Academic literature on the topic 'Electrolytes solide hybride polymère'
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Journal articles on the topic "Electrolytes solide hybride polymère":
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Kanai, Yamato, Koji Hiraoka, Mutsuhiro Matsuyama, and Shiro Seki. "Chemically and Physically Cross-Linked Inorganic–Polymer Hybrid Solvent-Free Electrolytes." Batteries 9, no. 10 (September 26, 2023): 492. http://dx.doi.org/10.3390/batteries9100492.
Abstract:
Safe, self-standing, all-solid-state batteries with improved solid electrolytes that have adequate mechanical strength, ionic conductivity, and electrochemical stability are strongly desired. Hybrid electrolytes comprising flexible polymers and highly conductive inorganic electrolytes must be compatible with soft thin films with high ionic conductivity. Herein, we propose a new type of solid electrolyte hybrid comprising a glass–ceramic inorganic electrolyte powder (Li1+x+yAlxTi2−xSiyP3−yO12; LICGC) in a poly(ethylene)oxide (PEO)-based polymer electrolyte that prevents decreases in ionic conductivity caused by grain boundary resistance. We investigated the cross-linking processes taking place in hybrid electrolytes. We also prepared chemically cross-linked PEO/LICGC and physically cross-linked poly(norbornene)/LICGC electrolytes, and evaluated them using thermal and electrochemical analyses, respectively. All of the obtained electrolyte systems were provided with homogenous, white, flexible, and self-standing thin films. The main ionic conductive phase changed from the polymer to the inorganic electrolyte at low temperatures (close to the glass transition temperature) as the LICGC concentration increased, and the Li+ ion transport number also improved. Cyclic voltammetry using [Li metal|Ni] cells revealed that Li was reversibly deposited/dissolved in the prepared hybrid electrolytes, which are expected to be used as new Li+-conductive solid electrolyte systems.
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Choi, Kyoung Hwan, Eunjeong Yi, Kyeong Joon Kim, Seunghwan Lee, Myung-Soo Park, Hansol Lee, and Pilwon Heo. "(Invited) Pragmatic Approach and Challenges of All Solid State Batteries: Hybrid Solid Electrolyte for Technical Innovation." ECS Meeting Abstracts MA2023-01, no. 6 (August 28, 2023): 988. http://dx.doi.org/10.1149/ma2023-016988mtgabs.
Abstract:
For the growth of electric vehicle market, lithium-ion batteries (LIBS) used in the EVs still requires safety and reliability. Unfortunately, large-scale application of the LIBs is being challenged due to the fact that the use of flammable liquid electrolytes has caused safety issues such as leakage and fire explosion. In this respect, all-solid-state batteries (ASSBs) have been intensively studied to ensure the safety and mileage that are superior to the current LIBs. In terms of solid electrolytes, oxide electrolytes not only shows high ionic conductivity (10-4 ~ 10-3 S/cm) but also high mechanical strength to suppress surface dendrite formation. In addition, the oxide electrolytes possess advantages such as non-flammability, high thermal stability, and excellent electrochemical stability (~ 6 V), enabling high temperature/high voltage operations of oxide-based ASSBs. However, most of oxide materials require a sintering process at high temperatures to form a planar solid electrolyte. And a lack of flexibility results in non-uniform electrolyte/electrode contact in the battery, which makes it difficult to apply the rigid oxide electrolyte directly. On the other hand, solid polymer electrolytes have also been actively investigated due to no leakage, good electrolyte/electrode contact, easy processing, flexibility, and good film formability. However, the solid polymer electrolytes have critical disadvantages such as low ionic conductivity at room temperature and low thermal/mechanical stability, which precludes commercialization of solid polymer-based ASSBs despite their advantages. To overcome each disadvantages of oxide and polymer electrolytes, we developed hybrid electrolytes for improved ionic conductivity, easy processing, and formation of continuous electrolyte/electrode interface. In this presentation, pragmatic approach and current challenges related to solid batteries will be discussed including innovative manufacturing process. Hybrid electrolytes and their synergistic effect on the battery performance as a promissing solution will be presented [Fig. 1]
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Liao, Cheng Hung, Chia-Chin Chen, Ru-Jong Jeng, and Nae-Lih (Nick) Wu. "Application of Artificial Interphase on Ni-Rich Cathode Materials Via Hybrid Ceramic-Polymer Electrolyte in All Solid State Batteries." ECS Meeting Abstracts MA2023-01, no. 6 (August 28, 2023): 1050. http://dx.doi.org/10.1149/ma2023-0161050mtgabs.
