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Journal articles on the topic 'Flexible MOF'

Author: Grafiati
Published: 9 March 2023
Last updated: 10 March 2023

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1

Xu, Li-Hao, Shen-Hui Li, Heng Mao, Yan Li, Ao-Shuai Zhang, Sen Wang, Wei-Min Liu, et al. "Highly flexible and superhydrophobic MOF nanosheet membrane for ultrafast alcohol-water separation." Science 378, no. 6617 (October 21, 2022): 308–13. http://dx.doi.org/10.1126/science.abo5680.

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High-performance pervaporation membranes have potential in industrial separation applications, but overcoming the permeability-selectivity trade-off is a challenge. We report a strategy to create highly flexible metal-organic framework nanosheet (MOF-NS) membranes with a faveolate structure on polymer substrates for alcohol-water separation. The controlled growth followed by a surface-coating method effectively produced flexible and defect-free superhydrophobic MOF-NS membranes. The reversible deformation of the flexible MOF-NS and the vertical interlamellar pathways were captured with electron microscopy. Molecular simulations confirmed the structure and revealed transport mechanism. The ultrafast transport channels in MOF-NS exhibited an ultrahigh flux and a separation factor of 8.9 in the pervaporation of 5 weight % ethanol-water at 40°C, which can be used for biofuel recovery. MOF-NS and polydimethylsiloxane synergistically contribute to the separation performance.
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2

Chakraborty, Anindita, Syamantak Roy, Muthusamy Eswaramoorthy, and Tapas Kumar Maji. "Flexible MOF–aminoclay nanocomposites showing tunable stepwise/gated sorption for C2H2, CO2 and separation for CO2/N2 and CO2/CH4." Journal of Materials Chemistry A 5, no. 18 (2017): 8423–30. http://dx.doi.org/10.1039/c6ta09886j.

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3

Wang, Hui-Ya, Xiao-bo Sun, and Guang-Sheng Wang. "A MXene-modulated 3D crosslinking network of hierarchical flower-like MOF derivatives towards ultra-efficient microwave absorption properties." Journal of Materials Chemistry A 9, no. 43 (2021): 24571–81. http://dx.doi.org/10.1039/d1ta06505j.

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3D crosslinking networks were constructed through hierarchicalower–like Co MOF (or CoNi MOF) with 2D flexible MXene. Combined with the introduction of Ni ions, the MOF derivatives/MXene composites accomplish remarkable MA ability at a lower content.
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4

Seth, Soana, Govardhan Savitha, and Jarugu Narasimha Moorthy. "Diverse isostructural MOFs by postsynthetic metal node metathesis: anionic-to-cationic framework conversion, luminescence and separation of dyes." Journal of Materials Chemistry A 3, no. 45 (2015): 22915–22. http://dx.doi.org/10.1039/c5ta04551g.

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Postsynthetic metal-node metathesis of a flexible, yet robust porous anionic Cd–MOF with different metal ions of varying ionic radii, charges and chemical nature leads to diverse isostructural MOFs. The Eu@MOF and Tb@MOF – accessed by PSME – are brilliantly luminescent. The modified MOFs permit organic dye separation.
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5

Ali, Ashraf, Husam H. D. AlTakroori, Yaser E. Greish, Ahmed Alzamly, Lamia A. Siddig, Naser Qamhieh, and Saleh T. Mahmoud. "Flexible Cu3(HHTP)2 MOF Membranes for Gas Sensing Application at Room Temperature." Nanomaterials 12, no. 6 (March 10, 2022): 913. http://dx.doi.org/10.3390/nano12060913.

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Mixed matrix membranes (MMMs), possessing high porosity, have received extensive attention for gas sensing applications. However, those with high flexibility and significant sensitivity are rare. In this work, we report on the fabrication of a novel membrane, using Cu3(HHTP)2 MOF (Cu-MOF) embedded in a polymer matrix. A solution comprising a homogenous suspension of poly-vinyl alcohol (PVA) and ionic liquid (IL), and Cu-MOF solid particles, was cast onto a petri dish to obtain a flexible membrane (215 μm in thickness). The sensor membrane (Cu-MOF/PVA/IL), characterized for its structure and morphology, was assessed for its performance in sensing against various test gases. A detection limit of 1 ppm at 23 °C (room temperature) for H2S was achieved, with a response time of 12 s. Moreover, (Cu-MOF/PVA/IL) sensor exhibited excellent repeatability, long-term stability, and selectivity towards H2S gas. The other characteristics of the (Cu-MOF/PVA/IL) sensor include high flexibility, low cost, low-power consumption, and easy fabrication technique, which nominate this sensor as a potential candidate for use in practical industrial applications.
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6

