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Relevant bibliographies by topics / Coordination Polymer Synthesis

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Academic literature on the topic 'Coordination Polymer Synthesis'

Author: Grafiati

Published: 4 June 2021

Last updated: 6 September 2023

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Journal articles on the topic "Coordination Polymer Synthesis"

1

Marchenko, Roman D., Taisiya S. Sukhikh, Alexey A. Ryadun, and Andrei S. Potapov. "Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane." Molecules 26, no. 17 (September 5, 2021): 5400. http://dx.doi.org/10.3390/molecules26175400.

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Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO3]n, in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings. Layers of the coordination polymer consist of rare 18- and 30-membered {Ag2L2} and {Ag4L4} metallocycles. Cadmium(II) nitrate formed two kinds of one-dimensional coordination polymers depending on the metal-to-ligand ratio used in the synthesis. Coordination polymer [Cd(L)2(NO3)2]n was obtained in case of a 1:2 M:L ratio, while for M:L = 2:1 product {[Cd(L)(NO3)2(CH3OH)]·0.5CH3OH}n was isolated. All coordination polymers demonstrated ligand-centered emission near 450 nm upon excitation at 370 nm.

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Kadir, M. A., and Christopher J. Sumby. "Synthesis, Characterization and Crystal Structure of Coordination Polymers Developed as Anion Receptor." Solid State Phenomena 273 (April 2018): 134–39. http://dx.doi.org/10.4028/www.scientific.net/ssp.273.134.

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Reaction of diamide ligand, namelyN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide (L) with cadmium nitrate and cadmium perchlorate has given rise to the formation of two types coordination polymers. Compound (CP1-Cd) with formula molecule {[Cd (L)2(H2O)2](NO3)2·6H2O}nis a one-dimensional coordination polymer while compound (CP2-Cd), with formula molecule {[Cd (L)2(H2O)2](ClO4)2·31⁄2H2O.CH3OH}n, is a two dimensional coordination polymer. These coordination polymers were preparedviaslow evaporation methods and completely characterized by combination of solid state techniques such as Fourier Transform Infrared (FTIR) spectroscopy, elemental analysis and X-ray crystallography. This study revealed that coordination polymers derived fromN,N’-2,6-bis (4-pyridylmethyl) pyridine dicarboxamide can accommodate anions with different sizes, showing good potential as anion receptor.

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Uemura, Takashi. "Polymer Synthesis in Coordination Nanospaces." Bulletin of the Chemical Society of Japan 84, no. 11 (November 15, 2011): 1169–77. http://dx.doi.org/10.1246/bcsj.20110211.

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Gorduk, Semih, Hakan Yilmaz, and Omer Andac. "Cu(II) and Cd(II) coordination polymers derived from pyrazine-2,3-dicarboxylato and 1-vinylimidazole ligands: Synthesis, characterization and hydrogen storage capacities." Macedonian Journal of Chemistry and Chemical Engineering 38, no. 1 (May 21, 2019): 19. http://dx.doi.org/10.20450/mjcce.2019.1711.

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In this study, two new coordination polymers of Cu(II) and Cd(II) ions with pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole were synthesized. The structures of these coordination polymers were characterized with elemental analysis, infrared spectroscopy, thermal analysis, powder X-ray diffraction, and magnetic susceptibility techniques. According to the results of the thermal analysis, the coordination polymers that contained water molecules decomposed below 100 °C, and the final products for both coordination polymers were the related metal oxides in an oxygen atmosphere. Powder X-ray diffraction analysis revealed that the coordination polymers were in the crystalline form. The hydrogen storage capacities and surface areas of the coordination polymers were also determined. The highest hydrogen storage capacities were measured as 296 ml/g for the Cu(II) coordination polymer and 330 ml/g for the Cd(II) coordination polymer at approximately 75 bar and 75 K.

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Luisi, Brian S., Kevin D. Rowland, and Brian Moulton. "Coordination polymer gels: synthesis, structure and mechanical properties of amorphous coordination polymers." Chemical Communications, no. 27 (2007): 2802. http://dx.doi.org/10.1039/b703768f.

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SHOOTO, NTAOTE DAVID. "A Convenient Synthesis of Antimony Nanorods using 1,2,4,5-Benzenetetracarboxylic Acid." Asian Journal of Chemistry 31, no. 6 (April 29, 2019): 1301–4. http://dx.doi.org/10.14233/ajchem.2019.21886.