Abstract:
Among many cathode materials, nickel-rich LiNi0.83Co0.12Mn0.05O2 (NCM 831205) has been spotlighted as one of the most feasible candidates for next-generation LIBs because of its high discharge capacity (~200 mAh/g). However, NCM 831205 shows significant performance degradation, which is mostly attributed to cation mixing, surface side reactions, and intrinsic structural instability originating from the large volume changes during repeated cycling. Conventional lithium ion batteries (LIB) normally use flammable nonaqueous liquid electrolytes, resulting in a serious safety issue in use. In this respect, all-solid-state batteries (ASSB) are regarded as a fundamental solution to address the safety issue by using a solid state electrolyte in place of the conventional liquid one. This work employed lithium sulfonate (SO3Li) tethered polymer, obtained from sulfonation of commercial polymer, to serve as the artificial protective coating on the active NCM831205 of the cathode for ASSB based on hybrid PEO-ceramic solid electrolyte. The coating layer should prevent direct contact of electrolyte with the cathode, thus avoid the negative effects such as microcracks of NCM831205 and undesired CEI formation. The preparation of hybrid ceramic-polymer electrolyte through a solvent-free process. The hybrid electrolytes exhibit good flexibility and processability with respect to pure ceramic and pure PEO polymer electrolyte. It is demonstrated that the hybrid electrolytes can penetrate into cathode under 60°C, providing a good Li+ transfer channel inside the battery. Moreover, the sulfone based polymer protective coating could effectively improve the electrochemical stability of the NCM831205 without sacrificing the battery performance. Keywords: NCM831205, Artificial Polymer Coating, All-Solid-State Batteries
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LI, X. D., X. J. YIN, C. F. LIN, D. W. ZHANG, Z. A. WANG, Z. SUN, and S. M. HUANG. "INFLUENCE OF I2 CONCENTRATION AND CATIONS ON THE PERFORMANCE OF QUASI-SOLID-STATE DYE-SENSITIZED SOLAR CELLS WITH THERMOSETTING POLYMER GEL ELECTROLYTE." International Journal of Nanoscience 09, no. 04 (August 2010): 295–99. http://dx.doi.org/10.1142/s0219581x10006831.
Abstract:
Thermosetting polymer gel electrolytes (TPGEs) based on poly(acrylic acid)-poly(ethylene glycol) (PAA-PEG) hybrid were prepared and applied to fabricate dye-sensitized solar cells (DSCs). N-methylpyrrolidone (NMP) and γ-butyrolactone (GBL) were used as solvents for liquid electrolytes and LiI and KI as iodide source, separately. The microstructure of PAA-PEG shows a well swelling ability in liquid electrolyte and excellent stability of the swollen hybrid. The TPGE was optimized in terms of the liquid electrolyte absorbency and ionic conductivity photovoltaic performance. Quasi-solid-state DSCs containing TPGE with optimized KI electrolyte show higher efficiency, voltage, fill factor, and lower photocurrent than those with LiI electrolyte. The related mechanism was discussed. A quasi-solid-state DSC fabricated with optimized polymer gel electrolyte obtained an overall energy conversion efficiency of 4.90% under irradiation of 100 mW/cm2 (AM1.5).
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Vargas-Barbosa, Nella Marie, Sebastian Puls, and Henry Michael Woolley. "Hybrid Material Concepts for Thiophosphate-Based Solid-State Batteries." ECS Meeting Abstracts MA2023-01, no. 6 (August 28, 2023): 984. http://dx.doi.org/10.1149/ma2023-016984mtgabs.
Abstract:
Solid-state batteries (SSBs) could replace conventional lithium-ion batteries due to the possibility of increasing the energy density of the cells by using lithium metal as the anode material.[1] Among the many electrolyte candidates for lithium SSBs, the lithium thiophosphates are particularly interesting due to their high ionic conductivities at room temperature (>1 mS/cm). However, the (electro)chemical stability of these solid electrolytes is limited and not fully compatible with state-of-the-art high-potential cathode active materials[2] or the lithium metal anode.[3] At the cell level, the formation of interparticle voids between the various battery components (solid electrolyte, cathode active material, anode material, additives, decomposition interphases) hinder the net transport during cycling. To address the latter electro-chemo-mechanical challenges, we are exploring hybrid material approaches, in which we combine established materials (solid electrolytes, liquid electrolytes and/or polymer additives) with state-of-the-art cathode active materials and test their electrochemical performance in solid-state battery (half-)cells. Such cycling results are complimented by detailed electrochemical transport studies in symmetrical cells using DC polarization and electrochemical impedance spectroscopy, including transmission-line modeling. ex.situ chemically-specific spectroscopic methods are used to support our hypotheses and interpretation of the electrochemical results. Taken together, we attain a better picture on the positive (or negative) role hybrid materials play in SSBs. In this talk, we will showcase two hybrid systems, namely ionic liquid/thiophosphate lithium hybrid electrolytes and conductive polymers additives in NMC-based catholyte composites for Li6PS5Cl cells. The first part of the talk we will discuss the results in which we evaluate the performance of liquid electrolyte-solid electrolyte materials against lithium metal using galvanostatic electrochemical impedance spectroscopy. In the second part, we elucidate the partial ionic and electronic transport in polymer electrolyte-Li6PS5Cl-NMC catholytes as a function of polymer content using impedance spectroscopy and its effect in the cycling performance, both the stability as well as the magnitude of the discharge capacities. These systems serve as a good starting point for the further development and incorporation of hybrid materials in SSBs. Literature: [1] W. G. Zeier and J. Janek Nature Energy, 2016, 1, 16141. [2] G.F. Dewald, S. Ohno, M.A. Kraft, R. Kroever, P. Till, N.M. Vargas-Barbosa, J. Janek, W.G. Zeier Chem. Mater. 2019, 31, 8328. [3] L. M. Riegger, R. Schlem, J. Sann, W. G. Zeier, J. Janek, Angew. Chem. Int Ed 2021, 60, 6718. Figure 1
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Spencer Jolly, Dominic, Dominic L. R. Melvin, Isabella D. R. Stephens, Rowena H. Brugge, Shengda D. Pu, Junfu Bu, Ziyang Ning, et al. "Interfaces between Ceramic and Polymer Electrolytes: A Comparison of Oxide and Sulfide Solid Electrolytes for Hybrid Solid-State Batteries." Inorganics 10, no. 5 (April 26, 2022): 60. http://dx.doi.org/10.3390/inorganics10050060.