Ahmad, Momin, Yi Luo, Christof Wöll, Manuel Tsotsalas, and Alexander Schug. "Design of Metal-Organic Framework Templated Materials Using High-Throughput Computational Screening." Molecules 25, no. 21 (October 22, 2020): 4875. http://dx.doi.org/10.3390/molecules25214875.

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The ability to crosslink Metal-Organic Frameworks (MOFs) has recently been discovered as a flexible approach towards synthesizing MOF-templated “ideal network polymers”. Crosslinking MOFs with rigid cross-linkers would allow the synthesis of crystalline Covalent-Organic Frameworks (COFs) of so far unprecedented flexibility in network topologies, far exceeding the conventional direct COF synthesis approach. However, to date only flexible cross-linkers were used in the MOF crosslinking approach, since a rigid cross-linker would require an ideal fit between the MOF structure and the cross-linker, which is experimentally extremely challenging, making in silico design mandatory. Here, we present an effective geometric method to find an ideal MOF cross-linker pair by employing a high-throughput screening approach. The algorithm considers distances, angles, and arbitrary rotations to optimally match the cross-linker inside the MOF structures. In a second, independent step, using Molecular Dynamics (MD) simulations we quantitatively confirmed all matches provided by the screening. Our approach thus provides a robust and powerful method to identify ideal MOF/Cross-linker combinations, which helped to identify several MOF-to-COF candidate structures by starting from suitable libraries. The algorithms presented here can be extended to other advanced network structures, such as mechanically interlocked materials or molecular weaving and knots.
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7

Li, Yue, Yutong Wang, Weidong Fan, and Daofeng Sun. "Flexible metal–organic frameworks for gas storage and separation." Dalton Transactions 51, no. 12 (2022): 4608–18. http://dx.doi.org/10.1039/d1dt03842g.

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8

Allen, Andrew, Winnie Wong-Ng, Eric Cockayne, Jeffrey Culp, and Christopher Matranga. "Structural Basis of CO2 Adsorption in a Flexible Metal-Organic Framework Material." Nanomaterials 9, no. 3 (March 4, 2019): 354. http://dx.doi.org/10.3390/nano9030354.

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This paper reports on the structural basis of CO2 adsorption in a representative model of flexible metal-organic framework (MOF) material, Ni(1,2-bis(4-pyridyl)ethylene)[Ni(CN)4] (NiBpene or PICNIC-60). NiBpene exhibits a CO2 sorption isotherm with characteristic hysteresis and features on the desorption branch that can be associated with discrete structural changes. Various gas adsorption effects on the structure are demonstrated for CO2 with respect to N2, CH4 and H2 under static and flowing gas pressure conditions. For this complex material, a combination of crystal structure determination and density functional theory (DFT) is needed to make any real progress in explaining the observed structural transitions during adsorption/desorption. Possible enhancements of CO2 gas adsorption under supercritical pressure conditions are considered, together with the implications for future exploitation. In situ operando small-angle neutron and X-ray scattering, neutron diffraction and X-ray diffraction under relevant gas pressure and flow conditions are discussed with respect to previous studies, including ex situ, a priori single-crystal X-ray diffraction structure determination. The results show how this flexible MOF material responds structurally during CO2 adsorption; single or dual gas flow results for structural change remain similar to the static (Sieverts) adsorption case, and supercritical CO2 adsorption results in enhanced gas uptake. Insights are drawn for this representative flexible MOF with implications for future flexible MOF sorbent design.
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9

Kondo, Atsushi, Takuro Fujii, and Kazuyuki Maeda. "Tuning of gate adsorption: modification of a flexible metal–organic framework by secondary organic ligands." Dalton Trans. 43, no. 22 (2014): 8174–77. http://dx.doi.org/10.1039/c4dt00116h.

