Academic literature on the topic 'Cyclohexadien-1'
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Journal articles on the topic "Cyclohexadien-1"
Kreiter, Cornelius G., and Klaus Lehr. "Photochemische Reaktionen von Übergangsmetall-Organyl-Komplexen mit Olefnen, VI. Reaktionen von Tricarbonyl-η5-2,4-cyclohexadienyl-mangan mit konjugierten Dienen / Photochemical Reactions of Transition Metal Organyl Complexes with Olefins, VI. Reactions of Tricarbonyl (η5-2,4-cyclohexadienyl)manganese with Conjugated Dienes." Zeitschrift für Naturforschung B 46, no. 10 (October 1, 1991): 1377–83. http://dx.doi.org/10.1515/znb-1991-1016.
Full textAkbar, Erum, Hafiz Rub Nawaz, and Abdul Malik. "Dihydroquinol And Quinol Derivatives From Ajuga Parviflora." Zeitschrift für Naturforschung B 56, no. 8 (August 1, 2001): 842–46. http://dx.doi.org/10.1515/znb-2001-0819.
Full textSchultz, Arthur G., Arthur G. Taveras, and Roger E. Harrington. "An improved procedure for the conversion of3,3-disubstituted-1,4-cyclohexadienes to 2,5-cyclohexadien-1-ones." Tetrahedron Letters 29, no. 32 (January 1988): 3907–10. http://dx.doi.org/10.1016/s0040-4039(00)80377-9.
Full textMorawietz, Jens, and Wolfram Sander. "Matrix Isolation ofo-Quinoid Compounds – 6-Imino-2,4-cyclohexadien-1-one and 1,2-Diimino-3,5-cyclohexadiene." Liebigs Annalen 1996, no. 12 (December 1996): 2029–37. http://dx.doi.org/10.1002/jlac.199619961213.
Full textChristl, Manfred, and Martin Braun. "Freisetzung und Abfangreaktionen von 1-Oxa-2,3-cyclohexadien." Chemische Berichte 122, no. 10 (October 1989): 1939–46. http://dx.doi.org/10.1002/cber.19891221019.
Full textSchreck, Michael, and Manfred Christl. "Freisetzung und Abfangreaktionen von 1-Oxa-3,4-cyclohexadien." Angewandte Chemie 99, no. 7 (July 1987): 720–21. http://dx.doi.org/10.1002/ange.19870990736.
Full textTobal, Ignacio E., Rocío Bautista, David Diez, Narciso M. Garrido, and Pilar García-García. "1,3-Cyclohexadien-1-Als: Synthesis, Reactivity and Bioactivities." Molecules 26, no. 6 (March 22, 2021): 1772. http://dx.doi.org/10.3390/molecules26061772.
Full textFraser, Craig, and Rowan D. Young. "Stable Carbocation Generated via 2,5-Cyclohexadien-1-one Protonation." Journal of Organic Chemistry 83, no. 1 (December 14, 2017): 505–9. http://dx.doi.org/10.1021/acs.joc.7b02668.
Full textLinker, Torsten, and Lothar Fröhlich. "Regio- und diastereoselektive Photooxygenierung chiraler 2,5-Cyclohexadien-1-carbonsäuren." Angewandte Chemie 106, no. 19 (October 5, 1994): 2064–66. http://dx.doi.org/10.1002/ange.19941061928.
Full textAVDEENKO, A. P., and N. M. GLINYANAYA. "ChemInform Abstract: Chlorination and Bromination of 4-Arylsulfonyloxyimino-2,5- cyclohexadien-1-ones and 1,4-Di(arylsulfonyloxyimino)-2,5- cyclohexadienes." ChemInform 27, no. 33 (August 5, 2010): no. http://dx.doi.org/10.1002/chin.199633064.
Full textDissertations / Theses on the topic "Cyclohexadien-1"
Adolph, Simone. "Untersuchungen zur Reaktivität carbokationischer Zwischenstufen bei heterogen induzierten polaren Reaktionen." Doctoral thesis, Universitätsbibliothek Chemnitz, 1999. http://nbn-resolving.de/urn:nbn:de:bsz:ch1-199900156.
Full textThe relative rate constant k´ (s-1m-2) of the surface mediated hydride transfer reaction of 1,4-cyclohexadiene towards triphenylmethylium is significantly dependend on the nature of the solid acid catalyst used. This hydride transfer reaction has been studied to be catalysed by various moderatly strong acid catalysts, e.g. silicas, aluminas, alumosilicates and titan dioxide particles. For the kinetic measurements the triphenylmethylium was generated by chemisorbing chloro triphenylmethane to the solid acid catalyst. The individual pseudo first order rate constant k (s-1) of the hydride transfer reaction increases linearly with the amount of the solid acid catalyst. k´ is then determined as quotient of k through the product of the used amount of the catalyst and its specific BET surface area. The k´ value was used as the reference parameter in order to quantify the catalytic activity of a solid acid
Krismanich, Anthony. "Studies Related to Tandem Reactivity of 1-Carbomethoxy-5-dicyanomethyl-1,3-cyclohexadiene." Thesis, University of Waterloo, 2006. http://hdl.handle.net/10012/2954.
Full textThe ring-opened adduct was also envisaged as a potential substrate in intramolecular Heck reactions. To this end, Heck substrates were generated from the ring-opened adduct anion and iodo- and bromo-benzyl halides. A key observation at this stage pertained to the unexpected acidity of the ring-opened adduct C5 proton, which could be deprotonated by DBU to bring about allylic isomerization, a finding that would provide a key insight to the pattern of reactivity later evidenced with alkyl propiolates. Optimization of the Heck substrate-generating reaction was followed by Heck reactions under Jeffery's conditions, which generated angular tricycles as intended, accompanied by aromatic compounds generated by base-induced HCN elimination/rearrangement and dehydrogenation. The Jeffery's conditions were optimized to limit the production of aromatics.
