Academic literature on the topic 'F-block metals'
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Journal articles on the topic "F-block metals"
Wilson, Robert J., Niels Lichtenberger, Bastian Weinert, and Stefanie Dehnen. "Intermetalloid and Heterometallic Clusters Combining p-Block (Semi)Metals with d- or f-Block Metals." Chemical Reviews 119, no. 14 (May 28, 2019): 8506–54. http://dx.doi.org/10.1021/acs.chemrev.8b00658.
Full textQuemet, Alexandre, Rene Brennetot, Jean-Yves Salpin, Alvaro Cimas, Colin Marsden, Jeanine Tortajada, and Pierre Vitorge. "How Can f-Block Monocations Behave as Monocations of d-Block Transition Metals?" European Journal of Inorganic Chemistry 2012, no. 22 (July 4, 2012): 3551–55. http://dx.doi.org/10.1002/ejic.201200455.
Full textRicano, Abel, Ilya Captain, Korey P. Carter, Bryan P. Nell, Gauthier J. P. Deblonde, and Rebecca J. Abergel. "Combinatorial design of multimeric chelating peptoids for selective metal coordination." Chemical Science 10, no. 28 (2019): 6834–43. http://dx.doi.org/10.1039/c9sc01068h.
Full textChen, Y. K., A. Chu, J. Cook, M. L. H. Green, P. J. F. Harris, R. Heesom, M. Humphries, J. Sloan, S. C. Tsang, and J. F. C. Turner. "Synthesis of carbon nanotubes containing metal oxides and metals of the d-block and f-block transition metals and related studies." Journal of Materials Chemistry 7, no. 3 (1997): 545–49. http://dx.doi.org/10.1039/a605652k.
Full textParker, T. Gannon, Amanda L. Chown, Austin Beehler, Divya Pubbi, Justin N. Cross, and Thomas E. Albrecht-Schmitt. "Ionothermal Synthesis of Tetranuclear Borate Clusters Containing f- and p-Block Metals." Inorganic Chemistry 54, no. 2 (January 2, 2015): 570–75. http://dx.doi.org/10.1021/ic502461d.
Full textGilge, John W., and Herbert W. Roesky. "Structurally Characterized Organometallic Hydroxo Complexes of the f- and d-Block Metals." Chemical Reviews 94, no. 4 (June 1994): 895–910. http://dx.doi.org/10.1021/cr00028a003.
Full textShabatina, Tatyana I. "Metastable complexes of some d- and f-block metals with mesogenic cyanobiphenyls." Structural Chemistry 18, no. 4 (April 5, 2007): 511–17. http://dx.doi.org/10.1007/s11224-007-9166-x.
Full textArnold, Polly L., and Stephen T. Liddle. "F-block N-heterocyclic carbene complexes." Chemical Communications, no. 38 (2006): 3959. http://dx.doi.org/10.1039/b606829d.
Full textSigel, Helmut, and Astrid Sigel. "The bio-relevant metals of the periodic table of the elements." Zeitschrift für Naturforschung B 74, no. 6 (June 26, 2019): 461–71. http://dx.doi.org/10.1515/znb-2019-0056.
Full textPatel, Dipti, and Stephen T. Liddle. "f-Element-metal bond chemistry." Reviews in Inorganic Chemistry 32, no. 1 (June 1, 2012): 1–22. http://dx.doi.org/10.1515/revic.2012.0001.
Full textDissertations / Theses on the topic "F-block metals"
Sze-To, Lap, and 司徒立. "The structural chemistry of coordination compounds containing d-block or f-block metals." Thesis, The University of Hong Kong (Pokfulam, Hong Kong), 2010. http://hub.hku.hk/bib/B45204470.
Full textKilpatrick, Alexander F. R. "Bimetallic complexes of d- and f-block metals with pentalene ligands." Thesis, University of Sussex, 2015. http://sro.sussex.ac.uk/id/eprint/53914/.
Full textZegke, Markus. "Reductive metalation of the uranyl oxo-groups with main Group-, d- and f-block metals." Thesis, University of Edinburgh, 2015. http://hdl.handle.net/1842/16186.
Full textStegmaier, Saskia [Verfasser], Thomas F. [Akademischer Betreuer] Fässler, Hubert [Akademischer Betreuer] Schmidbaur, and Karsten [Akademischer Betreuer] Reuter. "Clusters and Networks of Tetrel Elements and Late d Block Metals in Ternary Intermetallic Phases with Alkali and Alkaline Earth Metals / Saskia Stegmaier. Gutachter: Thomas F. Fässler ; Hubert Schmidbaur ; Karsten Reuter. Betreuer: Thomas F. Fässler." München : Universitätsbibliothek der TU München, 2012. http://d-nb.info/1051935032/34.
