Academic literature on the topic 'Crystallization systems'

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Journal articles on the topic "Crystallization systems"

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Balonin, Nikolay A., Victor S. Suzdal, and Yuriy S. Kozmin. "Modal Control of Crystallization Systems." Journal of Automation and Information Sciences 46, no. 8 (2014): 10–17. http://dx.doi.org/10.1615/jautomatinfscien.v46.i8.20.

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SHIOMI, TOMOO. "Crystallization in Multiphase Polymer Systems." Sen'i Gakkaishi 55, no. 3 (1999): P87—P91. http://dx.doi.org/10.2115/fiber.55.3_p87.

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Sanjoh, Akira. "PCMOS - Protein Crystallization Microfluidic Systems." Acta Crystallographica Section D Biological Crystallography 58, no. 10 (September 26, 2002): 1763. http://dx.doi.org/10.1107/s0907444902014890.

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BARD, J. "Automated systems for protein crystallization." Methods 34, no. 3 (November 2004): 329–47. http://dx.doi.org/10.1016/j.ymeth.2004.03.029.

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Ribeiro, Ana Paula Badan, Monise Helen Masuchi, Eriksen Koji Miyasaki, Maria Aliciane Fontenele Domingues, Valter Luís Zuliani Stroppa, Glazieli Marangoni de Oliveira, and Theo Guenter Kieckbusch. "Crystallization modifiers in lipid systems." Journal of Food Science and Technology 52, no. 7 (October 11, 2014): 3925–46. http://dx.doi.org/10.1007/s13197-014-1587-0.

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Vos, Max A. "Crystallization in natural silicate systems." Journal of Non-Crystalline Solids 84, no. 1-3 (July 1986): 318–19. http://dx.doi.org/10.1016/0022-3093(86)90791-x.

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Wibowo, Christianto, Wen-Chi Chang, and Ka M. Ng. "Design of integrated crystallization systems." AIChE Journal 47, no. 11 (November 2001): 2474–92. http://dx.doi.org/10.1002/aic.690471111.

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Newman, Janet. "Novel buffer systems for macromolecular crystallization." Acta Crystallographica Section D Biological Crystallography 60, no. 3 (February 25, 2004): 610–12. http://dx.doi.org/10.1107/s0907444903029640.

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Angell, C. A., and Y. Choi. "Crystallization and vitrification in aqueous systems." Journal of Microscopy 141, no. 3 (March 1986): 251–61. http://dx.doi.org/10.1111/j.1365-2818.1986.tb02720.x.

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Malinina, L. V., V. V. Makhaldiani, V. A. Tereshko, V. F. Zarytova, and E. M. Ivanova. "Phase Diagrams for DNA Crystallization Systems." Journal of Biomolecular Structure and Dynamics 5, no. 2 (October 1987): 405–33. http://dx.doi.org/10.1080/07391102.1987.10506402.

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Dissertations / Theses on the topic "Crystallization systems"

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Saleemi, Ali Nauman. "Strategic feedback control of pharmaceutical crystallization systems." Thesis, Loughborough University, 2011. https://dspace.lboro.ac.uk/2134/8530.

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Crystallization is a widely used purification and separation technique in the pharmaceutical industry. More than 90 % of the active pharmaceutical ingredients are produced in the crystalline form. The quality of the crystalline product greatly affects the downstream processing and bioavailability of the drug. The Food and Drug Administration (FDA) initiated in 2004 the use and implementation of process analytical technology (PAT) in the pharmaceutical development and production and encourages the pharmaceutical industry to adopt quality by design (QBD) approaches. The prime objective of this initiative has been to optimize the drug development and manufacturing process by reducing cost, improving product quality and reducing the number of failed batches. The work presented in this thesis focuses on expanding the use of two PAT tools, namely attenuated total reflection ultra violet/visible spectroscopy (ATR-UV/Vis spectroscopy) and focused beam reflectance measurement (FBRM). ATR-UV/Vis spectroscopy and FRBM are mostly used for process monitoring. The aim here was to develop sophisticated control approaches using these in situ tools for enhancing the product quality. Chemometrics is an integral part of PAT, and can provide valuable information about the system. This tool has also been used in this study for calibration model development and monitoring the cooling and antisolvent crystallization processes for single and muticomponent crystallisations. The development of an accurate and robust calibration model is necessary for qualitative and quantitative analysis of a system using spectroscopy. A systematic methodology was therefore presented for the selection of a suitable calibration model for ATR-UV/Vis spectroscopy. The developed model was then used as part of supersaturation control approach (SSC). SSC uses information from ATR-UV/Vis spectroscopy in a feedback control loop to keep the system at desired supersaturation. The developed approach resulted in the production of crystals of uniform size and can represent the bases for a model-free direct design approach for crystallization systems.
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Sheikh, Ahmad Yahya. "Synthesis, optimisation and control of crystallization systems." Thesis, University College London (University of London), 1997. http://discovery.ucl.ac.uk/1317664/.

