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Relevant bibliographies by topics / Cis-3-(2 -chloro-3,3,3-trifluoroprop-1-en-1-yl)-2 / Journal articles

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Journal articles on the topic 'Cis-3-(2 -chloro-3,3,3-trifluoroprop-1-en-1-yl)-2'

Author: Grafiati

Published: 4 June 2021

Last updated: 1 February 2022

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1

Rao, Guo-Wu, Xiao-Min Li, and Na-Bo Sun. "3-(2-Chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoromethyl)phenyl]cyclopropanecarboxamide." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (May 16, 2012): o1743. http://dx.doi.org/10.1107/s1600536812020922.

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In the title molecule, C16H14ClF6NO, the cyclopropane ring forms a dihedral angle of 70.82 (18)° with the benzene ring. The torsion angles about the ethylene and amide bonds are −2.2 (5) (Cl—C—C—C) and 0.8 (5)° (O—C—N—C). A supramolecular chain propagated by glide symmetry along [001] and mediated by N—H...O hydrogen bonds is observed in the crystal packing.

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2

Sun, Na-Bo, Guo-Wu Rao, and Jian-Bo Chu. "1-{[3-(2-Chloro-3,3,3-trifluoroprop-1-enyl)-2,2-dimethylcyclopropan-1-yl]carbonyl}-3-(methylsulfonyl)imidazolidin-2-one." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (May 16, 2012): o1744. http://dx.doi.org/10.1107/s1600536812021216.

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In the title molecule, C13H16ClF3N2O4S, the imidazolidine ring is approximately planar, the largest deviation from this plane being 0.025 (3) Å. The cyclopropane ring forms a dihedral angle of 64.1 (2)° with the imidazolidine ring. In the crystal, C—H...O hydrogen bonds are observed.

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3

Yan, Fan-Yong, Dong-Qing Liu, Jing-Yun Wen, Yun-Ying Gao, and Ai-Mei Li. "3-[(E)-2-Chloro-3,3,3-trifluoroprop-1-en-1-yl]-N-(2-fluorophenyl)-2,2-dimethylcyclopropane-1-carboxamide." Acta Crystallographica Section E Structure Reports Online 67, no. 1 (December 11, 2010): o60. http://dx.doi.org/10.1107/s1600536810050464.

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4

Liu, Dong-Qing, Fan-Yong Yan, Yun-Ying Gao, Lei Guo, and Zi Kong. "3-[(E)-2-Chloro-3,3,3-trifluoroprop-1-en-1-yl]-N-(2-chlorophenyl)-2,2-dimethylcyclopropane-1-carboxamide." Acta Crystallographica Section E Structure Reports Online 67, no. 1 (December 11, 2010): o61. http://dx.doi.org/10.1107/s1600536810050634.

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5

Prasath, R., S. Sarveswari, Seik Weng Ng, and Edward R. T. Tiekink. "(2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 69, no. 8 (July 20, 2013): o1274. http://dx.doi.org/10.1107/s1600536813019399.

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6

Prasath, R., S. Sarveswari, Seik Weng Ng, and Edward R. T. Tiekink. "(2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2,4-dimethylquinolin-3-yl)prop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 69, no. 8 (July 20, 2013): o1275. http://dx.doi.org/10.1107/s1600536813019405.

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7

Prasath, R., S. Sarveswari, Seik Weng Ng, and Edward R. T. Tiekink. "(2E)-3-(2-Chloro-8-methylquinolin-3-yl)-1-(2-methyl-4-phenylquinolin-3-yl)prop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 69, no. 8 (July 27, 2013): o1318. http://dx.doi.org/10.1107/s1600536813020229.

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8

Loh, Wan-Sin, Hoong-Kun Fun, S. Sarveswari, V. Vijayakumar, and B. Palakshi Reddy. "1-(6-Chloro-2-methyl-4-phenylquinolin-3-yl)-3-(3-methoxyphenyl)prop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 66, no. 1 (December 9, 2009): o91—o92. http://dx.doi.org/10.1107/s1600536809052179.

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9

Prasath, R., S. Sarveswari, Seik Weng Ng, and Edward R. T. Tiekink. "(2E)-3-(2-Chloro-7-methylquinolin-3-yl)-1-(6-chloro-2-methyl-4-phenylquinolin-3-yl)prop-2-en-1-one ethanol monosolvate." Acta Crystallographica Section E Structure Reports Online 69, no. 9 (August 14, 2013): o1414—o1415. http://dx.doi.org/10.1107/s1600536813022022.

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10

Prasath, R., S. Sarveswari, Seik Weng Ng, and Edward R. T. Tiekink. "(2E)-3-(6-Chloro-2-methoxyquinolin-3-yl)-1-(2-methyl-4-phenylquinolin-3-yl)prop-2-en-1-one acetone monosolvate." Acta Crystallographica Section E Structure Reports Online 69, no. 8 (July 27, 2013): o1319. http://dx.doi.org/10.1107/s1600536813020217.

