclopropanique. Favorisee par l'elevation de la temperature de reaction et une forte concentration en ethylene, l'oligomerisation qui est a l'origine des alcanes superieurs peut etre preponderante sur catalyseur vieilli et sur certains catalyseurs. Les sites acides forts necessaires a la reaction d'alkylation isomerisent les produits primaires d'alkylation et craquent les alcanes superieurs. L'oligomerisation necessite une force des sites moindre que l'alkylation. Une caracteristique essentielle du catalyseur alumine chloree est sa capacite a induire le transfert d'hydrogene
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Laouadi, Ornella Laura Nathalie. "Enantioselective Friedel-Crafts reaction catalysed by alginate aerogels." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2019. http://amslaurea.unibo.it/18622/.

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Alginates are polysaccharides derived from brown algae, available in nearly unlimited amounts at very low prices. In the presence of some divalent metals, these renewable biopolymers can readily form hydrogels, solvogels and aerogels, characterized by high surface areas, good mechanical properties, tolerance to different media, and easy manageability. For these reasons, alginates are nowadays being thoroughly studied in heterogeneous catalysis; several applications in supported metal catalysis and as heterogeneous Brønsted acids have emerged. However, none of these studies has given an answer to the following intriguing question: can we use the intrinsic chirality of alginates to induce enantioselectivity in a chemical reaction? In order to answer this question a representative reaction, the Friedel-Crafts alkylation of nitroalkenes with indoles, was tested in this master thesis. This study, which involved a large screening of a variety of alginate gels under different reaction conditions, showed that Cu2+ and Ba2+ are the best cross-linking metals to promote the Friedel-Crafts reaction. Indeed, good activity with moderate enantiomeric excesses were obtained under the optimized reaction conditions. Furthermore, these two metals allowed the access to both enantiomers of the products, an important aspect given that only one enantiomeric form of alginates is available. Finally, the heterogeneous nature of the catalysis by one of the two gels was proved, and a good recyclability was demonstrated, by showing that the same catalyst can be used at least five times with similar results.
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Smutek, Bernhard. "Réactions Organiques des Alcools en Conditions Hydrothermales." Thesis, Montpellier 2, 2011. http://www.theses.fr/2011MON20180.

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Cette thèse a pour objectif d'étudier les réactions des alcools en conditions hydrothermales. Dans une phase préliminaire, le phényl-éthanediol a été étudiés. Après aldolisation, cyclisation intramoléculaire et aromatisation sont suivi en formant 1-phénylnaphthalène. L'aldolisation et la cyclisation du type de Friedel et Crafts ont été mise en œuvre.Les transformations de l'éthylène glycol et du 1,2-propanediol sont fortement dépendantes des conditions de réaction (température, durée de réaction et nature du solvant). La réaction de transformation du 1,2-propanediol permet de synthètiser les composés suivants : mésitylène, 2-méthyl-pentènal et 2-éthyl-3,5-diméthyl-cyclopent-2-ènone. Ces produits peuvent être utilisés comme biocarburant ou solvant ou peuvent constituer des matières premières pour des synthèses organiques.Les alkylations du naphthalène et du phénol ont été étudiées en détails en fonction de la nature du solvant. L'emploi d'acide chlorhydrique en concentration de 0.05mol/L à 180°C permet l'alkylation des aromats par l'alcool benzylique. D'autres solvants (acide acétique, acide formique à 1mol/L) permettent d'obtenir ces composés avec des rendements d'alkylation inférieurs. Par ailleurs, le recyclage de ces solvants est réalisable. Notons enfin que l'alcool benzylique peut polymériser et cette polymérisation est fortement influencée par la température utilisée. La polymérisation de l'alcool benzylique a été appliquée avec succès à la séparation des platinoïdes d'une solution modèle d'effluents issue du traitement du combustible nucléaire
This thesis aims to study and to apply reactions of alcohols under hydrothermal conditions.Studies on 1-phenyl-ethanediol show an aldolisation, followed by an intramolecular Friedel-Crafts type reaction and an aromatisation. Finally, it ends up by as 1-phenyl-naphthalene.Ethylene glycol reacts on itself with a strong dependence on the temperature and the solvent. The conversion of 1,2-propanediol showed similar dependences and obtained even the aromatic compound mesitylene and especially the amount of products proves dependence on the temperature and the duration of the reaction. The main compounds can be used as solvents, as biofuel and for syntheses, whereas the byproducts might be biocarburants after hydrogenation.The Friedel-Crafts type reaction is transferred to an intermolecular one. Naphthalene and phenol are studied in more detail. 0.05mol/L HCl are enough in order to benzylate an aromatic compound at 180°C. HCl can be replaced by acetic acid or formic acid, but even concentrations of 1.0mol/L do not achieve results as good as 0.05mol/L HCl. The recycling of the aqueous phase of these reactions is advantageous. Additionally, benzyl alcohol alkylates benzyl alcohol and thus it can polymerize. Higher temperatures lead to longer polymers. This polymerization can be used in the domain of nuclear fuel recycling in order to separate platinum group metals out of a model solution
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Drouillard, Joe͏̈lle. "Utilisation de zéolithes dans les réactions de type Friedel-Crafts : acylation et alkylation du thiophène." Poitiers, 1995. http://www.theses.fr/1995POIT2266.

