Dissertations / Theses on the topic 'DCT TECHNIQUE'
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Guezzi, Messaoud Fadoua. "Analyse de l'apport des technologies d'intégration tri-dimensionnelles pour les imageurs CMOS : application aux imageurs à grande dynamique." Thesis, Paris Est, 2014. http://www.theses.fr/2014PEST1022/document.
Full textWith the increase of systems complexity, integrating different technologies together has become a major challenge. Another challenge has traditionally been the limitation on the throughout between different part of the system coming from the interconnections. If traditional two dimensional integration solutions like System In a Package (SIP) bring heterogonous technologies together there is still limitations coming from the restricted number and lengths of interconnections between the different system components. Three Dimensional stacking (3D), by exploiting short vertical interconnections between different circuits of mixed technologies, has the potential to overcome these limitations. Still, despite strong interests for the 3D concepts, there is no advanced analysis of 3D integration benefits, especially in the field of imagers and smart image sensors. This thesis study the potential benefits of 3D integration, with local processing and short feedback loops, for the realisation of a High Dynamic Range (HDR) image sensor. The dense vertical interconnections are used to locally adapt the integration time by group of pixels, called macro-pixels, while keeping a classic pixel architecture and hence a high fill factor. Stacking the pixel section and circuit section enables a compact pixel and the integration of flexible and versatile functions. High Dynamic Range values producing an important quantity of data, the choice has been made to implement data compression to reduce the circuit throughout. A first level of compression is produced by coding the pixel value using a floating format with a common exponent shared among the macro-pixel. A second level of compression is proposed based on a simplified version of the Discrete Cosine Transform (DCT). Using this two level scheme, a compression of 93% can be obtained with a typical PSNR of 30 dB. A validation of the architecture was carried out by the development; fabrication and test of a prototype on a 2D, 180 nm, CMOS technology. A few pixels of each macro-pixel had to be sacrificed to implement the high dynamic range control signals and emulate the 3D integration. The test results are very promising proving the benefits that will bring the 3D integration in term of power consumption and image quality compared to a classic 2D integration. Future realisations of this architecture, done using a real 3D technology, separating sensing and processing on different circuits communicating by vertical interconnection will not need the sacrifice of any pixel to adjust the integration time, improving power consumption, image quality and latency
Louis-sidney, Ludovic. "Modèles et outils de capitalisation des connaissances en conception : contribution au management et à l'ingénierie des connaissances chez Renault - DCT." Phd thesis, Ecole Centrale Paris, 2011. http://tel.archives-ouvertes.fr/tel-00659298.
Full textEkström, Alexander Gösta. "Developing dynamic combinatorial chemistry as a platform for drug discovery." Thesis, University of Edinburgh, 2018. http://hdl.handle.net/1842/31073.
Full textAimer, Younes. "Étude des performances d'un système de communication sans fil à haut débit." Thesis, Poitiers, 2019. http://www.theses.fr/2019POIT2269.
Full textThe request of the users in terms of rate, coverage and quality of service is growing exponentially, with increasing demand for electrical energy, to ensure networks link. In this context, new waveforms based on the OFDM modulation become widely popular and used intensively in recent radio communications architectures. However, these signals are sensitive to the power amplifier nonlinearities because of their high envelope fluctuations characterized by a high PAPR, which degrades the energy consumption and the transmitter efficiency.In this thesis, we first began by a state art of the PAPR reduction techniques. This presentation allowed us to propose a new method based on interleaving and coding techniques. The first contribution consists on the use of the interleaving technique using null-subcarriers for the transmission of the side information, while respecting the frequency specifications of the used standard. The second one is based on the conjunction of the Shaping technique and the Discrete Cosine Transform (DCT), with the aim of improving the performance of the system. Simulation results show that the use of these two techniques allows a significant gain in terms of PAPR reduction, which results in the improvement of the system efficiency. Finally, we presented an experimental study of the proposed techniques using an RF test bench with a commercial LDMOS 20 W PA, class AB operating at 3.7 GHz. The results obtained for the IEEE 802.11 standards show that the proposed approaches allow the transmission robustness and quality, while optimizing the power consumption
Edirisuriya, Amila. "Digital Hardware Architectures for Exact and Approximate DCT Computation Using Number Theoretic Techniques." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1363233037.
Full textMuradagha, Rafea. "A modified DFT technique for linear phase measurement." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1999. http://www.collectionscanada.ca/obj/s4/f2/dsk1/tape8/PQDD_0005/MQ45336.pdf.