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10

Li, Libo, Rajamani Krishna, Yong Wang, Jiangfeng Yang, Xiaoqing Wang, and Jinping Li. "Exploiting the gate opening effect in a flexible MOF for selective adsorption of propyne from C1/C2/C3 hydrocarbons." Journal of Materials Chemistry A 4, no. 3 (2016): 751–55. http://dx.doi.org/10.1039/c5ta09029f.

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11

Hirao, Shoya, Ruho Hamagami, Takashi Ohhashi, Keiichi Eguchi, Neo Kubo, Yohei Takashima, Kensuke Akamatsu, and Takaaki Tsuruoka. "Exploration of structural transition phenomenon in flexible metal–organic framework formed on polymer substrate." CrystEngComm 23, no. 48 (2021): 8498–505. http://dx.doi.org/10.1039/d1ce01383a.

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12

Thompson, Megan J., Claire L. Hobday, Irena Senkovska, Volodymyr Bon, Sebastian Ehrling, Mariia Maliuta, Stefan Kaskel, and Tina Düren. "Role of particle size and surface functionalisation on the flexibility behaviour of switchable metal–organic framework DUT-8(Ni)." Journal of Materials Chemistry A 8, no. 43 (2020): 22703–11. http://dx.doi.org/10.1039/d0ta07775e.

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13

Yan, Yan, Peng Gu, Shasha Zheng, Mingbo Zheng, Huan Pang, and Huaiguo Xue. "Facile synthesis of an accordion-like Ni-MOF superstructure for high-performance flexible supercapacitors." Journal of Materials Chemistry A 4, no. 48 (2016): 19078–85. http://dx.doi.org/10.1039/c6ta08331e.

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14

He, Yingdian, Jin Shang, Qinfen Gu, Gang Li, Jiaye Li, Ranjeet Singh, Penny Xiao, and Paul A. Webley. "Converting 3D rigid metal–organic frameworks (MOFs) to 2D flexible networks via ligand exchange for enhanced CO2/N2 and CH4/N2 separation." Chemical Communications 51, no. 79 (2015): 14716–19. http://dx.doi.org/10.1039/c5cc05867h.

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15

Deng, Mingli, Shijun Tai, Weiquan Zhang, Yongchen Wang, Jiaxing Zhu, Jinsheng Zhang, Yun Ling, and Yaming Zhou. "A self-catenated rob-type porous coordination polymer constructed from triazolate and carboxylate ligands: fluorescence response to the reversible phase transformation." CrystEngComm 17, no. 31 (2015): 6023–29. http://dx.doi.org/10.1039/c5ce00887e.

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16

Wang, Hao, Xinglong Dong, Ever Velasco, David H. Olson, Yu Han, and Jing Li. "One-of-a-kind: a microporous metal–organic framework capable of adsorptive separation of linear, mono- and di-branched alkane isomers via temperature- and adsorbate-dependent molecular sieving." Energy & Environmental Science 11, no. 5 (2018): 1226–31. http://dx.doi.org/10.1039/c8ee00459e.

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17

Xu, W., Li-H. Wang., Y. Chen, and Y. Liu. "Flexible carbon membrane supercapacitor based on γ-cyclodextrin-MOF." Materials Today Chemistry 24 (June 2022): 100896. http://dx.doi.org/10.1016/j.mtchem.2022.100896.

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18

Li, Ao, Liang Li, Zhi Lin, Lin Song, Zi-Hao Wang, Qiang Chen, Tao Yang, Xin-Hui Zhou, Hong-Ping Xiao, and Xiu-Ju Yin. "Guest-induced reversible structural transitions and concomitant on/off luminescence switching of an Eu(iii) metal–organic framework and its application in detecting picric acid." New Journal of Chemistry 39, no. 3 (2015): 2289–95. http://dx.doi.org/10.1039/c4nj01946f.

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19

Liang, Huixin, Xiuling Jiao, Cheng Li, and Dairong Chen. "Flexible self-supported metal–organic framework mats with exceptionally high porosity for enhanced separation and catalysis." Journal of Materials Chemistry A 6, no. 2 (2018): 334–41. http://dx.doi.org/10.1039/c7ta08210j.

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20

Sun, Yan-Qiong, Jie-Cen Zhong, Ling Ding, and Yi-Ping Chen. "Syntheses, structures, photoluminescence and photocatalysis of chiral 3D Cd(ii) frameworks from achiral mixed flexible ligands by spontaneous resolution." Dalton Transactions 44, no. 26 (2015): 11852–59. http://dx.doi.org/10.1039/c5dt01454a.

