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1

Modak, Monami Das, Ganesh Damarla, Somedutta Maity, Anil K. Chaudhary, and Pradip Paik. "Self-assembled pearl-necklace patterned upconverting nanocrystals with highly efficient blue and ultraviolet emission: femtosecond laser based upconversion properties." RSC Advances 9, no. 65 (2019): 38246–56. http://dx.doi.org/10.1039/c9ra06389g.

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2

Schanz, R., S. A. Kovalenko, V. Kharlanov, and N. P. Ernsting. "Broad-band fluorescence upconversion for femtosecond spectroscopy." Applied Physics Letters 79, no. 5 (July 30, 2001): 566–68. http://dx.doi.org/10.1063/1.1387257.

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3

A. S., Ashik, Callum F. O’Donnell, S. Chaitanya Kumar, M. Ebrahim-Zadeh, P. Tidemand-Lichtenberg, and C. Pedersen. "Mid-infrared upconversion imaging using femtosecond pulses." Photonics Research 7, no. 7 (June 24, 2019): 783. http://dx.doi.org/10.1364/prj.7.000783.

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4

Kee, Tak W., Ramkrishna Adhikary, Philip J. Carlson, Prasun Mukherjee, and Jacob W. Petrich. "Femtosecond Fluorescence Upconversion Investigations on the Excited-State Photophysics of Curcumin." Australian Journal of Chemistry 64, no. 1 (2011): 23. http://dx.doi.org/10.1071/ch10417.

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The demonstration of curcumin as a photodynamic therapy agent has generated a high level of interest in understanding the photoinduced chemical and physical properties of this naturally occurring, yellow-orange medicinal compound. Important photophysical processes that may be related to photodynamic therapy effects including excited-state intramolecular hydrogen atom transfer (ESIHT) occur within the femtosecond to picosecond time scales. Femtosecond fluorescence upconversion spectroscopy has sufficient time resolution to resolve and investigate these important photophysical processes. In this review, recent advances in using femtosecond fluorescence upconversion to reveal ultrafast solvation and ESIHT of curcumin are presented. The excited-state photophysics of curcumin has been investigated in alcohols and micellar solutions. The results of curcumin in methanol and ethylene glycol reveal the presence of two decay components in the excited-state kinetics with time scales of 12–20 ps and ∼100 ps. Similarly, in a micellar solution, biphasic kinetics are present with the fast decay component having a time constant of 3–8 ps, the slow decay component 50–80 ps. Deuteration of curcumin in both media leads to a pronounced isotope effect in the slow decay component, which suggests that ESIHT is an important photophysical process on this time scale. The results of multiwavelength fluorescence upconversion studies show that the fast component in the excited-state kinetics is due to ultrafast solvation. These advances form a part of the continuing efforts to elucidate the photodynamic therapy properties of curcumin.
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5

Ma, Shushu, Haiyuan Wei, Hai Zhu, Francis Chi-Chung Ling, Xianghu Wang, and Shichen Su. "Higher-Order Multiphoton Absorption Upconversion Lasing Based on ZnO/ZnMgO Multiple Quantum Wells." Nanomaterials 12, no. 17 (September 4, 2022): 3073. http://dx.doi.org/10.3390/nano12173073.

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In the progress of nonlinear optics, multiphoton absorption (MPA) upconversion lasing enables many vital applications in bioimaging, three-dimensional optical data storage, and photodynamic therapy. Here, efficient four-photon absorption upconversion lasing from the ZnO/ZnMgO multiple quantum wells (MQWs) at room temperature is realized. Moreover, the MPA upconversion lasing and third-harmonic generation peak generated in the MQWs under the excitation of a femtosecond (fs) laser pulse were observed concurrently, and the essential differences between each other were studied comprehensively. Compared with the ZnO film, the upconversion lasing peak of the ZnO/ZnMgO MQWs exhibits a clear blue shift. In addition, the four-photon absorption upconversion photoluminescence (PL) intensity was enhanced in the MQWs/Au nanoparticles (NPs) by the metal-localized surface plasmons (LSPs). The work paves the way for short-wavelength lasers by taking advantage of the high stability and large exciton binding energy of the MQWs’ structures.
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6

Kuzucu, Onur, Franco N. C. Wong, Sunao Kurimura, and Sergey Tovstonog. "Time-resolved single-photon detection by femtosecond upconversion." Optics Letters 33, no. 19 (September 30, 2008): 2257. http://dx.doi.org/10.1364/ol.33.002257.

