Relevant bibliographies by topics / Ferrocene Chemistry

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  1. Journal articles
  2. Dissertations / Theses
  3. Books
  4. Book chapters
  5. Conference papers

Academic literature on the topic 'Ferrocene Chemistry'

Author: Grafiati
Published: 4 June 2021
Last updated: 7 September 2023

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Journal articles on the topic "Ferrocene Chemistry"

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Snegur, Lubov V. "Modern Trends in Bio-Organometallic Ferrocene Chemistry." Inorganics 10, no. 12 (November 26, 2022): 226. http://dx.doi.org/10.3390/inorganics10120226.

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Organometallic sandwich compounds, especially ferrocenes, possess a wide variety of pharmacological activities and therefore are attracting more and more attention from chemists, biologists, biochemists, etc. Excellent reviews concerning biological aspects and design of ferrocene-modified compounds appear regularly in scientific journals. This brief overview highlights recent achievements in the field of bio-organometallic ferrocene chemistry from 2017 to 2022. During this period, new ferrocene-modified analogues of various bio-structures were synthesized, namely, betulin, artemisinin, steroids, and alkaloids. In addition, studies of the biological potential of ferrocenes have been expanded. Since ferrocene is 70 years old this year, a brief historical background is also given. It seemed to me useful to sketch the ‘ferrocene picture’ in broad strokes.
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Nakamura, E. "Bucky ferrocene. Hybrid of ferrocene and fullerene." Pure and Applied Chemistry 75, no. 4 (January 1, 2003): 427–34. http://dx.doi.org/10.1351/pac200375040427.

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The idea of “bucky ferrocene” intrigues chemists owing to its aesthetic beauty and to its polarized, extended conjugated system, but the idea has remained hypothetical. The synthesis of close analogs of Fe(C60Me5)Cp and Fe(C70Me3)Cp was achieved in two steps from [60] and [70]fullerenes, relying on an oxidative C–H bond activation starting with an iron(I) complex and the corresponding cyclopentadienyl precursors, respectively. The molecules can be regarded as members of a new organometallic conjugated system connected to a graphitic system. Numerous synthetic transformations and self-organization procedures that are known for the parent ferrocenes and fullerenes are expected to be employable toward productive use of the ferrocene/fullerene hybrid molecules in chemistry and materials sciences.
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Prokop, Petra, Rainer Richter, and Lothar Beyer. "Zur Reaktion von 2,4-Dioxo-4-ferrocenyl-butansäureethylester mit primären aromatischen Aminen / On the Reaction of Ethyl 2,4-Dioxo-4-ferrocenyl-butanoate with Primary Aromatic Amines." Zeitschrift für Naturforschung B 54, no. 7 (July 1, 1999): 849–57. http://dx.doi.org/10.1515/znb-1999-0705.

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Starting from ethyl 2,4-dioxo-4-ferrocenyl-butanoate (1) a series of new ferrocene derivatives has been prepared. While the reaction with o-phenylene diamine leads to two ferrocene-containing heterocyclic compounds, 4-ferrocenyl-3H-1,5-benzodiazepine-2-carbonic acid ethyl ester (3) and 3-(2-ferrocenyl-2-oxo-ethylidene)-3,4-dihydro-1H-quinoxalin-2-one · H20 (4), reactions with m- and p-phenylene diamine give both the mono- and disubstituted products 5 - 8, respectively. The conversion of 4 by Lawesson’s reagent results in 2-ferrocenvl-thieno[2,3- b]quinoxaline (9). The new compounds have been characterized by their 1H, 13C NMR, and mass spectra. The molecular structures of 4-ferrocenyl-4-oxo-2-phenylamino-but-2-enoic acid ethyl ester 2, and of 4 and 9 have been determined by X-ray crystal structure analysis.
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Apreutesei, Daniela, Gabriela Lisa, Natalia Hurduc, and Dan Scutaru. "Synthesis and un-isotherm kinetic study of some ferrocene acids." Open Chemistry 2, no. 4 (December 1, 2004): 553–62. http://dx.doi.org/10.2478/bf02482720.

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AbstractThe goal of this paper is to study thermal stability of some ferrocenes with acidic functional groups. Some other kinetic characteristics such as critical temperature and the rate constant corresponding to maximal degradation speed have been also evaluated. The type of functional units adjacent to the ferrocenyl unit determines thermal stability of ferrocene compounds. Groups with a powerful withdrawing effect determine a decreasing of the temperatures at which the material starts to lose weight. If a very long alkyl chain is connected to the ferrocene unit, a shielding effect in respect to the other carboxylic groups was observed, with an increase of the thermal stability.
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Rauf, Umair, Ghulam Shabir, Saba Bukhari, Fernando Albericio, and Aamer Saeed. "Contemporary Developments in Ferrocene Chemistry: Physical, Chemical, Biological and Industrial Aspects." Molecules 28, no. 15 (July 30, 2023): 5765. http://dx.doi.org/10.3390/molecules28155765.

