Academic literature on the topic 'Conjugated organic polymers'

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Journal articles on the topic "Conjugated organic polymers"

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Xiong, Miao, Jie-Yu Wang, and Jian Pei. "Controlling the Film Microstructure in Organic Thermoelectrics." Organic Materials 03, no. 01 (January 2021): 001–16. http://dx.doi.org/10.1055/s-0040-1722305.

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Doping is a vital method to increase the charge carrier concentration of conjugated polymers, thus improving the performance of organic electronic devices. However, the introduction of dopants may cause phase separation. The miscibility of dopants and polymers as well as the doping-induced microstructure change are always the barriers in the way to further enhance the thermoelectrical performance. Here, recent research studies about the influence of molecular doping on the microstructures of conjugated polymers are summarized, with an emphasis on the n-type doping. Highlighted topics include how to control the distribution and density of dopants within the conjugated polymers by modulating the polymer structure, dopant structure, and solution-processing method. The strong Coulombic interactions between dopants and polymers as well as the heterogeneous doping process of polymers can hinder the polymer film to achieve better miscibility of dopants/polymer and further loading of the charge carriers. Recent developments and breakthroughs provide guidance to control the film microstructures in the doping process and achieve high-performance thermoelectrical materials.
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R. Murad, Ary, Ahmed Iraqi, Shujahadeen B. Aziz, Sozan N. Abdullah, and Mohamad A. Brza. "Conducting Polymers for Optoelectronic Devices and Organic Solar Cells: A Review." Polymers 12, no. 11 (November 9, 2020): 2627. http://dx.doi.org/10.3390/polym12112627.

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In this review paper, we present a comprehensive summary of the different organic solar cell (OSC) families. Pure and doped conjugated polymers are described. The band structure, electronic properties, and charge separation process in conjugated polymers are briefly described. Various techniques for the preparation of conjugated polymers are presented in detail. The applications of conductive polymers for organic light emitting diodes (OLEDs), organic field effect transistors (OFETs), and organic photovoltaics (OPVs) are explained thoroughly. The architecture of organic polymer solar cells including single layer, bilayer planar heterojunction, and bulk heterojunction (BHJ) are described. Moreover, designing conjugated polymers for photovoltaic applications and optimizations of highest occupied molecular orbital (HOMO)–lowest unoccupied molecular orbital (LUMO) energy levels are discussed. Principles of bulk heterojunction polymer solar cells are addressed. Finally, strategies for band gap tuning and characteristics of solar cell are presented. In this article, several processing parameters such as the choice of solvent(s) for spin casting film, thermal and solvent annealing, solvent additive, and blend composition that affect the nano-morphology of the photoactive layer are reviewed.
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Xia, Hongyan, Chang Hu, Tingkuo Chen, Dan Hu, Muru Zhang, and Kang Xie. "Advances in Conjugated Polymer Lasers." Polymers 11, no. 3 (March 7, 2019): 443. http://dx.doi.org/10.3390/polym11030443.

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This paper provides a review of advances in conjugated polymer lasers. High photoluminescence efficiencies and large stimulated emission cross-sections coupled with wavelength tunability and low-cost manufacturing processes make conjugated polymers ideal laser gain materials. In recent years, conjugated polymer lasers have become an attractive research direction in the field of organic lasers and numerous breakthroughs based on conjugated polymer lasers have been made in the last decade. This paper summarizes the recent progress of the subject of laser processes employing conjugated polymers, with a focus on the photoluminescence principle and excitation radiation mechanism of conjugated polymers. Furthermore, the effect of conjugated polymer structures on the laser threshold is discussed. The most common polymer laser materials are also introduced in detail. Apart from photo-pumped conjugated polymer lasers, a direction for the future development of electro-pumped conjugated polymer lasers is proposed.
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Mdluli, Siyabonga B., Morongwa E. Ramoroka, Sodiq T. Yussuf, Kwena D. Modibane, Vivian S. John-Denk, and Emmanuel I. Iwuoha. "π-Conjugated Polymers and Their Application in Organic and Hybrid Organic-Silicon Solar Cells." Polymers 14, no. 4 (February 13, 2022): 716. http://dx.doi.org/10.3390/polym14040716.

