Academic literature on the topic 'Chlorohydrocarbons'

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Journal articles on the topic "Chlorohydrocarbons"

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Rantio, Tiina. "Chlorohydrocarbons in pulp mill effluent and the environment III. Persistent chlorohydrocarbon pollutants." Chemosphere 32, no. 2 (January 1996): 253–65. http://dx.doi.org/10.1016/0045-6535(95)00337-1.

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Paasivirta, Jaakko. "ChemInform Abstract: Alkylaromatic Chlorohydrocarbons." ChemInform 31, no. 24 (June 8, 2010): no. http://dx.doi.org/10.1002/chin.200024251.

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Shevko, V. M., and N. B. Badirova. "Thermodynamic Modeling of ZnO Chlorination by Chlorohydrocarbons by Using «Astra» Software." Eurasian Chemico-Technological Journal 12, no. 2 (January 11, 2010): 165. http://dx.doi.org/10.18321/ectj40.

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The disposal and recycling of chlorohydrocarbons waste from organic synthesis which is annually produced at least 1,5 million tons is one of the global problems and is under the great UN's attention. Organochlorine residues are xenobiotics and adversely affect the environment. Thermodynamic modeling of interactions in the systems ZnO-CHxCly (x + y= 4)-O2 for determination of the theoretical content of chlorohydrocarbons as chlorinating agents for extracting nonferrous metals from very concentrated ore is presented in this article. The studies were conducted using the "Astra" software based on the principle of maximum entropy. Infobase of the "Astra" complex contains information on 5547 compounds, 79 items codified in the National Bureau of Standards and the Joint Institute for High Temperatures, Russian Academy of Sciences.
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Straka, Martin, Květoslav Růžička, Michal Fulem, and Ctirad Červinka. "Heat capacities of selected chlorohydrocarbons." Fluid Phase Equilibria 336 (December 2012): 128–36. http://dx.doi.org/10.1016/j.fluid.2012.09.001.

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Yang, Liu, Xu Guangzhi, and Sha Qinggui. "ESR STUDY ON THE PHOTOLYSIS OF CHLOROHYDROCARBONS." Acta Physico-Chimica Sinica 5, no. 05 (1989): 525–30. http://dx.doi.org/10.3866/pku.whxb19890504.

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Agarwal, S. K., J. J. Spivey, and J. B. Butt. "Catalyst deactivation during deep oxidation of chlorohydrocarbons." Applied Catalysis A: General 82, no. 2 (March 1992): 259–75. http://dx.doi.org/10.1016/0926-860x(92)85009-z.

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INAGAKI, Atsushi, Eisho OKADA, and Hideki KAWAGUCHI. "Photodecomposition of Volatile Chlorohydrocarbons Using Fe(III)-salt." Journal of Japan Society on Water Environment 18, no. 8 (1995): 631–37. http://dx.doi.org/10.2965/jswe.18.631.

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Miyasaka, Erina, Tomoyuki Hamaguchi, and Tomoyuki Yatsuhashi. "Graphitization of Chlorohydrocarbons in Laser-induced Plasma Filaments." IEEJ Transactions on Electronics, Information and Systems 135, no. 9 (2015): 1075–79. http://dx.doi.org/10.1541/ieejeiss.135.1075.

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MIYASAKA, ERINA, TOMOYUKI HAMAGUCHI, and TOMOYUKI YATSUHASHI. "Graphitization of Chlorohydrocarbons in Laser-Induced Plasma Filaments." Electronics and Communications in Japan 99, no. 10 (September 15, 2016): 51–57. http://dx.doi.org/10.1002/ecj.11873.

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Vittal Prasad, T. E., A. Phanibhushan, and D. H. L. Prasad. "Bubble temperature measurements on m-cresol with some chlorohydrocarbons." Fluid Phase Equilibria 153, no. 1 (November 1998): 81–85. http://dx.doi.org/10.1016/s0378-3812(98)00406-3.

