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Journal articles on the topic 'Environmentally-benign design'

Author: Grafiati
Published: 6 September 2023

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1

Sinha, Manish, Luke E. K. Achenie, and Gennadi M. Ostrovsky. "Environmentally benign solvent design by global optimization." Computers & Chemical Engineering 23, no. 10 (December 1999): 1381–94. http://dx.doi.org/10.1016/s0098-1354(99)00299-9.

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2

TAKASU, Akinori. "Environmentally Benign Polyester Design by Room-Temperature Dehydration Polycondensation." KOBUNSHI RONBUNSHU 64, no. 8 (2007): 504–15. http://dx.doi.org/10.1295/koron.64.504.

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3

Chavali, Sunitha, Bao Lin, David C. Miller, and Kyle V. Camarda. "Environmentally-benign transition metal catalyst design using optimization techniques." Computers & Chemical Engineering 28, no. 5 (May 2004): 605–11. http://dx.doi.org/10.1016/j.compchemeng.2004.02.005.

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4

Dahmani, Abdelouahid, Zine Aidoun, and Nicolas Galanis. "Optimum design of ejector refrigeration systems with environmentally benign fluids." International Journal of Thermal Sciences 50, no. 8 (August 2011): 1562–72. http://dx.doi.org/10.1016/j.ijthermalsci.2011.02.021.

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5

Thomas, John Meurig, Robert Raja, Gopinathan Sankar, Robert G. Bell, and Dewi W. Lewis. "Benign by design. New catalysts for an environmentally conscious age." Pure and Applied Chemistry 73, no. 7 (July 1, 2001): 1087–101. http://dx.doi.org/10.1351/pac200173071087.

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There is a pressing need for: (i) cleaner fuels (free of aromatics and of minimal sulfur content) or ones that convert chemical energy directly to electricity, silently and without production of noxious oxides and particulates; (ii) chemical, petrochemical, and pharmaceutical processes that may be conducted in a one-step, solvent-free manner, and that use air as the preferred oxidant; and (iii) industrial processes that minimize consumption of energy, production of waste or the use of corrosive, explosive, volatile and nonbiodegradable materials. All these needs and other desiderata, such as the in situ production and containment of aggressive and hazardous reagents, and the avoidance of use of ecologically harmful elements, may be achieved by designing the appropriate heterogeneous inorganic catalyst, which, ideally should be cheap, readily preparable, and fully characterizable, preferably under in situ reaction conditions. A range of nanoporous and nanoparticle catalysts, designed, synthesized, characterized, and tested by the authors and their colleagues, that meet most of the stringent demands of sustainable development and responsible (clean) technology is described. Specific examples that are highlighted include: (a) the production of adipic acid (precursor of polyamides and urethanes) without the use of concentrated nitric acid or the production of greenhouse gases such as nitrous oxide; (b) the production of caprolactam (precursor of nylon) without the use of oleum and hydroxylamine sulfate; and (c) the terminal oxyfunctionalization of linear alkanes in air. The topic of biocatalysis and sustainable development is also briefly discussed, and a cautionary note is sounded concerning fast screening methods for the discovery of new inorganic catalysts.
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Kheawhom, Soorathep, and Masahiko Hirao. "Decision support tools for environmentally benign process design under uncertainty." Computers & Chemical Engineering 28, no. 9 (August 2004): 1715–23. http://dx.doi.org/10.1016/j.compchemeng.2004.01.005.

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7

Hostrup, Martin, Peter M. Harper, and Rafiqul Gani. "Design of environmentally benign processes: integration of solvent design and separation process synthesis." Computers & Chemical Engineering 23, no. 10 (December 1999): 1395–414. http://dx.doi.org/10.1016/s0098-1354(99)00300-2.

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8

Sakamoto, Ryu, and Keiji Maruoka. "The Design of Environmentally-Benign, High-Performance Organocatalysts for Asymmetric Catalysis." Journal of Synthetic Organic Chemistry, Japan 75, no. 11 (2017): 1141–49. http://dx.doi.org/10.5059/yukigoseikyokaishi.75.1141.

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9

Demchuk, Oleg M., Katarzyna Kielar, and K. Michał Pietrusiewicz. "Rational design of novel ligands for environmentally benign cross-coupling reactions." Pure and Applied Chemistry 83, no. 3 (January 31, 2011): 633–44. http://dx.doi.org/10.1351/pac-con-10-08-06.