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7

Li, Ruonan, Lifei Sun, Yangjian Cai, Yingying Ren, Hongliang Liu, Mark D. Mackenzie, and Ajoy K. Kar. "Near-infrared lasing and tunable upconversion from femtosecond laser inscribed Nd,Gd:CaF2 waveguides." Chinese Optics Letters 19, no. 8 (2021): 081301. http://dx.doi.org/10.3788/col202119.081301.

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8

Bennett, C. V., and B. H. Kolner. "Upconversion time microscope demonstrating 103× magnification of femtosecond waveforms." Optics Letters 24, no. 11 (June 1, 1999): 783. http://dx.doi.org/10.1364/ol.24.000783.

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9

Gerecke, Mario, Genaro Bierhance, Michael Gutmann, Nikolaus P. Ernsting, and Arnulf Rosspeintner. "Femtosecond broadband fluorescence upconversion spectroscopy: Spectral coverage versus efficiency." Review of Scientific Instruments 87, no. 5 (May 2016): 053115. http://dx.doi.org/10.1063/1.4948932.

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10

Zhao, Lijuan, J. Luis Pérez Lustres, Vadim Farztdinov, and Nikolaus P. Ernsting. "Femtosecond fluorescence spectroscopy by upconversion with tilted gate pulses." Phys. Chem. Chem. Phys. 7, no. 8 (2005): 1716–25. http://dx.doi.org/10.1039/b500108k.

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11

Yang Zhang, Yang Zhang, Quanzhong Zhao Quanzhong Zhao, Huaihai Pan Huaihai Pan, Chengwei Wang Chengwei Wang, Jing Qian Jing Qian, and and Zhanshan Wang and Zhanshan Wang. "Simultaneous upconversion luminescence and color centers generated by femtosecond laser irradiation of LiF crystals." Chinese Optics Letters 14, no. 8 (2016): 083201–83205. http://dx.doi.org/10.3788/col201614.083201.

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12

Zhang, X. X., C. Würth, L. Zhao, U. Resch-Genger, N. P. Ernsting, and M. Sajadi. "Femtosecond broadband fluorescence upconversion spectroscopy: Improved setup and photometric correction." Review of Scientific Instruments 82, no. 6 (June 2011): 063108. http://dx.doi.org/10.1063/1.3597674.

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13

Moll, Johannes, William J. Harrison, Donald V. Brumbaugh, and Annabel A. Muenter. "Exciton Annihilation in J-Aggregates Probed by Femtosecond Fluorescence Upconversion." Journal of Physical Chemistry A 104, no. 39 (October 2000): 8847–54. http://dx.doi.org/10.1021/jp993154d.

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14

Cannizzo, A., O. Bräm, G. Zgrablic, A. Tortschanoff, A. Ajdarzadeh Oskouei, F. van Mourik, and M. Chergui. "Femtosecond fluorescence upconversion setup with broadband detection in the ultraviolet." Optics Letters 32, no. 24 (December 12, 2007): 3555. http://dx.doi.org/10.1364/ol.32.003555.

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15

Johnson, T. A., and S. A. Diddams. "Mid-infrared upconversion spectroscopy based on a Yb:fiber femtosecond laser." Applied Physics B 107, no. 1 (October 11, 2011): 31–39. http://dx.doi.org/10.1007/s00340-011-4748-0.

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16

Han, Qiuju, Wenzhi Wu, Weilong Liu, and Yanqiang Yang. "The peak shift and evolution of upconversion luminescence from CsPbBr3nanocrystals under femtosecond laser excitation." RSC Advances 7, no. 57 (2017): 35757–64. http://dx.doi.org/10.1039/c7ra06211g.

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Compared with normal PL, a red shift of upconversion PL spectrum is observed. Time-resolved PL and TA spectroscopies show FWHM and peak position are changed at various times, which suggest the existence of more than single excited state.
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17

Anestopoulos, D., M. Fakis, I. Polyzos, G. Tsigaridas, G. Mousdis, P. Persephonis, and V. Giannetas. "Time-resolved spectroscopy of oligothiophenes using the femtosecond fluorescence upconversion technique." Journal of Physics: Conference Series 10 (January 1, 2005): 230–33. http://dx.doi.org/10.1088/1742-6596/10/1/057.

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18

Toele, P., H. Zhang, C. Trieflinger, J. Daub, and M. Glasbeek. "Femtosecond fluorescence upconversion study of a boron dipyrromethene dye in solution." Chemical Physics Letters 368, no. 1-2 (January 2003): 66–75. http://dx.doi.org/10.1016/s0009-2614(02)01834-1.