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11

Viji, A. J., S. Sarveswari, V. Vijayakumar, Kong Wai Tan, and Edward R. T. Tiekink. "(2E)-1-(6-Chloro-2-methyl-4-phenylquinolin-3-yl)-3-phenylprop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 66, no. 7 (June 26, 2010): o1780. http://dx.doi.org/10.1107/s160053681002386x.

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12

Sarveswari, S., V. Vijayakumar, Seik Weng Ng, and Edward R. T. Tiekink. "(2E)-1-(6-Chloro-2-methyl-4-phenylquinolin-3-yl)-3-(4-chlorophenyl)prop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 67, no. 3 (February 12, 2011): o624. http://dx.doi.org/10.1107/s1600536811004740.

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13

Yan, Fan-Yong, and Dong-Qing Liu. "(E)-3-(2-Chloro-3,3,3-trifluoroprop-1-enyl)-N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)-2,2-dimethylcyclopropanecarboxamide." Acta Crystallographica Section E Structure Reports Online 63, no. 11 (October 3, 2007): o4201. http://dx.doi.org/10.1107/s160053680704408x.

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In the title compound, C23H17ClF3NO3, the dihedral angle between the dihydroanthracene and cyclopropane ring systems is 58.5 (4)°. The amino H atom forms an intramolecular hydrogen bond to a carbonyl O atom of the dioxodihydroanthracene moiety. The crystal packing is further stabilized by an intermolecular C—H...F contact.

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14

Narayana, Badiadka, Vinutha V. Salian, Balladka K. Sarojini, and Jerry P. Jasinski. "(2E)-1-(4-Chlorophenyl)-3-[4-(propan-2-yl)phenyl]prop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 70, no. 8 (July 5, 2014): o855. http://dx.doi.org/10.1107/s1600536814015281.

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In the title compound, C18H17ClO, the dihedral angle between the benzene rings is 53.5 (1)°. The mean plane of the prop-2-en-1-one group is twisted by 24.5 (8) and 33.5 (3)° from the chloro- and propanyl-substituted rings, respectively.

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15

Rizvi, Syed Umar Farooq, Matloob Ahmad, Mujahid Hussain Bukhari, Catherine Montero, Payel Chatterjee, Mervi Detorio, and Raymond F. Schinazi. "Anti-HIV-1 screening of (2E)-3-(2-chloro-6-methyl/methoxyquinolin-3-yl)-1-(aryl)prop-2-en-1-ones." Medicinal Chemistry Research 23, no. 1 (June 4, 2013): 402–7. http://dx.doi.org/10.1007/s00044-013-0652-y.

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16

Rizvi, Syed Umar Farooq, Hamid Latif Siddiqui, Tanvir Hussain, Muhammad Azam, and Masood Parvez. "(E)-3-(2-Chloro-6-methyl-3-quinolyl)-1-(2,3-dihydro-1,4-benzodioxin-6-yl)prop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 66, no. 4 (March 3, 2010): o744. http://dx.doi.org/10.1107/s1600536810007464.

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17

Fischer, Andreas, H. S. Yathirajan, B. V. Ashalatha, B. Narayana, and B. K. Sarojini. "(2E)-3-(Biphenyl-4-yl)-1-(4-bromophenyl)prop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 63, no. 3 (February 16, 2007): o1355—o1356. http://dx.doi.org/10.1107/s1600536807006915.

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The title compound, C21H15BrO, was obtained from 4-bromoacetophenone and biphenyl-4-carbaldehyde. The geometry of the molecule is unexceptional. The compound crystallizes isostructurally with the corresponding chloro compound.

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18

Kubono, Koji, Keita Tani, Masaaki Omote, Futa Ogawa, and Taisuke Matsumoto. "Crystal Structure of (E)-2-(3,3,3-trifluoroprop-1-en-1-yl)aniline." Acta Crystallographica Section E Crystallographic Communications 74, no. 10 (September 18, 2018): 1448–50. http://dx.doi.org/10.1107/s2056989018012756.

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The molecule of the title compound, C9H8F3N, adopts an E configuration with respect to the C=C double bond. The dihedral angle between the benzene ring and the prop-1-enyl group is 25.4 (3)°. In the crystal, molecules are linked via pairs of N—H...F hydrogen bonds into inversion dimers with an R 2 2(16) ring motif. The dimers are linked by C—H...N hydrogen bonds, forming a ribbon structure along the b-axis direction. The ribbons are linked by N—H...π and C—H...π interactions, generating a three-dimensional network.

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19

Chen, Hongping, Xinlu Wang, Pingxiang Liu, Qi Jia, Haolei Han, Changling Jiang, and Jing Qiu. "Determination of Three Typical Metabolites of Pyrethroid Pesticides in Tea Using a Modified QuEChERS Sample Preparation by Ultra-High Performance Liquid Chromatography Tandem Mass Spectrometry." Foods 10, no. 1 (January 18, 2021): 189. http://dx.doi.org/10.3390/foods10010189.

