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Relevant bibliographies by topics / Chemiluminescent reactions

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Academic literature on the topic 'Chemiluminescent reactions'

Author: Grafiati

Published: 4 June 2021

Last updated: 13 February 2022

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Journal articles on the topic "Chemiluminescent reactions"

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Ibragimova, D. A., O. M. Kamil, T. V. Yankova, N. A. Yashtulov, and N. K. Zaitsev. "THE EFFECT OF SURFACTANTS ON THE CHEMILUMINESCENT REACTION OF LUMINOL WITH HYDROGEN PEROXIDE." Fine Chemical Technologies 12, no. 6 (December 28, 2017): 71–76. http://dx.doi.org/10.32362/2410-6593-2017-12-6-71-76.

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The luminol-hydrogen peroxide chemiluminescent system is widely used for the creation of diagnostic systems, for chemical analysis, for studying the kinetics and mechanisms of chemical reactions, for the creation of special and emergency light sources, and for monitoring living systems. However, the use of the luminol-hydrogen peroxide chemiluminescent system is limited by the fact that there are almost no ways of managing the reaction. The introduction of organized molecular systems into the luminol-hydrogen peroxide chemiluminescent system can create an additional channel for controlling chemiluminescent reactions. The luminol-hydrogen peroxide system was not previously studied in various classes of hydrocarbon and perfluorinated micellar solutions. This work was the first to study the effect of cationic, anionic and nonionic hydrocarbon surface-active substances (cetyltrimethylammonium bromide, sodium decyl sulfate, sodium dodecyl sulfate, triton X 100) and perfluorinated surface-active substances (FT-135 and FT-248) on the chemiluminescent systems luminol-hydrogen peroxide-potassium hexacyanoferrate(III) and luminol-hydrogen peroxide-copper(II) sulphate. The systems retain the ability to chemiluminescence in the presence of a surfactant. Cationic surfactants lower the intensity of chemiluminescence, and anionic surfactants increase the intensity of chemiluminescence. The introduction of a surfactant into the system allows increasing the range of dependence of the chemiluminescence intensity on the catalyst concentration. Kinetic curves of the growth and decay of chemiluminescence were measured in the systems. The rate constants of the chemiluminescence decay were measured in the framework of the first-order kinetics model.

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Fereja, Tadesse Haile, Ariaya Hymete, and Thirumurugan Gunasekaran. "A Recent Review on Chemiluminescence Reaction, Principle and Application on Pharmaceutical Analysis." ISRN Spectroscopy 2013 (November 26, 2013): 1–12. http://dx.doi.org/10.1155/2013/230858.

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This paper provides a general review on principle of chemiluminescent reactions and their recent applications in drug analysis. The structural requirements for chemiluminescent reactions and the different factors that affect the efficiency of analysis are included in the review. Chemiluminescence application in immunoassay is the new version for this review. Practical considerations are not included in the review since the main interest is to state, through the aforementioned applications, that chemiluminescence has been, is, and will be a versatile tool for pharmaceutical analysis in future years.

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Fethi, F., F. Poblete, E. Martinez, A. Gonzalez Urena, and G. Taieb. "Reaction Cross Sections of Ca (41S, 43P and 31D States) With Halogenated Compounds and Water." Laser Chemistry 16, no. 4 (January 1, 1996): 229–43. http://dx.doi.org/10.1155/1996/29359.

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By using two independent and different methods, absolute values of the reaction cross-sections have been determined for the following chemiluminescent reactions Ca(3P,1D)+Cl4C(CHBr3)→CaX*(A, B)(X=Cl, Br)+Cl3C(CHBr2) and Ca(1D)+H2O→CaOH*+H Both chemiluminescence and laser-induced fluorescence spectra are reported. A comparison with related types of reactions is also presented.

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Pranszke, B., P. Kierzkowski, and A. Kowalski. "A Search for Isotope Effects in Chemiluminescent Reactions of Metastable Ca*( 3Pj, 1D2 ) Atoms with CH3I and CD3I Molecules." Zeitschrift für Naturforschung A 54, no. 3-4 (April 1, 1999): 191–94. http://dx.doi.org/10.1515/zna-1999-3-406.

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Chemiluminescent reactions of calcium atoms in the metastable 3Pj and 1D2 states with CH3I and CD3I were studied in a beam-gas arrangement. Calcium monoiodide spectra associated with transitions from the electronic A 2Π, B 2Σ+ and C 2Π states to the X 2Σ+ ground state were recorded. Total collision and chemiluminescence cross sections were measured. It was found that isotopic substitution in the methyl group does not change the reaction cross sections and the chemiluminescence spectra.

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Peck, Evan M., Allen G. Oliver, and Bradley D. Smith. "Enhanced Squaraine Rotaxane Endoperoxide Chemiluminescence in Acidic Alcohols." Australian Journal of Chemistry 68, no. 9 (2015): 1359. http://dx.doi.org/10.1071/ch15196.