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Ferrocenyl-based compounds have many applications in diverse scientific disciplines, including in polymer chemistry as redox dynamic polymers and dendrimers, in materials science as bioreceptors, and in pharmacology, biochemistry, electrochemistry, and nonlinear optics. Considering the horizon of ferrocene chemistry, we attempted to condense the neoteric advancements in the synthesis and applications of ferrocene derivatives reported in the literature from 2016 to date. This paper presents data on the progression of the synthesis of diverse classes of organic compounds having ferrocene scaffolds and recent developments in applications of ferrocene-based organometallic compounds, with a special focus on their biological, medicinal, bio-sensing, chemosensing, asymmetric catalysis, material, and industrial applications.
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Fleischer, Ivana, and Štefan Toma. "Synthesis of New Chiral 1,2-Disubstituted Ferrocenes." Collection of Czechoslovak Chemical Communications 69, no. 2 (2004): 330–38. http://dx.doi.org/10.1135/cccc20040330.

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Synthesis of six chiral 1,2-disubstituted ferrocene derivatives is described starting from (S)-{[2-(methoxymethyl)pyrrolidin-1-yl]methyl}ferrocene (2) and {[N-((1R,2S)-methoxy-1-methyl-2-phenethyl)-N-methylamino]methyl}ferrocene (3). Oxidation of the (N-substituted aminomethyl)ferrocenes with active MnO2 furnished the corresponding 2-substituted ferrocenecarbaldehydes.
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7

Rajakumar, Perumal, Ramasamy Anandhan, and Ayyavoo Kannan. "1,2,3-Triazole Ferrocenyldendrimers Through Click Chemistry Approach and their Optical and Electrochemical Properties." Australian Journal of Chemistry 65, no. 10 (2012): 1457. http://dx.doi.org/10.1071/ch12166.

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Novel ferrocenyl dendrimers with ferrocene as a surface group and with triazole as a bridging unit have been synthesised through click chemistry. The increasing numbers of triazole and ferrocenyl units at the antenna increase the light absorbing ability. The electrochemical behaviour changes with increasing ferrocenyl and triazole units.
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Sobociková, Marie, Petr Štěpnička, Daniele Ramella, and Martin Kotora. "Synthesis of 1-Alkanoyl-1'-(trifluoroacetyl)ferrocenes." Collection of Czechoslovak Chemical Communications 71, no. 2 (2006): 190–96. http://dx.doi.org/10.1135/cccc20060190.

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Synthesis of the first representatives of mixed acyl(perfluoroacyl)ferrocenes, 1-acetyl-1'-(trifluoroacetyl)ferrocene (3a) and 1-propionyl-1'-(trifluoroacetyl)ferrocene (3b), by stepwise Friedel-Crafts acylation is described. A comparison of redox potentials of acetylferrocene, (trifluoroacetyl)ferrocene, and 3a as determined by cyclic voltammetry shows that the substitution effect is not purely additive.
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Sinha, Neeta. "Synthesis of 3-Ferrocenyl Isocoumarins." Oriental Journal Of Chemistry 36, no. 05 (October 25, 2020): 976–79. http://dx.doi.org/10.13005/ojc/360527.

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The derivatives of 3-ferrocenyl isocoumarin were synthesized by the condensation of substituted homothphalic anhydride with ferrocene using phosphoric acid or anhydrous aluminium chloride as cyclising agent. Substituted homophthalic acid did not condense with ferrocene so homophthalic acids were converted into their anhydride and then allowed to react with ferrocene in the presence of polyphosphoric acid or in the presence of anhydrous aluminium chloride using dichloromethane as the solvent to give 3-ferrocenyl isocoumarins. 7-Methoxy, 6-methyl, 5,7-dihydroxy, 6,7-dimethoxy and 5,7-dimethoxy derivatives of 3-ferrocenyl isocoumarin were synthesized. All the compounds were characterised by melting point determination, elemental and spectral analysis.
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Montes-González, Ingrid, Ambar M. Alsina-Sánchez, Juan C. Aponte-Santini, Sara M. Delgado-Rivera, and Geraldo L. Durán-Camacho. "Perspectives of ferrocenyl chalcones: synthetic scaffolds toward biomedical and materials science applications." Pure and Applied Chemistry 91, no. 4 (April 24, 2019): 653–69. http://dx.doi.org/10.1515/pac-2018-0802.

