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Journal articles on the topic 'Chemistry of zervalent irons'

Author: Grafiati

Published: 4 June 2021

Last updated: 2 February 2022

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1

Cardoso, P. H. S., C. L. Israel, and T. R. Strohaecker. "Abrasive wear in Austempered Ductile Irons: A comparison with white cast irons." Wear 313, no. 1-2 (May 2014): 29–33. http://dx.doi.org/10.1016/j.wear.2014.02.009.

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2

Zanardi, Franco, Franco Bonollo, Giuliano Angella, Nicola Bonora, Gianluca Iannitti, and Andrew Ruggiero. "Erratum to: A Contribution to New Material Standards for Ductile Irons and Austempered Ductile Irons." International Journal of Metalcasting 11, no. 3 (March 1, 2017): 631. http://dx.doi.org/10.1007/s40962-017-0145-8.

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3

Filipovic, Mirjana. "Iron-chromium-carbon-vanadium white cast irons: Microstructure and properties." Chemical Industry 68, no. 4 (2014): 413–27. http://dx.doi.org/10.2298/hemind130615064f.

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The as-cast microstructure of Fe-Cr-C-V white irons consists of M7C3 and vanadium rich M6C5 carbides in austenitic matrix. Vanadium changed the microstructure parameters of phase present in the structure of these alloys, including volume fraction, size and morphology. The degree of martensitic transformation also depended on the content of vanadium in the alloy. The volume fraction of the carbide phase, carbide size and distribution has an important influence on the wear resistance of Fe-Cr-C-V white irons under low-stress abrasion conditions. However, the dynamic fracture toughness of Fe-Cr-C-V irons is determined mainly by the properties of the matrix. The austenite is more effective in this respect than martensite. Since the austenite in these alloys contained very fine M23C6 carbide particles, higher fracture toughness was attributed to a strengthening of the austenite during fracture. Besides, the secondary carbides which precipitate in the matrix regions also influence the abrasion behaviour. By increasing the matrix strength through a dispersion hardening effect, the fine secondary carbides can increase the mechanical support of the carbides. Deformation and appropriate strain hardening occur in the retained austenite of Fe-Cr-C-V alloys under repeated impact loading. The particles of precipitated M23C6 secondary carbides disturb dislocations movement and contribute to increase the effects of strain hardening in Fe-Cr-C-V white irons.

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4

Sahoo, G., R. Balasubramaniam, and S. Misra. "Corrosion of Phosphoric Irons in Cement Grout." CORROSION 63, no. 10 (October 2007): 975–82. http://dx.doi.org/10.5006/1.3278315.

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5

Bartha, Csaba, Virgil Marinescu, Monica Jipa, Beatrice-Gabriela Sbarcea, Attila Tókos, Alina-Ruxandra Caramitu, and Iosif Lingvay. "Behavior in AC polarization of high-silicon cast irons." Studia Universitatis Babeș-Bolyai Chemia 66, no. 1 (March 31, 2021): 49–61. http://dx.doi.org/10.24193/subbchem.2021.01.04.

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6

Fima, P., and N. Sobczak. "Density and surface tension of molten cast irons." Journal of Mining and Metallurgy, Section B: Metallurgy, no. 00 (2021): 40. http://dx.doi.org/10.2298/jmmb210413040f.

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Computer-aided development of liquid-assisted metallurgical processes requires reliable basic data for the molten materials, including thermophysical properties such as density, surface tension and viscosity. Cast irons belong to the group of Fe-C alloys of practical importance due to their good technological and utility properties, yet experimental thermophysical data of cast irons in the literature are scarce. In this study, the density and surface tension of three compacted graphite cast iron alloys were measured by the sessile drop method in contact heating mode in the temperature range of 1473 - 1723 K with polycrystalline alumina as a substrate. The drop profile images were recorded both during heating and subsequent cooling regimes. At 1473 K, the density values of the studied compacted graphite irons are between 6.66 and 6.69 g?cm-3, whereas surface tension values are between 1130 and 1510 mN?m-1. The density decreases with increasing temperature, while surface tension dependence on temperature is less obvious. The obtained results are compared to the available literature data and analyzed taking into account chemical interaction of liquid cast irons with the substrate material.