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Squaraine rotaxane endoperoxides (SREPs) are storable chemiluminescent compounds that undergo a clean cycloreversion reaction that releases singlet oxygen and emits near-infrared light when warmed to body temperature. This study examined the effect of solvent on SREP chemiluminescence intensity and found that acidic alcohols, such as 2,2,2-trifluoroethanol, α-(trifluoromethyl)benzyl alcohol, and 1,1,1,3,3,3-hexafluoroisopropanol, greatly increased chemiluminescence. In contrast, aprotic solvents, such as trifluoroethylmethyl ether, had no effect. The interlocked rotaxane structure was necessary as no chemiluminescence was observed when the experiments were conducted with samples containing a mixture of the two non-interlocked components (squaraine thread and macrocycle endoperoxide). Spectroscopic analyses of the enhanced SREP chemiluminescent reactions showed a mixture of products. In addition to the expected squaraine rotaxane product caused by cycloreversion of the endoperoxide, a diol derivative was isolated. The results are consistent with an endoperoxide O–O bond cleavage process that is promoted by the hydrogen bonding solvent and produces light emission from a squaraine excited state.

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Motoyoshiya, Jiro. "Chemiluminescence in Organic Reactions: Fundamental Investigation and Application of Peroxyoxalate Chemiluminescence and Related Chemiluminescent Reactions." Journal of Synthetic Organic Chemistry, Japan 70, no. 10 (2012): 1018–29. http://dx.doi.org/10.5059/yukigoseikyokaishi.70.1018.

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Mei, Zhenhua, Shuyu Mei, and Xu Hun. "Thermodynamic Study of Chemiluminescent Reactions." Asian Journal of Chemistry 25, no. 8 (2013): 4731–34. http://dx.doi.org/10.14233/ajchem.2013.14075.

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Shinkai, Seiji, Kaori Ueda, Osamu Manabe, Yasuhiro Tezuka, Takashi Harayama, and Fumio Yoneda. "Chemiluminescent reactions of "unmodified" flavins." CHEMICAL & PHARMACEUTICAL BULLETIN 34, no. 5 (1986): 2272–74. http://dx.doi.org/10.1248/cpb.34.2272.

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Cui, Hua, Zhi-Feng Zhang, and Ming-Juan Shi. "Chemiluminescent Reactions Induced by Gold Nanoparticles." Journal of Physical Chemistry B 109, no. 8 (March 2005): 3099–103. http://dx.doi.org/10.1021/jp045057c.

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Marquette, Christophe A., Agnès Degiuli, and Loïc J. Blum. "Fiberoptic Biosensors Based on Chemiluminescent Reactions." Applied Biochemistry and Biotechnology 89, no. 2-3 (2000): 107–16. http://dx.doi.org/10.1385/abab:89:2-3:107.

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Dissertations / Theses on the topic "Chemiluminescent reactions"

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Smith, P. A. "Dynamics of chemiluminescent atomic reactions." Thesis, University of Nottingham, 1986. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.372672.

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Raybone, D. "Chemiluminescent and photochemical processes in the gas phase." Thesis, University of Manchester, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.383197.

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Hindson, Benjamin Joseph, and mikewood@deakin edu au. "The Chemistry, spectroscopy and analytical applications of certain chemiluminescent reactions." Deakin University. School of Biological and Chemical Sciences, 2001. http://tux.lib.deakin.edu.au./adt-VDU/public/adt-VDU20051017.114704.

