Relevant bibliographies by topics / Emulsion polymerization

Academic literature on the topic 'Emulsion polymerization'

Author: Grafiati
Published: 4 June 2021
Last updated: 31 August 2024

Create a spot-on reference in APA, MLA, Chicago, Harvard, and other styles

Select a source type:

Contents

Consult the lists of relevant articles, books, theses, conference reports, and other scholarly sources on the topic 'Emulsion polymerization.'

Next to every source in the list of references, there is an 'Add to bibliography' button. Press on it, and we will generate automatically the bibliographic reference to the chosen work in the citation style you need: APA, MLA, Harvard, Chicago, Vancouver, etc.

You can also download the full text of the academic publication as pdf and read online its abstract whenever available in the metadata.

Journal articles on the topic "Emulsion polymerization"

1

Prescott, S. W., M. J. Ballard, E. Rizzardo, and R. G. Gilbert. "RAFT in Emulsion Polymerization: What Makes it Different?" Australian Journal of Chemistry 55, no. 7 (2002): 415. http://dx.doi.org/10.1071/ch02073.

Full text
Abstract:
Reversible addition-fragmentation chain transfer (RAFT) polymerization techniques have been the focus of a great deal of recent work, particularly in their application to emulsion polymerization, which is the method of choice for implementing most free-radical polymerizations on an industrial scale. RAFT/emulsion polymerizations have considerable technical potential: to 'tailor-make' material properties, to eliminate added surfactant from surface coatings, and so on. However, considerable difficulties have been experienced in using RAFT in emulsion polymerization systems. Here, progress in the application of RAFT techniques to emulsion polymerization is reviewed, summarizing the difficulties that have been experienced and mechanisms that have been postulated to explain the observed behaviour. Possible origins of the difficulties in implementing RAFT in emulsion polymerizations include polymerization in droplets, water sensitivity of some RAFT agents, slow transport of highly hydrophobic RAFT agents across the water phase, and surface activity of some RAFT agents.
APA, Harvard, Vancouver, ISO, and other styles
2

Wang, Qiao, Jin Liang Li, Ai Ping Fu, and Hong Liang Li. "Effect Factors on the Preparation of Polystyrene Microspheres by Emulsifier-Free Emulsion Polymerization." Advanced Materials Research 926-930 (May 2014): 304–7. http://dx.doi.org/10.4028/www.scientific.net/amr.926-930.304.

Full text
Abstract:
Emulsifier-free emulsion polymerization is a technique derived from conventional emulsion polymerization in which polymerization is carried out in the absence of emulsifiers. This technique is useful for the preparation of polymer colloids with narrow particle size distributions and well defined surface properties. Emulsifier-free emulsion polymerization eliminates the disadvantages of conventional emulsion polymerizations stemming from the use of emulsifiers, e.g. impurities in products caused by residual emulsifier and poor water-resistance of films induced by polymer latex.
APA, Harvard, Vancouver, ISO, and other styles
3

Jiménez-Victoria, Ariadna, René D. Peralta-Rodríguez, Enrique Saldívar-Guerra, Gladis Y. Cortez-Mazatán, Lluvia de Abril A. Soriano-Melgar, and Carlos Guerrero-Sánchez. "Emulsion Polymerization Using an Amphiphilic Oligoether Ionic Liquid as a Surfactant." Polymers 14, no. 17 (August 25, 2022): 3475. http://dx.doi.org/10.3390/polym14173475.

Full text
Abstract:
We investigate the use of an ionic liquid (IL) as a surfactant in emulsion polymerization (EP) reactions. ILs have been proposed as surfactants for micellar dispersions, emulsions, micro-emulsions and suspensions. Thus, it is important to acquire knowledge of the application of ILs in heterogeneous polymerizations. We selected the amphiphile cationic oligoether IoLiLyte C1EG™ as an IL for this purpose and compared its performance to that of the conventional surfactant dodecyl trimethyl ammonium bromide (DTAB) in the EP of methyl methacrylate and styrene. After we found the proper concentration range of the IL, this amphiphile showed similar polymerization rates to those observed with DTAB for both monomers. The evolution of monomer conversion and the final average diameter of formed polymeric particles were similar for both evaluated surfactants, demonstrating their capability to stabilize the EPs of the investigated monomers. We simulated the evolution of monomer conversion and particle size using a conventional model for emulsion polymerization, which showed good agreement with the experimental data, suggesting that the EP with this IL follows Smith-Ewart kinetics.
APA, Harvard, Vancouver, ISO, and other styles
4

Wen, Shao Guo, Shi Gao Song, Hong Bo Liu, Ji Hu Wang, Qian Xu, and Yan Shen. "Application of a Novel Initiator on Acrylic Emulsion Polymerization." Advanced Materials Research 233-235 (May 2011): 1415–18. http://dx.doi.org/10.4028/www.scientific.net/amr.233-235.1415.