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Pyrethroid pesticides are widely used on tea plants, and their residues of high frequency and concentration have received great attention. Until recently, the residues of typical metabolites of pyrethroid pesticides in tea were unknown. Herein, a modified “quick, easy, cheap, effective, rugged and safe” (QuEChERS) method for the determination of three typical metabolites of pyrethroid pesticides in tea, using ultra performance liquid chromatography tandem mass spectrometry, was developed. The mixture of florisil, octadecylsilane, and graphite carbon black was employed as modified QuEChERS adsorbents. A Kinetex C18 column achieved good separation and chromatographic peaks of all analytes. The calibration curves of 3-phenoxybenzoic acid (3-PBA) and 4-fluoro-3-phenoxybenzoic acid (4-F-3-PBA) were linear in the range of 0.1–50 ng mL−1 (determination coefficient R2 higher than 0.999), and that of cis-3-(2-chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethylcyclopropanecarboxylic acid (TFA) was in the range of 1–100 ng mL−1 (R2 higher than 0.998). The method was validated and recoveries ranged from 83.0% to 117.3%. Intra- and inter-day precisions were lower than or equal to 13.2%. The limits of quantification of 3-PBA, 4-F-3-PBA, and TFA were 5, 2, and 10 μg kg−1, respectively. A total of 22 tea samples were monitored using this method, and 3-PBA and TFA were found in two green tea samples.

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20

Gupta, Apoorva, and Anand K. Halve. "Synthesis & Antifungal Screening of Novel Azetidin-2-ones." Open Chemistry Journal 2, no. 1 (February 27, 2015): 1–6. http://dx.doi.org/10.2174/1874842201502010001.

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A new series of 4-[3-chloro-2-(4-hydroxy-3-methoxybenzyllidene)-4-oxoazetidin-1-yl]amino-N-(substituted)benzenesulfonamide, 4-{3-chloro-2-[5-methoxy-2-nitro-4-(prop-2-en-1-yloxy)benz yllidene]-4-oxoazetidin-1-yl}]amino}-N-(substituted)benzenesulfonamide and 4-{3-chloro-2-[4-hydroxy-3-methoxy-5-(prop-2-en-1-yl)benzylidene]-4-oxoazetidin-1-yl}amino}-N-(substituted) benzenesulfonamide were synthesized using appropriate synthetic route. The chemical structures of all the synthesized compounds were deduced on the basis of elemental analysis and spectroscopic data. The antifungal activity of the synthesized compounds was screened against several fungus. The synthesized compounds show potent antifungal activity against Aspergillus niger & Aspergillus flavus and significant structure-activity relationship (SAR) trends.

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21

Rizvi, Syed Umar Farooq, Hamid Latif Siddiqui, Masood Parvez, Matloob Ahmad, Waseeq Ahmad Siddiqui, and Muhammad Masoom Yasinzai. "Antimicrobial and Antileishmanial Studies of Novel (2E)-3-(2-Chloro-6-methyl/methoxyquinolin-3-yl)-1-(Aryl)prop-2-en-1-ones." CHEMICAL & PHARMACEUTICAL BULLETIN 58, no. 3 (2010): 301–6. http://dx.doi.org/10.1248/cpb.58.301.

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22

Gao, Wentao, Shuai Lan, Yang Li, Hong Zhang, and Mingqin Chang. "A Facile synthesis of Novel Indole-Based Chalcones (E)-1-(2-Chloro-1-Methyl-1H-Indol-3-Yl)-3-Arylprop-2-En-1-Ones." Journal of Chemical Research 38, no. 9 (September 2014): 553–57. http://dx.doi.org/10.3184/174751914x14108592918139.

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23

Mafud, Ana C., Milene A. R. Oliviera, and Maria T. P. Gambardella. "(Benzyl isocyanide-κC1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)." Acta Crystallographica Section E Structure Reports Online 69, no. 1 (December 8, 2012): m36. http://dx.doi.org/10.1107/s1600536812049768.

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24

Sanjeeva Murthy, T. N., S. Naveen, C. S. Chidan Kumar, M. K. Veeraiah, Ching Kheng Quah, B. P. Siddaraju, and Ismail Warad. "Crystal structure and Hirshfeld surface analysis of (E)-3-(2-chloro-4-fluorophenyl)-1-(2,5-dichlorothiophen-3-yl)prop-2-en-1-one." Acta Crystallographica Section E Crystallographic Communications 74, no. 8 (July 24, 2018): 1134–37. http://dx.doi.org/10.1107/s2056989018010216.

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In the title chalcone–thiophene derivative, C13H6Cl3FOS, the aromatic rings are inclined to one another by 12.9 (2)°, and the thiophene ring is affected by π-conjugation. In the crystal, molecules are linked by C—H...F hydrogen bonds, forming an R 2 2(8) ring motif. A Hirshfeld surface analysis was conducted to verify the contribution of the different intermolecular interactions. The shape-index surface clearly shows that the two sides of the molecules are involved in the same contacts with neighbouring molecules and the curvedness plots show flat surface patches characteristic of planar stacking.

