Academic literature on the topic 'Free radical'

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Journal articles on the topic "Free radical"

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Yañez Jaramillo, Lina M., Joy H. Tannous, and Arno de Klerk. "Persistent Free Radicals in Petroleum." Processes 11, no. 7 (2023): 2067. http://dx.doi.org/10.3390/pr11072067.

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The persistent free radical content in petroleum is of the order 1018 spins/g (1 μmol/g), with higher and lower values found depending on origin and in different distillation fractions. The field of persistent free radicals in petroleum was reviewed with the aim of addressing and explaining apparent inconsistencies between free radical persistence and reactivity. The macroscopic average free radical concentration in petroleum is persistent over geological time, but individual free radical species in petroleum are short-lived and reactive. The persistent free radical concentration in petroleum
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Kim, Eun-Kyung, and Mi Ryeong Song. "Factors Influencing the Level of Oxygen Free Radicals in Female Nursing Students." Global Journal of Health Science 11, no. 7 (2019): 1. http://dx.doi.org/10.5539/gjhs.v11n7p1.

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This study was conducted to investigate the levels of oxygen free radicals and related health factors in 201 female nursing students. The questionnaire was completed by the participants and their oxygen free radical levels were measured by urine test. In this study, an oxygen free radical analyzer was used to measure oxygen free radical levels. The oxygen free radical analyzer analyzes the amount of oxygen free radicals in the body by measuring urinary malondialdehyde (MDA). To determine factors associated with oxygen free radical levels, multiple regression tests were conducted. Of the partic
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Stevanovic, Jelka, Suncica Borozan, Slavoljub Jovic, and Igor Ignjatovic. "Physiology of free radicals." Veterinarski glasnik 65, no. 1-2 (2011): 95–107. http://dx.doi.org/10.2298/vetgl1102095s.

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Free radicals imply that every atom, molecule, ion, group of atoms, or molecules with one or several non-paired electrons in outer orbital. Among these are: nitrogenoxide (NO?), superoxide-anion-radical (O2?-), hydroxyl radical (OH?), peroxyl radical (ROO?), alcoxyl radical (RO?) and hydroperoxyl radical (HO2?). However, reactive oxygen species also include components without non-paired electrons in outer orbital (so-called reactive non-radical agents), such as: singlet oxygen (1O2), peroxynitrite (ONOO-), hydrogen-peroxide (H2O2), hypochloric acid (eg. HOCl) and ozone (O3). High concentration
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Adrian, Gerild, Edi Suryanto, and Defny S. Wewengkang. "AKTIVITAS PENANGKAL RADIKAL BEBAS DARI FRAKSI KULIT KAYU SAGU BARUK (Arenga microcarpha Beccari)." PHARMACON 10, no. 1 (2021): 762. http://dx.doi.org/10.35799/pha.10.2021.32777.

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ABSTRACTThis study aims to determine the antioxidant activity and free radical antidote from fraction of bark sago baruk (Arenga microcarpha Beccari). This study initiated by extracting the powder of bark sago baruk using the maceration method for 3 days with ethanol 80%. The extract then partitioned using a series of solvent such as petroleum ether, ethyl acetate, buthanol, aquadest. The results showed that the ethyl acetate fraction had the highest free radical antidote content followed by the aquadest fraction, buthanol fraction, petroleum ether fraction. The content of free radical antidot
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Mikayil Aliyev, Mirza, Ulduz Yunis Safarova, and Shafiqa Jahangir Jafarova. "CHARACTERISTICS AND THERAPEUTIC EFFECTS OF THE NOVEL FREE RADICAL SCAVENGER – EDARAVONE." NATURE AND SCIENCE 04, no. 05 (2020): 17–20. http://dx.doi.org/10.36719/2707-1146/05/17-20.

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Edaravone is the first free radical scavenger which approved clinically and has an ability to decrease the level of free radicals in cells. Edaravone is a strong antioxidant, which can protect different cells (e.g. endothelial cells) against damage by ROS by inhibiting the lipoxygenase metabolism of arachidonic acid, by trapping hydroxyl radicals, by increasing prostacyclin production, by inhibiting alloxan-induced lipid peroxidation, etc. Because of that, Edaravone is used in treatment of diseases which are associated with oxidative stress. Key words: edaravone, free radical, antioxidant, neu
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Silaev, Michael M. "Free-Radical Nonbranched-Chain Oxidation of Hydrogen." International Journal of Innovative Research in Computer Science & Technology 6, no. 5 (2018): 91–98. http://dx.doi.org/10.21276/ijircst.2018.6.5.1.