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Les derives du thiophene ont trouve ces dernieres annees de nombreux debouches dans les domaines alimentaires, agrochimique et surtout pharmaceutique. En particulier, la decouverte des proprietes anti-inflammatoires et antalgiques de certains derives aroyles des acides thienylacetiques a initie de nombreuses recherches concernant les derives du thiophene, permettant de mettre a jour l'activite therapeutique d'autres molecules. L'acylation et l'alkylation des composes aromatiques heterocycliques sont traditionnellement realisees par des reactions de type friedel et crafts, par catalyse homogene au moyen d'acides de lewis ou d'acides protoniques forts. L'utilisation de ce type de catalyseur pose des problemes a la fois d'ordre economique et environnemental. L'objectif de ce travail etait d'essayer de les remplacer par des catalyseurs non polluants et regenerables, comme les catalyseurs acides solides, en particulier les zeolithes. Les resultats obtenus en acylation et en alkylation du thiophene montrent que les performances en terme d'activite et de selectivite des zeolithes sont semblables voire superieures a celles acides de lewis. De plus ces catalyseurs sont parfaitement regenerables, et la recuperation des produits est tres facile. Une etude cinetique complete des deux reactions realisee sur une zeolithe y d'acidite moyenne nous a permis de determiner les mecanismes reactionnels. Nous avons ensuite examine l'influence de la nature du catalyseur sur son activite et sa selectivite, en faisant varier l'acidite et/ou la porosite. L'ensemble des resultats obtenus montre que de nombreux parametres, tels que la temperature, la nature de l'agent acylant ou alkylant, la nature du solvant, l'acidite et la porosite du catalyseur influent sur les vitesses des reactions d'alkylation et d'acylation du thiophene. L'effet de la porosite semble tout particulierement important, car il modifie profondement la selectivite des reactions. Il est cependant difficile d'etendre ces conclusions a d'autres reactions similaires, chaque cas necessitant une etude systematique de l'influence des divers parametres
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Hlatywayo, Tapiwa. "Coal fly ash and acid mine drainage based heterogeneous Fe catalysts Friedel-Crafts alkylation reaction." University of Western Cape, 2020. https://hdl.handle.net/11394/7295.