Full text
Abstract:
New initiator of FFM6 is used to initiate the acrylic emulsion polymerization. The influences of concentration of FFM6 (c[I]) and polymerization temperature (T) on polymerization reaction rate (Rp) were discussed. Rp is proportional to (c[I])1.4 which is different with classical emulsion polymerization whose Rp is proportion to (c[I])0.4, that indicate polymerization mechanism of the reaction in the study is different with classical mechanism. The value of Ea, 56.4 kJ/mol, is lower than the value of general radical polymerization’s Ea (80.0-96.0 kJ/mol), which indicates the FFM6 can initiate acrylic emulsion polymerization at a lower temperature compared with the other kinds of initiator.
APA, Harvard, Vancouver, ISO, and other styles
5

Fei, Liang. "Synthesis and Properties of Acrylate Modified Waterborne Polyurethane Emulsion." Advanced Materials Research 535-537 (June 2012): 1386–92. http://dx.doi.org/10.4028/www.scientific.net/amr.535-537.1386.

Full text
Abstract:
Acrylate modified waterborne polyurethane (PUA) emulsion was prepared by means of core-shell polymerization processes. The structures and properties of emulsions were characterized by FTIR, TEM and DSC. The effects of polymerization temperature, the type and amount of initiator and the acrylic amount on the properties of emulsions were investigated. The experimental results showed that the emulsions prepared were core-shell composite, when the polymerization temperature was 70~75 °C, using oil-soluble initiator azobisisobutyronitrile (AIBN), and the percentage of AIBN was 2.0%~ 2.5%, the properties of the emulsion can be better, and the water resistance, stability and mechanical properties of the PUA films were improved increasingly.
APA, Harvard, Vancouver, ISO, and other styles
6

Cheah, Pohlee, Caitlin N. Bhikha, John H. O’Haver, and Adam E. Smith. "Effect of Oxygen and Initiator Solubility on Admicellar Polymerization of Styrene on Silica Surfaces." International Journal of Polymer Science 2017 (2017): 1–7. http://dx.doi.org/10.1155/2017/6308603.

Full text
Abstract:
Although admicellar polymerization has been termed the surface analog of emulsion polymerization, previous reports utilizing free radical-initiated admicellar polymerization relied on high levels of the free radical initiator when compared to emulsion polymerization, likely due to the presence of oxygen in the reported admicellar polymerization systems. Admicellar polymerizations of styrene on the surface of precipitated silica initiated by either a water-soluble or a water-insoluble initiator were studied to determine the effect of dissolved oxygen and free radical initiator solubility on the kinetics, yield, and molecular weight of the polymer formed. Results show that the presence of oxygen reduces the polymer yield and limits molecular weight. The solubility of the initiator also affected the polymer formed in the admicellar polymerization of styrene. While monomer conversions and polymer yield were similar, the molecular weights of polymerizations initiated by a water-soluble initiator were higher than comparable polymerizations initiated by a water-insoluble initiator.
APA, Harvard, Vancouver, ISO, and other styles
7

ISHII, Keizo. "Emulsion Polymerization." Journal of the Japan Society of Colour Material 71, no. 5 (1998): 339–44. http://dx.doi.org/10.4011/shikizai1937.71.339.

Full text
APA, Harvard, Vancouver, ISO, and other styles
8

Qun Wang, Shoukuan Fu, and Tongyin Yu. "Emulsion polymerization." Progress in Polymer Science 19, no. 4 (January 1994): 703–53. http://dx.doi.org/10.1016/0079-6700(94)90031-0.

Full text
APA, Harvard, Vancouver, ISO, and other styles
9

Huang, Tao, Qing-Xia Yuan, and Shu-Ling Gong. "Emulsifier-Free Acrylate-Based Emulsion Prepared by Reverse Iodine Transfer Polymerization." Polymers 12, no. 3 (March 24, 2020): 730. http://dx.doi.org/10.3390/polym12030730.

Full text
Abstract:
The self-emulsifying acrylate-based emulsions with solid content 45 wt.% were prepared in 3.5 h by reverse iodine transfer polymerization (RITP), and the polymer molecular weight (Mn) could be 30,000 g·mol−1. The influences of methacrylic acid (MAA) amount, soft/hard monomer mass ratio, and iodine amount on polymerization and latex were investigated. A moderate amount of ionized MAA was needed to stabilize the emulsion. Glass transition temperature (Tg) was decreased with the increasing mass ratio of soft/hard monomer. A higher iodine amount resulted in lower Mn. The increased Mn after chain extension of the polymer with water-insoluble monomers in iterative one-pot method proved the living of polymer. Compared with conventional emulsion polymerization, molecular weight (Mn) could be controlled, and Mn of polymer synthesized in RITP emulsion polymerization is higher; emulsion of polyacrylate-containing hydroxyl monomer units prepared by RITP emulsifier-free radical polymerization is more stable. Good properties, such as hardness, water resistance, adhesion, and increased value of maximum tensile of films modified by reaction of polyacrylate with melamine–formaldehyde (MF) resin, indicated potential application in baking coating.
APA, Harvard, Vancouver, ISO, and other styles
10

Save, Maud, Yohann Guillaneuf, and Robert G. Gilbert. "Controlled Radical Polymerization in Aqueous Dispersed Media." Australian Journal of Chemistry 59, no. 10 (2006): 693. http://dx.doi.org/10.1071/ch06308.