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Transition-metal (TM) complexes of new phosphines, readily prepared by a straight-forward three-step modular synthesis, were successfully employed in difficult cross-coupling reactions conducted under mild conditions (water, “open-flask”, low temperature) that aspire to meet green chemistry criteria. High yielding catalyzed by bismuth or rhodium complexes oxidative arylation of naphthoquinone gave the key 2-arylnaphthoquinone intermediates for facile bismuth triflate-catalyzed Michael addition of secondary phosphine oxides. Subsequent O-methylation and reductions of the resulting products gave access to the target air-stable phosphine ligands in good overall yields (up to 60 %).
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10

Mabuchi, Mamoru, Kohmei Halada, and Tatsuhiko Aizawa. "Barrier-Free Processing of Materials for Environmentally Benign Life-Cycle Design." MATERIALS TRANSACTIONS 43, no. 3 (2002): 285–91. http://dx.doi.org/10.2320/matertrans.43.285.

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11

Jonuzaj, Suela, Jingyue Cui, and Claire S. Adjiman. "Computer-aided design of optimal environmentally benign solvent-based adhesive products." Computers & Chemical Engineering 130 (November 2019): 106518. http://dx.doi.org/10.1016/j.compchemeng.2019.106518.

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12

Huebschmann, S., D. Kralisch, V. Hessel, U. Krtschil, and C. Kompter. "Environmentally Benign Microreaction Process Design by Accompanying (Simplified) Life Cycle Assessment." Chemical Engineering & Technology 32, no. 11 (November 2009): 1757–65. http://dx.doi.org/10.1002/ceat.200900337.

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13

Ghatak, Kamalika, Swastik Basu, Tridip Das, Vidushi Sharma, Hemant Kumar, and Dibakar Datta. "Effect of cobalt content on the electrochemical properties and structural stability of NCA type cathode materials." Physical Chemistry Chemical Physics 20, no. 35 (2018): 22805–17. http://dx.doi.org/10.1039/c8cp03237h.

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14

Yin, Dong-Ya, Jiang Pan, Jie Zhu, You-Yan Liu, and Jian-He Xu. "A green-by-design bioprocess for l-carnosine production integrating enzymatic synthesis with membrane separation." Catalysis Science & Technology 9, no. 21 (2019): 5971–78. http://dx.doi.org/10.1039/c9cy01622h.

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15

Drexler, Marius, Philipp Haltenort, Thomas A. Zevaco, Ulrich Arnold, and Jörg Sauer. "Synthesis of tailored oxymethylene ether (OME) fuels via transacetalization reactions." Sustainable Energy & Fuels 5, no. 17 (2021): 4311–26. http://dx.doi.org/10.1039/d1se00631b.

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16

Ran, Yang, Yunlong Guo, and Yunqi Liu. "Organostannane-free polycondensation and eco-friendly processing strategy for the design of semiconducting polymers in transistors." Materials Horizons 7, no. 8 (2020): 1955–70. http://dx.doi.org/10.1039/d0mh00138d.

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17

Griffin, Preston, Selene Ramer, Matthew Winfough, and Jakub Kostal. "Practical guide to designing safer ionic liquids for cellulose dissolution using a tiered computational framework." Green Chemistry 22, no. 11 (2020): 3626–37. http://dx.doi.org/10.1039/d0gc00923g.

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18

Ooi, Jecksin, Denny K. S. Ng, and Nishanth Chemmangattuvalappil. "A systematic molecular design framework for an environmentally benign solvent recovery process." MATEC Web of Conferences 268 (2019): 02001. http://dx.doi.org/10.1051/matecconf/201926802001.

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Computer Aided Molecular Design (CAMD) techniques have been extensively applied to design solvents for different applications. Most of the CAMD problems only aim at generating solvents that meet the predefined functionality. Nevertheless, it is important to consider the effect of solvent on the safety, health and environmental impacts during the recovery process. This paper presents a single stage CAMD framework that simultaneously quantifies the environmental impact of the solvent recovery process. The environmental impact of the process can be estimated through IChemE Sustainability Metrics. Besides, molecular properties that have an impact on the quantitative evaluation of the environmental impact of solvent recovery process are included in this framework. Weighted sum method coupled with Fuzzy Analytic Hierarchy Process (FAHP) weighting approach is employed to solve the multi-objective molecular design framework. A case study on solvent design for residual oil extraction from palm pressed fiber is presented to illustrate the proposed framework. In this work, only energy balance around multistage evaporator is incorporated into CAMD formulation as energy required to recover the solvent contributes to the largest portion of the whole process. The results show that the designed solvents simultaneously possess target functionalities and reduce the environmental impact of solvent recovery process.
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19

