Academic literature on the topic 'Diffusion d'hydrogène'
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Dissertations / Theses on the topic "Diffusion d'hydrogène":
Potvliege, Robert. "Etude théorique de la diffusion élastique et inélastique d'électrons et de positrons rapides par des atomes d'hydrogène." Doctoral thesis, Universite Libre de Bruxelles, 1985. http://hdl.handle.net/2013/ULB-DIPOT:oai:dipot.ulb.ac.be:2013/213632.
Ouraou, Ahmimed. "Mesure des fonctions de structure du proton par diffusion inélastique de muons sur cible d'hydrogène et tests de la chromodynamique quantique." Paris 11, 1988. http://www.theses.fr/1988PA112118.
Larbi, Fadila. "Traitement de couches minces et de dispositifs à base de a-Si : H par un plasma d'hydrogène : Etude in situ par ellipsométrie spectroscopique." Thesis, Reims, 2014. http://www.theses.fr/2014REIMS010/document.
This work is a contribution to the study of the interaction between hydrogenated amorphous silicon (a-Si:H) thin films and hydrogen plasma in a PECVD (Plasma Enhanced Chemical Vapor Deposition) reactor. The kinetics of silicon etching by atomic hydrogen is monitored in situ by UV - visble ellipsometry .Several plasma parameters (temperature, RF power, H2 gas pressure, the doping of the material) that may impact the kinetics were probed. An analysis of the spectroscopic ellipsometry spectra, thanks to an appropriate optical model, allowed evidencing their effects on the time constant, the thickness and the hydrogen excess of the H-modified layer.The same hydrogen plasma treatment repeated on i/p and i/n H base junctions revealed a particular behavior of the etching kinetics in the junction zone. This effect is interpreted in the frame of a simple of hydrogen diffusion model under an electric field
Bouachir, Mohamed. "Etude par diffusion de la lumière Rayleigh et Raman de la structure et de la dynamique moléculaire du sulfure d'hydrogène à l'état liquide." Bordeaux 1, 1985. http://www.theses.fr/1985BOR10556.
Kane-Diallo, Ousseynou. "Analyse morphologique des champs de cavités dans un élastomère sous décompression d'hydrogène : Influence des conditions de décompression et effets d'interaction." Thesis, Chasseneuil-du-Poitou, Ecole nationale supérieure de mécanique et d'aérotechnique, 2015. http://www.theses.fr/2015ESMA0014/document.
The morphology of cavitation is analyzed in an unfilled EPDM under different hydrogen decompression conditions. The experimental device allows a time-resolved tracking of the evolution of damage. Images are processed to obtain the onset time, the number and sizedistribution of cavities over time, and the inflation / deflation kinetics of the biggest cavities.Covariograms quantifies the spatial distribution of cavity fields. The analysis is thus led at two scales: that of independent cavities and that of the full cavity fields. At the cavity scale, kineticsis shown to be identical for independent cavities but different between inflation and deflation.Experimental kinetics is compared to that issued from Finite Element calculations in a cell containing one or two cavities, in coupled diffuso-mechanical conditions. Calculationshighlight the evolution of local mechanical and gas content fields, as well as interaction effects between close cavities. At the scale of cavity fields, the spatial distribution is influenced by the decompression conditions. The number and size of cavities increase with saturation pressure and/or decompression rate and a second population of small cavities is nucleated around the first one under severe decompression conditions. The homogeneity and isotropy of the distribution at macroscopic scale are studied. The influence of cycling on the evolution of cavitation morphology is addressed in the final part. It was finally found that the morphology of cavity fields evolves during successive cycles. The analysis provides information to discuss and to inquire the framework and ingredients of damage models
De, Iuliis Silvana. "Etude de la vitesse de formation des suies à partir de l'éthylène en présence d'hydrogène par les méthodes du tube à choc et du brûleur au moyen de différentes techniques optiques." Phd thesis, Université d'Orléans, 2009. http://tel.archives-ouvertes.fr/tel-00623053.
