Academic literature on the topic 'Chemically modified electrodes'

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Journal articles on the topic "Chemically modified electrodes"

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Kaya, Sariye I., Tutku C. Karabulut, Sevinç Kurbanoglu, and Sibel A. Ozkan. "Chemically Modified Electrodes in Electrochemical Drug Analysis." Current Pharmaceutical Analysis 16, no. 6 (July 1, 2020): 641–60. http://dx.doi.org/10.2174/1573412915666190304140433.

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Electrode modification is a technique performed with different chemical and physical methods using various materials, such as polymers, nanomaterials and biological agents in order to enhance sensitivity, selectivity, stability and response of sensors. Modification provides the detection of small amounts of analyte in a complex media with very low limit of detection values. Electrochemical methods are well suited for drug analysis, and they are all-purpose techniques widely used in environmental studies, industrial fields, and pharmaceutical and biomedical analyses. In this review, chemically modified electrodes are discussed in terms of modification techniques and agents, and recent studies related to chemically modified electrodes in electrochemical drug analysis are summarized.
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Guadalupe, Ana R., and Hector D. Abruna. "Electroanalysis with chemically modified electrodes." Analytical Chemistry 57, no. 1 (January 1985): 142–49. http://dx.doi.org/10.1021/ac00279a036.

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Bonakdar, M., and Horacio A. Mottola. "Electrocatalysis at chemically modified electrodes." Analytica Chimica Acta 224 (1989): 305–13. http://dx.doi.org/10.1016/s0003-2670(00)86567-8.

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Lu, Ziling, and Shaojun Dong. "Researches on chemically modified electrodes." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 233, no. 1-2 (September 1987): 19–27. http://dx.doi.org/10.1016/0022-0728(87)85002-7.

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Shaojun, Dong, and Li Fengbin. "Researches on chemically modified electrodes." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 217, no. 1 (January 1987): 49–63. http://dx.doi.org/10.1016/0022-0728(87)85063-5.

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Jiang, Rongzhong, and Shaojun Dong. "Research on chemically modified electrodes." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 246, no. 1 (May 1988): 101–17. http://dx.doi.org/10.1016/0022-0728(88)85054-x.

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Shaojun, Dong, and Li Fengbin. "Researches on chemically modified electrodes." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 210, no. 1 (October 1986): 31–44. http://dx.doi.org/10.1016/0022-0728(86)90313-x.

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Geno, Paul W., K. Ravichandran, and Richard P. Baldwin. "Chemically modified carbon paste electrodes." Journal of Electroanalytical Chemistry and Interfacial Electrochemistry 183, no. 1-2 (February 1985): 155–66. http://dx.doi.org/10.1016/0368-1874(85)85488-5.

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Dong, Shaojun, and Rongzhong Jiang. "Research on chemically modified electrodes." Journal of Molecular Catalysis 42, no. 1 (September 1987): 37–50. http://dx.doi.org/10.1016/0304-5102(87)85037-x.

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Chillawar, Rakesh R., Kiran Kumar Tadi, and Ramani V. Motghare. "Voltammetric Techniques at Chemically Modified Electrodes." Журнал аналитической химии 70, no. 4 (2015): 339–58. http://dx.doi.org/10.7868/s0044450215040180.

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Dissertations / Theses on the topic "Chemically modified electrodes"

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Dicks, J. M. "Amperometric biosensors and chemically modified electrodes." Thesis, Cranfield University, 1988. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.233354.

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Xin, Junhua Shannon Curtis. "Chemically modified electrodes a supramolecular assembly approach /." Auburn, Ala, 2008. http://hdl.handle.net/10415/1424.

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Przeworski, J. E. "The development of chemically modified electrodes for electrocatalysis." Thesis, Imperial College London, 1985. http://hdl.handle.net/10044/1/37822.

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Spencer, G. C. W. "The development of conducting polymer electrodes." Thesis, University of Oxford, 1994. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.239274.

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Xu, Shuanghua. "Development and application of chemically modified electrodes for analysis." Thesis, University of Canterbury. Chemistry, 1992. http://hdl.handle.net/10092/8317.