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1,2,4,5-Benzenetetracarboxylic acid (H4Btec) is an ideal candidate for the synthesis of new coordination polymers compounds because of its four carboxyl groups bridging moieties with antimony ions having distorted coordination configuration. This work reports a new compound of coordination polymer, namely, [Sb2(C4H4O6)2(Btec)(H2O)]n, [(C4H4O6)2 = tartrate and Btec4− = 1,2,4,5-benzenetetracarboxylic anion] has been synthesized under reflux. The physical and chemical properties of coordination polymers; Sb2(C4H4O6)2(Btec)(H2O) was affirmed by scanning electron microscope, Fourier transform infrared spectroscopy, X-ray powder diffraction, thermogravimetric analyses and photoluminescence spectroscopy.

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Uemura, Takashi. "Controlled Polymer Synthesis in Coordination Nanochannels." Journal of Synthetic Organic Chemistry, Japan 70, no. 4 (2012): 324–30. http://dx.doi.org/10.5059/yukigoseikyokaishi.70.324.

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Tarasenko, O. S., and E. I. Starovoitov. "Synthesis and Characterization of Metal-Organic Polymer based on Fe(III)." International Journal of Circuits, Systems and Signal Processing 15 (September 15, 2021): 1450–56. http://dx.doi.org/10.46300/9106.2021.15.157.

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In this work, a coordination polymer based on iron trinuclear acetate was synthesized. The coordination polymer was obtained in two stages. At the first stage [Fe3O(CH3CO2)6(H2O)3]·2H2O – tricyclic iron acetate was synthesized. As the dicarboxylate ligand, we chose muconic acid, which is not toxic to the body. Double bonds in its structure create additional nodes for interaction with drugs. The optimal conditions for the synthesis of a coordination polymer based on tricyclic iron acetate and muconic acid were selected: solvothermal synthesis at 78 °C, autogenous pressure and using ethanol as a solvent. The resulting coordination polymer is a nanosized mesoporous framework with a narrow pore distribution, an average radius of~1.18 nm, and a developed specific surface area of 512.1 m2/g. The composition and crystal structure of tricyclic iron acetate and a coordination polymer based on it have been confirmed by the methods of elemental and X-ray phase analysis.

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Lewis, Reece W., Nino Malic, Kei Saito, Neil R. Cameron, and Richard A. Evans. "Linear Coordination Polymer Synthesis from Bis‐Catechol Functionalized RAFT Polymers." Macromolecular Rapid Communications 41, no. 18 (August 5, 2020): 2000366. http://dx.doi.org/10.1002/marc.202000366.

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Shao, Zhi-Chao, Xiang-Ru Meng, and Hong-Wei Hou. "Two new CdII and ZnII coordination polymers incorporating 1-aminobenzene-3,4,5-tricarboxylic acid: synthesis, crystal structure and characterization." Acta Crystallographica Section C Structural Chemistry 75, no. 8 (July 5, 2019): 1065–72. http://dx.doi.org/10.1107/s2053229619009227.

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Aminobenzoic acid derivatives are widely used in the preparation of new coordination polymers since they contain O-atom donors, as well as N-atom donors, and have a rich variety of coordination modes which can lead to polymers with intriguing structures and interesting properties. Two new coordination polymers incorporating 1-aminobenzene-3,4,5-tricarboxylic acid (H3abtc), namely, poly[(μ3-1-amino-5-carboxybenzene-3,4-dicarboxylato)diaquacadmium(II)], [Cd(C9H5NO6)(H2O)2] n , (I), and poly[[bis(μ5-1-aminobenzene-3,4,5-tricarboxylato)triaquatrizinc(II)] dihydrate], {[Zn3(C9H4NO6)2(H2O)3]·2H2O} n , (II), have been prepared and structurally characterized by single-crystal X-ray diffraction. In polymer (I), each tridentate 1-amino-5-carboxybenzene-3,4-dicarboxylate (Habtc2−) ligand coordinates to three CdII ions to form a two-dimensional network structure, in which all of the CdII ions and Habtc2− ligands are equivalent, respectively. Polymer (II) also exhibits a two-dimensional network structure, in which three crystallographically independent ZnII ions are bridged by two crystallographically independent pentadentate 1-aminobenzene-3,4,5-tricarboxylate (abtc3−) ligands. This indicates that changing the metal ion can influence the coordination mode of the H3abtc-derived ligand and further influence the detailed architecture of the polymer. Moreover, the IR spectra, thermogravimetric analyses and fluorescence properties were investigated.

