Academic literature on the topic 'Electrochemical gating'

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Journal articles on the topic "Electrochemical gating"

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Ahonen, Päivi, Virginia Ruiz, Kyösti Kontturi, Peter Liljeroth, and Bernadette M. Quinn. "Electrochemical Gating in Scanning Electrochemical Microscopy." Journal of Physical Chemistry C 112, no. 7 (February 2008): 2724–28. http://dx.doi.org/10.1021/jp0776513.

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Liu, Yayuan, Chun-Man Chow, Katherine R. Phillips, Miao Wang, Sahag Voskian, and T. Alan Hatton. "Electrochemically mediated gating membrane with dynamically controllable gas transport." Science Advances 6, no. 42 (October 2020): eabc1741. http://dx.doi.org/10.1126/sciadv.abc1741.

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The regulation of mass transfer across membranes is central to a wide spectrum of applications. Despite numerous examples of stimuli-responsive membranes for liquid-phase species, this goal remains elusive for gaseous molecules. We describe a previously unexplored gas gating mechanism driven by reversible electrochemical metal deposition/dissolution on a conductive membrane, which can continuously modulate the interfacial gas permeability over two orders of magnitude with high efficiency and short response time. The gating mechanism involves neither moving parts nor dead volume and can therefore enable various engineering processes. An electrochemically mediated carbon dioxide concentrator demonstrates proof of concept by integrating the gating membranes with redox-active sorbents, where gating effectively prevented the cross-talk between feed and product gas streams for high-efficiency, directional carbon dioxide pumping. We anticipate our concept of dynamically regulating transport at gas-liquid interfaces to broadly inspire systems in fields of gas separation, miniaturized devices, multiphase reactors, and beyond.
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Mabeck, Jeffrey T., John A. DeFranco, Daniel A. Bernards, George G. Malliaras, Sandrine Hocdé, and Christopher J. Chase. "Microfluidic gating of an organic electrochemical transistor." Applied Physics Letters 87, no. 1 (July 4, 2005): 013503. http://dx.doi.org/10.1063/1.1991979.

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Kay, Nicola J., Simon J. Higgins, Jan O. Jeppesen, Edmund Leary, Jess Lycoops, Jens Ulstrup, and Richard J. Nichols. "Single-Molecule Electrochemical Gating in Ionic Liquids." Journal of the American Chemical Society 134, no. 40 (September 28, 2012): 16817–26. http://dx.doi.org/10.1021/ja307407e.

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Leighton, Chris, Turan Birol, and Jeff Walter. "What controls electrostatic vs electrochemical response in electrolyte-gated materials? A perspective on critical materials factors." APL Materials 10, no. 4 (April 1, 2022): 040901. http://dx.doi.org/10.1063/5.0087396.

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Electrolyte-gate transistors are a powerful platform for control of material properties, spanning semiconducting behavior, insulator-metal transitions, superconductivity, magnetism, optical properties, etc. When applied to magnetic materials, for example, electrolyte-gate devices are promising for magnetoionics, wherein voltage-driven ionic motion enables low-power control of magnetic order and properties. The mechanisms of electrolyte gating with ionic liquids and gels vary from predominantly electrostatic to entirely electrochemical, however, sometimes even in single material families, for reasons that remain unclear. In this Perspective, we compare literature ionic liquid and ion gel gating data on two rather different material classes—perovskite oxides and pyrite-structure sulfides—seeking to understand which material factors dictate the electrostatic vs electrochemical gate response. From these comparisons, we argue that the ambient-temperature anion vacancy diffusion coefficient ( not the vacancy formation energy) is a critical factor controlling electrostatic vs electrochemical mechanisms in electrolyte gating of these materials. We, in fact, suggest that the diffusivity of lowest-formation-energy defects may often dictate the electrostatic vs electrochemical response in electrolyte-gated inorganic materials, thereby advancing a concrete hypothesis for further exploration in a broader range of materials.
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Baghernejad, Masoud, David Zsolt Manrique, Chen Li, Thomas Pope, Ulmas Zhumaev, Ilya Pobelov, Pavel Moreno-García, et al. "Highly-effective gating of single-molecule junctions: an electrochemical approach." Chem. Commun. 50, no. 100 (2014): 15975–78. http://dx.doi.org/10.1039/c4cc06519k.

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Huang, Cancan, Alexander V. Rudnev, Wenjing Hong, and Thomas Wandlowski. "Break junction under electrochemical gating: testbed for single-molecule electronics." Chemical Society Reviews 44, no. 4 (2015): 889–901. http://dx.doi.org/10.1039/c4cs00242c.

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Reuter, H. "Modulation of Ion Channels by Phosphorylation and Second Messengers." Physiology 2, no. 5 (October 1, 1987): 168–71. http://dx.doi.org/10.1152/physiologyonline.1987.2.5.168.