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This thesis presents a study on development and application of chemically modified electrodes (CMEs) for analysis, especially for analysis of aluminium(III). A parallel study involved flow injection analysis with indirect amperometric detection. The electrochemistry was studied for several electroactive ligands which bind strongly to aluminium(III). The effect of pH on redox behaviour was investigated. The complex formation between aluminium(III) and these ligands was examined under different conditions such as pH, electrolyte and temperature. For quantitative determination of aluminium(III), either the increase in peak height due to the redox processes of the formed aluminium(III)-ligand complex, or the decrease of the peak height for free ligand redox processes, was used. Several CMEs were prepared using polymer coatings, chemisorption and by mixing ligand into the electrode material. The use of CMEs consisting of charged polymers for preconcentration of analytes was investigated. The accumulation of aluminium(III) in polyxylylviologen coated electrodes as anionic phenolic complexes was studied. The measurement of aluminium(III)(4-nitrocatechol) complexes which have an overall negative charge resulted in a sensitive method for analysis of aluminium(III). A 1,2-dihydroxyanthraquinone(alizarin)-modified graphite electrode was used in the voltammetric determination of aluminium(III). Alizarin was immobilised on a solid electrode by chemisorption. The electrode was applied in determination of exchangeable aluminium(III) in soils. This provided a simple, rapid method for monitoring aluminium in the environment. Ligands mixed into electrode materials (carbon paste and graphite epoxy) were studied. Graphite epoxy modified with 4- nitrocatechol showed good results for the determination of aluminium(III). In CME studies, it was found that the loss of ligand from CMEs due to irreversible oxidation of ligand and other reasons limits electrodes to single-use. The method for determination of aluminium(III) by adsorptive stripping voltammetry of its SVRS complex was modified by room temperature reaction at a higher pH, followed by accumulation in acidified solution. This method provided good results with high sensitivity and reproducibility and significantly shorter analysis time. Aluminium(III) was determined in a flow injection system involving the formation of the aluminium(III)-1,2- dihydroxyanthraquinone-3-sulphonic acid (DASA) complex and amperometric measurement of excess DASA at +0.50 V on a gold electrode. Electrode fouling by adsorption of ligand oxidation products was minimized by use of a double pumping system and cathodic/anodic voltage cycling. The method was applied to soil extracts. A simple flow system for magnesium(II) determination in natural waters and serum was developed. This involved complexation of magnesium(II) with the redox active ligand eriochrome black T (EBT). Analysis of human blood serum samples was effected by two methods: (1) direct injection of serum after dilution and (2) after dialysis to effect separation of magnesium(II) from acidified serum in the flow system. Electrode fouling by adsorption of EBT oxidation products and serum in the flow system was minimized by use of several surfactants and a dialyzer.
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Lowens, Michael James. "Studies on polypyrrole chemically modified electrodes for analytical voltammetry." Thesis, University of Salford, 1999. http://ethos.bl.uk/OrderDetails.do?uin=uk.bl.ethos.299127.

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Lau, Chung Yin. "Electroanalytical behaviors of chemically modified electrodes bearing complexing ligands." HKBU Institutional Repository, 2007. http://repository.hkbu.edu.hk/etd_ra/833.

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Song, Fayi. "Studies on the preparation and electroanalytical applications of chemically modified electrodes." HKBU Institutional Repository, 2000. http://repository.hkbu.edu.hk/etd_ra/268.

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Elhag, Sami. "Chemically Modified Metal Oxide Nanostructures Electrodes for Sensing and Energy Conversion." Doctoral thesis, Linköpings universitet, Institutionen för teknik och naturvetenskap, 2017. http://urn.kb.se/resolve?urn=urn:nbn:se:liu:diva-134275.

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The goal of this thesis is the development of scalable, low cost synthesis of metal oxide nanostructures based electrodes and to correlate the chemical modifications with their energy conversion performance. Methods in energy conversion in this thesis have focused on two aspects; a potentiometric chemical sensor was used to determine the analytical concentration of some components of the analyte solution such as dopamine, glucose and glutamate molecules. The second aspect is to fabricate a photo-electrochemical (PEC) cell. The biocompatibility, excellent electro-catalytic activities and fast electron transfer kinetics accompanied with a high surface area to volume ratio; are properties of some metal oxide nanostructures that of a potential for their use in energy conversion. Furthermore, metal oxide nanostructures based electrode can effectively be improved by the physical or a chemical modification of electrode surface. Among these metal oxide nanostructures are cobalt oxide (Co3O4), zinc oxide (ZnO), and bismuth-zincvanadate (BiZn2VO6) have all been studied in this thesis. Metal oxide nanostructures based electrodes are fabricated on gold-coated glass substrate by low temperature (< 100 0C) wet chemicalapproach. X-ray diffraction, x-ray photoelectron spectroscopy and scanning electron microscopy were used to characterize the electrodes while ultraviolet-visible absorption and photoluminescence were used to investigate the optical properties of the nanostructures. The resultant modified electrodes were tested for their performance as chemical sensors and for their efficiency in PEC activities. Efficient chemically modified electrodes were demonstrated through doping with organic additives like anionic, nonionic or cationic surfactants. The organic additives are showing a crucial role in the growth process of metal oxide nanocrystals and hence can beused to control the morphology. These organic additives act also as impurities that would significantly change the conductivity of the electrodes. However, no organic compounds dependence was observed to modify the crystallographic structure. The findings in this thesis indicate the importance of the use of controlled nanostructures morphology for developing efficient functional materials.
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Perera, Dingiri Mudiyanselage Neluni T. "Study of permeability changes induced by external stimuli on chemically modified electrodes." Diss., Kansas State University, 2010. http://hdl.handle.net/2097/7030.

