Academic literature on the topic 'Fluorine diffusion'

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Journal articles on the topic "Fluorine diffusion"

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Tian, Kun Viviana, Gregory A. Chass, and Devis Di Tommaso. "Simulations reveal the role of composition into the atomic-level flexibility of bioactive glass cements." Physical Chemistry Chemical Physics 18, no. 2 (2016): 837–45. http://dx.doi.org/10.1039/c5cp05650k.

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Baheiraei, Nafiseh, and Mahmoud Azami. "Investigation of Fluorine Incorporation within Gelatin/Calcium Phosphate Nanocomposite Scaffold Prepared through a Diffusion Method." Advanced Composites Letters 22, no. 5 (September 2013): 096369351302200. http://dx.doi.org/10.1177/096369351302200503.

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In this study diffusional method was used to prepare a biomimetic calcium phosphate/gelatin nanocomposite as a scaffold for bone and tooth tissue engineering. Incorporation of fluorine into mineral phase of the scaffold was also investigated. Addition of fluoride to the synthesis process caused formation of fluoroapatite and calcium fluoride along with hydroxyapatite within gelatin while in the sample lacking fluorine atoms, hydroxyapatite and octacalcium phosphate were detected. With addition of fluorine within the structure of precipitated minerals, morphology of minerals was dramatically changed from oriented rod-like minerals with rectangular cross section toward spherical particles consisting of smaller crystals with uneven surface scattered over the gelatinous bulk material.
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Wang, Heng, Zongzheng Cao, Yuying Zhu, Menghan Liao, Genda Gu, Qi-Kun Xue, and Ding Zhang. "Tuning superconductivity of Bi2Sr2CaCu2O8+x by fluoride ion intercalation with LaF3 gate dielectric." Journal of Applied Physics 132, no. 21 (December 7, 2022): 214301. http://dx.doi.org/10.1063/5.0121822.

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We demonstrate fluorine intercalation into Bi2Sr2CaCu2O8+x (BSCCO) flakes, as thick as 100 nm, by back-gating a single crystalline LaF3 substrate. Element-sensitive analysis not only confirms the presence of fluorine in BSCCO after gating but also reveals lateral diffusion of fluorine in BSCCO. Transport measurements further demonstrate the hole-doping effect of fluoride ions in BSCCO through effective modulation of the superconducting transitions. Our work introduces a distinct type of ions (F−) that can be intercalated into materials via solid state back-gating. It broadens the toolbox of ion back-gating and is useful for addressing exotic phenomena in the heavily hole doped regime.
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Virdi, S., A. C. T. Schettini, and R. França. "Fluoride varnishes: In vitro assessment of fluorine diffusion on enamel." Dental Materials 32 (2016): e75. http://dx.doi.org/10.1016/j.dental.2016.08.157.

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Shapiro, M. J., Tetsuo Matsuda, Son V. Nguyen, C. Parks, and C. Dziobkowski. "Fluorine Diffusion from Fluorosilicate Glass." Journal of The Electrochemical Society 143, no. 7 (July 1, 1996): L156—L158. http://dx.doi.org/10.1149/1.1836960.

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Hermann, Wilhelm, Angelika Raith, and Hans Rau. "Diffusion of Fluorine in Silica." Berichte der Bunsengesellschaft für physikalische Chemie 91, no. 1 (January 1987): 56–58. http://dx.doi.org/10.1002/bbpc.19870910112.

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Ko, Sen-Hou, Robert H. Doremus, X. S. Guo, and William Landford. "Refractive index gradient in the surface of a zirconium fluoride glass by exchange with chlorine." Journal of Materials Research 5, no. 1 (January 1990): 202–5. http://dx.doi.org/10.1557/jmr.1990.0202.

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The refractive index of the surface of a zirconium fluoride glass was increased by exchanging fluorine in the glass with gaseous chlorine. The chlorine profile in the glass surface, as measured by Rutherford backscattering, was that expected for diffusion. The refractive index change was measured with ellipsometry, and compared to models of the concentration profile of chlorine.
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Chen, Siyan, Zhengqing Zhou, Yong Ma, Li Zhang, Tianyi Wang, Shihao Wang, and Yinghua Zhang. "Study on Hazardous Areas of Hydrogen Fluoride Diffusion Based on CFD Simulation." Processes 9, no. 9 (August 30, 2021): 1545. http://dx.doi.org/10.3390/pr9091545.