Full textBoyko, Marina [Verfasser], Thomas F. [Akademischer Betreuer] Fässler, Thomas F. [Gutachter] Fässler, and Tom [Gutachter] Nilges. "Polar Intermetallics at the Border Between Hume-Rothery and Zintl Phases : Investigations in the Systems Alkali Metal – Tin with Late Transition and p-Block Metals / Marina Boyko ; Gutachter: Thomas F. Fässler, Tom Nilges ; Betreuer: Thomas F. Fässler." München : Universitätsbibliothek der TU München, 2019. http://nbn-resolving.de/urn:nbn:de:bvb:91-diss-20190930-1516421-1-7.
Full textGermeroth, Anne Inger. "Reactivity of electropositive f-block metal N-heterocyclic carbene complexes." Thesis, University of Edinburgh, 2013. http://hdl.handle.net/1842/9519.
Full textWoodman, Timothy J. "Formation, stabilisation and reactivity of D- and F-block metal cations." Thesis, University of Warwick, 1998. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.300388.
Full textRudd, Martin D. "Macrocyclic complexation of cationic f-block (lanthanide) and p-block (groups 14 and 15) metal species." Thesis, University of Warwick, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.282539.
Full textMydlowski, Christopher Michael. "Aminopolycarboxylate complexes of d- and f- block metal ions : a synthetic and structural study." Thesis, University of Manchester, 2009. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.496326.
Full textFiguerola, i. Silvestre Albert. "Compostos moleculars mixtos d'ions del bloc "f" i "d": Estudi del comportament magnètic." Doctoral thesis, Universitat de Barcelona, 2005. http://hdl.handle.net/10803/2774.
Full textTenint en compte que fins a l'actualitat no existeix cap model que inclogui simultàniament l'efecte de l'acoblament espín-òrbita, l'efecte de la simetria del camp cristal·lí i l'intercanvi magnètic descrit pel tensor anisòtrop J, l'estudi de la interacció magnètica existent entre cadascun dels ions Ln3+ i l'ió Fe3+ en tot aquest conjunt de diferents compostos s'ha pogut estudiar mitjançant l'aplicació d'una aproximació qualitativa que permet desxifrar la naturalesa de la interacció encara que no la seva magnitud. L'aplicació del mètode ha permès estudiar l'evolució de la interacció magnètica al llarg de la sèrie d'ions lantànid(III) combinats amb l'ió ferro(III) i observar-ne la seva dependència respecte de factors externs a la naturalesa de l'ió Ln3+, al contrari del que O.Kahn et al. proposaren al 1993 en afirmar que la interacció d'un ió Ln3+ amb l'ió Cu2+ depenia única i exclusivament del mode d'acoblament entre el moment angular d'espín i l'orbital d'un mateix ió Ln3+.
La presència d'acoblament espín-òrbita en la majoria d'ions Ln3+ provoca un allunyament significatiu del valor del factor g d'aquests ions respecte del valor del factor g corresponent a l'electró lliure (2,0023). A més, la presència d'entorns cristal·lins sovint de baixa simetria provoquen una anisotropia magnètica en aquests compostos fàcilment observable a baixa temperatura, on els valors de M no segueixen la llei de Curie. L'anisotropia magnètica dels sistemes més simples (compostos dinuclears LaFe, CeCo i CeFe) va ser estudiada mitjançant mesures magnètiques de monocristall i de ressonància paramagnètica electrònica de monocristall (rpe). Tant una tècnica com l'altra van permetre confirmar la presència d'acoblament magnètic entre els ions Ce3+ i Fe3+ en el compost dinuclear CeFe, corroborant el que ja apuntava l'aplicació del mètode qualitatiu anterior per a aquest sistema. A més les magnituds i direccions de les tres components dels tenors g per als ions Ce3+ i Fe3+ van ser determinades independentment mitjançant els espectres de rpe de monocristall dels compostos dinuclears CeCo i LaFe respectivament.
La utilització de Gd3+ com a ió Ln3+ i de [Cr(CN)6]3- enlloc de [Fe(CN)6]3- en la síntesi de nous compostos mixtos 3d-4f ha simplificat molt l'estudi magnètic d'aquest tipus de sistemes ja que l'ió Gd3+ no presenta acoblament espín-òrbita, al contrari de la resta d'ions Ln3+ paramagnètics, i l'ió Cr3+ és especialment isòtrop. Això ha permès ajustar les dades magnètiques d'aquests compostos mitjançant l'ús d'un Hamiltonià d'espín isòtrop obtenint valors de la constant isòtropa d'intercanvi magnètic iguals o inferioirs a 1 cm-1, valors previsibles tenint en compte les característiques dels sistemes 3d-4f.