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The evolution and emergence of organic solar cells and hybrid organic-silicon heterojunction solar cells have been deemed as promising sustainable future technologies, owing to the use of π-conjugated polymers. In this regard, the scope of this review article presents a comprehensive summary of the applications of π-conjugated polymers as hole transporting layers (HTLs) or emitters in both organic solar cells and organic-silicon hybrid heterojunction solar cells. The different techniques used to synthesize these polymers are discussed in detail, including their electronic band structure and doping mechanisms. The general architecture and principle of operating heterojunction solar cells is addressed. In both discussed solar cell types, incorporation of π-conjugated polymers as HTLs have seen a dramatic increase in efficiencies attained by these devices, owing to the high transmittance in the visible to near-infrared region, reduced carrier recombination, high conductivity, and high hole mobilities possessed by the p-type polymeric materials. However, these cells suffer from long-term stability due to photo-oxidation and parasitic absorptions at the anode interface that results in total degradation of the polymeric p-type materials. Although great progress has been seen in the incorporation of conjugated polymers in the various solar cell types, there is still a long way to go for cells incorporating polymeric materials to realize commercialization and large-scale industrial production due to the shortcomings in the stability of the polymers. This review therefore discusses the progress in using polymeric materials as HTLs in organic solar cells and hybrid organic-silicon heterojunction solar cells with the intention to provide insight on the quest of producing highly efficient but less expensive solar cells.
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Upadhyay, Anjali, and Subramanian Karpagam. "Movement of new direction from conjugated polymer to semiconductor composite polymer nanofiber." Reviews in Chemical Engineering 35, no. 3 (March 26, 2019): 351–75. http://dx.doi.org/10.1515/revce-2017-0024.

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Abstract In the past few years, there was a tremendous growth in conjugated polymer nanofibers via design of novel conjugated polymers with inorganic materials. Synthetic routes to these conjugated polymers involve new, mild polymerization techniques, which enable the formation of well-defined polymer architectures. This review provides interest in the development of novel (semi) conducting polymers, which combine both organic and inorganic blocks in one framework. Due to their ability to act as chemosensors or to detect various chemical species in environmental and biological systems, fluorescent conjugated polymers have gained great interest. Nanofibers of metal oxides and sulfides are particularly interesting in both their way of applications and fundamental research. These conjugated nanofibers operated for many applications in organic electronics, optoelectronics, and sensors. Synthesis of electrospun fibers by electrospinning technique discussed in this review is a simple method that forms conjugated polymer nanofibers. This review provides the basics of the technique and its recent advances in the formation of highly conducting and high-mobility polymer fibers towards their adoption in electronic application.
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Li, Zheng, and Ying-Wei Yang. "Conjugated macrocycle polymers." Polymer Chemistry 12, no. 32 (2021): 4613–20. http://dx.doi.org/10.1039/d1py00759a.

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Pokhodenko, V. D., and V. A. Krylov. "Electrochemistry of conjugated organic polymers." Theoretical and Experimental Chemistry 30, no. 3 (1994): 91–105. http://dx.doi.org/10.1007/bf00538188.

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Jiang, Jia-Xing, Chao Wang, Andrea Laybourn, Tom Hasell, Rob Clowes, Yaroslav Z. Khimyak, Jianliang Xiao, Simon J. Higgins, Dave J. Adams, and Andrew I. Cooper. "Metal-Organic Conjugated Microporous Polymers." Angewandte Chemie International Edition 50, no. 5 (December 22, 2010): 1072–75. http://dx.doi.org/10.1002/anie.201005864.

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Jiang, Jia-Xing, Chao Wang, Andrea Laybourn, Tom Hasell, Rob Clowes, Yaroslav Z. Khimyak, Jianliang Xiao, Simon J. Higgins, Dave J. Adams, and Andrew I. Cooper. "Metal-Organic Conjugated Microporous Polymers." Angewandte Chemie 123, no. 5 (December 22, 2010): 1104–7. http://dx.doi.org/10.1002/ange.201005864.

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Kausar, Ayesha. "Conjugated Polymer/Graphene Oxide Nanocomposites—State-of-the-Art." Journal of Composites Science 5, no. 11 (November 5, 2021): 292. http://dx.doi.org/10.3390/jcs5110292.