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21

Ling, Yajing, Jingjing Jiao, Mingxing Zhang, Huimin Liu, Dongjie Bai, Yunlong Feng, and Yabing He. "A porous lanthanide metal–organic framework based on a flexible cyclotriphosphazene-functionalized hexacarboxylate exhibiting selective gas adsorption." CrystEngComm 18, no. 33 (2016): 6254–61. http://dx.doi.org/10.1039/c6ce00497k.

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22

Bon, Volodymyr, Nicole Klein, Irena Senkovska, Andreas Heerwig, Jürgen Getzschmann, Dirk Wallacher, Ivo Zizak, Maria Brzhezinskaya, Uwe Mueller, and Stefan Kaskel. "Exceptional adsorption-induced cluster and network deformation in the flexible metal–organic framework DUT-8(Ni) observed by in situ X-ray diffraction and EXAFS." Physical Chemistry Chemical Physics 17, no. 26 (2015): 17471–79. http://dx.doi.org/10.1039/c5cp02180d.

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23

Xu, Xiaoyan, Fei Yang, Shi-Lu Chen, Jieya He, Yanqing Xu, and Wei Wei. "Dynamic behaviours of a rationally prepared flexible MOF by postsynthetic modification of ligand struts." Chemical Communications 53, no. 22 (2017): 3220–23. http://dx.doi.org/10.1039/c7cc00230k.

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24

Haldar, Ritesh, and Christof Wöll. "Hierarchical assemblies of molecular frameworks—MOF-on-MOF epitaxial heterostructures." Nano Research 14, no. 2 (July 20, 2020): 355–68. http://dx.doi.org/10.1007/s12274-020-2953-z.

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AbstractFunctional, porous metal-organic frameworks (MOFs) have attracted much attention as a very flexible class of crystalline, porous materials. For more advanced applications that exploit photophysical properties, the fabrication of hierarchical assemblies, including the creation of MOF/MOF heterointerfaces, is important. For the manufacturing of superstructures with length scales well beyond that of the MOF pore size, layer-by-layer (lbl) methods are particularly attractive. These allow the isoreticular approach to be extended to superstructures with micrometer length scales, a range that is not accessible using conventional MOF design. The lbl approach further substantially extends the compositional diversity in MOFs. At the same time, the favorable elastic properties of MOFs allow for heteroepitaxial growth, even in the case of lattice misfits as large as 20%. While the MOF-on-MOF approach to designing multicomponent superstructures with synergistic multifunctionality can also be realized with sophisticated solvothermal synthesis schemes, the lbl (or liquid-phase epitaxy) approach carries substantial advantages, in particular when it comes to the integration of such MOF superstructures into optical or electronic devices. While the structure vertical to the substrate can be adjusted using the lbl method, photolithographic methods can be used for lateral structuring. In this review, we will discuss the lbl liquid-phase epitaxy approach to growing surface-anchored MOF thins films (SURMOFs) as well as other relevant one-pot synthesis methods for constructing such hierarchically designed structures and their emerging applications.
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25

Bhatt, Prashant M., Eustina Batisai, Vincent J. Smith, and Leonard J. Barbour. "Creation of new guest accessible space under gas pressure in a flexible MOF: multidimensional insight through combination of in situ techniques." Chemical Communications 52, no. 76 (2016): 11374–77. http://dx.doi.org/10.1039/c6cc06709c.

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26

Li, Xingjun, Xueyuan Chen, Feilong Jiang, Lian Chen, Shan Lu, Qihui Chen, Mingyan Wu, Daqiang Yuan, and Maochun Hong. "The dynamic response of a flexible indium based metal–organic framework to gas sorption." Chemical Communications 52, no. 11 (2016): 2277–80. http://dx.doi.org/10.1039/c5cc09461e.

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27

Lange, Marcus, Merten Kobalz, Jens Bergmann, Daniel Lässig, Jörg Lincke, Jens Möllmer, Andreas Möller, et al. "Structural flexibility of a copper-based metal–organic framework: sorption of C4-hydrocarbons and in situ XRD." J. Mater. Chem. A 2, no. 21 (2014): 8075–85. http://dx.doi.org/10.1039/c3ta15331b.