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Chemiluminescence, the production of light from a chemical reaction, has found widespread use in analytical chemistry. Both tris (2, 2-bipyridyl) ruthenium (II) and acidic potassium permanganate are chemiluminescence reagents that have been employed for the determination of a diverse range of analytes. This thesis encompasses some fundamental investigations into the chemistry and spectroscopy of these chemiluminescence reactions as well as extending the scope of their analytical applications. Specifically, a simple and robust capillary electrophoresis chemiluminescence detection system for the determination of codeine, O6-methylcodeine and thebaine is described, based upon the reaction of these analytes with chemically generated tris(2,2'-bipyridyl)ruthenium(III) prepared in sulfuric acid (0.05 M). The reagent solution was contained in a glass detection cell, which also held both the capillary and the cathode. The resultant chemiluminescence was monitored directly using a photomultiplier tube mounted flush against the base of the detection cell. The methodology, which incorporated a field amplification sample introduction procedure, realised detection limits (3a baseline noise) of 5 x 10~8 M for both codeine and O6-methylcodeine and 1 x 10~7 M for thebaine. The relative standard deviations of the migration times and the peak areas for the three analytes ranged from 2.2 % up to 2.5 % and 1.9 % up to 4.6 % respectively. Following minor instrumental modifications, morphine, oripavine and pseudomorphine were determined based upon their reaction with acidic potassium permanganate in the presence of sodium polyphosphate. To ensure no migration of the permanganate anion occurred, the anode was placed at the detector end whilst the electroosmotic flow was reversed by the addition of hexadimethrine bromide (0.001% m/v) to the electrolyte. The three analytes were separated counter to the electroosmotic flow via their interaction with a-cyclodextrin. The methodology realised detection limits (3 x S/N) of 2.5 x 10~7 M for both morphine and oripavine and 5 x 10~7 M for pseudomorphine. The relative standard deviations of the migration times and the peak heights for the three analytes ranged from 0.6 % up to 0.8 % and 1.5% up to 2.1 % respectively. Further improvements were made by incorporating a co-axial sheath flow detection cell. The methodology was validated by comparing the results realised using this technique with those obtained by high performance liquid chromatography (HPLC), for the determination of both morphine and oripavine in seven industrial process liquors. A complimentary capillary electrophoresis procedure with UV-absorption detection was also developed and applied to the determination of morphine, codeine, oripavine and thebaine in nine process liquors. The results were compared with those achieved using a standard HPLC method. Although over eighty papers have appeared in the literature on the analytical applications of acidic potassium permanganate chemiluminescence, little effort has been directed towards identifying the origin of the luminescence. It was found that chemiluminescence was generated during the manganese(III), manganese(IV) and manganese(VII) oxidations of sodium borohydride, sodium dithionite, sodium sulfite and hydrazine sulfate in acidic aqueous solution. From the corrected chemiluminescence spectra, the wavelengths of maximum emission were 689 ± 5 nm and 734 ± 5 nm when the reactions were performed in sodium hexametaphosphate and sodium dihydrogenorthophosphate or orthophosphoric acid environments respectively. The corrected phosphorescence spectrum of manganese(II) sulfate in a solution of sodium hexametaphosphate at 77 K, exhibited two peaks with maxima at 688 nm and 730 nm. The chemical and spectroscopic evidence presented strongly supported the postulation that the emission was an example of solution phase chemically induced phosphorescence of manganese(II). Thereby confirming earlier predictions that the chemiluminescence from acidic potassium permanganate reactions originated from an excited manganese(II) species. Additionally, these findings have had direct analytical application in that manganese(IV) was evaluated as a new reagent for chemiluminescence detection. The oxidations of twenty five organic and inorganic species, with solublised manganese(IV), were found to elicit analytically useful chemiluminescence with detection limits (3 x S/N) for Mn(II), Fe(II), morphine and codeine of 5 x 10-8 M, 2.5 x 10-7 M, 7.5 x 10-8 M and 5 x 10-8M, respectively. The corrected emission spectra from four different analytes gave wavelengths of maximum emission in the range from 733 nm up to 740 nm indicating that these chemiluminescence reactions also shared a common emitting species, excited manganese(II). Whilst several analytical problems were addressed in this thesis and answers to certain questions regarding the fundamentals of acidic potassium permanganate chemiluminescence were proposed, there are several areas that would benefit from further research. These are outlined in the final chapter of this thesis.

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Gerardi, Richard David, and mikewood@deakin edu au. "Investigations into the analytical applications and fundamental chemistry of the chemiluminescent reactions of Tris(22-bipyridyl)ruthenium(III) with certain Papaver Somniferum alkaloids and other related compounds." Deakin University. School of Biological and Chemical Sciences, 1999. http://tux.lib.deakin.edu.au./adt-VDU/public/adt-VDU20060630.100432.

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The reaction of tris(2,2-bipyridyl)ruthenium(III) (Ru(bipy) ₃³⁺) with various analytes to generate chemiluminescence has been well documented. This investigation sought to undertake a chemiluminometic study of the reactions of Ru(bipy) ₃³⁺ with selected Papaver Somniferum alkaloids and specifically synthesised phenethylamines. The investigation, based on a kinetic study, primarily addressed the effect of varying reaction conditions (pH) on Ru(bipy) ₃³⁺ chemiluminescence production. To monitor these reactions, a batch chemiluminometer was specifically designed, fabricated and automated to conduct an extensive study on the selected compounds of interest. The instrumentation incorporated a custom built reaction cell and comprised an on-line sample preparation system with which calibration standards could be automatically prepared. The instrumentation provided both time-independent (peak area) and time-dependent (kinetic profile) information. A novel approach to the stabilisation of Ru(bipy) ₃³⁺ as a chemiluminescencent reagent was also investigated and a recirculating system was employed with the batch chemiluminometer to provide a stable supply of Ru(bipy) ₃³⁺. Codeine, thebaine and 6-methoxy-codeine were the Papaver Somniferum alkaloids selected for this study and several N-methylated and N,N-dimethylated phenethylamines and methoxy-substituted phenetheylamines were also synthesised to investigate the affect of pH on the chemiluminescence emission efficiency. The versatility of the batch chemiluminometer facilitated the kinetic study of numerous analytes over a broad pH range. The exemplary performance of the chemiluminometer as an analytical instrument, was demonstrated by the calibration functions, based on peak area data, which exhibited excellent linearity and sensitivity. The estimated detection limits (3σ) for the selected alkaloids were in the range 2 x 10&^{-9<&/sup;> M to 7 x 10&^{-9<&/sup;> at pH 5.0 and above, which compared favourably to detection limits for the same compounds determined using FIA. Relative standard deviations (n=5) for peak areas ranged between 1% to 5% with a mean of 3.1% for all calibration standards above 2.5 x 10&^{-8<&/sup;> M. Correlation between concentration and peak area, irrespective of pH and analyte was excellent, with all but two calibration functions having r-squared values greater than 0.990. The analytical figures of merit exemplified the precision and robustness of the reagent delivery and on-line sample preparation, as well as the sensitivity of the system. The employment of the chemiluminometer for the measurement of total chemiluminescence emission (peak area) was in itself a feasible analytical technique, which generated highly reproducible and consistent data. Excellent analytical figures of merit, based on peak area, were similarly achieved for the phenethylamines.

