Dissertations / Theses on the topic 'Complexes (Stratigraphy) New Zealand'

A quantitative understanding of the processes controlling sediment transport and deposition across the land/sea interface is crucial to linking terrestrial and marine environments and understanding the formation of marine stratigraphy. The nature and distribution of terrestrial-derived sediment preserved in shelf stratigraphy in turn provides insight into the complex linkages inherent in source-to-sink sediment dynamics. Located inboard of an actively subducting plate boundary and characterized by one of the highest sediment yields in the world, the open-shelf setting off of the Waiapu River in New Zealand presents an excellent location to improve our understanding of the factors controlling the formation of continental shelf stratigraphy and associated sediment transport. Over 850km of high-resolution seismic and swath bathymetry data ground-truthed by cores show significant stratigraphic spatial variation preserved on the Waiapu continental shelf. This spatial variation is likely controlled by regionally-specific sediment deposition and resuspension processes as well as antecedent geology. Chronostratigraphic control obtained from black carbon analysis reveals that deforestation of the Waiapu catchment is preserved as a distinct event in the adjacent inner shelf stratigraphy, and further indicates that the inner shelf is currently capturing a significant ∼16-34% of the total Waiapu sediment budget. Shelf-wide stratigraphy shows that the thickest deposits of Holocene stratigraphy are found in tectonically-created accommodation spaces, highlighting the role of neotectonics in strata formation. The primary control on strata formation on the Waiapu continental shelf is presumed to be tectonically-steered, local sediment supply, which likely still influences modern-day sediment transport via the effects of small-scale bathymetric lows steering gravity-dependent sediment flows at the river mouth.

An extensive study of the stratigraphy of the Amuri Limestone Group (Upper Cretaceous Upper Eocene) and the enclosing units in East Marlborough has been undertaken. The study includes regional correlation of detailed measured sections in conjunction with lithofacies descriptions, micropaleontological age determinations, petrographic examination, and geochemical analysis. A revised New Zealand Paleogene time scale has been compiled to take into account recent major revisions of international Cenozoic geochronology. The Amuri Limestone Group (c.660m maximum thickness) incorporates 6 formations: Mead Hill Formation (mid Haumurian - lower Waipawan); Teredo Limestone (mid Waipawan late Mangaorapan); Lower Limestone (mid Waipawan – mid Mangaorapan); Lower Marl (upper Waipawan - lower Heretaungan); Middle Limestone (lower Mangaorapan - lower Bortonian); Upper Marl (upper Porangan - upper Runangan). The Mead Hill Formation is diachronous and conformable on the Upper Iwitahi Group which includes the Woolshed Formation (lower - upper Haumurian) and the overlying Claverley Sandstone (upper Haumurian). The Mead Hill Formation contains the Flaxbourne Limestone Member (mid Haumurian) and Lower Chert Member (late Haumurian). The Lower Limestone contains the Upper Chert Member (mid Waipawan). The Fells Greensand Member (mid Bortonian) and Grass Seed Volcanics Member (upper Bortonian) are both intercalated within the Middle Limestone and Upper Marl. With the exception of post-unconformity sandy facies, the Amuri Limestone consists of dcm-bedded, light greenish grey, well indurated, foraminiferal biomicritic calcilutites and poorly indurated, smectite-rich marls. Macrofossils are extremely rare. Cretaceous sequences are characterized by a poorly developed Planolites - Teichichnus ichnoassemblage; Paleogene facies are dominated by a Zoophycos - Planolites ichnoassemblage. Pelagic limestone deposition was initiated within a central NW-trending trough and spread outwards onto the adjacent near-horizontal platform. Subsidence of the trough is inferred to have been maintained by reactivation of basement faults. Water depths on the platform are likely to have been relatively shallow (inner shelf) during the Late Cretaceous but much deeper (outer shelf - bathyal) during the Paleocene and Eocene. Basin morphology was the major control on lateral facies variations. Platform sediments are characteristically more thinly bedded, and the thickness of individual Formations is correspondingly attenuated, in comparison with trough facies. Chert and dolomite are restricted to the lower parts of the trough facies. Basin-wide unconformities are recognized in the late Haumurian, mid Waipawan (sub-Teredo Limestone unconformity), mid Bortonian, and mid Whaingaroan. Although these breaks are disconformable in platform areas, they regionally account for large amounts of differential erosion. Submarine erosion, hardground formation, development of a Thallasinoides-dominated ichnofauna, glauconitization, phosphatization, and accumulation of a thin sandy facies are typical of unconformities outside the trough. Within the trough, the Haumurian and Waipawan breaks in deposition are represented by paraconformities or coevally deposited siliceous, pyritic mudstones. The subfeldsarenitic Claverley Sandstone was intra-basinally derived from submarine erosion and reworking of the underlying Woolshed Formation. The detrital sand fraction of the Teredo Limestone was derived from reworking of the locally exhumed Claverley Sandstone, and from remobilization at depth and submarine extrusion of that unit. An extra-basinal source (possibly reworked quartzose coal measures) for the redeposited supermature quartzarenitic Fells Greensand is likely. Pulses of (compressional?) tectonic activity immediately preceded and possibly continued during unconformity development. These tectonic events may provide an independent estimate of the timing of some of the major (Late Cretaceous - Cenozoic) plate tectonic events affecting the New Zealand region. The amount of dextral movement on two of the major Marlborough Faults has been estimated from offsets in lithofacies and isopach patterns. 5-10km of transcurrent movement is recognized on the northern branch of the Hope Fault; 10-15km of right-lateral slip has occurred on the Kekerengu Fault.