Full text
Abstract:
Controlled radical polymerization (CRP), sometimes also termed ‘living’ radical polymerization, offers the potential to create a wide range of polymer architectures, and its implementation in aqueous dispersed media (e.g. emulsion polymerization, used on a vast scale industrially) opens the way to large-scale manufacture of products based on this technique. Until recently, implementing CRP in aqueous dispersed media was plagued with problems such as loss of ‘living’ character and loss of colloidal stability. This review examines the basic mechanistic processes in free-radical polymerization in aqueous dispersed media (e.g. emulsion polymerization), and then examines, through this mechanistic understanding, the new techniques that have been developed over the last few years to implement CRP successfully in emulsion polymerizations and related processes. The strategies leading to these successes can thus be understood in terms of the various mechanisms which dominate CRP systems in dispersed media; these mechanisms are sometimes quite different from those in conventional free-radical polymerization in these media.
APA, Harvard, Vancouver, ISO, and other styles
More sources

Dissertations / Theses on the topic "Emulsion polymerization"

1

Tsavalas, John George. "A molecular level investigation of hybrid miniemulsion polymerization." Diss., Georgia Institute of Technology, 2001. http://hdl.handle.net/1853/11153.

Full text
APA, Harvard, Vancouver, ISO, and other styles
2

Song, Zhiqiang. "Kinetics of emulsion polymerization." Diss., Georgia Institute of Technology, 1988. http://hdl.handle.net/1853/10148.

Full text
APA, Harvard, Vancouver, ISO, and other styles
3

Brunier, Barthélémy. "Modeling of Pickering Emulsion Polymerization." Thesis, Lyon 1, 2015. http://www.theses.fr/2015LYO10320/document.

Full text
Abstract:
L’objectif du présent projet est de développer une méthodologie pour la modélisation fondamentale de procédés de polymérisation en émulsion sans tensioactif stabilisés par des particules inorganiques, dénommées "polymérisation en émulsion Pickering". La modélisation des systèmes de polymérisation en émulsion nécessite la modélisation de la distribution de taille des particules (PSD), qui est une propriété importante d'utilisation finale du latex. Cette PSD comprend des sous-modèles dédiés à la nucléation des particules, le transfert de masse entre les différentes phases (monomère, radicaux, stabilisant) et la coagulation des particules. Ces modèles devraient de préférence être validés expérimentalement de manière individuelle. La première partie principale du travail est consacrée à l'étude expérimentale. Cette partie peut être divisée en trois parties. La première partie décrit l'adsorption de particules inorganiques sur le polymère sans réaction. Une adsorption multicouche a été observée et l’isotherme B.E.T. a été capable de décrire cette adsorption. L'adsorption se révèle être plus importante pour une force ionique plus élevée. La dynamique d'adsorption semple être rapide et par conséquent le partage peut être considéré à l'équilibre pendant la polymérisation. La deuxième partie concerne l'étude de différents paramètres de réaction sur le nombre de particules et la vitesse de réaction dans des polymérisations ab initio. L'effet du mélange, de la concentration initiale des monomères et de la concentration de l'initiateur a été étudié. L'optimisation de ces conditions a été utile pour la partie de modélisation. La dernière partie décrit les différences entre plusieurs Laponite® à travers la polymérisation en émulsion ab initio du styrène.La deuxième partie principale du manuscrit a porté sur la modélisation de la polymérisation en émulsion Pickering. Le modèle de bilan de population et le nombre moyen de radicaux par particule ont été calculés en fonction de l'effet des particules organiques. La croissance des particules de polymère a été optimisée en ajustant les modèles d'entrée et de désorption des radicaux décrits dans la littérature aux données expérimentales. Aucune modification n'a été nécessaire, ce qui nous a permis de conclure que l'argile n'avait aucune influence sur l'échange radical. Cependant, la stabilisation joue un rôle important dans la production de particules de polymère. Le modèle de nucléation coagulante a été capable de décrire le taux de nucléation et de prédire le nombre total de particules
The aim of the present project is to develop a methodology for fundamental modeling of surfactant-free emulsion polymerization processes stabilized by inorganic particles, referred to as “Pickering emulsion polymerization”. Modeling emulsion polymerization systems requires modeling the particle size distribution (PSD), which is an important end-use property of the latex. This PSD includes submodels dedicated to particle nucleation, mass transfer between the different phases (monomer, radicals, stabilizer), and particle coagulation. These models should preferably be individually identified and validated experimentally. The first main part of the work is dedicated to the experimental study. This part can be divided in three parts. The first part describes the adsorption of inorganic particles on polymer without reaction. Multilayer adsorption was observed and B.E.T. isotherm was able to describe this adsorption. The adsorption was found to be enhanced at higher ionic strength. The adsorption dynamics were found fast and therefore clay partitioning can be considered at equilibrium during polymerization. The second part concerned the investigation of different reaction parameters on the particles number and reaction rate in ab initio polymerizations. The effect of mixing, initial monomer concentration and initiator concentration were considered. Optimization of these conditions was useful for the modeling part. The last part described the differences between several LaponiteR_ grades through the ab initio emulsion polymerization of styrene. The second main part of the manuscript focused on the modeling of the Pickering emulsion polymerization. The population balance model and average number of radicals balance were adapted regarding the effect of inxi organic particles. The growth of the polymer particles was optimized by fitting the models of radicals’ entry and desorption described available in literature to the experimental data. No modification was needed, which allowed us to conclude that the clay had no influence on radical exchange. However, LaponiteR_ stabilization played an important role in polymer particles production. Coagulative nucleation model was able to describe the nucleation rate and predict the total number of particles
APA, Harvard, Vancouver, ISO, and other styles
4