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7

Bradley, W. L., and M. N. Srinivasan. "Fracture and fracture toughness of cast irons." International Materials Reviews 35, no. 1 (January 1990): 129–61. http://dx.doi.org/10.1179/095066090790324028.

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8

Kante, Stefan, and Andreas Leineweber. "The iron silicocarbide in cast irons revisited." Journal of Alloys and Compounds 815 (January 2020): 152468. http://dx.doi.org/10.1016/j.jallcom.2019.152468.

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9

Watson, S. W., B. W. Madsen, and S. D. Cramer. "Wear-corrosion study of white cast irons." Wear 181-183 (March 1995): 469–75. http://dx.doi.org/10.1016/0043-1648(95)90160-4.

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10

Poonawala, N. S., A. K. Chakrabarti, and A. B. Chattopadhyay. "Wear characteristics of nitrogenated chromium cast irons." Wear 162-164 (April 1993): 580–84. http://dx.doi.org/10.1016/0043-1648(93)90544-v.

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11

Riposan, Iulian, Mihai Chisamera, and Stelian Stan. "Enhanced Quality in Electric Melt Grey Cast Irons." ISIJ International 53, no. 10 (2013): 1683–95. http://dx.doi.org/10.2355/isijinternational.53.1683.

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12

Kiani-Rashid, A. R., and D. V. Edmonds. "Microstructural characteristics of Al-alloyed austempered ductile irons." Journal of Alloys and Compounds 477, no. 1-2 (May 2009): 391–98. http://dx.doi.org/10.1016/j.jallcom.2008.10.038.

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13

Jeen, Sung-Wook, Snezana Lazar, Lai Gui, and Robert W. Gillham. "Degradation of chlorofluorocarbons using granular iron and bimetallic irons." Journal of Contaminant Hydrology 158 (March 2014): 55–64. http://dx.doi.org/10.1016/j.jconhyd.2014.01.002.

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14

Sen, Ugur, Saduman Sen, and Fevzi Yilmaz. "Structural characterization of boride layer on boronized ductile irons." Surface and Coatings Technology 176, no. 2 (January 2004): 222–28. http://dx.doi.org/10.1016/s0257-8972(03)00731-x.

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15

Lima, M. S. F., and H. Goldenstein. "Structure of laser remelted surface of cast irons." Surface Engineering 16, no. 2 (April 2000): 127–30. http://dx.doi.org/10.1179/026708400101517017.

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16

Zandira, Masoud, and Seyyed Mohammad Ali Boutorabi. "Fracture characteristics of austempered spheroidal graphite aluminum cast irons." Journal of Iron and Steel Research International 17, no. 2 (February 2010): 31–35. http://dx.doi.org/10.1016/s1006-706x(10)60055-6.

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17

Ghosh, S., A. Prodhan, O. N. Mohanty, and A. K. Chakrabarti. "A study on the oxidation characteristics of cast irons containing aluminum." Oxidation of Metals 45, no. 1-2 (February 1996): 109–31. http://dx.doi.org/10.1007/bf01046822.

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18

Reardon, Eric J. "Zerovalent Irons: Styles of Corrosion and Inorganic Control on Hydrogen Pressure Buildup." Environmental Science & Technology 39, no. 18 (September 2005): 7311–17. http://dx.doi.org/10.1021/es050507f.

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19

Jeong, Bong-Yong, Jeong-Ho Chang, and Myung-Ho Kim. "Thermal fatigue characteristics of plasma duplex treated nodular cast irons." Surface and Coatings Technology 205, no. 3 (October 2010): 896–901. http://dx.doi.org/10.1016/j.surfcoat.2010.08.040.

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20

Domengès, Bernadette, Mayerling Martinez Celis, Florent Moisy, Jacques Lacaze, and Babette Tonn. "On the role of impurities on spheroidal graphite degeneracy in cast irons." Carbon 172 (February 2021): 529–41. http://dx.doi.org/10.1016/j.carbon.2020.10.030.