The effects of analyte structure on chemiluminescence activity was also investigated for the alkaloids and the phenethylamines. Subtle structural variations between the three alkaloids resulted in either a moderately reduced or enhanced total emission that was two or three fold difference only. A significant difference in reaction kinetics was observed between thebaine and codeine/6-methoxy-codeine, which was dependent upon pH. The time-dependent data, namely the observed rate constants for the initial rise in intensity and for the subsequent decay rate, were obtained by fitting a mathematical function (based on the postulated reaction mechanism) to the raw data. The determination of these rate constants for chemiluminescence reactions highlighted the feasibility for utilising such measurements for quantitative analytical applications. The kinetic data were used to discriminate between analyte responses in order to determine the concentrations of individual analytes in a binary mixture. A preliminary, multi-component investigation performed on a binary mixture of codeine and 6-methoxy-codeine (1:1) successfully determined the concentrations of these individual components using such rate constant measurements.

Consequently, variations in kinetics resulted in a significant difference between the relative chemiluminescence response based on peak area measurements and the relative response base on peak height measurements obtained using FIA. With regards to the observed reactivity of secondary amines and tertiary amines, chemiluminescence peak area determinations confirmed the vital role of pH on reaction efficiency, which was governed by structural features and kinetics. The tertiary amines investigated generally produced a greater emission under acidic conditions than the corresponding secondary amines. However, the measured chemiluminescence responses were highly dependent upon pH, with similar peak areas obtained for both amine groups under slightly alkaline conditions.}}}

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Green, Karen M. "Investigation of the mechanisms of chemiluminescent fluorine reactions of Manganese & Chromium /." The Ohio State University, 2002. http://rave.ohiolink.edu/etdc/view?acc_num=osu1486457871783155.

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Martínez, Muñoz Daniel. "Theoretical studies of the chemiluminescence reactions; luminol." Thesis, Uppsala universitet, Institutionen för kemi - BMC, 2015. http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-255902.

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The vast majority of chemical reactions occurs only in the ground state, however photochemical reactions like chemiluminescence take place in ground and excited states. In almost all chemiluminescence processes oxygen-oxygen bond breakage is involved. But, there is no general reason to explain why these processes occur via an oxygen-oxygen cleavage. These types of phenomena are usually highly exothermic. Computational chemistry has risen as a powerful tool to characterize and analyze chemical phenomena. Quantum mechanics are utilized to explain chemical observations. Applying these equations, one can compute the chemical properties of any system in any state. In the present study, three chemiluminescence reactions derived from luminol are modeled; nitrogen based, oxygen based and dianion nitrogen based models. The key factor of oxygen-oxygen bond rupture is discussed and rationalized. The electronic potential energy surfaces of the three compounds are computed at complete active space self-consistent field theory. Peroxide compounds compared to the dinitrogenated compounds show a lower activation energy and they are more exothermic. This study allows us to rationalize why luminol needs to be presented in a basic medium and oxidized in order to produce chemiluminescence.

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Silva, Sandra Maria da. "Estudo da etapa de quimiexcitação do sistema peroxioxalato." Universidade de São Paulo, 2004. http://www.teses.usp.br/teses/disponiveis/46/46135/tde-03102016-162828/.