Mead, Richard Norman. "Emulsion copolymerization in continuous reactors." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/11030.

Full text
APA, Harvard, Vancouver, ISO, and other styles
5

Billuart, Guilhem. "Free radical emulsion polymerization of ethylene." Thesis, Lyon 1, 2015. http://www.theses.fr/2015LYO10033.

Full text
Abstract:
Les travaux présentés dans cette thèse portent sur la polymérisation radicalaire de l'éthylène en émulsion, dans des conditions douces (P < 250 bar et T < 90 °C). Tout d'abord, l'homopolymérisation de l'éthylène a été étudiée. Des latex stables de polyéthylène présentant des taux de solide relativement élevés (30 %) ont été obtenus. Pour cela, deux systèmes différents d'amorçage et de stabilisation (cationique et anionique) ont été employés. Ces latex peuvent trouver des applications comme revêtements hydrophobes (par exemple du papier). L'étude des propriétés thermiques des latex a mis en évidence des phénomènes de cristallisation du polyéthylène à basse température, dû à son confinement dans les nanoparticules. Cela a une forte influence sur les morphologies finales des particules. D'autre part, la copolymérisation radicalaire de l'éthylène en émulsion a été étudiée. Les comonomères utilisés sont le styrène, l'acrylate de butyle, le méthacrylate de méthyle et l'acétate de vinyle qui différent par leur solubilité dans l'eau et leurs rapports de réactivité de copolymérisation avec l'éthylène. La composition des copolymères obtenus influence leurs propriétés thermiques (Tg, Tf). Des latex stables de copolymères de compositions variées ont pu ainsi être synthétisés. Ce travail en homo- et copolymérisation a souligné la complexité des milieux de polymérisation en émulsion impliquant un monomère gazeux supercritique comme l'éthylène
In this work, the free radical emulsion polymerization of ethylene under mild conditions (P < 250 bar and T < 90 °C) was investigated. Ethylene homopolymerization was first studied. Stable polyethylene latexes of significantly high solids content (30 %) were produced. This was achieved by the use of two different initiating and stabilizing systems (cationic and anionic). These latexes could be applied as hydrophobic coatings (e.g. on paper). Investigation of the thermal properties of the latexes evidenced crystallization phenomena at low temperatures, owing to PE confinement in the nanoparticles, which strongly impacted their final morphologies. Free radical emulsion copolymerization of ethylene was then studied. The investigated comonomers were styrene, butyl acrylate, methyl methacrylate and vinyl acetate. They differ in their reactivity ratios to ethylene and their water solubility. The composition of the obtained copolymers had a strong influence on their thermal properties (Tg, Tm). Stable latexes containing copolymers of various compositions were thus synthesized. This work on homo- and copolymerization evidenced the complexity of the polymerization media involving a gaseous supercritical monomer such as ethylene
APA, Harvard, Vancouver, ISO, and other styles
6

De, Bruyn Hank. "The Emulsion Polymerization of Vinyl Acetate." Thesis, The University of Sydney, 1999. http://hdl.handle.net/2123/381.

