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Journal articles on the topic 'Electrochemical Impedance Spectroscopy'

Author: Grafiati

Published: 4 June 2021

Last updated: 5 October 2024

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1

Chang, Byoung-Yong, and Su-Moon Park. "Electrochemical Impedance Spectroscopy." Annual Review of Analytical Chemistry 3, no. 1 (June 2010): 207–29. http://dx.doi.org/10.1146/annurev.anchem.012809.102211.

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2

Sacci, Robert L., and David Harrington. "Dynamic Electrochemical Impedance Spectroscopy." ECS Transactions 19, no. 20 (December 18, 2019): 31–42. http://dx.doi.org/10.1149/1.3247564.

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3

Ciucci, Francesco. "Modeling electrochemical impedance spectroscopy." Current Opinion in Electrochemistry 13 (February 2019): 132–39. http://dx.doi.org/10.1016/j.coelec.2018.12.003.

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4

Ragoisha, G. A., and A. S. Bondarenko. "Potentiodynamic electrochemical impedance spectroscopy." Electrochimica Acta 50, no. 7-8 (February 2005): 1553–63. http://dx.doi.org/10.1016/j.electacta.2004.10.055.

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5

Park, Su-Moon, Jung-Suk Yoo, Byoung-Yong Chang, and Eun-Shil Ahn. "Novel instrumentation in electrochemical impedance spectroscopy and a full description of an electrochemical system." Pure and Applied Chemistry 78, no. 5 (January 1, 2006): 1069–80. http://dx.doi.org/10.1351/pac200678051069.

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The evolution of impedance measurement methods into the current state of the art is reviewed briefly, and recent efforts to develop new instruments to make electrochemical impedance spectroscopy (EIS) measurements faster and more accurate are described. The most recent approach for impedance measurement uses a multichannel detection technique, which is analogous to a spectroscopic measurement such as in Fourier transform infrared spectroscopy. This method, which is capable of making impedance measurements in real time during an electrochemical experiment, allows us to come up with a new integrated equation that makes a full description of an electrochemical system possible.

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6

Fasmin, Fathima, and Ramanathan Srinivasan. "Review—Nonlinear Electrochemical Impedance Spectroscopy." Journal of The Electrochemical Society 164, no. 7 (2017): H443—H455. http://dx.doi.org/10.1149/2.0391707jes.

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7

Vereecken, Jean. "Book Review - Electrochemical Impedance Spectroscopy." Electrochemical Society Interface 18, no. 2 (June 1, 2009): 19–20. http://dx.doi.org/10.1149/2.006092if.

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8

Mukhopadhyay, Rajendrani. "Electrochemical impedance spectroscopy says “cheese!”." Analytical Chemistry 82, no. 21 (November 2010): 8756. http://dx.doi.org/10.1021/ac102467a.

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9

Tarola, Alessandro, Danilo Dini, Elisabetta Salatelli, Franco Andreani, and Franco Decker. "Electrochemical impedance spectroscopy of polyalkylterthiophenes." Electrochimica Acta 44, no. 24 (July 1999): 4189–93. http://dx.doi.org/10.1016/s0013-4686(99)00133-4.

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10

Talaga, David S., and Michael J. Vitarelli. "Electrochemical Impedance Spectroscopy of Nanopores." Biophysical Journal 104, no. 2 (January 2013): 521a. http://dx.doi.org/10.1016/j.bpj.2012.11.2882.

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11

Maouche, Naima, and Belkacem Nessark. "Cyclic Voltammetry and Impedance Spectroscopy Behavior Studies of Polyterthiophene Modified Electrode." International Journal of Electrochemistry 2011 (2011): 1–5. http://dx.doi.org/10.4061/2011/670513.

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We present in this work a study of the electrochemical behaviour of terthiophene and its corresponding polymer, which is obtained electrochemically as a film by cyclic voltammetry (CV) on platinum electrode. The analysis focuses essentially on the effect of two solvents acetonitrile and dichloromethane on the electrochemical behaviour of the obtained polymer. The electrochemical behavior of this material was investigated by cyclic voltammetry and electrochemical impedance spectroscopy (EIS). The voltammograms show that the film of polyterthiophene can oxide and reduce in two solutions; in acetonitrile, the oxidation current intensity is more important than in dichloromethane. The impedance plots show the semicircle which is characteristic of charge-transfer resistance at the electrode/polymer interface at high frequency and the diffusion process at low frequency.