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Process systems engineering has provided with a range of powerful tools to chemical engineers for synthesis, optimisation and control using thorough understanding of the processes enhanced with the aid of sophisticated and accurate multi-faceted mathematical models. Crystallization processes have rarely benefited from these new techniques, for they lack in models that could be used to bridge the gaps in their perception before utilising the resulting insight for the three above mentioned tasks. In the present work, first a consistent and sufficiently complex models for unit operations including MSMPR crystallizer, hydrocyclone and fines dissolver are developed to enhance the understanding of systems comprising these units. This insight is then utilised for devising innovative techniques to synthesise, optimise and control such processes. A constructive targeting approach is developed for innovative synthesis of stage-wise crystallization processes. The resulting solution surpasses the performance obtained from conventional design procedure not only because optimal temperature profiles are used along the crystallizers but also the distribution of feed and product removal is optimally determined through non-linear programming. The revised Machine Learning methodology presented here for continual process improvement by analysing process data and representing the findings as zone of best average performance, has directly utilised the models to generate the data in the absence of real plant data. The methodology which is demonstrated through KNO₃ crystallization process flowsheet quickly identifies three opportunities each representing an increase of 12% on nominal operation. An optimal multi-variable controller has been designed for a one litre continuous recycle crystallizer to indirectly control total number and average size of crystals from secondary process measurements. The system identification is solely based on experimental findings. Linear Quadratic Gaussian method based design procedure is developed to design the controller which not only shows excellent set-point tracking capabilities but also effectively rejects disturbance in the simulated closed loop runs.
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Montenegro, Rivelino V. D. "Crystallization, biomimetics and semiconducting polymers in confined systems." Phd thesis, Universität Potsdam, 2003. http://opus.kobv.de/ubp/volltexte/2005/76/.

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populärwissenschaftlicher Abstract:
Kristallisation, Biomimetik und halbleitende Polymere in räumlich begrenzten Systemen:
Öl und Wasser mischen sich nicht, man kann aber aus beiden Flüssigkeiten Emulsionen herstellen, bei denen Tröpfchen der einen Flüssigkeit in der anderen Flüssigkeit vorliegen. Das heißt, es können entweder Öltröpfchen in Wasser oder Wassertröpfchen in Öl erzeugt werden. Aus täglichen Erfahrungen, z.B. beim Kochen weiß man jedoch, dass sich eine Emulsion durch Schütteln oder Rühren herstellen lässt, diese jedoch nicht besonders stabil ist. Mit Hilfe von hohen Scherenergien kann man nun sehr kleine, in ihrer Größe sehr einheitliche und außerdem sehr stabile Tröpfchen von 1/10000 mm erhalten. Eine solche Emulsion wird Miniemulsion genannt.
In der Dissertation wurden nun z.B. Miniemulsionen untersucht, die aus kleinen Wassertröpfchen in einem Öl bestehen. Es konnte gezeigt werden, dass das Wasser in diesen Tröpfchen, also in den räumlich begrenzten Systemen, nicht bei 0 °C, sondern bei -22 °C kristallisierte. Wie lässt sich das erklären? Wenn man einen Eimer Wasser hat, dann bildet sich normalerweise bei 0 °C Eis, da nämlich in dem Wasser einige (manchmal ganz wenige) Keime (z.B. Schutzteilchen, ein Fussel etc.) vorhanden sind, an denen sich die ersten Kristalle bilden. Wenn sich dann einmal ein Kristall gebildet hat, kann das Wasser im gesamten Eimer schnell zu Eis werden. Ultrareines Wasser würde bei -22 °C kristallisieren. Wenn man jetzt die Menge Wasser aus dem Eimer in kleine Tröpfchen bringt, dann hat man eine sehr, sehr große Zahl, nämlich 1017 Tröpfchen, in einem Liter Emulsion vorliegen. Die wenigen Schmutzpartikel verteilen auf sehr wenige Tröpfchen, die anderen Tröpfchen sind ultrarein. Daher kristallisieren sie erst bei -22 °C.

Im Rahmen der Arbeit konnte auch gezeigt werden, dass die Miniemulsionen genutzt werden können, um kleine Gelatine-Partikel, also Nanogummibärchen, herzustellen. Diese Nanogummibärchen quellen bei Erhöhung der Temperatur auf ca. 38 °C an. Das kann ausgenutzt werden, um zum Beispiel Medikamente zunächst in den Partikeln im menschlichen Körper zu transportieren, die Medikamente werden dann an einer gewünschten Stelle freigelassen. In der Arbeit wurde auch gezeigt, dass die Gelatine-Partikel genutzt werden können, um die Natur nachzuahnen (Biomimetik). Innerhalb der Partikel kann nämlich gezielt Knochenmaterial aufgebaut werden kann. Die Gelatine-Knochen-Partikel können dazu genutzt werden, um schwer heilende oder komplizierte Knochenbrüche zu beheben. Gelatine wird nämlich nach einigen Tagen abgebaut, das Knochenmaterial kann in den Knochen eingebaut werden.