Full text
Abstract:
Abstract This work investigates the kinetics of the emulsion polymerization of vinyl acetate. Several aspects of this system have been clarified, including the induced decomposition of persulfate, retardation by oxygen and entry by, and analysis of, the aqueous phase oligomeric radicals. It has been shown that the retardation period observed in the emulsion polymerization of VAc can be explained by the effect of traces of oxygen (< 10-6 M) on the entry efficiency of the initiator-derived aqueous-phase oligomeric radicals. Comparison of rates of polymerization in V and persulfate -initiated polymerizations together with electrospray mass spectrometry of aqueous phase oligomers, has shown that the mechanism for the induced decomposition of persulfate by vinyl acetate is chain transfer to initiator from aqueous-phase oligomeric radicals. A value has been determined for the rate coefficient for transfer to initiator, by fitting literature data to a model based on this mechanism. The reported independence of the rate of polymerization from the monomer concentration in the emulsion polymerization of vinyl acetate has been investigated. Possible explanations for this behaviour have been proposed and tested in this work, by measuring radical-loss rates directly with y-relaxation techniques. Although the Y relaxations were found to be affected by experimental artefacts, it has been demonstrated that rapid exit is not responsible for the high radical-loss rates in this system. The major artefact identified in the y relaxations was the significant effect of relatively small exotherms on relaxation behaviour, Methodologies were developed for correcting affected data and for avoiding exotherms under certain conditions. Arrhenius parameters were determined for the rate coefficient for chain transfer to monomer using the In^M method, which utilises the whole MWD. This section of the work is incomplete, for reasons detailed in chapter 5. However, as a preliminary indication it was found that the frequency factor was 106.38 M-1 s-1 and the activation energy was 38.8 kJ mol-1.
APA, Harvard, Vancouver, ISO, and other styles
7

De, Bruyn Hank. "The Emulsion Polymerization of Vinyl Acetate." University of Sydney, Chemistry, 1999. http://hdl.handle.net/2123/381.

Full text
Abstract:
Abstract This work investigates the kinetics of the emulsion polymerization of vinyl acetate. Several aspects of this system have been clarified, including the induced decomposition of persulfate, retardation by oxygen and entry by, and analysis of, the aqueous phase oligomeric radicals. It has been shown that the retardation period observed in the emulsion polymerization of VAc can be explained by the effect of traces of oxygen (< 10-6 M) on the entry efficiency of the initiator-derived aqueous-phase oligomeric radicals. Comparison of rates of polymerization in V and persulfate -initiated polymerizations together with electrospray mass spectrometry of aqueous phase oligomers, has shown that the mechanism for the induced decomposition of persulfate by vinyl acetate is chain transfer to initiator from aqueous-phase oligomeric radicals. A value has been determined for the rate coefficient for transfer to initiator, by fitting literature data to a model based on this mechanism. The reported independence of the rate of polymerization from the monomer concentration in the emulsion polymerization of vinyl acetate has been investigated. Possible explanations for this behaviour have been proposed and tested in this work, by measuring radical-loss rates directly with y-relaxation techniques. Although the Y relaxations were found to be affected by experimental artefacts, it has been demonstrated that rapid exit is not responsible for the high radical-loss rates in this system. The major artefact identified in the y relaxations was the significant effect of relatively small exotherms on relaxation behaviour, Methodologies were developed for correcting affected data and for avoiding exotherms under certain conditions. Arrhenius parameters were determined for the rate coefficient for chain transfer to monomer using the In^M method, which utilises the whole MWD. This section of the work is incomplete, for reasons detailed in chapter 5. However, as a preliminary indication it was found that the frequency factor was 106.38 M-1 s-1 and the activation energy was 38.8 kJ mol-1.
APA, Harvard, Vancouver, ISO, and other styles
8

Barnette, Darrell Thomas. "Continuous miniemulsion polymerization." Diss., Georgia Institute of Technology, 1987. http://hdl.handle.net/1853/12518.

Full text
APA, Harvard, Vancouver, ISO, and other styles
9

Kashirsagar, Ravindra S. "Study of entry mechanism in emulsion polymerization." Thesis, Georgia Institute of Technology, 1993. http://hdl.handle.net/1853/11747.

Full text
APA, Harvard, Vancouver, ISO, and other styles
10

Leswin, Joost Sieger Kaspar. "Particle Formation in RAFT-mediated Emulsion Polymerization." Thesis, The University of Sydney, 2007. http://hdl.handle.net/2123/2176.