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21

Kishore, P. Sampathkumaran, and S. Seetharamu. "Erosion and abrasion characteristics of high manganese chromium irons." Wear 259, no. 1-6 (July 2005): 70–77. http://dx.doi.org/10.1016/j.wear.2005.03.001.

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22

Ribeiro, L., A. Barbosa, F. Viana, A. Monteiro Baptista, C. Dias, and C. A. Ribeiro. "Abrasion wear behaviour of alloyed and chilled cast irons." Wear 270, no. 7-8 (March 2011): 535–40. http://dx.doi.org/10.1016/j.wear.2011.01.008.

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23

Shepperson, S., and C. Allen. "The abrasive wear behaviour of austempered spheroidal cast irons." Wear 121, no. 3 (February 1988): 271–87. http://dx.doi.org/10.1016/0043-1648(88)90206-2.

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24

Sare, I. R., and B. K. Arnold. "Gouging abrasion of wear-resistant alloy white cast irons." Wear 131, no. 1 (May 1989): 15–37. http://dx.doi.org/10.1016/0043-1648(89)90243-3.

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25

Tomlinson, W. J., and M. G. Talks. "Cavitation erosion of laser surface melted phosphoric grey irons." Wear 129, no. 2 (February 1989): 215–22. http://dx.doi.org/10.1016/0043-1648(89)90259-7.

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26

Tomlinson, W. J., and M. G. Talks. "Cavitation erosion of heat-treated low alloy cast irons." Wear 137, no. 1 (April 1990): 143–46. http://dx.doi.org/10.1016/0043-1648(90)90023-4.

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27

Sare, I. R., B. K. Arnold, G. A. Dunlop, and P. G. Lloyd. "Repeated impact-abrasion testing of alloy white cast irons." Wear 162-164 (April 1993): 790–801. http://dx.doi.org/10.1016/0043-1648(93)90080-6.

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28

Jinzhu, Liu, and Man Yongfa. "Development of abrasion-resistant Ni-hard 4 cast irons." Wear 162-164 (April 1993): 833–36. http://dx.doi.org/10.1016/0043-1648(93)90084-y.

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29

Liang, Fang, Gao Yimin, Zhou Lin, and Li Peng. "Unlubricated sliding wear of ceramics against graphitized cast irons." Wear 171, no. 1-2 (January 1994): 129–34. http://dx.doi.org/10.1016/0043-1648(94)90355-7.

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30

Ovalıa, İsmail, and Ahmet Mavib. "Investigating the machinability of austempered ductile irons with dual matrix structures." International Journal of Materials Research 104, no. 2 (February 15, 2013): 192–98. http://dx.doi.org/10.3139/146.110849.

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31

Tsuchida, Eishun, Hiroyuki Nishide, Makoto Yuasa, Takeshi Babe, and Masaki Fukuzumi. "Synthesis of polymerizable and amphiphilic (porphinato)irons and their copolymers with polymerizable phospholipid." Macromolecules 22, no. 1 (January 1989): 66–72. http://dx.doi.org/10.1021/ma00191a013.

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32

Pryke, Kenneth. "The Woolwich Arsenal and Acadian Mines." Scientia Canadensis 34, no. 1 (December 16, 2011): 25–50. http://dx.doi.org/10.7202/1006927ar.

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In 1856 the Royal Arsenal undertook to locate a British source for high grade ore that would be suitable for purposes of ordnance. Early reports indicated that one of the irons being evaluated, an iron from Nova Scotia, was comparable to Swedish iron. Having adopted a rigid policy of modernization, the Arsenal insisted that all irons had to meet the standards established by the analytical chemists. When the Acadian iron was subsequently rejected, critics claimed that the chemists were promoting dogma, not science. The procedures being used by the chemists were certainly flawed, and the Arsenal project incident illustrated that at that time analytical chemistry had relatively little to offer the metal trades.

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33

Goryany, Vyacheslav, Eckart Hofmann, and Josef Mauk. "Influence of cooling conditions and amount of retained austenite on the fracture of austempered ductile iron." Journal of the Serbian Chemical Society 73, no. 1 (2008): 113–19. http://dx.doi.org/10.2298/jsc0801113g.