LEDs werden heute bereits vielfältig verwendet. LEDs bestehen aus Halbleitern, wie z.B. Silizium. Neuerdings werden dazu auch halbleitende Polymere eingesetzt. Das große Problem bei diesen Materialien ist, dass sie aus Lösungsmitteln aufgebracht werden. Im Rahmen der Doktorarbeit wurde gezeigt, dass der Prozess der Miniemulsionen genutzt werden kann, um umweltfreundlich diese LEDs herzustellen. Man stellt dazu nun wässrige Dispersionen mit den Polymerpartikeln her. Damit hat man nicht nur das Lösungsmittel vermieden, das hat nun noch einen weiteren Vorteil: man kann nämlich diese Dispersion auf sehr einfache Art verdrucken, im einfachsten Fall verwendet man einfach einen handelsüblichen Tintenstrahldrucker.
The colloidal systems are present everywhere in many varieties such as emulsions (liquid droplets dispersed in liquid), aerosols (liquid dispersed in gas), foam (gas in liquid), etc. Among several new methods for the preparation of colloids, the so-called miniemulsion technique has been shown to be one of the most promising. Miniemulsions are defined as stable emulsions consisting of droplets with a size of 50-500 nm by shearing a system containing oil, water, a surfactant, and a highly water insoluble compound, the so-called hydrophobe

1. In the first part of this work, dynamic crystallization and melting experiments are described which were performed in small, stable and narrowly distributed nanodroplets (confined systems) of miniemulsions. Both regular and inverse systems were examined, characterizing, first, the crystallization of hexadecane, secondly, the crystallization of ice. It was shown for both cases that the temperature of crystallization in such droplets is significantly decreased (or the required undercooling is increased) as compared to the bulk material. This was attributed to a very effective suppression of heterogeneous nucleation. It was also found that the required undercooling depends on the nanodroplet size: with decreasing droplet size the undercooling increases.

2. It is shown that the temperature of crystallization of other n-alkanes in nanodroplets is also significantly decreased as compared to the bulk material due to a very effective suppression of heterogeneous nucleation. A very different behavior was detected between odd and even alkanes. In even alkanes, the confinement in small droplets changes the crystal structure from a triclinic (as seen in bulk) to an orthorhombic structure, which is attributed to finite size effects inside the droplets. An intermediate metastable rotator phase is of less relevance for the miniemulsion droplets than in the bulk. For odd alkanes, only a strong temperature shift compared to the bulk system is observed, but no structure change. A triclinic structure is formed both in bulk and in miniemulsion droplets.

3. In the next part of the thesis it is shown how miniemulsions could be successfully applied in the development of materials with potential application in pharmaceutical and medical fields. The production of cross-linked gelatin nanoparticles is feasible. Starting from an inverse miniemulsion, the softness of the particles can be controlled by varying the initial concentration, amount of cross-link agent, time of cross-linking, among other parameters. Such particles show a thermo-reversible effect, e.g. the particles swell in water above 37 °C and shrink below this temperature. Above 37 °C the chains loose the physical cross-linking, however the particles do not loose their integrity, because of the chemical cross-linking. Those particles have potential use as drug carriers, since gelatin is a natural polymer derived from collagen.

4. The cross-linked gelatin nanoparticles have been used for the biomineralization of hydroxyapatite (HAP), a biomineral, which is the major constituent of our bones. The biomineralization of HAP crystals within the gelatin nanoparticles results in a hybrid material, which has potential use as a bone repair material.

5. In the last part of this work we have shown that layers of conjugated semiconducting polymers can be deposited from aqueous dispersion prepared by the miniemulsion process. Dispersions of particles of different conjugated semiconducting polymers such as a ladder-type poly(para-phenylene) and several soluble derivatives of polyfluorene could be prepared with well-controlled particle sizes ranging between 70 - 250 nm. Layers of polymer blends were prepared with controlled lateral dimensions of phase separation on sub-micrometer scales, utilizing either a mixture of single component nanoparticles or nanoparticles containing two polymers. From the results of energy transfer it is demonstrated that blending two polymers in the same particle leads to a higher efficiency due to the better contact between the polymers. Such an effect is of great interest for the fabrication of opto-electronic devices such as light emitting diodes with nanometer size emitting points and solar cells comprising of blends of electron donating and electron accepting polymers.
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Succaw, Gary Lee. "Dynamics of crystal growth of self-assembling systems /." view abstract or download file of text, 2004. http://wwwlib.umi.com/cr/uoregon/fullcit?p3136448.

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Thesis (Ph. D.)--University of Oregon, 2004.
Typescript. Includes vita and abstract. Includes bibliographical references (leaves 209-215). Also available for download via the World Wide Web; free to University of Oregon users.
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Sultana, Mahmooda. "Microfluidic systems for continuous crystallization of small organic molecules." Thesis, Massachusetts Institute of Technology, 2010. http://hdl.handle.net/1721.1/59879.

