Journal articles on the topic 'Fluid assisted metamorphism'
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Touret, Jacques L. R., and Jan Marten Huizenga. "Fluid-assisted granulite metamorphism: A continental journey." Gondwana Research 21, no. 1 (January 2012): 224–35. http://dx.doi.org/10.1016/j.gr.2011.07.022.
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Admou, Safouane, Yannick Branquet, Lakhlifi Badra, Luc Barbanson, Mohamed Outhounjite, Abdelali Khalifa, Mohamed Zouhair, and Lhou Maacha. "The Hajjar Regional Transpressive Shear Zone (Guemassa Massif, Morocco): Consequences on the Deformation of the Base-Metal Massive Sulfide Ore." Minerals 8, no. 10 (October 7, 2018): 435. http://dx.doi.org/10.3390/min8100435.
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The genesis of the base-metal massive sulfide deposits hosted within the Moroccan Hercynian Jebilet and Guemassa Massifs is still under debate. No consensus currently exists between the two models that have been proposed to explain the deposits, i.e., (1) syngenetic volcanogenic massive sulfide mineralization, and (2) synmetamorphic tectonic fluid-assisted epigenetic mineralization. Conversely, researchers agree that all Hercynian massive sulfide deposits in Morocco are deformed, even though 3D structural mapping at the deposit scale is still lacking. Therefore, while avoiding the use of a model-driven approach, the main aim of this contribution is to establish a first-order structural pattern and the controls of the Hajjar base metal deposit. We used a classical structural geology toolbox in surface and subsurface mining work to image finite strain at different levels. Our data demonstrate that: i) the Hajjar area is affected by a single foliation plane (not two) which developed during a single tectonic event encompassing a HT metamorphism. This syn-metamorphic deformation is not restricted to the Hajjar area, as it is widespread at the western Meseta scale, and it occurred during Late Carboniferous times; ii) the Hajjar ore deposit is hosted within a regional transpressive right-lateral NE-trending shear zone in which syn- to post-metamorphic ductile to brittle shear planes are responsible for significant inflexion (or virgation) of the foliation yielding an anastomosing pattern within the Hajjar shear zone. Again, this feature is not an exception, as various Late Carboniferous-Permian regional scale wrenching shear zones are recognized throughout the Hercynian Meseta orogenic segment. Finally, we present several lines of evidence emphasizing the role of deformation in terms of mechanical and fluid-assisted ore concentrations.
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Li, Yang, Ai-Cheng Zhang, Jia-Ni Chen, Li-Xin Gu, and Ru-Cheng Wang. "Formation of phosphorus-rich olivine in Dar al Gani 978 carbonaceous chondrite through fluid-assisted metamorphism." American Mineralogist 102, no. 1 (January 2017): 98–107. http://dx.doi.org/10.2138/am-2017-5881.
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Whittington, A. G., and P. J. Treloar. "Crustal anatexis and its relation to the exhumation of collisional orogenic belts, with particular reference to the Himalaya." Mineralogical Magazine 66, no. 1 (February 2002): 53–91. http://dx.doi.org/10.1180/0026461026610015.
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AbstractWe review the causes, mechanisms and consequences of crustal anatexis during the exhumation of metamorphic terranes, from a petrological perspective. During both prograde and retrograde metamorphism, limited influx of free hydrous fluids may result in small volumes of very hydrous melts, which cannot ascend far (if at all) before reaching their solidus. If thermal conditions for dehydration melting are attained in fertile micaceous crustal layers, much larger volumes of water-undersaturated granitic magmas may result, especially where limited external fluid influx raises water activities above those that may be buffered by dehydrating hydrous phases. Magmas have specific trace element characteristics depending on the reaction which formed them which, combined with accessory phase thermometry, may enable the (P-T) conditions of melting to be ascertained. Small volume-fraction magmas will typically remain as in situ migmatites unless their extraction is assisted by deformation. In turn, deformation will be focused in weaker partially molten zones, so that water-undersaturated magmas may often be mobilized. Once segregated, their ascent is limited by the rate of dyke propagation, and they may reach shallow levels (<2 kbar) before crystallizing. The complex interplay between deformation and melting is exemplified by the Miocene evolution of the central Himalaya, where thrust and normal faulting, melting and exhumation were all simultaneously active processes which were linked by feedback relations. In the Nanga Parbat Massif of the western Himalaya, rapid post-Miocene denudation and vigorous fluid flux enabled rocks to experience more than one episode of melting simultaneously, at different levels of the same exhuming crustal section.
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Fornelli, Annamaria, Vincenzo Festa, Francesca Micheletti, Richard Spiess, and Fabrizio Tursi. "Building an Orogen: Review of U-Pb Zircon Ages from the Calabria–Peloritani Terrane to Constrain the Timing of the Southern Variscan Belt." Minerals 10, no. 11 (October 23, 2020): 944. http://dx.doi.org/10.3390/min10110944.
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The application of zircon dating to the reconstruction of orogenic systems is invaluable since time constraints of the geological evolution of orogens are crucial for the proposal of geodynamic and paleogeographic models. Zircon is one of the most promising accessory minerals in geochronology of crystalline basements because of its high-closure temperature. Moreover, U-Pb data of relict and recrystallized grains indicate the maximum sedimentation age as well as the timing of metamorphism in metasediments. In addition, the U-Pb ages of magmatic zircons constrain the timescale of magmatism. The Calabria–Peloritani terrane (CPT) represents a key area in the Southern Variscan Belt, whose reconstruction is still unresolved. Therefore, a review of literature zircon age data accompanied with new data from six samples of orthogneisses, paragneisses, amphibolites, and actinolite schists, helps to constrain the evolution of this Cadomian fragment, affected by metamorphic and magmatic Variscan events. A revisiting of the timing of the geological events from Paleo-proterozoic to Permian is revealed by comparing the internal textures of zircons and their U-Pb age clusters. The detected age peaks at 2500 Ma, 1600 Ma, and 1000 Ma in the CPT were related to a provenance from West and East Gondwana realms. A sedimentation age around 630 Ma emerges for the middle-deep crust terranes of the CPT, affected by Ediacaran (579–540 Ma) intrusions, accompanied by metamorphism dated at 556–509 Ma in the host metasediments. In the following, during Ordovician–Silurian extensional tectonics, the former Cadomian terranes were at least locally affected by fluid-assisted metamorphism (around 450 Ma) whereas the upper extensional basins that formed, were infilled by sediments along with interspersed volcanic to subvolcanic products. All these pre-Silurian terranes were involved in the subduction process of the Palaeotethys–Gondwana margin beneath Laurussia. The compressive phase began around 347 Ma, with under-thrusting of the formerly Gondwana substrate that was subjected to middle-high grade metamorphism, while the Ordovician–Silurian sediments were scraped off along the front of the Southern Variscan Belt and affected by low-grade metamorphism. Decompression of the whole Variscan orogenic system started around 320 Ma, together with uplifting of the chain and emplacement of widespread granitic intrusions which ended around 280 Ma and completed the Variscan orogenic cycle in the CPT.
