Relevant bibliographies by topics / Crystallization onset time

Academic literature on the topic 'Crystallization onset time'

Author: Grafiati
Published: 4 June 2021
Last updated: 2 February 2022

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Journal articles on the topic "Crystallization onset time"

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Davoodi, E., M. Hasan, S. Rana, and G. Kumar. "Effect of loading rate on crystallization of metallic glass supercooled liquids." American Journal of Physical Sciences and Applications 1, no. 3 (July 1, 2020): 18–21. http://dx.doi.org/10.15864/ajps.1303.

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Metallic glasses exhibit unique thermoplastic processing capability, which is enabled by their metastable supercooled liquid state below the crystallization temperature. The thermoplastic processing critically depends on the crystallization time (processing time window), temperature (viscosity), applied load, and strain-rate. Among these parameters, the effects of crystallization time and processing temperature have been extensively studied. However, the effects of load and loading rate have not been thoroughly investigated. In this work, we performed a systematic study of load on the supercooled liquid state of three metallic glass formers: Pt-based, Zr-based, and Pd-based. The results show that the load-response of a metallic glass supercooled liquids is strongly composition dependent. The onset temperature of crystallization decreases with increasing load in Pt-based metallic glass whereas for Zr-based and Pd-based metallic glasses the onset temperature remains unchanged. The crystallization peak time is reduced for all three metallic glasses after thermoplastic forming. The results are discussed in terms of nucleation and growth of crystallites in metallic glasses.
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Tkatch, V. I., S. V. Vasiliev, and K. A. Svyrydova. "Identification of the onset crystallization time in metallic glasses at isothermal conditions." Journal of Non-Crystalline Solids 463 (May 2017): 102–7. http://dx.doi.org/10.1016/j.jnoncrysol.2017.03.008.

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Boudjemline, Attia, David T. Clarke, Neville J. Freeman, James M. Nicholson, and Gareth R. Jones. "Early stages of protein crystallization as revealed by emerging optical waveguide technology." Journal of Applied Crystallography 41, no. 3 (April 8, 2008): 523–30. http://dx.doi.org/10.1107/s0021889808005098.

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A highly sensitive method for studying the onset of protein crystallization in real time using an optical-waveguide-based technique is reported. Dual polarization interferometry uses light from sensing and reference waveguides to produce an interference pattern, which when the sensing waveguide is immersed in a protein solution supplies information on the thickness and density of any protein adlayer on the sensing waveguide's surface. This technique provides evidence that crystallization proceedsvialarge protein aggregates but, more strikingly, shows dramatic light loss from the sensing waveguide at a very early stage during crystallization. The technique proves relatively insensitive to the crystallization of small molecules or poorly formed protein crystals and affords a method of distinguishing crystal formation from the formation of other protein aggregates or salt crystals. The experimental setup currently necessitates crystallization using the batch method, and precipitant mixing at high supersaturation is known to introduce a greater variability compared with methods such as vapour diffusion or dialysis, but first results promise to bridge the paucity of real-time methods available to distinguish the onset of protein crystallization from other forms of aggregation.
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D´Eramo, F. J., J. J. Esteban, M. Demartis, E. Aragón, J. E. Coniglio, and L. P. Pinotti. "Time lag between metamorphism and crystallization of anatectic granites (Córdoba, Argentina)." Geologica Acta 18 (November 2, 2020): 1–14. http://dx.doi.org/10.1344/geologicaacta2020.18.17.

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SHRIMP and LA-ICP-MS analyses carried out on zircons from the Río de los Sauces granite revealed their metamorphic and igneous nature. The metamorphic zircons yielded an age of 537±4.8 (2σ)Ma that probably predates the onset of the anatexis during the Pampean orogeny. By contrast, the igneous zircons yielded a younger age of 529±6 (2σ)Ma and reflected its crystallization age. These data point to a short time lag of ca. 8Myr between the High Temperature (HT) metamorphic peak and the subsequent crystallization age of the granite. Concordia age of 534±3.8 (2σ)Ma, for both types of zircon populations, can be considered as the mean age of the Pampean HT metamorphism in the Sierras de Córdoba.
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Simmance, Kerry, Wouter van Beek, and Gopinathan Sankar. "Time resolved in situ X-ray diffraction study of crystallisation processes of large pore nanoporous aluminophosphate materials." Faraday Discussions 177 (2015): 237–47. http://dx.doi.org/10.1039/c4fd00179f.