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Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Chemical Engineering, 2010.
Cataloged from PDF version of thesis.
Includes bibliographical references.
This thesis presents one of the first demonstrations of continuous crystallization in microfluidic devices, and illustrates their use for various applications related to crystallization of small organic molecules. Crystallization is an important process in a number of industries, including specialty chemicals, food, cosmetics, nutraceuticals and, most importantly, pharmaceuticals. Most small molecule pharmaceuticals are isolated in crystalline form, and more than ninety percent of all pharmaceutical products are formulated in particulate, mainly crystalline form. However, crystallization is not a completely understood process. The sensitivity of the process to synthesis conditions gives rise to serious reproducibility issues. The traditional batch crystallizers suffer from non-uniform process conditions across the reactor, and chaotic, poorly controlled mixing of the reagents, often resulting in polydisperse crystal size distribution and impure polymorphs. This makes it difficult to obtain reliable information on the process kinetics that can be used for scale-up, as well as to study the fundamentals of the process. Microfluidic systems offer a unique toolset for crystallization because of well-defined laminar flow profiles, enhanced heat and mass transfer, better control over the contact mode of the reagents, and optical access for in situ characterization. The better control over the synthesis conditions gives rise to the potential for controlling the crystal size, as well as the polymorphic form. In addition, low consumption of reagents makes it an attractive research tool for expensive pharmaceutical compounds. Some of the advantages of microfluidics have been demonstrated for crystallization in micro-batches, but so far not in continuous devices. Continuous crystallization is difficult to achieve in microchannels as uncontrolled nucleation, crystal growth, agglomeration and sedimentation of crystals easily clog the small channels. The interaction of crystals with channel walls may also contribute to channel plugging in these devices. This thesis has developed microfluidic devices for continuous crystallization of small organic molecules for the first time. We have decoupled nucleation and growth, the two key steps of crystallization, using reaction engineering principles, and have developed two separate continuous devices, one for each of these two processes. We have used seeded crystallization and reactor design to achieve controlled growth, as well as to suppress secondary nucleation, agglomeration and sedimentation of crystals. In addition, we have eliminated any significant interaction of crystals with channel walls by controlling the properties of channel surfaces. We have also integrated microscopy and spectroscopy tools with the device for in-situ characterization of crystal size and polymorphic form. We have illustrated the use of these devices to extract growth kinetics data for crystals of various shapes, including high aspect ratio systems such as that with acicular or plate-like habits. The reproducibility and control in our devices have allowed us to elucidate the growth mechanism and fundamentals of the growth process for difficult crystal systems. In addition, we have demonstrated that continuous microfluidic devices offer a unique advantage over the current state-of-the art technology to measure the size, size distribution and growth kinetics of high aspect ratio crystal systems more accurately. Moreover, we have demonstrated the use of microfluidic devices for understanding crystal habit modification in the presence of impurities. We take advantage of the high spatiotemporal resolution of microfluidic devices to study the evolution of crystal habit over time, and to obtain information on the kinetics of habit modification in the presence of different impurities. We have developed an understanding of the habit modification mechanism for alpha glycine in the presence of alpha amino acids. Such information may not only provide insights into impurity-crystal interactions, but also serve as a powerful tool for the design of impurities that can be deliberately added to improve the crystallization process. Furthermore, we have designed and developed a second microfluidic device for continuous supercritical crystallization for the first time. Using supercritical fluid as an antisolvent, we have demonstrated continuous spontaneous nucleation of acetaminophen. We have shown the ability to produce micron-sized crystals, which may be useful for increasing the bioavailability of drugs with lower solubility, as well as for inhalable and highly potent drugs with stringent size requirements. The developed platform can also be used as a high-throughput device for safely screening crystallization conditions in the supercritical domain. We have demonstrated such use by screening the effects of pressure and various solvents on the habit, size and polymorphic form of acetaminophen crystals.
by Mahmooda Sultana.
Ph.D.
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Chavez, Krystle J. "Crystallization of pseudopolymorphic forms of sodium naproxen in mixed solvent systems." Diss., Atlanta, Ga. : Georgia Institute of Technology, 2009. http://hdl.handle.net/1853/29759.

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Thesis (Ph.D)--Chemical Engineering, Georgia Institute of Technology, 2009.
Committee Chair: Rousseau, Ronald; Committee Member: Meredith, Carson; Committee Member: Prausnitz, Mark; Committee Member: Teja, Amyn; Committee Member: Wilkinson, Angus. Part of the SMARTech Electronic Thesis and Dissertation Collection.
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Antonello, Alice [Verfasser]. "Crystallization of complex inorganic systems within the confinement of miniemulsion droplets / Alice Antonello." Mainz : Universitätsbibliothek Mainz, 2017. http://d-nb.info/1136638776/34.

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Shank, Dale. "Evaluating carbon dioxide as a causative agent of otolith crystallization in recirculating aquaculture systems." Bowling Green State University / OhioLINK, 2020. http://rave.ohiolink.edu/etdc/view?acc_num=bgsu1603716784275007.

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Böbel, Alexander [Verfasser], and Gregor [Akademischer Betreuer] Morfill. "Crystallization and demixing: morphological structure analysis in many-body systems / Alexander Böbel ; Betreuer: Gregor Morfill." München : Universitätsbibliothek der Ludwig-Maximilians-Universität, 2018. http://d-nb.info/1173616233/34.