Finalment l'intent de sintetitzar compostos mixtos d-f d'elevada nuclearitat ha donat lloc a un sistema amb estructura tipus clúster amb un ió Ce4+ diamagnètic central, amb un paper fonamental com a ió plantilla, envoltat de vuit ions Mn3+ als quals s'uneix mitjançant múltiples lligands pont oxo. Els ions Mn3+, units mitjançant lligands pont carboxilat, mostren una interacció ferromagnètica entre ells. Paral·lelament s'obtingueren dos compostos triangulars amb tres ions Cr3+ i amb un lligand pont oxo central cadascun: el primer completament simètric mentre que el segon presenta una distorsió que dóna lloc a un triangle de simetria isòsceles. La geometria dels compostos en determina les propietats magnètiques i per aquest motiu només pot observar-se el fenomen de frustració d'espín en el primer dels dos compostos.
Different kinds of mixed "d"-"f" molecular compounds with cyanide bridges have been obtained, structurally characterized and magnetically studied in this work. Depending on the nature of the blocking ligand added in the reaction media, and on the nature of the lanthanide(III) ion and the transition ion as well, dinuclear, trinuclear or monodimensional compounds were formed.
Up to now there is no suitable model that includes the spin-orbit coupling, the crystal field effect and the anisotropic magnetic superexchange between d and f paramagnetic ions. For this reason a qualitative approach was used in order to guess which is the nature of the magnetic interaction between each of the Ln3+ ions and the Fe3+ ion in these compounds, even if we cannot measure its magnitude.
The low symmetry crystal environment of most of the lanthanide(III) ions gives rise to a high magnetic anisotropy at low temperature. The anisotropy of the simplest dinuclear systems presented in this work (LaFe, CeCo and CeFe) has been studied by single crystal magnetic measurements and single crystal epr spectra. The magnitudes and directions of the three components of the g tensors for the Ce3+ and Fe3+ ions have been independently determined using the single crystal epr spectra of the CeCo and LaFe compounds respectively.
The use of Gd3+ as the Ln3+ ion and the substitution of the [Fe(CN)6]3- by [Cr(CN)6]3- in the synthesis of new compounds has simplified the magnetic study of these systems since Gd3+ has no spin-orbit coupling and Cr3+ is a very isotropic ion. We fitted the magnetic data for two of these compounds using an isotropic spin Hamiltonian and we obtained values for the magnetic exchange constant (J) between 0.5 and 1 cm-1, the expected values for this kind of systems.
Finally our attempt to synthesize new mixed d-f high-nuclearity compounds gave rise to a cluster-like structure compound with one diamagnetic Ce4+ ion, showing a template role, sorrounded by eight Mn3+ ions ferromagnetically coupled between them. Two chromium(III) triangular systems have been also obtained, which show presence or lack of spin frustration depending on the symmetry of the molecule in each case.
Books on the topic "F-block metals"
Jones, Chris J. D- and f-block chemistry. New York: J. Wiley, 2002.
Find full textChemistry of the f-block elements. Australia: Gordon & Breach, 2001.
Find full textRudd, Martin D. Macrocyclic complexation of cationic f-block (lanthanide) and p-block (groups 14 and 15) metal species. [s.l.]: typescript, 1994.
Find full textDavies, A. G., E. W. Abel, Chris J. Jones, J. Derek Woollins, and David Phillips. D- and F-Block Chemistry. Royal Society of Chemistry, The, 2007.
Find full textAspinall, Helen C. Chemistry of the F-Block Elements. CRC Press LLC, 2018.
Find full textAspinall, Helen C. Chemistry of the F-Block Elements. CRC Press LLC, 2018.
Find full textAspinall, Helen, and Helen C. Aspinall. Chemistry of the f-Block Elements (Advanced Chemistry Texts, Volume 5). Taylor & Francis, 2001.
Find full textD-And F-Block Chemistry (Tutorial Chemistry Texts). Royal Society of Chemistry, 2000.
Find full textBook chapters on the topic "F-block metals"
Orpen, A. G., L. Brammer, F. H. Allen, D. G. Watson, and R. Taylor. "Typical interatomic distances: organometallic compounds and coordination complexes of the d- and f -block metals." In International Tables for Crystallography, 812–96. Chester, England: International Union of Crystallography, 2006. http://dx.doi.org/10.1107/97809553602060000622.
Full textSchulz, Stephan. "Organoaluminum Complexes with Bonds to s-Block, p-Block, d-Block, and f-Block Metal Centers." In Modern Organoaluminum Reagents, 59–90. Berlin, Heidelberg: Springer Berlin Heidelberg, 2012. http://dx.doi.org/10.1007/3418_2012_33.