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25

Owens, Eric, Joseph Tawney, and Maged Henary. "2-{(E)-2-[(3E)-2-Chloro-3-{(2E)-2-[1,1-dimethyl-3-(3-phenylpropyl)-1,3-dihydro-2H-benzo[e]indol-2-ylidene]-ethylidene}cyclohex-1-en-1-yl]ethenyl}-1,1-dimethyl-3-(3-phenylpropyl)-1H-benzo[e]indolium Iodide." Molbank 2014, no. 1 (January 30, 2014): M814. http://dx.doi.org/10.3390/m814.

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26

El-Brollosy, Nasser R., Mohamed I. Attia, Ali A. El-Emam, Seik Weng Ng, and Edward R. T. Tiekink. "6-Chloro-1-({[(2E)-2-methyl-3-phenylprop-2-en-1-yl]oxy}methyl)-1,2,3,4-tetrahydroquinazoline-2,4-dione." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (May 19, 2012): o1770—o1771. http://dx.doi.org/10.1107/s1600536812020405.

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In the title compound, C19H17ClN2O3, the conformation about the ethylene bond [1.333 (2) Å] is E. The ten atoms comprising the quinazoline ring are essentially planar (r.m.s. deviation = 0.032 Å) and their mean plane forms a dihedral angle of 13.89 (7)° with the terminal phenyl ring; the molecule has an open conformation as these substituents are directed away from each other. In the crystal, centrosymmetrically related molecules are connected via N—H...O hydrogen bonds between the amide groups, leading to eight-membered {...HNCO}2 synthons. These are consolidated into a three-dimensional architecture by C—H...O, C—H...π and π–π interactions [ring centroid(N2C4)...centroid(C6) distance = 3.5820 (11) Å].

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27

Shakhmaev, Rinat N., Alisa Sh Sunagatullina, and Vladimir V. Zorin. "SYNTHESIS OF INDIVIDUAL ISOMERS OF 2-(3-CHLOROPROP-2-EN-1-YL)CYCLOHEXANONE." IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA KHIMICHESKAYA TEKHNOLOGIYA 62, no. 8 (August 19, 2019): 66–70. http://dx.doi.org/10.6060/ivkkt.20196208.5897.

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Recently, vinyl chlorides has been increasingly used as electrophilic partners in various cross-coupling reactions. In contrast to inaccessible and expensive vinyl bromides and iodides, in many cases vinyl chlorides are highly active in the presence of not only traditional palladium complexes, but also economical and safe compounds of iron, cobalt and nickel. Earlier, we reported on the development of new approaches to the getting of stereochemically pure (E)- and (Z)-vinyl chlorides and their successful use at the synthesis of medicines and insect pheromones. Continuing this work, an effective method of the synthesis of (E)- and (Z)-isomers of 2-(3-chloroprop-2-en-1-yl)cyclohexanone - convenient precursors of 2-(alk-2-en-1-yl)cyclohexanones, known flavors and intermediates in the synthesis of polycyclic compounds was developed. In the reaction of ethyl 2-oxocyclohexanecarboxylate with the (E)- and (Z)-isomers of 1,3-dichloropropene under the phase-transfer catalysis conditions in the presence of K2CO3, the corresponding (E)- and (Z)-isomers of ethyl 1-(3-chloroprop-2-en-1-yl)-2-oxocyclohexanecarboxylate were obtained in high yields (80-86%), without allyl rearrangement. The complete retention of the configuration of the chlorovinyl group is observed. Standard methods of the decarboxylation of isomers of ethyl 1-(3-chloroprop-2-en-1-yl)-2-oxocyclohexanecarboxylate under acidic or basic conditions result in very average yields of the corresponding chlorovinyl ketones. The best results were obtained by their decarbalkoxylation in slightly modernized Krapcho conditions. Carrying out reaction in N-methylpyrrolidone at 140-150 °C in the presence of 3 eq. LiCl and 2 eq. of H2O leads to individual (E)- and (Z)-isomers of 2-(3-chloroprop-2-en-1-yl)cyclohexanone in 79-82% yields and a stereochemical purity of ~ 99%. The structure of the obtained compounds were confirmed by HRGC, NMR, and GC/MS data. The configuration of the vinyl group was proved by the coupling constants of the vinyl hydrogens, equal to 13.2-13.4 and 7.0-7.3 Hz for the (E)- and (Z)-products, respectively, as well as by the downfield shift of the allyl carbon atom of trans-isomers by ~4 ppm as compared to the cis-analogs.

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28

Peng, Xin-Mei, Ben-Tao Yin, and Cheng-He Zhou. "(Z)-3-(4-Chlorophenyl)-1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)prop-2-en-1-one." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (May 19, 2012): o1828. http://dx.doi.org/10.1107/s1600536812022118.