Duvedi, Amit, and L. E. K. Achenie. "On the design of environmentally benign refrigerant mixtures: a mathematical programming approach." Computers & Chemical Engineering 21, no. 8 (April 1997): 915–23. http://dx.doi.org/10.1016/s0098-1354(96)00310-9.

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20

Kaneda, Kiyotomi, Kohsuke Mori, Takayoshi Hara, Tomoo Mizugaki, and Kohki Ebitani. "Design of hydroxyapatite-bound transition metal catalysts for environmentally-benign organic syntheses." Catalysis Surveys from Asia 8, no. 4 (December 2004): 231–39. http://dx.doi.org/10.1007/s10563-004-9114-3.

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21

Thomas, John Meurig, Robert Raja, Gopinathan Sankar, Robert G. Bell, and Dewi W. Lewis. "ChemInform Abstract: Benign by Design. New Catalysts for an Environmentally Conscious Age." ChemInform 33, no. 1 (May 23, 2010): no. http://dx.doi.org/10.1002/chin.200201299.

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22

Zong, Enmin, Guobo Huang, Xiaohuan Liu, Weiwei Lei, Shengtao Jiang, Zhongqing Ma, Jifu Wang, and Pingan Song. "A lignin-based nano-adsorbent for superfast and highly selective removal of phosphate." Journal of Materials Chemistry A 6, no. 21 (2018): 9971–83. http://dx.doi.org/10.1039/c8ta01449c.

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23

Demchuk, Oleg M., and Radomir Jasiński. "Organophosphorus ligands: Recent developments in design, synthesis, and application in environmentally benign catalysis." Phosphorus, Sulfur, and Silicon and the Related Elements 191, no. 2 (February 1, 2016): 245–53. http://dx.doi.org/10.1080/10426507.2015.1064921.

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24

Chanduluru, Hemanth Kumar, and Abimanyu Sugumaran. "Eco-friendly estimation of isosorbide dinitrate and hydralazine hydrochloride using Green Analytical Quality by Design-based UPLC Method." RSC Advances 11, no. 45 (2021): 27820–31. http://dx.doi.org/10.1039/d1ra04843k.

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Analysing isosorbide dinitrate and hydralazine by using an eco-friendly method is an initial stepping stone towards environmentally benign method development, and its combination with the AQbD makes it the method to use for ages without revalidation.
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25

Zhen, Yanzhong, Chunming Yang, Huidong Shen, Wenwen Xue, Chunrong Gu, Jinghao Feng, Yuecheng Zhang, Feng Fu, and Yucang Liang. "Photocatalytic performance and mechanism insights of a S-scheme g-C3N4/Bi2MoO6 heterostructure in phenol degradation and hydrogen evolution reactions under visible light." Physical Chemistry Chemical Physics 22, no. 45 (2020): 26278–88. http://dx.doi.org/10.1039/d0cp02199g.

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Photocatalysis with sustainable utilization and low cost is an environmentally benign method for the degradation of organic pollutants, but the rational design and fabrication of photocatalysts with high catalytic performance is still an challenge.
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26

Zhang, Guoying, Yinjun Xie, Zhengkun Wang, Yang Liu, and Hanmin Huang. "Diboron as a reductant for nickel-catalyzed reductive coupling: rational design and mechanistic studies." Chemical Communications 51, no. 10 (2015): 1850–53. http://dx.doi.org/10.1039/c4cc08703h.

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Diboron (B2pin2) has been identified as an efficient and environmentally benign reducing reagent for reductive coupling reactions for the first time, which enables the nickel-catalyzed reductive tetramerization of alkynes to be performed with high efficiency in the presence of formal substoichiometric amounts of (0.3 equiv.) the reductant.
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27

Ebitani, Kohki, Tomoo Mizugaki, Kohsuke Mori, and Kiyotomi Kaneda. "Design of Ruthenium Catalysts Bound to Inorganic Crystalline Materials for Environmentally-Benign Organic Synthesis." Current Organic Chemistry 10, no. 2 (January 1, 2006): 241–55. http://dx.doi.org/10.2174/138527206775192906.