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Ion channels are integral membrane proteins that regulate ion fluxes through the membrane;when channels are open, ions can move down their respective electrochemical gradients. The transitions between open-closed conformations, called gating, are regulated either by a change in membrane potential or by binding of ligands. Channel gating as well as channel availability can be modulated by biochemical reactions, such as phosporylation of the channel protein.
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Aragonès, Albert C., and Katrin F. Domke. "Electrochemical gating enhances nearfield trapping of single metalloprotein junctions." Journal of Materials Chemistry C 9, no. 35 (2021): 11698–706. http://dx.doi.org/10.1039/d1tc01535d.

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Metalloprotein junctions are used as model systems in the field of molecular bioelectronics to mimic electronic circuits. The junction lifetime increase achieved with electrochemical nearfield trapping enables thorough junction characterisation.
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Smieszek, Nicholas, Siddharth Joshi, and Vidhya Chakrapani. "Phase Transitions in Correlated Oxides Modulated through Electrochemical Gating." ECS Meeting Abstracts MA2021-01, no. 36 (May 30, 2021): 2058. http://dx.doi.org/10.1149/ma2021-01362058mtgabs.

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Dissertations / Theses on the topic "Electrochemical gating"

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Nasr, Babak [Verfasser], Horst [Akademischer Betreuer] Hahn, and Heinz von [Akademischer Betreuer] Seggern. "Electrochemical Gating of Oxide Nanowire Transistors at Low Operating Voltage / Babak Nasr. Betreuer: Horst Hahn ; Heinz von Seggern." Darmstadt : Universitäts- und Landesbibliothek Darmstadt, 2013. http://d-nb.info/1106454510/34.

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Nasr, Babak. "Electrochemical Gating of Oxide Nanowire Transistors at Low Operating Voltage." Phd thesis, 2013. http://tuprints.ulb.tu-darmstadt.de/3383/7/010513_Nasr_Thesis.pdf.

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Single-crystal, one-dimensional (1-D), metal-oxide nanostructures are well known for their excellent electronic transport properties. Moreover, metal oxide-nanowire field-effect transistors (FETs) offer both high optical transparency and large mechanical conformability which are essential for flexible and transparent display applications. While the “on-currents” achieved with nanowire channel transistors are already sufficient to drive active-matrix organic light-emitting diode (AMOLED) displays; it is shown here in addition that application of electrochemical-gating (EG) to nanowire electronics reduces the operation voltage to ≤2 V. This opens up new possibilities for the realization of flexible, portable, transparent displays that can be powered by thin film batteries. Electrolyte gated field-effect transistors are fabricated with single crystalline metal oxide nanowires such as ZnO and SnO2 as the channel and a composite solid polymer electrolyte (CSPE) is used as dielectric gating material. Excellent transistor performance and a very low-voltage operation (≤ 2 V) have been demonstrated. Practical use of such electrolyte-gated field-effect transistor (EG FET) devices is validated by their long-term stability in air. Moreover, due to the good conductivity (≈10−2 S/cm) of the CSPE, sufficiently high switching speed of such EG FETs is attainable; a cut-off frequency in excess of 100 kHz is measured for in-plane FETs. Furthermore, thermal stability of the FETs is systematically examined up to 180 °C. Unchanged transistor characteristics are obtained up to 70 °C, short exposure at 110 °C is found acceptable, making such devices compatible with organic photovoltaics or various biomedical applications. Additionally, the solid polymer electrolyte developed in this study has great potential for future device fabrication using all-solution processed and high throughput techniques.
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Ting, Ta-Cheng, and 丁大成. "Tuning the Single-molecule Conductance of Metal String Complexes by Electrochemical Gating." Thesis, 2015. http://ndltd.ncl.edu.tw/handle/39214636188149388162.

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碩士
國立臺灣大學
物理研究所
103
The single-molecule conductance is affected by the electron transport through the electrode–molecule–electrode junctions. One of the most important factors is the energy-level difference between the electrode Fermi level and the frontier molecular orbitals. This energy difference can be controlled by electrochemical gating, which means pushing the potential of the working electrode toward the redox potential of the molecule. The compounds here are extended metal-atom chains (EMACs), which have well-defined one-electron oxidation reactions, to study the effect of energy-level alignment on the single-molecule conductance. For the scans of electrochemical potential, the single-molecule conductance is measured at a fixed bias and monitored as a function of electrochemical potential. On the other hand, single-molecule i–V curves are obtained at fixed electrochemical potentials. Transition voltages derived from the corresponding Fowler-Nordheim plots are well correlated with the energy barrier heights. Larger conductance and smaller energy barrier heights were found when electrochemical potential was just about the redox potential, indicating the effect of energy-level alignment.
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Ho, Ching-Hwa, and 賀慶華. "Tuning the Tunneling Efficiency at Molecule-Electrode Contact and Molecule Moiety by Electrochemical Gating." Thesis, 2016. http://ndltd.ncl.edu.tw/handle/55559421318657372110.