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Vacher, Lionel G., and Wataru Fujiya. "Recent Advances in our Understanding of Water and Aqueous Activity in Chondrites." Elements 18, no. 3 (June 1, 2022): 175–80. http://dx.doi.org/10.2138/gselements.18.3.175.
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Water played a critical role in the evolution of rocky material and planetesimals in the early Solar System. Many primitive asteroids (the sources of chondrites) accreted a significant amount of water ice and were affected by aqueous alteration and/or fluid-assisted metamorphism. These secondary parent body processes have strongly modified the primary mineralogy of chondrites in favor of a wide diversity of secondary phases that formed by interaction with water. The mineralogical and isotopic characterization of these secondary phases in chondrites and returned samples from hydrous asteroids Ryugu and Bennu can help us reconstruct the dynamical evolution of water in the early Solar System and understand the timing and mechanisms of aqueous alteration on hydrous asteroids.
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Didier, A., V. Bosse, Z. Cherneva, P. Gautier, M. Georgieva, J. L. Paquette, and I. Gerdjikov. "Syn-deformation fluid-assisted growth of monazite during renewed high-grade metamorphism in metapelites of the Central Rhodope (Bulgaria, Greece)." Chemical Geology 381 (August 2014): 206–22. http://dx.doi.org/10.1016/j.chemgeo.2014.05.020.
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Hoerlle, Guilherme Sonntag, Marcus Vinicius Dorneles Remus, and Norberto Dani. "Metamafic dyke and sill swarms in the Dom Feliciano Belt: Insights for post-collisional strike-slip tectonics and fluid-assisted metamorphism." Precambrian Research 383 (December 2022): 106906. http://dx.doi.org/10.1016/j.precamres.2022.106906.
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Tursi, Fabrizio. "The key role of µH2O gradients in deciphering microstructures and mineral assemblages of mylonites: examples from the Calabria polymetamorphic terrane." Mineralogy and Petrology 116, no. 1 (October 20, 2021): 1–14. http://dx.doi.org/10.1007/s00710-021-00766-8.
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AbstractA careful petrologic analysis of mylonites’ mineral assemblages is crucial for a thorough comprehension of the rheologic behaviour of ductile shear zones active during an orogenesis. In this view, understanding the way new minerals form in rocks sheared in a ductile manner and why relict porphyroblasts are preserved in zones where mineral reactions are generally supposed to be deformation-assisted, is essential. To this goal, the role of chemical potential gradients, particularly that of H2O (µH2O), was examined here through phase equilibrium modelling of syn-kinematic mineral assemblages developed in three distinct mylonites from the Calabria polymetamorphic terrane. Results revealed that gradients in chemical potentials have effects on the mineral assemblages of the studied mylonites, and that new syn-kinematic minerals formed in higher-µH2O conditions than the surroundings. In each case study, the banded fabric of the mylonites is related to the fluid availability in the system, with the fluid that was internally generated by the breakdown of OH-bearing minerals. The gradients in µH2O favoured the origin of bands enriched in hydrated minerals alternated with bands where anhydrous minerals were preserved even during exhumation. Thermodynamic modelling highlights that during the prograde stage of metamorphism, high-µH2O was necessary to form new minerals while relict, anhydrous porphyroblasts remained stable in condition of low-µH2O even during exhumation. Hence, the approach used in this contribution is an in-depth investigation of the fluid-present/-deficient conditions that affected mylonites during their activity, and provides a more robust interpretation of their microstructures, finally helping to explain the rheologic behaviour of ductile shear zones.
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Kapsiotis, Argyrios. "Composition and alteration of Cr-spinels from Milia and Pefki serpentinized mantle peridotites (Pindos Ophiolite Complex, Greece)." Geologica Carpathica 65, no. 1 (February 1, 2014): 83–95. http://dx.doi.org/10.2478/geoca-2013-0006.
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Abstract The Pindos Ophiolite rocks include variably serpentinized peridotites derived from a harzburgitic and subordinately dunitic mantle. In the serpentinized matrix of these rocks pseudomorphic (mesh, bastite) and non-pseudomorphic (interpenetrating, type-2 hourglass) textures were recognized. Chromian spinel (Cr-spinel) is anhedral to subhedral and often replaced by a porous opaque phase. Chemistry data show that Cr-spinel cores retain their original composition, having Cr#[Cr/(Cr + Al)] that ranges between 0.45 and 0.73, and Mg#[Mg/(Mg + Fe2+)] that varies between 0.52 and 0.65, accompanied by low content in TiO2 ( < 0.11wt. %). The relatively wide variation of their Cr# values reflects that the studied peridotites were produced by variable degrees of melting. It is likely that the Pindos peridotites represent mantle residues originally formed in a mid-ocean ridge (MOR) environment, which were subsequently entrapped as part of a mantle wedge above a supra-subduction zone (SSZ) regime. Cr-spinel adjacent to clinochlore systematically displays limited compositional and textural zoning along grain boundaries and fractures. However, the degree of peridotite serpentinization does not correlate with the abundance of zoning effects in accessory Cr-spinel. Thus, Cr-spinel zoning is thought to represent a secondary feature obtained during the metamorphic evolution of the host peridotites. Core to rim compositional trends are expressed by MgO and Al2O3 impoverishment, mainly compensated by Cr2O3 and FeO increases. Such chemical trends are produced as a result of Cr-spinel re-equilibration with the surrounding serpentine, and their subsequent replacement by ferrian (Fe3+-rich) chromite and clinochlore, respectively, during a brief, fluid assisted, greenschist facies metamorphism episode (T > 300 °C). The limited occurrence of ferrian chromite with high Fe3+# values suggests that elevated oxidizing conditions were prevalent only on a local scale during Cr-spinel alteration
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Ziemniak, Grzegorz, Karolina Kośmińska, Igor Petrík, Marian Janák, Katarzyna Walczak, Maciej Manecki, and Jarosław Majka. "Th–U–total Pb monazite geochronology records Ordovician (444 Ma) metamorphism/partial melting and Silurian (419 Ma) thrusting in the Kåfjord Nappe, Norwegian Arctic Caledonides." Geologica Carpathica 70, no. 6 (December 1, 2019): 494–511. http://dx.doi.org/10.2478/geoca-2019-0029.
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Abstract The northern extent of the Scandinavian Caledonides includes the Skibotn Nappe Complex of still debated structural position. This paper is focused on part of this complex and presents new U–Th–total Pb monazite dating results for the migmatitic gneiss of the Kåfjord Nappe. The rocks show mineral assemblage of garnet + plagioclase + biotite + white mica + kyanite + rutile ± K-feldspar ± sillimanite. Thermodynamic modelling suggests that garnet was stable at P–T conditions of ca. 680–720 °C and 8–10 kbars in the stability field of kyanite and the rocks underwent partial melting during exhumation following a clockwise P–T path. This episode is dated to 444 ± 12 Ma using chemical Th–U–total Pb dating of the Y-depleted monazite core. Second episode highlighted by growth of secondary white mica resulted from subsequent overprint in amphibolite and greenschist facies. Fluid assisted growth of the Y-enriched monazite rim at 419 ± 8 Ma marks the timing of the nappe emplacement. Age of migmatization and thrusting in the Kåfjord Nappe is similar to the Kalak Nappe Complex, and other units of the Middle Allochthon to the south. Nevertheless, the obtained results do not allow for unambiguous definition of the tectonostratigraphic position of the Skibotn Nappe Complex.