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Dissertations / Theses on the topic "Coordination Polymer Synthesis"

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Rummel, Ian Ammon. "Cyanometallate coordination polymer nanostructures and thin films synthesis and applications /." [Gainesville, Fla.] : University of Florida, 2009. http://purl.fcla.edu/fcla/etd/UFE0041117.

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GARAU, FEDERICA. "DESIGN, SYNTHESIS AND CHARACTERISATION OF POLYFUNCTIONAL COORDINATION POLYMERS." Doctoral thesis, Università degli studi di Padova, 2010. http://hdl.handle.net/11577/3427373.

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The research group where I performed my PhD researches is interested in the synthesis and characterisation of Coordination Polymers (CPs). CPs are infinite systems built up with metal ions (connectors) and organic ligands (linkers) as main elementary units, connected via coordination bonds and other weak interactions [Robin & Fromm, Coord. Chem. Rev., 2006, 250, 2127]. One of the interests in building CPs is the creation of new tuneable functional materials, since CPs are promising materials for applications in gas storage, anion exchange, catalysis, conductivity, luminescence, chirality, magnetism, spin transition behaviour, NLO or deposition of thin films. CPs can be normally prepared by reacting a suitable polynucleating ligand with a transition metal ion, having at least two coordination sites available. In order to obtain new CPs, during the first year of my PhD studies, two different classes of new potentially polynucleating nitrogen containing ligands were designed, synthesised and fully characterised. Unfortunately, some preliminary tests on the reactivity of these linkers with Cu(II), Ag(I), Zn(II) and Ru(II) in hydroalcoholic solvents evidenced the relatively easy hydrolysis of the ligands. For these reasons, at the moment, the study of the coordination properties of these ligands to transition metal ions has been set aside, and the attention has been focused on the understanding of the decomposition mechanism upon treatment with transition metal compounds [Casarin et al. Inorg. Chim. Acta, 2009, 362, 4358; Casarin et al. J. Phys. Chem. A, 2008, 112, 6723]. Moreover, we continued some other studies, concerning the synthesis of trinuclear triangular Cu(II) clusters. The latter can be easily prepared by reacting copper(II) carboxylates with pyrazole (Hpz) in hydroalcoholic solvents, obtaining 1D, 2D or 3D CPs [Casarin et al. Inorg. Chem., 2004, 43, 5865; Casarin et al. Inorg. Chem., 2005, 44, 6265; Di Nicola et al. Inorg. Chem., 2007, 46, 221]. Particularly, during my PhD studies some other trinuclear triangular Cu(II) clusters (starting both from saturated and unsaturated Cu(II) carboxylates) were synthesised and characterised [Di Nicola et al. Eur. J. Inorg. Chem., 2009, 666; Contaldi et al. Dalton Trans., 2009, 4928]. We started also to study the reactivity of the trinuclear triangular copper(II)/carboxylate/pyrazolate clusters towards substitution reactions. Particularly, we examined first the stability of the trinuclear triangular moiety by treating [Cu3(μ3-OH)(μ-pz)3(CH3COO)2(Hpz)], 2, with strong acids, observing that the trinuclear moiety was in a good extent maintained, and obtaining new hexanuclear and heptanuclear coordination polymers, in some cases porous [Casarin et al. Cryst. Growth Des., 2007, 4, 676]. Since the trinuclear moieties resulted to be quite stable towards decomposition, we decided to use them as starting material to synthesise new different CPs, having the trinuclear Cu(II) clusters directly bridged by polynucleating ligands. We decided to follow two different approaches: i) substitution of the monocarboxylates with bicarboxylates; and ii) replacement of the neutral ligands coordinated to the Cu(II) centres (pyrazole and/or solvent molecules) with neutral bidentate nitrogen-containing ligands. First attempts under bench-top conditions to replace the carboxylate ions by reacting the trinuclear compounds with bicarboxylic acids were not successful, leading to the isolation of the starting materials, while reactions carried out upon deprotonation of the acids led to the instantaneous precipitation of insoluble powders. The reaction with bidentate nitrogen-containing ligands gave instead interesting results, and numerous new CPs were isolated and fully characterised. Noteworthy, upon reaction between [Cu3(μ3-OH)(μ-pz)3(HCOO)2(Hpz)2(H2O)], 1, and an excess of 4,4’-bipyridine, a porous coordination polymer was obtained. The electrochemical properties of some selected copper(II) CPs isolated by us were examined; we also investigated the catalytic activities of some of these compounds in the peroxidative oxidation of cyclohexane. Both of these researches were performed in prof. Armando J. L. Pombeiro laboratories, at the Centro de Química Estrutural of the Instituto Superior Técnico (Lisbon). Finally, more recently, we started to investigate the catalytic activity of 2 in the oxidation of methyl-p-tolyl sulfide to the corresponding sulfoxide. Preliminary results indicated that 2 is able to bind reversibly oxygen coming from H2O2 and transfer it to the sulfide.