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The asymmetric unit of the title compound, C17H10ClF2N3O, contains three independent molecules. In each molecule, the C=C bond has a cis conformation with respect to the triazole and chlorophenyl groups. The dihedral angles formed by the triazole ring with the diflurophenyl and chlorophenyl benzene rings, respectively, are 20.10 (14) and 73.22 (15), 25.31 (15) and 84.44 (15), and 16.44 (13) and 61.72 (14)° in the three molecules while the dihedral angles between the benzene rings are 66.54 (13), 85.82 (12) and 58.37 (12)°.

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29

Rizvi, Syed Umar Farooq, Hamid Latif Siddiqui, Masood Parvez, Matloob Ahmad, Waseeq Ahmad Siddiqui, and Muhammad Masoom Yasinzai. "ChemInform Abstract: Antimicrobial and Antileishmanial Studies of Novel (2E)-3-(2-Chloro-6-methyl/methoxyquinolin-3-yl)-1- (aryl)prop-2-en-1-ones." ChemInform 41, no. 35 (August 5, 2010): no. http://dx.doi.org/10.1002/chin.201035153.

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30

Gao, Wentao, Shuai Lan, Yang Li, Hong Zhang, and Mingqin Chang. "ChemInform Abstract: A Facile Synthesis of Novel Indole-Based Chalcones (E)-1-(2-Chloro-1-methyl-1H-indol-3-yl)-3-arylprop-2-en-1-ones." ChemInform 46, no. 14 (March 19, 2015): no. http://dx.doi.org/10.1002/chin.201514140.

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31

Desai, N. C., and Amit M. Dodiya. "Conventional and microwave techniques for synthesis and antimicrobial studies of novel 1-[2-(2-chloro(3-quinolyl))-5-(4-nitrophenyl)-(1,3,4-oxadiazolin-3-yl)]-3-(aryl)prop-2-en-1-ones." Medicinal Chemistry Research 21, no. 7 (May 25, 2011): 1480–90. http://dx.doi.org/10.1007/s00044-011-9670-9.

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32

Anderson, Alan J., Ray J. Butcher, and Edward Ollie. "Syntheses and structures of two benzoyl amides: 2-chloro-4-ethoxy-3,5-dimethoxy-N-(3-oxocyclohex-1-en-1-yl)benzamide and 2-chloro-N-(5,5-dimethyl-3-oxocyclohex-1-en-1-yl)-4-ethoxy-3,5-dimethoxybenzamide." Acta Crystallographica Section E Crystallographic Communications 77, no. 3 (February 26, 2021): 314–18. http://dx.doi.org/10.1107/s2056989021001778.

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The first title benzoyl amide, C17H20ClNO5 (3a), crystallizes in the monoclinic space group P21/c with Z = 4 and the second, C19H24ClNO5 (3b), also crystallizes in P21/c with Z = 8 (Z′ = 2), thus there are two independent molecules in the asymmetric unit. In 3a, the phenyl ring makes a dihedral angle of 50.8 (3)° with the amide moiety with the C=O group on the same side of the molecule as the C—Cl group. One methoxy group is almost in the plane of the benzene ring, while the ethoxy and other methoxy substituent are arranged on opposite sides of the ring with the ethoxy group occupying the same side of the ring as the C=O group in the amide moiety. For one of the two molecules in 3b, both the amide and 5,5-dimethyl-3-oxocyclohex-1-en-1-yl moieties are disordered over two sets of sites with occupancies of 0.551 (2)/0.449 (2) with the major difference between the two conformers being due to the conformation adopted by the cyclohex-2-en-1-one ring. The three molecules in 3b (i.e., the undisordered molecule and the two disorder components) differ in the arrangement of the subsituents on the phenyl ring and the conformation adopted by their 5,5-dimethyl-3-oxocyclohex-1-en-1-yl moieties. In the crystal of 3a, N—H...O hydrogen bonds link the molecules into a zigzag chain propagating in the [001] direction. For 3b a combination of C—H...O and N—H...O intermolecular interactions link the molecules into a zigzag ribbon propagating in the [001] direction.

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33

Zhang, Jiming, Xiaoming Zhao, and Long Lu. "Novel synthesis of 3-(3,3,3-trifluoroprop-1-en-2-yl)furans via stereoselective processing and palladium-catalyzed cycloisomerization." Tetrahedron Letters 48, no. 11 (March 2007): 1911–13. http://dx.doi.org/10.1016/j.tetlet.2007.01.097.

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34

Ooi, Chin Wei, Hoong-Kun Fun, Ching Kheng Quah, Murugan Sathishkumar, and Alagusundaram Ponnuswamy. "(Z)-3-(4-Methylphenyl)-2-[(2-phenylcyclohex-2-en-1-yl)imino]-1,3-thiazolidin-4-one." Acta Crystallographica Section E Structure Reports Online 68, no. 6 (May 19, 2012): o1796—o1797. http://dx.doi.org/10.1107/s1600536812021691.