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12

Wang, Hong Fang, Jiang Chun Hu, and Zhen Xia Yuan. "The Mathematical Foundation of Rock Electrochemical Impedance Spectroscopy." Advanced Materials Research 446-449 (January 2012): 1703–8. http://dx.doi.org/10.4028/www.scientific.net/amr.446-449.1703.

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The electromagnetic characteristics of rock and ore play an important role in resources, engineering and environmental fields. The high frequency part of rock electrochemical impedance spectroscopy can reveal its crack characteristics according to the test results and rock physical model and equivalent circuit. The mathematical foundation of high frequency part of rock electrochemical impedance spectroscopy is studied, and the ideal Nyquist figure is obtained from that, and the response characteristics of rock electrochemical impedance spectroscopy volume arc are been proofed. It provides the theory basis for further study rock electrochemical detection technology.

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13

Ramanavicius, A., A. Finkelsteinas, H. Cesiulis, and A. Ramanaviciene. "Electrochemical impedance spectroscopy of polypyrrole based electrochemical immunosensor." Bioelectrochemistry 79, no. 1 (August 2010): 11–16. http://dx.doi.org/10.1016/j.bioelechem.2009.09.013.

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14

Hallemans, Noël, David Howey, Alberto Battistel, Fabio La Mantia, Dhammika Widanalage, Annick Hubin, and John Lataire. "Electrochemical Impedance Spectroscopy Beyond Linearity and Stationarity." ECS Meeting Abstracts MA2024-01, no. 2 (August 9, 2024): 245. http://dx.doi.org/10.1149/ma2024-012245mtgabs.

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Electrochemical impedance spectroscopy (EIS) is a widely used experimental technique for characterising materials and electrochemical devices. By measuring the impedance at selected frequencies, one can distinguish between electrochemical processes happening at different time-scales (such as diffusion and charge transfer). Classical EIS measurements [1,2] require the electrochemical processes under investigation to behave as a linear time-invariant (LTI) system. However, electrochemical processes do not naturally satisfy this requirement: their dynamics are inherently nonlinear, and evolve depending on several parameters. For lithium-ion batteries, the dynamics change with temperature, state-of-charge, and state-of-health [3]. Due to the time-invariance constraint of EIS, the technique can only reveal information about electrochemical processes at operating points, that is, at fixed temperature and state-of-charge, while in steady-state. Moreover, due to the linearity constraint, EIS can only reveal information on linear dynamics about these operating points. Hence, classical EIS cannot be used to characterise electrochemical processes in operating conditions such as charge and discharge, or relaxation. These are severe limitations! In this contribution, we demonstrate how to measure impedance data beyond the limiting constraints of linearity and stationarity [4]. As a case-study, we measure the impedance of commercial lithium-ion batteries during charge and discharge using a recently-developed operando EIS technique [5,6] (leveraging the use of the frequency domain and multisine excitations). The measurements show that impedance data during operation is different from ‘classical’ impedance data (at rest). More specifically, the charge transfer resistance is shown to decrease during operation, which can be explained via physics-based battery models. This showcases that operando EIS is a promising experimental tool enabling the characterisation of electrochemical processes during operation (which is not possible with classical EIS). Examples of applications where operando EIS is promising include monitoring fast-charging [7] and parametrising physics-based models. [1] Orazem, M.E. and Tribollet, B., 2008. Electrochemical impedance spectroscopy. Wiley. [2] Wang, S., Zhang, J., Gharbi, O., Vivier, V., Gao, M. and Orazem, M.E., 2021. Electrochemical impedance spectroscopy. Nature Reviews Methods Primers, 1(1), p.41. [3] Doyle, M., Fuller, T.F. and Newman, J., 1993. Modeling of galvanostatic charge and discharge of the lithium/polymer/insertion cell. Journal of the Electrochemical society, 140(6), p.1526. [4] Hallemans, N., Howey, D., Battistel, A., Saniee, N.F., Scarpioni, F., Wouters, B., La Mantia, F., Hubin, A., Widanage, W.D. and Lataire, J., 2023. Electrochemical impedance spectroscopy beyond linearity and stationarity—A critical review. Electrochimica Acta, p.142939. [5] Hallemans, N., Pintelon, R., Van Gheem, E., Collet, T., Claessens, R., Wouters, B., Ramharter, K., Hubin, A. and Lataire, J., 2021. Best linear time-varying approximation of a general class of nonlinear time-varying systems. IEEE Transactions on Instrumentation and Measurement, 70, pp.1-14. [6] Hallemans, N., Widanage, W.D., Zhu, X., Moharana, S., Rashid, M., Hubin, A. and Lataire, J., 2022. Operando electrochemical impedance spectroscopy and its application to commercial Li-ion batteries. Journal of Power Sources, 547, p.232005. [7] Zhu, X., Hallemans, N., Wouters, B., Claessens, R., Lataire, J. and Hubin, A., 2022. Operando odd random phase electrochemical impedance spectroscopy as a promising tool for monitoring lithium-ion batteries during fast charging. Journal of Power Sources, 544, p.231852. Figure 1