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Abstract Ferrocene and its derivatives constitute versatile and interesting scaffolds for the global chemical enterprise due to its multiple applications that range from biomedical to materials science. Ferrocenyl derivatives are the leading compounds in our research for the syntheses and characterization as well as their potential biological applications. Among them, our recent focus has been in ferrocenyl chalcones as a framework for further derivatization. The proposed modifications consist on the incorporation of heterocyclic moieties into the ferrocenyl chalcone core. This can be afforded either by introducing a heterocyclic aromatic moiety as a substituent or functionalizing the α-β unsaturated system. Another modification explored is the formation of ammonium or pyridinium salts to increase water solubility. Studied ferrocenyl chalcones exhibit remarkable stability, physical, and electrochemical properties. These factors have led the approaches for them to be precursors of biologically active compounds (cancer, bacteria, malaria, and neurobiological diseases). Moreover, other potential applications include molecular materials, redox-sensors, and polymers. Our goal in this mini review is to highlight the chemistry of ferrocene derivatives with particular prominence to those ferrocenyl chalcones studied in our laboratory and their applications. Moreover, we are providing a background on ferrocene, chalcones, and ferrocenyl chalcones, emphasizing the methodologies with preeminent yields.
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Dissertations / Theses on the topic "Ferrocene Chemistry"

1

Kedge, Jonathan L. "Synthesis of ferrocene nucleic acid monomers and ferrocene containing drug candidates." Thesis, University of Birmingham, 2017. http://etheses.bham.ac.uk//id/eprint/7424/.

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The first ferrocene nucleic acid (FcNA) was reported by the Tucker group in 2012. Furnished with two nucleobases and two hydroxyl groups, the tetrasubstituted metallocene assumes the position traditionally occupied by the two sugars of a dinucleotide. This thesis describes the successful synthesis of two FcNA monomers; a tetrasubstituted dithyminyl variation and a disubstituted control compound bearing no nucleobases. These monomers were oligomerised, their binding characteristics assessed by thermal melting studies, and compared to other monomers belonging to the group. Through the study of these compounds the Tucker group has demonstrated that FcNA monomers behave similarly to conventional nucleic acids, displaying selective H-bonding and π-stacking interactions within a hybrid duplex. A preliminary methodology for the production of diguaninyl FcNA monomers was also explored. As published in 2014, the corresponding disubstituted systems, in which a hydroxyl and a nucleobase are linked through a sugar-like ferrocene unit, are also being investigated as potential nucleoside analogues. Adding to the groups growing library, a number of related compounds were synthesised in which the hydroxyl linker length, the planar chirality, the substitution pattern of the ferrocene and the nucleobase were varied. The compounds were electrochemically characterised and assessed for their biological activity which revealed interesting structure-activity-relationships involving both the redox potentials and chirality. Following the example of ferroquine and ferrocifen, in which existing pharmaceuticals are modified through the incorporation of ferrocene, the synthesis and preliminary biological activity of novel ferrocenyl β-blockers, in which the metallocene replaces the napthol unit of the prototypical β-blocker propranolol, is reported herein.
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Kelly, Michael Jon. "Hybrid ferrocene-based systems." Thesis, University of Oxford, 2014. http://ora.ox.ac.uk/objects/uuid:fd46594d-98d6-4f8a-a6ab-eb5ee74ba7f3.

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This thesis explores the capacity of sterically and electronically unsaturated boranes to bind substrates of biological and environmental interest, and transduce such binding events into a photo-physical and/or electrochemical response, hence reporting the presence of these substrates. Chapter three details the synthesis of a range of novel ferrocenyl boranes featuring either a proximal hydrogen-bond donor or a second Lewis acidic centre. These novel boranes were shown to be competent at binding both cyanide and fluoride anions, with the role played by a proximal hydrogen-bond donor or a second Lewis acidic centre in anion binding investigated by both NMR and crystallographic studies. Chapter four reports the synthesis of novel pyridinyl and related boronic esters, as well as unexpected mixed alkenyl/aryl boranes. The capacity of both types of system to bind fluoride or cyanide anions in solution was investigated by UV-Vis and NMR studies. The photo-physical responses to these anions were also probed, leading to the establishment of both switch-on and switch-off fluorescent responses. Chapter five extends the knowledge derived from selective anion receptor design and combines this with recent developments in the field of frustrated Lewis pairs (FLPs) to activate, bind and report the presence of nitrous oxide (N2O) molecule. Thus, the syntheses of novel, highly Lewis acidic ferrocenyl boranes that incorporate a high degree of steric loading around the boron centre are reported. The electrochemical and photo-physical response of an FLP system to the presence of N2O was investigated leading to the development of a novel N2O reporting system.
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Sachsinger, Niki. "Redox-active ligands containing ferrocene." Thesis, King's College London (University of London), 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.266646.