Full textGregušová, Michaela. "Modifikace techniky difúzních gelů (DGT) pro charakterizaci přírodních systémů." Doctoral thesis, Vysoké učení technické v Brně. Fakulta chemická, 2010. http://www.nusl.cz/ntk/nusl-233319.
Full textRio, Jérémy. "Modélisation à l'échelle atomique de Cycloparaphénylènes avec les techniques ab initio." Thesis, Nantes, 2017. http://www.theses.fr/2017NANT4078/document.
Full textThe work in this thesis concerns the study at the atomic scale of Cycloparaphenylene ([n]CPP) molecules and their complexes and derivatives, using ab initio modeling methods (DFT/LDA). I initially look at the stability of these molecular rings when functionalized by halogens, and the structural changes induced. The important notion of curvature energy is raised to find new synthesis routes. The encapsulation of C60 fullerene inside [10]CPPs is a very important part of this work and more particularly the interaction between the azafullerene dimer (C59N)2 and two [10]CPPs. This allowed us to look at supramolecular interactions and the alignment of two [10]CPPs on this dimer both theoretically and experimentally, through collaboration with research teams in Germany and Greece. The possibility of templated alignment of [10]CPPs leads to a study on the functionalization of these molecules with the aim of connecting them together with various connectors, for example with aromatic species, polymers or metals to form a new family of pseudo-nanotubes composed of multiply inter-linked [10]CPPs. Depending on the connections used, the conduction properties of the 'pseudo-nanotubes' can vary from wide-gap semiconductors to metallic structures. I also show in this manuscript, that [n]CPPs and carbon nanotubes can interact to form structures where the ring is encapsulated inside or around the carbon nanotube. In this context, the study of the rotation of cycloparaphenylene demonstrate a very low frictional force and thus predict ultra-rapid CPP rotation
Dale, Brian M. "Optimal Design of MR Image Acquisition Techniques." Case Western Reserve University School of Graduate Studies / OhioLINK, 2004. http://rave.ohiolink.edu/etdc/view?acc_num=case1081556784.
Full textAlrasheed, Waleed. "Time and Space Efficient Techniques for Facial Recognition." Doctoral diss., University of Central Florida, 2013. http://digital.library.ucf.edu/cdm/ref/collection/ETD/id/6238.
Full textPh.D.
Doctorate
Electrical Engineering and Computer Science
Engineering and Computer Science
Electrical Engineering
Wagner, Philipp. "Modélisation du graphène avec les techniques ab initio." Nantes, 2013. http://www.theses.fr/2013NANT2011.
Full textIn this thesis graphene and related nanostructures were studied, using density functional ab initio modelling techniques. The influence of different edge terminations has been investigated for typical pristine graphene edges (armchair, zigzag and Klein) and several reconstructed edge configurations. For unterminated graphene edges a new stable folded back edge has been identified, creating a nanotube along the graphene edge. A systematic study of hydrogenated edges was performed, and new favourable reconstructed Klein edge configurations were found. Furthermore hydrogenated edges are expected to play an important role for graphene growth processes, and thus possible adapted growth models via carbon dimer addition are proposed. Next more complex edge functionalisations such as hydroxylated (-OH) edges were studied, in particular modelling thin 4 - 25 Å wide armchair graphene nanoribbons. Notably the influence on structural, electronic, chemical and mechanical properties has been investigated. This promises new routes towards controlled design of specific nanoribbon properties. Finally the in-plane Young’s modulus of various nanosheets (including graphene, BN, MoS2, MoTe2 etc. ) were calculated. In this context a new geometry independent volume definition for nanoobjects has been developed, based on the average electron density. This new approach offers a transferable underlying framework to calculate the Young’s modulus, and thus values correctly extrapolate for example between graphene, carbon nanotubes and bulk graphite. The concept was further extended to organic polymers
Fleury, Christine Collet Anne-Christine. "Intégrer une thématique " Sciences et Société " dans une bibliothèque de lecture publique une approche globale pour la Médiathèque du Bachur /." [S.l.] : [s.n.], 2004. http://www.enssib.fr/bibliotheque/documents/dcb/fleury.pdf.
Full textAbdallah, Abdallah Sabry. "Investigation of New Techniques for Face detection." Thesis, Virginia Tech, 2007. http://hdl.handle.net/10919/33191.