Infrared stimulated luminescence ages are presented from the North Westland region, West Coast, South Island, New Zealand. These ages span much of the last interglacial-glacial cycle from 123.3 ± 12.7 ka to 33.6 ± 3.6 ka. Coverage is extended to c. 14 ka via cosmogenic isotope dating. A new Quaternary stratigraphy and Marine Isotope Stage correlation is proposed for the on-shore glacial-interglacial fluvioglacial, fluvial and marine terrace sequence. The new model incorporates previously published luminescence and radiocarbon ages. It necessitates reinterpretation of the evolution of the climate in North Westland for the period from 123 ka to 14 ka. Reinterpretation of fossil pollen and plant macrofossil records implies a period of probable near-interglacial climate in North Westland during the early to middle portion of Marine Isotope Stage 3. It also implies the presence in North Westland of raised marine terraces dating from this Isotope Stage. In addition it is concluded that during the period from c.60 ka to c.50 ka podocarp dominated forest was widespread in the lowland portion of Westland. Between Okarito and Westport Dacrydium cupressinum and Nestegis were ubiquitous components of this forest. This finding aligns the Marine Isotope Stage 3 climate of North Westland nicely with that of other parts of New Zealand where good records exist for this period.

This thesis examined the stratigraphy, petrography, and geochemistry of the Paleocene to Eocene pelagic sedimentary deposits in Pahaoa, Wairarapa, North Island, New Zealand. Laboratory and statistical techniques are employed to assess the change in depositional environment prior to the onset of subduction. The results provide insights into the modes of deposition, stratigraphic evolution of the passive margin sequence and tectonic setting of the receiving basin before subduction initiation of the Hikurangi margin.

In the mid-Cenozoic, New Zealand underwent slow subsidence interspersed with unconformity development, however significant controversy exists around both the extent of submergence below sea level during this period of maximum drowning, as well as the causes of these unconformities. Detailed field observations, combined with extensive petrographic analyses, stable isotopes, cathodoluminescence, and thin section staining were used to develop lithofacies, depositional, and sequence stratigraphic models of the mid-Cenozoic succession in the Waitaki region, South Island, to address these controversies. Twelve facies types have been described for Late Eocene-Early Miocene sedimentary rocks, leading to the identification of two major (Mid Oligocene & Early Miocene) and one minor (Late Oligocene) sequence boundaries. Surtseyan volcanism in the east produced a palaeohigh, resulting in a submerged rimmed cool-water carbonate platform, with low-lying land to the west. This eastern palaeohigh developed karst during sea-level lowstands, which correlate with silty submarine bored hardgrounds in the west. Glauconitic and phosphatic facies deposited during early marine transgression suggest an authigenic factory supplied by terrigenous clays existed during lowered sea level that was progressively shut down in favour of a carbonate factory as sea level rose and terrigenous supply decreased. The eastern palaeohigh served to nucleate this carbonate factory by raising the sea floor above the influence of siliciclastic sediment supply and providing a shallow substrate for marine colonisation. The higher energy eastern facies display dissolution of aragonitic taxa, while deeper western facies retained an aragonitic assemblage. This early bathymetric high created a barrier to submarine currents, but was gradually reduced by erosion during subsequent lowstands. Calcareous facies were often subjected to minor seafloor cement precipitation to shallow burial diagenesis, while eastern facies developed some meteoric cement during subaerial exposure. Comparisons between sea-level change in the study area and the New Zealand megasequence indicate eustatic changes as the primary driver of water depth in the Waitaki region until the development of the modern plate boundary in the Early Miocene.