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28

Zhang, Peng-Dan, Xue-Qian Wu, Tao He, Lin-Hua Xie, Qiang Chen, and Jian-Rong Li. "Selective adsorption and separation of C2 hydrocarbons in a “flexible-robust” metal–organic framework based on a guest-dependent gate-opening effect." Chemical Communications 56, no. 41 (2020): 5520–23. http://dx.doi.org/10.1039/d0cc01315c.

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29

Man, Ping, Bing He, Qichong Zhang, Zhenyu Zhou, Chaowei Li, Qiulong Li, Lei Wei, and Yagang Yao. "A one-dimensional channel self-standing MOF cathode for ultrahigh-energy-density flexible Ni–Zn batteries." Journal of Materials Chemistry A 7, no. 48 (2019): 27217–24. http://dx.doi.org/10.1039/c9ta11759h.

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30

Ma, Xu, Zhuoyi Li, Zheng Deng, Danke Chen, Xiaobin Wang, Xinyi Wan, Zhou Fang, and Xinsheng Peng. "Efficiently cogenerating drinkable water and electricity from seawater via flexible MOF nanorod arrays." Journal of Materials Chemistry A 9, no. 14 (2021): 9048–55. http://dx.doi.org/10.1039/d0ta11870b.

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A flexible Cu-CAT-1 MOF nanorod array membrane is rationally designed for water–electricity cogeneration from seawater with efficient solar desalination performance and nice all-weather electricity output.
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31

Cai, Jingsheng, Yingze Song, Xiang Chen, Zhongti Sun, Yuyang Yi, Jingyu Sun, and Qiang Zhang. "MOF-derived conductive carbon nitrides for separator-modified Li–S batteries and flexible supercapacitors." Journal of Materials Chemistry A 8, no. 4 (2020): 1757–66. http://dx.doi.org/10.1039/c9ta11958b.

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MOF-derived carbon nitride with good electrical conductivity and high nitrogen content for flexible energy storages in separator-modified Li–S batteries and wearable quasi-solid-state supercapacitor devices.
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32

Lanza, Arianna, Luzia S. Germann, Martin Fisch, Nicola Casati, and Piero Macchi. "Solid-State Reversible Nucleophilic Addition in a Highly Flexible MOF." Journal of the American Chemical Society 137, no. 40 (October 2, 2015): 13072–78. http://dx.doi.org/10.1021/jacs.5b09231.

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33

Qiu, Qian-feng, Cheng-Xia Chen, Zhang-Wen Wei, Chen-Chen Cao, Neng-Xiu Zhu, Hai-Ping Wang, Dawei Wang, Ji-Jun Jiang, and Cheng-Yong Su. "A Flexible Cu-MOF as Crystalline Sponge for Guests Determination." Inorganic Chemistry 58, no. 1 (December 27, 2018): 61–64. http://dx.doi.org/10.1021/acs.inorgchem.8b02993.

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34

Reichenbach, C., G. Kalies, J. Lincke, D. Lässig, H. Krautscheid, J. Moellmer, and M. Thommes. "Unusual adsorption behavior of a highly flexible copper-based MOF." Microporous and Mesoporous Materials 142, no. 2-3 (July 2011): 592–600. http://dx.doi.org/10.1016/j.micromeso.2011.01.005.

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35

Zhang, Mei-Li, Ye Bai, Xiao-Gang Yang, Yan-Jin Zheng, Yi-Xia Ren, Ji-Jiang Wang, Min-Le Han, Fei-Fei Li, and Lu-Fang Ma. "Dense π-stacking of flexible ligands fixed in interpenetrating Zn(ii) MOF exhibiting long-lasting phosphorescence and efficient carrier transport." Dalton Transactions 49, no. 29 (2020): 9961–64. http://dx.doi.org/10.1039/d0dt01810d.

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36

Xu, Xilian, Wenhui Shi, Wenxian Liu, Shaofeng Ye, Ruilian Yin, Lin Zhang, Lixin Xu, Minghua Chen, Mingqiang Zhong, and Xiehong Cao. "Preparation of two-dimensional assembled Ni–Mn–C ternary composites for high-performance all-solid-state flexible supercapacitors." Journal of Materials Chemistry A 6, no. 47 (2018): 24086–91. http://dx.doi.org/10.1039/c8ta06412a.