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19

Chen, Wang, Peng Mingying, Yang Lüyun, Hu Xiao, Da Ning, Chen Danping, Zhu Congshan, and Qiu Jianrong. "Upconversion Luminescence of Ce3+ Doped BK7 Glass by Femtosecond Laser Irradiation." Journal of Rare Earths 24, no. 6 (December 2006): 754–56. http://dx.doi.org/10.1016/s1002-0721(07)60023-4.

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20

Sun, Jinyu, Shian Zhang, Tianqing Jia, Zugeng Wang, and Zhenrong Sun. "Femtosecond spontaneous parametric upconversion and downconversion in a quadratic nonlinear medium." Journal of the Optical Society of America B 26, no. 3 (February 26, 2009): 549. http://dx.doi.org/10.1364/josab.26.000549.

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21

You, Hongpeng, Tomokatsu Hayakawa, and Masayuki Nogami. "Upconversion luminescence of Al2O3–SiO2:Ce3+ glass by femtosecond laser irradiation." Applied Physics Letters 85, no. 16 (October 18, 2004): 3432–34. http://dx.doi.org/10.1063/1.1808234.

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22

Dubietis, A., G. Tamošauskas, A. Varanavičius, G. Valiulis, and R. Danielius. "Generation of femtosecond radiation at 211 nm by femtosecond pulse upconversion in the field of a picosecond pulse." Optics Letters 25, no. 15 (August 1, 2000): 1116. http://dx.doi.org/10.1364/ol.25.001116.

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23

Underwood, David F., Tadd Kippeny, and Sandra J. Rosenthal. "Ultrafast Carrier Dynamics in CdSe Nanocrystals Determined by Femtosecond Fluorescence Upconversion Spectroscopy." Journal of Physical Chemistry B 105, no. 2 (January 2001): 436–43. http://dx.doi.org/10.1021/jp003088b.

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24

Humbs, W., H. Zhang, and M. Glasbeek. "Femtosecond fluorescence upconversion spectroscopy of vapor-deposited tris(8-hydroxyquinoline) aluminum films." Chemical Physics 254, no. 2-3 (April 2000): 319–27. http://dx.doi.org/10.1016/s0301-0104(00)00044-6.

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25

Gustavsson, Thomas, Alexei Sharonov, and Dimitra Markovitsi. "Thymine, thymidine and thymidine 5′-monophosphate studied by femtosecond fluorescence upconversion spectroscopy." Chemical Physics Letters 351, no. 3-4 (January 2002): 195–200. http://dx.doi.org/10.1016/s0009-2614(01)01375-6.

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26

Gustavsson, Thomas, Alexei Sharonov, Delphine Onidas, and Dimitra Markovitsi. "Adenine, deoxyadenosine and deoxyadenosine 5′-monophosphate studied by femtosecond fluorescence upconversion spectroscopy." Chemical Physics Letters 356, no. 1-2 (April 2002): 49–54. http://dx.doi.org/10.1016/s0009-2614(02)00290-7.

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27

ZHANG Yang, 张. 扬., 钱. 静. QIAN Jing, 李鹏飞 LI Peng-fei, 鲍宗杰 BAO Zong-jie, 王承伟 WANG Cheng-wei, and 赵全忠 ZHAO Quan-zhong. "Upconversion Luminescence of Mn2+Doped-germanate Glass Induced by Femtosecond Laser Pulses." Chinese Journal of Luminescence 36, no. 7 (2015): 738–43. http://dx.doi.org/10.3788/fgxb20153607.0738.

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28

van der Meer, M. J., H. Zhang, and M. Glasbeek. "Femtosecond fluorescence upconversion studies of barrierless bond twisting of auramine in solution." Journal of Chemical Physics 112, no. 6 (February 8, 2000): 2878–87. http://dx.doi.org/10.1063/1.480929.

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29

Cao, Simin, Haoyang Li, Zenan Zhao, Sanjun Zhang, Jinquan Chen, Jianhua Xu, Jay R. Knutson, and Ludwig Brand. "Ultrafast Fluorescence Spectroscopy via Upconversion and Its Applications in Biophysics." Molecules 26, no. 1 (January 3, 2021): 211. http://dx.doi.org/10.3390/molecules26010211.