This study utilises seismic data to improve understanding of the subsurface fluid flow behaviour in the Taranaki and Great South Basins offshore New Zealand. The aim of this study is to characterise fluid flow features and to investigate their genesis, fluid origins and implications for subsurface fluid plumbing system by integrating seismic interpretation and 3D petroleum systems modelling techniques. After an early phase studying Pliocene pockmarks in the Taranaki Basin, this study has been focused on the subsurface fluid plumbing system and on the fluid expulsion history in the Great South Basin. The Taranaki Basin lies on the west coast and offshore of the North Island, New Zealand. The seismic interpretation revealed that paleo-pockmark formation in the study area relates to fluid escape due to a rapid sediment loading environment in a distal fan setting. Seismic analysis rules out any links between the paleo-pockmarks and faulting. The relationship between paleo-pockmark occurrence and fan depositional thickness variations suggests that pore-water expulsion during overburden progradation is the most likely cause of the paleo-pockmarks. The rapid sediment loading generated overpressure which was greatest on the proximal fan due to a lateral gradient in overburden pressure. Fluids were consequently forced towards the fan distal parts where, eventually, the pore pressure exceeded the fracture gradient of the seal. The Great South Basin lies off the southern coast of the South Island of New Zealand and is located beneath the modern shelf area. Evidence for past and present subsurface fluid flow in this basin is manifested by the presence of numerous paleo-pockmarks, seabed pockmarks, polygonal fault systems, bright spots and bottom simulating reflections (BSR), all of which help constrain aspects of the overburden plumbing system and may provide clues to deeper hydrocarbon prospectivity in this frontier region. The various types of fluid flow features observed in this study are interpreted to be caused by different fluid origins and mechanisms based on evidences from seismic interpretation in the study area. The possible fluid origins which contribute to fluid flow features in the Great South Basin are compactional pore water as well as biogenic and thermogenic hydrocarbons. Using 3D seismic attribute analysis it was possible to highlight the occurrence of these features, particularly polygonal faults and pockmarks, which tend to be hosted within fine-grained sequences. Paleo- and present-day fluid flow features were investigated using 3D basin and petroleum systems modelling with varying heat flow scenarios. The models predict that thermogenic gas is currently being generated in mid-Cretaceous sedimentary sequences and possibly migrates along tectonic faults and polygonal faults feeding present-day pockmarks at the seabed. The models suggest that biogenic gas was the main fluid source for the Middle Eocene paleo-pockmarks and compactional pore fluid may be the main fluid contributor to the Late Eocene paleo-pockmarks. Different heat flow scenarios show that only mid-Cretaceous source rocks have reached thermal maturity in the basin, whilst Late Cretaceous and Paleocene source rocks would be largely immature. The observations and interpretations provided here contribute to the ongoing discussion on basin de-watering and de-gassing and the fluid contributors involved in pockmark formation and the use of pockmarks as a potential indicator of hydrocarbon expulsion. It is clear from this study that seismically-defined fluid flow features should be integrated into petroleum systems modelling of frontier and mature exploration areas in order to improve our understanding on fluid phases, their migration routes, timings and eventual expulsion history.

Charwell Basin is a 6 km-wide structural depression situated at the boundary between the axial ranges and faulted and folded Marlborough Fault Zone of north-eastern South Island, New Zealand. The basin contains the piedmont reach of the Charwell River, and a series of late Quaternary loess-mantled alluvial terraces and terrace remnants that have been uplifted and translocated from their sediment source due to strike-slip motion along the Hope Fault which bounds the basin to its immediate north. The aim of this study was to provide an interdisciplinary, integrated and holistic analysis of late Quaternary landscape evolution and environmental change in Charwell Basin using terrain analysis, loess stratigraphy, soil chemistry and paleoecological data. The study contributes new understanding of New Zealand landscape and ecosystem responses to regional and global climatic change extending to Marine Isotope Stage (MIS) 6, and shows that climatically-forced shifts in biogeomorphic processes play a significant role in lowland landscape evolution. Morphometric analysis of alluvial terraces and terrace remnants of increasing age demonstrated geomorphic evolution through time, with a decrease in extent of original planar terrace tread morphology and an increase in frequency of steeper slopes and convexo-concave land elements. Paleotopographic analysis of a >150 ka terrace mantled by up to three loess sheets revealed multiple episodes of alluvial aggradation and degradation and, subsequent to river abandonment, gully incision prior to and coeval with loess accumulation. Spatial heterogeneity in loess sheet preservation showed a complex history of loess accumulation and erosion. A critical profile curvature range of -0.005 to -0.014 (d2z/dx2, m-1) for loess erosion derived from a model parameterised in different ways successfully predicted loess occurrence on adjacent slope elements, but incorrectly predicted loess occurrence on an older terrace remnant from which all loess has been eroded. Future analyses incorporating planform curvature, regolith erosivity and other landform parameters may improve identification of thresholds controlling loess occurrence in Charwell Basin and in other South Island landscapes. A loess chronostratigraphic framework was developed for, and pedogenic phases identified in, the three loess sheets mantling the >150 ka terrace. Except for one age, infrared-stimulated luminescence dates from both an upbuilding interfluve loess exposure and colluvial gully infill underestimated loess age with respect to the widespread Kawakawa/Oruanui Tephra (KOT; 27,097 ± 957 cal. yr BP), highlighting the need for improvements in the methodology. Onset of loess sheet 1 accumulation started at ca. 50 ka, with a break at ca. 27 ka corresponding to the extended Last Glacial Maximum (eLGM) interstadial identified elsewhere in New Zealand. Loess accumulation through MIS 3 indicates a regional loess flux, and that glaciation was not a necessary condition for loess generation in South Island. Loess accumulation and local alluvial aggradation are decoupled: the youngest aggradation event only covers ~12 kyr of the period of loess sheet 1 accumulation. Older local aggradation episodes could not be the source because their associated terraces are mantled by loess sheet 1. In the absence of numerical ages, the timing of L2 and L3 accumulation is inferred on the basis of an offshore clastic sediment record. The upbuilding phase of loess sheet 2 occurred in late MIS 5a/MIS 4, and loess sheet 3 accumulated in two phases in MIS 5b and late MIS 6. Biogenic silica data were used to reconstruct broad shifts in vegetation and changes in gully soil saturation status. During interglacial/interstadial periods (MIS 1, early MIS 3, MIS 5) Nothofagus¬-dominated forest covered the area in association with Microlaena spp grasses. Lowering of treeline altitude during glacial/stadial periods (MIS 2, MIS 3, MIS 5b, late MIS 6) led to reduction in forest cover and a mosaic of shrubs and Chionochloa spp, Festuca spp and Poa spp tussock grasses. Comparison of interfluve and gully records showed spatial heterogeneity in vegetation cover possibly related to environmental gradients of exposure or soil moisture. A post-KOT peak in gully tree phytoliths corresponds to the eLGM interstadial, and a shift to grass-dominated vegetation occurred during the LGM sensu stricto. Diatoms indicated the site became considerably wetter from ca. 36 ka, with peak wetness at ca. 30, 25 and 21 ka, possibly due to reduced evapotranspiration and/or increased precipitation from a combination of strengthened westerly winds and increased cloudiness, or strengthened southerly flow and increased precipitation. Human influence after ca. 750 yr BP led to re-establishment of grassland in the area, which deposited phytoliths mixed to 30 cm depth in the soil. A coupled gully colluvial infilling/vegetation record showed that sediment flux during the late Pleistocene was ~0.0019 m3 m-1 yr-1 under a shrubland/grassland mosaic, and Holocene sediment flux was ~0.0034 m3 m-1 yr-1 under forest. This increase of 60% through the last glacial-interglacial transition resulted from increased bioturbation and down-slope soil transport via root growth and treethrow, which formed a biomantle as evidenced by slope redistribution of the KOT. These results contrast with sediment transport rates and processes hypothesised to occur contemporaneously in adjacent mountain catchments. This suggests that intraregional biogeomorphic processes can differ significantly depending on topography and geological substrate, with different landscapes responding in unique ways to the same climate shifts. Analysis of Quaternary terrestrial landscape evolution in non-glaciated mountainous and lowland areas must therefore consider spatial and temporal heterogeneity in sediment fluxes and underlying transport processes.