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37

Bu, Fanxing, Peitao Xiao, Jiadong Chen, Mohamed F. Aly Aboud, Imran Shakir, and Yuxi Xu. "Rational design of three-dimensional graphene encapsulated core–shell FeS@carbon nanocomposite as a flexible high-performance anode for sodium-ion batteries." Journal of Materials Chemistry A 6, no. 15 (2018): 6414–21. http://dx.doi.org/10.1039/c7ta11111h.

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Three-dimensional graphene encapsulated core–shell FeS@carbon nanocomposite have been fabricated based on spatially confined phase separation of MOF and then employed as a flexible high-performance anode for sodium-ion batteries.
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38

Lama, Prem, Raj Kumar Das, Vincent J. Smith, and Leonard J. Barbour. "Correction: A combined stretching–tilting mechanism produces negative, zero and positive linear thermal expansion in a semi-flexible Cd(ii)-MOF." Chemical Communications 54, no. 78 (2018): 11052. http://dx.doi.org/10.1039/c8cc90410c.

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Correction for ‘A combined stretching–tilting mechanism produces negative, zero and positive linear thermal expansion in a semi-flexible Cd(ii)-MOF’ by Prem Lama et al., Chem. Commun., 2014, 50, 6464–6467.
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39

Ma, Qintian, Qingyuan Yang, Aziz Ghoufi, Ke Yang, Ming Lei, Gérard Férey, Chongli Zhong, and Guillaume Maurin. "Guest-modulation of the mechanical properties of flexible porous metal–organic frameworks." J. Mater. Chem. A 2, no. 25 (2014): 9691–98. http://dx.doi.org/10.1039/c4ta00622d.

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The highly flexible hybrid nanoporous MOF MIL-53(Cr) was evoked as a potential medium to store mechanical energy via a structural switching from an open to a close pore form under moderate applied external pressures.
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40

Hazra, Arpan, Dewald P. van Heerden, Somananda Sanyal, Prem Lama, Catharine Esterhuysen, and Leonard J. Barbour. "CO2-induced single-crystal to single-crystal transformations of an interpenetrated flexible MOF explained by in situ crystallographic analysis and molecular modeling." Chemical Science 10, no. 43 (2019): 10018–24. http://dx.doi.org/10.1039/c9sc04043a.

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A flexible twofold interpenetrated MOF reversibly switches between closed, narrow and large pore forms. In situ crystallographic analysis of a narrow-pore intermediate phase provides a detailed explanation of a plateau observed during desorption.
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41

Millan, Simon, Beatriz Gil-Hernández, Erik Milles, Serkan Gökpinar, Gamall Makhloufi, Alexa Schmitz, Carsten Schlüsener, and Christoph Janiak. "rtl-M-MOFs (M = Cu, Zn) with a T-shaped bifunctional pyrazole-isophthalate ligand showing flexibility and S-shaped Type F-IV sorption isotherms with high saturation uptakes for M = Cu." Dalton Transactions 48, no. 23 (2019): 8057–67. http://dx.doi.org/10.1039/c9dt01499c.

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42

Okada, Kenji, Keyaki Mori, Arisa Fukatsu, and Masahide Takahashi. "Oriented growth of semiconducting TCNQ@Cu3(BTC)2 MOF on Cu(OH)2: crystallographic orientation and pattern formation toward semiconducting thin-film devices." Journal of Materials Chemistry A 9, no. 35 (2021): 19613–18. http://dx.doi.org/10.1039/d1ta02968a.

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Oriented film and pattern of TCNQ@Cu3(BTC)2(HKUST-1) fabricated via epitaxial growth exhibit anisotropic electrical properties toward MOF-based (flexible) thin-film smart device applications, such as transistors and thermoelectric thin films.
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43

Ling, Yajing, Chengling Song, Yunlong Feng, Mingxing Zhang, and Yabing He. "A metal–organic framework based on cyclotriphosphazene-functionalized hexacarboxylate for selective adsorption of CO2 and C2H6 over CH4 at room temperature." CrystEngComm 17, no. 33 (2015): 6314–19. http://dx.doi.org/10.1039/c5ce00930h.