Abstract:
Hybrid solid-state batteries using a bilayer of ceramic and solid polymer electrolytes may offer advantages over using a single type of solid electrolyte alone. However, the impedance to Li+ transport across interfaces between different electrolytes can be high. It is important to determine the resistance to Li+ transport across these heteroionic interfaces, as well as to understand the underlying causes of these resistances; in particular, whether chemical interphase formation contributes to giving high resistances, as in the case of ceramic/liquid electrolyte interfaces. In this work, two ceramic electrolytes, Li3PS4 (LPS) and Li6.5La3Zr1.5Ta0.5O12 (LLZTO), were interfaced with the solid polymer electrolyte PEO10:LiTFSI and the interfacial resistances were determined by impedance spectroscopy. The LLZTO/polymer interfacial resistance was found to be prohibitively high but, in contrast, a low resistance was observed at the LPS/polymer interface that became negligible at a moderately elevated temperature of 50 °C. Chemical characterization of the two interfaces was carried out, using depth-profiled X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry, to determine whether the interfacial resistance was correlated with the formation of an interphase. Interestingly, no interphase was observed at the higher resistance LLZTO/polymer interface, whereas LPS was observed to react with the polymer electrolyte to form an interphase.
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Spencer Jolly, Dominic, Dominic L. R. Melvin, Isabella D. R. Stephens, Rowena H. Brugge, Shengda D. Pu, Junfu Bu, Ziyang Ning, et al. "Interfaces between Ceramic and Polymer Electrolytes: A Comparison of Oxide and Sulfide Solid Electrolytes for Hybrid Solid-State Batteries." Inorganics 10, no. 5 (April 26, 2022): 60. http://dx.doi.org/10.3390/inorganics10050060.
Abstract:
Hybrid solid-state batteries using a bilayer of ceramic and solid polymer electrolytes may offer advantages over using a single type of solid electrolyte alone. However, the impedance to Li+ transport across interfaces between different electrolytes can be high. It is important to determine the resistance to Li+ transport across these heteroionic interfaces, as well as to understand the underlying causes of these resistances; in particular, whether chemical interphase formation contributes to giving high resistances, as in the case of ceramic/liquid electrolyte interfaces. In this work, two ceramic electrolytes, Li3PS4 (LPS) and Li6.5La3Zr1.5Ta0.5O12 (LLZTO), were interfaced with the solid polymer electrolyte PEO10:LiTFSI and the interfacial resistances were determined by impedance spectroscopy. The LLZTO/polymer interfacial resistance was found to be prohibitively high but, in contrast, a low resistance was observed at the LPS/polymer interface that became negligible at a moderately elevated temperature of 50 °C. Chemical characterization of the two interfaces was carried out, using depth-profiled X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry, to determine whether the interfacial resistance was correlated with the formation of an interphase. Interestingly, no interphase was observed at the higher resistance LLZTO/polymer interface, whereas LPS was observed to react with the polymer electrolyte to form an interphase.
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Lee, Yan Ying, and Andre Weber. "Harmonization of Testing Procedures for All Solid State Batteries." ECS Meeting Abstracts MA2023-02, no. 2 (December 22, 2023): 340. http://dx.doi.org/10.1149/ma2023-022340mtgabs.
Abstract:
All Solid State Batteries (ASSBs) with lithium-ion based conducting solid state electrolytes are considered the next generation high performance batteries. They enable high power densities due to their single ion conducting solid electrolyte, eliminating salt concentration gradients and related polarization losses in the cell, and ensuring an unrivalled level of safety due to their non-combustibility. Currently, a variety of ASSBs based on different solid state electrolytes such as polymers, thiophosphates, oxides and combinations thereof are being developed. One general problem with ASSBs is establishing and maintaining contact between the solid electrolyte and the active material phase during production and cycling, respectively. In conventional lithium-ion batteries (LiBs), this contact is ensured by the liquid state of the electrolyte, but in ASSBs, chemical expansion and contraction of the active material during lithiation and delithiation can detach this contact, resulting in decreased capacity due to the loss of active material. As a consequence, ASSBs are often operated under pressurized conditions, applying pressures significantly exceeding those in conventional LiBs. The same holds for the operating temperature window. Especially for polymer electrolyte-based ASSBs, they are often operated at higher temperatures to compensate for the low ionic conductivity of polymers at room temperature. With respect to cell testing, such operating requirements must be considered, and testing protocols are designed according to the individual requirements of the tested cell. This contribution aims to provide an overview of testing protocols for various types of ASSBs applied to different cells with polymer-, thiophosphate-, oxide-, and hybrid-electrolytes. These protocols will be compared with standardized testing routines for conventional LiBs. Based on this compilation, a harmonized testing procedure that covers the special requirements of the individual cell types and enables a fair comparison of different ASSBs is suggested. Additionally, examples of ASSB testing results will be discussed, taking into consideration the harmonization of different testing parameters.
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Villaluenga, Irune, Kevin H. Wujcik, Wei Tong, Didier Devaux, Dominica H. C. Wong, Joseph M. DeSimone, and Nitash P. Balsara. "Compliant glass–polymer hybrid single ion-conducting electrolytes for lithium batteries." Proceedings of the National Academy of Sciences 113, no. 1 (December 22, 2015): 52–57. http://dx.doi.org/10.1073/pnas.1520394112.