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Hydrogen fluoride (HF) is a typical dangerous gas in the fluorine chemical industry. Its leakage is one of the most common types of accidents in this industry, and it poses a serious threat to personnel safety and health, environmental sanitation, and social stability. In this paper, the process and consequences of an HF leakage accident in a fluorine chemical plant were simulated by using computational fluid dynamics (CFD) simulation software, and hazardous areas (lethal area, severe injury area, light injury area, and maximum allowable concentration area) of HF diffusion were determined according to the HF concentration corresponding to the degree of personal injury. Moreover, the effects of wind speed and height on hazardous areas were analyzed. The research results of this paper provide model support for similar enterprises to predict the consequences of harmful gas leakage accidents, and give suggestions on emergency evacuation and rescue work, which have practical application significance.
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Noda, Taiji. "Fluorine-enhanced boron diffusion induced by fluorine postimplantation in silicon." Journal of Applied Physics 96, no. 7 (October 2004): 3721–26. http://dx.doi.org/10.1063/1.1784618.

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Balcone-Boissard, Hélène, Don R. Baker, Benoit Villemant, Jean Cauzid, Georges Boudon, and E. Deloule. "Br diffusion in phonolitic melts: Comparison with fluorine and chlorine diffusion." American Mineralogist 105, no. 11 (November 1, 2020): 1639–46. http://dx.doi.org/10.2138/am-2020-7372.

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Abstract Bromine diffusion was measured in two natural phonolitic melts: (1) a K2O-rich (~10 wt%) one synthesized from the white pumice phase of the 79 AD eruption of Vesuvius (Italy), and (2) a Na2O-rich (~10 wt%) one corresponding to the most differentiated melt of the 12 000 BC eruption of the Laacher See (Germany). Experiments were performed at 0.5 and 1.0 GPa, 1250 to 1450 °C, at anhydrous and hydrous (2.65 ± 0.35 wt% of dissolved water) conditions. Experiments conducted with the diffusion-couple technique in the piston cylinder were performed with only bromine diffusing and with the simultaneous diffusion of a halogen mixture (F, Cl, Br) to evaluate the interactions between the halogens during diffusion. The diffusion profiles of Br were measured by X-ray fluorescence using synchrotron radiation microprobe (SYXRF), ID18F, at the European Synchrotron Radiation Facility (ESRF, France). Bromine diffusion displays Arrhenian behavior under anhydrous conditions that is similar when it diffuses alone and when it diffuses with F and Cl. The Br diffusion coefficients range between 2 × 10–12 m2/s at 1250 °C and 1.5 × 10–11 m2/s at 1450 °C for the Na-rich melt and between 3 × 10–12 m2/s at 1250 °C and 2.5 × 10–11 m2/s at 1450 °C for the K-rich melt, at 1.0 GPa. Although Br mobility is independent of F and Cl in anhydrous phonolitic melts, its behavior may be dependent on the dominant alkali in the melt, as previously observed for Cl, but not F. For hydrous experiments, although the data are scattered, the Br diffusivity increases slightly with water and the Na/K ratio seems to influence Br diffusivity. Similarly to noble gases, halogen diffusivity at a given temperature in the phonolitic melts appears related to the ionic porosity of the silicate structure. Compared to basaltic melt, Br diffusivities are approximately one order of magnitude lower in the Na-phonolite melt, because of the difference of the pre-exponential factor. Br mobility appears to be decoupled from melt viscosity, considering the results here.
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Dissertations / Theses on the topic "Fluorine diffusion"

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Robison, Robert Russell. "Simulation of fluorine-diffusion behavior and boron-fluorine co-interaction in silicon." [Gainesville, Fla.] : University of Florida, 2006. http://purl.fcla.edu/fcla/etd/UFE0013790.

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Jin, Jian-Yue. "Fluorine Adsorption and Diffusion in Polycrystalline Silica." Thesis, University of North Texas, 1998. https://digital.library.unt.edu/ark:/67531/metadc277986/.

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The measurement of fluorine penetration into archeological flint artifacts using Nuclear Reaction Analysis (NRA) has been reported to be a potential dating method. However, the mechanism of how fluorine is incorporated into the flint surface, and finally transported into the bulk is not well understood. This research focuses on the study of the fluorine uptake phenomenon of flint mineral in aqueous fluoride solutions. Both theoretical and experimental approaches have been carried out. In a theoretical approach, a pipe-diffusion model was used to simulate the complicated fluorine transportation problem in flint, in which several diffusion mechanisms may be involved.
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Gao, Chun. "19F DOSY Diffusion NMR Spectroscopy of Fluoropolymers." University of Akron / OhioLINK, 2015. http://rave.ohiolink.edu/etdc/view?acc_num=akron1447069266.