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28

Lee, Hyo-Jun, Natarajan Arumugam, Abdulrahman Almansour, Raju Kumar, and Keiji Maruoka. "Design of New Amino Tf-Amide Organocatalysts: Environmentally Benign Approach to Asymmetric Aldol Synthesis." Synlett 30, no. 04 (December 19, 2018): 401–4. http://dx.doi.org/10.1055/s-0037-1610408.

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A new type of optically pure primary amino aromatic Tf-amide organocatalyst can be easily prepared from 8-amino-1-tetralone, and its chemical behavior was investigated in the context of asymmetric aldol and Mannich reactions. Most notably, the asymmetric aldol reaction proceeded smoothly in brine.
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29

Kunthakudee, Naphaphan, Niti Sunsandee, Boonta Chutvirasakul, and Prakorn Ramakul. "Extraction of lycopene from tomato with environmentally benign solvents: Box-Behnken design and optimization." Chemical Engineering Communications 207, no. 4 (May 10, 2019): 574–83. http://dx.doi.org/10.1080/00986445.2019.1610882.

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30

Thomas, John Meurig, Juan Carlos Hernandez-Garrido, and Robert G. Bell. "A General Strategy for the Design of New Solid Catalysts for Environmentally Benign Conversions." Topics in Catalysis 52, no. 12 (June 2, 2009): 1630–39. http://dx.doi.org/10.1007/s11244-009-9302-5.

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31

Takeshita, Tokio, Akihisa Kitagawa, Fumiya Yokosu, Ryo Matsumoto, Toshiki Nokami, and Toshiyuki Itoh. "Design of Acyl Donor for Environmentally Benign Acylation of Cellulose Using an Ionic Liquid." Australian Journal of Chemistry 72, no. 2 (2019): 61. http://dx.doi.org/10.1071/ch18253.

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Esterification is the most important derivatization to utilise cellulose as a sustainable resource for the materials industry. Homogeneous esterification is generally the most convenient means to achieve this aim. We found that N-methyl-N-(2-methoxyethyl)pyrrolidinium acetate [P1ME][OAc] easily dissolved cellulose. To achieve the environmental benign acylation of cellulose, we attempted to design acyl donor molecules under strong base catalyst-free conditions. It was found that a [P1ME][OAc] solution of cellulose when mixed with 2,2,2-trifluoroethyl benzoates at 80°C afforded the corresponding cellulose benzoate with a perfect (3.0) degree of substitution (DS) value in almost quantitative yield. We also succeeded in preparing 4-[(4-hydroxyphenyl)diazenyl]benzoate or 4-[(4-methoxyphenyl)diazenyl]benzoate of the cellulose with a DS value of 2.38 or 2.67 by the same protocol, respectively; the DMSO solution prepared by the resulting compounds exhibited a photochromic property, although only a slight colour change from light yellow to colourless was obtained by UV irradiation.
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32

Suk, Morten, Stefanie Lorenz, and Klaus Kümmerer. "Identification of environmentally biodegradable scaffolds for the benign design of quinolones and related substances." Sustainable Chemistry and Pharmacy 31 (April 2023): 100947. http://dx.doi.org/10.1016/j.scp.2022.100947.

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33

Ledesma, Julieta, Santiago A. Bortolato, Carlos E. Boschetti, and Débora M. Martino. "Optimization of Environmentally Benign Polymers Based on Thymine and Polyvinyl Sulfonate Using Plackett-Burman Design and Surface Response." Journal of Chemistry 2013 (2013): 1–9. http://dx.doi.org/10.1155/2013/947137.