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Horgan, John. "Free Radical." Scientific American 262, no. 5 (1990): 40–44. http://dx.doi.org/10.1038/scientificamerican0590-40.

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Silaev, Michael M. "KINETIC EQUATIONS FOR RADICAL-CHAIN OXIDATION INVOLVING PROCESS-INHIBITING ALKYL (OR HYDRO)TETRAOXYL FREE RADICAL." American Journal of Applied Sciences 05, no. 06 (2023): 29–48. http://dx.doi.org/10.37547/tajas/volume05issue06-07.

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The derivation of kinetic equations for the oxidation processes by the free-radical nonbranched-chain mechanism is shown. This derivation is based on the proposed reaction scheme for the initiated addition of free radicals to the multiple bond of the molecular oxygen includes the addition reaction of the peroxyl free radical to the oxygen molecule to form the tetraoxyl free radical. This reaction competes with chain propagation reactions through a reactive free radical. The chain evolution stage in this scheme involves a few of free radicals, one of which – alkyl(or hydro)tetraoxyl – is relati
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Livi Kharisma Wibawa, Vinda Maharani Patricia, and Livia Syafnir. "Aktivitas Antioksidan pada Tanaman Mengkudu (Morinda citrifolia L.)." Bandung Conference Series: Pharmacy 4, no. 2 (2024): 313–20. http://dx.doi.org/10.29313/bcsp.v4i2.13911.

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Abstract. Degenerative diseases are caused by highly reactive free radicals. This free radical activity can be inhibited by antioxidant compounds. Antioxidants are substances necessary for the body to neutralize free radicals, compensating for the lack of electrons in free radicals, inhibiting the chain reaction of free radical formation, and preventing free radicals from damaging normal cells. The noni plant (Morinda citrifolia L.) has the potential to exert antioxidant effects by reducing the concentration of free radicals in the body and contains many flavonoids that may be useful as antiox
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Zhao, Zizhen, Chen Fu, Yuping Zhang, and Ailing Fu. "Dimeric Histidine as a Novel Free Radical Scavenger Alleviates Non-Alcoholic Liver Injury." Antioxidants 10, no. 10 (2021): 1529. http://dx.doi.org/10.3390/antiox10101529.

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Non-alcoholic liver injury (NLI) is a common disease worldwide. Since free radical damage in the liver is a crucial initiator leading to diseases, scavenging excess free radicals has become an essential therapeutic strategy. To enhance the antioxidant capacity of histidine, we synthesized a protonated dimeric histidine, H-bihistidine, and investigated its anti-free radical potential in several free-radical-induced NLI. Results showed that H-bihistidine could strongly scavenge free radicals caused by H2O2, fatty acid, and CCl4, respectively, and recover cell viability in cultured hepatocytes. I
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Dissertations / Theses on the topic "Free radical"

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Barreto, Joao Pedro Cabaco Moniz. "Dioxygen free radical reactions." Thesis, Oxford Brookes University, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.389105.

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Euapermkiati, Anucha. "Free radical telomerisation reactions." Thesis, University of Bradford, 1990. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.278895.

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Shooter, Andrew James. "Living free radical polymerisation." Thesis, University of Warwick, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.263817.

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Wood, Geoffrey Paul Farra. "Theoretical Investigations of Radical-Mediated Protein Oxidation." Thesis, The University of Sydney, 2006. http://hdl.handle.net/2123/1413.

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This thesis primarily details the application of high-level ab initio quantum chemistry techniques in order to understand aspects of free-radical mediated protein oxidation. Traditionally, product analysis and electron paramagnetic resonance (EPR) spectroscopy are the primary means for elucidating the chemistry of protein oxidation. However, in experiments involving relatively small proteins reacting with a controlled radical-flux, a vast array of compounds can be produced, which are often difficult to analyse. Quantum chemical techniques on the other hand, can calculate the properties of any
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Wood, Geoffrey Paul Farra. "Theoretical Investigations of Radical-Mediated Protein Oxidation." University of Sydney, 2006. http://hdl.handle.net/2123/1413.