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Dissertations / Theses on the topic "Chlorohydrocarbons"

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Costanza, Jed. "Degradation of tetrachloroethylene and trichloroethylene under thermal remediation conditions." Diss., Available online, Georgia Institute of Technology, 2005, 2005. http://etd.gatech.edu/theses/available/etd-08262005-021152/.

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Thesis (Ph. D.)--Civil & Environmental Engineering, Georgia Institute of Technology, 2006.
Pennell, Kurt, Committee Chair ; Lawrence Bottomley, Committee Member ; James Mulholland, Committee Member ; Carolyn Ruppel, Committee Member ; D. Webster, Committee Member. Includes bibliographical references.
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Dayan, Hannah. "Isotopic fractionation of chlorinated ethenes during reductive dehalogenation by zero valent iron." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/tape17/PQDD_0008/MQ36111.pdf.

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Shirley, Matt, and n/a. "Characterisation of an 84 kb linear plasmid that encodes DDE cometabolism in Terrabacter sp. strain DDE-1." University of Otago. Department of Microbiology & Immunology, 2006. http://adt.otago.ac.nz./public/adt-NZDU20060804.094902.

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DDT, an extremely widely used organochlorine pesticide, was banned in most developed countries more than 30 years ago. However, DDT residues, including 1,1-dichloro-2,2-bis(4-chlorophenyl)ethylene (DDE), still persist in the environment and have been identified as priority pollutants due to their toxicity and their ability to bioaccumulate and biomagnify in the food chain. In particular, DDE was long believed to be "enon-biodegradable"e, however some microorganisms have now been isolated that are able to metabolise DDE in pure culture. Terrabacter sp. strain DDE-1 was enriched from a DDT-contaminated agricultural soil from the Canterbury plains and is able to metabolise DDE to 4-chlorobenzoic acid when induced with biphenyl. The primary objective of this study was to identify the gene(s) responsible for Terrabacter sp. strain DDE-1�s ability to metabolise DDE and, in particular, to investigate the hypothesis that DDE-1 degrades DDE cometabolically via a biphenyl degradation pathway. Catabolism of biphenyl by strain DDE-1 was demonstrated, and a biphenyl degradation (bph) gene cluster containing bphDA1A2A3A4BCST genes was identified. The bphDA1A2A3A4BC genes are predicted to encode a biphenyl degradation upper pathway for the degradation of biphenyl to benzoate and cis-2-hydroxypenta-2,4-dienoate and the bphST genes are predicted to encode a two-component signal transduction system involved in regulation of biphenyl catabolism. The bph gene cluster was found to be located on a linear plasmid, designated pBPH1. A plasmid-cured strain (MJ-2) was unable to catabolise both biphenyl and DDE, supporting the hypothesis that strain DDE-1 degrades DDE cometabolically via the biphenyl degradation pathway. Furthermore, preliminary evidence from DDE overlayer agar plate assays suggested that Pseudomonas aeruginosa carrying the strain DDE-1 bphA1A2A3A4BC genes is able to catabolise DDE when grown in the presence of biphenyl. A second objective of this study was to characterise pBPH1. The complete 84,054-bp sequence of the plasmid was determined. Annotation of the DNA sequence data revealed seventy-six ORFs predicted to encode proteins, four pseudogenes, and ten gene fragments. Putative functions were assigned to forty-two of the ORF and pseudogenes. Besides biphenyl catabolism, the major functional classes of the predicted proteins were transposition, regulation, heavy metal transport/resistance, and plasmid maintenance and replication. It was shown that pBPH1 has the terminal structural features of an actinomycete invertron, including terminal proteins and terminal inverted repeats (TIRs). This is the first report detailing the nucleotide sequence and characterisation of a (linear) plasmid from the genus Terrabacter.
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Gill, Christopher Ellis. "Environmental contaminants, food availability, and reproduction of bald eagles, Haliaeetus leucocephalus, on Vancouver Island, British Columbia." Thesis, National Library of Canada = Bibliothèque nationale du Canada, 1998. http://www.collectionscanada.ca/obj/s4/f2/dsk2/ftp03/MQ37537.pdf.