Full text
Abstract:
Particle formation in RAFT-mediated emulsion polymerization has been studied using reaction calorimetry. By measuring the heat flow during controlled feed ab-initio emulsion polymerization in the presence of amphipathic RAFT agents, particle formation by self-assembly of these species could be observed. Two different monomer systems, i.e. styrene and n-butyl acrylate, and various degrees of hydrophobicity of the initial macro-RAFT agents have been studied and compared. The different macro-RAFT agents were synthesized by first forming a hydrophilic block of poly(acrylic acid) that would later on act as the electrosteric stabilizing group for the particles. Subsequently, different lengths of hydrophobic blocks were grown at the reactive end of the poly(acrylic acid) hydrophilic block via the RAFT-mediated controlled radical polymerization, either comprised of n-butyl acrylate or styrene. Two processes govern particle formation: adsorption of macro-RAFT agents onto growing particles and formation of new particles by initiation of micellar aggregates or by homogeneous nucleation. Competition between these processes could be observed when monomers with a relatively high (n-butyl acrylate) or low (styrene) propagation rate coefficient were used. A model describing particle formation has been developed and the results of model calculations are compared with experimental observations. Preliminary modeling results based on a set of reasonable physico-chemical parameters already showed good agreement with the experimental results. Most parameters used have been verified experimentally. The development of the molecular weight distribution of the macro-RAFT agents has been analyzed by different techniques. Quantification of the particle formation process by analytical techniques was difficult, but qualitative insights into the fundamental steps governing the nucleation process have been obtained. The amount of macro-RAFT agents initially involved in particle formation could be determined from the increase of molecular weight. The particle size distribution has been measured by capillary hydrodynamic fractionation, transmission electron microscopy and dynamic light scattering. From the data obtained from these particle-sizing techniques, the number of particles during the reaction could be monitored, leading to an accurate estimate for the particle formation time. Upon implementation of the experimental data obtained for the surface active macro-RAFT systems, the model demonstrated to be very sensitive towards the “headgroup” area of the macro-RAFT species. Three nucleation cases based on the initial surface activity of the macro-RAFT species in the aqueous phase are proposed to explain the deviations from the assumptions of the nucleation model. Even though the macro-RAFT species have a narrow molecular weight distribution, they are nevertheless made up of a distribution of block lengths of polystyrene upon a distribution of block lengths of poly(acrylic acid). The resulting differences in initial surface activity are the most probable reason for the observed differences between model calculations and experimental results for the nucleation time and particle size distribution of the final latex product. With the procedure described above, latexes have been synthesized without using conventional surfactants and the mechanisms involved in the particle formation for these systems have been elucidated. The results of this work enable production of latex systems with well defined molecular mass distributions and narrow particle size distributions. Furthermore, the technique based on the application of amphipathic RAFT agents is promising for the production of complex polymeric materials in emulsion polymerization on a technical scale.
APA, Harvard, Vancouver, ISO, and other styles
More sources

Books on the topic "Emulsion polymerization"

1

A, Lovell P., and El-Aasser Mohamed S, eds. Emulsion polymerization and emulsion polymers. New York: J. Wiley, 1997.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
2

Ruckenstein, Eli, Hangquan Li, and Chong Cheng. Concentrated Emulsion Polymerization. Edited by Eli Ruckenstein, Hangquan Li, and Chong Cheng. Boca Raton : Taylor & Francis, a CRC title, part of the Taylor & Francis imprint, a member of the Taylor & Francis Group, the academic division of T&F Informa, plc, 2018.: CRC Press, 2019. http://dx.doi.org/10.1201/9780429026577.

Full text
APA, Harvard, Vancouver, ISO, and other styles
3

Warson, Henry. Polymer emulsion adhesives. Solihull, England: Solihull Chemical Services, 1993.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
4

Mittal, Vikas. Miniemulsion polymerization technology. Salem, MA: Scrivener, 2010.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
5

-H, Reichert K., Geiseler W, and Berlin International Workshop on Polymer Reaction Engineering (2nd : 1986?), eds. Polymer reaction engineering: Emulsion polymerization, high conversion polymerization, polycondensation. Basel: Hüthig & Wepf, 1986.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
6

Masayoshi, Okubo, ed. Polymer particles. Berlin: Springer, 2005.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
7

Mittal, Vikas. Miniemulsion polymerization technology. Salem, Mass: Scrivener ; Hoboken, N.J., 2010.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
8

Kemmere, Maria Francisca. Batch emulsion polymerization: A chemical engineering approach. Eindhoven: Technische Universiteit Eindhoven, 1999.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
9

Caneba, Gerard. Emulsion-based Free-Radical Retrograde-Precipitation Polymerization. Berlin, Heidelberg: Springer-Verlag Berlin Heidelberg, 2011.

Find full text
APA, Harvard, Vancouver, ISO, and other styles
10

Mittal, Vikas, ed. Polymer Nanocomposites by Emulsion and Suspension Polymerization. Cambridge: Royal Society of Chemistry, 2010. http://dx.doi.org/10.1039/9781849732192.

Full text
APA, Harvard, Vancouver, ISO, and other styles
More sources

Book chapters on the topic "Emulsion polymerization"

1

El-Aasser, Mohamed S. "Emulsion Polymerization." In An Introduction to Polymer Colloids, 1–34. Dordrecht: Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-009-0521-4_1.