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O fenômeno de quimiluminescência é uma das mais fascinantes demonstrações de conversão de energia química em energia de excitação. O representante de maior eficiência dentro desta classe é a reação peroxioxalato, pois possui rendimento de emissão de aproximadamente 30%, comparado apenas a sistemas bioluminescentes, cujo rendimento é da ordem de 100%. O sistema peroxioxalato consiste na reação de derivados fenólicos com substituintes atraentes de elétrons do éster oxálico com peróxido de hidrogênio catalisada por base na presença de um hidrocarboneto aromático policondensado com baixo potencial de oxidação (Eox) e altos rendimentos de fluorescência, denominado ativador. O mecanismo desta reação é bastante complexo com várias etapas consecutivas e paralelas que antecedem a emissão de luz. O ponto chave do mecanismo é a etapa de quimiexcitação, onde um intermediário de alta energia (IAE), formado em etapas anteriores, interage com o ativador (ACT), resultando na formação de estados eletronicamente excitados e subseqüentemente em emissão de luz. Para explicar esta interação, é utilizado o mecanismo de Luminescência Induzida Quimicamente pela Transferência de Elétron (UChemically Initiated Electron Exchange Luminescence\" - CIEEL), o qual envolve transferência e retro-transferência de elétron. O ponto de controvérsia entre vários pesquisadores que estudam a reação peroxioxalato está relacionado com a estrutura do intermediário de alta energia (IAE), pois, de acordo, com os resultados destes trabalhos, diferentes intermediários foram postulados (A-H). (Ver arquivo). O enfoque geral deste trabalho foi estudar a natureza do IAE e a etapa de quimiexcitação com o intuito de obter evidências sobre o mecanismo de geração de estados excitados no sistema peroxioxalato. Para que isto fosse possível, o trabalho foi abordado da seguinte maneira: 1- Síntese e caracterização de intermediários perácidos do tipo D contendo OCH3, CH3, H e NO2 substituídos no anel aromático. Do estudo cinético da reação destes compostos, catalisada por imidazol, na presença de 9,10-difenilantraceno, foi possível propor um mecanismo completo e obter informações a respeito da estrutura do IAE; através da correlação de Hammett foram obtidas evidências para a ocorrência da 1,2-dioxetanodiona (A), como IAE na reação peroxioxalato. 2- Estudo da eficiência de transferência de elétron na etapa de quimiexcitação (mecanismo CIEEL) utilizando a reação do bis(2,4,6-triclorofenil) oxalato (TCPO) com H2O2 catalisado por imidazol na presença de 3-(2-aril-5,5-dimetiloxazol-4-ilideno)androsta-1 ,4-dien-17-onas como ativadores. As constantes de velocidade relativas da interação do ACT com o IAE mostram correlação linear com o Eox do ACT e os rendimentos quânticos singlete em concentrações infinitas do ACT (Φs∞) correlacionam com as energias livres para a formação do ativador no estado excitado (ΔG*BET) através do processo de retro-transferência de elétron. Desde modo, os resultados obtidos apresentam evidências para a validade do mecanismo CIEEL utilizado para explicar a formação de estados excitados na etapa de quimiexcitação da reação peroxioxalato. 3- Com o objetivo de obter informações sobre a influência da viscosidade no rendimento quântico singlete (Φs) foram feitos estudos da reação do TCPO catalisada por imidazol com H2O2 na presença de 9,1 O-difenilantraceno (DPA) como ativador, utilizando-se misturas variadas de tolueno e difenilmetano. Foi observado aumento de até 10 vezes no rendimento quântico singlete com o aumento da viscosidade de 0,5 para 2,5 cP. Este comportamento é compatível com o mecanismo CIEEL, indicando que a etapa de quimiexcitação ocorre em uma seqüência de eventos, envolvendo intermediários íons radicais. 4- Síntese de derivados de oxazolonas esteroidais substituídos, com o objetivo de obter compostos com novas propriedades foto-físicas e físicoquímicas para aplicar no estudo da reação peroxioxalato, especificamente para obter informações adicionais sobre a etapa de quimiexcitação. O outro interesse nestes compostos era o de transformá-los em reagentes de derivatização para futuramente empregá-los em trabalhos de química analítica que utilizam a reação peroxioxalato. Foram preparados dois novos compostos fluorescentes, além de vários intermediários sintéticos e estes derivados possuem potencial para o uso como ACT em futuras aplicações analíticas.
The phenomenon of chemiluminescence (CL) is one of the most fascinating demonstrations of chemical energy conversion into excitation energy. The most prominent example of this c1ass of reaction is the peroxyoxalate system showing emission quantum yields of around 30 %, comparable only to the 100 % efficiency bioluminescence systems. The peroxyoxalate system consists in the base catalyzed reaction of activated oxalate esters with hydrogen peroxide in the presence of polycondensed aromatic hydrocarbons with low oxidation potentials (Eox) and high fluorescence quantum yields, denominated activatars (ACT). The mechanism of this reaction is quite complex with various subsequent and parallel reaction steps prior to light emission. The crucial mechanistic step is the chemiexcitation step, where a highenergy intermediate (HEI), formed in former reaction steps, interacts with the ACT resulting in excited state formation and subsequent light emission. This interaction can be understood on the basis of the Chemically Initiated Electron Exchange (CIEEL) mechanism, which involves electron and back-electron transfer steps. A controversial point between various authors who study mechanistic aspects of the peroxyoxalate reaction is related to the nature of the high-energy intermediate (HEI) and different proposal for its structure (A - I) have been made. (See file). The main object of this work was to study the nature of the HEI and the chemiexcitation step in arder to obtain evidence with respect to the chemiexcitation mechanism in peroxyoxalate CL. For this purpose, the following approach was used: 1 - Synthesis and characterization of peracid intermediates of type

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Sanders, Matthew Graham. "Analytical applications of the peroxyoxalate chemiluminescence reaction." Thesis, University of Plymouth, 1999. http://hdl.handle.net/10026.1/1832.