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Mirri, Giorgio. "Ferrocene-based electrochemical chiral sensors." Thesis, University of Birmingham, 2011. http://etheses.bham.ac.uk//id/eprint/3140/.

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Chiral recognition, determination of enantiomeric excess and the separation of enantiomers are challenging problems for the chemist. This work has as its aim the design and syntheses of new electrochemical chiral receptors for neutral molecules. All the receptors prepared contain a ferrocene group as electroactive reporting unit. The differences among the receptors mainly relate to the binding site and the chiral group. The first type of receptor, presented in Chapter 2, consists of chiral ferrocene containing boronic acids that have been used to electrochemically sense aromatic and aliphatic chiral and achiral diols. The electrochemical determination of the enantiomeric excess of a mixture of two enantiomers of Binol performed with one of these boronic acids represents a new advance in supramolecular chiral sensing. In Chapter 3 the synthesis of ferrocene-containing chiral macrocycles of different sizes is described. The binding site is a cavity featuring a diamidopyridine moiety, with the chirality introduced through a Binol unit. These receptors showed low interaction with achiral cyclic ureas and chiral carboxylic acids. Chapter 4 describes the study of self-assembled monolayers onto gold surfaces. The monolayers are formed by ferrocene-containing amides of lipoic (thioctic) acid and, for the first time, isolipoic acid. The studies indicate that isolipoic acid could be an attractive anchor group for SAM formation when strong control over the chirality of the monolayer is required.
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Sansook, Supojjanee. "Biological evaluation of ferrocene derivatives." Thesis, University of Sussex, 2017. http://sro.sussex.ac.uk/id/eprint/68599/.

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Organometallic complexes containing transition metals, such as Ru(II), Os(II), Ir(III), have been moderately and recently used in medicinal chemistry as anticancer, antimalarial, antimicrobial or diagnostic agents. Current trends have led researchers to explore and define new synthetic methods in the quest for the design of new drugs and reduce the inherit associated toxic side-effects by using metal based compounds. Ferrocene based derivatives have been subjected to study for their biological and medicinal applications. Examples include ferrocenophane polyphenol, ferrocenyl quinone methides, ferrocenyl-aminoquinoline-carboxamide and a ferrocene-substituted hydroxytamoxifen, which has been proved as a potential new breast cancer therapeutic. Ferroquine displays antimalarial activity and ferrocifen is a tamoxifen-ferrocene anticancer agent. During the course of our research, we have focused on synthesizing and studying the biological activity of novel organometallic compounds containing the corresponding ferrocene moiety. We aimed to make, at least, 3 different families of compounds, which were cannabinoid receptor (CB1/CB2 receptor agonists), histone deacetylase (HDAC) selective inhibitors and general kinase inhibitors. Firstly, a review covering the state-of-the-art in bioorganometallic chemistry will be presented. Secondly, we started with the synthesis of a small library of compounds containing the following groups: ferrocenylamine, 4-oxo-1, 4-dihydropyridine and dihydroquinoline. We used aminoferrocene as a bioisostere of the adamantylamine group where previous studies of compounds containing the latter group had showed it to effectively interact with the cannabinoid receptors, CB1 and CB2. Some of our compounds displayed good to excellent potency in the nM range against the CB1 and CB2 receptors. Thirdly, we embarked to synthesise HDAC inhibitors knowing their potential as anti-cancer drugs and trying to obtain, wherever possible, enzyme isoform selectivity. One of the well-known HDAC inhibitors is suberoylanilide hydroxamic acid (SAHA). Vorinastat, as it is also known, has received Food and Drug Administration approval for treating patients with cutaneous T-cell lymphoma. The compound developed in our group by replacing ferrocene for the phenyl ring in SAHA, called JAHA, is another example of a highly potent HDAC inhibitor. Our research led to compounds where the hydroxamic acid moiety in JAHA has been replaced by a benzamide group. This transformation has produced a significant effect in delivering a potent HDAC3 selective HDAC inhibitor. This is supported by biological studies and a molecular modelling rationalisation. Next, a series of oxindole based analogues have been synthesized by the Knoevenagel condensation reaction of: 5-(pentafluorosulfanyl)-1,3-dihydro-indol-2-one and 6-(pentafluorosulfanyl)-1,3-dihydro-indol-2-one compound with: ferrocenecarboxaldehyde and pyrrole-2-carboxaldehyde. The compounds thereby synthesised have been studied against a panel of kinases, and kinase inhibitory data will be discussed and presented. In a Future directions section, we will describe the synthesis of FAAH (fatty acid amide hydrolase) inhibitors based on an aminoferrocene backbone.
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Broomsgrove, Alexander Edward John. "Ferrocene based Lewis acids for anion sensing." Thesis, University of Oxford, 2010. http://ora.ox.ac.uk/objects/uuid:bfab3690-f1de-4c8d-b111-ce9083710b16.