Full text
APA, Harvard, Vancouver, ISO, and other styles
2

Tadros, Tharwat. "Emulsion Polymerization." In Encyclopedia of Colloid and Interface Science, 414. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-20665-8_82.

Full text
APA, Harvard, Vancouver, ISO, and other styles
3

El-Aasser, Mohamed S. "Emulsion Polymerization." In Scientific Methods for the Study of Polymer Colloids and Their Applications, 1–34. Dordrecht: Springer Netherlands, 1990. http://dx.doi.org/10.1007/978-94-009-1950-1_1.

Full text
APA, Harvard, Vancouver, ISO, and other styles
4

POEHLEIN, GARY W. "Emulsion Polymerization." In ACS Symposium Series, 131–50. Washington, D.C.: American Chemical Society, 1985. http://dx.doi.org/10.1021/bk-1985-0285.ch006.

Full text
APA, Harvard, Vancouver, ISO, and other styles
5

Gooch, Jan W. "Emulsion Polymerization." In Encyclopedic Dictionary of Polymers, 267. New York, NY: Springer New York, 2011. http://dx.doi.org/10.1007/978-1-4419-6247-8_4385.

Full text
APA, Harvard, Vancouver, ISO, and other styles
6

Kumar, Anil, and Rakesh K. Gupta. "Emulsion Polymerization." In Fundamentals of Polymer Engineering, 263–300. Third edition. | Boca Raton, FL : CRC Press/Taylor & Francis Group, 2018. | Earlier edition by Anil Kumar, Rakesh K. Gupta. | “Includes bibliographical references and index.: CRC Press, 2018. http://dx.doi.org/10.1201/9780429398506-7.

Full text
APA, Harvard, Vancouver, ISO, and other styles
7

Mishra, Munmaya, and Biao Duan. "Emulsion Polymerization." In The Essential Handbook of Polymer Terms and Attributes, 54–55. Boca Raton: CRC Press, 2024. http://dx.doi.org/10.1201/9781003161318-53.

Full text
APA, Harvard, Vancouver, ISO, and other styles
8

Ruckenstein, Eli, Hangquan Li, and Chong Cheng. "Conductive Polymer Composites." In Concentrated Emulsion Polymerization, 1–2. Boca Raton : Taylor & Francis, a CRC title, part of the Taylor & Francis imprint, a member of the Taylor & Francis Group, the academic division of T&F Informa, plc, 2018.: CRC Press, 2019. http://dx.doi.org/10.1201/9780429026577-1.

Full text
APA, Harvard, Vancouver, ISO, and other styles
9

Ruckenstein, Eli, and Xiang Zheng Kong. "Control of Pore Generation and Pore Size in Nanoparticles of Poly(styrene-methyl methacrylate-acrylic acid) *." In Concentrated Emulsion Polymerization, 104–14. Boca Raton : Taylor & Francis, a CRC title, part of the Taylor & Francis imprint, a member of the Taylor & Francis Group, the academic division of T&F Informa, plc, 2018.: CRC Press, 2019. http://dx.doi.org/10.1201/9780429026577-10.

Full text
APA, Harvard, Vancouver, ISO, and other styles
10

Li, Hangquan, and Eli Ruckenstein. "Amphiphilic Particles with Hydrophilic Core/Hydrophobic Shell Prepared via Inverted Emulsions *." In Concentrated Emulsion Polymerization, 115–27. Boca Raton : Taylor & Francis, a CRC title, part of the Taylor & Francis imprint, a member of the Taylor & Francis Group, the academic division of T&F Informa, plc, 2018.: CRC Press, 2019. http://dx.doi.org/10.1201/9780429026577-11.

Full text
APA, Harvard, Vancouver, ISO, and other styles

Conference papers on the topic "Emulsion polymerization"

1

Fahmiati, Sri, Sri Budi Harmami, Yenny Meliana, and Agus Haryono. "Emulsion polymerization of polystyrene-co-acrylic acid with Cu2O incorporation." In INTERNATIONAL SYMPOSIUM ON APPLIED CHEMISTRY (ISAC) 2016. Author(s), 2017. http://dx.doi.org/10.1063/1.4973170.

Full text
APA, Harvard, Vancouver, ISO, and other styles
2

Arora, Sachin, and Sebastian Engell. "Online optimizing control of emulsion polymerization processes with evaporative cooling." In 2006 IEEE Conference on Computer Aided Control System Design, 2006 IEEE International Conference on Control Applications, 2006 IEEE International Symposium on Intelligent Control. IEEE, 2006. http://dx.doi.org/10.1109/cacsd-cca-isic.2006.4776839.

Full text
APA, Harvard, Vancouver, ISO, and other styles
3

Arora, Sachin, and Sebastian Engell. "Online Optimizing Control of Emulsion Polymerization Processes with Evaporative Cooling." In 2006 IEEE International Conference on Control Applications. IEEE, 2006. http://dx.doi.org/10.1109/cca.2006.286055.