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The title compound, C22H22N2OS, exists in a cis conformation with respect to the N=C bond. The cyclohexene ring adopts a distorted sofa conformation. The thiazolidine ring is essentially planar with a maximum deviation of 0.025 (2) Å and forms dihedral angles of 63.50 (7) and 57.52 (6)° with the benzene rings. In the crystal, molecules are linked by C—H...O and C—H...N hydrogen bonds, generating R 2 2(8) ring motifs, and forming infinite chains along the c axis. The crystal is further consolidated by C—H...π interactions.

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35

Ikeda, Akari, Masaaki Omote, Shiho Nomura, Miyuu Tanaka, Atsushi Tarui, Kazuyuki Sato, and Akira Ando. "Oxidative 3,3,3-trifluoropropylation of arylaldehydes." Beilstein Journal of Organic Chemistry 9 (November 11, 2013): 2417–21. http://dx.doi.org/10.3762/bjoc.9.279.

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A reaction between (E)-trimethyl(3,3,3-trifluoroprop-1-en-1-yl)silane (1) and arylaldehydes 2 was triggered by fluoride anions to afford aryl 3,3,3-trifluoropropyl ketones 3 in moderate to good yield. A mechanistic study of this reaction indicated that it occurred via an allyl alkoxide (4). A subsequent 1,3-proton shift of the benzylic proton of 4 forms 3. This reaction involves oxidative 3,3,3-trifluoropropylation of an arylaldehyde to afford 4,4,4-trifluoro-1-arylbutan-1-one.

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36

Caracelli, Ignez, Julio Zukerman-Schpector, Rodrigo L. O. R. Cunha, and Edward R. T. Tiekink. "Crystal structure of (E)-dichloro(1-chloro-3-methoxyprop-1-en-2-yl)(4-methoxyphenyl)-λ4-tellane, C11H13Cl3O2Te." Zeitschrift für Kristallographie - New Crystal Structures 235, no. 6 (October 27, 2020): 1535–37. http://dx.doi.org/10.1515/ncrs-2020-0380.

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37

Desai, N. C., and Amit M. Dodiya. "Conventional and microwave techniques for the synthesis and antimicrobial studies of novel 1-[2-(2-chloro-6-methyl(3-quinolyl))-5-(4-nitrophenyl)-(1,3,4-oxadiazolin-3-yl)]-3-(aryl)prop-2-en-1-ones." Arabian Journal of Chemistry 9 (September 2016): S379—S387. http://dx.doi.org/10.1016/j.arabjc.2011.05.004.

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38

Naresh, P., B. Pramodh, S. Naveen, S. Ganguly, J. Panda, K. Sunitha, W. Maniukiewicz, and N. K. Lokanath. "Cis and trans isomers of 1-(5-bromothiophen-2-yl)-3-(10-chloroanthracen-9-yl)prop-2-en-1-one: Synthesis and characterization." Journal of Molecular Structure 1236 (July 2021): 130228. http://dx.doi.org/10.1016/j.molstruc.2021.130228.

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39

Abdullah, Amzar Ahlami, Nur Hafiq Hanif Hassan, Suhana Arshad, Nuridayanti Che Khalib, and Ibrahim Abdul Razak. "(E)-1-(Anthracen-9-yl)-3-(2-chloro-6-fluorophenyl)prop-2-en-1-one: crystal structure and Hirshfeld surface analysis." Acta Crystallographica Section E Crystallographic Communications 72, no. 5 (April 8, 2016): 648–51. http://dx.doi.org/10.1107/s2056989016005028.

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In the title compound, C23H14ClFO, the enone moiety adopts anEconformation. The dihedral angle between the benzene and anthracene ring is 63.42 (8)° and an intramolecular C—H...F hydrogen bond generates anS(6) ring motif. In the crystal, molecules are arranged into centrosymmetric dimersviapairs of C—H...F hydrogen bonds. The crystal structure also features C—H...π and π–π interactions. Hirshfeld surface analysis was used to confirm the existence of intermolecular interactions.

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40

Macías, M. A., J. A. Henao, Lina María Acosta, and Alirio Palma. "Synthesis and X-ray diffraction data of 6,8-dimethyl-cis-2-vinyl-2,3,4,5-tetrahydro-1H-benzo[b]azepin-4-ol and 8-chloro-9-methyl-cis-2-(prop-1-en-2-yl)-2,3,4,5-tetrahydro-1H-benzo[b]azepin-4-ol." Powder Diffraction 26, no. 4 (December 2011): 346–49. http://dx.doi.org/10.1154/1.3656975.

