Academic literature on the topic 'Chiroptical switch'

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Journal articles on the topic "Chiroptical switch"

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Feringa, Ben L., Wolter F. Jager, Ben De Lange, and Egbert W. Meijer. "Chiroptical molecular switch." Journal of the American Chemical Society 113, no. 14 (July 1991): 5468–70. http://dx.doi.org/10.1021/ja00014a057.

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Opačak, Saša, Darko Babić, Berislav Perić, Željko Marinić, Vilko Smrečki, Barbara Pem, Ivana Vinković Vrček, and Srećko I. Kirin. "A ferrocene-based pseudopeptide chiroptical switch." Dalton Transactions 50, no. 13 (2021): 4504–11. http://dx.doi.org/10.1039/d1dt00508a.

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Westermeier, Christian, Hans-Christoph Gallmeier, Markus Komma, and Jörg Daub. "Bispyrene based chiroptical molecular redox switch." Chemical Communications, no. 23 (1999): 2427–28. http://dx.doi.org/10.1039/a907454f.

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van Delden, Richard A., Matthijs K. J. ter Wiel, and Ben L. Feringa. "A chiroptical molecular switch with perfect stereocontrol." Chemical Communications, no. 2 (2004): 200. http://dx.doi.org/10.1039/b312170d.

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Isla, Helena, Monika Srebro-Hooper, Marion Jean, Nicolas Vanthuyne, Thierry Roisnel, Jamie L. Lunkley, Gilles Muller, J. A. Gareth Williams, Jochen Autschbach, and Jeanne Crassous. "Conformational changes and chiroptical switching of enantiopure bis-helicenic terpyridine upon Zn2+ binding." Chemical Communications 52, no. 35 (2016): 5932–35. http://dx.doi.org/10.1039/c6cc01748g.

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Takaishi, Kazuto, Makoto Yasui, and Tadashi Ema. "Binaphthyl–Bipyridyl Cyclic Dyads as a Chiroptical Switch." Journal of the American Chemical Society 140, no. 16 (April 13, 2018): 5334–38. http://dx.doi.org/10.1021/jacs.8b01860.

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Haridas, V., Sandhya Sadanandan, Sameer Dhawan, Rituraj Mishra, Ishani Jain, Gaurav Goel, Yuan Hu, and Sandeep Patel. "Synthetic minimalistic tryptophan zippers as a chiroptical switch." Organic & Biomolecular Chemistry 15, no. 7 (2017): 1661–69. http://dx.doi.org/10.1039/c6ob02617f.

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Supramolecular helices with left and right handed chirality were designed and synthesized based on l-tryptophan that undergo helical inversion upon addition of H2PO4.
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Lu, Jinjie, Ganquan Jiang, Zhengbiao Zhang, Wei Zhang, Yonggang Yang, Yong Wang, Nianchen Zhou, and Xiulin Zhu. "A cyclic azobenzenophane-based smart polymer for chiroptical switches." Polymer Chemistry 6, no. 47 (2015): 8144–49. http://dx.doi.org/10.1039/c5py01301a.

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Polymers based on cyclic azobenzenophanes as pendants with different methylene spacers (n = 2, 6, 11) have been synthesized. And the one with a six-methylene spacer is a good candidate for a chiroptical switch.
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Rodríguez, Rafael, Emilio Quiñoá, Ricardo Riguera, and Félix Freire. "Multistate Chiroptical Switch Triggered by Stimuli-Responsive Chiral Teleinduction." Chemistry of Materials 30, no. 8 (April 11, 2018): 2493–97. http://dx.doi.org/10.1021/acs.chemmater.8b00800.

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Guo, P., L. Zhang, and M. Liu. "A Supramolecular Chiroptical Switch Exclusively from an Achiral Amphiphile." Advanced Materials 18, no. 2 (January 19, 2006): 177–80. http://dx.doi.org/10.1002/adma.200501047.

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Dissertations / Theses on the topic "Chiroptical switch"

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Schoevaars, Anne Marie. "Chiroptical molecular switches." [S.l. : [Groningen : s.n.] ; University Library Groningen] [Host], 1991. http://irs.ub.rug.nl/ppn/291295282.

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Huck, Hubertina Petronella Maria. "Chiroptical molecular switches." [S.l. : [Groningen : s.n.] ; University of Groningen] [Host], 2008. http://irs.ub.rug.nl/ppn/.

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Olivieri, Enzo. "Application de la catalyse pour l'alimentation de systèmes chimiques sans déchet." Electronic Thesis or Diss., Aix-Marseille, 2021. http://theses.univ-amu.fr.lama.univ-amu.fr/211216_OLIVIERI_825ir382ikksw374agndg983uvnl_TH.pdf.