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Philosophiae Doctor - PhD
The catalytic support materials used in the present study are zeolite HBEA and MCM-41. These high silica zeolites were synthesised from coal fly ash (CFA) waste via a novel approach that involved a fusion step, acid assisted silica extraction and removal of Al, Ca and Na from the silica by treatment with oxalic acid. The generated silica was converted to HBEA and MCM-41 via conventional hydrothermal treatment. The metal incorporation onto HBEA was done via two approaches namely; liquid phase ion exchange (LIE) and wet impregnation (WI) while the loading on MCM-41 was only done via WI since the material does not possess exchange sites. The metal solution precursors were AMD and Fe extracted from CFA (FeAsh) via acid leaching followed by pH regulation by concentrated NaOH. This is the first time these solutions were tested as possible metal precursors in catalyst synthesis.
2021-08-30
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Kirk, Andrew. "Mesoporous supports for the catalysis of Friedel-Crafts alkylation and cyclialkylation reactions with sulfur-containing aromatics." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk3/ftp04/nq31041.pdf.

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Montagne, Fabienne. "Les sels de terres rares en catalyse hétérogène des réactions de Friedel-Crafts : applications en polycondensation." Dijon, 1997. http://www.theses.fr/1997DIJOS033.

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En chimie fine, le réactif universel des réactions d'alkylation et d'acylation de composés aromatiques selon Friedel-Crafts est le trichlorure d'aluminium mais l'emploi de cet acide de Lewis présente plusieurs inconvénients : la réaction est au mieux stoechiométrique, le réactif est d'un usage unique et les effluents sont nuisibles à l'environnement. Les sels de terres rares déposés sur un support minéral sont d'excellents catalyseurs des réactions de Friedel-Crafts ; leur activité catalytique est nettement plus élevée que celle des chlorures de terres rares et leurs analogues coordonnés non supportés. Les conditions opératoires sont douces, l'isolement des produits ne nécessite pas d'hydrolyse et les catalyseurs, facilement éliminés du milieu réactionnel par simple filtration, sont recyclables. Différentes techniques d'analyse ont été utilisées pour caractériser les catalyseurs supportés et étudier l'influence des divers traitements sur la nature de l'espèce déposée. Après avoir évalué leurs performances catalytiques dans deux réactions tests, la gamme de réactivité des catalyseurs supportés a été étudiée. Les catalyseurs supportés ont également été étudiés dans des réactions conduites sous irradiation micro-ondes. Les différents tests ont confirmé qu'un accroissement de la température, module par la puissance du rayonnement micro-ondes, s'accompagne d'une augmentation du rendement ; la sélectivité est semblable à celle obtenue pour les réactions effectuées en chauffage traditionnel. L'application des réactions d'alkylation de type Friedel-Crafts à des réactions de polycondensation a conduit à la synthèse de nouveaux polybenzyles solubles, dont les caractéristiques physico-chimiques ont été déterminées.
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Fishlock, Daniel. "The Catalytic Intramolecular Friedel-Crafts Acylation of Meldrum's Acid Derivatives and The Total Synthesis of Taiwaniaquinol B." Thesis, University of Waterloo, 2005. http://hdl.handle.net/10012/1226.

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The intramolecular Friedel-Crafts acylation of aromatics with Meldrum?s acid derivatives catalyzed by metal trifluoromethanesulfonates and other Lewis acids is reported. Meldrum?s acids are easily prepared, functionalized, handled, and purified. The synthesis of polysubstituted 1-indanones from benzyl Meldrum's acids was investigated thoroughly, and it was shown that a variety of catalysts were effective, whilst accommodating a diversity of functional groups under mild conditions. The scope, limitations, and functional group tolerance (terminal alkene and alkyne, ketal, dialkyl ether, dialkyl thioether, aryl methyl ether, aryl TIPS and TBDPS ethers, nitrile- and nitro-substituted aryls, alkyl and aryl halides) for a variety of 5-benzyl (enolizable Meldrum?s acids) and 5-benzyl-5-substituted Meldrum?s acids (quaternarized Meldrum?s acids), forming 1-indanones and 2-substituted-1-indanones respectively, are delineated.

This method was further applied to the synthesis of 1-tetralones, 1-benzosuberones, and the potent acetylcholinesterase inhibitor donepezil.

