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Journal articles on the topic 'Diphenylcarbene'

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Published: 25 July 2024

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1

Griller, D., M. Majewski, W. G. McGimpsey, A. S. Nazran, and J. C. Scaiano. "Reaction of diphenylcarbene with diphenyldiazomethane." Journal of Organic Chemistry 53, no. 7 (April 1988): 1550–53. http://dx.doi.org/10.1021/jo00242a040.

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2

Bally, Thomas, Stephan Matzinger, Leo Truttman, Matthew S. Platz, Atnaf Admasu, Fabian Gerson, Anton Arnold, and Reto Schmidlin. "Diphenylcarbene cation: electronic and molecular structure." Journal of the American Chemical Society 115, no. 15 (July 1993): 7007–8. http://dx.doi.org/10.1021/ja00068a082.

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3

Chateauneuf, J. E. "Picosecond spectroscopic investigations of diphenylcarbene protonation." Research on Chemical Intermediates 20, no. 2 (January 1994): 249–63. http://dx.doi.org/10.1163/156856794x00225.

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4

TOMIOKA, Hideo, and Katsuyuki HIRAI. "Generation and Characterization of Persistent Triplet Diphenylcarbene." Journal of Synthetic Organic Chemistry, Japan 54, no. 9 (1996): 783–93. http://dx.doi.org/10.5059/yukigoseikyokaishi.54.783.

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5

Savino, T. G., V. P. Senthilnathan, and M. S. Platz. "Contrasting chemistry of diphenylcarbene and fluorenylidene in cyclohexane." Tetrahedron 42, no. 8 (January 1986): 2167–80. http://dx.doi.org/10.1016/s0040-4020(01)90595-2.

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6

Dannenberg, J. J., Laura K. Vinson, M. Moreno, and J. Bertran. "A molecular orbital study of phenylcarbene and diphenylcarbene." Journal of Organic Chemistry 54, no. 23 (November 1989): 5487–91. http://dx.doi.org/10.1021/jo00284a020.

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7

Henkel, Stefan, Paolo Costa, Linda Klute, Pandian Sokkar, Miguel Fernandez-Oliva, Walter Thiel, Elsa Sanchez-Garcia, and Wolfram Sander. "Switching the Spin State of Diphenylcarbene via Halogen Bonding." Journal of the American Chemical Society 138, no. 5 (February 2, 2016): 1689–97. http://dx.doi.org/10.1021/jacs.5b12726.

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8

Haider, K. W., Matthew S. Platz, Alain Despres, Violaine Lejeune, and Eva Migirdicyan. "Triplet-triplet fluorescence and spin polarization: diphenylcarbene and dibenzocycloheptadienylidene." Journal of Physical Chemistry 94, no. 1 (January 1990): 142–47. http://dx.doi.org/10.1021/j100364a021.

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9

Tanaka, Kazuyoshi, Tomonari Takeuchi, Kazunari Yoshizawa, Michio Toriumi, and Tokio Yamabe. "Theoretical study on ferromagnetic interaction in stacked diphenylcarbene polymer." Synthetic Metals 44, no. 1 (July 1991): 1–8. http://dx.doi.org/10.1016/0379-6779(91)91852-2.

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10

TOMIOKA, H., and K. HIRAI. "ChemInform Abstract: Generation and Characterization of Persistent Triplet Diphenylcarbene." ChemInform 28, no. 10 (August 4, 2010): no. http://dx.doi.org/10.1002/chin.199710243.

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11

Chateauneuf, John E. "Absolute Rate Constant for the Reaction of Diphenylcarbene with C60." Journal of the American Chemical Society 117, no. 9 (March 1995): 2677–78. http://dx.doi.org/10.1021/ja00114a044.

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12

Turro, Nicholas J., Yuan Cha, and Ian R. Gould. "Temperature dependence of the reactions of singlet and triplet diphenylcarbene." Tetrahedron Letters 26, no. 48 (January 1985): 5951–54. http://dx.doi.org/10.1016/s0040-4039(00)98269-8.

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13

Zayas, José, and Matthew S. Platz. "The effect of oxygen on the matrix chemistry of diphenylcarbene." Tetrahedron Letters 26, no. 24 (January 1985): 2853–56. http://dx.doi.org/10.1016/s0040-4039(00)98854-3.

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14

McDonald, Richard N., and Wei Yi Gung. "Generation, thermodynamics, and chemistry of the diphenylcarbene anion radical (Ph2C.cntdot.-)." Journal of the American Chemical Society 109, no. 24 (November 1987): 7328–34. http://dx.doi.org/10.1021/ja00258a015.