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The 6,8-dimethyl-cis-2-vinyl-2,3,4,5-tetrahydro-1H-benzo[b]azepin-4-ol (2a) (Chemical formula C14H19NO) and 8-chloro-9-methyl-cis-2-(prop-1-en-2-yl)-2,3,4,5-tetrahydro-1H-benzo[b]azepin-4-ol (2b) (Chemical formula C14H18ClNO) were prepared via the reductive cleavage of the bridged N-O bond of the corresponding 1,4-epoxytetrahydro-1-benzazepines. The X-ray powder diffraction patterns for the new compounds were obtained. The compound 2a was found to crystallize in an orthorhombic system with space group Pmn21 (No. 31), refined unit-cell parameters a = 19.422(6) Å, b = 6.512(3) Å, c = 9.757(4) Å and V = 1234.0(5) Å3. The compound 2b was found to crystallize in a monoclinic system with space group P21/m (No. 11), refined unit-cell parameters a = 17.570(4) Å, b = 8.952(3) Å, c = 14.985(4) Å, β = 101.66(2)°, and V = 2308.3(9) Å3.

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41

Mikhed’kina, E. I., O. S. Bylina, I. I. Mel’nik, and D. T. Kozhich. "Reaction of ethyl 4-[(E)-1-chloro-3-oxoprop-1-en-1-yl]-3,5-dimethyl-1H-pyrrole-2-carboxylate with hydrazines." Russian Journal of Organic Chemistry 45, no. 4 (April 2009): 564–71. http://dx.doi.org/10.1134/s1070428009040162.

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42

Mafud, Ana C., Milene A. R. Oliviera, and Maria T. P. Gambardella. "μ-Azido-κ2N1:N1-μ-chlorido-bis[(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-κ2C1,N)palladium(II)] chloroform monosolvate." Acta Crystallographica Section E Structure Reports Online 69, no. 1 (December 8, 2012): m15. http://dx.doi.org/10.1107/s1600536812047927.

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43

Sarveswari, S., and V. Vijayakumar. "A rapid microwave assisted synthesis of 1-(6-chloro-2-methyl-4-phenylquinolin-3-yl)-3-(aryl)prop-2-en-1-ones and their anti bacterial and anti fungal evaluation." Arabian Journal of Chemistry 9 (September 2016): S35—S40. http://dx.doi.org/10.1016/j.arabjc.2011.01.032.

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44

Zaini, Muhamad Fikri, Ibrahim Abdul Razak, Wan Mohd Khairul, and Suhana Arshad. "Crystal structure and optical spectroscopic analyses of (E)-3-(1H-indol-2-yl)-1-(4-nitrophenyl)prop-2-en-1-one hemihydrate." Acta Crystallographica Section E Crystallographic Communications 74, no. 11 (October 16, 2018): 1589–94. http://dx.doi.org/10.1107/s2056989018014329.

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The asymmetric unit of the title compound, 2C17H12N2O3·H2O comprises two molecules of (E)-3-(1H-indol-2-yl)-1-(4-nitrophenyl)prop-2-en-1-one and a water molecule. The main molecule adopts an s-cis configuration with respect to the C=O and C=C bonds. The dihedral angle between the indole ring system and the nitro-substituted benzene ring is 37.64 (16)°. In the crystal, molecules are linked by O—-H...O and N—H...O hydrogen bonds, forming chains along [010]. In addition, weak C—H...O, C—H...π and π–π interactions further link the structure into a three-dimensional network. The optimized structure was generated theoretically via a density functional theory (DFT) approach at the B3LYP/6–311 G++(d,p) basis level and the HOMO–LUMO behaviour was elucidated to determine the energy gap. The obtained values of 2.70 eV (experimental) and 2.80 eV (DFT) are desirable for optoelectronic applications. The intermolecular interactions were quantified and analysed using Hirshfeld surface analysis.

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45

Wang, Aoli, Xixiang Li, Hong Wu, Fengming Zou, Xiao-E. Yan, Cheng Chen, Chen Hu, et al. "Discovery of (R)-1-(3-(4-Amino-3-(3-chloro-4-(pyridin-2-ylmethoxy)phenyl)-1H-pyrazolo[3,4-d]pyrimidin-1-yl)piperidin-1-yl)prop-2-en-1-one (CHMFL-EGFR-202) as a Novel Irreversible EGFR Mutant Kinase Inhibitor with a Distinct Binding Mode." Journal of Medicinal Chemistry 60, no. 7 (March 22, 2017): 2944–62. http://dx.doi.org/10.1021/acs.jmedchem.6b01907.

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46

Kedjadja, Allaoua, Rachid Merdes, Sofiane Bouacida, Thierry Roisnel, and Ali Belfaitah. "(2E,2′E)-1,1′-Bis(6-chloro-2-methyl-4-phenylquinolin-3-yl)-3,3′-(1,4-phenylene)diprop-2-en-1-one ethyl acetate disolvate." Acta Crystallographica Section E Structure Reports Online 69, no. 1 (December 8, 2012): o37—o38. http://dx.doi.org/10.1107/s1600536812049422.

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47

Kanamaru, Hiroshi, Kazuo Kawahara, Takeshi Kamada, Akira Yoshitake, and Iwao Nakatsuka. "14C-Labelling of prallethrin SF, (4S)-1-OXO-2-propargyl-3-methylcyclopent-2-en-4-yl (1R)-CIS- and (1R)-trans-chrysanthemates." Journal of Labelled Compounds and Radiopharmaceuticals 23, no. 9 (September 1986): 995–1004. http://dx.doi.org/10.1002/jlcr.2580230912.