Full textMaster of Science
Nguyen, Thi Minh Tam. "Approches basées sur DCA pour la programmation mathématique avec des contraintes d'équilibre." Thesis, Université de Lorraine, 2018. http://www.theses.fr/2018LORR0113/document.
Full textIn this dissertation, we investigate approaches based on DC (Difference of Convex functions) programming and DCA (DC Algorithm) for mathematical programs with equilibrium constraints. Being a classical and challenging topic of nonconvex optimization, and because of its many important applications, mathematical programming with equilibrium constraints has attracted the attention of many researchers since many years. The dissertation consists of four main chapters. Chapter 2 studies a class of mathematical programs with linear complementarity constraints. By using four penalty functions, we reformulate the considered problem as standard DC programs, i.e. minimizing a DC function on a convex set. The appropriate DCA schemes are developed to solve these four DC programs. Two among them are reformulated again as general DC programs (i.e. minimizing a DC function under DC constraints) in order that the convex subproblems in DCA are easier to solve. After designing DCA for the considered problem, we show how to develop these DCA schemes for solving the quadratic problem with linear complementarity constraints and the asymmetric eigenvalue complementarity problem. Chapter 3 addresses a class of mathematical programs with variational inequality constraints. We use a penalty technique to recast the considered problem as a DC program. A variant of DCA and its accelerated version are proposed to solve this DC program. As an application, we tackle the second-best toll pricing problem with fixed demands. Chapter 4 focuses on a class of bilevel optimization problems with binary upper level variables. By using an exact penalty function, we express the bilevel problem as a standard DC program for which an efficient DCA scheme is developed. We apply the proposed algorithm to solve a maximum flow network interdiction problem. In chapter 5, we are interested in the continuous equilibrium network design problem. It was formulated as a Mathematical Program with Complementarity Constraints (MPCC). We reformulate this MPCC problem as a general DC program and then propose a suitable DCA scheme for the resulting problem
Gauthier, Évelyne. "Les techniques de manipulation du roman populaire dit féminin." Limoges, 1986. http://www.theses.fr/1986LIMO0503.
Full textGauthier, Évelyne. "Les Techniques de manipulation du roman populaire dit féminin." Lille 3 : ANRT, 1987. http://catalogue.bnf.fr/ark:/12148/cb375985549.
Full textBourguignat, Christelle Muller Joëlle. "La part des ouvrages scientifiques et techniques en bibliothèque municipale." [S.l.] : [s.n.], 2004. http://www.enssib.fr/bibliotheque/documents/dcb/bourguignat.pdf.
Full textDevillers, Delphine. "Fiabilisation de la quantification des éléments traces cationiques et anioniques par la technique d'échantillonnage DGT en milieu aquatique naturel." Thesis, Limoges, 2017. http://www.theses.fr/2017LIMO0058/document.
Full textThe passive sampling DGT technique (Diffusive Gradients in Thin Films) has a lot of benefits (time-weighted average concentrations, low limits of quantification) and would therefore be a useful tool for monitoring studies to quantify trace elements in natural water. However, there are still some limitations and grey areas that put the brakes on the development of the method for regulatory applications. The aim of this work is to identify potential biases and contribute to increase the method reliability. This study shows that a minimized uncertainty on results can be obtained only if elution factors are experimentally determined; however, standard values of 0.8 for Cr(III) and 0.85 for Al(III), Cd(II), Co(II), Cu(II), Ni(II), Pb(II) and Zn(II) are suggested to reduce manipulations while keeping reasonable uncertainty (<10%). Studying the influence of fouling developed on DGT devices showed that the sorption of cations Cd(II), Cu(II) and Pb(II) had, respectively, a slight, moderate and strong impact on their accumulation in DGT samplers and therefore on their quantification. Samplers should then be deployed for less than one week. In contrast, fouling had a negligible impact on oxyanions As(V), Cr(VI), Sb(V) and Se(VI). Finally, a method was developed to simultaneously quantify both Cr oxidation states naturally occurring in natural waters, which are Cr(III), essential to life, and Cr(VI), toxic. Both forms are accumulated in a single DGT sampler before being selectively separated during an elution step. This method is robust for wide ranges of ionic strengths and sulfate concentrations but for a narrower range of pH (4 to 6)
Shuttleworth, Sarah M. "The application of gel-based sampling techniques (DET and DGT) to the measurement of sediment pore-water solutes at high (mm) spatial resolution." Thesis, Lancaster University, 2000. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.369497.