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In this review, the experimental set-up and functional characteristics of single-wavelength and broad-band femtosecond upconversion spectrophotofluorometers developed in our laboratory are described. We discuss applications of this technique to biophysical problems, such as ultrafast fluorescence quenching and solvation dynamics of tryptophan, peptides, proteins, reduced nicotinamide adenine dinucleotide (NADH), and nucleic acids. In the tryptophan dynamics field, especially for proteins, two types of solvation dynamics on different time scales have been well explored: ~1 ps for bulk water, and tens of picoseconds for “biological water”, a term that combines effects of water and macromolecule dynamics. In addition, some proteins also show quasi-static self-quenching (QSSQ) phenomena. Interestingly, in our more recent work, we also find that similar mixtures of quenching and solvation dynamics occur for the metabolic cofactor NADH. In this review, we add a brief overview of the emerging development of fluorescent RNA aptamers and their potential application to live cell imaging, while noting how ultrafast measurement may speed their optimization.
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30

Huang, Yunxia, Shuwu Xu, Xianming Ji, and Xiaohua Yang. "Optimizing femtosecond laser-induced upconversion luminescence enhancement and suppression of Dy3+-doped glass." Laser Physics Letters 17, no. 1 (November 4, 2019): 016001. http://dx.doi.org/10.1088/1612-202x/ab4f65.

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31

Dong, Yongjun, Jun Xu, Guoqing Zhou, Guangjun Zhao, Mingyin Jie, LuYun Yang, Liangbi Su, Jianrong Qiu, Weiwei Feng, and Lihuang Lin. "Blue upconversion luminescence generation in Ce3+:Gd2SiO5 crystals by infrared femtosecond laser irradiation." Optics Express 14, no. 5 (2006): 1899. http://dx.doi.org/10.1364/oe.14.001899.

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32

Rosales, Tilman, Jianhua Xu, Xiongwu Wu, Milan Hodoscek, Patrik Callis, Bernard R. Brooks, and Jay R. Knutson. "Molecular Dynamics Simulations of Perylene and Tetracene Librations: Comparison With Femtosecond Upconversion Data." Journal of Physical Chemistry A 112, no. 25 (June 2008): 5593–97. http://dx.doi.org/10.1021/jp7117289.

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33

Yang, Luyun, Yongjun Dong, Danping Chen, Chen Wang, Xiao Hu, Ning Da, Guangjun Zhao, et al. "Three-photon-excited upconversion luminescence of Ce3+: YAP crystal by femtosecond laser irradiation." Optics Express 14, no. 1 (2006): 243. http://dx.doi.org/10.1364/opex.14.000243.

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34

De Belder, G., S. Jordens, M. Lor, G. Schweitzer, R. De, T. Weil, A. Herrmann, U. K. Wiesler, K. Müllen, and F. C. De Schryver. "Femtosecond fluorescence upconversion study of rigid dendrimers containing peryleneimide chromophores at the rim." Journal of Photochemistry and Photobiology A: Chemistry 145, no. 1-2 (November 2001): 61–70. http://dx.doi.org/10.1016/s1010-6030(01)00569-x.

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35

Xu, Jianhua, Xiaohua Shen, and Jay R. Knutson. "Femtosecond Fluorescence Upconversion Study of the Rotations of Perylene and Tetracene in Hexadecane." Journal of Physical Chemistry A 107, no. 41 (October 2003): 8383–87. http://dx.doi.org/10.1021/jp030113f.

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36

Yao, Yunhua, Cheng Xu, Ye Zheng, Chengshuai Yang, Pei Liu, Tianqing Jia, Jianrong Qiu, Zhenrong Sun, and Shian Zhang. "Femtosecond Laser-Induced Upconversion Luminescence in Rare-Earth Ions by Nonresonant Multiphoton Absorption." Journal of Physical Chemistry A 120, no. 28 (July 12, 2016): 5522–26. http://dx.doi.org/10.1021/acs.jpca.6b04444.

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37

Yu, Lixin, and Masayuki Nogami. "Upconversion luminescence properties of europium in ZnO–SiO2 glasses by femtosecond laser excitation." Materials Chemistry and Physics 107, no. 2-3 (February 2008): 186–88. http://dx.doi.org/10.1016/j.matchemphys.2007.08.038.

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38

Sharonov, Alexei, Thomas Gustavsson, Vincent Carré, Eric Renault, and Dimitra Markovitsi. "Cytosine excited state dynamics studied by femtosecond fluorescence upconversion and transient absorption spectroscopy." Chemical Physics Letters 380, no. 1-2 (October 2003): 173–80. http://dx.doi.org/10.1016/j.cplett.2003.09.021.

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39

Beckwith, Joseph S., Arnulf Rosspeintner, Giuseppe Licari, Markus Lunzer, Brigitte Holzer, Johannes Fröhlich, and Eric Vauthey. "Specific Monitoring of Excited-State Symmetry Breaking by Femtosecond Broadband Fluorescence Upconversion Spectroscopy." Journal of Physical Chemistry Letters 8, no. 23 (November 20, 2017): 5878–83. http://dx.doi.org/10.1021/acs.jpclett.7b02754.