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Traditional approaches to the development of integrated circuits involve the use and/or manufacture of toxic materials that have a potential environmental impact. An extensive research has been done to design environmentally benign synthetic polymers containing nucleic acid bases, which can be used to enhance the photoresistor technologies. Water soluble, environmentally benign photopolymers of 1-(4-vinylbenzyl) thymine (VBT) and vinylphenyl sufonate (VPS) undergo a photodimerization reaction when exposed to low levels of ultraviolet irradiation leading to an immobilization of the copolymer on a variety of substrates. Plackett-Burman design (PBD) and central composite design (CCD) were applied to identify the significant factors influencing the polymer crosslinking and dye adsorption processes, which are relevant in the fabrication of copolymer films for potential photoresist use. The PBD results assigned a maximum absorption signal of 0.67, while optimal conditions obtained in this experiment following the CCD method predictions provided a response of 0.83 ± 0.03, being a solid foundation for further use of this methodology in the production of potential photoresistors. The pH effect was relevant for low concentrations but not significant for higher concentrations. To the best of our knowledge, this was the first report applying statistical experimental designs to optimize the crosslinking of thymine-based polymers.
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34

Kumar, Navneet, Anjali Chauhan, Anuj, and Prachi. "Green and Benign Strategies for Synthesis of Biologically Active Compounds using Lipase as Biocatalyst." Bulletin of Pure and Applied Sciences-Chemistry 42, no. 1 (June 20, 2023): 33–40. http://dx.doi.org/10.48165/bpas.2023.42c.1.6.

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An efficient, feasible, mild, affordable, and environmentally friendly method has been developed for the synthesis of biologically active compound 3-methylene-indoline-2-one from Isatin and active methylene compounds using Lipase as a Green and Biocatalyst. Biological Processes are very important to optimization to increase and improve the efficiency of cost. In this project, Malononitrile, or Dimedone reacts with Isatin in presence of lipase. The essential features of this approach are metal-free reaction, high yield, nontoxic, and less hazardous. These reactions surpass metal-catalyzed processes because these reactions have violent reaction conditions, toxic, less yields, complex workups, and environmentally hazardous ingredients. This approach replaces hazardous chemicals with benign material during their design, manufacture, use and disposal. Designing of product is cost-effective and environmentally benign chemically products. It is completely followed to Green Approach. The entire given biologically active compound have shown biological activities such as Antiviral, Anti-HIV, Antibacterial, and Anticonvulsants.
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35

Acharya, Shakuntala, and Amaresh Chakrabarti. "A conceptual tool for environmentally benign design: development and evaluation of a “proof of concept”." Artificial Intelligence for Engineering Design, Analysis and Manufacturing 34, no. 1 (February 2020): 30–44. http://dx.doi.org/10.1017/s0890060419000313.

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AbstractDesign is a decision-making process for which knowledge is a prerequisite. Most decisions are taken at the conceptual stage and have pronounced influence on the final design. The literature, therefore, recommends the incorporation of sustainability criteria, such as environment, at this stage. Difficulty in performing life cycle assessment (LCA) due to low availability of information at the conceptual stage for evaluation and highly abstract nature of solutions, inadequate incorporation of DfE (Design for Environment) guidelines and LCA reports into the design process, and a lack of effective communication of the same to the designers for prompt decision-making are major motivations for the development of a support. This paper discusses a “conceptual Tool for environmentally benign design” – concepTe – that supports designers in decision-making during the conceptual design stage, by offering environmental impact (EI) estimates of abstract solutions with associated uncertainty, for evaluation and selection of the most environmentally benign solution as concept. The EI estimates are calculated by a module in the tool based on a proposed EI estimation method, which requires the support of a knowledge base to fetch appropriate LCA information corresponding to the design element being conceptualized. This knowledge base is grounded in the domain-agnostic SAPPhIRE model ontology, allows semantic operability of the knowledge, and offers the results to the designers in a familiar domain language to aid decision-making. A “proof of concept” of the tool is developed for application in design of building in the AEC (Architectural design, Engineering, and Construction) domain. Further, empirical studies are conducted to evaluate the effectiveness of the “proof of concept” to support decision-making and results are found favorable. The paper also discusses the future scope for further development of the tool into a holistic design decision-making platform.
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36

Thomas, John Meurig, Juan Carlos Hernandez-Garrido, and Robert G. Bell. "ChemInform Abstract: A General Strategy for the Design of New Solid Catalysts for Environmentally Benign Conversions." ChemInform 41, no. 21 (May 25, 2010): no. http://dx.doi.org/10.1002/chin.201021245.

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37

Madhukar, Reddy T., and Kumar M. Ranadheer. "Design, Synthesis and Biological Evaluaion of Novel Indole-Isoxazole Conjugates as Potent Anticancer Agents." Research Journal of Chemistry and Environment 25, no. 10 (September 25, 2021): 37–42. http://dx.doi.org/10.25303/2510rjce3742.