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Time resolved high-resolution X-ray powder diffraction was utilized to obtain detailed changes in the crystal structure parameters during the hydrothermal crystallization process of the nanoporous aluminophosphate AlPO-5 (AFI) structure. This in situ study offered not only the influence of metal ions on the onset of crystallization and estimation of the activation energy of the process, but also allowed us to determine in detail the changes in lattice parameters during this process. More importantly the time-resolved study clearly showed the lattice expansion in the divalent metal ions substituted system right from the on-set of crystallization process, compared to the one without any dopant ions, which suggest that an amorphous or poorly crystalline network is formed prior to crystallization that contains the large divalent ions (compared to Al(iii), the substituting element), which is in agreement with the combined XAS/XRD study reported earlier. A mechanism based on this and the earlier study is suggested.
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Misyura, S. Y., and V. S. Morozov. "Nonisothermal desorption of droplets of LiBr salt solution on a heated wall." MATEC Web of Conferences 194 (2018): 01040. http://dx.doi.org/10.1051/matecconf/201819401040.

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Nonisothermal desorption and crystallization of droplets of aqueous salts solution of H2O/LiBr were studied experimentally. A droplet was placed on a horizontal heated wall. The initial concentration of salt C0 varied within 0-53 %. The wall temperature Tw varied within 80 - 235 °C and ambient air pressure was 1 bar. It was shown that the desorption time t1 decreases sharply with increasing Tw and at Tw < 150-160 °C. The desorption time t1 is the time until the onset of crystallization. The desorption time t1 is quasi-constant at Tw > 160 °C and increases with growth in C0.
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Lednický, František, and Miroslava Muchová. "Revival of the Induction Time Concept in the Theory of Polymer Crystallization." Collection of Czechoslovak Chemical Communications 58, no. 10 (1993): 2444–50. http://dx.doi.org/10.1135/cccc19932444.

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To monitor early stages of spherulite growth, a microscopical method has been worked out based on the photometrical measurement of the intensity of depolarized light during isothermal crystallization. Application of the technique to polypropylene yields the evidence of existence of nucleation induction time which reflects the processes taking place prior to the onset of spherulite growth, viz. the formation of stable crystal nuclei. Using the method, it is possible to evaluate also systems with a dispersed phase, the interfacial relations being reflected in the induction time of the nucleation on the surface of the dispersed phase. Application to the model PP/carbon fibres system yields differing results for carbon fibres of various provenance and of various properties.
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Cai, Yan-Hua, and Yan-Hua Zhang. "The Crystallization, Melting Behavior, and Thermal Stability of Poly(L-lactic acid) Induced byN,N,N′-Tris(benzoyl) Trimesic Acid Hydrazide as an Organic Nucleating Agent." Advances in Materials Science and Engineering 2014 (2014): 1–8. http://dx.doi.org/10.1155/2014/843564.

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N,N,N′-Tris(benzoyl) trimesic acid hydrazide (TTAD), as a novel nucleating agent of poly(L-lactic acid) (PLLA), was synthesized and characterized by FT-IR and1H NMR. The crystallization, melting behavior, and thermal stability of PLLA induced by TTAD were investigated through DSC, TGA, depolarized-light intensity measurement, and so forth. The crystallization behavior indicated that the presence of TTAD accelerated the overall PLLA crystallization. Compared to neat PLLA, the crystallization onset temperature of PLLA/1%TTAD increased from 101.36°C to 125.26°C, the melt-crystallization peak temperature increased from 94.49°C to 117.56°C, crystallization enthalpy increased from 0.1023 J·g−1to 33.44 J·g−1at a cooling rate of 1°C/min from melt, and the crystallization half-time of PLLA/TTAD decreased from 2997.2 s to 108.9 s at 110°C. Moreover, the nonisothermal crystallization measurements also indicated that the crystallization peak became wider and shifted to a lower temperature with increasing cooling rate. With the presence of TTAD, the melting behavior of PLLA was affected significantly, and a double-melting peak occurred due to melting-recrystallization. Thermal stability research showed that there existed one degradation stage of PLLA and PLLA/TTAD samples, and the thermal degradation temperature of PLLA/TTAD decreased compared to neat PLLA.
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Hadinata, Chitiur, Claus Gabriel, Maximilian Ruellmann, Nhol Kao, and Hans-Martin Laun. "Correlation between the gel time and quiescent/quasi-quiescent crystallization onset time of poly(butene-1) as determined from rheological methods." Rheologica Acta 45, no. 5 (November 29, 2005): 631–39. http://dx.doi.org/10.1007/s00397-005-0017-7.