The Cenozoic was a time of climatic, tectonic and eustatic change in the Southern Hemisphere. Cooling at the pole, glaciation and substantial sea ice formation occurred as latitudinal temperature gradients increased and tectonics altered Southern Hemisphere circulation patterns. During this same time frame, the tectonic regime of the New Zealand continental block transitioned from a passive margin to an active plate boundary, resulting in the reversal of a long-standing transgression and an influx of terrigenous sediment to marine basins. In this transition, depositional basins in the South Island became more localized; however, the influence of oceanographic and tectonic drivers is poorly understood on a local scale. Here we apply sedimentological, biostratigraphic and geochemical analyses to revise understanding of the effects of the changing climatic regime and active tectonics on the development of Oligocene and Miocene rocks in the Northern Canterbury Basin. The Late Oligocene to Middle Miocene sedimentary rocks of the northern Canterbury Basin record oceanographic and tectonic influences on basin formation, sediment supply and deposition. The Palaeocene to Late Eocene Amuri Formation in the basin are micrites and biogenic cherts recording deepwater, terrigenous-starved environments, and do not show any influence of active tectonics. The Early Oligocene development of ice on the Antarctic continent and the associated global sea level response is reflected in this basin as the Marshall Paraconformity, an eroded, glauconitized and phosphatised firm ground and hardground atop the Amuri. Sedimentation above this unconformity resumed in the Late Oligocene-Early Miocene with cleaner, deep-water, bathyal planktic foraminifera packstones and wackestones in eastern areas and Late Oligocene inner shelf volcaniclastic packstones in parts of the western basin. Post-unconformity sedimentation resumed earlier in western areas, as the currents responsible for scouring the sea floor moved progressively to the east. The development of tectonic uplift in terrestrial settings is first seen in the northwestern basin in Lower Miocene fine quartz-rich sandstones, and by the Middle Miocene, bathyal sandstones and quartz-rich wackestones appear in the basin, replacing earlier, more pure carbonates. The uplift caused shallowing to the west, in the form of shelf progradation due to sediment influx. This shallowing is not observed to the east; instead, the palaeoenvironments show a deepening as a result of sea level rise.