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Kham, Man Niang. "Reduced boron diffusion under point defect injection in fluorine implanted silicon." Thesis, University of Southampton, 2007. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.443049.

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Gaschen, Annina Alice-Maria. "Relevance of fluorine diffusion for exposure age dating in archeological bones and teeth /." [S.l.] : [s.n.], 2005. http://www.zb.unibe.ch/download/eldiss/05gaschen_a.pdf.

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El, Mubarek Huda Abdel Wahab Abdel Rahim. "Suppression of boron transient enhanced and thermal diffusion in silicon and silicon germanium by fluorine implantation." Thesis, University of Southampton, 2004. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.419196.

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Girard-Alcindor, Valerian. "Above barrier narrow resonances in fluorine-15." Thesis, Normandie, 2020. http://www.theses.fr/2020NORMC209.

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L’étude des noyaux non liés permet de tester notre compréhension du noyau atom- ique dans des conditions extrêmes. Dans cette thèse nous avons analysé deux expériences distinctes réalisées au GANIL au cours desquels nous avons étudié le fluor 15 situé deux neutrons au delà de la drip-line proton. Une des particularités intéressante de ce noyau est la présence d’états de parité négative particulièrement étroits et situés au dessus des barrières Coulombiennes et centrifuges. Nous nous sommes intéressés dans ce travail à ces états, nous avons confirmé l’existence du second état excité 1/2- et avons observé deux nouveaux états, un état 5/2- et un état 3/2- en mesurant leur décroissance par émission d’un ou de deux protons. Nous avons discuté la structure de ces états et avons tenté d’expliquer l’asymétrie observée entre l’état 3/2- du fluor 15 et son analogue dans le carbone 15. Nous avons détaillé aussi la possibilité d’observer des décroissances gammas entre états non-liés
The study of unbound nuclei beyond the drip-lines allows us to test our understand- ing of the atomic nucleus under extreme conditions. In this thesis, we have analyzed two separate GANIL experiments in which fluorine 15, located two proton beyond the proton drip-line, was studied. One of the interesting particularity of this nucleus is the presence of particularly narrow negative parity states, above the Coulomb and centrifugal barriers. In this work, we were interested in theses states. We have confirmed the existence of the second excited state 1/2- and have observed two new states, a 5/2- state and a 3/2- state by measuring their decay by emitting either one or two protons. The structure of these states has been discussed and we have tried to explain the origin of the asymmetry observed between the 3/2- state of fluorine 15 and its analogue state in carbon 15. We have also detailed the possibility of gamma transitions between unbound states
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Diebel, Milan. "Application of ab-initio calculations to modeling of nanoscale diffusion and activation in silicon /." Thesis, Connect to this title online; UW restricted, 2004. http://hdl.handle.net/1773/9727.

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Evangelakis, Georgios A. "Superconducteurs ioniques de structure fluorine : A) mesure de la conductivité ionique du fluorure de strontium : B) étude des propriétés thermodynamiques du fluorure de calcium par simulation numérique." Nancy 1, 1989. http://www.theses.fr/1989NAN10311.

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Dans ce travail nous présentons les résultats d'une étude expérimentale de la conductivité ionique du fluorure de strontium, ainsi que ceux d'une investigation des propriétés thermodynamiques du fluorure de calcium dans le domaine de conduction superionique par simulation à l'aide de la dynamique moléculaire. Les mesures de la conductivité ionique du fluorure de strontium ont été effectuées à haute température (700-1350 K) en fonction de la fréquence du champ électrique utilisé (10 HZ-10 MHZ). Pour toutes les températures exploitées, nous avons trouvé une dépendance de la conductivité en fonction de la fréquence. L'analyse des résultats au moyen de diagrammes d'impédance complexe a montré que cette dépendance est due aux mauvais contacts entre l'échantillon et les électrodes. L'utilisation de ces diagrammes a permis de déterminer la conductivité intrinsèque du matériau. Des diagrammes d'arrhenius pour la conductivité nous avons pu déterminer les énergies d'activation apparentes pour les différentes régions de conduction. Celles-ci ne permettent malheureusement pas d'identifier les mécanismes atomiques de superconductivité ionique. La simulation par la dynamique moléculaire (DM) du fluorure de calcium a été effectuée en utilisant un potentiel d'ions rigides. Nous avons calculé la constante de diffusion, le facteur de structure, la chaleur spécifique, le déplacement quadratique moyen et leur variation en fonction de la température. Les résultats sont en bon accord avec l'expérience, ce qui justifie à postériori le choix du potentiel. En utilisant la DM hors d'équilibre dans la région de réponse linéaire, la superconductivité ionique du fluorure de calcium a pu être obtenue. Les calculs indépendants de la conductivité et la constante de diffusion, fournissent le rapport de Haven, HR 0. 34, dans la région supérionique. Cette valeur suggère que la superconductivité ionique de ce matériau est due à un mécanisme collectif et corrélé ce qui est confirmé par l'analyse des trajectoires des particules
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Meiler, Michael Rudolf. "In Vivo Characterization of RIF-1 Tumors via Diffusion and Fluorine-19 NMR Methods." Link to electronic version, 1999. http://www.wpi.edu/Pubs/ETD/Available/etd-100999-170738/.