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Aléon, Jérôme, Alice Aléon-Toppani, Bernard Platevoet, Jacques-Marie Bardintzeff, Kevin D. McKeegan, and François Brisset. "Alkali magmatism on a carbonaceous chondrite planetesimal." Proceedings of the National Academy of Sciences 117, no. 15 (March 30, 2020): 8353–59. http://dx.doi.org/10.1073/pnas.1919550117.
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Recent isotopic and paleomagnetic data point to a possible connection between carbonaceous chondrites and differentiated planetary materials, suggesting the existence, perhaps ephemeral, of transitional objects with a layered structure whereby a metal-rich core is enclosed by a silicate mantle, which is itself overlain by a crust containing an outermost layer of primitive solar nebula materials. This idea has not received broad support, mostly because of a lack of samples in the meteoritic record that document incipient melting at the onset of planetary differentiation. Here, we report the discovery and the petrologic–isotopic characterization of UH154-11, a ferroan trachybasalt fragment enclosed in a Renazzo-type carbonaceous chondrite (CR). Its chemical and oxygen isotopic compositions are consistent with very-low-degree partial melting of a Vigarano-type carbonaceous chondrite (CV) from the oxidized subgroup at a depth where fluid-assisted metamorphism enhanced the Na content. Its microdoleritic texture indicates crystallization at an increasing cooling rate, such as would occur during magma ascent through a chondritic crust. This represents direct evidence of magmatic activity in a carbonaceous asteroid on the verge of differentiating and demonstrates that some primitive outer Solar System objects related to icy asteroids and comets underwent a phase of magmatic activity early in the Solar System. With its peculiar petrology, UH154-11 can be considered the long-sought first melt produced during partial differentiation of a carbonaceous chondritic planetary body, bridging a previously persistent gap in differentiation processes from icy cometary bodies to fully melted iron meteorites with isotopic affinities to carbonaceous chondrites.
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Li, Jiahao, Xing Ding, and Junfeng Liu. "The Role of Fluids in Melting the Continental Crust and Generating Granitoids: An Overview." Geosciences 12, no. 8 (July 22, 2022): 285. http://dx.doi.org/10.3390/geosciences12080285.
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Granite is a distinctive constituent part of the continental crust on Earth, the formation and evolution of which have long been hot research topics. In this paper, we reviewed the partial melting processes of crustal rocks without or with fluid assistance and summarized the role of fluids and volatiles involved in the formation of granitic melts. As a conventional model, granitoids were thought to be derived from the dehydration melting of hydrous minerals in crustal basement metamorphic rocks in the absence of external fluids. However, the external-fluid-assisted melting of crustal metamorphic rocks has recently been proposed to produce granitoids as extensive fluids could be active in the deep continental crust, especially in the subduction zones. It has been demonstrated experimentally that H2O plays a crucial role in the partial melting of crustal rocks, in which H2O can (1) significantly lower the solidus temperature of the melted rocks to facilitate partial melting; (2) affect the melting reaction process, mineral stability, and the composition of melt; and (3) help the melt to separate more easily from the source area and aggregate to form a large-scale magma chamber. More importantly, dissolved volatiles and salts in the crustal fluids could also lower the solidus temperature of rocks, affect the partitioning behaviors of trace elements between minerals and melts, and facilitate the formation of some distinctive granitoids (e.g., B-rich, F-rich, and high-K granitoids). Furthermore, various volatiles dissolved in fluids could result in elemental or isotopic fractionation as well as the diversity of mineralization during fluid-assisted melting. In-depth studies regarding the fluid-assisted partial melting of crustal rocks will facilitate a more comprehensive understanding of melting of the Earth’s crust, thus providing strong theoretical constraints on the genesis and mineralization of granitoids as well as the formation and evolution of the continental crust.
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Hertwig, A., W. V. Maresch, and H. P. Schertl. "Jadeitite and Related Rocks in Serpentinite Mélanges from the Rio San Juan Complex, Dominican Republic: Evidence for Both Isochemical Replacement and Metasomatic Desilication of Igneous Protoliths with Fluid-Assisted Jadeite Growth." Russian Geology and Geophysics 62, no. 5 (May 1, 2021): 496–524. http://dx.doi.org/10.2113/rgg20204265.
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Abstract —This study presents an overview of the systematic petrography, mineralogy, and geochemistry of jadeitite and jadeite-rich rocks found as blocks in the serpentinite mélanges of the Rio San Juan Complex (RSJC) of the northern Dominican Republic. The RSJC is one of the remnants of the subduction/accretionary complex of the Great Caribbean Arc that once spanned the gap between North and South America, moved relatively eastward to its present position as the Lesser Antilles island arc, and left collisional fragments along the two continental margins. Our systematic collection of heterogeneous samples ranges from jadeitite s.str. (sensu stricto) with ≥90 vol.% jadeite to quartz-rich rocks with jadeite and lawsonite. Two suites of rock types can be recognized. In the matrix-quartz-free rock suite, albite is the principal vein-filling or interstitial phase. Quartz is present only as inclusions in the cores of some jadeite crystals. In the matrix-quartz-bearing rock suite, quartz is abundant and albite is relatively rare. The first-order question concerning jadeite-rich rocks is whether jadeite precipitated from a high-pressure aqueous fluid (“vein precipitation” or “P-type”) or whether the jadeite-rich rock formed through comprehensive metasomatic replacement of an igneous protolith (“R-type”). Some examples occur as discordant veins and are clearly P-type. For most, however, classification has been equivocal. The systematic data on the petrography and whole-rock chemistry of jadeite rocks from the RSJC presented in this paper leads to significant clarification. A major argument against R-type genesis is that the metasomatic mass transfer required to produce jadeitite and jadeite-rich rocks from any normal igneous protolith is prohibitively complex. Using whole-rock, major-element compositions, we show that many members of the matrix-quartz-bearing rock suite from the RSJC can be derived by isochemical HP/LT metamorphism of normal oceanic plagiogranites subducted together with oceanic crust. Isocon analysis shows, furthermore, that more jadeite-rich rock types and also members of the matrix-quartz-free suite can be derived from such plagiogranites primarily by straightforward desilication, a realistic scenario in a serpentine-rich environment. The quartz inclusions found in jadeite crystals of the matrix-quartz-free suite corroborate a genetic path in which the plagioclase in a plagiogranite protolith reacts to jadeite + quartz. Later desilication and the formation of albite in the Si-undersaturated rock matrix leave tell-tale quartz inclusions as relics in jadeite crystals.
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Harlaux, Matthieu, Kalin Kouzmanov, Stefano Gialli, Oscar Laurent, Andrea Rielli, Andrea Dini, Alain Chauvet, Andrew Menzies, Miroslav Kalinaj, and Lluís Fontboté. "Tourmaline as a Tracer of Late-Magmatic to Hydrothermal Fluid Evolution: The World-Class San Rafael Tin (-Copper) Deposit, Peru." Economic Geology 115, no. 8 (August 18, 2020): 1665–97. http://dx.doi.org/10.5382/econgeo.4762.