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A series of new indole derived mono and bis isoxazole (4a-4f and 5a-5f) was synthesized using highly efficient and environmentally benign ionic liquid containing click synthesis. Anticipated structures of all titled compounds were in agreement with spectral and analytical (C, H and N) analyses. The newly synthesized compounds were screened for their in vitro anticancer activity against MCF-7 and HeLa. The anticancer activity screening results of 5f, 4f and 5a exhibited potent cytotoxic activity against two cancer cell lines with IC50 values nearer to the standard drug doxorubicin. The remaining compounds have shown moderate activity against the tested cell lines.
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38

Joglekar-Athavale, Amruta, and Ganapti S. Shankarling. "Deep eutectic solvent: a green and sustainable alternative for the synthesis of copper phthalocyanine blue and its value added applications." Pigment & Resin Technology 49, no. 4 (April 25, 2020): 325–30. http://dx.doi.org/10.1108/prt-09-2019-0083.

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Purpose This paper aims to propose a simple, effective and environmentally benign method for the synthesis of commercially important pigment copper phthalocyanine (PC) blue has been developed using deep eutectic solvent (DES). Design/methodology/approach DES prepared from choline chloride and urea is used as a reaction medium, as well as a source of ammonia. The design of the experiment and factorial design study has proved that the milder reaction conditions with high yields and reusability of DES are the key features of the present study. Findings The synthesized pigment is obtained at milder reaction conditions with excellent yield, which can be seen from the design of experiments done for the optimization of results. Practical implications The synthesized pigment was used as a colorant in epoxy-based paint and in screen ink, which gave satisfactory results with respect to color values and stability. Social implications The screen ink prepared was formulated considering environmental aspects to avoid the use of solvents. Biodegradable components were added to the colorant to make the ink environment friendly. Originality/value Reactions occur at moderate temperatures without affecting the time factor, thus, it saves energy. A simple, effective and environmentally benign method for the synthesis of commercially important copper PC has been developed using DES. After the first batch, DES synthesized can be reused as a reaction medium where only a stoichiometric amount of urea is to be added. Simple work up, high yield and purity are achieved.
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39

Strauss, Christopher R., and Robert W. Trainor. "Reactions of Ethyl Indole-2-carboxylate in Aqueous Media at High Temperature." Australian Journal of Chemistry 51, no. 8 (1998): 703. http://dx.doi.org/10.1071/c98084.

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Direct, preparative methods utilizing high-temperature aqueous media were developed for indole and indole-2-carboxylic acid from ethyl indole-2-carboxylate. Yields were excellent for these reactions, which were carried out in 1 h or less, at temperatures up to 270°C, in a microwave batch reactor of the authors" design. Avoidance of undesirable copper salts, high-boiling organic bases and heat-transfer oils made the methods environmentally benign.
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40

Neramballi, Abhijna, Tomohiko Sakao, Siri Willskytt, and Anne-Marie Tillman. "A design navigator to guide the transition towards environmentally benign product/service systems based on LCA results." Journal of Cleaner Production 277 (December 2020): 124074. http://dx.doi.org/10.1016/j.jclepro.2020.124074.

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41

Lamberth, Clemens, Stephane Jeanmart, Torsten Luksch, and Andrew Plant. "Current Challenges and Trends in the Discovery of Agrochemicals." Science 341, no. 6147 (August 15, 2013): 742–46. http://dx.doi.org/10.1126/science.1237227.

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Crop protection chemistry has come a long way from its “alchemic” beginnings in the late 19th century to a high-tech science that supports the sustainable production of food, feed, and fiber for a rapidly growing population. Cutting-edge developments in the design and synthesis of agrochemicals help to tackle today’s challenges of weed and pest resistance, higher regulatory safety margins, and higher cost of goods with the invention of selective, environmentally benign, low use rate, and cost-effective active ingredients.
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42

Jose, Diana Elizabeth, U. S. Kanchana, Thomas V. Mathew, and Gopinathan Anilkumar. "Recent Developments and Perspectives in the C-Se Cross Coupling Reactions." Current Organic Chemistry 24, no. 11 (September 11, 2020): 1230–62. http://dx.doi.org/10.2174/1385272824999200528130131.