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A new MOF constructed from a flexible cyclotriphosphazene-functionalized hexacarboxylate exhibits selective adsorption of CO2 and C2H6 over CH4 at room temperature.
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44

Bolinois, Linius, Tanay Kundu, Xuerui Wang, Yuxiang Wang, Zhigang Hu, Kenny Koh, and Dan Zhao. "Breathing-induced new phase transition in an MIL-53(Al)–NH2 metal–organic framework under high methane pressures." Chemical Communications 53, no. 58 (2017): 8118–21. http://dx.doi.org/10.1039/c7cc02743e.

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The room temperature methane sorption tests on a flexible MOF reveal a new phase transition to a large pore phase above 45 bar, which is helpful to increase the deliverable capacity for natural gas storage.
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45

Schmieder, P., D. Denysenko, M. Grzywa, O. Magdysyuk, and D. Volkmer. "A structurally flexible triazolate-based metal–organic framework featuring coordinatively unsaturated copper(i) sites." Dalton Transactions 45, no. 35 (2016): 13853–62. http://dx.doi.org/10.1039/c6dt02672a.

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46

Leelasree, T., Venkatarao Selamneni, T. Akshaya, Parikshit Sahatiya, and Himanshu Aggarwal. "MOF based flexible, low-cost chemiresistive device as a respiration sensor for sleep apnea diagnosis." Journal of Materials Chemistry B 8, no. 44 (2020): 10182–89. http://dx.doi.org/10.1039/d0tb01748e.

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47

Bennett, T. D., J. Sotelo, Jin-Chong Tan, and S. A. Moggach. "Mechanical properties of zeolitic metal–organic frameworks: mechanically flexible topologies and stabilization against structural collapse." CrystEngComm 17, no. 2 (2015): 286–89. http://dx.doi.org/10.1039/c4ce02145b.

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48

Zheng, Shasha, Qing Li, Huaiguo Xue, Huan Pang, and Qiang Xu. "A highly alkaline-stable metal oxide@metal–organic framework composite for high-performance electrochemical energy storage." National Science Review 7, no. 2 (September 12, 2019): 305–14. http://dx.doi.org/10.1093/nsr/nwz137.

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Abstract Most metal–organic frameworks (MOFs) hardly maintain their physical and chemical properties after exposure to alkaline aqueous solutions, thus precluding their use as potential electrode materials for electrochemical energy storage devices. Here, we present the design and synthesis of a highly alkaline-stable metal oxide@MOF composite, Co3O4 nanocube@Co-MOF (Co3O4@Co-MOF), via a controllable and facile one-pot hydrothermal method under highly alkaline conditions. The obtained composite possesses exceptional alkaline stability, retaining its original structure in 3.0 M KOH for at least 15 days. Benefitting from the exceptional alkaline stability, unique structure, and larger surface area, the Co3O4@Co-MOF composite shows a specific capacitance as high as 1020 F g−1 at 0.5 A g−1 and a high cycling stability with only 3.3% decay after 5000 cycles at 5 A g−1. The as-constructed solid-state flexible device exhibits a maximum energy density of 21.6 mWh cm−3.
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49

Liu, Zhao, Junwei Ye, Abdul Rauf, Siqi Zhang, Guangyao Wang, Suqi Shi, and Guiling Ning. "A flexible fibrous membrane based on copper(ii) metal–organic framework/poly(lactic acid) composites with superior antibacterial performance." Biomaterials Science 9, no. 10 (2021): 3851–59. http://dx.doi.org/10.1039/d1bm00164g.

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A flexible fibrous membrane was prepared by electrospinning a Cu(ii)-based MOF and poly(lactic acid), which showed excellent broad-spectrum antibacterial properties based on the steady and prolonged release of Cu2+ in biocidal concentrations.
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50

Huang, Lijin, Man He, Beibei Chen, and Bin Hu. "A mercapto functionalized magnetic Zr-MOF by solvent-assisted ligand exchange for Hg2+ removal from water." Journal of Materials Chemistry A 4, no. 14 (2016): 5159–66. http://dx.doi.org/10.1039/c6ta00343e.

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A facile preparation of magnetic MOF composites with flexible mercapto group pendants in their pores is realized through solvent-assisted ligand exchange (SALE) under mild conditions in water, and terephthalate in UIO-66 is replaced with mercaptoacetic acid (MAA).
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