Il gruppo di ricerca presso cui ho svolto il Dottorato di Ricerca si occupa della sintesi e caratterizzazione di Polimeri di Coordinazione (CP). I CP sono dei sistemi polimerici infiniti, costruiti a partire da ioni metallici (connettori) e leganti organici (linkers) come principali unità di base, connessi tra loro attraverso legami di coordinazione e altre interazioni relativamente deboli [Robin & Fromm, Coord. Chem. Rev., 2006, 250, 2127]. Uno dei principali interessi nella costruzione di CP è l'ottenimento di nuovi materiali funzionali, dotati di proprietà modulabili; i CP, infatti, presentano potenziali applicazioni in diversi settori, quali ad esempio immagazzinamento di gas, scambio ionico, catalisi, conduttività, luminescenza, chiralità, magnetismo, ottica non lineare o deposizione di strati sottili. I CP vengono generalmente sintetizzati per “copolimerizzazione” di un opportuno legante polinucleanti con uno ione di un metallo di transizione avente almeno due siti di coordinazione disponibili. Al fine di ottenere nuovi CP, durante il primo anno del Dottorato di Ricerca sono state progettate e sintetizzate due diverse classi di nuovi leganti azotati potenzialmente polinucleanti. Test preliminari sulla reattività di questi composti con Cu(II), Ag(I), Zn(II) e Ru(II) in solventi protici hanno messo in evidenza la relativamente facile idrolisi dei leganti. Per questo motivo, lo studio delle loro proprietà coordinative a metalli di transizione è stato momentaneamente accantonato, e l’attenzione è stata focalizzata sulla comprensione del meccanismo della decomposizione in seguito al trattamento con metalli di transizione [Casarin et al. Inorg. Chim. Acta, 2009, 362, 4358; Casarin et al. J. Phys. Chem. A, 2008, 112, 6723]. E’ stato inoltre sviluppato un secondo progetto, riguardante la sintesi di cluster trinucleari triangolari di rame(II). Questi composti possono essere preparati facendo reagire carbossilati di Cu(II) con pirazolo (Hpz) in solvente protico (H2O, MeOH o EtOH). L’autoassemblaggio dei building blocks porta alla formazione di CP di diversa dimensionalità (1D, 2D o 3D) [Casarin et al. Inorg. Chem., 2004, 43, 5865; Casarin et al. Inorg. Chem., 2005, 44, 6265; Di Nicola et al. Inorg. Chem., 2007, 46, 221]. Sono stati quindi sintetizzati e caratterizzati nuovi cluster trinucleari triangolari di Cu(II) (partendo sia da carbossilati di Cu(II) saturi che insaturi) [Di Nicola et al. Eur. J. Inorg. Chem., 2009, 666; Contaldi et al. Dalton Trans., 2009, 4928]. Abbiamo inoltre esaminato la stabilità del frammento trinucleare [Cu3(μ3-OH)(μ-pz)3]2+ facendo reagire il composto [Cu3(μ3-OH)(μ-pz)3(CH3COO)2(Hpz)], 2, con diversi acidi forti. Benché in tutti i casi siano stati isolati complessi mononucleari, derivanti dalla parziale decomposizione del cluster trinucleare, la contemporanea formazione di derivati tri-, esa- ed eptanucleari, in alcuni casi porosi [Casarin et al. Cryst. Growth Des., 2007, 4, 676], ha messo in evidenza la relativa stabilità del frammento [Cu3(μ3-OH)(μ-pz)3]2+. Si è deciso quindi di utilizzare i differenti cluster trinucleari come materiale di partenza per la sintesi di nuovi CP, in cui più unità trinucleari fossero connesse tra loro tramite leganti polinucleanti. Abbiamo deciso di seguire due diversi approcci: i) sostituzione dei monocarbossilati con bicarbossilati; e ii) sostituzione dei leganti neutri coordinati ai centri di Cu(II) (pirazolo e/o molecole di solvente) con leganti azotati neutri bidentati. I primi tentativi in condizioni bench-top di sostituire gli ioni carbossilato facendo reagire i composti trinucleari con acidi bicarbossilici non hanno avuto successo, portando all’isolamento dei composti di partenza, mentre le reazioni condotte utilizzando i bicarbossilati hanno portato all’istantanea precipitazione di polveri insolubili. Le reazioni con leganti azotati neutri bidentati hanno invece portato all’ottenimento di risultati interessanti; infatti, sono stati isolati e caratterizzati numerosi nuovi CP. In particolare, dalla reazione di [Cu3(μ3-OH)(μ-pz)3(HCOO)2(Hpz)2(H2O)], 1, con un largo eccesso di 4,4’-bipiridina, è stato isolato un polimero di coordinazione poroso. Infine, sono state esaminate sia le proprietà elettrochimiche di alcuni CP di rame(II) da noi isolati che l’attività catalitica di alcuni di questi composti nella reazione di ossidazione perossidativa del cicloesano. Entrambi questi studi sono stati condotti nei laboratori del prof. Armando J. L. Pombeiro, presso il Centro de Química Estrutural dell’Instituto Superior Técnico (Lisbona). Più recentemente, abbiamo iniziato a studiare l’attività catalitica di 2 nell’ossidazione del metil-p-tolil solfuro al corrispondente solfossido. Risultati preliminari indicano che 2 è in grado di legare in modo reversibile l’ossigeno proveniente da H2O2 e di trasferirlo al solfuro.