Charwell Basin is a 6 km-wide structural depression situated at the boundary between the axial ranges and faulted and folded Marlborough Fault Zone of north-eastern South Island, New Zealand. The basin contains the piedmont reach of the Charwell River, and a series of late Quaternary loess-mantled alluvial terraces and terrace remnants that have been uplifted and translocated from their sediment source due to strike-slip motion along the Hope Fault which bounds the basin to its immediate north. The aim of this study was to provide an interdisciplinary, integrated and holistic analysis of late Quaternary landscape evolution and environmental change in Charwell Basin using terrain analysis, loess stratigraphy, soil chemistry and paleoecological data. The study contributes new understanding of New Zealand landscape and ecosystem responses to regional and global climatic change extending to Marine Isotope Stage (MIS) 6, and shows that climatically-forced shifts in biogeomorphic processes play a significant role in lowland landscape evolution. Morphometric analysis of alluvial terraces and terrace remnants of increasing age demonstrated geomorphic evolution through time, with a decrease in extent of original planar terrace tread morphology and an increase in frequency of steeper slopes and convexo-concave land elements. Paleotopographic analysis of a >150 ka terrace mantled by up to three loess sheets revealed multiple episodes of alluvial aggradation and degradation and, subsequent to river abandonment, gully incision prior to and coeval with loess accumulation. Spatial heterogeneity in loess sheet preservation showed a complex history of loess accumulation and erosion. A critical profile curvature range of -0.005 to -0.014 (d²z/dx², m⁻¹) for loess erosion derived from a model parameterised in different ways successfully predicted loess occurrence on adjacent slope elements, but incorrectly predicted loess occurrence on an older terrace remnant from which all loess has been eroded. Future analyses incorporating planform curvature, regolith erosivity and other landform parameters may improve identification of thresholds controlling loess occurrence in Charwell Basin and in other South Island landscapes. A loess chronostratigraphic framework was developed for, and pedogenic phases identified in, the three loess sheets mantling the >150 ka terrace. Except for one age, infrared-stimulated luminescence dates from both an upbuilding interfluve loess exposure and colluvial gully infill underestimated loess age with respect to the widespread Kawakawa/Oruanui Tephra (KOT; 27,097 ± 957 cal. yr BP), highlighting the need for improvements in the methodology. Onset of loess sheet 1 accumulation started at ca. 50 ka, with a break at ca. 27 ka corresponding to the extended Last Glacial Maximum (eLGM) interstadial identified elsewhere in New Zealand. Loess accumulation through MIS 3 indicates a regional loess flux, and that glaciation was not a necessary condition for loess generation in South Island. Loess accumulation and local alluvial aggradation are decoupled: the youngest aggradation event only covers ~12 kyr of the period of loess sheet 1 accumulation. Older local aggradation episodes could not be the source because their associated terraces are mantled by loess sheet 1. In the absence of numerical ages, the timing of L2 and L3 accumulation is inferred on the basis of an offshore clastic sediment record. The upbuilding phase of loess sheet 2 occurred in late MIS 5a/MIS 4, and loess sheet 3 accumulated in two phases in MIS 5b and late MIS 6. Biogenic silica data were used to reconstruct broad shifts in vegetation and changes in gully soil saturation status. During interglacial/interstadial periods (MIS 1, early MIS 3, MIS 5) Nothofagus-dominated forest covered the area in association with Microlaena spp grasses. Lowering of treeline altitude during glacial/stadial periods (MIS 2, MIS 3, MIS 5b, late MIS 6) led to reduction in forest cover and a mosaic of shrubs and Chionochloa spp, Festuca spp and Poa spp tussock grasses. Comparison of interfluve and gully records showed spatial heterogeneity in vegetation cover possibly related to environmental gradients of exposure or soil moisture. A post-KOT peak in gully tree phytoliths corresponds to the eLGM interstadial, and a shift to grass-dominated vegetation occurred during the LGM sensu stricto. Diatoms indicated the site became considerably wetter from ca. 36 ka, with peak wetness at ca. 30, 25 and 21 ka, possibly due to reduced evapotranspiration and/or increased precipitation from a combination of strengthened westerly winds and increased cloudiness, or strengthened southerly flow and increased precipitation. Human influence after ca. 750 yr BP led to re-establishment of grassland in the area, which deposited phytoliths mixed to 30 cm depth in the soil. A coupled gully colluvial infilling/vegetation record showed that sediment flux during the late Pleistocene was ~0.0019 m³ m⁻¹ yr⁻¹ under a shrubland/grassland mosaic, and Holocene sediment flux was ~0.0034 m³ m⁻¹ yr⁻¹ under forest. This increase of 60% through the last glacial-interglacial transition resulted from increased bioturbation and down-slope soil transport via root growth and treethrow, which formed a biomantle as evidenced by slope redistribution of the KOT. These results contrast with sediment transport rates and processes hypothesised to occur contemporaneously in adjacent mountain catchments. This suggests that intraregional biogeomorphic processes can differ significantly depending on topography and geological substrate, with different landscapes responding in unique ways to the same climate shifts. Analysis of Quaternary terrestrial landscape evolution in non-glaciated mountainous and lowland areas must therefore consider spatial and temporal heterogeneity in sediment fluxes and underlying transport processes.