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Lihl, Christina Marie [Verfasser], and Martin [Akademischer Betreuer] Elsner. "Deciphering Chlorohydrocarbon Transformation Mechanisms by Advancing δ13C/δ37Cl Compound-Specific Isotope Analysis / Christina Marie Lihl ; Betreuer: Martin Elsner." Tübingen : Universitätsbibliothek Tübingen, 2020. http://d-nb.info/1209540649/34.

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Morrill, Penny Lea. "Investigation of stable carbon compound specific isotope analysis to monitor and quantify the biodegradation of chlorinated ethenes in groundwater systems /." 2004. http://proquest.umi.com/pqdweb?did=1273093921&sid=1&Fmt=2&clientId=12520&RQT=309&VName=PQD.

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Hei, Cheng-Ming, and 黑正明. "Performace study on the treatment of gas-borne chlorohydrocarbons by Regenerative Thermal Oxidizer." Thesis, 2002. http://ndltd.ncl.edu.tw/handle/27794083993755345967.

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碩士
國立中山大學
環境工程研究所
90
In this study, a pilot-scale regenerative thermal oxidizer (RTO) was used to test its performance for volatile organic compound (VOC) destruction and degree of thermal energy recovery. The purposes were to improve its performance and establish its operation conditions. The RTO is electrically heated and contains two 0.5 m × 0.5 m × 2.0 m (L × W × H) beds both packed with gravel particles of around 1.16 cm in average diameter to a height of 1.48 m. The bed has a void fraction of 0.405. Experiments include two phases: (1) tests to find the degree of energy conservation and the pressure drop for the air stream with no VOC in the influent air stream, and (2) tests to find the degree of VOC destruction with influent air streams containing one of the three VOCs: trichloroethylene, dichloromethane, and dibutyl ether. Intermediates in the course of VOC destruction were also detected in the second phase experiment. Phase one experiment was conducted for the following conditions: superficial gas velocity (evaluated at ambient temperatures of 26-29oC) Ug = 10-20 m/min, bed shift time ts = 1.5 min, and maximum gravel temperature Tmax = 474-778oC. Results show that the RTO has a thermal recovery efficiency R of over 85% and Ug is the main affecting factor. R is inversely proportional to Ug. Gas pressure drop over the bed height is proportional to the average temperature of the bed gravels. In the phase two experiments, Ug of 10-20 m/min, ts of 1.5 min, and Tmax of 475-487 and 758-778oC were used. Results show that over 90% of the influent VOCs were destructed when Tmax was set in the higher range. However, in the lower Tmax, over 80% destruction was obtained only for dibutyl ether and the VOC destruction was not closely related to Ug. For Tmax = 475-487oC and Ug = 10-20 m/min, complete oxidation products of trichloroethylene and dichloromethane are HCl, CO2, and H2O, and the main intermediates are CO, COCl2, and C2Cl4 (detected only for trichloroethylene). For dibutyl ether, complete oxidation products are CO2, and H2O, and the main intermediates are CO, alkenes, alcohol, alkenes, and acetic acid. For Tmax = 758-778oC and Ug = 10-14.5 m/min, complete oxidation products of trichloroethylene and dichloromethane are HCl, CO2, and H2O, and the main intermediates are CO and COCl2. No acetic acid was detected for dibutyl ether in the higher temperature range. An operation cost of US$ 3.33/(1,000 m3 waste gas) was estimated with the RTO operated in the higher temperatures and a flowrate of 2.5 m3/min (Ug = 10 m/min).
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Kim, Young. "Aerobic cometabolism of chlorinated aliphatic hydrocarbons by a butane-grown mixed culture : transformation abilities, kinetics and inhibition." Thesis, 2000. http://hdl.handle.net/1957/33093.

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Li, Jun. "Molecular analysis of bacterial community dynamics during bioaugmentation studies in a soil column and at a field test site." Thesis, 2004. http://hdl.handle.net/1957/29873.