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Knichal, Jane. "Design, synthesis and characterisation of advanced switchable functional materials." Thesis, University of Bath, 2017. https://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.760896.

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Choi, Ming Fai. "Design and synthesis of coordination polymer gels and high dichroic ratio azo dyes /." View Abstract or Full-Text, 2002. http://library.ust.hk/cgi/db/thesis.pl?CHEM%202002%20CHOI.

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Akiyama, George. "Studies on Synthesis and Application of Water Durable Porous Coordination Polymers." 京都大学 (Kyoto University), 2015. http://hdl.handle.net/2433/198948.

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Konkol, Kristine Louise. "Synthesis and Design of Thiophene Materials: Effects of Ring Fusion and Metal Coordination." Diss., North Dakota State University, 2019. https://hdl.handle.net/10365/31608.

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Conjugated organic materials comprise a field of materials chemistry focused on the development of semiconducting organic plastics, popular applications of which are plastic solar cells and display technologies. One of the reasons these materials have gained so much attention is that their optical and electronic properties can be tuned through engineering at the molecular level. Thiophene, an aromatic heterocycle, is a popular building block in the synthesis of many conjugated materials, prized for both the ease in which it can be synthetically functionalized and its ability to form highly conductive and low band gap materials. The Rasmussen group has previously reported on the generation of two classes of materials, the inorganic metal thiophenedithiolenes and the fused-ring heterocycle unit thieno[3,4-b]pyrazine (TP), both of which have applications in conducting materials. In an effort to expand upon the applicability and versatility of these materials, a series of interconnected projects were performed to further tune their optical, electronic, and physical (e.g. solubility) properties. This involved synthetic molecular design, including judicious consideration of structure-function relationships, and characterization of the resulting materials. Highlights include a sterics vs. electronics consideration of the catalyzed hydrodebromination of the molecular building-block 2,3,5-tribromothiophene, variation of the coordinating metal in thiophenedithiolenes to tune the optics and electronics, and characterization of the effects of ring-fusion on TP-based terthienyl homopolymers. Additionally, a new application of the TP monomer was found, whereby it was successfully incorporated as a bridging ligand into a multi-metallic Ru(II) supramolecular assembly, which demonstrated good metal-metal communication.

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Ritch, Grayson D. "Synthesis, Characterization, and Reactivity of Novel Zinc Coordination Complexes." Kent State University Honors College / OhioLINK, 2014. http://rave.ohiolink.edu/etdc/view?acc_num=ksuhonors1399675758.

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Wojtecki, Rudy James. "Toward the Design and Synthesis of Mechanically Interlocked Polymers." Case Western Reserve University School of Graduate Studies / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=case1380061061.

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Itakura, Tomoya. "Synthesis and Characterization of Proton Conducting Coordination Polymers Working under Low-humidity Condition." Kyoto University, 2017. http://hdl.handle.net/2433/217993.