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48

Hasratyan, A., G. Danagulyan, and H. Attaryan. "DEVELOPMENT OF TECHNOLOGY FOR LOW-TONNAGE PRODUCTION OF VINYL ACETYLENE ON THE BASIS OF 1,3-DICHLORBUT-2-ENE." ASJ 1, no. 51 (August 11, 2021): 41–44. http://dx.doi.org/10.31618/asj.2707-9864.2021.1.50.116.

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The process of dehydrochlorination of 1,3-dichlorobut-2-ene using caustic potassium in ethylene glycol has been studied, and a technological scheme for the production of vinyl acetylene has been proposed. It is noted that during the process of dehydrochlorination of 1,3-dichlorobut-2-ene, in addition to vinyl acetylene, acetylene homologues are also formed, which are easily separated from commercial vinyl acetylene. Composition and percentage of the formed acetylene homologues has been determined. In addition to chloroprene, three more compounds were separated and identified as by-products formed during the dehydrochlorination of 1,3-dichlorobut-2-ene – 3-(chloro-1-[3-chlorobut-2-en-1-yl]oxy)but-2-en, 1-(but-2-yn1-yloxy)-3-chlorobut-2-ene and 1-(but-2-ynyloxy)but-2-yne.

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49

Hřebabecký, Hubert, and Antonín Holý. "Synthesis of Carbocyclic 4'-C-Hydroxymethyl Analogues of Azidodeoxythymidine, Deoxythymidine, Deoxydidehydrothymidine and Thymidine Carba Analogue with Fused Oxetane Ring." Collection of Czechoslovak Chemical Communications 65, no. 3 (2000): 395–406. http://dx.doi.org/10.1135/cccc20000395.

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Tosylation of (±)-1-[trans-4-hydroxy-3,3-bis(hydroxymethyl)cyclopentyl]-5-methylpyrimidine-2(1H),4(3H)-dione (1) and (±)-1-[cis-4-hydroxy-3,3-bis(hydroxymethyl)cyclopentyl]-5-methylpyrimidine-2(1H),4(3H)-dione (2) and treatment of the obtained 1-{(1R*,3R*,4S*)- 4-hydroxy-3-(hydroxymethyl)-3-[(tosyloxy)methyl]cyclopentyl}-5-methylpyrimidine- 2(1H),4(3H)-dione (6) and 1-{(1R*,3S*,4R*)-4-hydroxy-3-(hydroxymethyl)-3-[(tosyloxy)- methyl]cyclopentyl}-5-methylpyrimidine-2(1H),4(3H)-dione (9) with methanolic sodium methoxide gave 1-[(1R*,4S*,6S*)-4-hydroxymethyl-2-oxabicyclo[3.2.0]hept-6-yl]-5-methylpyrimidine-2(1H),4(3H)-dione (7) and 1-[(1R*,4S*,6R*)-4-hydroxymethyl-2-oxabicyclo[3.2.0]hept-6-yl]-5-methylpyrimidine-2(1H),4(3H)-dione (10), respectively. Treatment of (±)-1-{cis-4-mesyloxy-3,3-bis[(trityloxy)methyl]cyclopentyl}-5-methylpyrimidine-2(1H),4(3H)-dione (11), which was prepared from 2 by tritylation and mesylation, with 1,8-diazabicyclo[5.4.0]undec-7-ene in dimethylformamide afforded after deprotection (±)-1-[4,4-bis(hydroxymethyl)cyclopent-2-en-1-yl]-5-methylpyrimidine-2(1H),4(3H)-dione (14). Hydrogen- ation of 14 led to (±)-1-[3,3-bis(hydroxymethyl)cyclopentyl]-5-methylpyrimidine-2(1H),4(3H)- dione (15). (±)-1-{trans-4-Mesyloxy-3,3-bis[(trityloxy)methyl]cyclopentyl}-5-methylpyrimidine- 2(1H),4(3H)-dione (17), which was prepared from 1, was converted to (1R*,9R*)-6-methyl-5-oxo-11,11-bis(trityloxymethyl)-2-oxa-4,8-diazatricyclo[7.2.1.03,8]dodec-3,6-diene (18). The compound 18 was deprotected and heated with lithium azide in dimethylformamide to give (±)-1-[trans-4-azido-3,3-bis(hydroxymethyl)cyclopentyl]-5-methylpyrimidine-2(1H),4(3H)-dione (21).

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Ashok, D., M. Sarasija, D. Shravani, B. Vijayalaxmi, and K. Sudershan. "Microwave assisted selective synthesis of (E)-1-(4-Chloro-7-hydroxy-2-aryl-2H-chromen-6-yl)-3-arylprop-2-en-1-ones and their antimicrobial activity." Russian Journal of General Chemistry 86, no. 4 (April 2016): 930–33. http://dx.doi.org/10.1134/s1070363216040290.

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