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Doctor of Philosophy (PhD)<br>This thesis primarily details the application of high-level ab initio quantum chemistry techniques in order to understand aspects of free-radical mediated protein oxidation. Traditionally, product analysis and electron paramagnetic resonance (EPR) spectroscopy are the primary means for elucidating the chemistry of protein oxidation. However, in experiments involving relatively small proteins reacting with a controlled radical-flux, a vast array of compounds can be produced, which are often difficult to analyse. Quantum chemical techniques on the other hand, can ca
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Grice, I. Darren, and n/a. "Some New Aspects of Radical Trapping Using an Aminoxyl Radical Trap." Griffith University. School of Science, 1993. http://www4.gu.edu.au:8080/adt-root/public/adt-QGU20050915.150556.

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An investigation of the initiation mechanism in the free radical copolymerisation of acrylonitrile and vinyl acetate using the aminoxyl radical trapping technique, employing 1,1 ,3,3-tetramethyl-2,3-dihydro- 1 Hisoindol-2-yloxyl is reported. Based upon the experimental results, the mechanism of initiation is suggested as proceeding via the 'free monomer' mechanism. Additionally, the effect of Lewis acids on the initiation mechanism is reported. A study of the addition of phosphorus-centred radicals to alkenes and phenylacetylene, utilising the aminoxyl radical trapping technique is reported. T
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Grice, I. Darren. "Some New Aspects of Radical Trapping Using an Aminoxyl Radical Trap." Thesis, Griffith University, 1993. http://hdl.handle.net/10072/365216.

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An investigation of the initiation mechanism in the free radical copolymerisation of acrylonitrile and vinyl acetate using the aminoxyl radical trapping technique, employing 1,1 ,3,3-tetramethyl-2,3-dihydro- 1 Hisoindol-2-yloxyl is reported. Based upon the experimental results, the mechanism of initiation is suggested as proceeding via the 'free monomer' mechanism. Additionally, the effect of Lewis acids on the initiation mechanism is reported. A study of the addition of phosphorus-centred radicals to alkenes and phenylacetylene, utilising the aminoxyl radical trapping technique is reported. T
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Johansson, Erik. "Free radical mediated cellulose degradation." Doctoral thesis, KTH, Chemistry, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3477.

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<p>This thesis addresses the mechanisms involved in cellulosedegradation in general and Totally Chlorine Free (TCF) bleachingof pulp in particular. The thesis shows that the cellulosedegradation during high consistency ozone bleaching is explainedby free radical chain reactions.</p><p>By simulation, it has been shown that the number, weight andviscosity average of liner polymer chain length can be used tocalculate the number of random scissions in a linear polymer ofany molecular weight distribution, provided that there is acalibrated Mark-Houwink equation. A model describing partialdegradatio
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Hancock-Chen, Tanya. "Biologically relevant free radical reactions." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 2000. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape3/PQDD_0019/NQ58282.pdf.

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Johansson, Erik E. "Free radical mediated cellulose degradation /." Stockholm : Department of Chemistry, Nuclear Chemistry, Royal Institute of Technology, 2003. http://urn.kb.se/resolve?urn=urn:nbn:se:kth:diva-3477.

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Books on the topic "Free radical"

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Coupé, Nez. Free radical. Croomia Books, 1992.

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Murphy, Claire Rudolf. Free radical. Clarion Books, 2002.

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Myette, Michael. Free radical. Pemberton Mysteries, 2008.

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Paulauskas, Irena O. Radical polymerization: New developments. Nova Science Publishers, 2011.

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Fehér, J. Free radical reactions in medicine. Springer-Verlag, 1987.

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Perkins, M. John. Radical chemistry. Ellis Horwood, 1994.

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Derek, Barton. Half a century of free radical chemistry. Cambridge University Press, 1993.

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Bruce, Wallace Kendall, ed. Free radical toxicology. Taylor & Francis, 1997.

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Postigo, J. Alberto. Organic radical reactions in water and alternative media. Nova Science Publishers, 2011.