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Yan, Zhicheng, Yan Liu, Shaopeng Pan, Yihua Hu, Jing Pang, and Weimin Wang. "The Structural Evolution of Al86Ni9La5 Glassy Ribbons during Milling at Room and Cryogenic Temperatures." Materials 11, no. 10 (October 12, 2018): 1956. http://dx.doi.org/10.3390/ma11101956.

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Melt-spun metallic Al86Ni9La5 glassy ribbons solidified at different circumferential speeds (Sc) were subjected to high-energy ball milling at room and cryogenic temperatures. Crystallization induced by milling was found in the Al86Ni9La5 solidified at lower circumferential speed (Sc = 14.7 m/s), while the Al86Ni9La5 with Sc = 36.6 m/s kept amorphous. Besides, a trend of structural rejuvenation during milling process was observed, as the onset temperatures (Tx1, Tx2) and the crystallization enthalpies (ΔH1, ΔH2) first decreased and then increased along with the milling time. We explored the structural origin of crystallization by ab initio molecular dynamic simulations and found that the tricapped trigonal prism (TTP) Ni-centered clusters with a higher frequency in samples solidified at a lower cooling rate, which tend to link into medium-range orders (MROs), may promote crystallization by initiating the shear bands during milling. Based on the deformation mechanism and crush of metallic glasses, we presented a qualitative model to explain the structural rejuvenation during milling.
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Dissertations / Theses on the topic "Crystallization onset time"

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Hadinata, Chitiur, and chitiurh@yahoo com au. "Flow-induced crystallization of polybutene-1 and effect of molecular parameters." RMIT University. Civil, Environmental and Chemical Engineering, 2007. http://adt.lib.rmit.edu.au/adt/public/adt-VIT20080212.163803.

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There are two main goals of this thesis: to investigate the flow-induced crystallization behaviour of Polybutene-1 (PB-1 samples, and to study the effects of molecular parameters on the crystallization behaviour While flow-induced crystallization is not a new area in polymer research, well-defined experimental methods that allow access to high flow rate range comparable to that encountered in real processing are still lacking. Two types of flow are considered: shear and uniaxial elongational. Regarding the second aim, several molecular parameters considered are: molecular weight, molecular weight distribution, isotacticity, presence of nucleating agents, and copolymer content. For this purpose an array of PB-1 samples were used. It is found that each of these parameters can have significant effect on the crystallization behaviour. Mainly rheological methods were utilized to conduct the flow-induced crystallization experiments. Crystallization onset time is define d from the change in viscosity or other related parameters. The experiments begin with low shear rate range, to ensure that the results are comparable with literature data. In this range we encounter the quasi-quiescent onset time at very small. shear rates, which draws an interesting comparison with another physical parameter, the gel time. Beyond a critical flow rate a decrease in the onset time is seen, and a plateau-and-slope trend is evident for a curve of onset time vs. shear rate. Using a combination of three experimental methods, shear rates ranging from Q0001 - 500 s-1 are successfully achieved, and a good agreement between these methods is observed. Furthermore, a normalization procedure is introduced, which yields temperature-invariant curves for the mentioned range of shear rate. For the uniaxial elongation flow, the Elongational Viscosity Fixture (EVF) is employed, with the strain rate ranging from 0.0001 - 10 s'. A greater reduction in onset time as compared to shear (at the same shear/strain r ate) is observed, and the difference in the onset times for shear and elongation already reaches more than one decade for a flow rate of 10 5. This quantitative comparison is particularly important; since not so many data on elongation-induced crystallization are available in the literature. Finally, the thesis compares several flow induced crystallization models that can be useful as prediction tools and selects one of these models to be compared with the experimental data. A qualitative agreement is found, however, for better quantitative prediction the model still needs to be.
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Conference papers on the topic "Crystallization onset time"

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Vestel, Michael J., David S. Grummon, and Albert P. Pisano. "Crystallization of Sputtered NiTi Films." In ASME 2003 International Mechanical Engineering Congress and Exposition. ASMEDC, 2003. http://dx.doi.org/10.1115/imece2003-41216.