Abstract:
Despite high ionic conductivities, current inorganic solid electrolytes cannot be used in lithium batteries because of a lack of compliance and adhesion to active particles in battery electrodes as they are discharged and charged. We have successfully developed a compliant, nonflammable, hybrid single ion-conducting electrolyte comprising inorganic sulfide glass particles covalently bonded to a perfluoropolyether polymer. The hybrid with 23 wt% perfluoropolyether exhibits low shear modulus relative to neat glass electrolytes, ionic conductivity of 10−4 S/cm at room temperature, a cation transference number close to unity, and an electrochemical stability window up to 5 V relative to Li+/Li. X-ray absorption spectroscopy indicates that the hybrid electrolyte limits lithium polysulfide dissolution and is, thus, ideally suited for Li-S cells. Our work opens a previously unidentified route for developing compliant solid electrolytes that will address the challenges of lithium batteries.
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Kirchberger, Anna Maria, Patrick Walke, and Tom Nilges. "Effect of Nanostructured Inorganic Ceramic Filler on Poly(ethylene oxide)-Based Solid Polymer Electrolytes." ECS Meeting Abstracts MA2023-01, no. 6 (August 28, 2023): 991. http://dx.doi.org/10.1149/ma2023-016991mtgabs.
Abstract:
In view of the ongoing changes in energy science and technology, the possibilities of energy storage are getting increasingly important. In particular, storing electrical energy is more complex than with fossil fuels. Lithium-Ion batteries are the most commonly used media for energy storage, but they also have some safety-related problems: toxic decomposition products can leak out and the devices can catch fire. Research is underway to find alternatives to minimize this potential hazards. Great improvements in safety matters can be achieved by replacing liquid electrolytes with ceramic/polymer hybrid electrolytes. These hybrid electrolytes combine the advantages of polymer electrolytes with the benefits of inorganic ceramic fillers.1 Flexibility, good contact ability and in addition the good processability is provided through the polymer. The inorganic ceramic filler in contrast adds mechanical stability, opens new pathways for the Lithium-Ions and can enhance the stability of the electrolyte. Figure 1: different Lithium-ion pathways in ceramic/polymer hybrid electrolytes dependent on different filler amounts. 2 In this work the impact of the manufacturing method on the conductivity of a series of electrolytes was examined. Therefore, hot pressing, solution casting and electrospinning were tested. Also, different distribution methods for the particles in the material were tested to monitor the influence of agglomeration on the conductivity. The materials were characterized regarding the crystallinity using X-Ray diffraction, the surface and particle distribution was monitored with SEM/EDX, the thermal character was investigated using DSC, the conductivity was determined using impedance spectroscopy and the electrochemical behavior was tested using cyclic voltammetry. Furthermore, the Arrhenius equation was used to interpret the results of impedance spectroscopy regarding their activation energy. The addition of inorganic ceramic fillers leads to an enhancement of the ionic conductivity in PEO based electrolytes and increases processability and stability of the electrolyte. In this work conductivities of 10-5 S/cm were reached at room temperature. The performance of the electrolyte was increased above three orders of magnitude compared to a PEO electrolyte without inorganic ceramic fillers. Walke, P.; Kirchberger, A.; Reiter, F.; Esken, D.; Nilges, T., Effect of nanostructured Al2O3 on poly(ethylene oxide)-based solid polymer electrolytes. Zeitschrift für Naturforschung B 2021, 76 (10-12), 615-624. Chen, L.; Li, Y.; Li, S.-P.; Fan, L.-Z.; Nan, C.-W.; Goodenough, J. B., PEO/garnet composite electrolytes for solid-state lithium batteries: From “ceramic-in-polymer” to “polymer-in-ceramic”. Nano Energy 2018, 46, 176-184. Figure 1
Dissertations / Theses on the topic "Electrolytes solide hybride polymère":
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Maouacine, Koceila. "Matériaux hybrides poreux silice/polymère comme électrolytes pour batterie lithium-ion tout solide." Electronic Thesis or Diss., Aix-Marseille, 2023. http://www.theses.fr/2023AIXM0024.
Abstract:
La conception de batteries lithium-ion utilisant un électrolyte solide est actuellement l’une des voies les plus étudiées pour s’affranchir des problèmes de sécurité lié à ces dispositifs. Dans ces travaux de thèse, nous proposons une nouvelle approche d'élaboration d'un électrolyte hybride poreux silice/polymère, contenant une fraction massique plus élevée de silice mésoporeuse que de polymère. Deux morphologies de matériaux hybrides de silice ont été étudiées : sous forme de poudres compressées (pastilles) et sous forme de films minces. Dans la première partie du travail, une poudre de silice hybride a été synthétisée puis calcinée pour libérer la porosité. La silice mésoporeuse a, ensuite, été fonctionnalisée par imprégnation en solution avec différents polymères de type PEG de faible poids moléculaire puis, par un sel de lithium, le LiTFSI. Les poudres hybrides ont été compressées sous forme de pastilles, présentant une porosité inter- et intraparticulaire. Il a été montré que, les pastilles hybrides présentent des propriétés de conductivité ionique prometteuse lorsque les porosités inter et intraparticulaires sont remplies par le complexe PEG-LiTFSI pour PEG de faible masse molaire (300-600 g/mol). Dans la seconde partie, des films de silice mésoporeuse ont été déposés sur une électrode de carbone vitreux en utilisant une électrode à disque rotatif (RDE). Après avoir caractérisé ces films du point des propriétés texturales et de la microstructure, ces derniers ont été fonctionnalisés par le complexe PEG-LiTFSI via un procédé d’imprégnation et l’étude préliminaire de leur conductivité ionique a été réaliséeThe design of lithium-ion batteries using a solid electrolyte is currently one of the most studied ways to overcome safety problem of these devices. In this thesis work, we propose a new approach to develop a porous silica/polymer hybrid electrolyte, containing a higher weight fraction of mesoporous silica than polymer. Two morphologies of silica hybrid materials were studied: as compressed powders (pellets) and as thin films. In the first part of the work, a hybrid silica powder was synthesized and then calcined to liberate the porosity. The mesoporous silica was then functionalized with different polymers of PEG of low molecular weight then by a simple solution impregnation. The hybrid powders were shaped as pellets, presenting inter- and intra-particle porosity. It was shown that the hybrid pellets present promising ionic conductivity properties when the inter- and intraparticle porosities are filled with the PEG-LiTFSI complex for PEG of low molar mass (300-600 g/mol). In the second part, mesoporous silica films were deposited on a glassy carbon electrode using a rotating disc electrode (RDE). After the characterization of these films from a textural properties and a microstructure point of view, they were functionalized by the PEG-LiTFSI complex via an impregnation process and the preliminary study of their ionic conductivity was performed
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Issa, Sébastien. "Synthèse et caractérisation d'électrolytes solides hybrides pour les batteries au lithium métal." Electronic Thesis or Diss., Aix-Marseille, 2022. http://www.theses.fr/2022AIXM0046.