Full text
APA, Harvard, Vancouver, ISO, and other styles
4

Wang, Yang, and Francis J. Doyle. "Reachability analysis of particle size distribution in semibatch emulsion polymerization." In 2003 European Control Conference (ECC). IEEE, 2003. http://dx.doi.org/10.23919/ecc.2003.7085066.

Full text
APA, Harvard, Vancouver, ISO, and other styles
5

Hwang, Ho-Sang, Bum-Kyoung Seo, and Kune-Woo Lee. "Strippable Core-Shell Polymer Emulsion for Decontamination of Radioactive Surface Contamination." In ASME 2010 13th International Conference on Environmental Remediation and Radioactive Waste Management. ASMEDC, 2010. http://dx.doi.org/10.1115/icem2010-40193.

Full text
Abstract:
In this study, the core-shell composite polymer for decontamination from the surface contamination was synthesized by the method of emulsion polymerization and blends of polymers. The strippable polymer emulsion is composed of the poly(styrene-ethyl acrylate) [poly(St-EA)] composite polymer, poly(vinyl alcohol) (PVA) and polyvinylpyrrolidone (PVP). The morphology of the poly(St-EA) composite emulsion particle was core-shell structure, with polystyrene (PS) as the core and poly(ethyl acrylate) (PEA) as the shell. Core-shell polymers of styrene (St)/ethyl acrylate (EA) pair were prepared by sequential emulsion polymerization in the presence of sodium dodecyl sulfate (SDS) as an emulsifier using ammonium persulfate (APS) as an initiator. Related tests and analysis confirmed the success in synthesis of composite polymer. The products are characterized by FT-IR spectroscopy, TGA that were used, respectively, to show the structure, the thermal stability of the prepared polymer. Two-phase particles with a core-shell structure were obtained in experiments where the estimated glass transition temperature and the morphologies of emulsion particles. Decontamination factors of the strippable polymeric emulsion were evaluated with the polymer blend contents.
APA, Harvard, Vancouver, ISO, and other styles
6

Osenberg, Marco, Jan Forster, Soren Rust, Thomas Fritsch, Jan Tebrugge, Werner Pauer, and Thomas Musch. "Ultrasound Sensor for Process and Fouling Monitoring in Emulsion Polymerization Processes." In 2022 IEEE Sensors. IEEE, 2022. http://dx.doi.org/10.1109/sensors52175.2022.9967228.

Full text
APA, Harvard, Vancouver, ISO, and other styles
7

Paulen, Radoslav, Brahim Benyahia, M. A. Latifi, and Miroslav Fikar. "Optimal feeding of emulsion polymerization reactor for styrene and butyl acrylate copolymerization." In 2013 International Conference on Process Control (PC). IEEE, 2013. http://dx.doi.org/10.1109/pc.2013.6581448.

Full text
APA, Harvard, Vancouver, ISO, and other styles
8

MA, Gui-yu, Jin-juan TENG, Jia-ling PU, and Zhong-xiao LI. "The Preparation of a Reactive Emulsifier and Its Application in Emulsion Polymerization." In International Conference on Advanced Material Science and Engineeering (AMSE2016). WORLD SCIENTIFIC, 2016. http://dx.doi.org/10.1142/9789813141612_0011.

Full text
APA, Harvard, Vancouver, ISO, and other styles
9

Yılmaz, Onur, Çiğdem Kılıçarislan Özkan, Catalina N. Yılmaz, Ali Yorgancıoğlu, Hasan Özgünay, and Hüseyin Ata Karavana. "Synthesis and characterization of functional acrylic copolymers via RAFT mini-emulsion polymerization." In PROCEEDINGS OF THE 1ST INTERNATIONAL CONFERENCE ON MECHANICAL ENGINEERING AND APPLIED SCIENCE (ICMEAS 2017). Author(s), 2017. http://dx.doi.org/10.1063/1.5018501.

Full text
APA, Harvard, Vancouver, ISO, and other styles
10

Xing, Zhaoliang, Chong Zhang, He Huang, Hui Liu, Xiangyu Zhang, Yu Xiao, Yinghao Qi, Tao Jiang, and Jian Li. "Constructing spherical Ziegler-Natta catalyst through an emulsion process for ethylene polymerization." In MATERIALS SCIENCE, ENERGY TECHNOLOGY AND POWER ENGINEERING III (MEP 2019). AIP Publishing, 2019. http://dx.doi.org/10.1063/1.5125362.

Full text
APA, Harvard, Vancouver, ISO, and other styles
You might also be interested in the extended bibliographies on the topic 'Emulsion polymerization' for particular source types:
Journal articles Dissertations / Theses Books
We offer discounts on all premium plans for authors whose works are included in thematic literature selections. Contact us to get a unique promo code!

To the bibliography