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Doctor of Philosophy
Department of Chemistry
Takashi Ito
This research was focused on understanding how external stimuli affect the permeability of the chemically modified electrodes, and how the materials used in modifying the working electrodes respond to the changes in the surface charge. We adopted a voltammetric type electrochemical sensor to investigate the permeability effects induced by pH and organic solvents. The working electrodes used in this research were chemically modified with thioctic acid self assembled monolayer (TA SAM), track etched polycarbonate membranes (TEPCM) and PS-b-PMMA nanoporous films (polystyrene-block-polymethylmethacrylate). We studied the permeability behavior of each of the material upon application of external stimuli. In chapter 3, the permeability changes induced by change in surface charge of thioctic acid SAM was investigated. The surface charge of the monolayer was tuned by changing pH of the medium, which resulted in decrease of redox current of a negatively charged marker due to deprotonation of the surface –COOH groups of TA SAM. Decrease in redox current reflected a decrease in the reaction rate, and by using closed form equations the effective rate constants at several pKa values were extracted. In chapter 4, permeability changes induced by pH in TEPCM were investigated. We assessed the surface charge of these membranes via cyclic voltammetry generated for neutral and charged redox molecules. Limiting current of charged markers were affected by the surface charge induced by pH, where as the redox current for the neutral marker was not affected. Experimental redox currents were larger than the theoretical current, indicating that redox molecules preferentially distributed in a surface layer on the nanopore. Organic solvent induced permeability changes of PS-b-PMMA nanoporous films were investigated via electrochemical impedance spectroscopy and AFM. Higher response of pore resistance in the presence of organic solvents indicated either swelling of the nanoporous film or partitioning of organic solvents in the pores. However AFM data revealed that the permeability changes are due to partitioning of the solvents rather than swelling of the porous film, since there was no appreciable change if the pore diameter in the presence of solvents.
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Books on the topic "Chemically modified electrodes"

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Alkire, Richard C., Dieter M. Kolb, Jacek Lipkowski, and Philip N. Ross, eds. Chemically Modified Electrodes. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2009. http://dx.doi.org/10.1002/9783527627059.

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Alkire, Richard C., Dieter M. Kolb, Jacek Lipkowski, and Phil N. Ross. Chemically Modified Electrodes. Wiley & Sons, Incorporated, John, 2009.

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Alkire, Richard C., Dieter M. Kolb, Jacek Lipkowski, and Phil N. Ross. Chemically Modified Electrodes. Wiley & Sons, Limited, John, 2011.

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Simonet, Jacques. Electro-Catalysis at Chemically Modified Solid Surfaces. World Scientific Publishing Co Pte Ltd, 2017.

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Chemically Modified Electrodes Advances in Electrochemical Sciences and Engineering. Wiley-VCH Verlag GmbH, 2009.

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Hutton, Emily Anne. Chemically modified carbon-based electrodes for the detection of some substances of environmental and biomedical significance. 2003.

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Book chapters on the topic "Chemically modified electrodes"

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Wallace, G. G. "Chemically modified electrodes." In Chemical Sensors, 132–54. Dordrecht: Springer Netherlands, 1988. http://dx.doi.org/10.1007/978-94-010-9154-1_5.

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Gooding, J. Justin, Leo M. H. Lai, and Ian Y. Goon. "Nanostructured Electrodes with Unique Properties for Biological and other Applications." In Chemically Modified Electrodes, 1–56. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527627059.ch1.

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Tagliazucchi, Mario, and Ernesto J. Calvo. "Electrochemically Active Polyelectrolyte-Modified Electrodes." In Chemically Modified Electrodes, 57–115. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527627059.ch2.

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Esplandiu, María José. "Electrochemistry on Carbon-Nanotube-Modified Surfaces." In Chemically Modified Electrodes, 117–68. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527627059.ch3.

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Buttry, Daniel A. "Electrochemistry of Electroactive Surface-Immobilized Nanoparticles." In Chemically Modified Electrodes, 169–96. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527627059.ch4.