Full textKane, David. "Evaluating phosphorus availability in soils receiving organic amendment application using the Diffusive Gradients in Thin-films (DGT) technique." Thesis, Cranfield University, 2013. http://dspace.lib.cranfield.ac.uk/handle/1826/8001.
Full textBouallagui, Sarra. "Techniques d'optimisation déterministe et stochastique pour la résolution de problèmes difficiles en cryptologie." Phd thesis, INSA de Rouen, 2010. http://tel.archives-ouvertes.fr/tel-00557912.
Full textLundell, Johan. "Efficiency Enhancement Techniques for a 0.13 µm CMOS DECT PA." Thesis, Linköpings universitet, Institutionen för teknik och naturvetenskap, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-96235.
Full textHo, Vinh Thanh. "Techniques avancées d'apprentissage automatique basées sur la programmation DC et DCA." Thesis, Université de Lorraine, 2017. http://www.theses.fr/2017LORR0289/document.
Full textIn this dissertation, we develop some advanced machine learning techniques in the framework of online learning and reinforcement learning (RL). The backbones of our approaches are DC (Difference of Convex functions) programming and DCA (DC Algorithm), and their online version that are best known as powerful nonsmooth, nonconvex optimization tools. This dissertation is composed of two parts: the first part studies some online machine learning techniques and the second part concerns RL in both batch and online modes. The first part includes two chapters corresponding to online classification (Chapter 2) and prediction with expert advice (Chapter 3). These two chapters mention a unified DC approximation approach to different online learning algorithms where the observed objective functions are 0-1 loss functions. We thoroughly study how to develop efficient online DCA algorithms in terms of theoretical and computational aspects. The second part consists of four chapters (Chapters 4, 5, 6, 7). After a brief introduction of RL and its related works in Chapter 4, Chapter 5 aims to provide effective RL techniques in batch mode based on DC programming and DCA. In particular, we first consider four different DC optimization formulations for which corresponding attractive DCA-based algorithms are developed, then carefully address the key issues of DCA, and finally, show the computational efficiency of these algorithms through various experiments. Continuing this study, in Chapter 6 we develop DCA-based RL techniques in online mode and propose their alternating versions. As an application, we tackle the stochastic shortest path (SSP) problem in Chapter 7. Especially, a particular class of SSP problems can be reformulated in two directions as a cardinality minimization formulation and an RL formulation. Firstly, the cardinality formulation involves the zero-norm in objective and the binary variables. We propose a DCA-based algorithm by exploiting a DC approximation approach for the zero-norm and an exact penalty technique for the binary variables. Secondly, we make use of the aforementioned DCA-based batch RL algorithm. All proposed algorithms are tested on some artificial road networks
Soupart, Adrien. "Nouveau regard sur les propriétés photophysiques et photochimiques du complexe tris(2,2'-bipyridine) ruthénium II : apport de la DFT." Thesis, Toulouse 3, 2019. http://www.theses.fr/2019TOU30143.
Full textRuthenium polypyridyl complexes are of great interest for photovoltaic applications, photocatalysis, sensing, photodynamic therapy (PDT) or photoactivated chemotherapy (PACT). But even for the archetype [Ru(bpy)3]2+, not all experimental features have been unravelled yet. It is then mandatory to map the topology of the excited states potential energy surfaces and to characterize the associated processes with state-of-the-art theoretical methods. The first part of the manuscript describes the methods used to explore these surfaces and the rationalization of photophysical properties of two complexes, [Ru(bpy)3]2+ and [Ru(tpy)2]2+: simulation of Vibrationally Resolved Electronic emission Spectra (VRES), study of the non-radiative decay process through the optimization of Minimum Energy Crossing Points (MECP) and calculation of energy barriers and minimum energy paths using the Nudged Elastic Band method (NEB). The photoreactivity of [Ru(bpy)3]2+ has never been studied using theoretical methods. It involves 3MC dark states, poorly described by spectroscopic data. Therefore, it represents a great challenge for theoreticians. We describe in a second part a true 3MC basin and a Natural Bond Orbital analysis was conducted on the states composing it. We compare our simulations of various absorption spectra (UV-Vis, XAS, IR) of all triplet excited states of [Ru(bpy)3]2+ with the few experimental data available, and their contradictory interpretations, in order to provide a guide for future experiments. Finally, we propose the first and complete theoretical mechanism for a photosubstitution reaction using the model reaction: [Ru(bpy)3]2+ + 2 MeCN → cis/trans-[Ru(bpy)2(MeCN)2]2+ + bpy, by exploring fundamental and excited potential energy surfaces. This multi-step, sequential, two photon, mechanism allowed us to rationalize the preferential formation of the cis photoproduct
Ouerhani, Yousri. "Contribution à la définition, à l'optimisation et à l'implantation d'IP de traitement du signal et des données en temps réel sur des cibles programmables." Phd thesis, Université de Bretagne occidentale - Brest, 2012. http://tel.archives-ouvertes.fr/tel-00840866.