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Graphene oxide is an imperative modified form of graphene. Similar to graphene, graphene oxide has gained vast interest for the myriad of industrial applications. Conjugated polymers or conducting polymers are well known organic materials having conducting backbone. These polymers have semiconducting nature due to π-conjugation along the main chain. Doping and modification have been used to enhance the electrical conductivity of the conjugated polymers. The nanocomposites of the conjugated polymers have been reported with the nanocarbon nanofillers including graphene oxide. This review essentially presents the structure, properties, and advancements in the field of conducting polymer/graphene oxide nanocomposites. The facile synthesis, processability, and physical properties of the polymer/graphene oxide nanocomposites have been discussed. The conjugated polymer/graphene oxide nanocomposites have essential significance for the supercapacitors, solar cells, and anti-corrosion materials. Nevertheless, the further advanced properties and technical applications of the conjugated polymer/graphene oxide nanocomposites need to be explored to overcome the challenges related to the high performance.
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Dissertations / Theses on the topic "Conjugated organic polymers"

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Samuel, Ifor David William. "Femtosecond spectroscopy of conjugated polymers." Thesis, University of Cambridge, 1991. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239657.

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Bakbak, Selma. "Structural manipulation of conjugated polymers." Diss., Available online, Georgia Institute of Technology, 2006, 2006. http://etd.gatech.edu/theses/available/etd-01112006-211158/.

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Thesis (Ph. D.)--Chemistry and Biochemistry, Georgia Institute of Technology, 2006.
Dr. Uwe H. F. Bunz, Committee Chair ; Dr. Laren M. Tolbert, Committee Member ; Dr. Joseph Perry, Committee Member ; Dr. David M. Collard, Committee Member ; Dr. Anselm C. Griffin, Committee Member.
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Wang, Chao. "Synthesis of Conjugated Polymers." University of Akron / OhioLINK, 2013. http://rave.ohiolink.edu/etdc/view?acc_num=akron1362783501.

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Isaksson, Joakim. "Organic Bioelectronics : Electrochemical Devices using Conjugated Polymers." Doctoral thesis, Linköpings universitet, Institutionen för teknik och naturvetenskap, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-9679.

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Since the Nobel Prize awarded discovery that some polymers or “plastics” can be made electronically conducting, the scientific field of organic electronics has arisen. The use of conducting polymers in electronic devices is appealing, because the materials can be processed from a liquid phase, much like ordinary non-conducting plastics. This gives the opportunity to utilize printing technologies and manufacture electronics roll-to-roll on flexible substrates, ultimately at very low costs. Even more intriguing are the possibilities to achieve completely novel functionalities in combination with the inherent compatibility of these materials with biological species. Therefore, organic electronics can be merged with biology and medicine to create organic bioelectronics, i.e. organic electronic devices that interact with biological samples directly or are used for biological applications. This thesis aims at giving a background to the field of organic bioelectronics and focuses on how electrochemical devices may be utilized. An organic electronic wettability switch that can be used for lab-on-a-chip applications and control of cell growth as well as an electrochemical ion pump for cell communication and drug delivery are introduced. Furthermore, the underlying electrochemical structures that are the basis for the above mentioned devices, electrochemical display pixels etc. are discussed in detail. In summary, the work contributes to the understanding of electrochemical polymer electronics and, by presenting new bioelectronic inventions, builds a foundation for future projects and discoveries.
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Vokata, Tereza. "Synthetic Approaches to Flexible Fluorescent Conjugated Polymers." FIU Digital Commons, 2015. http://digitalcommons.fiu.edu/etd/1910.