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Buck, Manfred. "Structure, Electrochemistry and Applications of Self-Assembled Monolayers of Thiols." In Chemically Modified Electrodes, 197–255. Weinheim, Germany: Wiley-VCH Verlag GmbH & Co. KGaA, 2011. http://dx.doi.org/10.1002/9783527627059.ch5.

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Rodrigues, L. F. F. T. T. G., M. O. S. P. Caldeira, and C. A. C. Sequeira. "Chemically Modified Electrodes and Mesoporous Inorganic Materials." In Multifunctional Mesoporous Inorganic Solids, 473–83. Dordrecht: Springer Netherlands, 1993. http://dx.doi.org/10.1007/978-94-015-8139-4_35.

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Baronas, Romas, Feliksas Ivanauskas, and Juozas Kulys. "Chemically Modified Enzyme and Biomimetic Catalysts Electrodes." In Springer Series on Chemical Sensors and Biosensors, 207–42. Cham: Springer International Publishing, 2020. http://dx.doi.org/10.1007/978-3-030-65505-1_7.

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Gorton, L., B. Persson, M. Polasek, and G. Johansson. "Chemically Modified Electrodes for the Electrocatalytic Oxidation of NADH." In Contemporary Electroanalytical Chemistry, 183–89. Boston, MA: Springer US, 1990. http://dx.doi.org/10.1007/978-1-4899-3704-9_18.

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Gorton, L., B. Persson, P. D. Hale, L. I. Boguslavsky, H. I. Karan, H. S. Lee, T. A. Skotheim, H. L. Lan, and Y. Okamoto. "Electrocatalytic Oxidation of Nicotinamide Adenine Dinucleotide Cofactor at Chemically Modified Electrodes." In ACS Symposium Series, 56–83. Washington, DC: American Chemical Society, 1992. http://dx.doi.org/10.1021/bk-1992-0487.ch006.

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Conference papers on the topic "Chemically modified electrodes"

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Izumi, F., C. A. A. de Souza, S. G. dos Santos Filho, and M. R. Gongora-Rubio. "Chemically modified platinum screen-printed electrodes for electrochemical detection of acetylene." In 2016 31st Symposium on Microelectronics Technology and Devices (SBMicro). IEEE, 2016. http://dx.doi.org/10.1109/sbmicro.2016.7731323.

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Sakata, Toshiya, Shinya Matsumoto, Yoshio Nakajima, and Yuji Miyahara. "Potential Behavior of Bio-Chemically Modified Electrode for Extended Gate Field Effect Transistor." In 2004 International Conference on Solid State Devices and Materials. The Japan Society of Applied Physics, 2004. http://dx.doi.org/10.7567/ssdm.2004.p14-4.

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Mecheri, N. "P2EC.8 - Iron (III)-Selective Sensor Based on Modified Glassy Carbon Electrode." In 17th International Meeting on Chemical Sensors - IMCS 2018. AMA Service GmbH, Von-Münchhausen-Str. 49, 31515 Wunstorf, Germany, 2018. http://dx.doi.org/10.5162/imcs2018/p2ec.8.

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Delgertsetseg, Byambasuren, Khayankhyarvaa Sarangerel, Altantsetseg Delgerjargal, Namsrai Javkhlantugs, Chimed Ganzorig, Kazuyoshi Ueda, and Masaru Sakomura. "Enhanced performance in organic photovoltaic cells with chemically modified indium-tin oxide anode electrode." In 2013 8th International Forum on Strategic Technology (IFOST). IEEE, 2013. http://dx.doi.org/10.1109/ifost.2013.6616934.

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Anan, Hiroo, Kazuo Nakazato, Masao Kamahori, and Yu Ishige. "6.1.4 Redox PotentialSensor Arrayby Extended-Gate FET with Ferrocenyl-Alkanethiol Modified Gold Electrode." In 14th International Meeting on Chemical Sensors - IMCS 2012. AMA Service GmbH, Von-Münchhausen-Str. 49, 31515 Wunstorf, Germany, 2012. http://dx.doi.org/10.5162/imcs2012/6.1.4.

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Sriprachuabbwonga, Chakrit, Chanpen Karuwana, Anurat Wisitsorrata, Ditsayut Phokharatkula, Adisorn Tuantranont, and Pornpimol Sritongkham. "P2.1.3 Inkjet-printed graphene-PEDOT:PSS modified on screen printed carbon electrode for sensing applications." In 14th International Meeting on Chemical Sensors - IMCS 2012. AMA Service GmbH, Von-Münchhausen-Str. 49, 31515 Wunstorf, Germany, 2012. http://dx.doi.org/10.5162/imcs2012/p2.1.3.