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Books on the topic "Fluorine diffusion"

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Attiah, Abdul-Redha Dinar. Diffusion of tritium in neutron irradiated lithium fluoride and lithium carbonate. Salford: University of Salford, 1992.

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Book chapters on the topic "Fluorine diffusion"

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Winkelmann, Jochen. "Self-diffusion coefficient of fluorine." In Diffusion in Gases, Liquids and Electrolytes, 492. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-540-73735-3_305.

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Winkelmann, Jochen. "Self-diffusion coefficient of dodecahydro-fluorene." In Diffusion in Gases, Liquids and Electrolytes, 395. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-540-73735-3_236.

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Winkelmann, Jochen. "Self-diffusion coefficient of deuterium fluoride." In Diffusion in Gases, Liquids and Electrolytes, 470–72. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-540-73735-3_298.

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Winkelmann, Jochen. "Self-diffusion coefficient of hydrogen fluoride." In Diffusion in Gases, Liquids and Electrolytes, 489–91. Berlin, Heidelberg: Springer Berlin Heidelberg, 2017. http://dx.doi.org/10.1007/978-3-540-73735-3_304.

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Cherniak, D. J. "19. Diffusion in Carbonates, Fluorite, Sulfide Minerals, and Diamond." In Diffusion in Minerals and Melts, edited by Youxue Zahng and Daniele J. Cherniak, 871–98. Berlin, Boston: De Gruyter, 2010. http://dx.doi.org/10.1515/9781501508394-020.

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"Dl 2 Values for Lithium Ion Diffusion in Graphite Fluoride Electrode." In Fluorine-Carbon and Fluoride-Carbon Materials, 266–69. CRC Press, 1994. http://dx.doi.org/10.1201/9781482293562-52.

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DANESI, P., A. MEHDAOUI, J. C. PERUCHETTI, D. BOLMONT, and B. LOEGEL. "A SPECTROSCOPIC STUDY OF FLUORINE DIFFUSION IN Y-Ba-Cu MULTILAYERS." In High Tc Superconductor Thin Films, 801–5. Elsevier, 1992. http://dx.doi.org/10.1016/b978-0-444-89353-6.50129-9.

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Herbert, Bruce E., and Paul M. Bertsch. "A 19F and 2H NMR Spectroscopic Investigation of the Interaction Between Nonionic Organic Contaminants and Dissolved Humic Material." In Nuclear Magnetic Resonance Spectroscopy in Environment Chemistry. Oxford University Press, 1997. http://dx.doi.org/10.1093/oso/9780195097511.003.0009.

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Interaction between nonionic organic contaminants (NOC) and natural organic matter strongly influences the fate and transport of NOC in the environment. Microscopic descriptions of NOC-organic matter interaction have been developed based on macroscopic observations of NOC sorption to organic matter and organic solute transport under varying conditions. These models include the partitioning concept describing NOC sorption to organic matter and the concept of intra-organic matter diffusion used to account for nonequilibrium organic solute transport; however, little microscopic information exists to validate them. NMR may be a powerful method to gain information and insight concerning NOC-organic matter interaction. Chemical shifts, linewidths, and the magnitude of spin-spin couplings exhibited in the NMR spectra of a given nucleus are dependent on the characteristics of the surrounding media and therefore can be used to study the NOC-organic matter interaction. NMR characterization of the chemical interaction between NOC and organic matter can potentially provide information on important aspects of the sorption mechanism. This information may be useful to explain the influence of organic matter characteristics on NOC sorption and the mechanisms controlling nonequilibrium sorption of NOC to organic matter and mineral phases, and to evaluate different conceptual models of natural humic material, including the polymer concept, where humics are considered to be flexible linear polyelectrolytes, and the micelle concept, which considers humics to be aggregates of simple organic compounds, oligomers, and humic molecules ultimately forming micellar-type structures. NMR has been used to study the interactions of small organic solutes with macromolecules and organized organic assemblies. Fluorine-19 NMR has been particularly useful to study these interactions because this magnetically active nucleus is 100% abundant, has a high sensitivity (83% of 1H) and large chemical shift range, and exhibits no background signal. Several NMR studies have followed the interactions between fluorinated anesthetics and phospholipids, sodium dodecyl sulfate (SDS) micelles, and intact rabbit brain tissue. Generally, these studies have indicated both that sorption sites are less polar than aqueous solutions and that there is decreased mobility of the sorbed solute. Fluorine-19 NMR has also been used to characterize the interactions between fluorine-containing ligands, such as fluorotryptophan, and human serum albumin (HSA).
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Yanaka, Takaaki. "Sampling of Hydrogen Fluoride by Diffusional Transport in a Circular Glass Tube Coated with Sodium Carbonate." In Fluoride Research 1985 - Selected Papers from the 14th Conference of the International Society for Fluoride Research, 81–88. Elsevier, 1986. http://dx.doi.org/10.1016/s0166-1116(08)71830-2.