Full textHosmane, N. S., and J. A. Maguire. "Metallacarboranes of d- and f-Block Metals." In Comprehensive Organometallic Chemistry III, 175–264. Elsevier, 2007. http://dx.doi.org/10.1016/b0-08-045047-4/00046-7.
Full textRodger, Alison, and Mark Rodger. "Complexes of Transition Metals and f-Block Elements." In Molecular Geometry, 105–37. Elsevier, 1995. http://dx.doi.org/10.1016/b978-0-7506-2295-0.50010-8.
Full textBarrett, Jack, and Mounir A. Malati. "Chemistry of the d and f Block Metals." In Fundamentals of Inorganic Chemistry, 257–85. Elsevier, 1998. http://dx.doi.org/10.1016/b978-1-898563-38-9.50017-7.
Full textSoni, P. L., and Vandna Soni. "Inner Transition or f-block Elements: The Lanthanides." In The Chemistry of Coordination Complexes and Transition Metals, 345–58. CRC Press, 2021. http://dx.doi.org/10.1201/9781003183426-24.
Full textTonks, Ian A. "Volume 10 and 11: Applications II. d- and f- Block Metal Complexes in Organic Synthesis." In Reference Module in Chemistry, Molecular Sciences and Chemical Engineering. Elsevier, 2022. http://dx.doi.org/10.1016/b978-0-12-820206-7.00168-2.
Full textConference papers on the topic "F-block metals"
Roy, Ting, Kamel Ben Naceur, Manjinder Singh, Daniel Markel, Leonard Harp, Hifzi Ardic, Christian Wilkinson, and Indranil Roy. "Design of a 750 °F, 15 K packer for Enhanced Geothermal Systems, Supercritical CO2 - Sequestration and SAGD: Energy Transition Through Technology Synthesis." In Offshore Technology Conference. OTC, 2022. http://dx.doi.org/10.4043/31895-ms.
Full textNagar, Arvind. "Fatigue Damage at Open Holes in Laminated Composite Under Thermo Mechanical Loads." In ASME 2002 Engineering Technology Conference on Energy. ASMEDC, 2002. http://dx.doi.org/10.1115/etce2002/cmda-29080.
Full textLe Nevé, Charles, Sophie Loyan, Léonard Le Jeune, Steve Mahaut, Serge Demonte, Daniel Chauveau, Romain Renaud, Manuel Tessier, Nicolas Nourrit, and Anthony Le Guellaut. "High Temperature Hydrogen Attack: New NDE Advanced Capabilities — Development and Feedback." In ASME 2019 Pressure Vessels & Piping Conference. American Society of Mechanical Engineers, 2019. http://dx.doi.org/10.1115/pvp2019-94001.
Full textReports on the topic "F-block metals"
Hay, Benjamin P., David M. Roundhill, Robert Treat Paine, Jr, Kenneth N. Raymond, Robin D. Rogers, James E. Hutchison, David A. Dixon, Gregg J. Lumetta, and Brian M. Rapko. Architectural Design Criteria for F-Block Metal Ion Sequestering Agents. Office of Scientific and Technical Information (OSTI), June 1999. http://dx.doi.org/10.2172/827036.
Full textHay, Benjamin P., David A. Dixon, Gregg J. Lumetta, Brian M. Rapko, David M. Roundhill, R. D. Rogers, James E. Hutchison, R. T. Paine, and Kenneth N. Raymond. Architectural Design Criteria for f- Block Metal Ion Sequestering Agents--Final Report. Office of Scientific and Technical Information (OSTI), June 2000. http://dx.doi.org/10.2172/15001497.
Full textBP Hay, DA Dixon, GJ Lumetta, BM Rapko, DM Roundhill, RD Rogers, JE Hutchison, RT Paine, and KN Raymond. Architectural Design Criteria for f-Block Metal Ion Sequestering Agents Final Report. Office of Scientific and Technical Information (OSTI), June 2000. http://dx.doi.org/10.2172/756591.
Full textHay, B. P., R. T. Paine, and D. M. Roundhill. Architectural design criteria for f-block metal sequestering agents. 1997 annual progress report. Office of Scientific and Technical Information (OSTI), June 1997. http://dx.doi.org/10.2172/12612.
Full textHay, B. P., D. A. Dixon, D. M. Roundhill, R. D. Rogers, R. T. Paine, and K. N. Raymond. Architectural design criteria for f-block metal ion sequestering agents. 1998 annual progress report. Office of Scientific and Technical Information (OSTI), December 1998. http://dx.doi.org/10.2172/12613.
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