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Carr, Joel Matthew. "CONFINED LAYERED POLYMERIC SYSTEMS FOR PACKAGING ANDCAPACITOR APPLICATIONS." Case Western Reserve University School of Graduate Studies / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=case1363104386.

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Books on the topic "Crystallization systems"

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Crystallization process systems. Oxford: Butterworth-Heinemann, 2002.

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Born, Philip G. Crystallization of Nanoscaled Colloids. Heidelberg: Springer International Publishing, 2013.

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Farrow, Robin F. C. Magnetism and structure in systems of reduced dimension. Boston, MA: Springer, 1993.

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The crystallization of the Arab state system, 1945-1954. Syracuse: Syracuse University Press, 1993.

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Vargin, V. V., ed. Catalyzed Controlled Crystallization of Glasses in the Lithium Aluminosilicate System / Katalizirovannaya Reguliruemaya Kristallizatsiya Stekol Litievoalyumosilikatnoi Sistemy / Катализированная Регулируемая Кристаллизация Стекол Литиеволюмосиликатной Системы. Boston, MA: Springer US, 1995. http://dx.doi.org/10.1007/978-1-4899-4908-0.

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J, Kelly M. Low-dimensional semiconductors: Materials, physics, technology, devices. Oxford: Clarendon Press, 1995.

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Jones, Alan G. Crystallization Process Systems. Elsevier Science & Technology Books, 2015.

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Jones, Alan G. Crystallization Process Systems. Elsevier Science & Technology Books, 2002.

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Thomas, Sabu, Nandakumar Kalarikkal, P. Mohammed Arif, and E. Bhoje Gowd. Crystallization in Multiphase Polymer Systems. Elsevier Science & Technology Books, 2017.

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Crystallization in Multiphase Polymer Systems. Elsevier, 2018. http://dx.doi.org/10.1016/c2015-0-04665-2.

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Book chapters on the topic "Crystallization systems"

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Hilfiker, Rolf. "Polymorphism of Crystalline Systems." In Crystallization, 85–103. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2013. http://dx.doi.org/10.1002/9783527650323.ch5.

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Cimmino, S., E. Pace, E. Martuscelli, and C. Silvestre. "Crystallization of Multicomponent Polymer Systems." In Crystallization of Polymers, 381–402. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1950-4_35.

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de Jeu, Wim H. "Lamellar Ethylene Oxide-Butadiene Block Copolymer Films as Model Systems for Confined Crystallisation." In Polymer Crystallization, 196–207. Berlin, Heidelberg: Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/3-540-45851-4_11.

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Abbas, Ali, Jose Romagnoli, and David Widenski. "Modeling of Crystallization Processes." In Process Systems Engineering, 239–85. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2014. http://dx.doi.org/10.1002/9783527631209.ch68.

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Abbas, Ali, Jose Romagnoli, and David Widenski. "Modeling of Crystallization Processes." In Process Systems Engineering, 239–85. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527631339.ch8.

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Varga, Jozsef. "β-Modification of Polypropylene and Its Two-Component Systems." In Crystallization of Polymers, 599–608. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-011-1950-4_63.

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Müller, Alejandro J., Maria Luisa Arnal, and Arnaldo T. Lorenzo. "Crystallization in Nano-Confined Polymeric Systems." In Handbook of Polymer Crystallization, 347–78. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118541838.ch12.

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Hoyer, Walter, Ivan Kaban, and Markus Merkwitz. "Liquid-Liquid Interfacial Tension and Wetting in Immiscible Al-Based Systems." In Solidification and Crystallization, 110–18. Weinheim, FRG: Wiley-VCH Verlag GmbH & Co. KGaA, 2005. http://dx.doi.org/10.1002/3527603506.ch13.

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Bayés-García, Laura, Teresa Calvet, and Miquel À. Cuevas-Diarte. "Effects of Dynamic Temperature Variations on Microstructure and Polymorphic Behavior of Lipid Systems." In Crystallization of Lipids, 183–210. Chichester, UK: John Wiley & Sons, Ltd, 2018. http://dx.doi.org/10.1002/9781118593882.ch6.

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Azizi Topkanlo, Hasan, Zahed Ahamadi, and Faramarz Afshar Taromi. "PET/PLA Blends Crystallization Kinetics." In Eco-friendly and Smart Polymer Systems, 682–85. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-45085-4_164.

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Conference papers on the topic "Crystallization systems"

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Knowles, David, and Brian Klene. "Laser Crystallization for Flat Panel Displays." In Photonic Applications Systems Technologies Conference. Washington, D.C.: OSA, 2006. http://dx.doi.org/10.1364/phast.2006.ptub1.

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Bray, Terry, Deborah Powell, Larry Kim, Rita Gray, Tam Le, Raymond Askew, Michael Harrington, William Rosenblum, W. Wilson, and Lawrence DeLucas. "New crystallization systems envisioned for microgravity studies." In Space Programs and Technologies Conference. Reston, Virigina: American Institute of Aeronautics and Astronautics, 1995. http://dx.doi.org/10.2514/6.1995-3582.