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Pollino, Joel Matthew. "The "Universal Polymer Backbone" concept." Diss., Available online, Georgia Institute of Technology, 2004:, 2004. http://etd.gatech.edu/theses/available/etd-11112004-143714/unrestricted/pollino%5Fjoel%5Fm%5F200412%5Fphd.pdf.pdf.

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Thesis (Ph. D.)--Chemistry and Biochemistry, Georgia Institute of Technology, 2005.
Weck, Marcus, Committee Chair ; Jones, Christopher, Committee Member ; Collard, David, Committee Member ; Liotta, Charles, Committee Member ; Bunz, Uwe, Committee Member. Includes bibliographical references.

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Books on the topic "Coordination Polymer Synthesis"

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K, Bregg Robert, ed. Current topics in polymer research. Hauppauge, N.Y: Nova Science Publishers, 2005.

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Design and construction of coordination polymers. Hoboken, N.J: Wiley, 2009.

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Organometallic and Coordination Clusters and Polymers: Syntheses And Applications Symposium (2004 London, Ont.). Organometallic and coordination clusters and polymers: Syntheses and applications : London, Ontario, Canada, May 29-June 1, 2004. Edited by Abd-El-Aziz Alaa S and Harvey Pierre Dominique 1960-. Weinheim, Ger: Wiley-VCH, 2004.

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Walder, Anthony J. Synthesis of novel ion exchange/coordination resins and the mechanistic study of ion exchange/redox dual mechanism bifunctional polymers with their application in metal ion recovery. Ann Arbor, MI: UMI Dissertation Services, 1989.

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(Editor), Alaa S. Abd-El-Aziz, and Pierre D. Harvey (Editor), eds. Organometallic and Coordination Clusters and Polymers: Synthesis and Applications (Macromolecular Symposia). Wiley-VCH, 2005.

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Book chapters on the topic "Coordination Polymer Synthesis"

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Osakada, Kohtaro, and Daisuke Takeuchi. "Coordination Polymerization of Dienes, Allenes, and Methylenecycloalkanes." In Polymer Synthesis, 137–94. Berlin, Heidelberg: Springer Berlin Heidelberg, 2004. http://dx.doi.org/10.1007/b13016.

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Soares, João B. P., and Odilia Pérez. "Coordination Polymerization." In Handbook of Polymer Synthesis, Characterization, and Processing, 85–104. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118480793.ch5.

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de Lange, Kim, Jos M. J. Paulusse, Antonius T. M. Marcelis, and Han Zuilhof. "Reversible Coordination Polymers." In Ionic Interactions in Natural and Synthetic Macromolecules, 337–59. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2012. http://dx.doi.org/10.1002/9781118165850.ch10.

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Kaes, Christian, and Mir Wais Hosseini. "Molecular Networks: An Approach to Coordination Polymers." In Supramolecular Engineering of Synthetic Metallic Materials, 53–66. Dordrecht: Springer Netherlands, 1999. http://dx.doi.org/10.1007/978-94-011-5280-8_4.

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Costantino, Ferdinando, Andrea Ienco, and Marco Taddei. "The Influence of Non-covalent Interactions in the Structure and Dimensionality of Hybrid Compounds and Coordination Polymers." In Non-covalent Interactions in the Synthesis and Design of New Compounds, 163–84. Hoboken, NJ: John Wiley & Sons, Inc, 2016. http://dx.doi.org/10.1002/9781119113874.ch9.

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Friščić, Tomislav. "Toward Mechanochemical Synthesis of Metal-Organic Frameworks: From Coordination Polymers and Lattice Inclusion Compounds to Porous Materials." In Metal-Organic Frameworks, 267–99. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2010. http://dx.doi.org/10.1002/9780470606858.ch9.

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Visseaux, Marc, Thomas Chenal, and Philippe Zinck. "Coordinative Chain Transfer Polymerization and Copolymerization by Means of Rare Earth Organometallic Catalysts for the Synthesis of Tailor-Made Polymers." In Advances in Organometallic Chemistry and Catalysis, 343–58. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2013. http://dx.doi.org/10.1002/9781118742952.ch27.

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"Design of Stimuli-responsive Macromolecular Blocks." In Stimuli-Responsive Materials: From Molecules to Nature Mimicking Materials Design, 18–54. The Royal Society of Chemistry, 2016. http://dx.doi.org/10.1039/bk9781849736565-00018.