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Mathias, Maureen Anne. "Modeling cometabolic transformation of a CAH mixture by a butane utilizing culture." Thesis, 2002. http://hdl.handle.net/1957/31659.

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The goal of this research was to mathematically simulate the ability of bioaugmented microorganisms to aerobically cometabolize a mixture of chlorinated aliphatic hydrocarbon (CAH) compounds during in-situ treatment. Parameter values measured from laboratory experiments were applied to the transport model with biotransformation processes included. In laboratory microcosm studies, a butane-grown, enriched culture was inoculated in soil and groundwater microcosms and exposed to butane and several repeated additions of 1,1,1-trichloroethane (TCA), 1,1-dichioroethylene (DCE), and 1,1-dichloroethane (DCA) at aqueous concentrations of 200 ��g/L, 100 ��g/L, and 200 ��g/L, respectively. Microcosms containing the bioaugmented culture showed 1,1-DCE to be rapidly transformed, followed by slower transformation of 1,1-DCA and 1,1,1-TCA. After most of the butane had been consumed, transformation of these latter CAHs increased, indicating strong inhibition by butane. With repeat biostimulations, butane utilization and CAH transformation accelerated, showing the increase in cell mass. These trends occurred in two sets of microcosm triplicates. No stimulation was observed in controls containing only the microorganisms indigenous to Moffett Field, confirming that activity seen in the bioaugmented microcosms was a result of the introduced culture's activity. Batch reactor results were simulated using differential equations accounting for Michaelis-Menten kinetics, transformation product toxicity, substrate inhibition, butane utilization, and CAH transformation. The equations were solved simultaneously by Runge-Kutta numerical integration with parameter values adjusted to match the microcosm data. Having defined the parameter values from laboratory studies, the biotransformation model was combined with 1-D advective-dispersive transport to simulate behavior of the culture and the substrates within an aquifer. The model was used to simulate the results of field studies where the butane-utilizing culture was injected into a 7 m subsurface test site and exposed to alternating pulses of oxygen and butane, along with the contaminant mixture studied in the microcosms. Monitoring wells spaced at 1 m, 2.2 m, and 4 m from the injection well allowed temporal and spatial changes in substrate concentrations to be determined. Model simulations of the field demonstration were performed to determine how well the biotransformation/solute transport model predicted actual field observations. To model the influences of solute transport, simulations were run and compared to breakthrough test data (prior to bioaugmentation) to determine the values for advection, dispersion, and sorption. The simulations showed that flow ranged from 1.0 to 1.5 m��/day (average linear velocity of 2.0 m/day). Dispersion was estimated as 0.31 m��/day. Sediment sorption partitioning coefficients for 1,1-DCE, 1,1-DCA, and 1,1,1-TCA were determined to be approximately 0.69, 0.50, and 0.50 L/kg, respectively. It was more difficult to determine an appropriate value of the mass transfer rate coefficient for non-equilibrium sorption, so simulations were run to compare equilibrium and non-equilibrium cases. Results indicated that non-equilibrium (with mass transfer rate coefficient of approximately 0.2 day�����) better simulated the field data. Using these transport parameters and the biotransformation values determined from the laboratory experiments, simulations of the field data showed that the model was capable of simulating the effects of transformation rates, butane inhibition, and 1,1-DCE product toxicity. Simulations for varying pulsing cycles and durations provided possible improvements for future field demonstrations. Overall, this work proved that there is good potential in extrapolating laboratory based kinetics to simulate biotransformation at a field scale. Although the complexity of such systems makes modeling difficult, such simulations are useful in understanding and interpreting field data.
Graduation date: 2003
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Books on the topic "Chlorohydrocarbons"

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Shkaraputa, L. N. Osnovy tekhnologii i khlorgidrinirovanii͡a︡. Kiev: Nauk. dumka, 1989.

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Heinisch, Emanuel. Umweltbelastung in Ostdeutschland: Fallbeispiele, chlorierte Kohlenwasserstoffe. Darmstadt: Wissenschaftliche Buchgesellschaft, 1992.