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The overall objectives of this thesis were to investigate the potential of the peroxyoxalate chemiluminescence (POOL) reaction for the quantitative detection of target analytes in non-aqueous matrices and to compare quantitative performance with fluorescence detection. The target analytes investigated were polycyclic aromatic hydrocarbons (PAHs) and aliphatic amines. These were selected as an important class of compounds in engine exhaust emissions and a detergent additive in diesel fuel respectively. Chapter one outlines the challenges of analysing petroleum products and engine exhaust emissions and discusses the potential of luminescence techniques, particularly chemiluminescence (CL), for the quantification of trace components. The chapter also reviews the technique of flow injection (FT) as a means of sample delivery for CL detection and as a potential technique for field deployment. Liquid chromatography techniques are described as a means of separation of complex matrices, e.g. fuels and engine exhaust particulates, in the laboratory prior to CL detection. The luminescence properties of several PAHs were investigated in Chapter Two. Optimum excitation and emission wavelengths for eleven PAHs in four different solvents were determined using a batch fluorescence technique. A FI approach was used to determine PAH concentrations using fluorescence and POCL detection. Two aryl oxalates; bis(2,4-dinitophenyl)oxalate and bis(2,4,6-trichlorophenyl)oxalate were compared for their suitability for PAH determinations and an investigation of the key variables (e.g. concentration of aryl oxalate and hydrogen peroxide, mobile phase composition and pH) affecting POCL was performed. Recommendations for the optimum conditions for the determination of PAHs by POCL detection were determined, A comparison between a photodiode based detection device and a low power (12V) photomultiplier tube was also described. In Chapter Three the procedure of using POCL detection as a post column liquid chromatography (LC) detector for PAHs has been considered. The performance of the POCL detection system was compared with wavelength programmed fluorescence. Both reversed and normal phase LC was investigated and the suitability of POCL detection with each approach was discussed. Additionally the procedure for the LC separation and analysis of SRM 1649 (Urban Dust/Organics) and SRM 1650 (Diesel Particulate Matter) was described. The relative performance of fluorescence and CL detection are discussed. Chapter four describes the principles of multivariate calibration of spectrophotometric data, and three commonly applied techniques (PCR, PLSI and PLS2). Fluorescence data was obtained for synthetic mixtures of PAHs containing two, three, four and five components. A procedure whereby individual spectra were 'glued' together before undergoing data analysis has been developed and the results obtained discussed. POCL emission spectra for five PAHs were acquired using a two-dimensional charge coupled device (CCD). The sensitivity of the CCD system toward POCL detection of PAHs and a multivariate investigation using benzo[a]pyrene and benzo[k]fluoranthene has been described. The potential of the fluorescence and CL approaches used has been discussed. Chapter five describes the aryl oxalate sulphorhodamine-101 CL reaction and its application to the determination of amines. A FI optimisation of the reaction parameters is presented together with some quantitative data for the detection of a homologous series of amines and dodecylamine (a commonly added detergent compound in diesel fuels). The application of the technique toward the detection of dodecylamine in a diesel fuel matrix and the potential as a field deployable technique was also considered.

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Braynis, H. S. "Chemiluminescence and kinetic studies of gaseous fluorine atom reactions." Thesis, University of Manchester, 1987. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.377719.

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Otamonga, Jean Paul. "Stopped-flow kinetic investigation of manganese-based chemiluminescence oxidation reactions." Thesis, University of Huddersfield, 2013. http://eprints.hud.ac.uk/id/eprint/18054/.

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In order to better understand the mechanism of solution manganese-based chemilumines-cence, the kinetics of a number of chemiluminescent oxidations by manganese species were studied using stopped-flow spectrophotometry. Both the kinetics of the decay of the oxi-dant and the chemiluminescence emission were followed for oxidations by permanganate, manganese dioxide sol and Mn3+(aq) of a range of organic compounds. The most detailed studies were carried out on the oxidation of the relatively simple compounds including glyoxylic acid and glyoxal under pseudo first order conditions and an acidic medium at 25oC. For permanganate under these conditions, the decay is sigmoidal consistent with autocatalysis and for managanese dioxide sol and Mn3+ pseudo first order. Simple mechanisms are suggested and compared with the experimental kinetic data. For per-manganate CL system, the following chemical kinetic model was considered: MnO4- + xsR à MnO2 (k1) MnO2 + xsR à Mn3+ (k2) MnO4- + 3Mn3+ à 4MnO2 (k3) Mn3+ + xsR à (Mn2+)*

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Books on the topic "Chemiluminescent reactions"

1

Birks, John W. Chemiluminescence and Photochemical Reaction Detection in Chromatography. Wiley-VCH Verlag GmbH, 1989.