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Abstract The world-class San Rafael tin (-copper) deposit (central Andean tin belt, southeast Peru) is an exceptionally large and rich (>1 million metric tons Sn; grades typically >2% Sn) cassiterite-bearing hydrothermal vein system hosted by a late Oligocene (ca. 24 Ma) peraluminous K-feldspar-megacrystic granitic complex and surrounding Ordovician shales affected by deformation and low-grade metamorphism. The mineralization consists of NW-trending, quartz-cassiterite-sulfide veins and fault-controlled breccia bodies (>1.4 km in vertical and horizontal extension). They show volumetrically important tourmaline alteration that principally formed prior to the main ore stage, similar to other granite-related Sn deposits worldwide. We present here a detailed textural and geochemical study of tourmaline, aiming to trace fluid evolution of the San Rafael magmatic-hydrothermal system that led to the deposition of tin mineralization. Based on previous works and new petrographic observations, three main generations of tourmaline of both magmatic and hydrothermal origin were distinguished and were analyzed in situ for their major, minor, and trace element composition by electron microprobe analyzer and laser ablation-inductively coupled plasma-mass spectrometry, as well as for their bulk Sr, Nd, and Pb isotope compositions by multicollector-inductively coupled plasma-mass spectrometry. A first late-magmatic tourmaline generation (Tur 1) occurs in peraluminous granitic rocks as nodules and disseminations, which do not show evidence of alteration. This early Tur 1 is texturally and compositionally homogeneous; it has a dravitic composition, with Fe/(Fe + Mg) = 0.36 to 0.52, close to the schorl-dravite limit, and relatively high contents (10s to 100s ppm) of Li, K, Mn, light rare earth elements, and Zn. The second generation (Tur 2)—the most important volumetrically—is pre-ore, high-temperature (>500°C), hydrothermal tourmaline occurring as phenocryst replacement (Tur 2a) and open-space fillings in veins and breccias (Tur 2b) and microbreccias (Tur 2c) emplaced in the host granites and shales. Pre-ore Tur 2 typically shows oscillatory zoning, possibly reflecting rapid changes in the hydrothermal system, and has a large compositional range that spans the schorl to dravite fields, with Fe/(Fe + Mg) = 0.02 to 0.83. Trace element contents of Tur 2 are similar to those of Tur 1. Compositional variations within Tur 2 may be explained by the different degree of interaction of the magmatic-hydrothermal fluid with the host rocks (granites and shales), in part because of the effect of replacement versus open-space filling. The third generation is syn-ore hydrothermal tourmaline (Tur 3). It forms microscopic veinlets and overgrowths, partly cutting previous tourmaline generations, and is locally intergrown with cassiterite, chlorite, quartz, and minor pyrrhotite and arsenopyrite from the main ore assemblage. Syn-ore Tur 3 has schorl-foititic compositions, with Fe/(Fe + Mg) = 0.48 to 0.94, that partly differ from those of late-magmatic Tur 1 and pre-ore hydrothermal Tur 2. Relative to Tur 1 and Tur 2, syn-ore Tur 3 has higher contents of Sr and heavy rare earth elements (10s to 100s ppm) and unusually high contents of Sn (up to >1,000 ppm). Existence of these three main tourmaline generations, each having specific textural and compositional characteristics, reflects a boron-rich protracted magmatic-hydrothermal system with repeated episodes of hydrofracturing and fluid-assisted reopening, generating veins and breccias. Most trace elements in the San Rafael tourmaline do not correlate with Fe/(Fe + Mg) ratios, suggesting that their incorporation was likely controlled by the melt/fluid composition and local fluid-rock interactions. The initial radiogenic Sr and Nd isotope compositions of the three aforementioned tourmaline generations (0.7160–0.7276 for 87Sr/86Sr(i) and 0.5119–0.5124 for 143Nd/144Nd(i)) mostly overlap those of the San Rafael granites (87Sr/86Sr(i) = 0.7131–0.7202 and 143Nd/144Nd(i) = 0.5121–0.5122) and support a dominantly magmatic origin of the hydrothermal fluids. These compositions also overlap the initial Nd isotope values of Bolivian tin porphyries. The initial Pb isotope compositions of tourmaline show larger variations, with 206Pb/204Pb(i), 207Pb/204Pb(i), and 208Pb/204Pb(i) ratios mostly falling in the range of 18.6 to 19.3, 15.6 to 16.0, and 38.6 to 39.7, respectively. These compositions partly overlap the initial Pb isotope values of the San Rafael granites (206Pb/204Pb(i) = 18.6–18.8, 207Pb/204Pb(i) = 15.6–15.7, and 208Pb/204Pb(i) = 38.9–39.0) and are also similar to those of other Oligocene to Miocene Sn-W ± Cu-Zn-Pb-Ag deposits in southeast Peru. Rare earth element patterns of tourmaline are characterized, from Tur 1 to Tur 3, by decreasing (Eu/Eu*)N ratios (from 20 to 2) that correlate with increasing Sn contents (from 10s to >1,000 ppm). These variations are interpreted to reflect evolution of the hydrothermal system from reducing toward relatively more oxidizing conditions, still in a low-sulfidation environment, as indicated by the pyrrhotite-arsenopyrite assemblage. The changing textural and compositional features of Tur 1 to Tur 3 reflect the evolution of the San Rafael magmatic-hydrothermal system and support the model of fluid mixing between reduced, Sn-rich magmatic fluids and cooler, oxidizing meteoric waters as the main process that caused cassiterite precipitation.
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Müller, Axel, Morgan Ganerød, Michael Wiedenbeck, Skule Svendsen Spjelkavik, and Rune Selbekk. "The Hydrothermal Breccia of Berglia-Glassberget, Trøndelag, Norway: Snapshot of a Triassic Earthquake." Minerals 8, no. 5 (April 23, 2018): 175. http://dx.doi.org/10.3390/min8050175.
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The quartz-K-feldspar-cemented breccia of Berglia-Glassberget in the Lierne municipality in central Norway forms an ellipsoid structure 250 m × 500 m in size. The hydrothermal breccia is barren in terms of economic commodities but famous among mineral collectors for being a large and rich site of crystal quartz of various colours and habits. Despite being a famous collector site, the mineralization is rather unique in respect to its geological setting. It occurs within Late Palaeoproterozoic metarhyolites of the Lower Allochthon of the Norwegian Caledonides regionally isolated from any other contemporaneous hydrothermal or magmatic event. In order to understand better the formation of the Berglia-Glassberget breccia, the chemistry, fluid inclusion petrography and age of the breccia cement were determined. Structural features indicate that the Berglia-Glassberget is a fault-related, fluid-assisted, hydraulic breccia which formed by single pulse stress released by a seismic event. 40Ar-39Ar dating of K-feldspar cement revealed a middle Triassic age (240.3 ± 0.4 Ma) for this event. The influx into the fault zone of an aqueous CO2-bearing fluid triggered the sudden fault movement. The high percentage of open space in the breccia fractures with cavities up 3 m × 3 m × 4 m in size, fluid inclusion microthermometry, and trace element chemistry of quartz suggests that the breccia was formed at depths between 4 and 0.5 km (1.1 to 0.1 kbar). The origin of the breccia-cementing, CO2-bearing Na-HCO3-SO4 fluid may have been predominantly of metamorphic origin due to decarbonation reactions (T > 200 °C) of limestones of the underlying Olden Nappe. The decarbonation reactions were initiated by deeply derived, hot fluids channelled to sub-surface levels by a major fault zone, implying that the breccia is situated on a deep-seated structure. Regionally, the Berglia-Glassberget occurs at a supposed triple junction of long-lived fault zones belonging to the Møre-Trøndelag, Lærdal-Gjende and the Kollstraumen fault complexes. These fault systems and the associated Berglia-Glassberget earthquake are the expression of rifting and faulting in northern Europe during the middle/late Triassic.