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: The C-Se bond forming reactions are attractive synthetic strategies for biochemists and synthetic chemists alike for the synthesis of various molecules that are of biological, pharmaceutical and material interest. Therefore, the design and synthesis of organoselenium compounds currently constitute engaging fundamental problems in applied chemistry both in pharmaceutical and academic laboratories. This review discusses the recent works reported in carbon–selenium cross-coupling reactions with the emphasis on the mechanistic aspects of the reactions. The reacting species, the addition of ligands, selection of catalysts, use of suitable solvents, proper setting of reaction time, are well discussed to understand the detailed mechanism. Various simple, economical and environmentally friendly protocols are demonstrated, which ensured product stability, low toxicity, environmentally benign and excellent reactivity for the synthesis of organoselenium compounds. This review covers the scientific literature from 2010 to 2019.
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43

McCormick, Alon, and Vijay John. "Consortium for the Molecular Engineering of Dispersant Systems (C-MEDS)." Marine Technology Society Journal 52, no. 6 (November 1, 2018): 95–98. http://dx.doi.org/10.4031/mtsj.52.6.12.

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AbstractThe primary objective of the Consortium for the Molecular Engineering of Dispersant Systems (C-MEDS) was to understand the molecular basis of dispersant systems, the way the components of dispersants act in breaking oil into small drops by studying in detail the processes at the interface of oil and water. As a consequence of such improved understanding, it was also an objective to design alternative concepts in oil dispersion, taking into account natural processes occurring in ocean environments. The development of new environmentally benign dispersants was always an underlying focus of research efforts.
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Grabitz, Elisa, Marco Reich, Oliver Olsson, and Klaus Kümmerer. "Using structure biodegradability relationships for environmentally benign design of organosilicons – An experimental comparison of organosilicons and their carbon analogues." Sustainable Chemistry and Pharmacy 18 (December 2020): 100331. http://dx.doi.org/10.1016/j.scp.2020.100331.

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Ahady, Shambalid, Nirendra Dev, and Anubha Mandal. "Toward Zero Energy: Active and passive design strategies to achieve net zero Energy Building." International Journal of Advance Research and Innovation 7, no. 1 (2019): 49–61. http://dx.doi.org/10.51976/ijari.711908.

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Buildingsare found to be an essential part of the needed transition towards energy sustainability. In the past few years, there have been growing interests in net zero energy buildings (NZEB) adapted worldwide. The minimized energy demand and airtightness of a passive house and the low energy buildings have provided in the past a step forward to the energy efficiency goal and the net-zero energy building. Implementation of proven energy efficiency technologies offers the world the fastest, most economical, and most environmentally benign way to alleviate threats. This paper will discuss Net Zero Energy Building definition and design strategies targeting for energy efficiency and environmental sustainability. The literature shows that to improve the integrated performance of the building and to achieve the goal of energy efficient and NZEB, appropriate active and passive design strategies should utilize. Also, energy demand should reduce to a minimum, through energy efficient building designs, leaving only a fraction of the energyrequired to be covered by renewable energy generation.
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46

Singh, Prashant Kumar, and Prabir Sarkar. "Understanding the priorities of designers for an ecodesign support during environmentally sustainable product development." World Journal of Science, Technology and Sustainable Development 18, no. 1 (February 2, 2021): 76–92. http://dx.doi.org/10.1108/wjstsd-12-2020-0101.

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PurposeThe main purpose of this research is to understand the priorities of designers for an ecodesign support, while developing environmentally sustainable products. Also, this study identifies the requirements of the designers for managing the environmental quality of products.Design/methodology/approachThis research is conducted in two phases of survey. In the first phase, various requirements of designers are collected, refined and segregated under certain well defined characteristics of the ecodesign support. In second phase, the designers are asked to rank each characteristic of the ecodesign support in a questionnaire. The responses obtained from the designers are analyzed separately for engineering designers and design researchers by using Henry Garrett ranking technique to identify the priorities of designers for an ecodesign support.FindingsResults show that there is a contrast between the perspective of engineering designers and design researchers, and their priorities for an ecodesign support are opposite to each other. Thus it can be understood that the features which are added by design researchers in ecodesign support may not be adequate for engineering designers to manage the environmental quality of products.Originality/valueThe designers play a key role in the development of environmentally benign products through the use of different ecodesign supports (i.e. tools or methods). Therefore, it is important to understand the desired characteristics of the ecodesign support from designer's perspective. Also, the priorities of designers from academia (design researchers) and industry (engineering designers) must be understood because they are the two stakeholders indulged in the development and usage of various ecodesign supports for environmentally conscious product development (ECPD).
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Chao, Dongliang, Wanhai Zhou, Fangxi Xie, Chao Ye, Huan Li, Mietek Jaroniec, and Shi-Zhang Qiao. "Roadmap for advanced aqueous batteries: From design of materials to applications." Science Advances 6, no. 21 (May 2020): eaba4098. http://dx.doi.org/10.1126/sciadv.aba4098.