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Richard, Patrick, Annie Gervois, Luc Oger, and Jean-Paul Troadec. "Crystallization in hard sphere systems: A structural analysis." In PHYSICS OF GLASSES. ASCE, 1999. http://dx.doi.org/10.1063/1.1301469.

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Putis, Sergey, Andrey Mershin, Sergey Dushenok, Aleksandr Krasnov, and Tat’yana Vidyaeva. "A NEW METHOD OF CRYSTALLIZATION OF HNIW." In Chemistry of nitro compounds and related nitrogen-oxygen systems. LLC MAKS Press, 2019. http://dx.doi.org/10.29003/m795.aks-2019/375-377.

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Tao Xu, Prasanna Thwar, Vijay Srinivasan, Vamsee K. Pamula, and Krishnendu Chakrabarty. "Digital microfluidic biochip design for protein crystallization." In 2007 IEEE/NIH Life Science Systems and Applications Workshop. IEEE, 2007. http://dx.doi.org/10.1109/lssa.2007.4400904.

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Maeno, Yoshiharu, and Yukio Ohsawa. "Stable Deterministic Crystallization for Discovering Hidden Hubs." In 2006 IEEE International Conference on Systems, Man and Cybernetics. IEEE, 2006. http://dx.doi.org/10.1109/icsmc.2006.384911.

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Hsu, Y. W., C. H. Chen, and S. K. Fan. "Programmable protein crystallization in metered encapsulated droplets." In 2012 IEEE 25th International Conference on Micro Electro Mechanical Systems (MEMS). IEEE, 2012. http://dx.doi.org/10.1109/memsys.2012.6170197.

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Suarez, Luis Alberto Paz, Petia Georgieva, and Sebastião Feyo de Azevedo. "Intelligent Predictive Control - Application to Scheduled Crystallization Processes." In 2009 International Conference on Adaptive and Intelligent Systems (ICAIS). IEEE, 2009. http://dx.doi.org/10.1109/icais.2009.34.

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Kawasaki, T., T. Araki, H. Tanaka, Michio Tokuyama, Irwin Oppenheim, and Hideya Nishiyama. "Link between Vitrification and Crystallization in Two Dimensional Polydisperse Colloidal Liquid." In COMPLEX SYSTEMS: 5th International Workshop on Complex Systems. AIP, 2008. http://dx.doi.org/10.1063/1.2897794.

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SOUZA, Anderson de Almeida, Leandro Seizo GLOVASKI, and Roberto Carlos de Castro SILVA. "CFD effectiveness of AUS32 crystallization prediction in SCR systems." In XXIV Simpósio Internacional de Engenharia Automotiva. São Paulo: Editora Edgard Blücher, 2016. http://dx.doi.org/10.5151/engpro-simea2016-pap85.

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Reports on the topic "Crystallization systems"

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Cullinan, Timothy Edward. Crystallization dynamics in glass-forming systems. Office of Scientific and Technical Information (OSTI), February 2016. http://dx.doi.org/10.2172/1342537.

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Neyedley, K., J. J. Hanley, Z. Zajacz, and M. Fayek. Accessory mineral thermobarometry, trace element chemistry, and stable O isotope systematics, Mooshla Intrusive Complex (MIC), Doyon-Bousquet-LaRonde mining camp, Abitibi greenstone belt, Québec. Natural Resources Canada/CMSS/Information Management, 2021. http://dx.doi.org/10.4095/328986.

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The Mooshla Intrusive Complex (MIC) is an Archean polyphase magmatic body located in the Doyon-Bousquet-LaRonde (DBL) mining camp of the Abitibi greenstone belt, Québec, that is spatially associated with numerous gold (Au)-rich VMS, epizonal 'intrusion-related' Au-Cu vein systems, and shear zone-hosted (orogenic?) Au deposits. To elucidate the P-T conditions of crystallization, and oxidation state of the MIC magmas, accessory minerals (zircon, rutile, titanite) have been characterized using a variety of analytical techniques (e.g., trace element thermobarometry). The resulting trace element and oxythermobarometric database for accessory minerals in the MIC represents the first examination of such parameters in an Archean magmatic complex in a world-class mineralized district. Mineral thermobarometry yields P-T constraints on accessory mineral crystallization consistent with the expected conditions of tonalite-trondhjemite-granite (TTG) magma genesis, well above peak metamorphic conditions in the DBL camp. Together with textural observations, and mineral trace element data, the P-T estimates reassert that the studied minerals are of magmatic origin and not a product of metamorphism. Oxygen fugacity constraints indicate that while the magmas are relatively oxidizing (as indicated by the presence of magmatic epidote, titanite, and anhydrite), zircon trace element systematics indicate that the magmas were not as oxidized as arc magmas in younger (post-Archean) porphyry environments. The data presented provides first constraints on the depth and other conditions of melt generation and crystallization of the MIC. The P-T estimates and qualitative fO2 constraints have significant implications for the overall model for formation (crystallization, emplacement) of the MIC and potentially related mineral deposits.
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Brenan, J. M., K. Woods, J. E. Mungall, and R. Weston. Origin of chromitites in the Esker Intrusive Complex, Ring of Fire Intrusive Suite, as revealed by chromite trace element chemistry and simple crystallization models. Natural Resources Canada/CMSS/Information Management, 2021. http://dx.doi.org/10.4095/328981.