Full textRemersaro, Santiago. "On low power test and DFT techniques for test set compaction." Diss., University of Iowa, 2008. https://ir.uiowa.edu/etd/211.
Full textVenianaki, Maria. "Cancer tissue classification from DCE-MRI data using pattern recognition techniques." Thesis, IMT Alti Studi Lucca, 2019. http://e-theses.imtlucca.it/264/1/Venianaki_phdthesis.pdf.
Full textPolo, Montes Carlos A. "The effect of cementation technique on the retention of adhesively cemented prefabricated posts." Thesis, Birmingham, Ala. : University of Alabama at Birmingham, 2007. https://www.mhsl.uab.edu/dt/2007m/polomontes.pdf.
Full textHussein, Ahmed. "Design Techniques for Low Spur Wide Tuning All-Digital Millimeter-Wave Frequency Synthesizers." Research Showcase @ CMU, 2017. http://repository.cmu.edu/dissertations/801.
Full textGier, Sylvie Caraco Alain. "Quelle place pour les automates de prêt et de retour dans les bibliothèques publiques françaises ? Analyse technique et stratégique." [S.l.] : [s.n.], 2004. http://www.enssib.fr/bibliotheque/documents/dcb/gier.pdf.
Full textRojas, Daniel. "Revenue management techniques applied to the parking industry." [Tampa, Fla] : University of South Florida, 2006. http://purl.fcla.edu/usf/dc/et/SFE0001835.
Full textPoulos, Konstantinos. "NEW TECHNIQUES ON VLSI CIRCUIT TESTING & EFFICIENT IMPLEMENTATIONS OF ARITHMETIC OPERATIONS." OpenSIUC, 2020. https://opensiuc.lib.siu.edu/dissertations/1872.
Full textÖsterlund, Helene. "Applications of the DGT technique for measurements of anions and cations in natural waters." Licentiate thesis, Luleå tekniska universitet, Geovetenskap och miljöteknik, 2010. http://urn.kb.se/resolve?urn=urn:nbn:se:ltu:diva-16785.
Full textGodkänd; 2010; 20100517 (helost); LICENTIATSEMINARIUM Ämnesområde: Tillämpad geologi/Applied Geology Examinator: Professor Johan Ingri, Luleå tekniska universitet Diskutant: Docent Per Andersson, Naturhistoriska Riksmuseet Tid: Fredag den 18 juni 2010 kl 10.00 Plats: F341, Luleå tekniska universitet
Bořek, Tomáš. "Toxické kovy ve vodě a sedimentech vodní nádrže Brno." Master's thesis, Vysoké učení technické v Brně. Fakulta chemická, 2009. http://www.nusl.cz/ntk/nusl-216543.
Full textMeredith, Scott. "Extended techniques in Stanley Friedman's Solus for unaccompanied trumpet." Thesis, connect to online resource, 2008. http://digital.library.unt.edu/permalink/meta-dc-6075.
Full textSystem requirements: Adobe Acrobat Reader. Accompanied by 4 recitals, recorded Apr. 12, 2004, June 3, 2004, June 14, 2005, and Mar. 10, 2008. Includes bibliographical references (p. 36-37).
Du, Ke. "Noval nanoindentation-based techniques of MEMS and microfluidics applications." [Tampa, Fla] : University of South Florida, 2008. http://purl.fcla.edu/usf/dc/et/SFE0002778.
Full textDamodara, Eswar Keran C. "Clinical trial to determine the accuracy of prefabricated trays for making alginate impressions." Thesis, Birmingham, Ala. : University of Alabama at Birmingham, 2008. https://www.mhsl.uab.edu/dt/2009r/damodara.pdf.