Abstract:
Les problématiques engendrées par l’extraction et l’utilisation intensives des ressources fossiles ont forcé l’humanité à se tourner vers le développement d’énergies renouvelables et de véhicules électriques. Cependant, ces technologies doivent être couplées à des moyens de stockage de l’énergie efficaces pour exploiter leur potentiel. Les systèmes embarquant une anode de lithium métallique sont particulièrement intéressants car ils présentent une densité d’énergie élevée. Cependant, cette technologie souffre de la formation de dendrites pouvant déclencher des courts-circuits provoquant l’explosion du dispositif. Ainsi, de nombreux efforts ont été consacrés à l’élaboration d’électrolytes solides polymères (SPE) à base de POE permettant de constituer une barrière qui bloque la croissance dendritique tout en préservant les propriétés de conduction ionique. Cependant, la conductivité ionique des SPE à base de POE décroît fortement avec la température. A l’heure actuelle, les meilleurs SPE de la littérature nécessiteraient de fonctionner à 60 °C, ce qui signifie qu’une partie de l’énergie de la batterie sera détournée de son utilisation pour maintenir cette température. Ainsi, l’objectif principal de ce travail de thèse est de concevoir un SPE permettant le fonctionnement de la technologie de batterie au lithium métal à température ambiante. Ces SPE doivent présenter une conductivité ionique élevée à température ambiante (≈ 10-4 S.cm-1) et des propriétés mécaniques permettant l’inhibition du phénomène de croissance dendritique. Pour cela, les objectifs du projet sont focalisés sur le développement de nouveaux SPE nanocomposites et hybridesThe problems caused by the intensive extraction and use of fossil fuels have forced humanity to turn to the development of renewable energies and electric vehicles. However, these technologies need to be coupled with efficient energy storage means to exploit their potential. Lithium metal anode systems are particularly interesting because they have a high energy density. However, this technology suffers from the formation of dendrites that can trigger short circuits causing the device to explode. Thus, many efforts have been devoted to the development of POE-based solid polymer electrolytes (SPEs) that provide a barrier that blocks dendritic growth while preserving ionic conduction properties. However, the ionic conductivity of POE-based SPEs decreases strongly with temperature. Currently, the best SPEs in the literature would require operation at 60 °C, which means that some of the energy in the battery will be diverted from its use to maintain this temperature. Thus, the main objective of this thesis work is to design an SPE that allows the operation of lithium metal battery technology at room temperature. These SPEs must exhibit high ionic conductivity at room temperature (≈ 10-4 S.cm-1) and mechanical properties that allow the inhibition of the dendritic growth phenomenon. For this, the objectives of the project are focused on the development of new nanocomposite and hybrid SPEs
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Meabe, Iturbe Leire. "Innovative polycarbonates for lithium conducting polymer electrolytes." Thesis, Pau, 2019. http://www.theses.fr/2019PAUU3042.