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To better constrain the origin of the chromitites associated with the Esker Intrusive Complex (EIC) of the Ring of Fire Intrusive Suite (RoFIS), a total of 50 chromite-bearing samples from the Black Thor, Big Daddy, Blackbird, and Black Label chromite deposits have been analysed for major and trace elements. The samples represent three textural groups, as defined by the relative abundance of cumulate silicate phases and chromite. To provide deposit-specific partition coefficients for modeling, we also report on the results of laboratory experiments to measure olivine- and chromite-melt partitioning of V and Ga, which are two elements readily detectable in the chromites analysed. Comparison of the Cr/Cr+Al and Fe/Fe+Mg of the EIC chromites and compositions from previous experimental studies indicates overlap in Cr/Cr+Al between the natural samples and experiments done at >1400oC, but significant offset of the natural samples to higher Fe/Fe+Mg. This is interpreted to be the result of subsolidus Fe-Mg exchange between chromite and the silicate matrix. However, little change in Cr/Cr+Al from magmatic values, owing to the lack of an exchangeable reservoir for these elements. A comparison of the composition of the EIC chromites and a subset of samples from other tectonic settings reveals a strong similarity to chromites from the similarly-aged Munro Township komatiites. Partition coefficients for V and Ga are consistent with past results in that both elements are compatible in chromite (DV = 2-4; DGa ~ 3), and incompatible in olivine (DV = 0.01-0.14; DGa ~ 0.02), with values for V increasing with decreasing fO2. Simple fractional crystallization models that use these partition coefficients are developed that monitor the change in element behaviour based on the relative proportions of olivine to chromite in the crystallizing assemblage; from 'normal' cotectic proportions involving predominantly olivine, to chromite-only crystallization. Comparison of models to the natural chromite V-Ga array suggests that the overall positive correlation between these two elements is consistent with chromite formed from a Munro Township-like komatiitic magma crystallizing olivine and chromite in 'normal' cotectic proportions, with no evidence of the strong depletion in these elements expected for chromite-only crystallization. The V-Ga array can be explained if the initial magma responsible for chromite formation is slightly reduced with respect to the FMQ oxygen buffer (~FMQ- 0.5), and has assimilated up to ~20% of wall-rock banded iron formation or granodiorite. Despite the evidence for contamination, results indicate that the EIC chromitites crystallized from 'normal' cotectic proportions of olivine to chromite, and therefore no specific causative link is made between contamination and chromitite formation. Instead, the development of near- monomineralic chromite layers likely involves the preferential removal of olivine relative to chromite by physical segregation during magma flow. As suggested for some other chromitite-forming systems, the specific fluid dynamic regime during magma emplacement may therefore be responsible for crystal sorting and chromite accumulation.
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HERTING DL. FRACTIONAL CRYSTALLIZATION LABORATORY TESTING WITH INTERIM PRETREATMENT SYSTEM FEEDS. Office of Scientific and Technical Information (OSTI), September 2008. http://dx.doi.org/10.2172/938409.

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5

Neyedley, K., J. J. Hanley, P. Mercier-Langevin, and M. Fayek. Ore mineralogy, pyrite chemistry, and S isotope systematics of magmatic-hydrothermal Au mineralization associated with the Mooshla Intrusive Complex (MIC), Doyon-Bousquet-LaRonde mining camp, Abitibi greenstone belt, Québec. Natural Resources Canada/CMSS/Information Management, 2021. http://dx.doi.org/10.4095/328985.