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Jhai, You-Syuan, Wen Wang, Meng-Jiy Wang, and Chiapyng Lee. "Direct Electrochemistry of Glucose Oxidase Immobilized on Multi-walled Carbon Nanotubes Modified Sputtering Deposited Gold Electrodes." In 14th Asia Pacific Confederation of Chemical Engineering Congress. Singapore: Research Publishing Services, 2012. http://dx.doi.org/10.3850/978-981-07-1445-1_343.

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Paul, Subir, Saptarshi Nandi, and Sanghita Mridha. "Characterization of Bioelectrochemical Fuel Cell Fabricated With Agriculture Wastes and Surface Modified Electrode Materials." In ASME 2010 8th International Conference on Fuel Cell Science, Engineering and Technology. ASMEDC, 2010. http://dx.doi.org/10.1115/fuelcell2010-33353.

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A Bioelectrochemical fuel cell was fabricated with pretreated and fermented rice husks. The fuel was characterized with variation of process variables by determination of chemical oxygen demand (COD) which is a measure of the oxygen equivalent of electrochemically oxidizable organic fuel to produce electrical energy. The electrodes of the cell were made with nano porous anodized Al coated with Platinum, Platinum-Ruthenium and Platinum-Ruthenium-Carbon. Anodization parameters were optimized by studying E-I characteristics in sulphuric and oxalic acids with variation of concentration and temperature. Pore size in the order of 30–50 nm was obtained by a two stage anodization. The performance of the cell was evaluated by determining open circuit potential, E-I characteristics, polarization studies and cyclic voltammetry. A steady onload potential of 600–800 mV was obtained with current density in the order of 15–25 mA/cm2. High power density of 10–15 mW/cm2 has been obtained with electrode materials coated with Pt+Ru or Pt+Ru+C. The performance of coating on nanoporous structure was much reflected in the polarization studies, which showed a huge reduction of polarization resistance and increase of exchange current density by many times, the effect being more for anode in anodic solution, fermented rice husk, than with cathode in phosphate buffer cathodic solution. The surface morphology examined by SEM, showed nano deposits of Pt, Pt-Ru and the presence of carbon like structure. XRD peaks clearly reveal presence of Pt, Pt-Ru and carbon.
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Goyal, R. N., Vinod Kumar Gupta, and S. Chatterjee. "P1.1.1 Voltammetric biosensors for the determination of paracetamol at carbon nanotube modified pyrolytic graphite electrode." In 14th International Meeting on Chemical Sensors - IMCS 2012. AMA Service GmbH, Von-Münchhausen-Str. 49, 31515 Wunstorf, Germany, 2012. http://dx.doi.org/10.5162/imcs2012/p1.1.1.

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Mori, Masami, Yoshihiko Sadoaka, Shinichi Nakagawa, Masahito Kida, and Takio Kojima. "6.5.4 VOC Sensing Devices with a Planar-type Structure based on YSZ and Modified Pt Electrode." In 14th International Meeting on Chemical Sensors - IMCS 2012. AMA Service GmbH, Von-Münchhausen-Str. 49, 31515 Wunstorf, Germany, 2012. http://dx.doi.org/10.5162/imcs2012/6.5.4.

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Reports on the topic "Chemically modified electrodes"

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Elliott, C. M. Chemically modified electrodes and related solution studies. Office of Scientific and Technical Information (OSTI), April 1993. http://dx.doi.org/10.2172/6889307.

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Elliott, C. M. Chemically modified electrodes and related solution studies. Office of Scientific and Technical Information (OSTI), January 1990. http://dx.doi.org/10.2172/6547308.

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Chang, Hsiangpin. Selective electrocatalysis of anodic oxygen-transfer reactions at chemically modified, thin-film lead dioxide electrodes. Office of Scientific and Technical Information (OSTI), January 1990. http://dx.doi.org/10.2172/6974822.

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Elliott, C. M. Chemically modified electrodes and related solution studies. Final technical report, January 15, 1991--January 14, 1992. Office of Scientific and Technical Information (OSTI), April 1993. http://dx.doi.org/10.2172/10143275.

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Bergren, Adam Johan. Electron Transfer Reactivity Patterns at Chemically Modified Electrodes: Fundamentals and Application to the Optimization of Redox Recycling Amplification Systems. Office of Scientific and Technical Information (OSTI), January 2006. http://dx.doi.org/10.2172/888934.

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Bergren, Adam Johan. Electron transfet reactivity patterns at chemically modified electrodes: fundamentals and application to the optimization of redox recycling amplification systems. Office of Scientific and Technical Information (OSTI), January 2006. http://dx.doi.org/10.2172/882891.

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