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Soret, Mathieu, Philippe Agard, Benoît Ildefonse, Benoît Dubacq, Cécile Prigent, and Claudio Rosenberg. "Deformation mechanisms in mafic amphibolites and granulites: record from the Semail metamorphic sole during subduction infancy." Solid Earth 10, no. 5 (October 23, 2019): 1733–55. http://dx.doi.org/10.5194/se-10-1733-2019.
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Abstract. This study sheds light on the deformation mechanisms of subducted mafic rocks metamorphosed at amphibolite and granulite facies conditions and on their importance for strain accommodation and localization at the top of the slab during subduction infancy. These rocks, namely metamorphic soles, are oceanic slivers stripped from the downgoing slab and accreted below the upper plate mantle wedge during the first million years of intraoceanic subduction, when the subduction interface is still warm. Their formation and intense deformation (i.e., shear strain ≥5) attest to a systematic and transient coupling between the plates over a restricted time span of ∼1 Myr and specific rheological conditions. Combining microstructural analyses with mineral chemistry constrains grain-scale deformation mechanisms and the rheology of amphibole and amphibolites along the plate interface during early subduction dynamics, as well as the interplay between brittle and ductile deformation, water activity, mineral change, grain size reduction and phase mixing. Results indicate that increasing pressure and temperature conditions and slab dehydration (from amphibolite to granulite facies) lead to the nucleation of mechanically strong phases (garnet, clinopyroxene and amphibole) and rock hardening. Peak conditions (850 ∘C and 1 GPa) coincide with a pervasive stage of brittle deformation which enables strain localization in the top of the mafic slab, and therefore possibly the unit detachment from the slab. In contrast, during early exhumation and cooling (from ∼850 down to ∼700 ∘C and 0.7 GPa), the garnet–clinopyroxene-bearing amphibolite experiences extensive retrogression (and fluid ingression) and significant strain weakening essentially accommodated in the dissolution–precipitation creep regime including heterogeneous nucleation of fine-grained materials and the activation of grain boundary sliding processes. This deformation mechanism is closely assisted with continuous fluid-driven fracturing throughout the exhumed amphibolite, which contributes to fluid channelization within the amphibolites. These mechanical transitions, coeval with detachment and early exhumation of the high-temperature (HT) metamorphic soles, therefore controlled the viscosity contrast and mechanical coupling across the plate interface during subduction infancy, between the top of the slab and the overlying peridotites. Our findings may thus apply to other geodynamic environments where similar temperatures, lithologies, fluid circulation and mechanical coupling between mafic rocks and peridotites prevail, such as in mature warm subduction zones (e.g., Nankai, Cascadia), in lower continental crust shear zones and oceanic detachments.
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Hurai, Vratislav, Marian Janák, and Rainer Thomas. "Fluid-assisted retrogression of garnet and P–T history of metapelites from HP/UHP metamorphic terrane (Pohorje Mountains, Eastern Alps)." Contributions to Mineralogy and Petrology 160, no. 2 (December 15, 2009): 203–18. http://dx.doi.org/10.1007/s00410-009-0473-7.
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Galliski, Miguel Ángel, María Florencia Márquez-Zavalía, Encarnación Roda-Robles, and Albrecht von Quadt. "The Li-Bearing Pegmatites from the Pampean Pegmatite Province, Argentina: Metallogenesis and Resources." Minerals 12, no. 7 (June 30, 2022): 841. http://dx.doi.org/10.3390/min12070841.
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The Li-bearing pegmatites of the Pampean Pegmatite Province (PPP) occur in a rare-element pegmatite belt developed mainly in the Lower Paleozoic age on the southwestern margin of Gondwana. The pegmatites show Li, Rb, Nb ≤ Ta, Be, P, B, Bi enrichment, and belong to the Li-Cs-Ta (LCT) petrogenetic family, Rare-Element-Li (REL-Li) subclass; most of them are of complex type and spodumene subtype, some are of albite-spodumene type, and a few of petalite subtype. The origin of the pegmatites is attributed predominantly to fractionation of fertile S-type granitic melts produced by either fluid-absent or fluid-assisted anatexis of a thick pile of Gondwana-derived turbiditic sediments. Most of the pegmatites are orogenic (530–440 Ma) and developed during two overlapped collisional orogenies (Pampean and Famatinian); a few are postorogenic (~370 Ma), related to crustal contaminated A-type granites. The pegmatites were likely intruded in the hinterland, preferably in medium-grade metamorphic rocks with PT conditions ~200–500 MPa and 400–650 °C, where they are concentrated in districts and groups. Known combined resources add up 200,000 t of spodumene, with variable grades between 5 and 8 wt.% Li2O. The potential for future findings and enlargement of the resources is high, since no systematic exploration program has yet been developed.
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Holloway, M. I., F. Bussy, and T. W. Vennemann. "Low-pressure, water-assisted anatexis of basic dykes in a contact metamorphic aureole, Fuerteventura (Canary Islands): oxygen isotope evidence for a meteoric fluid origin." Contributions to Mineralogy and Petrology 155, no. 1 (July 6, 2007): 111–21. http://dx.doi.org/10.1007/s00410-007-0230-8.
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Viegas, G., L. Menegon, and C. J. Archanjo. "Brittle grain size reduction of feldspar, phase mixing and strain localization in granitoids at mid-crustal conditions (Pernambuco shear zone, NE Brazil)." Solid Earth Discussions 7, no. 4 (October 30, 2015): 2953–98. http://dx.doi.org/10.5194/sed-7-2953-2015.