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This chapter covers fundamental concepts in polymer synthesis, with the focus on controllable synthesis of stimuli-responsive polymers. The first sections introduce the basic concepts of molecular weight and molecular weight definitions. Various polymer architectures are introduced, with an ultimate goal of being able to synthesize sometimes very challenging synthetic steps. The following polymerizations are discussed: chain and step growth, statistical radical, cationic and anionic, coordination, ring opening, ring-opening metathesis polymerization, and controlled radical polymerization, which is represented by nitroxy-mediated polymerization, atom transfer radical polymerization, and reversible addition-fragmentation chain transfer.

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Walton, David J., and Fred J. Davis. "The synthesis of conducting polymers based on heterocyclic compounds." In Polymer Chemistry. Oxford University Press, 2004. http://dx.doi.org/10.1093/oso/9780198503095.003.0011.

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Polymers are best known for their effectiveness as electrical insulators, indeed electrical wiring throughout the world is now sheathed in plastic. However, it was recognized early on that polymers with an appropriate structure ought to be able to conduct electricity. Unfortunately, the same features that might allow this phenomenon also introduce intractability and processing difficulties. As a consequence, it was not until the mid-1970s that the potential of these materials was explored and better-defined materials started to be made. There are now numerous polymers with substantial electrical conductivities and the topic of electrically conducting polymers still continues to excite with many hundreds of new publications printed each year. The backbone structures of some of conjugated polymers are given in Table 6.1. In this chapter we shall deal with electrochemical and chemical syntheses of some relatively simple examples. For electrical conductivity, it is necessary to transfer charge along a conjugated chain, between chains, and also along grain boundaries or between particles. The most energetically difficult process will control the rate of charge transport and this will vary with nature of the polymer, its physical form, and other parameters, but in all cases conjugation along the chain is necessary although it is not sufficient for carbonaceous polymers to simply possess a conjugated chain. To promote conductivity π-overlap along the entire polymer chain length is required to give a half-filled band of delocalized π -electrons. In real systems, distortions of the bonds disrupt the conjugation, and the materials are generally semiconductors. The higher metallic conduction can be achieved by a process known as doping in which electrons are added or more generally removed from the conjugated system (although this is not same as the doping process found in semiconductor technology) The simplest conjugated polymer chain is a polyacetylene chain. Such materials can be prepared by coordination polymerization, or using a sophisticated route involving the degradation of a soluble precursor polymer.

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Dembaremba, Tendai O., Adeniyi S. Ogunlaja, and Zenixole R. Tshentu. "Coordination Polymers and Polymer Nanofibers for Effective Adsorptive Desulfurization." In Research Anthology on Synthesis, Characterization, and Applications of Nanomaterials, 730–83. IGI Global, 2021. http://dx.doi.org/10.4018/978-1-7998-8591-7.ch032.

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Desulfurization of fuel oils is an essential process employed in petroleum refineries to reduce the sulfur content to levels mandated for environmental protection. Hydrodesulfurization (HDS), which is currently being employed, is limited in treating refractory organosulfur compounds and only reduces the sulfur content in fuels to a range of 200-500 ppmS. In this chapter, several scientific and technological advances reported in the literature for the desulfurization of fuels are reviewed and discussed. Amongst these techniques, oxidative desulfurization (ODS) and adsorptive desulfurization (ADS) are proposed as additional steps to complement HDS in meeting the mandated ultra-low sulfur levels (10 ppmS). In the ODS technique, refractory organosulfur compounds are oxidized to organosulfones, followed by solvent extraction or adsorption of the organosulfones. The chemistry involved in the development and fabrication of sulfur/sulfone responsive adsorbents is also discussed. The use of molecular imprinted polymers (MIPs) and coordination polymers (CPs) for the selective adsorption of organosulfone compounds (in ODS) and/or organosulfur (in ADS) offers various properties such as imprinting effect, hydrogen bonding, π-π interactions, van der Waals forces, π-complexation, and electrostatic interactions. CPs, in particular metal organic frameworks (MOFs), have been reported to possess suitable features to overcome most of these challenges associated with adsorptive ultra-deep desulfurization when design strategies to achieve good selectivity are strictly followed. Matching the sizes of the cavities to the critical dimensions of the sulfur containing compounds (SCCs), using suitable metal centres which allow for coordinative interaction with the SCCs and using linkers with suitable functionality as to enhance specific interaction (dispersion forces) with the SCCs were considered to be pivotal features to prioritize. The prospects for the use of MIPs and CPs for future industrial applications in desulfurization are envisaged.