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15

Tomy, Ann Mary, Bhasha Sathyan, and Jobin Cyriac. "Ni(OH)₂-MoS₂ Nanocomposite Modified Glassy Carbon Electrode for the Detection of Dopamine and α-Lipoic Acid." Journal of The Electrochemical Society 170, no. 4 (April 1, 2023): 047506. http://dx.doi.org/10.1149/1945-7111/acc97f.

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Here, we report an electrochemical sensor realized using a nanocomposite consisting of nickel hydroxide nanosheets and exfoliated MoS2 nanosheets. The system was able to detect dopamine and α-lipoic acid in phosphate-buffered saline (PBS) solution at a pH of 7.4. The nanocomposites were characterized using microscopic and spectroscopic methods. The electrochemical characterizations were carried out using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and differential pulse voltammetry (DPV). It was observed that Ni(OH)2/MoS2 composite in the weight ratio of 2:1 has better results in terms of electrochemically active surface area, impedance, analytical parameters and stability. The dynamic range for dopamine detection was 0.75 − 95 μM with a LOD value of 56 nM and for α-lipoic acid, the range was 1 − 75 μM and the LOD was 51 nM.

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16

Zhao, Lei, Haifeng Dai, Fenglai Pei, Pingwen Ming, Xuezhe Wei, and Jiangdong Zhou. "A Comparative Study of Equivalent Circuit Models for Electro-Chemical Impedance Spectroscopy Analysis of Proton Exchange Membrane Fuel Cells." Energies 15, no. 1 (January 5, 2022): 386. http://dx.doi.org/10.3390/en15010386.

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Electrochemical impedance spectroscopy is one of the important tools for the performance analysis and diagnosis of proton exchange membrane fuel cells. The equivalent circuit model is an effective method for electrochemical impedance spectroscopy resolution. In this paper, four typical equivalent circuit models are selected to comprehensively compare and analyze the difference in the fitting results of the models for the electrochemical impedance spectroscopy under different working conditions (inlet pressure, stoichiometry, and humidity) from the perspective of the fitting accuracy, change trend of the model parameters, and the goodness of fit. The results show that the fitting accuracy of the model with the Warburg element is the best for all under each working condition. When considering the goodness of fit, the model with constant phase components is the best choice for fitting electrochemical impedance spectroscopy under different inlet pressure and air stoichiometry. However, under different air humidity, the model with the Warburg element is best. This work can help to promote the development of internal state analysis, estimation, and diagnosis of the fuel cell based on the equivalent circuit modeling of electrochemical impedance spectroscopy.

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17

Valiūnienė, Aušra, Jurate Petroniene, Inga Morkvenaite-Vilkonciene, Georgi Popkirov, Almira Ramanaviciene, and Arunas Ramanavicius. "Redox-probe-free scanning electrochemical microscopy combined with fast Fourier transform electrochemical impedance spectroscopy." Physical Chemistry Chemical Physics 21, no. 19 (2019): 9831–36. http://dx.doi.org/10.1039/c9cp00187e.

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Scanning electrochemical microscopy (SECM) hybridized with fast Fourier transform-based electrochemical impedance spectroscopy (FFT-EIS) seems to be a powerful variation of scanning electrochemical impedance microscopy (SEIM).

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18

Mansfeld, F., and M. W. Kendig. "Electrochemical Impedance Spectroscopy of Protective Coatings." Materials Science Forum 8 (January 1986): 337–50. http://dx.doi.org/10.4028/www.scientific.net/msf.8.337.