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Abstract. The Pernambuco shear zone (northeastern Brazil) is a large-scale strike-slip fault that, in its eastern segment, deforms granitoids at mid-crustal conditions. Initially coarse (> 50 μm) grained feldspar porphyroclasts are intensively fractured and reduced to an ultrafine-grained mixture consisting of plagioclase and K-feldspar grains (~ < 15 μm in size) localized in C' shear bands. Detailed microstructural observations and EBSD analysis do not show evidence of intracrystalline plasticity in feldspar porphyroclasts and/or fluid-assisted replacement reactions. Quartz occurs either as thick (~ 1–2 mm) monomineralic bands or as thin ribbons dispersed in the feldspathic mixture. The microstructure and c axis crystallographic preferred orientation are similar in the thick monomineralic band and in the thin ribbons, and suggest dominant subgrain rotation recrystallization and activity of prism ⟨a⟩ and rhomb ⟨a⟩ slip systems. However, the grain size in monophase recrystallized domains decreases when moving from the transposed veins to the thin ribbons embedded in the feldspathic C' bands (14 μm vs. 5 μm, respectively). The fine-grained feldspar mixture has a weak crystallographic preferred orientation interpreted as the result of oriented growth during diffusion creep, as well as the same composition as the fractured porphyroclasts, suggesting that it generated by mechanical fragmentation of rigid porphyroclasts with a negligible role of chemical disequilibrium. Assuming that the C' shear bands deformed under constant stress conditions, the polyphase feldspathic aggregate would have deformed at a strain rate one order of magnitude faster than the monophase quartz ribbons. Overall, our dataset indicates that feldspar underwent a brittle-viscous transition while quartz was deforming via crystal plasticity. The resulting rock microstructure consists of a two-phase rheological mixture (fine-grained feldspars and recrystallized quartz) in which the polyphase feldspathic material localized much of the strain. Extensive grain-size reduction and weakening of feldspars is attained in the East Pernambuco mylonites mainly via fracturing under relatively fluid-absent conditions which would trigger a switch to diffusion creep and further strain localization without a prominent role of metamorphic reactions.
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Janssen, Martijn T. G., Auke Barnhoorn, Deyan Draganov, Karl-Heinz A. A. Wolf, and Sevket Durucan. "Seismic Velocity Characterisation of Geothermal Reservoir Rocks for CO2 Storage Performance Assessment." Applied Sciences 11, no. 8 (April 18, 2021): 3641. http://dx.doi.org/10.3390/app11083641.
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As part of a seismic monitoring project in a geothermal field, where the feasibility of re-injection and storage of produced CO2 is being investigated, a P- and S-wave seismic velocity characterisation study was carried out. The effect of axial (up to 95 MPa) and radial (up to 60 MPa) stress on the seismic velocity was studied in the laboratory for a broad range of dry sedimentary and metamorphic rocks that make up the Kızıldere geothermal system in Turkey. Thin section texture analyses conducted on the main reservoir formations, i.e., marble and calcschist, confirm the importance of the presence of fractures in the reservoir: 2D permeability increases roughly by a factor 10 when fractures are present. Controlled acoustic-assisted unconfined and confined compressive strength experiments revealed the stress-dependence of seismic velocities related to the several rock formations. For each test performed, a sharp increase in velocity was observed at relatively low absolute stress levels, as a result of the closure of microcracks, yielding an increased mineral-to-mineral contact area, thus velocity. A change in radial stress appeared to have a negligible impact on the resulting P-wave velocity, as long as it exceeds atmospheric pressure. The bulk of the rock formations studied showed reducing P-wave velocities as function of increasing temperature due to thermal expansion of the constituting minerals. This effect was most profound for the marble and calcschist samples investigated.
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Viegas, Gustavo, Luca Menegon, and Carlos Archanjo. "Brittle grain-size reduction of feldspar, phase mixing and strain localization in granitoids at mid-crustal conditions (Pernambuco shear zone, NE Brazil)." Solid Earth 7, no. 2 (March 9, 2016): 375–96. http://dx.doi.org/10.5194/se-7-375-2016.
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Abstract. The Pernambuco shear zone (northeastern Brazil) is a large-scale strike-slip fault that, in its eastern segment, deforms granitoids at mid-crustal conditions. Initially coarse-grained (> 50 µm) feldspar porphyroclasts are intensively fractured and reduced to an ultrafine-grained mixture consisting of plagioclase and K-feldspar grains (< 15 µm) localized in C' shear bands. Detailed microstructural observations and electron backscatter diffraction (EBSD) analysis do not show evidence of intracrystalline plasticity in feldspar porphyroclasts and/or fluid-assisted replacement reactions. Quartz occurs either as thick (∼ 1–2 mm) monomineralic veins transposed along the shear zone foliation or as thin ribbons ( ≤ 25 µm width) dispersed in the feldspathic mixture. The microstructure and c axis crystallographic-preferred orientation are similar in the thick monomineralic veins and in the thin ribbons, and they suggest dominant subgrain rotation recrystallization and activity of prism < a > and rhomb < a > slip systems. However, the grain size in monophase recrystallized domains decreases when moving from the quartz monomineralic veins to the thin ribbons embedded in the feldspathic C' bands (14 µm vs. 5 µm respectively). The fine-grained feldspar mixture has a weak crystallographic-preferred orientation interpreted as the result of shear zone parallel-oriented growth during diffusion creep, as well as the same composition as the fractured porphyroclasts, suggesting that it generated by mechanical fragmentation of rigid porphyroclasts with a negligible role of chemical disequilibrium. Once C' shear bands were generated and underwent viscous deformation at constant stress conditions, the polyphase feldspathic aggregate would have deformed at a strain rate 1 order of magnitude faster than the monophase quartz monomineralic veins, as evidenced by applying experimentally and theoretically calibrated flow laws for dislocation creep in quartz and diffusion creep in feldspar. Overall, our data set indicates that feldspar underwent a brittle-viscous transition while quartz was deforming via crystal plasticity. The resulting rock microstructure consists of a two-phase rheological mixture (fine-grained feldspars and recrystallized quartz) in which the polyphase feldspathic material localized much of the strain. Extensive grain-size reduction and weakening of feldspars is attained in the East Pernambuco mylonites mainly via fracturing which would trigger a switch to diffusion creep and strain localization without a prominent role of metamorphic reactions.
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Auréjac, Jean-Baptiste, Gérard Gleizes, Hervé Diot, and Jean-Luc Bouchez. "The Quérigut Complex (Pyrenees, France) revisited by the AMS technique : a syntectonic pluton of the Variscan dextral transpression." Bulletin de la Société Géologique de France 175, no. 2 (March 1, 2004): 157–74. http://dx.doi.org/10.2113/175.2.157.