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15

Horn, Keith A., and Bruce D. Allison. "The absorption spectrum and reactivity of excited triplet state diphenylcarbene." Chemical Physics Letters 116, no. 2-3 (May 1985): 114–18. http://dx.doi.org/10.1016/0009-2614(85)80137-8.

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16

Langan, J. G., E. V. Sitzmann, and K. B. Eisenthal. "Inverse deuterium isotope effect in the intersystem crossing of diphenylcarbene." Chemical Physics Letters 124, no. 1 (February 1986): 59–62. http://dx.doi.org/10.1016/0009-2614(86)85013-8.

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17

Régimbald-Krnel, Michèle J., and Curt Wentrup. "Laser-Induced Carbene–Carbene Rearrangement in Solution: The Diphenylcarbene–Fluorene Rearrangement." Journal of Organic Chemistry 78, no. 17 (August 13, 2013): 8789–95. http://dx.doi.org/10.1021/jo401607m.

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18

McGarry, P. F., L. J. Johnston, and J. C. Scaiano. "Kinetics and mechanism of the reaction of diphenylcarbene with [1.1.1]propellane." Journal of the American Chemical Society 111, no. 10 (May 1989): 3750–51. http://dx.doi.org/10.1021/ja00192a043.

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19

Knorr, Johannes, Pandian Sokkar, Paolo Costa, Wolfram Sander, Elsa Sanchez-Garcia, and Patrick Nuernberger. "How Protic Solvents Determine the Reaction Mechanisms of Diphenylcarbene in Solution." Journal of Organic Chemistry 84, no. 18 (July 25, 2019): 11450–57. http://dx.doi.org/10.1021/acs.joc.9b01228.

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20

Chateauneuf, J. E. "Exploratory laser flash photolysis investigations of diphenylcarbene reactivity in supercritical fluids." Research on Chemical Intermediates 20, no. 2 (January 1994): 159–73. http://dx.doi.org/10.1163/156856794x00171.

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21

MAERKL, G., K. HOHENWARTER, M. L. ZIEGLER, and B. NUBER. "ChemInform Abstract: Reaction of λ3-Phosphinines with Diphenylcarbene Generated from Diphenyldiazomethane." ChemInform 23, no. 9 (August 22, 2010): no. http://dx.doi.org/10.1002/chin.199209258.

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22

Hirai, Katsuyuki, Kana Bessho, Kosaku Tsujita, and Toshikazu Kitagawa. "Diphenylcarbene Protected by Four ortho-Iodine Groups: An Unusually Persistent Triplet Carbene." Molecules 21, no. 11 (November 15, 2016): 1545. http://dx.doi.org/10.3390/molecules21111545.

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23

Hirai, Katsuyuki, Takashi Iikubo, and Hideo Tomioka. "Effects ofpara-Phenyl Group on the Reactivities of Sterically Congested Triplet Diphenylcarbene." Chemistry Letters 31, no. 12 (December 2002): 1226–27. http://dx.doi.org/10.1246/cl.2002.1226.

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24

Nazran, A. S., and David Griller. "Reaction of diphenylcarbene with amines and the question of triplet-singlet equilibration." Journal of the American Chemical Society 107, no. 16 (August 1985): 4613–15. http://dx.doi.org/10.1021/ja00302a002.

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25

Murata, Shigeru, Tadashi Sugawara, and Hiizu Iwamura. "Magnetic interaction of two diphenylcarbene units linked with an ethylenic double bond." Journal of the American Chemical Society 109, no. 4 (February 1987): 1266–67. http://dx.doi.org/10.1021/ja00238a058.

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26

Jones, Michelle B., and Matthew S. Platz. "The kinetics of the ylid-forming reaction between triplet diphenylcarbene and pyridine." Tetrahedron Letters 31, no. 7 (January 1990): 953–56. http://dx.doi.org/10.1016/s0040-4039(00)94401-0.

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27

Bleuel, Elke, Olaf Gevert, Matthias Laubender, and Helmut Werner. "Synthesis, Molecular Structure, and Reactivity of Indenylrhodium Complexes Containing Diphenylcarbene as Ligand†." Organometallics 19, no. 16 (August 2000): 3109–14. http://dx.doi.org/10.1021/om000188v.

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28

Ge, Yang, Yunxiang Lu, Zhijian Xu, and Honglai Liu. "Controlling the spin state of diphenylcarbene via halogen bonding: A theoretical study." International Journal of Quantum Chemistry 118, no. 15 (March 1, 2018): e25616. http://dx.doi.org/10.1002/qua.25616.