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19

Li, Jing, Byung Kun Kim, Kang-Kyun Wang, Ji-Eun Im, Han Nim Choi, Dong-Hwan Kim, Seong In Cho, Won-Yong Lee, and Yong-Rok Kim. "Sensing Estrogen with Electrochemical Impedance Spectroscopy." Journal of Analytical Methods in Chemistry 2016 (2016): 1–6. http://dx.doi.org/10.1155/2016/9081375.

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This study demonstrates the application feasibility of electrochemical impedance spectroscopy (EIS) in measuring estrogen (17β-estradiol) in gas phase. The present biosensor gives a linear response (R2=0.999) for 17β-estradiol vapor concentration from 3.7 ng/L to 3.7 × 10−4 ng/L with a limit of detection (3.7 × 10−4 ng/L). The results show that the fabricated biosensor demonstrates better detection limit of 17β-estradiol in gas phase than the previous report with GC-MS method. This estrogen biosensor has many potential applications for on-site detection of a variety of endocrine disrupting compounds (EDCs) in the gas phase.

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20

Farace, G., G. Lillie, T. Hianik, P. Payne, and P. Vadgama. "Reagentless biosensing using electrochemical impedance spectroscopy." Bioelectrochemistry 55, no. 1-2 (January 2002): 1–3. http://dx.doi.org/10.1016/s1567-5394(01)00166-9.

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21

Strašák, L., J. Dvořák, S. Hasoň, and V. Vetterl. "Electrochemical impedance spectroscopy of polynucleotide adsorption." Bioelectrochemistry 56, no. 1-2 (May 2002): 37–41. http://dx.doi.org/10.1016/s1567-5394(02)00019-1.

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22

Pajkossy, Tamás, and Rafal Jurczakowski. "Electrochemical impedance spectroscopy in interfacial studies." Current Opinion in Electrochemistry 1, no. 1 (February 2017): 53–58. http://dx.doi.org/10.1016/j.coelec.2017.01.006.

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23

Pébère, Nadine, and Vincent Vivier. "Electrochemical Impedance Spectroscopy (EIS 2019): Foreword." Electrochimica Acta 363 (December 2020): 137266. http://dx.doi.org/10.1016/j.electacta.2020.137266.

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24

Bruce, P. G., A. Lisowska-Oleksiak, P. Los, and C. A. Vincent. "Electrochemical impedance spectroscopy at an ultramicroelectrode." Journal of Electroanalytical Chemistry 367, no. 1-2 (March 1994): 279–83. http://dx.doi.org/10.1016/0022-0728(94)03303-x.

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25

Gassa, L. M., J. R. Vilche, M. Ebert, K. J�ttner, and W. J. Lorenz. "Electrochemical impedance spectroscopy on porous electrodes." Journal of Applied Electrochemistry 20, no. 4 (July 1990): 677–85. http://dx.doi.org/10.1007/bf01008882.

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26

Metrot, A., and A. Harrach. "Electrochemical impedance spectroscopy of intercalated electrodes." Electrochimica Acta 38, no. 14 (October 1993): 2005–9. http://dx.doi.org/10.1016/0013-4686(93)80332-t.

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27

Halpern, Jeffrey M., Emily Ziino, and Sabrina Marnoto. "Measurement Drift in Electrochemical Impedance Spectroscopy." ECS Meeting Abstracts MA2020-01, no. 45 (May 1, 2020): 2577. http://dx.doi.org/10.1149/ma2020-01452577mtgabs.

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28

ARIYOSHI, Kingo, Zyun SIROMA, Atsushi MINESHIGE, Mitsuhiro TAKENO, Tomokazu FUKUTSUKA, Takeshi ABE, and Satoshi UCHIDA. "Electrochemical Impedance Spectroscopy Part 1: Fundamentals." Electrochemistry 90, no. 10 (October 31, 2022): 102007. http://dx.doi.org/10.5796/electrochemistry.22-66071.

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ARIYOSHI, Kingo, Atsushi MINESHIGE, Mitsuhiro TAKENO, Tomokazu FUKUTSUKA, Takeshi ABE, Satoshi UCHIDA, and Zyun SIROMA. "Electrochemical Impedance Spectroscopy Part 2: Applications." Electrochemistry 90, no. 10 (October 31, 2022): 102008. http://dx.doi.org/10.5796/electrochemistry.22-66080.

