Academic literature on the topic 'Chloride abstraction'
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Journal articles on the topic "Chloride abstraction"
Menkir, Mengistu Gemech, and Shyi-Long Lee. "Mechanisms of metal-catalyzed cycloisomerizations of o-propargylbiaryls and o-allenylbiaryls to phenanthrenes: a DFT study." Catalysis Science & Technology 7, no. 24 (2017): 6026–41. http://dx.doi.org/10.1039/c7cy01899a.
Full textSchr�del, Hans-Peter, Alfred Schmidpeter, and Heinrich N�th. "Chlorophosphaethenyl phosphonium ions by chloride abstraction from dichlorophosphanyl ylides." Heteroatom Chemistry 7, no. 5 (1996): 355–58. http://dx.doi.org/10.1002/(sici)1098-1071(199610)7:5<355::aid-hc11>3.0.co;2-p.
Full textConrad, Eamonn, Neil Burford, Robert McDonald, and Michael J. Ferguson. "Phosphinoarsonium and Diarsonium Cations from Chloride-Abstraction-Induced Pnictogen Coupling." Inorganic Chemistry 47, no. 8 (April 2008): 2952–54. http://dx.doi.org/10.1021/ic800287e.
Full textBalcar, Hynek, Alena Dosedlová, and Bohumír Matyska. "Interactions of tungsten hexachloride with esters of carboxylic acids." Collection of Czechoslovak Chemical Communications 51, no. 4 (1986): 753–62. http://dx.doi.org/10.1135/cccc19860753.
Full textBhasin, Menka, Indu Sharma, and P. D. Sharma. "Kinetics and Mechanism of Ruthenium(III) Chloride Catalyzed Oxidation of Propane-1,3-diol by Thallium(III) in Acid Perchlorate Medium." Journal of Chemical Research 23, no. 1 (January 1999): 1. http://dx.doi.org/10.1177/174751989902300106.
Full textSchleicher, David, Alexander Tronnier, Hendrik Leopold, Horst Borrmann, and Thomas Strassner. "Unusual dimer formation of cyclometalated ruthenium NHC p-cymene complexes." Dalton Transactions 45, no. 8 (2016): 3260–63. http://dx.doi.org/10.1039/c6dt00100a.
Full textGrieco, Gabriele, Olivier Blacque, and Heinz Berke. "A facile synthetic route to benzimidazolium salts bearing bulky aromatic N-substituents." Beilstein Journal of Organic Chemistry 11 (September 17, 2015): 1656–66. http://dx.doi.org/10.3762/bjoc.11.182.
Full textNovák, Miroslav, Jan Turek, Yaraslava Milasheuskaya, Zdeňka Růžičková, Štěpán Podzimek, and Roman Jambor. "N-Donor stabilized tin(ii) cations as efficient ROP catalysts for the synthesis of linear and star-shaped PLAs via the activated monomer mechanism." Dalton Transactions 50, no. 44 (2021): 16039–52. http://dx.doi.org/10.1039/d1dt02658e.
Full textBeach, Nicholas J., Hilary A. Jenkins, and Gregory J. Spivak. "Electrophilic Attack on [Cp*Cl(PPh3)Ru(CCHR)]: Carbyne Formation vs Chloride Abstraction." Organometallics 22, no. 25 (December 2003): 5179–81. http://dx.doi.org/10.1021/om030559i.
Full textLaganà, A., and L. Ciccarelli. "Abstraction and exchange contributions to the rate constant of muonium+hydrogen chloride reaction." Hyperfine Interactions 36, no. 1 (February 1987): 59–63. http://dx.doi.org/10.1007/bf02396848.
Full textDissertations / Theses on the topic "Chloride abstraction"
Tronoff, Ashley. "Chloride abstraction from ruthenium alkyl bis-diphosphine dichlorides." Thesis, The University of Sydney, 2008. http://hdl.handle.net/2123/2801.
Full textTronoff, Ashley. "Chloride abstraction from ruthenium alkyl bis-diphosphine dichlorides." Science, 2008. http://hdl.handle.net/2123/2801.