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Forbes, Malcolm D. E., ed. Carbon-Centered Free Radicals and Radical Cations. John Wiley & Sons, Inc., 2009. http://dx.doi.org/10.1002/9780470584118.

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Book chapters on the topic "Free radical"

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Gooch, Jan W. "Free Radical." In Encyclopedic Dictionary of Polymers. Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_5286.

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Punekar, Narayan S. "Free Radicals and Radical Enzymology." In ENZYMES: Catalysis, Kinetics and Mechanisms. Springer Nature Singapore, 2025. https://doi.org/10.1007/978-981-97-8179-9_34.

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Drăguţan, I., A. Caragheorgheopol, H. Căldăraru, and R. J. Mehlhorn. "Hydrophobic Radical-Ions." In Organic Free Radicals. Springer Berlin Heidelberg, 1988. http://dx.doi.org/10.1007/978-3-642-73963-7_24.

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Hayashi, Nariyuki, and Dalton W. Dietrich. "Free Radical Production." In Brain Hypothermia Treatment. Springer Japan, 2004. http://dx.doi.org/10.1007/978-4-431-53953-7_14.

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Norman, Richard, and James M. Coxon. "Free-radical reactions." In Principles of Organic Synthesis. Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-2166-8_17.

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Serra, Christophe. "Free Radical Polymerization." In Micro Process Engineering. Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527631445.ch29.

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Grossman, Robert B. "Free-Radical Reactions." In The Art of Writing Reasonable Organic Reaction Mechanisms. Springer New York, 1999. http://dx.doi.org/10.1007/978-1-4757-3030-2_5.

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Grossman, Robert B. "Free-Radical Reactions." In The Art of Writing Reasonable Organic Reaction Mechanisms. Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-28733-7_5.

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Carey, Francis A., and Richard J. Sundberg. "Free-Radical Reactions." In Advanced Organic Chemistry. Springer US, 1990. http://dx.doi.org/10.1007/978-1-4613-9795-3_12.

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Hess, John L. "Free radical scavenging." In Plant Responses to the Gaseous Environment. Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-011-1294-9_6.

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Conference papers on the topic "Free radical"

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Dunlop, A. K. "Catalysis and Inhibition in Oxygen Scavenging." In CORROSION 1986. NACE International, 1986. https://doi.org/10.5006/c1986-86176.

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Abstract The catalysis of oxygen scavenging reactions can be placed in two categories, 1) those depending on a free radical chain mechanism and 2) those in which a catalytic intermediate redox cycle is involved. Sulfite scavenging exemplifies the first category as the free radical chain mechanism is the only one effective in this system. This mechanism makes the sulfite system susceptible to a great variety of inhibiting effects. However, mechanistic understanding is available to solve such problems. Hydrazine can provide examples in each category. Catalysis via the hydroquinone/quinone cycle
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Lewandowski, Heather J., L. Paul Parazzoli, and Daniel Lobser. "Cold Free-Radical NH Molecules." In Laser Science. OSA, 2006. http://dx.doi.org/10.1364/ls.2006.ltuh1.

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Leahy, David J., Douglas R. Cyr, David L. Osborn, and Daniel M. Neumark. "Fast-beam studies of free-radical photodissociation: the CH2NO2 radical." In OE/LASE'93: Optics, Electro-Optics, & Laser Applications in Science& Engineering, edited by Cheuk Yiu Ng. SPIE, 1993. http://dx.doi.org/10.1117/12.143115.

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Scott, T. W., and S. N. Liu. "Picosecond cage recombination measurements of polyatomic free radical pairs." In International Laser Science Conference. Optica Publishing Group, 1986. http://dx.doi.org/10.1364/ils.1986.thl51.

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Geminate free radical recombination is an important testing ground for current theories of chemical reaction dynamics in liquids. The work described here deals with the recombination of phenyl thiyl radicals in liquid hydrocarbons. Photolysis of diphenyl disulfides using near-ultraviolet light generates thiyl radicals which are detected by picosecond transient absorption spectroscopy. We find that the rate and extent of cage recombination is controlled by solvent viscosity and by the dipole-dipole reorientation energy of a polar radical pair. In moderately viscous liquids such as decalin, for
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Pfaendtner, Jim, Linda J. Broadbelt, and Q. Jane Wang. "Quantum Chemical Studies of Free-Radical, Hindered Phenol Stabilizers." In World Tribology Congress III. ASMEDC, 2005. http://dx.doi.org/10.1115/wtc2005-64007.