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30

Ramón Nóvoa, X., and Carmen Pérez. "Electrochemical Impedance Spectroscopy (EIS 2016) Foreword." Electrochimica Acta 252 (October 2017): 55–57. http://dx.doi.org/10.1016/j.electacta.2017.08.138.

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Soares, C., J. A. Tenreiro Machado, António M. Lopes, E. Vieira, and C. Delerue-Matos. "Electrochemical impedance spectroscopy characterization of beverages." Food Chemistry 302 (January 2020): 125345. http://dx.doi.org/10.1016/j.foodchem.2019.125345.

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32

Liu, Hongqin, Gaëlle Piret, Brigitte Sieber, Jacky Laureyns, Pascal Roussel, Wenguo Xu, Rabah Boukherroub, and Sabine Szunerits. "Electrochemical impedance spectroscopy of ZnO nanostructures." Electrochemistry Communications 11, no. 5 (May 2009): 945–49. http://dx.doi.org/10.1016/j.elecom.2009.02.019.

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Mansfeld, F., and M. W. Kendig. "Electrochemical Impedance Spectroscopy of protective coatings." Materials and Corrosion/Werkstoffe und Korrosion 36, no. 11 (November 1985): 473–83. http://dx.doi.org/10.1002/maco.19850361102.

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Radhakrishnan, Rajeswaran, Michael Jahne, Shane Rogers, and Ian I. Suni. "Detection ofListeria Monocytogenesby Electrochemical Impedance Spectroscopy." Electroanalysis 25, no. 9 (August 27, 2013): 2231–37. http://dx.doi.org/10.1002/elan.201300140.

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35

Goffman, Vladimir G., Alexander V. Gorokhovsky, Anna D. Makarova, Elena V. Tretyachenko, Mariya A. Vikulova, Alexey M. Bainyashev, Elena V. Kolokolova, and Tatiana S. Teliukova. "Impedance spectroscopy of modified potassium titanates. I." Electrochemical Energetics 22, no. 2 (October 28, 2022): 61–69. http://dx.doi.org/10.18500/1608-4039-2022-22-2-61-69.

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The electrochemical and electrophysical properties of the protonated and modified with silver iodide potassium titanates, which can be applied in energy storage units, have been investigated by impedance spectroscopy. It has been shown that the dielectric losses at medium and high frequencies are weakly dependent on the polarizing voltage. It has also been established that transfer in modified potassium titanate can be made through potassium and silver ions. The equivalent scheme of the process has been proposed and the magnitudes of the Warburg impedances have been calculated.

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36

Wang, Hong Fang, and Jiang Chun Hu. "Research on Topological Structure of Rock Electrochemical Impedance Spectroscopy." Advanced Materials Research 243-249 (May 2011): 2920–24. http://dx.doi.org/10.4028/www.scientific.net/amr.243-249.2920.

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It is important of rock crack fine test for deep rock engineering. The high frequency part of Nyquist diagram of rock electrochemical impedance spectroscopy reflects the rock volume change characteristics, which can express the change information of rock internal cracks. With the topological theory, the topological characteristics of Nyquist diagram of sandstone, mudstone and granite are researched. The results show that the electrochemical impedance spectroscopy diagrams which come from the same size sample using the uniform test are isomorphism, and which can express using the same function. It shows the rock electrochemical process is regularity. At the same time, topological separation of rock electrochemical impedance spectroscopy diagram is researched. Fine change of rock crack can be detected with topological separation.

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Ribeiro, Josimar. "Electrochemical Impedance Spectroscopy: a tool on the electrochemical investigations." Revista Virtual de Química 12, no. 6 (2020): 1626–41. http://dx.doi.org/10.21577/1984-6835.20200123.

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Moradighadi, Negar, Srdjan Nesic, and Bernard Tribollet. "Identifying the dominant electrochemical reaction in electrochemical impedance spectroscopy." Electrochimica Acta 400 (December 2021): 139460. http://dx.doi.org/10.1016/j.electacta.2021.139460.

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Park, Su-Moon, and Jung-Suk Yoo. "Peer Reviewed: Electrochemical Impedance Spectroscopy for Better Electrochemical Measurements." Analytical Chemistry 75, no. 21 (November 2003): 455 A—461 A. http://dx.doi.org/10.1021/ac0313973.