Abstract:
E 21ème siècle doit faire face à de nouveaux défis sociétaux et environnementaux. Pour cela, la gestion de l’énergie est un élément clé et en particulier le développement des énergies renouvelables. Progressivement les énergies basées sur le solaire, l’éolienne, l’hydraulique, la géothermie et les bio-ressources prennent le pas sur les énergies fossiles. Néanmoins, ces sources d’énergie sont bien souvent intermittentes, par conséquent, il est indispensable de développer des systèmes de stockage d'énergie fiables. Parmi toutes les options le stockage électrochimique semble être le plus prometteur pour les appareils électroniques, les véhicules électriques ainsi que les réseaux. Aujourd’hui, même si les batteries lithium-ion sont largement répandues, car relativement performantes, il reste indispensable de concevoir et de développer de nouvelles batteries répondant mieux encore aux nouvelles contraintes.Une batterie classique est constituée de deux électrodes et entre les deux se trouve l’électrolyte. Actuellement, et en général, dans les batteries commercialisées l’électrolyte est un liquide constitué d’un sel de lithium dissout dans un solvant organique. Celui-ci présente plusieurs risques : i) d’inflammabilité ; ii) de fuite ; iii) de volatilité ; et iv) de toxicité. Ainsi, des recherches sont menées pour développer de nouveaux matériaux polymériques, qui en plus de répondre aux risques mentionnés précédemment, cherchent à optimiser les propriétés de : conductivité ionique, nombre de transport, stabilité électrochimique, stabilité thermique, stabilité mécanique, etc. Parmi les polymères envisagés, les polycarbonates ont montré ces dernières années des propriétés très intéressantes. Dans ce contexte, au cours de la thèse, plusieurs familles de polycarbonates ont été synthétisées par polycondensation, puis évaluées en tant qu'électrolytes polymères solides afin de mettre en évidence l'impact de la structure chimique sur les performancesThe 21st century must address new challenges. The highly qualified life, demanded by modern society, requires constant developments. Energy is the essential ingredient for the economic and social development. The technological revolution that we are now suffering has as a principle the energy produced by coal, oil, and gas. However, the consumption of these energy sources are limited and additionally, during the last decades have been strongly criticized due to the high CO2 emissions released. Besides, the energy produced by renewable energies are promising alternative supplies to limited non-renewable resources. Little by little, the use of fuel-based energy sources will be reduced and renewable solar energy, wind power, hydropower, geothermal energy and bioenergy will be settled in our life. Nevertheless, due to the intermittent availability of these type of resources, good energy storage systems have to be designed. Among the all systems, electrochemical energy storage systems (EESS)s seem to be the best alternative for the use of portable electronics, electric vehicles and smart grid facilities.Generally, a battery contains a liquid electrolyte on it, which is based on a salt dissolved in a liquid organic solvent. This solvent is known to be toxic and highly flammable. Great efforts have been devoted to design safe electrolytes. Thus, polymer electrolytes have been proposed as safe materials. Nevertheless, the ionic conductivity, lithium transference number and electrochemical stability window should be addressed in order to be used in different applications. In this direction, in this thesis different polycarbonates have been proposed as promising host materials and they have been evaluated in as safe electrolytes
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Weldekidan, Ephrem Terefe. "Design of lithium ion conducting porous hybrid materials for the development of solid Li-battery electrolytes." Thesis, Aix-Marseille, 2019. http://www.theses.fr/2019AIXM0707.
Abstract:
Dans ce travail, des matériaux hybrides polymères-silice poreuse sous forme de poudre et de film mince ont été synthétisés et caractérisés. L'étude préliminaire de leurs conductivité ionique Li+ a également été réalisée. Les poudres hybrides ont été synthétisées par voie sol-gel en utilisant des triblocs classiques (Pluronic, P123) et des diblocs copolymères amphiphiles bifonctinels fabriqués en laboratoire comme agents dirigeant la structure (SDA). Dans le premier cas, la modification post-synthétique a été utilisée pour fonctionnaliser la surface des pores de la silice avec du PEO. Dans un second temps, la fonctionnalisation de la surface des pores avec le bloc hydrophile (PEO) a été réalisée par extraction du bloc hydrophobe. Des films de silice avec des mésocanaux ordonnés de manière hexagonale et orientés verticalement ont été synthétisés sur la surface de l'électrode via un procédé d'auto-assemblage électro-assisté dans des conditions hydrodynamiques. Les films formés sont mésoporeux (3 nm de diamètre) et entièrement accessibles. Un film de 660 nm d'épaisseur a été obtenu en 200 secondes. Ce film a été fonctionnalisé avec du PEO puis du sel de lithium par le biais d'une méthode d'imprégnation en solution. La conductivité ionique des matériaux hybrides a été étudiée après la mise en forme de la poudre sous forme de pastille ou de film directement formé à la surface de l'électrode. Les résultats montrent la conductivité des ions Li+ apportée aux matériaux. Les pastilles ont une porosité interparticulaire de 40% et le remplissage avec l’électrolyte polymère a un effet positif sur l’optimisation de la conductivité des pastillesIn this work, porous polymer-silica hybrid materials as a powder and thin film are synthesized and characterized. The preliminary study of their Li+ ionic conductivity properties are carried out as well. Here, the polymer electrolyte is embedded in silica matrix - polymer-in-ceramic approach. The hybrid powders are synthesized through sol-gel using conventional triblock (Pluronic, P123) and laboratory made bifunctional diblock amphiphilic copolymers as structure directing agents (SDA). In the first case, post-synthetic modification is used to functionalize the pore surface of silica with PEO. The second allowed to direct functionalization the pore surface with hydrophilic block (PEO) through extraction of hydrophobic block. Particle-free mesoporous silica films with hexagonally ordered and vertically oriented mesochannels are synthesized on electrode surface via electro-assisted self-assembly method under hydrodynamic condition. The resulting films are mesoporous (a diameter of 3 nm) and fully accessible. A film with thickness of 660 nm was grown in 200 s, and functionalized with PEO and then lithium salt through solution impregnation method. The ionic conductivity properties of hybrids were performed after shaping the powder as a pellet or with the hybrid film directly formed on the electrode surface. The results showed that the Li+ conductivity brought to the materials. The pellets have 40 % interparticle porosity and filling this with polymer electrolyte has positive effect on optimizing conductivity of the pellets (2.0 x 10-7 Scm-1 for 35 % filling and 6.8 x 10-7 Scm-1 for 100% filling at 25 °C)
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Yahata, Yoshikazu. "Extended Design of Concentrated-Polymer-Brush-Decorated Hybrid Nanoparticles and Their Use for Phase-Separation Control." Kyoto University, 2018. http://hdl.handle.net/2433/232486.
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Frenck, Louise. "Study of a buffer layer based on block copolymer electrolytes, between the lithium metal and a ceramic electrolyte for aqueous Lithium-air battery." Thesis, Université Grenoble Alpes (ComUE), 2016. http://www.theses.fr/2016GREAI041/document.