Mechanistic investigations were undertaken to determine the rate-determining step in the acylation sequence using Meldrum?s acid, as well as to examine the role of the Lewis acid catalyst. Enolizable Meldrum?s acid derivatives can react via an acyl ketene intermediate under thermal conditions, while quaternarized Meldrum?s acid derivatives are thermally stable and only act as effective Friedel-Crafts acylating agents in the presence of a Lewis acid catalyst.

The total synthesis of (±)-Taiwaniaquinol B was completed. This natural product was the first ever isolated containing an unusual 6-5-6 fused ring system, and it also contains a hexasubstituted aromatic ring, and two all-carbon quaternary centers. This synthesis was accomplished via an intramolecular Friedel-Crafts acylation/carbonyl a-tert-alkylation reaction that exploits the unique chemistry of Meldrum?s acid. This novel methodology can be used to access a variety of highly substituted fused ring systems of various sizes.
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Books on the topic "Friedel Crafts alkylation"

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Catalytic asymmetric Friedel-Crafts alkylations. Weinheim: Wiley-VCH, 2009.

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Olah, George A., Marco Bandini, and Achille Umani-Ronchi. Catalytic Asymmetric Friedel-Crafts Alkylations. Wiley & Sons, Limited, John, 2009.

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Bandini, Marco, and Achille Umani‐Ronchi, eds. Catalytic Asymmetric Friedel–Crafts Alkylations. Wiley, 2009. http://dx.doi.org/10.1002/9783527626977.

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Book chapters on the topic "Friedel Crafts alkylation"

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Blay, Gonzalo, Marc Montesinos-Magraner, and José R. Pedro. "Friedel-Crafts Alkylation of Arenes in Total Synthesis." In Arene Chemistry, 33–58. Hoboken, NJ: John Wiley & Sons, Inc, 2015. http://dx.doi.org/10.1002/9781118754887.ch2.

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Chateauneuf, John E., and Kan Nie. "An Investigation of Friedel—Crafts Alkylation Reactions in Super- and Subcritical CO2and under Solventless Reaction Conditions." In ACS Symposium Series, 136–50. Washington, DC: American Chemical Society, 2002. http://dx.doi.org/10.1021/bk-2002-0819.ch010.

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Black, D. A., and K. Fagnou. "Friedel–Crafts Alkylation." In Monocyclic Arenes, Quasiarenes, and Annulenes, 1. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-045-00558.

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Toyota, S., and T. Iwanaga. "Friedel–Crafts Alkylation." In Monocyclic Arenes, Quasiarenes, and Annulenes, 1. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-045-00831.

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Black, D. A., and K. Fagnou. "Asymmetric Friedel–Crafts Alkylation." In Monocyclic Arenes, Quasiarenes, and Annulenes, 1. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-045-00563.

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Loh, T. P. "Reductive Friedel–Crafts Alkylation." In Compounds of Groups 13 and 2 (Al, Ga, In, Tl, Be...Ba), 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-007-00353.

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Hapiot, F., and E. Monflier. "Friedel–Crafts Alkylation of Indoles." In Water in Organic Synthesis, 1. Georg Thieme Verlag KG, 2012. http://dx.doi.org/10.1055/sos-sd-206-00564.

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Schatz, J., and M. Seler. "Friedel–Crafts Alkylation of Thiophenes." In Fully Unsaturated Small-Ring Heterocycles and Monocyclic Five-Membered Hetarenes with One Heteroatom, 1. Georg Thieme Verlag KG, 2011. http://dx.doi.org/10.1055/sos-sd-109-00219.

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Zysman-Colman, E. "Friedel–Crafts Alkylation of Arenes." In Monocyclic Arenes, Quasiarenes, and Annulenes, 1. Georg Thieme Verlag KG, 2010. http://dx.doi.org/10.1055/sos-sd-045-00108.

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"39. Friedel‒Crafts Acylation & Alkylation." In Organic Chemistry: 100 Must-Know Mechanisms, 92–93. De Gruyter, 2020. http://dx.doi.org/10.1515/9783110608373-039.

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