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Wang, Yun, and Xiao Xi Hu. "The Influence of AC Perturbations on EIS Measurement of Copper/LDPE Composite with High Resistance." Advanced Materials Research 690-693 (May 2013): 355–58. http://dx.doi.org/10.4028/www.scientific.net/amr.690-693.355.

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Copper/LDPE composites are novel materials for intrauterine devices and they are the dispersion-type composites with high resistances. When the electrochemical impedance spectroscopy was used to evaluate the properties of materials with high resistances, in order to reduce the fluctuations in the measured data, the AC perturbation should be optimized. In this paper, the effects of the AC perturbations on the electrochemical impedance spectroscopy of copper/LDPE were discussed and the optimal AC perturbation was confirmed. The results have shown that the optimal perturbation of the electrochemical impedance spectroscopy of copper/LDPE composite, in the earlier period was 50mV, after achieving the saturation point the perturbation would change to 5mV.

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Sun, Qi Lei, Li Zhang, Jie Dong, and Lu Hua He. "Study on Electrochemical Behavior of Prestressed Reinforcement in Simulated Concrete Solution." Applied Mechanics and Materials 357-360 (August 2013): 917–20. http://dx.doi.org/10.4028/www.scientific.net/amm.357-360.917.

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Using electrochemical impedance spectroscop (EIS) and polarization curve technique, the electrochemical behavior of prestressed reinforcement under different stress levels was studied in simulated concrete solution. The results show that: As the stress increasing, the impedance spectroscopy changes significantly, the entire impedance spectroscopy shows an elongated semi-circular deformation, high-frequency capacitance arc radius corrosion decreases with the corrosion progress, in other words, the reaction resistance decreases, the corrosion rate of the sample increases. And when the galvanized steel is in 1064MPa stresss condition, corrosion current density reaches the maximum, is 9 times larger than that of none stress corrosions condition. Under the combined effects of the external stress and corrosive media, dislocation can be emitted, value-added and moves. When it reached a critical state, it would lead to the crack nucleation of Stress corrosion cracking (SCC).

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Hallemans, Noël, Dhammika Widanalage, Xinhua Zhu, Annick Hubin, and John Lataire. "Operando Electrochemical Impedance Spectroscopy and Its Application to Commercial Li-Ion Batteries." ECS Meeting Abstracts MA2023-01, no. 2 (August 28, 2023): 555. http://dx.doi.org/10.1149/ma2023-012555mtgabs.