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The synthesis, characterisation and anion binding properties of a series of mono- and bifunctional Lewis acidic borylferrocene compounds are described within this thesis. The original parent compound FcBMes₂ (3.1), revealed a versatile route for the synthesis of such borylferrocenes and subsequently the analogous compound Fc*BMes₂ (3.2) was synthesised. The anion binding properties of (3.1) and (3.2) were investigated and both were shown to bind one equivalent of cyanide. The binding event was signalled by an electrochemical shift (ca. -560 mV) and a quenching of bands at 510 or 542 nm respectively in the UV/Vis spectrum, while the mode of anion binding in the solid state was established by X-ray crystallography for [nBu₄N]⁺[(3.1)·CN]⁻. Incorporation of a suitable redox active dye (i.e. tetrazolium violet for 3.2) allowed conversion of the electrochemical response to a colorimetric change on cyanide binding. However, a competing response for fluoride is also seen for (3.1) and (3.2). Thus a two component system is reported involving (3.2) and the boronic ester FcB(OR)₂ (3.4), [where (OR)₂ = OCH(Ph)CH(Ph)O], which from previous research is known to selectively bind fluoride, and allows for selective colorimetric cyanide sensing by simple Boolean AND/NOT logic. 1,4-C₆H₄(BMes₂)[B(OR)₂] (3.5), 4,4-C12H₈(BMes₂)[B(OR)₂] (3.6) and 1,1′-fc(BMes2)(B(OR)2) (3.7) were synthesised as possible single molecules for discrimination between cyanide and fluoride. (3.5) and (3.6) proved only capable of binding one equivalent of either anion, (3.7) showed some ability to bind two equivalents of fluoride however based on ESI-MS studies although only in the presence of a large excess of anion. Systematic variation of the para-boryl substituent was investigated by synthesis of compounds FcB(XylF)₂ (4.1), FcB(Xyl)₂ (4.2) and FcB(XylOMe)₂ (4.3). Anion binding studies reveal a linear increase in fluoride binding affinity consistent with that expected based on the para,/em>-Hammett parameters, however with only minor differences, while no pattern is observed with respect to their cyanide binding capabilities. The addition of neutral and cationic peripheral substituents has been investigated through synthesis of [1,2-fc(CH₂NMe₂)BMes₂] (4.6) and [1,2-fc(CH₂NMe₃)BMes₂]⁺ (4.7). Subsequent binding studies revealed (4.6) to be moisture sensitive, however reaction of (4.7) with fluoride and cyanide led to formation of the adducts [(4.7)·F]⁻ and [(4.7)·CN]⁻. The anion affinity of (4.7) exhibits a substantial increase when compared to the parent compound (3.1). Even when compared to the isomeric 1,1′ system an increase of approximately three orders of magnitude is seen attributed to the closer nature of the cationic charge and in the fluoride adduct the presence of a cooperative intramolecular hydrogen bond. The 1,1′-bifunctional analogues of the mono-substituted systems were synthesised [e.g. 1,2-fc(BMes₂)₂ (5.1)] and shown to complex two equivalents of fluoride or cyanide in acetonitrile. The 1:1 cyanide adduct of (5.1) was isolated in chloroform however, no evidence for chelation was observed. The analogous systems 1,2-fc(BMes₂)₂ (5.5), 1,2-fc(BXyl₂)2 (5.7), and 1,2-fc(BMes₂)(BXyl₂) (5.8) were also investigated. Reaction of (5.5) with fluoride and cyanide revealed it to bind only one equivalent of either anion, neither however was bound in a chelating fashion although X-ray crystallography revealed cyanide binds exo whilst fluoride binds endo to the B···B cavity. Finally the kinetics of fluoride binding were studied by UV/Vis spectroscopy and showed a systematic increase in rate constant upon reduction of steric bulk.
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Cho, Yongjin. "Chiral ferrocene ligands for asymmetric cross coupling." Thesis, Imperial College London, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.300034.

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Humphries, Kristina. "Synthesis and reactivity of chiral ferrocene complexes." Thesis, Keele University, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.265643.

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Winder, Robert John. "The synthesis of some ferrocene substituted porphyrinic macrocycles." Thesis, University of Nottingham, 1992. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.315068.

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Herbert, Simon Anthony. "Oxazoline directed lithiation of Calix[4]arene and Ferrocene." Thesis, Stellenbosch : Stellenbosch University, 2011. http://hdl.handle.net/10019.1/17867.