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Sputtered, crystalline thin films of nickel-titanium (NiTi) can display both superelastic properties and the shape memory effect, either of which may be used in films for MEMS sensors and actuators. However, direct deposition of crystalline NiTi films requires high deposition temperature and cooldown can lead to catastrophic delamination from extrinsic residual stress. To avoid delamination, especially for thick films (&gt;5 micrometers) the amorphous form of NiTi can be sputter deposited at a low temperature, patterned and etched, released, and then crystallized to develop the proper microstructure. Here we report some results from a study of the crystallization process using differential scanning calorimetry (DSC) and transmission electron microscopy (TEM). The minimum temperature for complete crystallization in a reasonable length of time was found to be about 400°C. Crystalline grains always nucleated first at the surface, rapidly grew laterally until impingement, and then continued to grow inward to form columnar grains as the parent amorphous phase was consumed. Surface roughness delayed the onset of surface nucleation. For very smooth surfaces, crystallization nucleated quickly, but after lateral impingement, growth inward was apparently more sluggish. Multiple DSC exotherms observed in some cases suggest that additional nucleation events may have occurred in the interior of the films.
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Trask, Jason, Lin Cui, Andrew J. Wagner, K. Andre Mkhoyan, and Uwe Kortshagen. "Seed-Induced Crystallization of Amorphous Silicon for the Formation of Large-Grain Poly-Crystalline Silicon." In ASME 2010 4th International Conference on Energy Sustainability. ASMEDC, 2010. http://dx.doi.org/10.1115/es2010-90443.

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A new method for reducing crystallization time of hydrogenated amorphous silicon thin films and more successfully controlling grain structure has been studied through seeding of the bulk matrix with nanocrystallites during film deposition. Films were deposited by a system in which crystallites and amorphous film were synthesized in separate RF-powered plasmas. Average crystallite size was confirmed to be 20 to 50 nm via TEM imaging. Several films with various initial crystallite population densities were produced, and their crystallization kinetics were studied via Raman spectroscopy throughout a staged annealing process. Seeded films consistently displayed a characteristic crystallization time less than the incubation time of unseeded control films. Furthermore, films with larger initial seed densities exhibited earlier crystallization onset. A separate study also was performed in which the dark conductivity was compared between films re-crystallized from various initial seed densities.
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Shi, Bohui, Yang Liu, Lin Ding, Xiaofang Lv, and Jing Gong. "Simulation of Gas-Hydrate Slurry Stratified Flow With Inward and Outward Hydrate Growth Model." In 2016 11th International Pipeline Conference. American Society of Mechanical Engineers, 2016. http://dx.doi.org/10.1115/ipc2016-64303.

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The topic of hydrate formation and blocking in offshore petroleum industry has attracted more and more attentions, which is known as one of the flow assurance issues. A new technology has been proposed to avoid the occurrence of hydrate blockage in multiphase transportation system, which is hydrate slurry flow technology, also named as cold flow technology. The low dosage hydrate inhibitor of anti-agglomerate was added into the flow systems to allow hydrate formation in the liquid phase while it prevented the aggregation of hydrate particles. Thus these particles were evacuated with the liquid phase as pseudo-fluid like slurry. In this work, an inward and outward hydrate growth shell model coupled with two phase flow hydrodynamic model was applied to investigate the characteristics of gas-hydrate slurry stratified flow. The inward and outward hydrate growth shell model considered the kinetics, mass transfer and heat transfer process of hydrate formation, which could predict the hydrate formation rate and the released heat. The two phase flow hydrodynamic model included mass, momentum and energy equations. A case for an inclined pipeline was simulated using the combined models. The results showed that once the kinetic requirements for hydrate crystallization was satisfied, hydrates would form quickly at the initial stage and then hydrate formation rate would decrease obviously due to the limitation of mass transfer and heat transfer. Meanwhile, the flow characteristics, such as the liquid holdup and pressure drop, were predicted by the model, which also provided an acceptable results about the state of hydrates (onset time of formation, formation rate, volume fraction, etc.) in multiphase system for the operation engineers in the field. The key parameters of the inward and outward hydrate growth shell model were determined by referring to the literatures. To investigate the reliability and influence of these set values on the results, a sensitivity analysis of the key parameters of the shell model was implemented. Further works should be done, such as the flow mechanism in other flow regimes as well as the influence of particle aggregation.
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