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Quantum chemical investigations of the action of hindered phenol radical stabilizers in lubricant degradation chemistry have been completed. We are currently developing the first mechanistic models of lubricant degradation with the aim of including the chemistry of additives such as radical stabilizers that are found in commercial lubricant formulations. A key component of development of these models is obtaining reliable estimates of the kinetic parameters for all reactions. Specifically, rate constants and structure-reactivity correlations for the interaction of hindered phenol radical stabi
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Bochinski, J. R., E. R. Hudson, and J. Ye. "Stark manipulation of the free radical OH." In Quantum Electronics and Laser Science (QELS). Postconference Digest. IEEE, 2003. http://dx.doi.org/10.1109/qels.2003.238172.

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Chen, H., Y. T. Chan, H. V. Poor, and K. Sezaki. "Range-Free Localization with the Radical Line." In ICC 2010 - 2010 IEEE International Conference on Communications. IEEE, 2010. http://dx.doi.org/10.1109/icc.2010.5502304.

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Lulan, Theodore Y. K., Sri Fatmawati, Mardi Santoso, and Taslim Ersam. "Free radical scavenging activity of Artocarpus champeden extracts." In THE 3RD INTERNATIONAL SEMINAR ON CHEMISTRY: Green Chemistry and its Role for Sustainability. Author(s), 2018. http://dx.doi.org/10.1063/1.5082460.

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Girbu, Vladilena, Nicon Ungur, Philippe Renaud, and Veaceslav Kulcitki. "Free radical functionalizations of labdanes and related diterpenoids." In New frontiers in natural product chemistry, scientific seminar with international participation. Institute of Chemistry, 2021. http://dx.doi.org/10.19261/nfnpc.2021.ab20.

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Hudson, Eric, J. R. Bochinski, H. J. Lewandowski, and Jun Ye. "Cold free radical molecules in the laboratory frame." In International Quantum Electronics Conference. OSA, 2004. http://dx.doi.org/10.1364/iqec.2004.imi5.

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Reports on the topic "Free radical"

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Dagdigian, Paul J. Spectroscopic Characterization of Free Radical Intermediates. Defense Technical Information Center, 2001. http://dx.doi.org/10.21236/ada394529.

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Wang, M., J. M. Smith, and B. J. McCoy. Free-radical kinetics of coal liquefaction. Office of Scientific and Technical Information (OSTI), 1994. http://dx.doi.org/10.2172/26601.

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Cyr, Douglas Robert. Fast beam studies of free radical photodissociation. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/10148491.

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Osborn, David Lewis. Photodissociation dynamics and spectroscopy of free radical combustion intermediates. Office of Scientific and Technical Information (OSTI), 1996. http://dx.doi.org/10.2172/503521.

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Miller, Roger E. The Growth and Characterization of Metastable Free Radical Nanoclusters. Defense Technical Information Center, 2004. http://dx.doi.org/10.21236/ada424162.

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Baer, Tomas, and Roger E. Miller. The Growth and Characterization of Metastable Free Radical Nanoclusters. Defense Technical Information Center, 2007. http://dx.doi.org/10.21236/ada469731.

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Brennecke, Joan F. Studies of Ionic and Free Radical Reactions in Supercritical Water. Defense Technical Information Center, 2001. http://dx.doi.org/10.21236/ada396304.

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Jacox, Marilyn E. Free Radical Detection and Reactions in the Decomposition of Energetic Materials. Defense Technical Information Center, 1987. http://dx.doi.org/10.21236/ada184677.

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Curl, R. F., and G. P. Glass. Infrared absorption spectroscopy and chemical kinetics of free radicals. [HCCN; CCH-H[sub 2] reaction; propargyl radical recombination]. Office of Scientific and Technical Information (OSTI), 1993. http://dx.doi.org/10.2172/6566601.

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Lampe, F. W. The free-radical and ion chemistry of volatile silanes, germanes and phosphines. Office of Scientific and Technical Information (OSTI), 1990. http://dx.doi.org/10.2172/6290400.

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