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Conference papers on the topic "Fluorine diffusion"

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Zhang, Kai, Xiaozhi Yang, Hanyong Liu, Jannick Ingrin, and Baohua Zhang. "Chemical diffusion of fluorine in phlogopite." In Goldschmidt2022. France: European Association of Geochemistry, 2022. http://dx.doi.org/10.46427/gold2022.9897.

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Kirchhof, J., S. Unger, and K. F. Klein. "Diffusion behavior of fluorine in fiber-lightguide materials." In Optical Fiber Communication Conference. Washington, D.C.: OSA, 1993. http://dx.doi.org/10.1364/ofc.1993.wg4.

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Shayesteh, M., V. Djara, M. Schmidt, M. White, A. M. Kelleher, and Ray Duffy. "Fluorine implantation in germanium for dopant diffusion control." In ION IMPLANTATION TECHNOLOGY 2012: Proceedings of the 19th International Conference on Ion Implantation Technology. AIP, 2012. http://dx.doi.org/10.1063/1.4766503.

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Jinyu Zhang, Y. Ashizawa, and H. Oka. "Modeling and Simulation of Fluorine Related Diffusion in Silicon." In 2006 International Workshop on Junction Technology. IEEE, 2006. http://dx.doi.org/10.1109/iwjt.2006.220859.

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Yuan, Li, Maojun Wang, and Kevin J. Chen. "Atomistic modeling of fluorine implantation and diffusion in III-nitride semiconductors." In 2008 IEEE International Electron Devices Meeting (IEDM). IEEE, 2008. http://dx.doi.org/10.1109/iedm.2008.4796746.

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Impellizzeri, G., S. Mirabella, M. G. Grimaldi, F. Priolo, F. Giannazzo, V. Raineri, E. Napolitani, and A. Carnera. "Boron Diffusion and Electrical Activation in Pre-Amorphized Si Enriched with Fluorine." In 2007 15th International Conference on Advanced Thermal Processing of Semiconductors. IEEE, 2007. http://dx.doi.org/10.1109/rtp.2007.4383823.

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Noda, T., S. Felch, V. Parihar, C. Vrancken, T. Janssens, H. Bender, B. Van Daele, and W. Vandervorst. "Impact of Fluorine co-implant on Boron Diffusion during Non-melt Laser Annealing." In ION IMPLANTATION TECHNOLOGY: 16th International Conference on Ion Implantation Technology - IIT 2006. AIP, 2006. http://dx.doi.org/10.1063/1.2401452.

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Miakonkikh, Andrey V., Aleksander E. Rogozhin, Valeriy I. Rudakov, Konstantin V. Rudenko, and Vladimir F. Lukichev. "Carbon and fluorine co-implantation for boron diffusion suppression in extremely ultra shallow junctions." In The International Conference on Micro- and Nano-Electronics 2014, edited by Alexander A. Orlikovsky. SPIE, 2014. http://dx.doi.org/10.1117/12.2181006.

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Shigemasu, Shogo, Hideaki Tanimura, Hikaru Kawarazaki, and Shinichi Kato. "Forming Low-Resistivity Tungsten Contacts and Avoiding Fluorine Diffusion by Flash Lamp Annealing (FLA)." In 2021 5th IEEE Electron Devices Technology & Manufacturing Conference (EDTM). IEEE, 2021. http://dx.doi.org/10.1109/edtm50988.2021.9421021.

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Hara, M., T. Masuzumi, L. Zhiming, C. Kimura, H. Aoki, and T. Sugino. "Suppression of Fluorine Diffusion into Low-k Material (Methyl-BCN) using Low Temperature Etching." In 2009 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 2009. http://dx.doi.org/10.7567/ssdm.2009.p-2-3.

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