The steep forearc slope along the northern sector of the obliquely convergent Hikurangi subduction zone is characteristic of non-accretionary and tectonically eroding continental margins, with reduced sediment supply in the trench relative to further south, and the presence of seamount relief on the Hikurangi Plateau. These seamounts influence the subduction process and the structurally-driven geomorphic development of the over-riding margin of the Australian Plate frontal wedge. The Poverty Indentation represents an unusual, especially challenging and therefore exciting location to investigate the tectonic and eustatic effects on this sedimentary system because of: (i) the geometry and obliquity of the subducting seamounts; (ii) the influence of multiple repeated seamount impacts; (iii) the effects of structurally-driven over-steeping and associated widespread occurrence of gravitational collapse and mass movements; and (iv) the development of a large canyon system down the axis of the indentation. High quality bathymetric and backscatter images of the Poverty Indentation submarine re-entrant across the northern part of the Hikurangi margin were obtained by scientists from the National Institute of Water and Atmospheric Research (NIWA) (Lewis, 2001) using a SIMRAD EM300 multibeam swath-mapping system, hull-mounted on NIWA’s research vessel Tangaroa. The entire accretionary slope of the re-entrant was mapped, at depths ranging from 100 to 3500 metres. The level of seafloor morphologic resolution is comparable with some of the most detailed Digital Elevation Maps (DEM) onshore. The detailed digital swath images are complemented by the availability of excellent high-quality processed multi-channel seismic reflection data, single channel high-resolution 3.5 kHz seismic reflection data, as well as core samples. Combined, these data support this study of the complex interactions of tectonic deformation with slope sedimentary processes and slope submarine geomorphic evolution at a convergent margin. The origin of the Poverty Indentation, on the inboard trench-slope at the transition from the northern to central sectors of the Hikurangi margin, is attributed to multiple seamount impacts over the last c. 2 Myr period. This has been accompanied by canyon incision, thrust fault propagation into the trench fill, and numerous large-scale gravitational collapse structures with multiple debris flow and avalanche deposits ranging in down-slope length from a few hundred metres to more than 40 km. The indentation is directly offshore of the Waipaoa River which is currently estimated to have a high sediment yield into the marine system. The indentation is recognised as the “Sink” for sediments derived from the Waipaoa River catchment, one of two target river systems chosen for the US National Science Foundation (NSF)-funded MARGINS “Source-to-Sink” initiative. The Poverty Canyon stretches 70 km from the continental shelf edge directly offshore from the Waipaoa to the trench floor, incising into the axis of the indentation. The sediment delivered to the margin from the Waipaoa catchment and elsewhere during sea-level high-stands, including the Holocene, has remained largely trapped in a large depocentre on the Poverty shelf, while during low-stand cycles, sediment bypassed the shelf to develop a prograding clinoform sequence out onto the upper slope. The formation of the indentation and the development of the upper branches of the Poverty Canyon system have led to the progressive removal of a substantial part of this prograding wedge by mass movements and gully incision. Sediment has also accumulated in the head of the Poverty Canyon and episodic mass flows contribute significantly to continued modification of the indentation by driving canyon incision and triggering instability in the adjacent slopes. Prograding clinoforms lying seaward of active faults beneath the shelf, and overlying a buried inactive thrust system beneath the upper slope, reveal a history of deformation accompanied by the creation of accommodation space. There is some more recent activity on shelf faults (i.e. Lachlan Fault) and at the transition into the lower margin, but reduced (~2 %) or no evidence of recent deformation for the majority of the upper to mid-slope. This is in contrast to current activity (approximately 24 to 47% shortening) across the lower slope and frontal wedge regions of the indentation. The middle to lower Poverty Canyon represents a structural transition zone within the indentation coincident with the indentation axis. The lower to mid-slope south of the canyon conforms more closely to a classic accretionary slope deformation style with a series of east-facing thrust-propagated asymmetric anticlines separated by early-stage slope basins. North of the canyon system, sediment starvation and seamount impact has resulted in frontal tectonic erosion associated with the development of an over-steepened lower to mid-slope margin, fault reactivation and structural inversion and over-printing. Evidence points to at least three main seamount subduction events within the Poverty Indentation, each with different margin responses: i) older substantial seamount impact that drove the first-order perturbation in the margin, since approximately ~1-2 Ma ii) subducted seamount(s) now beneath Pantin and Paritu Ridge complexes, initially impacting on the margin approximately ~0.5 Ma, and iii) incipient seamount subduction of the Puke Seamount at the current deformation front. The overall geometry and geomorphology of the wider indentation appears to conform to the geometry accompanying the structure observed in sandbox models after the seamount has passed completely through the deformation front. The main morphological features correlating with sandbox models include: i) the axial re-entrant down which the Poverty Canyon now incises; ii) the re-establishment of an accretionary wedge to the south of the indentation axis, accompanied by out-stepping, deformation front propagation into the trench fill sequence, particularly towards the mouth of the canyon; iii) the linear north margin of the indentation with respect to the more arcuate shape of the southern accretionary wedge; and, iv) the set of faults cutting obliquely across the deformation front near the mouth of the canyon. Many of the observed structural and geomorphic features of the Poverty Indentation also correlate well both with other sediment-rich convergent margins where seamount subduction is prevalent particularly the Nankai and Sumatra margins, and the sediment-starved Costa Rican margin. While submarine canyon systems are certainly present on other convergent margins undergoing seamount subduction there appears to be no other documented shelf to trench extending canyon system developing in the axis of such a re-entrant, as is dominating the Poverty Indentation. Ongoing modification of the Indentation appears to be driven by: i) continued smaller seamount impacts at the deformation front, and currently subducting beneath the mid-lower slope, ii) low and high sea-level stands accompanied by variations on sediment flux from the continental shelf, iii) over-steepening of the deformation front and mass movement, particularly from the shelf edge and upper slope.