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Abstract The Variscan Querigut Pluton (eastern Axial Zone, Pyrenees), recently dated at 307 ± 2 Ma, is a classical example for the structural study of granitoids. We present a new structural analysis of this pluton using the powerful technique of magnetic susceptibility anisotropy (AMS). A model of pluton emplacement is proposed on the basis of complementary microstructural analyses allowing the determination of the temperatures of fabric acquisition in the magmatic units, and of the shear sense criteria in the surrounding country rocks. This pluton is constituted by two main units that have intruded metasedimentary rocks where regional metamorphic conditions decrease from southwest to northeast. A well-foliated southern granodioritic unit, rich in Devonian marble xenoliths, is bounded to the south by Cambro-Ordovician metapelites. A weakly foliated northern monzogranitic unit, bounded to the north by Devonian marbles, comprises two sub-types : an outer biotite-monzogranite and an inner biotite-muscovite leucomonzogranite. Abundant basic stocks of variable sizes and lithologies outcrop in the granodioritic unit and in the southern part of the monzogranitic unit. Mean magnetic susceptibility and magnetic foliation maps show a very good agreement with the previous compiled petrographic and structural maps, strengthening the validity of the AMS technique. The northern monzogranitic units display two unevenly distributed structural patterns : (a) a NE-SW-trending pattern of weakly to steeply dipping foliations, dominant in the outer biotite monzogranite, is associated to subhorizontal NE-SW lineations ; and (b) a NW-SE-trending pattern of steeply dipping foliations, dominant in the inner biotite-muscovite monzogranite, is concentrated in NW-SE elongated corridors, associated to subhorizontal NW-SE lineations. In the southern granodioritic unit, foliation patterns follow roughly both the main regional foliation pattern and the pluton boundary, with foliation dips increasing to the south. Subhorizontal NW-SE trending magnetic lineations in the inner parts of this unit, are progressively verticalized toward the southern pluton boundary. A progressive increase in total magnetic anisotropy is observed toward the border of the pluton, correlated with both an increase in solid-state deformation and a decrease of the final temperature of fabric acquisition. These features result from a pluri-kilometric shear zone localized in the western half of the granodioritic unit, decreasing in thickness in its eastern half and along N060oE trending contacts with the country rocks. In the northern monzogranitic unit, one can roughly correlate the magmatic microstructures to the NE-SW trending fabric, and the superimposed subsolidus microstructures to the NW-SE-trending corridors, where rather low-temperature (< 300 oC) fluid-assisted cataclastic microstructures may also appear. The country-rocks, half kilometer away from the pluton border, display the D2 regional Variscan pattern, with subvertical and N110oE-striking foliations and subhorizontal and E-W-trending stretching lineations associated to a dextral shear. Closer to the pluton, the country-rocks are subjected to the pluton influence, particularly along the southern border where a strong flattening is associated to subvertical lineations related to local thrusting of the pluton onto its country rocks. An emplacement model is proposed through the injection of three principal magma batches (granodiorite, biotite-monzogranite and biotite-muscovite monzogranite) that successively and progressively built up the pluton while the whole region was subjected to a dextral and compressive deformation regime, in agreement with AMS results obtained from several other plutons of the Pyrenees.
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Gnos, Edwin, Josef Mullis, Emmanuelle Ricchi, Christian A. Bergemann, Emilie Janots, and Alfons Berger. "Episodes of fissure formation in the Alps: connecting quartz fluid inclusion, fissure monazite age, and fissure orientation data." Swiss Journal of Geosciences 114, no. 1 (May 10, 2021). http://dx.doi.org/10.1186/s00015-021-00391-9.
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AbstractFluid assisted Alpine fissure-vein and cleft formation starts at prograde, peak or retrograde metamorphic conditions of 450–550 °C and 0.3–0.6 GPa and below, commonly at conditions of ductile to brittle rock deformation. Early-formed fissures become overprinted by subsequent deformation, locally leading to a reorientation. Deformation that follows fissure formation initiates a cycle of dissolution, dissolution/reprecipitation or new growth of fissure minerals enclosing fluid inclusions. Although fissures in upper greenschist and amphibolite facies rocks predominantly form under retrograde metamorphic conditions, this work confirms that the carbon dioxide fluid zone correlates with regions of highest grade Alpine metamorphism, suggesting carbon dioxide production by prograde devolatilization reactions and rock-buffering of the fissure-filling fluid. For this reason, fluid composition zones systematically change in metamorphosed and exhumed nappe stacks from diagenetic to amphibolite facies metamorphic rocks from saline fluids dominated by higher hydrocarbons, methane, water and carbon dioxide. Open fissures are in most cases oriented roughly perpendicular to the foliation and lineation of the host rock. The type of fluid constrains the habit of the very frequently crystallizing quartz crystals. Open fissures also form in association with more localized strike-slip faults and are oriented perpendicular to the faults. The combination of fissure orientation, fissure quartz fluid inclusion and fissure monazite-(Ce) (hereafter monazite) Th–Pb ages shows that fissure formation occurred episodically (1) during the Cretaceous (eo-Alpine) deformation cycle in association with exhumation of the Austroalpine Koralpe-Saualpe region (~ 90 Ma) and subsequent extensional movements in association with the formation of the Gosau basins (~ 90–70 Ma), (2) during rapid exhumation of high-pressure overprinted Briançonnais and Piemontais units (36–30 Ma), (3) during unroofing of the Tauern and Lepontine metamorphic domes, during emplacement and reverse faulting of the external Massifs (25–12 Ma; except Argentera) and due to local dextral strike-slip faulting in association with the opening of the Ligurian sea, and (4) during the development of a young, widespread network of ductile to brittle strike-slip faults (12–5 Ma).
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Mintrone, M., A. Galli, and M. W. Schmidt. "Exhumation of a migmatitic unit through self-enhanced magmatic weakening enabled by tectonic contact metamorphism (Gruf complex, Central European Alps)." Contributions to Mineralogy and Petrology 177, no. 5 (May 2022). http://dx.doi.org/10.1007/s00410-022-01919-4.
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AbstractThe Central Alpine lower crustal migmatitic Gruf complex was exhumed in contact to the greenschist-grade Chiavenna ophiolite and gneissic Tambo nappe leading to a lateral gradient of ~ 70 °C/km within the ophiolite. The 14 km long, E-W striking subvertical contact now bridges metamorphic conditions of ~ 730 °C, 6.6 kbar in the migmatitic gneisses and ~ 500 °C, 4.2 kbar in the serpentinites and Tambo schists 2–4 km north of the contact. An obvious fault, mylonite or highly sheared rock that could accommodate the ~ 8.5 km vertical displacement is not present. Instead, more than half of the movement was accommodated in a 0.2–1.2 km thick orthogneiss of the Gruf complex that was heterogeneously molten. Discrete bands with high melt fractions (45–65%) now contain variably stretched enclaves of the adjacent MOR-derived amphibolite. In turn, the adjacent amphibolites exhibit tonalitic in-situ leucosomes and dikes i.e., were partially molten. The H2O necessary for fluid-assisted melting of the orthogneiss and amphibolites was likely derived from the tectonic contact metamorphism of the Chiavenna serpentinites, at the contact now in enstatite + olivine-grade. U–Pb dating of zircons shows that partial melting and diking occurred at 29.0–31.5 Ma, concomitant with the calc-alkaline Bergell batholith that intruded the Gruf. The major driving forces of exhumation were hence the strong regional North–South shortening in the Alpine collisional belt and the buoyancy provided by the Bergell magma. The fluids available through tectonic contact metamorphism led to self-enhanced magmatic weakening and concentration of movement in an orthogneiss, where melt-rich bands provided a low friction environment. Continuous heating of the originally greenschist Chiavenna ophiolite and Tambo gneisses + schists by the migmatitic Gruf complex during differential uplift explains the skewed temperature profile, with intensive contact heating in the ophiolite but little cooling in the portion of the now-exposed Gruf complex.
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Herrmann, Maria, Ulf Söderlund, Anders Scherstén, Tomas Næraa, Sanna Holm-Alwmark, and Carl Alwmark. "The effect of low-temperature annealing on discordance of U–Pb zircon ages." Scientific Reports 11, no. 1 (March 29, 2021). http://dx.doi.org/10.1038/s41598-021-86449-y.