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29

Costa, Paolo, and Wolfram Sander. "1-Phenyl-1,2,4,6-cycloheptatetraene: the missing intermediate of the diphenylcarbene to fluorenerearrangement." Journal of Physical Organic Chemistry 28, no. 2 (October 9, 2014): 71–74. http://dx.doi.org/10.1002/poc.3355.

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30

Costa, Paolo, and Wolfram Sander. "Hydrogen Bonding Switches the Spin State of Diphenylcarbene from Triplet to Singlet." Angewandte Chemie 126, no. 20 (April 2, 2014): 5222–25. http://dx.doi.org/10.1002/ange.201400176.

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31

Jones, Michelle B., Vincent M. Maloney, and Matthew S. Platz. "Reaction of phenylchlorocarbene and diphenylcarbene with the carbon-chlorine bond: kinetics and mechanisms." Journal of the American Chemical Society 114, no. 6 (March 1992): 2163–69. http://dx.doi.org/10.1021/ja00032a034.

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32

Izuoka, Akira, Shigeru Murata, Tadashi Sugawara, and Hiizu Iwamura. "Ferro- and antiferromagnetic interaction between two diphenylcarbene units incorporated in the [2.2]paracyclophane skeleton." Journal of the American Chemical Society 107, no. 6 (March 1985): 1786–87. http://dx.doi.org/10.1021/ja00292a068.

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33

Barcus, Robert L., Matthew S. Platz, and J. C. Scaiano. "Arrhenius parameters for hydrogen and chlorine atom abstraction reactions of triplet diphenylcarbene and dibenzocycloheptadienylidene." Journal of Physical Chemistry 91, no. 3 (January 1987): 695–99. http://dx.doi.org/10.1021/j100287a040.

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34

Peon, Jorge, Dmitrii Polshakov, and Bern Kohler. "Solvent Reorganization Controls the Rate of Proton Transfer from Neat Alcohol Solvents to Singlet Diphenylcarbene." Journal of the American Chemical Society 124, no. 22 (June 2002): 6428–38. http://dx.doi.org/10.1021/ja017485r.

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35

Bleuel, Elke, and Helmut Werner. "Diphenylcarbene rhodium complexes: of the halfsandwich type with (η5-C5H4SiMe3)Rh as a molecular unit." Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry 2, no. 5-6 (May 1999): 341–49. http://dx.doi.org/10.1016/s1387-1609(00)88544-8.

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36

JONES, M. B., V. M. MALONEY, and M. S. PLATZ. "ChemInform Abstract: Reaction of Phenylchlorocarbene and Diphenylcarbene with the Carbon- Chlorine Bond: Kinetics and Mechanisms." ChemInform 23, no. 27 (August 21, 2010): no. http://dx.doi.org/10.1002/chin.199227115.

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37

Eliason, Robert. "Article." Canadian Journal of Chemistry 77, no. 5-6 (June 1, 1999): 744–51. http://dx.doi.org/10.1139/v99-039.

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Abstract:

Acid-catalyzed decomposition of diazodiphenylmethane (DDM) has been studied in DMSO containing varying amounts of water. The reaction was found to be first-order in DDM and first-order in acid. The Brønsted plot for a series of carboxylic acids is curved with the H+ point falling below the curve defined by the carboxylic acids. In near-anhydrous DMSO, kinetic hydrogen isotope effects (KIEs) are 1.7 and 1.6 for acetic acid and chloroacetic acid, respectively. The chloroacetic acid KIE increases with increasing water concentration, rising to 2.9 at 3.6 M water. As a function of [H2O], kHA for chloroacetic acid shows a sharply defined minimum occurring at 1 M water. This behavior and the water effect on KIE suggest that the carboxylic acid-catalyzed reactions in near-anhydrous DMSO do not use the ASE-2 mechanism attributed to the reaction of DDM in hydroxylic solvents. A mechanism, leading to an azoalkane, is suggested. Either directly or indirectly, this may lead to diphenylcarbene, which would account for the observed products: benzophenone, benzhydrol, and benzhydryl esters. For the H+ catalyzed decomposition of DDM in near-anhydrous DMSO, benzophenone is not found among the products, and we suggest that this reaction does not undergo a change in mechanism and continues to use the ASE-2 mechanism.Key words: decomposition mechanism, kinetics, solvent effect, reaction with carboxylic acids.

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38

Chateauneuf, John E. "Absolute Rate Constant for the Reaction of Diphenylcarbene with C60. [Erratum to document cited in CA122:238990]." Journal of the American Chemical Society 117, no. 28 (July 1995): 7582. http://dx.doi.org/10.1021/ja00133a049.

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39

Savino, T. G., N. Soundararajan, and M. S. Platz. "Confirmation of a large kinetic isotope effect in the low-temperature matrix reaction of diphenylcarbene with toluene." Journal of Physical Chemistry 90, no. 5 (February 1986): 919–23. http://dx.doi.org/10.1021/j100277a042.