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Conjugated polymers (CPs) are intrinsically fluorescent materials that have been used for various biological applications including imaging, sensing, and delivery of biologically active substances. The synthetic control over flexibility and biodegradability of these materials aids the understanding of the structure-function relationships among the photophysical properties, the self-assembly behaviors of the corresponding conjugated polymer nanoparticles (CPNs), and the cellular behaviors of CPNs, such as toxicity, cellular uptake mechanisms, and sub-cellular localization patterns. Synthetic approaches towards two classes of flexible CPs with well-preserved fluorescent properties are described. The synthesis of flexible poly(p-phenylenebutadiynylene)s (PPBs) uses competing Sonogashira and Glaser coupling reactions and the differences in monomer reactivity to incorporate a small amount (~10%) of flexible, non-conjugated linkers into the backbone. The reaction conditions provide limited control over the proportion of flexible monomer incorporation. Improved synthetic control was achieved in a series of flexible poly(p-phenyleneethynylene)s (PPEs) using modified Sonogashira conditions. In addition to controlling the degree of flexibility, the linker provides disruption of backbone conjugation that offers control of the length of conjugated segments within the polymer chain. Therefore, such control also results in the modulation of the photophysical properties of the materials. CPNs fabricated from flexible PPBs are non-toxic to cells, and exhibit subcellular localization patterns clearly different from those observed with non-flexible PPE CPNs. The subcellular localization patterns of the flexible PPEs have not yet been determined, due to the toxicity of the materials, most likely related to the side-chain structure used in this series. The study of the effect of CP flexibility on self-assembly reorganization upon polyanion complexation is presented. Owing to its high rigidity and hydrophobicity, the PPB backbone undergoes reorganization more readily than PPE. The effects are enhanced in the presence of the flexible linker, which enables more efficient π-π stacking of the aromatic backbone segments. Flexibility has minimal effects on the self-assembly of PPEs. Understanding the role of flexibility on the biophysical behaviors of CPNs is key to the successful development of novel efficient fluorescent therapeutic delivery vehicles.
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Isaksson, Joakim. "Organic bioelectronics : electrochemical devices based on conjugated polymers /." Norrköping : [Department of Science and Technology], Linköping University, 2007. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-9679.

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Chen, Yi 1974. "Organic thin film transistors based on conjugated polymers." Thesis, McGill University, 2004. http://digitool.Library.McGill.CA:80/R/?func=dbin-jump-full&object_id=81533.

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Thin film transistors with different polymers (PTFTs) as active channel layers have been fabricated and studied in this work. Three different fabrication procedures were used to fabricate long and short channel PTFTs on silicon substrates and long channel PTFTs on glass substrates. It has been shown that the success rate of fabrication of PTFTs on glass substrates with anodic Al 2O3 gate dielectrics is higher than that on silicon substrates with thermally grown SiO2 gate dielectrics.
The characteristics of PTFTs fabricated using several polymers were studied. Among them, the ones based on regioregualr poly[3-hexylthiophene-2.5diy] (RR-P3HT) have the best performance with a field effect mobility (mueff) of about 0.01 cm2/V-s and ION/IOFF value of about 50 when doped with FeCl3. Results of measurement suggested that FeCl3 doping of P3HT could lead to a decrease of about 5 orders of magnitude in its contact resistance to Au electrodes, giving rise to two orders of magnitude increase of its apparent mobility. Therefore, it can be concluded that the contact resistances are the major limitation of performance of many PTFTs and need to be studied intensively in the future.
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Murad, Ary. "Development of new conjugated polymers for organic photovoltaics." Thesis, University of Sheffield, 2017. http://etheses.whiterose.ac.uk/16317/.

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Mask, Walker. "MODELING THE CONDENSED-PHASE BEHAVIOR OF Π-CONJUGATED POLYMERS." UKnowledge, 2019. https://uknowledge.uky.edu/chemistry_etds/120.

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It is well established that the morphology and physical properties of an organic semiconducting (OSC) material regulate its electronic properties. However, structure-function relationships remain difficult to describe in polymer-based OSC, which are of particular interest due to their robust mechanical properties. If relationships among the molecular and bulk levels of structure can be found, they can aid in the design of improved materials. To explore and detail important structure-function relationships in polymer-based OSC, this work employs molecular dynamics (MD) simulations to study various π-conjugated polymers in different environments. Two independent investigations are discussed in this work. One investigation examines how the purposeful disruption of the π-conjugated backbone to increase the chain flexibility impacts the chain structure and packing in the condensed phase. This is done by adding a conjugation break spacer (CBS) unit of one to ten carbons in length into the monomer structure of diketopyrrolopyrrole-based polymers. It is found that trends in the folding and glass structure follow the increase and the parity (odd versus even) of the CBS length. The second investigation analyzes a variety of polymers and small molecule acceptor (SMA) blends to observe the effects of changing the shape of either component and the physical properties of the material, as well as the structure of the polymer chains. It is found that the conjugated core, the side chains, and the planarity or sphericity each influence the density and diffusion of the materials made.
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Halls, Jonathan James Michael. "Photoconductive properties of conjugated polymers." Thesis, University of Cambridge, 1997. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.368812.