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Au cours de cette thèse nous avons pris avantage de la catalyse pour le développement de nouveaux carburants, limitant l’accumulation de déchets lors de l’activation sélective de nouveaux systèmes chimiques. Dans une première partie, nous avons transposé le principe de réactions d’hydrogénations réversibles au domaine des machines moléculaires. Cette approche a permis l’élaboration d’un interrupteur moléculaire de type tolane fonctionnant lors de deux cycles consécutifs de dés/hydrogénation. Celui-ci représente le premier système alimenté par carburant chimique sans aucune production de déchet. Nous avons aussi étendu l’utilisation de l’acide trichloracétique (TCA), pour le développement de nouveaux systèmes d’autoassemblages et notamment d’organogels contrôlés dans le temps. Ainsi à partir d’un dérivé d’aminoacide naturel (O-tert-Butyl-L-tyrosine), nous avons pu mettre au point deux systèmes complémentaires permettant une transition gel-sol-gel ou sol-gel-sol. Nous avons ainsi pu réaliser 11 cycles gel-sol-gel consécutifs, et plus 25 cycles sol-gel-sol consécutifs avant de devoir régénérer le système par une simple évaporation. Cette stratégie a pu être étendue à l’octadécylamine avec laquelle nous avons réalisés 12 cycles gel-sol-gel consécutifs. Il est important de noter que les deux systèmes gel-sol-gel et sol-gel-sol à base de O-tert-Butyl-L-tyrosine, possèdent des propriétés chiroptiques uniques. Finalement, nous nous sommes attelés au développement de systèmes hybrides capables de répondre à deux stimuli différents, l’hydrogène et le TCA. Basés sur des squelettes de type phénanthridines, ils permettent une rotation contrôlée en réponse à ces deux types de stimuli
In this thesis we have taken advantage of catalysis for the development of new fuels, limiting the accumulation of waste during the selective activation of new chemical systems. In a first part, we transposed the principle of reversible hydrogenation reactions to the field of molecular machines. This approach has allowed the development of a tolane-type molecular switch operating during two consecutive de/hydrogenation cycles. This represents the first system powered by chemical fuel without any waste production. We have also extended the use of trichloroacetic acid (TCA), for the development of new self-assembly systems and in particular time-controlled organogels. Thus, starting from a natural amino acid derivative (O-tert-Butyl-L-tyrosine), we were able to develop two complementary systems allowing a gel-sol-gel or sol-gel-sol transition. We were able to perform 11 consecutive gel-sol-gel cycles, and more than 25 consecutive sol-gel-sol cycles before having to regenerate the system by simple evaporation. This strategy could be extended to octadecylamine with which we performed 12 consecutive gel-sol-gel cycles. It is important to note that both gel-sol-gel and sol-gel-sol systems based on O-tert-Butyl-L-tyrosine, have unique chiroptical properties. Finally, we set out to develop hybrid systems capable of responding to two different stimuli, hydrogen and TCA. Based on phenanthridine backbones, they allow a controlled rotation in response to these two types of stimuli
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Li, Jie. "Design and synthesis of organic chiroptical switches." Diss., Georgia Institute of Technology, 1999. http://hdl.handle.net/1853/27385.

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Jager, Wolter Frens. "Chiroptical molecular switches application of inherently dissymmetric alkenes /." [S.l. : [Groningen : s.n.] ; University of Groningen] [Host], 1994. http://irs.ub.rug.nl/ppn/.

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Ouyang, Jiangkun. "Helicenes for chiral molecular switches, magnetic materials, and chiral fullerene derivatives." Thesis, Rennes 1, 2017. http://www.theses.fr/2017REN1S160.

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Dans ce travail de thèse, nous avons d'abord développé deux études basées sur des unités dites ''stilbène rigide'' qui sont connues pour s'interconvertir de manière réversible entre deux formes trans et cis grâce à la lumière. La première étude correspond à des photocommutateurs chiraux à base d'hélicènes, l'autre à des complexes photocommutables alcynyles d'or(I). Ensuite, nous avons examiné la synthèse et la caractérisation de complexes de Dy(III) à base d'hélicène-bipyridine comme nouveaux types d'aimants moléculaires (SMM) chiraux et comparé la différence des propriétés magnétiques entre les SMM racémique et énantiopurs. Enfin, nous avons développé la première utilisation de la cycloaddition réversible d'hélicènes racémiques sur le [60]fullerène et de sa rétrocycloaddition ultérieure comme une stratégie alternative efficace pour le dédoublement énantiomérique d'un hélicène-carboxaldéhyde
In this PhD work, we firstly developed two studies based on the so-called ''stiff stilbene'' units that are known to reversibly interconvert between two trans and cis forms through light. The first study corresponds to photoresponsive chiral switches based on helicenes, the other one to photoresponsive gold(I) complexes. Then, we dealt with the synthesis and characterization of helicene-bipyridine based Dy(III) complexes as novel kinds of chiral single molecule magnets (SMMs) and compared the difference of the magnetic properties between racemic and enantiopure SMMs. Finally, we developed the first use of the reversible sterodivergent cycloaddition of racemic helicenes onto [60]fullerene with its subsequent retro-cycloaddition as an efficient alternative strategy for the enantiomeric resolution of a helicene-carboxaldehyde
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Book chapters on the topic "Chiroptical switch"

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Browne, Wesley R., and Ben L. Feringa. "Chiroptical Molecular Switches." In Molecular Switches, 121–79. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527634408.ch5.

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Conference papers on the topic "Chiroptical switch"

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Parakka, James P., Robert R. Schumaker, Brenda S. Kesler, and John D. Thoburn. "Molecular-based chiroptical dipole switches." In Optical Engineering for Sensing and Nanotechnology (ICOSN '01), edited by Koichi Iwata. SPIE, 2001. http://dx.doi.org/10.1117/12.427073.

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Hutchison, Katherine A., James P. Parakka, Brenda S. Kesler, and Robert R. Schumaker. "Chiropticenes: molecular chiroptical dipole switches for optical data storage." In Symposium on Integrated Optoelectronics, edited by Joseph W. Perry and Axel Scherer. SPIE, 2000. http://dx.doi.org/10.1117/12.382795.

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