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SEM Analysis of fracture surfaces from tensile test specimens of thick-walled, austempered ductile irons (diameter 160 mm) shows different fracture behavior depending on the austenite retained in the matrix. The results show ductile fractures only in areas containing retained austenite sections. In section areas without or with a very low content of retained austenite, only brittle fracture without any plastic deformation occurs. The content of retained austenite determines the amount of ductile fracture in the microstructure.

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34

Angella, G., M. Cova, G. Bertuzzi, and F. Zanardi. "Soundness Discrimination in Ferrite Ductile Irons Through Tensile Data Analysis." International Journal of Metalcasting 14, no. 3 (February 20, 2020): 816–26. http://dx.doi.org/10.1007/s40962-020-00435-0.

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35

Boeri, Roberto E., Marcos G. López, Nicolás E. Tenaglia, and Juan M. Massone. "Solidification, Macrostructure and Shrinkage Formation of Ductile and Compacted Irons." International Journal of Metalcasting 14, no. 4 (April 2, 2020): 1172–82. http://dx.doi.org/10.1007/s40962-020-00444-z.

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36

Yilmaz, Serdar Osman, and Tanju Teker. "Investigation on mechanical properties of solution strengthened and austempered ferritic ductile irons." International Journal of Materials Research 111, no. 12 (December 9, 2020): 976–82. http://dx.doi.org/10.3139/146.111963.

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37

Chen, Xupeng, Zhuowen Sun, and Jianyong Pang. "Effects of Various Corrosive Ions on Metakaolin Concrete." Crystals 11, no. 9 (September 12, 2021): 1108. http://dx.doi.org/10.3390/cryst11091108.

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In order to study and verify if the three corrosive irons of SO42−, Mg2+, and Cl− could promote or inhibit each other in concrete corrosion as time goes by, we take Metakaolin (MK) as the research object to explore the interaction mechanism among ions by testing the physical and mechanical properties, the ion content, the phase composition, and the microstructural changes of the MK concrete under the action of various ion combinations. The results show that during the initial and middle stages of the corrosion (40–80 days), SO42− and Mg2+ are in reciprocal inhibition relation, Cl− could inhibit the action of SO42−, and Mg2+ could promote the diffusion of Cl−. However, at the final stage of corrosion (120 days), SO42− and Mg2+ could mutually promote each other, and both irons could promote the diffusion of Cl−. Mg2+ could mainly produce magnesium hydroxide and M-S-H inside the concrete, SO42− mainly generates the ettringite and gypsum, while Cl− mainly produces Friedel salt and NaCl crystal.

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38

Dommarco, R. C., and J. D. Salvande. "Contact fatigue resistance of austempered and partially chilled ductile irons." Wear 254, no. 3-4 (February 2003): 230–36. http://dx.doi.org/10.1016/s0043-1648(03)00008-5.

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39

Cueva, G., A. Sinatora, W. L. Guesser, and A. P. Tschiptschin. "Wear resistance of cast irons used in brake disc rotors." Wear 255, no. 7-12 (August 2003): 1256–60. http://dx.doi.org/10.1016/s0043-1648(03)00146-7.

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40

Rajagopal, Vathsala, and Iwao Iwasaki. "Wear behaviors of chromium-bearing cast irons in wet grinding." Wear 154, no. 2 (May 1992): 241–58. http://dx.doi.org/10.1016/0043-1648(92)90157-4.

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41

Abreu, Marcio, Jessica Elfsberg, and Stefan Jonsson. "Cavitation erosion behavior of austempered ductile irons of increasing hardness." Wear 484-485 (November 2021): 204036. http://dx.doi.org/10.1016/j.wear.2021.204036.

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42

Tsoncheva, T., S. Vankova, O. Bozhkov, and D. Mehandjiev. "Rhenium and manganese modified activated carbon as catalyst for methanol decomposition." Canadian Journal of Chemistry 85, no. 2 (February 1, 2007): 118–23. http://dx.doi.org/10.1139/v07-004.