Abstract:
La technologie Lithium-air développée par EDF utilise une électrode à air qui fonctionne avec un électrolyte aqueux ce qui empêche l’utilisation de lithium métal non protégé comme électrode négative. Une membrane céramique (LATP:Li1+xAlxTi2-x(PO4)3) conductrice d’ion Li+ est utilisée pour séparer le milieu aqueux de l’électrode négative. Cependant, cette céramique n'est pas stable au contact du lithium, il est donc nécessaire d'intercaler entre le lithium et la céramique un matériau conducteur des ions Li+. Celui-ci devant être stable au contact du lithium et empêcher ou fortement limiter la croissance dendritique. Ainsi, ce projet s'est intéressé à l'étude d'électrolytes copolymères à blocs (BCE).Tout d'abord, l'étude des propriétés physico-chimiques spécifiques de ces BCEs en cellule lithium-lithium symétrique a été réalisée notamment les propriétés de transport (conductivités, nombre de transport), et la résistance à la croissance dendritique du lithium. Puis dans un second temps, l'étude des composites BCE-céramique a été mise en place. Nous nous sommes en particulier focalisés sur l'analyse du transfert ionique polymère-céramique.Plusieurs techniques de caractérisation ont été utilisées telles que la spectroscopie d'impédance électrochimique (transport et interface), le SAXS (morphologies des BCEs), la micro-tomographie par rayons X (morphologies des interfaces et des dendrites).Pour des électrolytes possédant un nombre de transport unitaire (single-ion), nous avons obtenus des résultats remarquables concernant la limitation à la croissance dendritique. La micro-tomographie des rayons X a permis de montrer que le mécanisme de croissance hétérogène dans le cas des single-ion est très différent de celui des BCEs neutres (t+ < 0.2)The lithium-air (Li-air) technology developed by EDF uses an air electrode which works with an aqueous electrolyte, which prevents the use of unprotected lithium metal electrode as a negative electrode. A Li+ ionic conductor glass ceramic (LATP:Li1+xAlxTi2-x(PO4)3) has been used to separate the aqueous electrolyte compartment from the negative electrode. However, this glass-ceramic is not stable in contact with lithium, it is thus necessary to add between the lithium and the ceramic a buffer layer. In another hand, this protection should ideally resist to lithium dendritic growth. Thus, this project has been focused on the study of block copolymer electrolytes (BCE).In a first part, the study of the physical and chemical properties of these BCEs in lithium symmetric cells has been realized especially transport properties (ionic conductivities, transference number), and resistance to dendritic growth. Then, in a second part, the composites BCE-ceramic have been studied.Several characterization techniques have been employed and especially the electrochemical impedance spectroscopy (for the transport and the interface properties), the small angle X-ray scattering (for the BCE morphologies) and the hard X-ray micro-tomography (for the interfaces and the dendrites morphologies). For single-ion BCE, we have obtained interesting results concerning the mitigation of the dendritic growth. The hard X-ray micro-tomography has permitted to show that the mechanism involved in the heterogeneous lithium growth in the case of the single-ion is very different from the one involved for the neutral BCEs (t+ < 0.2)
Conference papers on the topic "Electrolytes solide hybride polymère":
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Yoshida, Hideki, Shinji Amaha, and Hisataka Yakabe. "Hybrid Systems Using Solid Oxide Fuel Cell and Polymer Electrolyte Fuel Cell." In ASME 2008 International Mechanical Engineering Congress and Exposition. ASMEDC, 2008. http://dx.doi.org/10.1115/imece2008-66213.
Abstract:
In this paper, the concept of an SOFC (Solid Oxide Fuel Cell) and PEFC (Polymer Electrolyte Fuel Cell) hybrid system is presented. Large-scale SOFC systems operated in a thermally self-sustainable state produce excess heat. The excess heat can be used for producing hydrogen. Several variations of hydrogen production systems are presented here. One way is to produce the hydrogen by using an extra reformer. Another way is purifying the off-fuel of SOFCs. The produced hydrogen can be used as the fuel for PEFCs. The overall electrical efficiency of a combination of an SOFC and PEFCs is higher than that of a standalone SOFC. When the hydrogen produced by purifying the off-fuel of the SOFC is used as the fuel for PEFCs, the overall electrical conversion efficiency increases by around 20%.
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Gallagher, Tanya M., Constantin Ciocanel, and Cindy Browder. "Structural Load Bearing Supercapacitors Using a PEGDGE Based Solid Polymer Electrolyte Matrix." In ASME 2011 Conference on Smart Materials, Adaptive Structures and Intelligent Systems. ASMEDC, 2011. http://dx.doi.org/10.1115/smasis2011-5113.
Abstract:
The interest in developing multifunctional materials has greatly increased in the last decade. Power storage composites are just one class of multifunctional materials that has the potential to lead to significant size and weight reduction. Many electronic devices (i.e. laptops, cellphones, iPods, etc.) and mechanical systems that require or generate electrical power during operation (i.e., hybrid or fully electric cars, wind turbines, airplanes, etc.) could benefit substantially from these materials. While several types of power storage structural composites have been developed to date, i.e. composite batteries and fuel cells, structural load bearing super- and ultra-capacitors appear to be the most promising ones. To date, two classes of structural capacitors have been explored: dielectric and solid electrolyte capacitors; the former are suitable for applications where very high voltage bursts of electrical energy are needed, while the latter are suitable for applications where lower voltage levels are required (i.e. more general power storage/delivery applications). This paper describes the efforts made to develop and characterize electro-mechanically structural supercapacitors. The load-bearing supercapacitors discussed here have been made with carbon fiber weave electrodes and separators of various materials, glued together with a solid polymer electrolyte (SPE) matrix. Electrochemical characterization reported specific capacitances as high as 2.9μF/mm3 and energy densities as high as 4.9 kJ/g.