Lekbir, Choukri. "Effet de la déformation plastique du nickel monocristallin sur l'état d'équilibre de l'hydrogène en surface et subsurface." Thesis, La Rochelle, 2012. http://www.theses.fr/2012LAROS368.
The present work has for objective to study the synergy between the plastic strain and the processes of adsorption and absorption of hydrogen on the surface and the subsurface of nickel single crystal.Hydrogen Evolution Reaction (HER) and Hydrogen Absorption in subsurface (HAR) share mostly the common intermediate: the adsorbed hydrogen (Hads). The HER pathway on nickel (100) single crystal surfaces in sulphuric acid medium can be related by a Volmer-Heyrovsky mechanism. The corresponding elementary kinetic parameters as symmetry coefficients, activation enthalpies, number of active sites, have been identified via a thermokinetic model using experimental data. These parameters can be affected by defects associted with plastic strain. Irreversible plastic strain modifies the density and the distribution of storage dislocations affecting the surface roughness at atomic scale and generating additional active adsorption sites. Further more, surface emergence of mobile dislocations induces the formation of slip bands, which modify the surface roughness and the electronic state of the surface and increases the (111) surface density. The entry of hydrogen atoms associated to the transfer step surface-Subsurface can be measured using a potentiostatic double-Steptechnique (pulse method). This last allowed to characterizing the diffusion and trapping of hydrogen in the subsurface. Two domains can be distinguished, that of the subsurface and that of the bulk of the sample. In this case, the diffusion coefficient near the surface (subsurface) seems to be much higher than that obtained in the bulk of the metal. On the other hand, the application of mechanical stressleads to an increase of traps density. This last, developed near the surface: « subsurface », is lower than that at the bulk of material, which suggest a softening effect in the subsurface
Demmano, Gustave. "Réactions enzymatiques cycliques : études systématiques des modèles de transport-réaction transmembranaires d'électrons et de protons. Cycles amplificateurs multienzymatiques en solution." Rouen, 1992. http://www.theses.fr/1992ROUES027.
Nizeyimana, Fidèle. "Etude du vieillissement hydrolytique et thermo-oxydatif de blindages neutroniques." Phd thesis, Paris, ENSAM, 2012. http://pastel.archives-ouvertes.fr/pastel-00697087.
Ruffio, Emmanuel. "Estimation de paramètres et de conditions limites thermiques en conduction instationnaire pour des matériaux anisotropes." Phd thesis, Chasseneuil-du-Poitou, Ecole nationale supérieure de mécanique et d'aérotechnique, 2011. http://www.theses.fr/2011ESMA0019.
This study deals with the resolution of two types of inverse heat transfer problem: estimation of thermophysical parameters and estimation of thermal boundary conditions. A first part is devoted to the 3D-flash method which is used to estimate the three thermal diffusivities corresponding to the three principal directions of an anisotropic material. This work led to the realization of a experimental setup. The thermal excitation is provided by a CO2 laser and the temperature fields are acquired using infrared thermography. The thermal diffusivities are estimated by combining an estimator, an experiment and an analytical modeling. Different estimators are proposed and compared, based on their standard deviations. Moreover, a procedure to perform experiment design is presented to further reduce these standard deviations. In the second part, two studied cases consisting in estimating thermal boundary conditions are presented. Both underlying systems involve materials whose thermal properties are known. The thermal boundaries are estimated using temperature measurement provided by thermocouples. The first case deals with the evaluation of heat transfer between the gas and the inner-surface of a high pressure hydrogen tank. In the second case, the objective is to estimate the heat flux absorbed by a composite sample exposed to an oxygen-acetylene torch, in order to simulate the ablation phenomena under extreme conditions. Optimization algorithms are essential in this work. Gradient-based methods are used for parameters estimation and thermal boundary estimation problems. Stochastic algorithms appear to be well adapted in the framework of experiment design problems