The possibility of ring-opened adduct-derived vinyl silane intermediates undergoing cationic cyclizations led to a minor study based upon the bromination of allylsilanes and the elimination of TMSBr from 1,2-dibromo-3-trimethylsilyl compounds, accessible compounds unaccounted for in the review literature. It was determined that the combination of HBr and Br2 (perhaps as HBr3) was required to eliminate TMSBr, in contravention of the textbook account of electrophilic substitutions being the inherent reactions of allylsilanes and Br2.
Unexpected tandem reactivity was observed in the reactions of the anionic ring-opened adduct and alkyl propiolates under catalytic DBU conditions. Rather than tandem cyclization or simple adduct formation, the allenolate intermediates were determined to undergo extremely facile formal allenolate Cope rearrangements involving the ?,d-double-bond of the parent ring. Excess base intercepted the allenolate by deprotonating ring C5 and effecting 1,2-vinyl transfer by 3-exo-trig addition-elimination. The chemistry of the highly delocalized side-chain carbanion in the Cope product was studied in detail.
Lange, Catherine. "Chimie des insectes : synthèse, par réaction entre dienamines et aldéhydes insaturés, de molécules potentiellement toxiques. Analyse d'un écosystème termite-fourmi." Paris 6, 1986. http://www.theses.fr/1986PA066234.
Full textMing, Yuan Wang, and 王明遠. "Synthesis and Reactivity of [Ethyl 3-(-cyclohexadien-1-yl) propionate]tricarbonyliron cation complex." Thesis, 1993. http://ndltd.ncl.edu.tw/handle/53334824601471630598.
Full text國立師範大學
化學學系
81
The reaction of the highly functionlized zinc-copper reagents RCu(CN)ZnI tricarbonyl(cyclohexadienyl)iron(+1)salt occurred predominantly at the less hindred terminal,generating function lized side chain at C-5 of (η-cyclohexa-1,3-diene)tricarbonyl (0)complexes.Reaction of [ethyl exo-3-(η-cyclohexa-1,3-diene- 5-yl)propionate]tricarbonyliron complex with hydride abstractio n reagent(Ph3CPF6)produced[ethyl-3-(η-cyclohexadien-1-yl) propionate]tricarbonyliron cationic salt.application of the ationic salt,by treatment with hydride reagents produced [ethyl -3-(η-cyclohexa-1,3-diene-1-yl)propionate]tricarbonyliron(0) complexes.and by treatment with basic reagents produced O-Alkyl ation complexes.
張文垣. "1. The Diels-Alder Reaction of Cage-annulated Cyclohexadiene. Synthesis of A Bispentacyclo Undecadione-fused Bicyclo[2.2.2]octene." Thesis, 1995. http://ndltd.ncl.edu.tw/handle/86476890285653414012.
Full textBooks on the topic "Cyclohexadien-1"
Meredith, John Anthony. The interactions of Cis-3, 5-cyclohexadiene-1, 2-diol (cis-1, 2-dihydroxycyclohexa-3, 5-diene) (benzene-cis-glycol/BCG) with boric and phenylboronic acids. Birmingham: University of Birmingham, 1990.
Find full textBook chapters on the topic "Cyclohexadien-1"
Schomburg, Dietmar, and Ida Schomburg. "2-succinyl-6-hydroxy-2,4-cyclohexadiene-1-carboxylate synthase 4.2.99.20." In Class 3.4–6 Hydrolases, Lyases, Isomerases, Ligases, 596–600. Berlin, Heidelberg: Springer Berlin Heidelberg, 2013. http://dx.doi.org/10.1007/978-3-642-36260-6_71.
Full textChristl, Manfred, and Martin Braun. "Generation and Interception of 1-Oxa-2, 3-Cyclohexadiene and 1,2,4-Cyclohexatriene." In Strain and Its Implications in Organic Chemistry, 121–31. Dordrecht: Springer Netherlands, 1989. http://dx.doi.org/10.1007/978-94-009-0929-8_9.
Full textChowdhury, R. L., C. C. Lee, A. Piórko, and R. G. Sutherland. "(R,S)-1-5-η5-1-NITRO-6-EXO-(2-OXO-1-PROPYL)-CYCLOHEXADIENYL-η5-CYCLOPENTADIENYLIRON." In Organometallic Syntheses, 191–93. Elsevier, 1988. http://dx.doi.org/10.1016/b978-0-444-42956-8.50052-9.
Full textKuthirummal, N., and P. M. Weber. "Probing reaction dynamics with Rydberg states: The ring opening reaction of 1, 3-cyclohexadiene." In Femtochemistry and Femtobiology, 37–40. Elsevier, 2004. http://dx.doi.org/10.1016/b978-044451656-5/50006-2.
Full textTaber, Douglass. "Stereocontrolled Carbocyclic Construction: The Trauner Synthesis of the Shimalactones." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0080.
Full textTaber, Douglass F. "Transition-Metal Catalyzed Ring Construction: The Yu Synthesis of α-Agorafuran." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0074.
Full textTaber, Douglass F. "Other Methods for Carbocyclic Construction: The Porco Synthesis of (-)-Hyperibone K." In Organic Synthesis. Oxford University Press, 2013. http://dx.doi.org/10.1093/oso/9780199965724.003.0081.
Full textConference papers on the topic "Cyclohexadien-1"
Petrovic, Vladimir S. "Ring opening of 1, 3-cyclohexadiene probed by time-resolved optical and x-ray fragmentation." In Laser Science. Washington, D.C.: OSA, 2012. http://dx.doi.org/10.1364/ls.2012.ltu1h.3.
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