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W, Birks John, ed. Chemiluminescence and photochemical reaction detection in chromatography. New York: VCH Publishers, 1989.

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Miller, Robert J. Characterization and applications of polyphenol chemiluminescence reactions and flow cell instrumentation. 1991.

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Spence, M. A. Chemiluminescence and rotational alignment in energetic manganese oxidation reactions. 1999.

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Bolden, Michael E. Investigation of the tris(2,2'-bipyridine)ruthenium(III) chemiluminescence reaction for the determination of aromatic amines and aldehydes by flow injection or liquid chromatography. 2001.

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Book chapters on the topic "Chemiluminescent reactions"

1

Mccapra, Frank. "Chemiluminescent Reactions of Acridines." In Chemistry of Heterocyclic Compounds: A Series Of Monographs, 615–30. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2008. http://dx.doi.org/10.1002/9780470186596.ch10.

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Davis, Stephen J., and Anne M. Woodward. "State Selective Chemiluminescent Reactions for Chemical Laser Applications." In Selectivity in Chemical Reactions, 497–513. Dordrecht: Springer Netherlands, 1988. http://dx.doi.org/10.1007/978-94-009-3047-6_29.

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Givens, Richard S., Richard L. Schowen, John Stobaugh, Theodore Kuwana, Francisco Alvarez, Nikhil Parekh, Bogdan Matuszewski, et al. "Peroxyoxalate Chemiluminescence Reaction." In ACS Symposium Series, 127–54. Washington, DC: American Chemical Society, 1989. http://dx.doi.org/10.1021/bk-1989-0383.ch008.

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Costantini, F., R. M. Tiggelaar, R. Salvio, M. Nardecchia, S. Schlautmann, C. Manetti, H. J. G. E. Gardeniers, D. Caputo, A. Nascetti, and G. de Cesare. "Portable Optoelectronic System for Monitoring Enzymatic Chemiluminescent Reaction." In Lecture Notes in Electrical Engineering, 189–94. Cham: Springer International Publishing, 2019. http://dx.doi.org/10.1007/978-3-030-04324-7_25.

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Trautmann, M., T. Trickl, and J. Wanner. "IF(A-X, B-X) Chemiluminescence of Fluorine-Iodide Systems in a Crossed Molecular Beam Experiment." In Selectivity in Chemical Reactions, 525–29. Dordrecht: Springer Netherlands, 1988. http://dx.doi.org/10.1007/978-94-009-3047-6_31.

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Yasuda, Hiroshi, Masayuki Miki, Yoshito Takenaka, Hiroshi Tamai, and Makoto Mino. "Chemiluminescence from Vitamin E-Deficient Erythrocyte Membranes Induced by Xanthine Oxidase Reaction." In Oxygen Radicals in Biology and Medicine, 249–54. Boston, MA: Springer US, 1988. http://dx.doi.org/10.1007/978-1-4684-5568-7_39.

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Burshtein, A. I. "Non-Markovian Theories of Transfer Reactions in Luminescence and Chemiluminescence and Photo- and Electrochemistry." In Advances in Chemical Physics, 105–418. Hoboken, NJ, USA: John Wiley & Sons, Inc., 2004. http://dx.doi.org/10.1002/047168077x.ch3.

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Allen, Robert C. "Phagocyte Dioxygenation Reactions Yielding Chemiluminescence: The Maximum Multiplicity and Spin Conservation Rules Relative to Oxygen Reactivity." In Oxygen Radicals in Biology and Medicine, 219–22. Boston, MA: Springer US, 1988. http://dx.doi.org/10.1007/978-1-4684-5568-7_33.

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"The Nature of Chemiluminescent Reactions." In Chemiluminescence in Analytical Chemistry, 85–100. CRC Press, 2001. http://dx.doi.org/10.1201/9781482270693-9.

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Thorpe, Gary H. G., and Larry J. Kricka. "[29] Enhanced chemiluminescent reactions catalyzed by horseradish peroxidase." In Methods in Enzymology, 331–53. Elsevier, 1986. http://dx.doi.org/10.1016/0076-6879(86)33078-7.

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Conference papers on the topic "Chemiluminescent reactions"

1

KIMURA, M., H. IGA, H. ARAKI, and M. MATSUMOTO. "RELATIONSHIP BETWEEN HEAT OF REACTION AND CHEMILUMINESCENCE EFFICIENCY OF CHEMILUMINESCENT REACTIONS." In Proceedings of the 13th International Symposium. WORLD SCIENTIFIC, 2005. http://dx.doi.org/10.1142/9789812702203_0036.