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Safety concerns about organic media-based batteries are the key public arguments against their widespread usage. Aqueous batteries (ABs), based on water which is environmentally benign, provide a promising alternative for safe, cost-effective, and scalable energy storage, with high power density and tolerance against mishandling. Research interests and achievements in ABs have surged globally in the past 5 years. However, their large-scale application is plagued by the limited output voltage and inadequate energy density. We present the challenges in AB fundamental research, focusing on the design of advanced materials and practical applications of whole devices. Potential interactions of the challenges in different AB systems are established. A critical appraisal of recent advances in ABs is presented for addressing the key issues, with special emphasis on the connection between advanced materials and emerging electrochemistry. Last, we provide a roadmap starting with material design and ending with the commercialization of next-generation reliable ABs.
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Safaei-Ghomi, Javad, Hossein Shahbazi-Alavi, and Pouria Babaei. "One-pot multicomponent synthesis of furo[3,2-c]coumarins promoted by amino-functionalized Fe3O4@SiO2 nanoparticles." Zeitschrift für Naturforschung B 71, no. 8 (August 1, 2016): 849–56. http://dx.doi.org/10.1515/znb-2016-0041.

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AbstractAmino-functionalized Fe3O4@SiO2 nanoparticles (Fe3O4@SiO2–NH2 NPs) were prepared by treating Fe3O4@SiO2 NPs with (3-aminopropyl)-triethoxysilane. They have been characterized by powder X-ray diffraction, vibrating sample magnetometer, scanning electronic microscopy, energy dispersive X-ray, thermogravimetric analysis and FT-IR spectroscopy. A neat, atom-economical, environmentally benign one-pot multicomponent synthetic route for the synthesis of furo[3,2-c]coumarins in good yields has been devised using the Fe3O4@SiO2–NH2 NPs. The present methodology can be used for the design of libraries and diversity-oriented synthesis, and has potential for biological applications and drug discovery.
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Thomas, John Meurig. "The societal significance of catalysis and the growing practical importance of single-site heterogeneous catalysts." Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences 468, no. 2143 (April 27, 2012): 1884–903. http://dx.doi.org/10.1098/rspa.2012.0196.

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The concept of single-site heterogeneous catalysis, herein defined and extensively illustrated, offers a strategy for the design of new solid catalysts. By capitalizing on the opportunities presented by nanoporous materials to assemble a wide range of new, well-defined, catalytically active centres, it is possible to bring about numerous environmentally benign processes that can replace traditional methods of chemical production. The latter often employs aggressive, corrosive or hazardous reagents. By using both microporous (less than 20 Å diameter) and mesoporous solids (20–500 Å diameter), abundant scope exists for the construction and application of shape-selective, regio-selective and enantioselective catalysts.
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Jiang, Tao, Elizabeth L. Magnotti, and Vincent P. Conticello. "Geometrical frustration as a potential design principle for peptide-based assemblies." Interface Focus 7, no. 6 (October 20, 2017): 20160141. http://dx.doi.org/10.1098/rsfs.2016.0141.

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Two-dimensional peptide and protein assemblies have been the focus of increased scientific research as they display significant potential for the creation of functional nanomaterials. Soluble subunits derived from a variety of protein motifs have been demonstrated to self-assemble into structurally defined nanosheets under environmentally benign conditions in which the components often retain their native structure and function. These types of two-dimensional assemblies may have an advantage for nanofabrication in that their extended planar shapes can be more straightforwardly incorporated into the current formats of nanoscale devices. However, significant challenges remain in the fabrication of these materials, particularly in devising methods to control the size, shape and internal structure of the resultant materials. Geometrical frustration may be envisioned as a possible mechanism to exert control over these structural parameters through rational design. While this objective has yet to be realized in practice, we discuss in this article the potential role of geometrical frustration as a principle to rationalize unusual self-assembly behaviour in several examples of two-dimensional peptide assemblies.
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