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Geological Survey (U.S.) and National Water-Quality Assessment Program (U.S.), eds. Concentrations of chlorinated organic compounds in biota and bed sediment in streams of the lower San Joaquin River drainage, California. Sacramento, Calif: U.S. Dept. of the Interior, U.S. Geological Survey, 1998.

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Garcia, Carmen A. Subsurface occurrence and potential source areas of chlorinated ethenes identified using concentrations and concentration ratios, Air Force Plant 4 and Naval Air Station-Joint Reserve Base Carswell Field, Fort Worth, Texas. Reston, Va: U.S. Geological Survey, 2005.

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Eisler, Ronald. Carbofuran hazards to fish, wildlife, and invertebrates: A synoptic review. Washington, DC: Fish and Wildlife Service, U.S. Dept. of the Interior, 1985.

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A, Vroblesky Don, South Carolina. Water Resources Division, and Geological Survey (U.S.), eds. Transport and transformations of chlorinated-solvent contamination in a saprolite and fractured rock aquifer near a former wastewater-treatment plant, Greenville, South Carolina. Columbia, S.C: U.S. Dept. of the Interior, U.S. Geological Survey, 1997.

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Eisler, Ronald. Carbofuran hazards to fish, wildlife, and invertebrates: A synoptic review. Washington, DC: Fish and Wildlife Service, U.S. Dept. of the Interior, 1985.

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A, Vroblesky Don, South Carolina. Water Resources Division., and Geological Survey (U.S.), eds. Transport and transformations of chlorinated-solvent contamination in a saprolite and fractured rock aquifer near a former wastewater-treatment plant, Greenville, South Carolina. Columbia, S.C: U.S. Dept. of the Interior, U.S. Geological Survey, 1997.

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Eisler, Ronald. Carbofuran hazards to fish, wildlife, and invertebrates: A synoptic review. Washington, DC: Fish and Wildlife Service, U.S. Dept. of the Interior, 1985.

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Huff, Glenn F. Assessment of potential for natural attenuation of chlorinated ethenes and ethanes in ground water at a petrochemical reclamation site, Harris County, Texas. Austin, Tex: U.S. Dept. of the Interior, U.S. Geological Survey, 2000.

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Book chapters on the topic "Chlorohydrocarbons"

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Elsner, Martin, and Thomas B. Hofstetter. "Current Perspectives on the Mechanisms of Chlorohydrocarbon Degradation in Subsurface Environments: Insight from Kinetics, Product Formation, Probe Molecules, and Isotope Fractionation." In ACS Symposium Series, 407–39. Washington, DC: American Chemical Society, 2011. http://dx.doi.org/10.1021/bk-2011-1071.ch019.

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Rantio, Tiina, Jaana Koistinen, and Jaakko Paasivirta. "Bioaccumulation of Pulp Chlorobleacfflng-Originated Aromatic Chlorohydrocarbons in Recipient Watercourses." In ENVIRONMENTAL FATE and EFFECTS of PULP and PAPER MILL EFFLUENTS, 341–45. CRC Press, 2020. http://dx.doi.org/10.1201/9780367812690-33.

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Lennon, David, and John M. Winfield. "Heterogeneous Catalysts Used for Large-Scale Syntheses of Selected Chlorohydrocarbons and Fluorohydrocarbons: Fluorinated Chromia and eta-Alumina." In New Materials for Catalytic Applications, 193–217. Elsevier, 2016. http://dx.doi.org/10.1016/b978-0-444-63587-7.00007-x.

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Conference papers on the topic "Chlorohydrocarbons"

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Ma, Yan, Xiao-Ming Du, Bin-Bin Dong, Yi Shi, and Fa-Sheng Li. "Quicklime-Enhanced Remediation of Volatile Chlorohydrocarbon-Contaminated Soil in an Abandoned Chemical Plant Site by Mechanical Soil Aeration." In Geo-Chicago 2016. Reston, VA: American Society of Civil Engineers, 2016. http://dx.doi.org/10.1061/9780784480168.035.

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