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Thesis (PhD)--Stellenbosch University, 2011.
ENGLISH ABSTRACT: The use of chiral oxazoline directed lithiation provides a highly diastereoselective (up to >99% de) route to meta functionalised inherently chiral calixarenes. This methodology can be used on both the butylated and debutylated calixarene systems and is tolerant of a wide range of different electrophillic quenches allowing access to a structurally diverse range of inherently chiral metafunctionalised calixarenes. The oxazoline directing group can be removed via hydrolysis, generating a range of functionalised calixarene carboxylic acids in high ee. We also demonstrate that the use of derivative alkyllithiums such as cyclopentyl lithium can provide significantly enhanced diastereoselectivity over the conventional organolithiums such as sec-butyl lithium, when employed in ortholithiation reactions of this nature. The differences in diastereoselectivity associated with the different alkyllithiums can be tied, in certain cases, to the steric bulkiness associated with the individual reagents. In this regard we have found that the use of the so called Tolman angle or cone angle approach allows quantification of the relative steric bulk of the alkyllithium. We also detail that the oxazoline directing group provides a hitherto unknown ability to be diastereoselectively tuned through the choice of the ligand system in the ortholithiation reaction. In this regard the development of a series of diglyme based ligands have proved to provide a highly diastereoselective means of inverting the chirality from that which the use of the conventional TMEDA ligand is able to generate (up to –92% de). The use of diglyme ligands to invert the sense of chirality is also shown to occur on the ferrocenyloxazoline system and presents an apparently general and hitherto unknown facet of asymmetric oxazoline directed ortholithiation. This diglyme induced inversion has been shown to be controlled through a secondary nitrogen coordinated mechanism that is able to operate with chiral oxazolines.
AFRIKAANSE OPSOMMING: Die gebruik van chirale oksasoliengerigte litiëring verskaf ’n hoogs diastereoselektiewe (tot en met >99% do) roete om metagefunksionaliseerde, inherente chirale calixareen produkte te sintetiseer. Deur gebruik te maak van verskillende elektrofiele kan die metodologie toegepas word op beide gebutileerde en de-gebutileerde calixareen sisteme om ’n reeks uiteenlopende inherente chirale, meta-gefunksionaliseerde calixareen produkte te vorm. Die oksasolien groep kan daarna verwyder word deur hidroliese om ’n reeks gefunksionaliseerde calixareenkarboksielsure te vorm in baie hoë eo. Ons het ook gedemonstreer dat die gebruik van afgeleide alkiel-litiums, soos siklopentiel-litium, kan bydrae tot aansienlik verhoogde diastereoselektiwiteit as dit vergelyk word met meer algemene organolitiums soos sekbutiellitium, tydens ortolitiëring reaksies van hierdie natuur. Die verskille in diastereoselektiwiteit kan verbind word, in sekere gevalle, tot die steriese bonkigheid van die individuele reagense. Deur gebruik te maak van die sogenaamde Tolmanhoeke of die koniesehoek benadering is dit moontlik om die relatiewe steriese bonkighied van alkiellitiums te kwantifiseer. Daar was ook bepaal dat die oksasoliengroep die ongekende vermoë besit om die diastereoselektiwiteit van die produk te stem deur die keuse van verskillende ligand sisteme tydens die ortolitiëring reaksie. Daar was bepaal dat die chiralitiet van die produkte omgekeer kan word op ’n hoogs diastereoselektiewe manier, deur gebruik te maak van ’n reeks ontwikkelde diglymegebaseerde ligande, indien dit vergelyk word met die produkte wat deur die konvensionele TMEDA gegenereer was (tot en met –92% do). Die gebruik van diglyme ligande was ook getoets op ferroseenoksasolien sisteme en dit was bevind dat dieselfde omkering in chiraliteit ook plaasvind wat aanleiding kan gee tot 'n oënskynlik algemene en tot nou toe onbekende faset van asimmetriese oksasoliengerigte orto-litiëring. Dit is bepaal dat hierdie diglyme geïnduseerde omkering in chiraliteit beheer word deur middel van 'n sekondêre stikstofgekoördineerde meganisme, wat in staat is om saam te werk met chirale oksasoliene.
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Books on the topic "Ferrocene Chemistry"

1

Xue-Long, Hou, ed. Chiral ferrocenes in asymmetric catalysis. Weinheim: Wiley-VCH, 2010.

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ößmar-Wolf, Marianne, Adolf Slawisch, R. Bohrer, U. Nohl, and H. J. Richter-Ditten. Fe Organoiron Compounds: Ferrocene 10. Springer London, Limited, 2013.

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Rudolph, E., Adolf Slawisch, R. Bohrer, U. Nohl, H. J. Richter-Ditten, and Marianne Drößmar-Wolf. Fe Organoiron Compounds: Ferrocene 10. Springer, 2013.