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AbstractDiscordant U–Pb data of zircon are commonly attributed to Pb loss from domains with variable degree of radiation damage that resulted from α-decay of U and Th, which often complicates the correct age interpretation of the sample. Here we present U–Pb zircon data from 23 samples of ca. 1.7–1.9 Ga granitoid rocks in and around the Siljan impact structure in central Sweden. Our results show that zircon from rocks within the structure that form an uplifted central plateau lost significantly less radiogenic Pb compared to zircon grains in rocks outside the plateau. We hypothesize that zircon in rocks within the central plateau remained crystalline through continuous annealing of crystal structure damages induced from decay of U and Th until uplifted to the surface by the impact event ca. 380 Ma ago. In contrast, zircon grains distal to the impact have accumulated radiation damage at shallow and cool conditions since at least 1.26 Ga, making them vulnerable to fluid-induced Pb-loss. Our data are consistent with studies on alpha recoil and fission tracks, showing that annealing in zircon occurs at temperatures as low as 200–250 °C. Zircon grains from these samples are texturally simple, i.e., neither xenocrysts nor metamorphic overgrowths have been observed. Therefore, the lower intercepts obtained from regression of variably discordant zircon data are more likely recording the age of fluid-assisted Pb-loss from radiation-damaged zircon at shallow levels rather than linked to regional magmatic or tectonic events.
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Kaatz, Lisa, Julien Reynes, Jörg Hermann, and Timm John. "How fluid infiltrates dry crustal rocks during progressive eclogitization and shear zone formation: insights from H2O contents in nominally anhydrous minerals." Contributions to Mineralogy and Petrology 177, no. 7 (July 2022). http://dx.doi.org/10.1007/s00410-022-01938-1.
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AbstractGranulites from Holsnøy (Bergen Arcs, Norway) maintained a metastable state until fluid infiltration triggered the kinetically delayed eclogitization. Interconnected hydrous eclogite-facies shear zones are surrounded by unreacted granulites. Macroscopically, the granulite–eclogite interface is sharp and there are no significant compositional changes in the bulk chemistry, indicating the fluid composition was quickly rock buffered. To better understand the link between deformation, fluid influx, and fluid–rock interaction one cm-wide shear zone at incipient eclogitization is studied here. Granulite and eclogite consist of garnet, pyroxene, and plagioclase. These nominally anhydrous minerals (NAMs) can incorporate H2O in the form of OH groups. H2O contents increase from granulite to eclogite, as documented in garnet from ~ 10 to ~ 50 µg/g H2O, pyroxene from ~ 50 to ~ 310 µg/g H2O, and granulitic plagioclase from ~ 10 to ~ 140 µg/g H2O. Bowl-shape profiles are characteristic for garnet and pyroxene with lower H2O contents in grain cores and higher at the rims, which suggest a prograde water influx into the NAMs. Omphacite displays a H2O content range from ~ 150 to 425 µg/g depending on the amount of hydrous phases surrounding the grain. The granulitic plagioclase first separates into a hydrous, more albite-rich plagioclase and isolated clinozoisite before being replaced by new fine-grained phases like clinozoisite, kyanite and quartz during ongoing fluid infiltration. Results indicate a twofold fluid influx with different mechanisms to act simultaneously at different scales and rates. Fast and more pervasive proton diffusion is recorded by NAMs that retain the major element composition of the granulite-facies equilibration where hydrogen decorates pre-existing defects in the crystal lattice and leads to OH increase. Contemporaneously, slower grain boundary-assisted aqueous fluid influx enables element transfer and results in progressive formation of new minerals, e.g., hydrous phases. Both mechanisms lead to bulk H2O increase from ~ 450 to ~ 2500 µg/g H2O towards the shear zone and convert the system from rigid to weak. The incorporation of OH groups reduces the activation energy for creep, promotes formation of smaller grain sizes (phase separation of plagioclase), and synkinematic metamorphic mineral reactions. These processes are part of the transient weakening, which enhance the sensitivity of the rock to deform.
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Liu, Shuaiqi, Guibin Zhang, Lifei Zhang, Shuzhen Wang, Bishal N. Upreti, Danda P. Adhikari, Chenguang Wu, and Jiaxing Wang. "Diverse Anatexis in the Main Central Thrust Zone, Eastern Nepal: Implications for Melt Evolution and Exhumation Process of the Himalaya." Journal of Petrology 63, no. 3 (January 28, 2022). http://dx.doi.org/10.1093/petrology/egac003.
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Abstract Sitting between the Greater Himalayan sequence (GHS) and Lesser Himalayan sequence (LHS), the Main Central Thrust zone (MCTZ) has experienced multiple episodes of anatexis, which presents an opportunity to explore the nature of partial melting and its response to Himalayan orogenic processes. A series of deformed rocks, including migmatites, gneisses, and leucosomes were collected across the MCT at Arun Valley, eastern Nepal. We investigated the bulk rock major and trace elements, Sr-Nd isotopes, mineral chemistry, zircon geochronology and Hf isotopes, and conducted phase equilibria modeling. The protolith boundary between the GHS and LHS is recognized on the basis of Sr–Nd isotopes with εNd(0) of −16.7 to −8.0 for the GHS and −31.2 to −23.9 for the LHS. Samples from both the GHS and LHS have undergone partial melting, as revealed by in situ leucosomes at outcrops and melt inclusions at thin-section scale. Leucosomes separated from their host rocks are divided into four groups: those derived from hydration melting, muscovite dehydration melting, amphibole dehydration melting, and feldspar accumulation. Phase equilibria modeling results for the GHS migmatite show isothermal decompression from peak P–T conditions of 11 kbar and 795°C, accompanied by muscovite dehydration melting evolving into biotite dehydration melting. In contrast, rocks from the LHS are modeled to have undergone hydration melting at P–T conditions of 9 kbar and 685°C. Zircon U–Pb geochronology suggests that long-lived partial melting (35–13 Ma) occurred in the MCTZ. Moreover, anatectic zircon Hf isotopes show that the protoliths for partial melting changed from the GHS to the LHS with εHf(t) of −19.4 to −5.7 during the early Miocene, and lower values of −42.5 to −16.7 during the middle to late Miocene. These zircon geochemical results indicate that hydrous metasediments from the LHS were progressively accreted to the base of the GHS, resulting in hydration melting of both the GHS and LHS assisted by MCT. The timing of activity of the MCT is constrained to 25–13 Ma, coeval with movement of the South Tibetan detachment system. Integration of petrogenetic modeling, the chronology of partial melting, and metamorphic P–T paths allows us to propose that thickened Himalayan crust was heated from the middle to late Eocene, and widespread anatexis occurred during the Oligocene to middle Miocene, forming a large-scale melt channel. The hot GHS channel flow moved upward in association with the synchronous activity of the MCT system, triggered intense dehydration of LHS metasediments, resulting in fluid-present melting in both the GHS and LHS during middle to late Miocene, and the formation of leucogranite with mixture features of GHS and LHS. Furthermore, with the cooling of the melt channel, duplexing has gradually operated since the middle to late Miocene in the shallow crust.