A basin analysis was conducted at the Conway Flat coast (Marlborough Fault Zone, South Island, New Zealand) to investigate the interaction of regional and local structure in a transpressional plate boundary and its control on basin formation. A multi-tiered approach has been employed involving: (i) detailed analysis of sedimentary deposits; (ii) geomorphic mapping of terraces, fault traces and lineaments; (iii) dating of deposits by 14C and OSL and (iv) the integration of data to form a basin-synthesis in a sequence stratigraphy framework. A complex thrust fault zone (the Hawkswood Thrust Fault Zone), originating at the hinge of the thrust-cored Hawkswood anticline, is interpreted to be a result of west-dipping thrust faults joining at depth with the Hundalee Fault and propagating eastwards. The faults uplift and dissect alluvial fans to form terraces along the Conway Flat coast that provide the necessary relief to form the fan deltas. These terrace/fan surfaces are ~9 km long and ~3 km wide, composite features, with their upper parts representing sub-aerial alluvial fans. These grade into delta plains of Quaternary Gilbert-style fan deltas. Uplift and incision have created excellent 3D views of the underlying Gilbert-style fan delta complexes from topsets to prodelta deposits. Erosive contacts between the Medina, Rafa, Ngaroma and modern Conway fan delta deposits, coupled with changes in terrace elevations allow an understanding of the development of multiple inset terraces along the Conway Flat coast. These terraces are divided into five stages of evolution based on variations in sedimentary facies and geomorphic mapping: Stage I involves the uplift of the Hawkswood Range and subsequent increased sedimentation rate such that alluvial fans prograded to the sea to form the Medina fan delta Terrace. Stage II began with a period of incision, from lowering sea level or changes in the uplift and sedimentation rate and continued with the deposition of the Dawn and Upham fan deltas. Stage III starts with the incision of the Rafa Terrace and deposition of aggradational terraces in the upper reaches. Stage IV initiated by a period of incision followed by deposition of estuarine facies at ~8ka and Stage V began with a period of incision and continues today with the infilling of the incised valley by the modern fan delta of the Conway River and its continued progradation. New dates from within the Gilbert-type fan deltas along the Conway Flat coast are presented, using OSL and 14C dating techniques. Faulting at the Conway Flat coast began ~ 94 ka, based on the development of the Medina Terrace fan delta with uplift rates ~1.38~1.42 m/ka. The interplay of tectonics and sea level fluctuations continued as the ~79 ka Rafa Terrace fan deltas were created, with uplift rates calculated at ~1.39 m/ka. Detailed 14C ages from paleoforest (~8.4-~6.4 ka) in the Ngaroma Terrace and from the mouths of smaller streams have established uplift rates during the Holocene ~1-3 m/ka, depending on sea level.

Topography growth and sediment fluxes in active subduction margin settings are poorly understood. Geological record is often scarce or hardly accessible as a result of intensive deformation. The Hawke Bay forearc basin of the Hikurangi margin in New Zealand is well suited for studying morphstructural evolution. It is well preserved, partly emerged and affected by active tectonic deformation during Pleistocene stage for which we have well dated series and well-known climate and eustasy. The multidisciplinary approach, integrating offshore and onshore seismic interpretations, well and core data, geological mapping and sedimentological sections, results in the establishment of a detailed stratigraphic scheme for the last 1.1 Ma forearc basin fill. The stratigraphy shows a complex stack of 11 eustasy-driven depositional sequences of 20, 40 and 100 ka periodicity. These sequences are preserved in sub-basins that are bounded by active thrust structures. Each sequence is characterized by important changes of the paleoenvironment that evolves between the two extremes of the glacial maximum and the interglacial optimum. Thus, the Hawke Bay forearc domain shows segmentation in sub-basins separated by tectonic ridges during sea level lows that become submerged during sea level highs. Over 100 ka timescale, deformation along active structures together with isostasy are responsible of a progressive migration of sequence depocenters towards the arc within the sub-basins. Calculation of sediment volumes preserved for each of the 11 sequences allows the estimation of the sediment fluxes that transit throughout the forearc domain during the last 1.1 Ma. Fluxes vary from c. 3 to c. 6 Mt.a⁻¹. These long-term variations with 100 ka to 1 Ma timescale ranges are attributed to changes in the forearc domain tectonic configuration (strain rates and active structure distribution). They reflect the ability of sub-basin to retain sediments. Short-term variations of fluxes (<100 ka) observed within the last 150 ka are correlated to drastic Pleistocene climate changes that modified erosion rates in the drainage area. This implies a high sensitiveness and reactivity of the upstream area to environmental changes in terms of erosion and sediment transport. Such behaviour of the drainage basin is also illustrated by the important increase of sediment fluxes since the European settlement during the 18th century and the following deforestation.