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40

Costa, Paolo, Joel Mieres-Perez, Nesli Özkan, and Wolfram Sander. "Activation of the B−F Bond by Diphenylcarbene: A Reversible 1,2-Fluorine Migration between Boron and Carbon." Angewandte Chemie International Edition 56, no. 7 (January 10, 2017): 1760–64. http://dx.doi.org/10.1002/anie.201610179.

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41

Costa, Paolo, Joel Mieres-Perez, Nesli Özkan, and Wolfram Sander. "Activation of the B−F Bond by Diphenylcarbene: A Reversible 1,2-Fluorine Migration between Boron and Carbon." Angewandte Chemie 129, no. 7 (January 10, 2017): 1786–90. http://dx.doi.org/10.1002/ange.201610179.

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42

DESPRES, A., V. LEJEUNE, E. MIGIRDICYAN, A. ADMASU, M. S. PLATZ, G. BERTHIER, O. PARISEL, J. P. FLAMENT, I. BARALDI, and F. MOMICCHIOLI. "ChemInform Abstract: Electronic Structure and Spectra of Diphenylcarbene Conformers in Their Ground State and Lower Excited States." ChemInform 25, no. 14 (August 19, 2010): no. http://dx.doi.org/10.1002/chin.199414044.

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43

Despres, A., V. Lejeune, E. Migirdicyan, A. Admasu, M. S. Platz, G. Berthier, O. Parisel, J. P. Flament, I. Baraldi, and F. Momicchioli. "Study of the electronic structure and spectra of diphenylcarbene conformers in their ground state and lower excited states." Journal of Physical Chemistry 97, no. 50 (December 1993): 13358–67. http://dx.doi.org/10.1021/j100152a048.

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44

KOGA, Noboru, and Hiizu IWAMURA. "Generation of tetraphenylporphyrins and their zinc complexes carrying phenylmethylenyl groups. Exchange interaction between diphenylcarbene units through a porphyrin ring." NIPPON KAGAKU KAISHI, no. 8 (1989): 1456–62. http://dx.doi.org/10.1246/nikkashi.1989.1456.

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45

Zayas, Jose, and Matthew S. Platz. "The formation of an enantiomerically pure product of free radical coupling. The chemistry of diphenylcarbene in polycrystalline S-(+)-2-butanol." Journal of the American Chemical Society 107, no. 24 (November 1985): 7065–69. http://dx.doi.org/10.1021/ja00310a050.

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46

Wilson, R. Marshall, Karlyn A. Schnapp, and Wesley S. Patterson. "High-intensity, argon ion laser-jet photochemistry. Reactions between transient species: the addition of diphenylcarbene to the photoenol of 2-methylbenzophenone." Journal of the American Chemical Society 114, no. 27 (December 1992): 10987–89. http://dx.doi.org/10.1021/ja00053a060.

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47

Kohtani, Shigeru, Chizuko Sugita, and Michiya Itoh. "Resonance Energy Transfer from the Lowest Excited Triplet State of Diphenylcarbene to Dye Molecules: Utilization for the Characterization of the Triplet−Triplet Fluorescence." Journal of Physical Chemistry 100, no. 45 (January 1996): 17735–39. http://dx.doi.org/10.1021/jp961881s.

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48

BUSYGINA, I. N., T. A. STROMNOVA, D. I. KOCHUBEI, M. YA BOTNIKOV, and I. I. MOISEEV. "ChemInform Abstract: Substitution of a Carbonyl Group by a Carbene Ligand. Synthesis of Tetrakis(diphenylcarbene)tetraacetatotetrapalladium Pd4(μ-CPh2)4(. mu.-OAc)4." ChemInform 23, no. 34 (August 21, 2010): no. http://dx.doi.org/10.1002/chin.199234261.

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49

WILSON, R. M., K. A. SCHNAPP, and W. S. PATTERSON. "ChemInform Abstract: High-Intensity, Argon Ion Laser-Jet Photochemistry. Reactions Between Transient Species: The Addition of Diphenylcarbene to the Photoenol of 2-Methylbenzophenone." ChemInform 24, no. 18 (August 20, 2010): no. http://dx.doi.org/10.1002/chin.199318113.

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50

Simon, John D., and Kevin S. Peters. "Determination of the heat of reaction for the formation of diphenylcarbene from diphenyldiazomethane using photoacoustic calorimetry [Erratum to document cited in CA99(11):87472W]." Journal of the American Chemical Society 110, no. 10 (May 1988): 3336. http://dx.doi.org/10.1021/ja00218a074.

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