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Hashim, Mohd Azman, Nadhrah Md Yatim, Nor Azura Che Mahmud, Nur Ezniera Shafieza Sazali, Ellisah Hamdan, Mohd Adib Yahya, Che Wan Zanariah Che Wan Ngah, and Syahida Suhaimi. "Hybrid solid polymer electrolyte from diapers as separator for electrochemical double layer capacitor (EDLC)." In RECENT ADVANCEMENT ON APPLIED PHYSICS, INDUSTRIAL CHEMISTRY AND CHEMICAL TECHNOLOGY: Proceedings of the International Conference on Recent Advancements in Science and Technology 2017 (ICoRAST2017). Author(s), 2018. http://dx.doi.org/10.1063/1.5041219.
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Saadiah, M. A., and A. S. Samsudin. "Study on ionic conduction of solid bio-polymer hybrid electrolytes based carboxymethyl cellulose (CMC)/polyvinyl alcohol (PVA) doped NH4NO3." In GREEN DESIGN AND MANUFACTURE: ADVANCED AND EMERGING APPLICATIONS: Proceedings of the 4th International Conference on Green Design and Manufacture 2018. Author(s), 2018. http://dx.doi.org/10.1063/1.5066864.
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K., Lee T., A. Ahmad, and N. Hasyareeda. "Preparation and characterization on nano-hybrid composite solid polymer electrolyte of PVdF-HFP /MG49-ZrO2 for battery application." In THE 2014 UKM FST POSTGRADUATE COLLOQUIUM: Proceedings of the Universiti Kebangsaan Malaysia, Faculty of Science and Technology 2014 Postgraduate Colloquium. AIP Publishing LLC, 2014. http://dx.doi.org/10.1063/1.4895231.
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Gadalla, Mohamed, and Nabil Al Aid. "Analysis of a Hybrid PEMFC-SOFC Gas Turbine Power Plant." In ASME 2013 Power Conference. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/power2013-98242.
Abstract:
In this study, a complete economic analysis of integrating different types of fuel cells in Gas Turbine power plants is conducted. The paper investigates the performance of a hybrid system that comprises of a SOFC (Solid-Oxide-Fuel-Cell), a PEMFC (polymer electrolyte membrane fuel Cell), and SOFC-PEMFC which is/are integrated into a Gas Turbine power plant. Detailed modeling, thermodynamic, kinetic, geometric models are developed, implemented and validated for the synthesis/design and operational analysis of the combined hybrid system. The economic analysis is considered to be the basic concepts for thermo-economic optimization of the power plant under investigation, with the aim of finding the optimum set of design/operating parameters. Moreover, one of the aims of this paper is to present a detailed economic analysis of a highly coupled PEMFC-SOFC–GT hybrid plant, paying special attention to the sources of inefficiency and analyzing their variations with respect to changes in their operational parameters.
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Gadalla, Mohamed, and Nabil Al Aid. "Thermodynamic Modeling and Energy Analysis of a SOFC-PEMFC Combination in a Gas Turbine Cycle." In ASME 2010 8th International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2010. http://dx.doi.org/10.1115/fuelcell2010-33339.
Abstract:
This paper studies the performance of a hybrid system that comprises a SOFC (Solid-Oxide-Fuel-Cell) combined with a PEMFC (polymer electrolyte membrane fuel Cell) which is integrated into a Gas Turbine power plant. Detailed modeling, thermodynamic, kinetic, geometric models are developed, implemented and validated for the synthesis/design and operational analysis of the combined hybrid system. In this system, the PEMFC makes use of the internal reforming ability of the SOFC to produce hydrogen which is necessary for the PEMFC operation. The heat released in the SOFC is utilized in the internal reforming process. Different levels of modeling for the SOFC, the PEMFC and the integrated system are presented. The overall system performance is analyzed by employing individual models and further applying thermodynamic laws for the entire cycle. The paper also introduces different methods of using shift reactors where CO reacts with H2O to produce CO2 and H2 to further increase the efficiency of the system by introducing a new factor to control parasitic energy consumption. In addition to this, the paper also suggests cooling the H2 stream before entering the PEMFC stack using the exhaust air of the Gas turbine. The main components of the SOFC+PEMFC system are a SOFC stack, shift reactors, selective oxidizer and a PEMFC stack. The fuel cells are connected in series for fuel feeding. Furthermore, although the efficiency of the SOFC increases with increasing operating pressures, the paper describes that the efficiency of the SOFC-PEMFC combination also varies with changing the temperatures. Energy and entropy balances are performed not only for the whole system but also for each component to evaluate the distribution of irreversibility and thermodynamic inefficiencies. According to the study, around 5% efficiency improvement was obtained with a parallel SOFC-PEMFC system as compared with a stand-alone SOFC. Alternative methods of improving the efficiencies are also introduced.
Reports on the topic "Electrolytes solide hybride polymère":
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Oh, Kyeong-Seok, Shuai Yuan, and Sang-Young Lee. Scalable semi-solid batteries based on hybrid polymer-liquid electrolytes. Peeref, June 2023. http://dx.doi.org/10.54985/peeref.2306p1973287.