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Slawisch, Adolf, Edgar Rudolph, and Marianne Drössmar-Wolf. Fe Organoiron Compounds: Mononuclear Disubstituted Ferrocene Derivatives with C-, H-, and O-Containing Substituents. Springer, 1986.

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Mark, James E., Harry R. Allcock, and Robert West. Inorganic Polymers. Oxford University Press, 2005. http://dx.doi.org/10.1093/oso/9780195131192.001.0001.

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Polymer chemistry and technology form one of the major areas of molecular and materials science. This field impinges on nearly every aspect of modern life, from electronics technology, to medicine, to the wide range of fibers, films, elastomers, and structural materials on which everyone depends. Although most of these polymers are organic materials, attention is being focused increasingly toward polymers that contain inorganic elements as well as organic components. The goal of Inorganic Polymers is to provide a broad overview of inorganic polymers in a way that will be useful to both the uninitiated and those already working in this field. There are numerous reasons for being interested in inorganic polymers. One is the simple need to know how structure affects the properties of a polymer, particularly outside the well-plowed area of organic materials. Another is the bridge that inorganic polymers provide between polymer science and ceramics. More and more chemistry is being used in the preparation of ceramics of carefully controlled structure, and inorganic polymers are increasingly important precursor materials in such approaches. This new edition begins with a brief introductory chapter. That is followed with a discussion of the characteristics and characterization of polymers, with examples taken from the field. Other chapters in the book detail the synthesis, reaction chemistry, molecular structure, and uses of polyphosphazenes, polysiloxanes, and polysilanes. The coverage in the second edition has been updated and expanded significantly to cover advances and interesting trends since the first edition appeared. Three new chapters have been added, focusing on ferrocene-based polymers, other phosphorous-containing polymers, and boron-containing polymers; inorganic-organic hybrid composites; and preceramic inorganic polymers.
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Book chapters on the topic "Ferrocene Chemistry"

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Hillard, Elizabeth A., Anne Vessières, and Gerard Jaouen. "Ferrocene Functionalized Endocrine Modulators as Anticancer Agents." In Topics in Organometallic Chemistry, 81–117. Berlin, Heidelberg: Springer Berlin Heidelberg, 2010. http://dx.doi.org/10.1007/978-3-642-13185-1_4.

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Kaifer, Angel E. "Ferrocene as a Building Block for Supramolecular Chemistry Systems." In Transition Metals in Supramolecular Chemistry, 227–43. Dordrecht: Springer Netherlands, 1994. http://dx.doi.org/10.1007/978-94-015-8380-0_12.

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Gokel, George W., Julio C. Medina, Chensheng Li, Timothy T. Goodnow, Maria T. Rojas, Jeanette C. Hernandez-Medina, Servando Muñoz, Akio Nakano, Jerry L. Atwood, and Angel E. Kaifer. "Ferrocene as the Central Unit in Novel, Redox-Sensitive Ligands, Monomers, and Receptors." In Supramolecular Chemistry, 429–42. Dordrecht: Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2492-8_29.

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Blas, A. M., G. Santis, L. Fabbrizzi, M. Licchelli, P. Pallavicini, and A. Poggi. "Multi-Electron Redox Activity of Supramolecular Coordination Compounds Containing Metallocyclam and Ferrocene Fragments." In Supramolecular Chemistry, 87–103. Dordrecht: Springer Netherlands, 1992. http://dx.doi.org/10.1007/978-94-011-2492-8_6.

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Pinto, Patrícia, Maria J. Calhorda, Vitor Félix, Teresa Avilés, and Michael G. B. Drew. "Syntheses and Crystal Structures of Polynuclear Cu(I) Complexes Containing the 1,1′-Bis-(diphenylphosphino)-ferrocene Ligand." In Organometallic Chemistry and Catalysis, 29–41. Vienna: Springer Vienna, 2001. http://dx.doi.org/10.1007/978-3-7091-6274-3_3.

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Varret, F., H. Rabah, J. Guillin, and D. Talham. "An Example of the Influence of the Ligand Field on the Electron Localisation: The Mixed Valence Ferrocene-Ferricinium." In Mixed Valency Systems: Applications in Chemistry, Physics and Biology, 359–64. Dordrecht: Springer Netherlands, 1991. http://dx.doi.org/10.1007/978-94-011-3606-8_24.

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Manoury, Eric, and Rinaldo Poli. "Phosphine-Containing Planar Chiral Ferrocenes: Synthesis, Coordination Chemistry and Applications to Asymmetric Catalysis." In Phosphorus Compounds, 121–49. Dordrecht: Springer Netherlands, 2011. http://dx.doi.org/10.1007/978-90-481-3817-3_5.