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Books on the topic "Conjugated organic polymers"

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1956-, Reynolds John R., and Skotheim Terje A. 1949-, eds. Conjugated polymers: Processing and applications. Boca Raton: CRC, 2007.

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Roth, S. One-dimensional metals: Conjugated polymers, organic crystals, carbon nanotubes. 2nd ed. Weinheim: Wiley-VCH, 2004.

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Kuzmany, Hans. Electronic Properties of Conjugated Polymers: Proceedings of an International Winter School, Kirchberg, Tirol, March 14-21, 1987. Berlin, Heidelberg: Springer Berlin Heidelberg, 1987.

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Conjugated organic materials: Synthesis, structure, device and applications : March 24-28, 2008, San Francisco, California, USA. Warrendale, PA: Materials Research Society, 2008.

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F, Perepichka Dmitrii, ed. Handbook of thiophene-based materials. Hoboken: Wiley, 2009.

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Brédas, J. L. Conjugated Polymeric Materials: Opportunities in Electronics, Optoelectronics, and Molecular Electronics. Dordrecht: Springer Netherlands, 1990.

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Conjugated Polymers: Processing and Applications (Handbook of Conducting Polymers). 3rd ed. CRC, 2006.

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Yang, Szu-Wei Steve. Conjugated hybrid inorganic-organic polymers for electronic applications. 2002.

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(Editor), Terje A. Skotheim, and John Reynolds (Editor), eds. Conjugated Polymers: Theory, Synthesis, Properties, and Characterization (Handbook of Conducting Polymers). CRC, 2006.

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Handbook of conducting polymers. 3rd ed. Boca Raton, Fla: CRC, 2007.

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Book chapters on the topic "Conjugated organic polymers"

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Nechtschein, Maxime. "Doped Conjugated Polymers: Conducting Polymers." In Organic Conductors, 647–89. Boca Raton: CRC Press, 2022. http://dx.doi.org/10.1201/9780367811907-13.

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Schott, Michel. "Undoped (Semiconducting) Conjugated Polymers." In Organic Conductors, 539–646. Boca Raton: CRC Press, 2022. http://dx.doi.org/10.1201/9780367811907-12.

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Menon, Reghu. "Transport Properties of Conjugated Polymers." In Organic Photovoltaics, 91–117. Berlin, Heidelberg: Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05187-0_3.

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Matsushita, Satoshi, Benedict San Jose, and Kazuo Akagi. "Functional Nanostructured Conjugated Polymers." In Functional Organic and Hybrid Nanostructured Materials, 547–73. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2018. http://dx.doi.org/10.1002/9783527807369.ch15.

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Schott, Michel, and Maxime Nechtschein. "Introduction to Conjugated and Conducting Polymers." In Organic Conductors, 495–538. Boca Raton: CRC Press, 2022. http://dx.doi.org/10.1201/9780367811907-11.

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Lanzani, G., G. Cerullo, D. Polli, A. Gambetta, M. Zavelani-Rossi, and C. Gadermaier. "Ultrafast Photophysics in Conjugated Polymers." In Physics of Organic Semiconductors, 129–51. Weinheim, FRG: Wiley-VCH Verlag GmbH & Co. KGaA, 2006. http://dx.doi.org/10.1002/3527606637.ch5.

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Cobet, Christoph, Jacek Gasiorowski, Dominik Farka, and Philipp Stadler. "Polarons in Conjugated Polymers." In Ellipsometry of Functional Organic Surfaces and Films, 355–87. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-75895-4_16.

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Ansari, Shahid Pervez, and Farman Ali. "Conjugated Organic Polymers for Optoelectronic Devices." In Polymers and Polymeric Composites: A Reference Series, 749–88. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-319-95987-0_21.