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碩士
國立臺灣大學
化學研究所
104
Transport efficiency plays an important role to single-molecule conductance as the electrons pass through an electrode−molecule−electrode junction. One of the important factors is the degree of energy level alignment between Fermi levels of electrodes and molecular frontier orbitals. Scanning tunneling microscope incorporated with electrochemical control was implemented to manipulate tip-substrate the gap suitable for single molecule conductance measurements and studies of energy level alignment. The conductance of alkanediamines and oligo(phenyleneethynylene)s increases as the electrochemical potential of the electrodes moves positively (i.e., the Fermi level of electrodes approaches the HOMO of molecules), suggesting the dominant transport pathway via HOMO for both molecule series. Via the comparison in the change of the contact conductance with that of the tunneling decay constant under different working potentials, it is concluded that the conductance change of molecules primarily comes from the contact conductance. Simmons model and Newns-Anderson model were both applied to derive the behaviors of contact conductance and tunneling decay constant associated with Fermi levels of electrodes. In Simmons model, the contact conductance and the tunneling decay constant are related with the Fermi level in the power of second order and the square root respectively. On the other hand, results by Newns-Anderson model show that the contact conductance and the tunneling decay constant are sensitive to Fermi level in the power of fourth order and in logarithm relation, respectively. Both models predict the contact conductance is more sensitive to the energy level alignment, consistent with the experimental results.
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Book chapters on the topic "Electrochemical gating"

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Blank, Martin. "An Electrochemical Perspective on Excitable Membranes, Channels and Gating." In Bioelectrochemistry II, 431–56. Boston, MA: Springer US, 1987. http://dx.doi.org/10.1007/978-1-4613-0951-2_17.

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Conference papers on the topic "Electrochemical gating"

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Shim, Moonsub. "Electrochemical gating and molecular adsorption on carbon nanotubes." In Optics & Photonics 2005, edited by Clemens Burda and Randy J. Ellingson. SPIE, 2005. http://dx.doi.org/10.1117/12.612820.

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George, Lijin, and Manu Shaji. "Electrochemical gating of CVD graphene–ZnO based tansistor." In ADVANCED MATERIALS AND RADIATION PHYSICS (AMRP-2020): 5th National e-Conference on Advanced Materials and Radiation Physics. AIP Publishing, 2021. http://dx.doi.org/10.1063/5.0052570.

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Gladush, Yuriy, Michael Staniforth, James Lloyd-Hughes, Albert G. Nasibulin, Aram Mkrtchyan, Daria Kopylova, Aleksey Ivanenko, et al. "Control of Nonlinear Optical Properties of the Carbon Nanotubes Saturable Absorber with Electrochemical Gating." In 2019 Conference on Lasers and Electro-Optics Europe & European Quantum Electronics Conference (CLEO/Europe-EQEC). IEEE, 2019. http://dx.doi.org/10.1109/cleoe-eqec.2019.8872519.

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Jayant, Krishna, Kshitij Auluck, Sharlin Anwar, and Edwin C. Kan. "Electrochemical gating on CMOS: Interplay of field, acidity and salinity on an electrolyte-insulator interface." In 2013 Transducers & Eurosensors XXVII: The 17th International Conference on Solid-State Sensors, Actuators and Microsystems (TRANSDUCERS & EUROSENSORS XXVII). IEEE, 2013. http://dx.doi.org/10.1109/transducers.2013.6627217.

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Bingham, Bruce C., Atanas A. Atanasov, and John P. Parmigiani. "The Design and Fabrication of an Electrochemical Machining Test Apparatus." In ASME 2013 International Mechanical Engineering Congress and Exposition. American Society of Mechanical Engineers, 2013. http://dx.doi.org/10.1115/imece2013-66299.

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The removal of residual casting material from gating has traditionally been performed by abrasive grinding techniques. However, high amounts of belt wear can occur when working with high strength alloys, especially those typically seen in the aerospace industry. An alternative machining process called electrochemical machining (ECM) uses electrolysis to precisely remove material at high rates. ECM has many advantages over conventional grinding: no tool wear, no induced mechanical or thermal stresses, and high removal rates independent of material hardness or strength. The industrial application of ECM to residual casting material removal can potentially realize large cost savings and decreased component processing time by eliminating belt wear and increasing material removal rates. The approach taken in this work is the design and fabrication of a laboratory apparatus for the purpose of testing the ECM of casting material. Commercial ECM machines, while more powerful, can be excessively large and cost prohibitive when performing an initial feasibility study. Many times these commercial machines are calibrated to mass produce a specific part, and do not have the level of variability desired for laboratory experimentation. The test apparatus presented provides a robust and relatively low cost method of investigating the applicability of ECM to this purpose. The device is comprised of an electrolyte filtration and delivery system, a stable machining enclosure, and a single axis computer controlled tool. The ECM variables that can be adjusted include electrolyte temperature, mass flow rate, applied voltage, tool feed rate, and electrode gap. Process data from these variables is collected via multiple sensors in the machine and provides real-time feedback to users. A universal tool connection and workpiece fixture allows for different experimental setups to be easily tested. From experimentation with this test apparatus, it will be possible to identify optimum methods for the ECM of these residual casting artifacts.
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