Full textDespite their early discovery, relatively few classes of ruthenium dinitrogen complexes are known. This work describes the successful coordination of dinitrogen to the electron-rich alkylphosphine cores [RuCl(dmpe)2]+ and [RuCl(depe)2]+ by chloride abstraction from both the cis and trans dichloro derivatives. One such complex, trans-[RuCl(N2)(dmpe)2](BArF24), possesses the most activated ruthenium νNN reported to date. A variety of chloride abstraction agents were tested on the cis and trans isomers of [RuCl2(P-P)2] (P-P = dmpe, depe) with the choice of abstracting agent, anion and solvent all found to significantly affect the outcome. Reaction with silver triflate and trimethylsilyl triflate was found to give dichlororuthenium(III) products, which could be readily reduced to the ruthenium(II) starting materials with common reducing agents, as well as by alcohols and hydrazine. The use of thallium triflate avoided oxidation and led to the formation of the crystallographically characterised polymeric incorporation product, [{trans-[RuCl2(dmpe)2]•Tl(OTf)}n] from trans-[RuCl2(dmpe)2] and the interesting chloride-bridged ruthenium dimer cis-[{Ru(depe)2}2(μ-Cl)2](OTf)2 from trans-[RuCl2(depe)2]. Anion exchange of the complex [{trans-[RuCl2(dmpe)2]•Tl(OTf)}n] with the non-coordinating anion tetrakis(3,5-bis(trifluoromethyl)phenyl)borate resulted in removal of thallium from the system and coordination of dinitrogen to give trans-[RuCl(N2)(dmpe)2](BArF24). Cis-[{Ru(depe)2}2(μ-Cl)2](OTf)2 was found to readily react with a variety of small ligands and gave products such as cis-[RuCl(CO)(depe)2](OTf), cis-[RuCl(NCMe)(depe)2](OTf), cis-[RuCl(CNtBu)(depe)2](OTf), cis-[RuCl(NH3)(depe)2](OTf), cis-[RuCl(N3)(depe)2], and trans-[RuCl(η2-H2)(depe)2](OTf). A preliminary X-ray single crystal structure analysis was conducted on the complex cis-[RuCl(CNtBu)(depe)2](OTf). The thallium(I) salt Tl(BArF24) was found to be an efficient chloride abstraction agent under mild conditions. Reactions with cis- and trans-[RuCl2(depe)2] and cis-[RuCl2(dmpe)2] furnished dinitrogen complexes of the form cis-[{RuCl(P-P)2}2(μ-N2)](BArF24)2, whilst reaction of trans-[RuCl2(dmpe)2] with Tl(BArF24) led to the stable five-coordinate complex trans-[RuCl(dmpe)2](BArF24). Vapour diffusion techniques applied to a solution of cis-[{RuCl(depe)2}2(μ-N2)](BArF24)2 gave rise to crystals of trans-[RuCl(N2)(depe)2](BArF24), on which preliminary X-ray molecular structure analysis was performed. Reactions of both cis-[{Ru(depe)2}2(μ-Cl)2](OTf)2 and trans-[RuCl2(dmpe)2] with high pressure (140 psi) dinitrogen at 140 150°C in methanol or tetrahydrofuran resulted in solvent carbonyl abstraction to afford trans-[RuCl(CO)(depe)2](OTf) and trans-[RuCl(CO)(dmpe)2](Cl) from the depe and dmpe complexes respectively. The molecular structure of trans-[RuCl(CO)(dmpe)2](Cl) was determined via single crystal X-ray structure analysis.
Huskey, Dow T. "A temperature and pressure dependent kinetics study of the gas-phase reactions of bromine (2P3/2) and chlorine (2PJ) atoms with methylvinyl ketone." Thesis, Atlanta, Ga. : Georgia Institute of Technology, 2008. http://hdl.handle.net/1853/24734.
Full textKrosley, Kevin W. "Part I. The identity of the chain propagating radical(s) in photoinitiated benzylic bromination by bromotrichloromethane ; Part II. Chlorine atom abstraction from α- and β-chloroepoxides by the triphenyltin radical." Thesis, 1991. http://hdl.handle.net/1957/37160.
Full textBooks on the topic "Chloride abstraction"
Krosley, Kevin W. Part I. The identity of the chain propagating radical(s) in photoinitiated benzylic bromination by bromotrichloromethane ; Part II. Chlorine atom abstraction from Ü- and Ý-chloroepoxides by the triphenyltin radical. 1991.
Find full textBook chapters on the topic "Chloride abstraction"
Yu, Lei, Tianyuan Zhao, and Zhi Wang. "Study on the Properties of Concrete with Different Admixtures in Acid Corrosive Environment." In Advances in Frontier Research on Engineering Structures, 231–39. Singapore: Springer Nature Singapore, 2023. http://dx.doi.org/10.1007/978-981-19-8657-4_21.
Full textSlootweg, J. C., and K. Lammertsma. "Chloride Abstraction." In Organophosphorus Compounds (incl. RO-P and RN-P), 1. Georg Thieme Verlag KG, 2009. http://dx.doi.org/10.1055/sos-sd-042-00023.
Full textBansal, R. K., N. Gupta, and S. J. Collier. "Synthesis by Chloride Abstraction." In Five-Membered Hetarenes with Three or More Heteroatoms, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-013-00932.
Full textBansal, R. K., and Neelima Gupta. "Aromatization by Chloride Abstraction." In Five-Membered Hetarenes with Three or More Heteroatoms, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-013-01074.
Full textCollier, S. J. "Synthesis by Chloride Abstraction." In Five-Membered Hetarenes with Three or More Heteroatoms, 1. Georg Thieme Verlag KG, 2004. http://dx.doi.org/10.1055/sos-sd-013-01150.
Full textTaber, Douglass. "The Castle Synthesis of (-)-Acutumine." In Organic Synthesis. Oxford University Press, 2011. http://dx.doi.org/10.1093/oso/9780199764549.003.0104.
Full textConference papers on the topic "Chloride abstraction"
Hudgens, Jeffrey W., Jeffrey L. Brum, Russell D. Johnson, and David V. Dearden. "Structure Matters: Detection of Difluoromethyl and Difluoroethyl Radicals by Resonance Enhanced Multiphoton Ionization Spectroscopy." In Laser Applications to Chemical Analysis. Washington, D.C.: Optica Publishing Group, 1994. http://dx.doi.org/10.1364/laca.1994.fa.4.
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