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Electrochemical impedance spectroscopy (EIS) is a powerful non-invasive tool for characterising electrochemical systems. Applied to Li-ion batteries, EIS is shown to be an informative indicator for their state-of-health (SoH) [1,2,3]. However, EIS is limited by the constraints of linearity and stationarity, while Li-ion batteries inherently behave in a nonlinear and nonstationary way. Regarding linearity, the voltage over the electrodes is a nonlinear function of the current through the electrodes. Linearity is achieved by applying a small amplitude zero-mean current excitation around an operating point, such that the nonlinear function is quasi linear in this range. Regarding time-variation, the impedances of fully charged and fully discharged cells are different, the same for pristine and aged cells, or cells kept at room temperature and in freezing environments. For Li-ion batteries, this means that EIS experiments should be performed in steady-state when at a specific state-of-charge (SoC) and temperature. The impedance therefore depends on the operating point (temperature and SoC) and the constraints of linearity and stationarity are very restrictive. Lately, we have developed operando to reveal impedance data from measurements not satisfying linearity and stationarity [4,5]. This technique allows to measure the impedance of electrochemical systems along a time-varying trajectory, for instance, while charging or discharging Li-ion batteries [5,6]. For this purpose, a nonzero-mean odd random phase multisine current excitation is used, and the time-varying impedance along the trajectory is estimated from the spectrum of the voltage response. Moreover, nonlinear distortions in the measurements are detected and quantified, the noise level is estimated, and uncertainty bounds are enclosed on the time-varying impedance. For Li-ion batteries most time-variation happens at low frequencies. However, obtaining time-varying impedance data at low frequencies is a challenging problem. This on the one hand due to drift signals, for instance the increasing voltage while charging a battery, hiding the low frequency content, and on the other hand due to low-frequency noise. Operando EIS implements a drift signal suppression such that obtaining impedance data at low frequencies becomes attainable [4]. In this paper operando EIS measurements while charging and discharging commercial LG M50 Li-ion batteries are presented, demonstrating that the battery’s impedance while charging, discharging and resting are different from each other. Prospectives are given for utilizing operando EIS data for smart-charging and SOH prognosis applications. [1] Pastor-Fernández, C., Uddin, K., Chouchelamane, G.H., Widanage, W.D. and Marco, J., 2017. A comparison between electrochemical impedance spectroscopy and incremental capacity-differential voltage as Li-ion diagnostic techniques to identify and quantify the effects of degradation modes within battery management systems. Journal of Power Sources, 360, pp.301-318. [2] Zhang, Y., Tang, Q., Zhang, Y., Wang, J., Stimming, U. and Lee, A.A., 2020. Identifying degradation patterns of lithium ion batteries from impedance spectroscopy using machine learning. Nature communications, 11(1), pp.1-6. [3] Jones, P.K., Stimming, U. and Lee, A.A., 2022. Impedance-based forecasting of lithium-ion battery performance amid uneven usage. Nature communications, 13(1), pp.1-9. [4] Hallemans, N., Pintelon, R., Zhu, X., Collet, T., Havigh, M.D., Wouters, B., Revilla, R.I., Claessens, R., Ramharter, K., Hubin, A. and Lataire, J., 2022. Trend Removal in Measurements of Best Linear Time-Varying Approximations—With Application to Operando Electrochemical Impedance Spectroscopy. IEEE Transactions on Instrumentation and Measurement, 71, pp.1-11. [5] Hallemans, N., Widanage, W.D., Zhu, X., Moharana, S., Rashid, M., Hubin, A. and Lataire, J., 2022. Operando electrochemical impedance spectroscopy and its application to commercial Li-ion batteries. Journal of Power Sources, 547, p.232005. [6] Zhu, X., Hallemans, N., Wouters, B., Claessens, R., Lataire, J. and Hubin, A., 2022. Operando odd random phase electrochemical impedance spectroscopy as a promising tool for monitoring lithium-ion batteries during fast charging. Journal of Power Sources, 544, p.231852.

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Weinstein, L., W. Yourey, J. Gural, and G. G. Amatucci. "Electrochemical Impedance Spectroscopy of Electrochemically Self-Assembled Lithium–Iodine Batteries." Journal of The Electrochemical Society 155, no. 8 (2008): A590. http://dx.doi.org/10.1149/1.2940323.

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Marmisollé, Waldemar A., M. Inés Florit, and Dionisio Posadas. "Electrochemically induced ageing of polyaniline. An electrochemical impedance spectroscopy study." Journal of Electroanalytical Chemistry 673 (May 2012): 65–71. http://dx.doi.org/10.1016/j.jelechem.2012.03.016.

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Chou, Jung-Chuan, Chin-Hui Huang, Yi-Hung Liao, Yu-Jen Lin, Chia-Ming Chu, and Yu-Hsun Nien. "Analysis of Different Series-Parallel Connection Modules for Dye-Sensitized Solar Cell by Electrochemical Impedance Spectroscopy." International Journal of Photoenergy 2016 (2016): 1–8. http://dx.doi.org/10.1155/2016/6595639.

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The internal impedances of different dye-sensitized solar cell (DSSC) models were analyzed by electrochemical impedance spectrometer (EIS) with an equivalent circuit model. The Nyquist plot was built to simulate the redox reaction of internal device at the heterojunction. It was useful to analyze the component structure and promote photovoltaic conversion efficiency of DSSC. The impedance of DSSC was investigated and the externally connected module assembly was constructed utilizing single cells on the scaled-up module. According to the experiment results, the impedance was increased with increasing cells connected in series. On the contrary, the impedance was decreased with increasing cells connected in parallel.

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Zhang, Xiu Zhi, and Yuan Long Du. "Effects of Immersion Time on the Electrochemical Impedance Spectroscopy Model of Epoxy Coating Modified by Nano-Sized Titanium." Advanced Materials Research 139-141 (October 2010): 43–46. http://dx.doi.org/10.4028/www.scientific.net/amr.139-141.43.