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Bicomponent manganese and rhenium modified activated carbon materials, prepared by different methods, are studied and compared with the corresponding monocomponent materials as catalysts in methanol decomposition to CO and hydrogen. The best catalytic activity and stability is observed for the sample obtained by simultaneous deposition of Mn and Re precursors. The complex character of the catalytic active centre, including manganese and rhenium irons in various oxidative states, is discussed. The determining role of the Mn(II) ions in the improvement of the catalytic properties is assumed.Key words: rhenium, manganese, activated carbon, methanol decomposition.

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43

Lacaze, Jacques, Anna Regordosa, Jon Sertucha, and Urko de la Torre. "Quantitative Analysis of Solidification of Compacted Graphite Irons – A Modelling Approach." ISIJ International 61, no. 5 (May 15, 2021): 1539–49. http://dx.doi.org/10.2355/isijinternational.isijint-2020-476.

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44

Jaeger, Tilman, and Heinrich Vahrenkamp. "Alkin-induzierter Abbau von Fe4P2-Clustern / Alkyne Induced Fragmentation of Fe4P2 Clusters." Zeitschrift für Naturforschung B 41, no. 6 (June 1, 1986): 789–90. http://dx.doi.org/10.1515/znb-1986-0621.

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The unsaturated clusters Fe4(CO)11(μ4-PR)2 (R = Ph, Tol) insert terminal alkynes HC2R′ (R′ = Me, Ph) between iron and phosphorus to form clusters Fe4(CO)11(μ4-PR)(μ4-RP−CR′−CH) in which according to a structure determination the RP -CR′−CH ligand has the phosphorus μ2-bridging to two irons, the CR′−CH unit η2-bonding to the third and the CH unit o-bonding to the fourth iron. Under CO these clusters lose one iron unit to form Fe3(CO)9(PR)(RP−CR′−CH).

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45

Tomovic-Petrovic, Stanka, Srdjan Markovic, and Slavica Zec. "The effect of boron on the amount and type of carbides in chromium white irons." Journal of the Serbian Chemical Society 67, no. 10 (2002): 697–707. http://dx.doi.org/10.2298/jsc0210697t.

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The effect of boron, in the amounts of 0.26, 0.39, and 0.59 wt.%, on the volume fraction and structure of carbides in Cr white irons was examined. It was demonstrated that the addition of boron can change the microstructural characteristics of white iron containing about 13 wt.% Cr. With increasing boron content, the volume fractions of M3C carbide increase, but the volume fracton of M7C3 carbide remains unchanged. The addition of boron tends to produce hard borides and/or borocarbides. It also prevents the formation of pearlite, which results in alloys possessing good wear resistance.

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46

Sahoo, Gadadhar, and R. Balasubramaniam. "On the corrosion behaviour of phosphoric irons in simulated concrete pore solution." Corrosion Science 50, no. 1 (January 2008): 131–43. http://dx.doi.org/10.1016/j.corsci.2007.06.017.

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47

Kravchenko, Yu G., A. A. Semykin, and A. Ya Yaroshik. "Optimization of machining variables in turning hard cast irons with PCBN-inserted tools." Journal of Superhard Materials 30, no. 5 (October 2008): 333–37. http://dx.doi.org/10.3103/s1063457608050080.

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48

Riposan, Iulian, Stelian Stan, Mihai Chisamera, Loredana Neacsu, Ana Maria Cojocaru, Eduard Stefan, and Iuliana Stan. "Simultaneous thermal and contraction / expansion curves analysis for solidification control of cast irons." China Foundry 17, no. 2 (March 2020): 96–110. http://dx.doi.org/10.1007/s41230-020-9147-x.

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49

Zhang, A. F., J. D. Xing, L. Fang, and J. Y. Su. "Inter-phase corrosion of chromium white cast irons in dynamic state." Wear 257, no. 1-2 (July 2004): 198–204. http://dx.doi.org/10.1016/j.wear.2003.12.002.

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50

Beltowksi, Mark, Peter J. Blau, and J. Qu. "Wear of spheroidal graphite cast irons for tractor drive train components." Wear 267, no. 9-10 (September 2009): 1752–56. http://dx.doi.org/10.1016/j.wear.2009.03.030.

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