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Kausar, Samia, Ataf Ali Altaf, Muhammad Hamayun, Amin Badshah, and Abdul Razzaq. "Supramolecular Chemistry and DNA Interaction Studies of Ferrocenyl Ureas and Thioureas." In Photophysics, Photochemical and Substitution Reactions- Recent Advances [Working Title]. IntechOpen, 2020. http://dx.doi.org/10.5772/intechopen.84412.

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In this chapter, we have discussed the characteristics and bioapplicabilities of different ferrocene derivatives, for example, amides, amines, sulfonamide, and polymers, focusing mainly on urea and thiourea derivatives due to their autonomous and widespread spectroscopic action and bioactivities. Supramolecular chemistry of ferrocenyl ureas and thioureas is described owing to exploring their mode of interactions within and among the molecules and the role of these supramolecular structures in enhancing the DNA intercalation. DNA interaction studies of these ferrocenyl-based ureas and thioureas are explored with approaches like electrochemical study, viscosity measurements, molecular docking, electronic spectroscopy, dynamic light scattering (DLS), and radical scavenging activity. Attachment of ferrocene moiety to ureas an thiouereas closer to DNA is very promising strategy which most possibly boosts the probability of DNA damage and cell apoptosis which is responsible for enormous biological activities.
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Falcone, Natashya, and Heinz-Bernhard Kraatz. "Ferrocene Peptide-based Supramolecular Gels." In Advances in Bioorganometallic Chemistry, 57–74. Elsevier, 2019. http://dx.doi.org/10.1016/b978-0-12-814197-7.00003-0.

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Schäfer, André. "Ferrocene and Related Metallocene Polymers." In Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Elsevier, 2021. http://dx.doi.org/10.1016/b978-0-12-820206-7.00138-4.

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Conference papers on the topic "Ferrocene Chemistry"

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Barberá, Joaquín, Fernando Langa, Robert Deschenaux, Stéphane Campidelli, Laura Pérez, and Julián Rodríguez-López. "Dendritic Liquid-Crystalline Fullerene-Ferrocene Dyads." In The 9th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2005. http://dx.doi.org/10.3390/ecsoc-9-01648.

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Chatelain, Grégory, and Carole Chaix. "Thermodynamic studies of ferrocene modified hairpin oligonucleotides." In XIVth Symposium on Chemistry of Nucleic Acid Components. Prague: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, 2008. http://dx.doi.org/10.1135/css200810358.

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Jangid, Vikas, Damien Brunel, Esteban Sanchez Adaime, Anil Kumar Bharwal, David Duche, Fréderic Dumur, Gérard Berginc, Rose Marie Sauvage, Chrystelle Lebouin, and Ludovic Escoubas. "Bi-ferrocene based molecular rectifier for nano-patch rectenna device." In Physical Chemistry of Semiconductor Materials and Interfaces XX, edited by Daniel Congreve, Christian Nielsen, Andrew J. Musser, and Derya Baran. SPIE, 2021. http://dx.doi.org/10.1117/12.2595192.

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Srihakulung, Ornin. "The study of computational chemistry simulation of Ferrocene for solid propellant." In 2015 Asian Conference on Defence Technology (ACDT). IEEE, 2015. http://dx.doi.org/10.1109/acdt.2015.7111600.

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Comasseto, João, Rogério Gariani, Fábio Simonelli, Alfredo Oliveira, and Andersson Barison. "A Chiral Tellurium Ferrocene as a Chiral Agent in NMR Enantiomeric Purity Determination." In The 10th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2006. http://dx.doi.org/10.3390/ecsoc-10-01434.

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Rodríguez-Otero, Jesús, Enrique Cabaleiro-Lago, Angeles Peña-Gallego, and M. Montero-Campillo. "Study of the Lithium Cation-Ferrocene Interaction by DFT Calculations: an In-Depth Analysis of the Existence of a Planetary System." In The 12th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2008. http://dx.doi.org/10.3390/ecsoc-12-01285.

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Imrie, Christopher, Christa Loubser, Pieter Engelbrecht, Cedric McCleland, Nomefuneko Tolem, and Vincent Nyamori. "Synthetic Methods to Ferrocenomesogens containing a Pendent Ferrocenyl Group." In The 4th International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 2000. http://dx.doi.org/10.3390/ecsoc-4-01858.

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Imrie, Christopher, Christa Loubser, Pieter Engelbrecht, and Cedric McCleland. "Synthesis and Characterization of Ferrocenomesogens containing a Pendent Ferrocenyl Group." In The 1st International Electronic Conference on Synthetic Organic Chemistry. Basel, Switzerland: MDPI, 1997. http://dx.doi.org/10.3390/ecsoc-1-02037.

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