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Conference papers on the topic "Coordination Polymer Synthesis"

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Misran, Halina, A. M. Aminuddin, F. A. M. Zini, M. J. Ghazali, S. Ramesh, Francisco Chinesta, Yvan Chastel, and Mohamed El Mansori. "Facile Synthesis and Characterizations of MOF-5 Coordination Polymer with Various Metal Linker Ratios for Ammonia Gas Storage." In INTERNATIONAL CONFERENCE ON ADVANCES IN MATERIALS AND PROCESSING TECHNOLOGIES (AMPT2010). AIP, 2011. http://dx.doi.org/10.1063/1.3552454.

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Xiao, Fengping, and Peng Hu. "Synthesis, characterization, magnetic properties of cobalt coordination polymer based on 4,4'-Oxybisbenzoic acid and 1,4-bis(pyrid-4-yl)benzene." In 2017 International Conference on Material Science, Energy and Environmental Engineering (MSEEE 2017). Paris, France: Atlantis Press, 2017. http://dx.doi.org/10.2991/mseee-17.2017.81.

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Luo, Ya-Nan, Zhi-Chen Liu, Hui-Ying Jiang, Li-Ying Yu, and Xiao-Yang Yu. "A NEW NICKEL COORDINATION POLYMER CONSTRUCTED FROM 4-[(8-HYDROX -Y 5-QUINOLINYL) AZO]-BENZENESULFONIC ACID: SYNTHESIS, STRUCTURE AND PROPERTY." In International Conference on New Materials and Intelligent Manufacturing (ICNMIM). Volkson Press, 2018. http://dx.doi.org/10.26480/icnmim.01.2018.323.325.

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Bet, Fernanda, and Joel Dias da Silva. "Biodegradable composites of cassava starch and agro-industrial by-products: a review." In ENSUS2023 - XI Encontro de Sustentabilidade em Projeto. Grupo de Pesquisa Virtuhab/UFSC, 2023. http://dx.doi.org/10.29183/2596-237x.ensus2023.v11.n4.p85-96.

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The environmental concern with the use of synthetic polymers, above all, used in single-use packaging such as expanded polystyrene (EPS), is related to the use of non-renewable resources and, it is accentuated, with the prolonged decomposition time of this material in the environment. Cassava starch, a renewable and biodegradable polymer, offer a partial solution to the problem. Therefore, the objective of this work was to gather publications in natural polymers and to discuss the similarities and differences between these studies. The method of systematic literature review proposed by Conforto, Amaral and da Silva (2011) was used. The database used was the CAPES Journal Portal (Coordination for the Improvement of Higher Education Personnel).

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Fuylani, A., M. V. Russo, G. Polzonetti, and M. Cuccu. "/spl pi/-conjugated organometallic polymers based on Pd(II) coordination sites." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.835255.

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Ok-Sanz Jung, Young-A Lee, and C. G. Pierpont. "Bistability, low energy electron transter, and photomechanics: diimlne-bridged cobalt semiquinonate-catecholate coordination polymer." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.834778.

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Qin, Yan, Yu Xiao, Pu Huang, Yun Zhu, and Ming Yi. "The Research Progress on the Synthesis and Application of Microporous Coordination Polymers." In 2015 International Symposium on Material, Energy and Environment Engineering. Paris, France: Atlantis Press, 2015. http://dx.doi.org/10.2991/ism3e-15.2015.2.

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Bader, Mamoun M., and Phuong-Truc T. Pham. "Synthesis and characterization of some new coordination polymers for third-order nonlinear optical applications." In SPIE's International Symposium on Optical Science, Engineering, and Instrumentation, edited by Manfred Eich and Mark G. Kuzyk. SPIE, 1999. http://dx.doi.org/10.1117/12.368273.

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Sadeghzadeh, Homa, and Ali Morsali. "Syntheses and characterization of a new nano-structure lead (II) coordination polymer by sonochemical method." In 2010 International Conference on Enabling Science and Nanotechnology (ESciNano). IEEE, 2010. http://dx.doi.org/10.1109/escinano.2010.5701073.

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Kawata, S., S. Kitagawa, M. Kondo, and M. Katada. "Fabrication of infinite two- and three-dimensional copper coordination polymers of chloranilic acid and its derivatives. crystal structures and magnetic properties." In International Conference on Science and Technology of Synthetic Metals. IEEE, 1994. http://dx.doi.org/10.1109/stsm.1994.834727.

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