Full textArwood, Bryan Stuart. "The effectiveness of advanced oxidation techniques in degrading steroids in wastewater." Birmingham, Ala. : University of Alabama at Birmingham, 2010. https://www.mhsl.uab.edu/dt/2010m/arwood.pdf.
Full textGabucci, Ilenia. "Dual energy computed tomography techniques applied to the characterization of cartilage tissue." Master's thesis, Alma Mater Studiorum - Università di Bologna, 2022. http://amslaurea.unibo.it/25617/.
Full textShiva, Amir Houshang. "Evaluating the Performance of DGT Technique for Selective Measurement of Trace Metals and Assessment of Environmental Health in Coastal Waters." Thesis, Griffith University, 2016. http://hdl.handle.net/10072/367257.
Full textThesis (PhD Doctorate)
Doctor of Philosophy (PhD)
Griffith School of Environment
Science, Environment, Engineering and Technology
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Baylis, Charles Passant. "Improved techniques for nonlinear electrothermal FET modeling and measurement validation." [Tampa, Fla.] : University of South Florida, 2007. http://purl.fcla.edu/usf/dc/et/SFE0001989.
Full textAravamudhan, Shyam. "Development of micro/nanosensor elements and packaging techniques for oceanography." [Tampa, Fla.] : University of South Florida, 2007. http://purl.fcla.edu/usf/dc/et/SFE0002219.
Full textGhai, Dhruva V. Mohanty Saraju. "Variability-aware low-power techniques for nanoscale mixed-signal circuits." [Denton, Tex.] : University of North Texas, 2009. http://digital.library.unt.edu/permalink/meta-dc-9850.
Full textNicolas, Yann. "La réforme maorie de la Bibliothèque Nationale de Nouvelle-Zélande dimension stratégique et enjeux techniques (collections, catalogues, accès, conservation) /." [S.l.] : [s.n.], 2003. http://www.enssib.fr/bibliotheque/documents/dcb/nicolas.pdf.
Full textALGHAMDI, HASAN A. "Dynamic Cone Penetrometer (DCP) Based Evaluation of Sustainable Low Volume Road Rehabilitation Techniques." Ohio University / OhioLINK, 2016. http://rave.ohiolink.edu/etdc/view?acc_num=ohiou1470661119.
Full textRoy, Soumyaroop. "A compiler-based leakage reduction technique by power-gating functional units in embedded microprocessors." [Tampa, Fla] : University of South Florida, 2006. http://purl.fcla.edu/usf/dc/et/SFE0001832.
Full textSchmied, Marten. "Business Intelligence in Healthcare - Data Mining Techniques as a Possible Hospital Management Tool in Austria." Master's thesis, Vysoká škola ekonomická v Praze, 2016. http://www.nusl.cz/ntk/nusl-264283.
Full textPopović, Slobodan. "Reliability testing of R-DAT tapes subjected to mechanical and environmental stress." Thesis, McGill University, 1992. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=56757.
Full textTurgut, Canan. "Deposition and adsorption of organic matter in the sub-monolayer range studied by experimental and numerical techniques." Thesis, Université de Lorraine, 2015. http://www.theses.fr/2015LORR0012/document.
Full textPlasma surface treatments present an efficient, economical and ecological tool for surface functionalization. For this technique the deposition and adhesion of molecules and precursors in the sub-monolayer range are of utmost interest, since this layer defines the surface properties and the adhesion between deposit and substrate. The species in the plasma and their energy and angular distributions control the deposition process. To get insights into the latter, a multidisciplinary approach combining DFT calculations with experimental techniques is used for the preparation and characterisation of sub-monolayer deposits of PS and PMMA. The deposits are prepared by sputter deposition using an Ar beam and analysed by ToF-SIMS and XPS. The amount of deposited matter increases well with deposition time or fluence. ToF-SIMS analyses showed also that the proportion of large fragments on the collector surface is increasing with fluence, although the opposite was expected. This can only be explained by the recombination of smaller fragments to form larger ones. This hypothesis is supported by DFT calculations which showed that the adsorption energy, and hence the adsorption probability, is higher for the small fragments than for the large ones. DFT calculations have been extended to Si, Pt and Al2O3 substrates, showing that adsorption energies are highest for Si and Pt
Kasprzyk, Christina Ridley. "Practical applications of molecular dynamics techniques and time correlation function theories." [Tampa, Fla] : University of South Florida, 2006. http://purl.fcla.edu/usf/dc/et/SFE0001644.
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