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40

Wu, W. Z., Z. R. Zheng, W. L. Liu, J. P. Zhang, Y. X. Yan, Q. H. Jin, Y. Q. Yang, and W. H. Su. "Upconversion luminescence of CdTe nanocrystals by use of near-infrared femtosecond laser excitation." Optics Letters 32, no. 9 (April 3, 2007): 1174. http://dx.doi.org/10.1364/ol.32.001174.

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41

Haacke, S., R. A. Taylor, I. Bar-Joseph, M. J. S. P. Brasil, M. Hartig, and B. Deveaud. "Improving the signal-to-noise ratio of femtosecond luminescence upconversion by multichannel detection." Journal of the Optical Society of America B 15, no. 4 (April 1, 1998): 1410. http://dx.doi.org/10.1364/josab.15.001410.

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42

Kee, Tak W., Ramkrishna Adhikary, Philip J. Carlson, Prasun Mukherjee, and Jacob W. Petrich. "ChemInform Abstract: Femtosecond Fluorescence Upconversion Investigations on the Excited-State Photophysics of Curcumin." ChemInform 42, no. 22 (May 5, 2011): no. http://dx.doi.org/10.1002/chin.201122279.

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43

Yang, Luyun, Chen Wang, Yongjun Dong, Ning Da, Xiao Hu, Danping Chen, and Jianrong Qiu. "Three-photon-excited upconversion luminescence of YVO4 single crystal by infrared femtosecond laser irradiation." Optics Express 13, no. 25 (2005): 10157. http://dx.doi.org/10.1364/opex.13.010157.

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44

Nakamura, Ryosuke, Yoshizumi Inagaki, Hidefumi Hata, Norio Hamada, Nobuhiro Umemura, and Tomosumi Kamimura. "Wide-bandgap nonlinear crystal LiGaS_2 for femtosecond mid-infrared spectroscopy with chirped-pulse upconversion." Applied Optics 55, no. 33 (November 14, 2016): 9365. http://dx.doi.org/10.1364/ao.55.009365.

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45

Bhasikuttan, Achikanath C., Avinash V. Sapre, and Tadashi Okada. "Ultrafast Relaxation Dynamics from the S2State of Malachite Green Studied with Femtosecond Upconversion Spectroscopy." Journal of Physical Chemistry A 107, no. 17 (May 2003): 3030–35. http://dx.doi.org/10.1021/jp034486s.

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46

Maffeis, Valentin, Romain Brisse, Vanessa Labet, Bruno Jousselme, and Thomas Gustavsson. "Femtosecond Fluorescence Upconversion Study of a Naphthalimide–Bithiophene–Triphenylamine Push–Pull Dye in Solution." Journal of Physical Chemistry A 122, no. 25 (June 2018): 5533–44. http://dx.doi.org/10.1021/acs.jpca.8b05177.

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47

Fakis, M., I. Polyzos, G. Tsigaridas, V. Giannetas, and P. Persephonis. "Excited state dynamics of a partially conjugated polymer studied by femtosecond fluorescence upconversion spectroscopy." Chemical Physics Letters 394, no. 4-6 (August 2004): 372–76. http://dx.doi.org/10.1016/j.cplett.2004.07.030.

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48

Wang, Xinshun, Jianrong Qiu, Juan Song, Jian Xu, Yang Liao, Haiyi Sun, Ya Cheng, and Zhizhan Xu. "Simultaneous three-photon absorption induced ultraviolet upconversion in Pr3+:Y2SiO5 crystal by femtosecond laser irradiation." Optics Communications 281, no. 2 (January 2008): 299–302. http://dx.doi.org/10.1016/j.optcom.2007.09.019.

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49

Portella, Marcia T., Wilhelm Frey, and Thomas Elsaesser. "Tunable femtosecond pulses in the ultraviolet, generated by upconversion of a traveling-wave dye laser." Journal of the Optical Society of America B 9, no. 11 (November 1, 1992): 2028. http://dx.doi.org/10.1364/josab.9.002028.

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50

Yang, Lu-Yun, Yong-Jun Dong, Dan-Ping Chen, Cheng Wang, Nin Da, XiongWei Jiang, Conghan Zhu, and Jiang-rong Qiu. "Upconversion luminescence from 2E state of Cr3+ in Al2O3 crystal by infrared femtosecond laser irradiation." Optics Express 13, no. 20 (2005): 7893. http://dx.doi.org/10.1364/opex.13.007893.

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