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Ansari, Shahid Pervez, and Farman Ali. "Conjugated Organic Polymers for Optoelectronic Devices." In Polymers and Polymeric Composites: A Reference Series, 1–40. Cham: Springer International Publishing, 2018. http://dx.doi.org/10.1007/978-3-319-92067-2_21-1.

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Comoretto, Davide, and Guglielmo Lanzani. "Optical and Spectroscopic Properties of Conjugated Polymers." In Organic Photovoltaics, 57–90. Berlin, Heidelberg: Springer Berlin Heidelberg, 2003. http://dx.doi.org/10.1007/978-3-662-05187-0_2.

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Conference papers on the topic "Conjugated organic polymers"

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Hertel, Dirk, and Klaus Meerholz. "Triplet-Polaron Quenching in Conjugated Polymers." In Organic Photonics and Electronics. Washington, D.C.: OSA, 2006. http://dx.doi.org/10.1364/ope.2006.optua2.

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Strohriegl, Peter, Philipp Knauer, Christina Saller, and Esther Scheler. "Patternable conjugated polymers for organic solar cells." In SPIE Organic Photonics + Electronics, edited by Zakya H. Kafafi and Paul A. Lane. SPIE, 2013. http://dx.doi.org/10.1117/12.2023899.

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Kajzar, Francois. "Multiphoton resonance effects in conjugated organic polymers." In OE/LASE '90, 14-19 Jan., Los Angeles, CA, edited by Nasser Peyghambarian. SPIE, 1990. http://dx.doi.org/10.1117/12.18125.

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Azoulay, Jason D., Benjamin A. Zhang, and Alexander E. London. "Narrow band gap conjugated polymers for emergent optoelectronic technologies." In SPIE Organic Photonics + Electronics, edited by Jon A. Schuller. SPIE, 2015. http://dx.doi.org/10.1117/12.2186357.

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O'Connor, Brendan, Xiao Xue, and Tianlei Sun. "Charge transport in highly aligned conjugated polymers (Presentation Recording)." In SPIE Organic Photonics + Electronics, edited by Iain McCulloch, Oana D. Jurchescu, Ioannis Kymissis, Ruth Shinar, and Luisa Torsi. SPIE, 2015. http://dx.doi.org/10.1117/12.2187646.

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Irvin, Jennifer A., David J. Irvin, Andrew P. Chafin, Andrew J. Guenthner, Geoffrey A. Lindsay, Michael E. Wright, and Warren N. Herman. "Synthesis and characterization of chiral conjugated polymers for optical waveguides." In Organic Thin Films. Washington, D.C.: OSA, 2002. http://dx.doi.org/10.1364/otf.2001.owc2.

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Lim, HanWhuy, Jong Un Hwang, Byeonggwan Kim, and Eunkyoung Kim. "Photothermal actuators based on conjugated polymers (Conference Presentation)." In Organic Photonic Materials and Devices XX, edited by Christopher E. Tabor, François Kajzar, Toshikuni Kaino, and Yasuhiro Koike. SPIE, 2018. http://dx.doi.org/10.1117/12.2291083.

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Nguyen, Thuc-Quyen. "Doping of Conjugated Polymers by Lewis Acids." In 1st Interfaces in Organic and Hybrid Thin-Film Optoelectronics. València: Fundació Scito, 2019. http://dx.doi.org/10.29363/nanoge.inform.2019.004.

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Repenko, Tatjana, and Alexander J. C. Kuehne. "Near-infrared (NIR) emitting conjugated polymers for biomedical applications (Presentation Recording)." In SPIE Organic Photonics + Electronics, edited by Iain McCulloch, Oana D. Jurchescu, Ioannis Kymissis, Ruth Shinar, and Luisa Torsi. SPIE, 2015. http://dx.doi.org/10.1117/12.2188002.

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Sawyer, Eric J., Suchol Savagatrup, Timothy F. O'Connor, Aditya S. Makaram, Daniel J. Burke, Aliaksandr V. Zaretski, Adam D. Printz, and Darren J. Lipomi. "Toward intrinsically stretchable organic semiconductors: mechanical properties of high-performance conjugated polymers." In SPIE Organic Photonics + Electronics, edited by Zhenan Bao, Iain McCulloch, Ruth Shinar, and Ioannis Kymissis. SPIE, 2014. http://dx.doi.org/10.1117/12.2059098.

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