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In this paper, the effects of immersion time on the electrochemical impedance spectroscopy model of nano-sized titanium modified epoxy coating immersed in 3.5(wt.%) sodilum chloride solution has been studied using electrochemical impedance spectroscopy(EIS). Through the analysis of the spectra of the coating at different immersion times, the results showed that the spectrum was different at the different immersion times. Therefore, the equivalent electrical circuit was varied with the increasing immersion time and there were the characteristics of the powder in the equivalent electrical circuits (electrochemical impedance spectroscopy model). By the study on the evlolution of impedance model in the given system, it was found that the nano-sized powder played an important part during the electrolyte diffusing to the surface of the substrate and the electrolyte reacting with the substrate

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Liu, Tao, Meng Li, Yongjie Wang, Yimin Fang, and Wei Wang. "Electrochemical impedance spectroscopy of single Au nanorods." Chemical Science 9, no. 19 (2018): 4424–29. http://dx.doi.org/10.1039/c8sc00983j.

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Rueda Rueda, Manuela, and Francisco Prieto Dapena. "Application of electrochemical impedance spectroscopy to the study of surface processes." Collection of Czechoslovak Chemical Communications 76, no. 12 (2011): 1825–54. http://dx.doi.org/10.1135/cccc2011118.

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The application of Electrochemical Impedance Spectroscopy to the study of surface electrode processes is reviewed. The impedance expressions and the physical meaning of the parameters included in them are shown for three surface processes: adsorption kinetics, diffusion towards partially blocked electrodes and surface confined redox reactions. The models are applied to selected examples, showing the capability of Electrochemical Impedance Spectroscopy to obtain fundamental kinetic information of these processes. A review with 83 references.

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Pang, Tao-Tao, Li-Ming Du, Hai-Long Liu, and Yun-Long Fu. "Supramolecular p-sulfonated calix[4,6,8]arene for tryptophan detection." Canadian Journal of Chemistry 92, no. 12 (December 2014): 1139–44. http://dx.doi.org/10.1139/cjc-2014-0150.

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Numerous techniques have focused on the ability of p-sulfonated calix[n]arene to form complexes with tryptophan. Scanning electron microscopy and Fourier transform infrared spectroscopy were utilized to study the organization and molecular structure of different layers of the electrode surface. Scanning electron microscopy results showed that SC4A displayed a cubic structure whereas SC6A and SC8A displayed dendrite structures. The electrochemical properties and potential complex formation between SCnA and tryptophan were characterized by cyclic voltammetry and electrochemical impedance spectroscopy. Cyclic voltammetry experiments showed that the gold electrode was successfully functionalized by self-assembled cysteamine and SC4A. Electrochemical impedance spectroscopy results showed the observation of the tryptophan–SCnA interaction and indicated that SC4A had the highest sensitivity to tryptophan and allowed 2.04 μg L−1 tryptophan to be detected. Electrochemical impedance spectroscopy analysis and molecular modeling calculation confirmed that SC4A has higher tryptophan sensitivity than SC6A and SC8A.

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Anseth, Ronnie, Nils-Olav Skeie, and Magne Waskaas. "Preliminary studies on monitoring fouling layers on a charged electrode using Electrical Impedance Spectroscopy." tm - Technisches Messen 85, no. 2 (February 23, 2018): 137–46. http://dx.doi.org/10.1515/teme-2017-0129.

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Abstract The objective of the study described in this paper was to examine whether fouling on an electrode surface can be monitored through impedance measurements using a modified Electrochemical Impedance Spectroscopy technique. The attempt was to evaluate a measurement system that could monitor fouling, within an electrochemical cell, by using EIS to find one single frequency to measure the impedance magnitude. An electrical potential difference was applied to the electrochemical cell to generate an electrical field to accelerate the deposition layer growth on one electrode. Experimental results show that the magnitude of the electrochemical cell impedance was in the range of 110 Ω over the duration of the experiment, which lasted one week. A measurable change in the impedance magnitude was detected when a deposition layer, caused by fouling, was present on one of the electrodes. The measurement frequency was selected specifically for the purpose to increase the deposition layer influence on the measured impedance magnitude, which was achieved by selecting a frequency that kept the capacitive reactance as low as possible. Results indicate that a measurement system, using one frequency, is capable of monitoring the deposition layer by measuring the magnitude of the electrochemical cell impedance.

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