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Chen, Kuo-mei. "Chemiluminescent reactions of laser-generated metal atoms with oxidants." In OE/LASE '92, edited by Cheuk-Yiu Ng. SPIE, 1992. http://dx.doi.org/10.1117/12.58153.

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Park, Y. S., M. M. Andringa, D. P. Neikirk, H. S. Hewage, and E. V. Anslyn. "Smart microplates: integrated photodiodes for detecting bead-based chemiluminescent reactions." In 2006 5th IEEE Conference on Sensors. IEEE, 2006. http://dx.doi.org/10.1109/icsens.2007.355534.

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Pranszke, B. "Steric effects in the chemiluminescent reactions of metastable Ca*(3P) atoms with isomeric alkyl halides." In IV Workshop on Atomic and Molecular Physics, edited by Jozef Heldt. SPIE, 2003. http://dx.doi.org/10.1117/12.544435.

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FENG, Y., R. H. DAVIES, and J. D. ANDRADE. "ENZYME KINETICS MODEL OF THE BACTERIAL LUCIFERASE REACTIONS FOR BIOSENSOR APPLICATIONS." In Bioluminescence and Chemiluminescence - Progress and Current Applications - 12th International Symposium on Bioluminescence (BL) and Chemiluminescence (CL). WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812776624_0100.

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KAZAKOV, VP, SS OSTAKHOV, DV KAZAKOV, AV MAMIKIN, VA ANTIPIN, SN KLIMINA, LN KHAZIMULLINA, and OA KOCHNEVA. "CHEMILUMINESCENCE IN THE REACTIONS OF URANIUM AND LANTHANIDES." In Proceedings of the 13th International Symposium. WORLD SCIENTIFIC, 2005. http://dx.doi.org/10.1142/9789812702203_0033.

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NAKASHIMA, K., K. ABE, S. NAKAMURA, M. WADA, S. HARADA, and N. KURODA. "EFFECT OF SURFACTANTS ON PEROXYOXALATE CHEMILUMINESCENCE REACTION." In Proceedings of the 15th International Symposium. WORLD SCIENTIFIC, 2008. http://dx.doi.org/10.1142/9789812839589_0031.

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CHAICHI, M. J., and M. SHAMSIPOUR. "A STUDY OF CHEMILUMINESCENCE FROM REACTIONS OF PEROXYOXALATE ESTERS, HYDROGEN PEROXIDE AND 7-AMINO-4-TRIFLUOROMETHYLCOUMARIN." In Bioluminescence and Chemiluminescence - Progress and Current Applications - 12th International Symposium on Bioluminescence (BL) and Chemiluminescence (CL). WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812776624_0031.

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MOTOYOSHIYA, J., M. YOKOTA, M. HOTTA, Y. NISHII, and H. AOYAMA. "CHEMILUMINESCENCE REACTION OF 4-STYRYLPHTHALHYDRAZIDES: REMARKABLE SUBSTITUENT EFFECT ON THE EMITTING SPECIES AND CHEMILUMINESCENCE EFFICIENCY." In Proceedings of the 13th International Symposium. WORLD SCIENTIFIC, 2005. http://dx.doi.org/10.1142/9789812702203_0040.

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ITO, KATSUTOSHI, KAZUTO NAKAGAWA, SEIJI MURAKAMI, HIDETOSHI ARAKAWA, and MASAKO MAEDA. "DEVELOPMENT OF SIMULTANEOUS BIOLUMINESCENT ASSAY OF ACETATE KINASE AND PYRUVATE PHOSPHATE DIKINASE USING FIREFLY LUCIFERASE-LUCIFERIN REACTION." In Bioluminescence and Chemiluminescence - Progress and Current Applications - 12th International Symposium on Bioluminescence (BL) and Chemiluminescence (CL). WORLD SCIENTIFIC, 2002. http://dx.doi.org/10.1142/9789812776624_0102.

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Reports on the topic "Chemiluminescent reactions"

1

Vaghjiani, Ghanshyam L. Kinetic Studies of UV/Vis-Chemiluminescence in the CH + O2 Gas Phase Reaction. Fort Belvoir, VA: Defense Technical Information Center, February 2003. http://dx.doi.org/10.21236/ada412562.

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Vaghjiani, Ghanshyam L. Investigations of the CO-Chemiluminescence in the Reaction of Ketene With Excess Oxygen Atoms. Fort Belvoir, VA: Defense Technical Information Center, January 2000. http://dx.doi.org/10.21236/ada381370.

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Vaghjiani, Ghanshyam. Kinetics of CH Radicals With O2: Evidence for CO-Chemiluminescence in the Gas Phase Reaction. Fort Belvoir, VA: Defense Technical Information Center, June 2002. http://dx.doi.org/10.21236/ada406218.

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