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The Mooshla Intrusive Complex (MIC) is an Archean polyphase magmatic body located in the Doyon-Bousquet-LaRonde (DBL) mining camp of the Abitibi greenstone belt, Québec. The MIC is spatially associated with numerous gold (Au)-rich VMS, epizonal 'intrusion-related' Au-Cu vein systems, and shear zone-hosted (orogenic?) Au deposits. To elucidate genetic links between deposits and the MIC, mineralized samples from two of the epizonal 'intrusion-related' Au-Cu vein systems (Doyon and Grand Duc Au-Cu) have been characterized using a variety of analytical techniques. Preliminary results indicate gold (as electrum) from both deposits occurs relatively late in the systems as it is primarily observed along fractures in pyrite and gangue minerals. At Grand Duc gold appears to have formed syn- to post-crystallization relative to base metal sulphides (e.g. chalcopyrite, sphalerite, pyrrhotite), whereas base metal sulphides at Doyon are relatively rare. The accessory ore mineral assemblage at Doyon is relatively simple compared to Grand Duc, consisting of petzite (Ag3AuTe2), calaverite (AuTe2), and hessite (Ag2Te), while accessory ore minerals at Grand Duc are comprised of tellurobismuthite (Bi2Te3), volynskite (AgBiTe2), native Te, tsumoite (BiTe) or tetradymite (Bi2Te2S), altaite (PbTe), petzite, calaverite, and hessite. Pyrite trace element distribution maps from representative pyrite grains from Doyon and Grand Duc were collected and confirm petrographic observations that Au occurs relatively late. Pyrite from Doyon appears to have been initially trace-element poor, then became enriched in As, followed by the ore metal stage consisting of Au-Ag-Te-Bi-Pb-Cu enrichment and lastly a Co-Ni-Se(?) stage enrichment. Grand Duc pyrite is more complex with initial enrichments in Co-Se-As (Stage 1) followed by an increase in As-Co(?) concentrations (Stage 2). The ore metal stage (Stage 3) is indicated by another increase in As coupled with Au-Ag-Bi-Te-Sb-Pb-Ni-Cu-Zn-Sn-Cd-In enrichment. The final stage of pyrite growth (Stage 4) is represented by the same element assemblage as Stage 3 but at lower concentrations. Preliminary sulphur isotope data from Grand Duc indicates pyrite, pyrrhotite, and chalcopyrite all have similar delta-34S values (~1.5 � 1 permille) with no core-to-rim variations. Pyrite from Doyon has slightly higher delta-34S values (~2.5 � 1 permille) compared to Grand Duc but similarly does not show much core-to-rim variation. At Grand Duc, the occurrence of Au concentrating along the rim of pyrite grains and associated with an enrichment in As and other metals (Sb-Ag-Bi-Te) shares similarities with porphyry and epithermal deposits, and the overall metal association of Au with Te and Bi is a hallmark of other intrusion-related gold systems. The occurrence of the ore metal-rich rims on pyrite from Grand Duc could be related to fluid boiling which results in the destabilization of gold-bearing aqueous complexes. Pyrite from Doyon does not show this inferred boiling texture but shares characteristics of dissolution-reprecipitation processes, where metals in the pyrite lattice are dissolved and then reconcentrated into discrete mineral phases that commonly precipitate in voids and fractures created during pyrite dissolution.
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Mohammadi, N., D. Corrigan, A. A. Sappin, and N. Rayner. Evidence for a Neoarchean to earliest-Paleoproterozoic mantle metasomatic event prior to formation of the Mesoproterozoic-age Strange Lake REE deposit, Newfoundland and Labrador, and Quebec, Canada. Natural Resources Canada/CMSS/Information Management, 2022. http://dx.doi.org/10.4095/330866.

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A complete suite of bulk major- and trace-elements measurements combined with macroscopic/microscopic observations and mineralogy guided by scanning electron microscope-energy dispersive spectrometry (SEM-EDS) analyses were applied on Nekuashu (2.55 Ga) and Pelland (2.32 Ga) intrusions in northern Canada, near the Strange Lake rare earth elements (REE) deposit, to evaluate their magmatic evolution and possible relations to the Mesoproterozoic Strange Lake Peralkaline Complex (SLPC). These Neoarchean to earliest-Paleoproterozoic intrusions, part of the Core Zone in southeastern Churchill Province, comprise mainly hypersolvus suites, including hornblendite, gabbro, monzogabbro/monzodiorite, monzonite, syenite/augite-syenite, granodiorite, and mafic diabase/dyke. However, the linkage of the suites and their petrogenesis are poorly understood. Geochemical evidence suggests a combination of 'intra-crustal multi-stage differentiation', mainly controlled by fractional crystallization (to generate mafic to felsic suites), and 'accumulation' (to form hornblendite suite) was involved in the evolution history of this system. Our model proposes that hornblendite and mafic to felsic intrusive rocks of both intrusions share a similar basaltic parent magma, generated from melting of a hydrous metasomatized mantle source that triggered an initial REE and incompatible element enrichment that prepared the ground for the subsequent enrichment in the SLPC. Geochemical signature of the hornblendite suite is consistent with a cumulate origin and its formation during the early stages of the magma evolution, however, the remaining suites were mainly controlled by 'continued fractional crystallization' processes, producing more evolved suites: gabbronorite/hornblende-gabbro ? monzogabbro/monzodiorite ? monzonite ? syenite/augite-syenite. In this proposed model, the hydrous mantle-derived basaltic magma was partly solidified to form the mafic suites (gabbronorite/hornblende-gabbro) by early-stage plagioclase-pyroxene-amphibole fractionation in the deep crust while settling of the early crystallized hornblende (+pyroxene) led to the formation of the hornblendite cumulates. The subsequent fractionation of plagioclase, pyroxene, and amphibole from the residual melt produced the more intermediate suites of monzogabbro/monzodiorite. The evolved magma ascended upward into the shallow crust to form monzonite by K-feldspar fractionation. The residual melt then intruded at shallower depth to form syenite/augite-syenite with abundant microcline crystals. The granodiorite suite was probably generated from lower crustal melts associated with the mafic end members. Later mafic diabase/dykes were likely generated by further partial melting of the same source at depth that were injected into the other suites.
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