The application of neutral dicopper helicates to the encapsulation of a number of anions was investigated. Two dicopper salen derived helicates were studied which contained phenolic and either iminophenyl (1) or oxime (2) donor groups. UV-visible spectroscopy was used to determine the binding stoichiometry and formation constants of the anion complexes. Complex binding was supported by electrospray ionisation mass spectrometry. Receptor 1 possessed a remarkable selectivity for sulfate in isopropanol (IPA) for which a log K value of 5.07 ± 0.24 was obtained. Receptor 2 bound all anions studied more strongly than 1. Crystal structural data supports the proposition that there is a steric barrier to contraction of 1 from the bulky iminophenyl groups. Receptor 2 was not restricted by the small oxime moieties allowing for optimum copper-anion interactions.

High rates of Neogene sediment influx to the offshore Canterbury Basin resulted in preservation of a high-resolution record of seismically resolvable sequences (~0.1-0.54 my periods). Subsequent sequence development was strongly influenced by submarine currents. This study focuses on correlating seismically interpreted sequence boundaries and sediment drifts architectures beneath the modern shelf and slope with sediment facies observed in cores from shelf Site U1351 and slope Site U1352 drilled by Integrated Ocean Drilling Program (IODP) Expedition 317. A traveltime-depth conversion was created using sonic and density logs and is compared with two previous traveltime-depth conversions for the sites. Eleven large elongate drifts were interpreted prior to drilling. Two new small-scale plastered slope drifts in the vicinity of the IODP sites, together with sediment waves drilled at Site U1352, have been interpreted as part of this study. Lithologic discontinuity surfaces and transitions together with associated sediment packages form the basis of identifying sequences and sequence boundaries in the cores. Contacts and facies were characterized using shipboard core descriptions, emphasizing grain-size contrasts and the natures of the lower and upper contacts of sediment packages. Lithologic surfaces in cores from sites U1351- (surfaces S1-S8) and U1352- (surfaces S1-S6) correlate with early Pleistocene to recent seismic sequence boundaries U12-U19 and U14-U19, respectively. The limited depths achieved by downhole logging, in particular sonic and density logs, together with poor recovery in the deeper section did not allow correlation of older lithologic surfaces. Slope Site U1352 experienced a complex interplay of along-strike and downslope depositional processes and cores provide information about the principal facies forming sediment waves. The general facies are fine-grained mud rich sediment interbedded decimeter-centimeter thick sand and sandy mud. Core evidence for current activity is reinforced at larger scale by seismic interpretations of sediment waves and drifts.
text

With increasing concerns of global warming and the impending exhaustion of fossil fuels attention is being turned to renewable sources of energy. The sun supplies 3 x 1024 J per year to the earth which is around 104 times more energy than what the human race consumes. The world’s energy needs would be satisfied if a mere 0.1% of the planet’s surface was covered with solar cells(< = 10%)1, causing the conversion of solar energy (sunlight) into electricity to represent a very practical renewable source. Past research into solar energy has produced a photovoltaic device, which when coupled with highly coloured coordination compounds, enables this conversion. This device is known as a dye-sensitised solar cell (DSSC). Further research has been conducted into the properties of the dyes, and has shown that highly coloured coordination compounds are able to convert solar energy into electrical energy with the highest efficiencies. The dominant compounds in this area to date have been Grätzel’s ruthenium complexes and porphyrins. However, there exists a class of smaller compounds called dipyrrins, described most simply as “half a porphyrin”, which possess many of the attractive qualities for DSSC dyes. Although there are no examples of ruthenium-dipyrrin complexes in the literature, the combination of advantageous properties from both components represent very attractive synthetic targets with huge potential as dyes for DSSCs. The objectives of this thesis were firstly to develop a series of dipyrrin complexes which would be suitable as dyes for DSSCs; then to fully characterise the complexes and investigate the spectroscopic properties of each complex; and finally to determine the suitability of the complexes as dyes for DSSCs. These objectives were fully met, resulting in a set of generic target compounds characterised via 1H NMR, 13C NMR, mass spectrometry (ESI-MS), elemental analysis, and x-ray crystallography. From analyses of the UV-visible, fluorescence, emission, and Raman spectra; and electrochemistry results; the complexes were concluded to be suitable as dyes for DSSC’s. An additional bonus is that the syntheses for these complexes are applicable to any dipyrrin, thus aiding future studies into the use of dipyrrins as dyes for DSSC’s. This thesis summarises the findings of the above outlined research project.